EP1264562A1 - Vorrichtung zum Aufbewahren und Auftragen eines Produktes mit Fasern mit absorbierenden oder löslichen Partikeln - Google Patents

Vorrichtung zum Aufbewahren und Auftragen eines Produktes mit Fasern mit absorbierenden oder löslichen Partikeln Download PDF

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Publication number
EP1264562A1
EP1264562A1 EP02291370A EP02291370A EP1264562A1 EP 1264562 A1 EP1264562 A1 EP 1264562A1 EP 02291370 A EP02291370 A EP 02291370A EP 02291370 A EP02291370 A EP 02291370A EP 1264562 A1 EP1264562 A1 EP 1264562A1
Authority
EP
European Patent Office
Prior art keywords
particles
fibers
liquid
fiber
product
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Withdrawn
Application number
EP02291370A
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English (en)
French (fr)
Inventor
Jean-Louis Gueret
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
LOreal SA
Original Assignee
LOreal SA
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by LOreal SA filed Critical LOreal SA
Publication of EP1264562A1 publication Critical patent/EP1264562A1/de
Withdrawn legal-status Critical Current

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Classifications

    • AHUMAN NECESSITIES
    • A46BRUSHWARE
    • A46DMANUFACTURE OF BRUSHES
    • A46D1/00Bristles; Selection of materials for bristles
    • A46D1/02Bristles details
    • A46D1/023Bristles with at least a core and at least a partial sheath
    • AHUMAN NECESSITIES
    • A46BRUSHWARE
    • A46BBRUSHES
    • A46B13/00Brushes with driven brush bodies or carriers
    • A46B13/001Cylindrical or annular brush bodies
    • AHUMAN NECESSITIES
    • A46BRUSHWARE
    • A46DMANUFACTURE OF BRUSHES
    • A46D1/00Bristles; Selection of materials for bristles
    • AHUMAN NECESSITIES
    • A46BRUSHWARE
    • A46BBRUSHES
    • A46B2200/00Brushes characterized by their functions, uses or applications
    • A46B2200/10For human or animal care
    • A46B2200/1046Brush used for applying cosmetics
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00Stock material or miscellaneous articles
    • Y10T428/29Coated or structually defined flake, particle, cell, strand, strand portion, rod, filament, macroscopic fiber or mass thereof
    • Y10T428/2913Rod, strand, filament or fiber
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00Stock material or miscellaneous articles
    • Y10T428/29Coated or structually defined flake, particle, cell, strand, strand portion, rod, filament, macroscopic fiber or mass thereof
    • Y10T428/2913Rod, strand, filament or fiber
    • Y10T428/2933Coated or with bond, impregnation or core

Definitions

  • the present invention relates to the application of a product, in particular a cosmetic or care product, on the skin or the integuments.
  • cosmetic product we means a product as defined in Council Directive 93/35 / EEC of June 14, 1993.
  • the present invention relates in particular to the fibers used for the application of a product or as a filler in a product.
  • a device for packaging and / or the application of a cosmetic or care product characterized in that it comprises fibers comprising particles capable of absorbing a liquid or a compound solution in a liquid or dissolve in a liquid. These particles can be capable of absorbing at least their weight from a liquid. These particles can, in a example of implementation of the invention, be devoid of cotton.
  • fiber is meant in the sense of the present invention any body generally elongated, intended for example to constitute a bristle of mascara brush, a flock coating hair, a paintbrush, especially a paintbrush nail polish or brush for applying a powder, or to constitute a filler introduced into a product to be applied to the eyelashes, for example, to lengthen them.
  • the fibers can be relatively flexible, see elastically deformable, and be made of synthetic material.
  • the aforementioned liquid can be a cosmetically acceptable liquid, for example example of water or an aqueous, alcoholic or oily oil or solution which may be applied to the human body, this list is not exhaustive.
  • This liquid may be contained in the product to be applied.
  • At least one of said fibers may have a cross section substantially constant, being for example produced by extrusion or coextrusion of one or several thermoplastic and / or elastomeric materials.
  • Fiber can be made by coextrusion of two synthetic materials, one of them being for example charged with the above particles. These can be present at least on the surface at least part of the fibers, on their surface only or be dispersed within plastic.
  • the particles are capable of increasing by volume in contact with the product to be applied, being for example capable of swelling on contact with a solvent contained in the product to be applied, this solvent being for example the water.
  • This increase in volume can be used to create on the surface of the fiber surface irregularities, capable of forming product retention zones, which is advantageous when the fibers are used for application and are soaked in a container containing a reserve of cosmetic or care product.
  • the presence of particles capable of absorbing liquid and possibly of swelling on contact with the latter can also be useful in delaying the drying of the cosmetic or care product present on the surface of the fiber, since progressively evaporation of a solvent contained in the cosmetic or care product, for example water, the particles having absorbed this liquid can release it into the product present around the fiber.
  • Delaying the drying of the product present at the surface area of an applicator is advantageous because it not only increases the autonomy of the applicator but also to delay its drying when it is not not immersed in the product when not in use, but simply protected by a protective cover for example.
  • the particles can for example be in dry crystallized form and be able to soften on contact with a liquid, in particular a liquid contained in the product to apply. This can make the fiber more flexible after absorption of the liquid, for example water. By choosing the nature of the particles and the quantity introduced, fibers can be made with the desired flexibility.
  • the particles can for example absorb at least their weight in liquid, this being for example water.
  • hydrogonflating polymers or lipo-inflating super absorbent cross-linked polyacrylates with high swelling rates in water
  • polyvinyl alcohol carboxyvinyl polymers
  • semi-synthetic derivatives cellulose starches, bio-gums, bio-saccharides, sclero-glucans, casein, phytocolloids such as alginates, gelatin, gelans, xantane, laponite, silicas, especially colloidal silica, or mixtures thereof.
  • the particles, before swelling may have a particle size for example between 0.1 and 300 ⁇ m, or even between 5 and 200 ⁇ m, even between 10 and 150 ⁇ m.
  • the particle size of these particles will be chosen according to the roughness desired after swelling.
  • the mass proportion of said particles can be between 0 and 20%, preferably being less than or equal to 6%, dry, relative to the total weight of the fiber, before swelling.
  • the material used can be chosen so as to be able to swell on contact with the product to be applied, for example to the point of having a relative volume increase of 15%.
  • Plastic material chosen from the following: polyamides, PET, acetates, PE, PP, PVC, polyester amide block, plasticized Rilsan®, elastomers, in particular elastomers of polyester, PE elastomers, silicone elastomers, nitrile elastomers, or a mixture of these materials.
  • At least one of the fibers comprises particles capable of dissolving on contact with a liquid, for example water.
  • the particles can be water-soluble or liposoluble. The dissolution of these particles causes the appearance of roughness on the surface of the fiber and if necessary even makes the porous fiber.
  • the initial particle size of these particles can be between 0.1 and 300 ⁇ m.
  • At least one of the fibers may contain particles capable of absorbing a liquid such as water, with or without swelling.
  • the use of such particles can be advantageous in that it makes it possible to pump one or more compounds into the fiber, in order for example to confer on the latter biocidal properties, in particular bactericides.
  • the fiber may contain particles capable of absorbing preservatives in solution in a liquid, especially in aqueous solution.
  • the proportion of particles able to absorb a liquid or a compound in solution in a liquid can be in a proportion by mass understood, before putting in contact of the fiber with this liquid, between 0 and 20%, or even between 0 and 6%, compared to the total weight of the fiber.
  • the fiber can have a wide variety of cross sections, for example example a shape chosen among the following: of revolution or not, in circle, in square full or hollow, in disc with groove if necessary, in full or hollow triangle, in solid or hollow star, in U, in V, in I, in T, in Z, in -, in +, reniform, in three branches, full, hollow, or a combination of these.
  • the fiber can be twisted. At least one fiber can be substantially not tapered.
  • the packaging and application device using fibers according to the invention may or may not include a wiper member.
  • the fibers according to the invention can belong to an applicator capable of load with product, as explained above.
  • the presence of particles capable of absorbing liquid and / or swell on contact with a liquid or dissolve in a liquid can allow to confer on the bristles of the brush a certain roughness or porosity which favors the hanging of the mascara and delays its drying.
  • Particles, in particular when they are film-forming, can also deposit on the surface of the eyelashes a film which allows for example to improve the hold of the eyelashes or their appearance or to promote the sliding of the applicator.
  • the applicator may also, as a variant, be constituted by a brush and one at least the bristles of the brush consist of one of said fibers.
  • the diameter of the fibers can be for example between 0.5 and 500 ⁇ m, or even 50 and 500 ⁇ m depending on the use made of it, and their length can be understood for example between 0.5 and 50 mm, for example.
  • Fibers can also form a filler in a product cosmetic or care products, in particular a mascara, in which case the fibers contribute to eyelash lengthening. Incorporating particles capable of absorbing a liquid and / or swell on contact with the latter in the fibers can then help to improve the hold of the fibers on the eyelashes, for example.
  • Magnetic or magnetizable particles can be introduced into the same fibers as those which already contain particles capable of absorbing a liquid or swell on contact with a liquid or dissolve in a liquid or alternatively, the packaging and / or application device may include fibers containing only magnetic particles and other fibers containing particles able to absorb a liquid, swell on contact with a liquid or dissolve in liquid.
  • the magnetic particles can be particles coated with a resin, for example cyanoacrylate, or be produced by depositing a magnetic substance on a non-magnetic support, for example a glass microbead or a wood fiber.
  • the fibers have magnetic properties can allow facilitate the removal of the product, improve application on the treated surface or create new makeup effects, if necessary.
  • Magnetic properties can also promote penetration active ingredients by promoting microcirculation.
  • the fibers can be fixed or mobile.
  • particles are used able to swell on contact with said liquid, and their particle size is chosen so as to give the fiber, after swelling of said particles, a predefined roughness.
  • a fiber is extruded or coextruded plastic material comprising particles capable of dissolving in a liquid, in particular water, and said particles can be dissolved at least partially from so as to form roughness on the surface of the fiber.
  • the subject of the invention is also a fiber which can be used as a brush bristle, brush or flocking in a device for packaging and / or applying a cosmetic or care product, characterized in that it comprises, in addition to a material synthetic particles capable of absorbing at least their weight from a liquid or a compound in solution in this liquid or capable of dissolving in a liquid.
  • the invention also relates to a porous or rough fiber, obtained in particular by the above method.
  • FIGS. 1A to 9R show fibers according to the invention can be used in a packaging and / or application device such as shown in one of Figures 12 to 26, for example.
  • FIG. 1A shows a fiber comprising a charge of particles 30 of a hydro-swelling compound, before bringing the fiber into contact with a liquid, for example water, and in FIG. 1B the same fiber after contact with it liquid.
  • a liquid for example water
  • the fiber is full and has a cross section circular, but it could have other sections, as explained below.
  • the fiber can be produced for example by means of an installation shown in Figure 10, comprising an extruder 20 and a bath 21 of a liquid cooling in which the fibers are immersed as they exit the extruder.
  • the swelling of the particles 30 makes it possible to produce a relief on the surface of the fiber, such relief being useful in particular to allow the fiber to charge with a greater amount of product or to hang more eyelashes in case the fiber is used as a mascara brush bristle, for example.
  • the particles 30 may also be useful for absorbing within the fiber one or more substances, for example preservatives or active ingredients cosmetic or dermatological.
  • the fibers leaving the bath 21 are charged with the compounds which have been pumped by the particles contained in the fibers.
  • These compounds can then be gradually released on contact with a cosmetic or care product, in order to improve its conservation, for example.
  • the fibers can be dehydrated at the end of the bath 21.
  • the fibers may also contain, optionally in addition to particles 30, particles 40 soluble in a liquid, for example bath water 21 used for cool the fibers as they exit the extruder.
  • These particles 40 can be formed for example by a salt, or a sugar soluble in the liquid used, or even gelatin when the liquid is water.
  • FIG. 2A shows a fiber containing such particles 40, before dissolution, that is to say for example just at the outlet of the extruder 20 and in FIG. 2B the same fiber after passing through the bath 21.
  • the soluble particles 40 that were present on the surface of the fiber have been dissolved by the liquid in the bath 21, creating a roughness on the surface of the fiber, or even making the fiber porous.
  • Such roughness or porosity can be used to increase loading the fiber with product, for example.
  • the roughness or porosity obtained will depend on the initial particle size of the particles 40.
  • the particles 40 may also be dissolved only partially upon leaving bath 21, so that they continue to dissolve on contact with the cosmetic or care product present at their area.
  • the particles 40 may consist of one or more substances having a cosmetic or dermatological effect. In this case, the dissolution of the particles 40 at contact with the product may be accompanied by the release of these substances on the surface treated.
  • the fibers may, where appropriate, be exposed to shocks intended to cause or to facilitate the departure of the particles 40 present at the surface.
  • the particles 40 can also be produced from a material which is not soluble in bath water 21 but which is only gradually soluble in the cosmetic or care product present in contact with fibers.
  • a gel layer 51 can modify for example the affinity of the fiber with the cosmetic or care product in contact with it.
  • the gel can still deposit on the treated surface, for example the eyelashes, to improve their hold, their appearance or the sliding of the applicator on contact.
  • the use of particles capable of absorbing a liquid, in particular of water, can still have the advantage of delaying the drying of a composition cosmetic or care on the surface of the fiber, when the liquid absorbed by the particles is likely to be released gradually to compensate for the evaporation of a solvent contained in the composition.
  • particles 30, 40 or 50 can also make it possible to create at the fiber surface of the preferred anchoring zones for the product, for example thanks to the affinity of the particles used with respect to the hydrophilic or lipophilic compounds contained in the product.
  • the latter can optionally be an oil / water emulsion and the fibers absorb only oil or water, and more generally absorb a component of the selectively produced.
  • Particles 30, 40 or 50 may, if necessary, be present on the surface only fibers, as shown in Figure 4.
  • the initial particle size of particles 30, 40 or 50 is understood by example between 1 and 300 ⁇ m, even between 5 and 200 ⁇ m, or even between 10 and 150 ⁇ m.
  • the proportion of particles 30, 40 or 50 is for example between 0 and 20% in mass, or even between 0 and 6% by mass, dry.
  • the fibers may also contain magnetic particles 12 dispersed substantially homogeneously within the plastic 11.
  • the magnetic particles 12 can still be deposited only at the surface of the fibers, by a suitable process, for example coating, as illustrated in the Figure 8A or confined inside the fiber, as illustrated in Figure 8B.
  • a suitable process for example coating, as illustrated in the Figure 8A or confined inside the fiber, as illustrated in Figure 8B.
  • the mass proportion of magnetic particles can be understood by example between 0.2 and 30%.
  • FIGS. 6A and 6B correspond to a fiber which differs from that of the figures 2A and 2B by the presence of magnetic particles 12.
  • Figure 7 shows the fiber of Figure 3 with magnetic particles 12 dispersed throughout its mass.
  • the fibers can be given very diverse cross sections, other than full circular, as will now be described with reference to FIGS. 9A to 9R.
  • the fibers can be extruded with a flat cross section, as illustrated in FIG. 9A, crosswise as shown in FIG. 9B, in the shape of a star three branches, as illustrated in Figure 9C.
  • Fibers can have a section hollow, as shown in Figure 9D or solid with a capillary groove, as illustrated in Figure 9E.
  • the fibers may also have a U-shaped cross section, as illustrated in figure 9F, a cross section in I as illustrated in figure 9H, in T as illustrated in FIG. 9I, in V as illustrated in FIG. 9J, in Z as illustrated in figure 9K or a combination of the above forms, for example the combination shown in FIG. 9G of the shapes corresponding to FIGS. 9B and 9C.
  • FIG. 9G of the shapes corresponding to FIGS. 9B and 9C.
  • the fibers When the fibers contain magnetic particles, the fibers can be exposed to a magnetic field of magnetization at the exit of the bath 21, by means of a magnetization device 60, as illustrated in FIG. 11, in order for example to be magnetized with a predefined polarity. Magnetization of fibers, if any, can also take place after incorporation of these fibers in a packaging and / or application, by submitting this device or a batch of these devices with a magnetization field. Magnetizing fibers only once these in place in the packaging and / or application device can allow to facilitate manufacturing by limiting the risks of fiber agglomeration.
  • the fibers can be used in various applicators and devices conditioning, as will now be described.
  • FIG. 12 shows a packaging device and 100, comprising a container 101 to contain a product P to be applied as than a mascara and an applicator 102.
  • the container 101 is provided with a wiper member 106 which can, in a variant not shown, be flocked.
  • Applicator 102 includes a rod 103, provided at one end with a gripping member 104 also constituting a closure cap for the container 101 and at the other end of a brush 105. This the latter has a core consisting of a twisted metal wire, in whose turns are retained hairs consisting of fibers which have just been described, comprising or not magnetic particles.
  • 28A and 28B have illustrated the effect of lateral deviation of the bristles of the brush in the event of a transverse magnetic field.
  • the magnetization of the hairs can also be used only to exercise during the application of the product to the eyelashes a magnetic field having a beneficial action on these or on part of the face, for example the eyelids.
  • the magnetic field exerted by the bristles of the brush is liable to change over time, in particular when the brush configuration is changed, for example when removing the the applicator or during application.
  • Product P may have properties magnetic, for example containing magnetizable or magnetized particles. In the case where product P has magnetic properties, having brush bristles that also have magnetic properties can help promote the loading of the brush with product, for example by attraction of the product by the bristles the brush.
  • the product may still contain fibers or flakes having magnetic properties and the applicator interact magnetically with these glitters, to bring them for example in a particular orientation at the time of application, so for example to favor the sliding of the applicator
  • FIG. 13 shows a device 110 for packaging and applying a nail polish, comprising a container 111 and an applicator 112 comprising a rod 113 provided at one end with a gripping element 114 also constituting a closure cap for the container and at the other end of a brush 115 comprising a bundle of relatively grouped bristles.
  • These last are made from fibers according to the invention with or without properties magnetic, which can be used if necessary to bring the hairs of the brush 115 in a predefined orientation, in order to facilitate the loading of the brush 115 in product or exert an action on the treated surface.
  • interactions magnetic between the bristles of the brush according to the polarity of the magnetic field of each hair, can contribute to group the hairs or on the contrary to spread them.
  • FIGs 29A and 29B an effect bristle spacing due to magnetic interactions between the bristles.
  • Product P can whether or not they have magnetic properties.
  • FIG. 15 shows a packaging device and application 130 of a product P, in particular a liquid lipstick, comprising a end piece 131 covered by a flocking 132 produced with fibers according to the invention having magnetic properties or not.
  • FIG. 16 shows a brush 140 intended for applying a powder, the bristles of which are produced with fibers according to the invention, having magnetic properties or not.
  • an applicator 150 having a foam 151 covered on its surface by a flocking 152 made of fibers according to the invention, having magnetic properties or not.
  • Such an applicator can be used for example to apply a blush on the skin.
  • FIG. 18A shows a liquid lipstick applicator 160 comprising a tip 161 in flocked elastomer and in FIG. 18B an eyeliner 160 ′ also comprising a tip 161 ′ in flocked elastomer.
  • the hairs flocking consist of fibers according to the invention, having properties magnetic or not.
  • the fibers according to the invention can also be used to produce a flocking a powder puff 170, as illustrated in figure 19 or a sponge with remove makeup 180, shown in Figure 20.
  • the flock coating may also extend over a film 191 fixed on a foam block 192, as is the case in the applicator 190 shown in FIG. 21.
  • fibers according to the invention whether or not having magnetic properties, in a 200 disc or a towel comprising at least one layer 201 of a nonwoven or of a fabric incorporating said fibers, as illustrated in the figure 22.
  • FIG. 23 shows a comb 210 for applying a product on the eyelashes, comprising flocked teeth 211.
  • the hairs of the flocking are produced with fibers according to the invention, having magnetic properties or not.
  • the applicator may include one or more monoblock magnets in addition to fibers with magnetic properties.
  • FIG. 24 shows an applicator 220 comprising a handle 221 on which is fixed a magnet 222.
  • the latter is covered by a block of foam 223, itself coated externally by a flocking 224 consisting of fibers with magnetic properties.
  • the presence of magnet 222 allows subject the hairs of flocking 294 to a magnetic field.
  • the hairs of the flocking which connects substantially perpendicular to the underlying support can be oriented along the lines of this magnetic field M, as illustrated on the figure 27.
  • the hairs tend to stand up on the surface of the application element or take other orientations according to the position relative to the magnet 222, which allows for example loading the applicator with more product or rendering the application softer.
  • the product is a powder brought into contact with the applicator and that the latter has magnetic properties, the powder particles tend to deposit on the applicator, especially on the fibers, and this reduces the risk of steal the powder and the sternutatory effect.
  • FIG. 25 shows a device 230 in which the product is contained in a flexible pocket 231 surmounted by a pump 232.
  • the applicator comprises a foam 234, coated on its surface with a flocking 235 and secured to a cover 236.
  • a magnet 237, housed in the foam 234 is carried by the cover 236.
  • the hairs of the flocking 235 are made with fibers according to the invention, having magnetic properties, and are subjected to the magnetic field of magnet 237, like the example of embodiment previous.
  • an applicator 280 comprising a flocked end piece 282 housed under a cover 281 when not in use.
  • the use of fibers containing hydroabsorbents or hydrogonflants helps maintain humid atmosphere under the hood, delaying the drying out of the nozzle, which could be replaced by other application elements, for example a brush or a paint brush.
  • the product P can contain magnetic particles 241 and the applicator have properties magnetic, for example because it consists of a flocked tip whose flocking coating consists of fibers according to the invention, magnetized.
  • the tip 242 is capable of attracting the magnetic particles 241 contained in the product.
  • the mesh size of the sieve 240 we can ensure that these particles magnets 241 attracted by the end piece 242 do not pass through the screen 240 but move from the product P to the end piece 242, which improves the loading of the end piece 242 in product.
  • the product P itself is magnetic, comprising for example magnetic coated particles, and can pass through the meshes of the sieve 240.
  • the fibers can be magnetized over only part of their length.

Landscapes

  • Brushes (AREA)
  • Cosmetics (AREA)
  • Coating Apparatus (AREA)
  • Containers And Packaging Bodies Having A Special Means To Remove Contents (AREA)
  • Closures For Containers (AREA)
  • Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
EP02291370A 2001-06-05 2002-06-04 Vorrichtung zum Aufbewahren und Auftragen eines Produktes mit Fasern mit absorbierenden oder löslichen Partikeln Withdrawn EP1264562A1 (de)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
FR0107308A FR2825246B1 (fr) 2001-06-05 2001-06-05 Dispositif de conditionnement et/ou d'application comprenant des fibres comportant des particules capables d'absorber un liquide ou un compose en solution dans ce liquide ou de se dissoudre dans un liquide
FR0107308 2001-06-05

Publications (1)

Publication Number Publication Date
EP1264562A1 true EP1264562A1 (de) 2002-12-11

Family

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EP02291370A Withdrawn EP1264562A1 (de) 2001-06-05 2002-06-04 Vorrichtung zum Aufbewahren und Auftragen eines Produktes mit Fasern mit absorbierenden oder löslichen Partikeln

Country Status (8)

Country Link
US (1) US20020182409A1 (de)
EP (1) EP1264562A1 (de)
JP (2) JP2003125846A (de)
CN (1) CN1246197C (de)
BR (1) BR0202112A (de)
CA (1) CA2389556C (de)
FR (1) FR2825246B1 (de)
MX (1) MXPA02005565A (de)

Cited By (9)

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Publication number Priority date Publication date Assignee Title
WO2006037903A1 (fr) 2004-10-05 2006-04-13 L'oreal Procede de maquillage au moyen d'une composition magnetique incorporant au moins un agent de coloration ayant des proprietes optiques sensibles a un stimulus exterieur
EP2123189A1 (de) * 2008-05-20 2009-11-25 Braun Gmbh Zahnbürste, Zahnbürstenfaser und Verfahren zu deren Herstellung
US7981404B2 (en) 2004-04-08 2011-07-19 L'oreal S.A. Composition for application to the skin, to the lips, to the nails, and/or to hair
US8007772B2 (en) 2002-10-02 2011-08-30 L'oreal S.A. Compositions to be applied to the skin and the integuments
WO2012168894A1 (en) 2011-06-07 2012-12-13 L'oreal An assembly including a composition containing fibers for making-up the eyelashes
US8544475B2 (en) 2005-08-30 2013-10-01 L'oreal Packaging and applicator assembly including a magnetic device, a magnetic device, a method of forming a pattern on a nail using a magnetic device and a method of manufacturing a magnetic device
FR3014299A1 (fr) * 2013-12-09 2015-06-12 Oreal Necessaire de produit cosmetique comprenant au moins un lot de produit cosmetique et un applicateur
WO2016016436A1 (de) * 2014-07-31 2016-02-04 Geka Gmbh Applikator mit borsten aus partikelgefülltem kunststoff
US9649261B2 (en) 2004-10-05 2017-05-16 L'oreal Method of applying makeup to a surface and a kit for implementing such a method

Families Citing this family (23)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20060039876A1 (en) * 2002-10-02 2006-02-23 Christophe Dumousseaux Compositions to be applied to the skin and the integuments
FR2860960B1 (fr) * 2003-10-17 2007-03-30 Oreal Applicateur d'un produit, notamment cosmetique
US20050257715A1 (en) * 2004-04-08 2005-11-24 Christophe Dumousseaux Compositions for application to the skin, to the lips, to the nails, and/or to hair
US20050260146A1 (en) * 2004-04-08 2005-11-24 Xavier Blin Set of at least two solid compositions for application to the skin, to the lips, to the nails, and/or to hair
FR2870697B1 (fr) * 2004-05-25 2006-08-11 Oreal Dispositif de conditionnement et d'application d'un produit
FR2882506B1 (fr) 2005-02-25 2007-05-18 Oreal Procede de maquillage au moyen d'un applicateur vibrant
FR2914163B1 (fr) * 2007-04-02 2009-06-05 Oreal Applicateur pour appliquer une composition sur les cils
FR2914162B1 (fr) * 2007-04-02 2010-10-29 Oreal Applicateur pour appliquer une composition sur les cils
US8568049B2 (en) * 2010-03-16 2013-10-29 Geka Gmbh Mascara brush with eyelash retaining member
JP5936599B2 (ja) * 2010-03-29 2016-06-22 ロレアルL′Oreal ヒトのケラチン繊維に繊維を貼着するための装置
US20140008258A1 (en) * 2010-10-27 2014-01-09 Kraft Foods Global Brands Llc Magnetically closable product accommodating package
CN102462151B (zh) 2010-11-05 2016-05-11 Hct亚洲有限公司 具有磁性细丝的刷子
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EP3174434A1 (de) * 2014-07-31 2017-06-07 GEKA GmbH Drahtkernapplikator mit mehrmaterialborsten
EP3174432A1 (de) * 2014-07-31 2017-06-07 GEKA GmbH Applikator mit borsten aus partikelgefülltem kunststoff
US10499725B2 (en) 2014-07-31 2019-12-10 Geka Gmbh Applicator with bristles of particle-filled plastic
EP3174434B1 (de) * 2014-07-31 2022-01-05 GEKA GmbH Drahtkernapplikator mit mehrmaterialborsten

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MXPA02005565A (es) 2004-07-16
CA2389556C (fr) 2008-09-30
US20020182409A1 (en) 2002-12-05
JP2003125846A (ja) 2003-05-07
CN1389379A (zh) 2003-01-08
CN1246197C (zh) 2006-03-22
FR2825246B1 (fr) 2004-06-04
BR0202112A (pt) 2003-05-20
CA2389556A1 (fr) 2002-12-05
FR2825246A1 (fr) 2002-12-06

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