EP1257687A2 - Verfahren und einrichtung zum beizen von gewalztem metall-, insbesondere von stahlband - Google Patents

Verfahren und einrichtung zum beizen von gewalztem metall-, insbesondere von stahlband

Info

Publication number
EP1257687A2
EP1257687A2 EP01919285A EP01919285A EP1257687A2 EP 1257687 A2 EP1257687 A2 EP 1257687A2 EP 01919285 A EP01919285 A EP 01919285A EP 01919285 A EP01919285 A EP 01919285A EP 1257687 A2 EP1257687 A2 EP 1257687A2
Authority
EP
European Patent Office
Prior art keywords
pickling
measured values
coil
scale
measured
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Withdrawn
Application number
EP01919285A
Other languages
German (de)
English (en)
French (fr)
Inventor
Rolf BÜNTEN
Rolf Brisberger
Bodo Block
Jürgen Seidel
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
SMS Siemag AG
Original Assignee
SMS Demag AG
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from DE10062869A external-priority patent/DE10062869A1/de
Application filed by SMS Demag AG filed Critical SMS Demag AG
Publication of EP1257687A2 publication Critical patent/EP1257687A2/de
Withdrawn legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23GCLEANING OR DE-GREASING OF METALLIC MATERIAL BY CHEMICAL METHODS OTHER THAN ELECTROLYSIS
    • C23G3/00Apparatus for cleaning or pickling metallic material
    • C23G3/02Apparatus for cleaning or pickling metallic material for cleaning wires, strips, filaments continuously
    • C23G3/027Associated apparatus, e.g. for pretreating or after-treating
    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23GCLEANING OR DE-GREASING OF METALLIC MATERIAL BY CHEMICAL METHODS OTHER THAN ELECTROLYSIS
    • C23G1/00Cleaning or pickling metallic material with solutions or molten salts
    • C23G1/02Cleaning or pickling metallic material with solutions or molten salts with acid solutions
    • C23G1/08Iron or steel

Definitions

  • the invention relates to a method and a device for pickling metal, in particular steel strip, which is fed to a controlled pickling process.
  • a method for pickling a metal strip is known from DE 19743 022 A1, which is based on a measurement in the direction of flow behind the pickling system and in which pickling parameters are set according to defect categories that the measuring device detects, such as Temperature of the pickling liquid, throughput speed of the metal strip, the acid content in the pickling liquid, the metal content, in particular the iron content, strip parameters, e.g. Material and geometrical dimensions.
  • the defects can only be determined retrospectively and conclusions can be drawn about a cheaper stain.
  • the controlled system only covers the pickling system itself.
  • EP 0482725 A1 Another known method (EP 0482725 A1) works with turbulent flows which are generated in the pickling tank by nozzles. The aim is to achieve an optimal pickling result with minimal consumption of pickling medium. This result is to be achieved by regulating the turbulence of the flow in the pickling medium as a function of the throughput speed of the strip to be pickled. Further effects are not expected.
  • Another method for pickling a rolled strip in a pickling plant is known from EP 0602437 B1. The process is based on a special mode of operation of several pickling tanks connected in series.
  • An acidic pickling medium is injected into the pickling tank via injection nozzles arranged at least on the side, above and below the belt running level on the pool, the nozzles being variably controlled and the pickling medium being input in any desired quantity.
  • the acid concentration and / or the medium temperature and / or the nozzle outlet speed of the pickling medium can be preselected.
  • the object of the invention is to carry out the pickling process not only on the basis of the usual pickling parameters, but also to take additional parameters outside the pickling tank into account.
  • the object is achieved according to the invention in that the pickling process in addition to the pickling medium parameters is regulated on the basis of parameters of the coil and / or the metal strip that have been determined and / or measured before the metal strip enters the pickling part.
  • the advantage is to set the pickling parameters in advance so that under or over pickling is avoided, the acid concentration and the acid supply are set correctly and the pickling medium is used economically so that the correct temperature can be calculated in advance together with other pickling parameters to be set in advance. After casting, hot forming and after annealing removed scale, pre-descaling and other deposits can already be taken into account.
  • the invention therefore also takes into account the fact that the scale has broken up (via stretch bending straighteners), with cracks and pores in the scale layer which enlarge the surface wetted by acid.
  • the amount of scale to be dissolved in the pickling process can be reduced, so that the pickling time is reduced depending on the type of pre-descaling can be. If the temperature of the metal strip is increased before it runs into the stain, the contact time between the strip surface and the pickling medium is extended at the optimum pickling temperature. The heating distance of the metal strip is shortened and the pickling time is reduced. The pickling time also decreases if the scale is removed by laser optics before entering the pickle and the amount of scale to be removed is reduced.
  • the method is used in such a way that the pickling process is preset with measured values of a coil on the basis of a built-up calculation model and on the basis of a control calculation model that at least measures values for scale; Strip temperature; Pickling medium temperature and / or acid concentration is taken into account, is regulated.
  • the amount of scale needs e.g. no longer being valued, as has been the case so far.
  • the goal of such an optimization can be: minimal energy consumption, more variable coil sequences, accelerated reaction to the type and amount of surface contamination, minimization of pickling consumption and pickling losses, minimization of over-pickling and minimization of under-pickling.
  • measuring devices for detecting the scale its layer thickness, shape, distribution and color can be used. Exact calculation models are used for this.
  • actuators of the pickling are regulated or readjusted. This enables regulation of the pickling section with the shortest possible transmission times.
  • the procedure is such that additional measured values for scale deposits or deposits are recorded in an area in the direction of movement in front of the pickling part and are used for readjusting the actuators of the pickling part and / or for comparing measured or calculated values. Additional parameters outside the pickling section are taken into account in that the pickling times are regulated based on the strip entrance information of the coil and the machine setting.
  • Another method step provides that the recorded measured values via the deposits or the scale are used for regulating a pretreatment unit upstream of the pickling part.
  • the pickling medium can be regulated even more precisely in its parameters due to the pretreatment unit.
  • pretreatment unit and the actuators of the pickling part are readjusted in comparison with the measured or calculated values.
  • the device for pickling rolled metal, in particular steel strip, which can be fed in the treatment direction from a coil of a pickling system, for which a control of several parameters is provided solves the task in that coil measurement or information sensors have a structure - Computational model Measured values can be switched to the control units of the pickling section using a control computing model. This allows the pickling section to be operated more economically and more precisely, which leads to the advantages mentioned.
  • measured values from coil measured value sensors can be entered into the control calculation model.
  • the construction computing model uses general input information for the metal strip. From this, scale orders can already be calculated using calculation approaches to preset or adjust the slow and fast actuators of the pickling section.
  • measured values from a transducer via the linings or the scale can be used to readjust the actuator of the pickling part.
  • the pickling part is preceded by a pretreatment unit, the measured values of which can be input into the control computing model.
  • the pretreatment unit can influence the pickling time if the necessity is recognized and the coil information and the current machine setting are evaluated appropriately.
  • the pretreatment unit can be a preheating unit, a mechanical, an abrasive, a hydromechanical, a laser-optical or a vibration descaler.
  • a further improvement is given by the fact that an induction heater for the strip is switched on between the pretreatment unit and the pickling part.
  • the inductive preheating of the metal strip is switched on before the pickling and is used to quickly regulate the metal strip temperature and to set the metal strip pickling temperature.
  • Fig. 1 is a block diagram of the coil and pickling plant with control in one
  • FIG. 3 shows the block diagram in a second variant with a pretreatment unit
  • Fig. 4 shows the block diagram in a third variant with the transducer and the pretreatment unit and
  • Fig. 5 shows the block diagram in a fourth variant with the sensor, the pretreatment unit and an induction heater.
  • the metal strip 1 runs from a coil 2 into the pickling section 3.
  • coil information 4 is input by an information sensor 4a and an information sensor 4b into a superstructure computing model 6 and / or into a control computing model 8 and processed according to the program. Further measured values 7 can be taken into account in the construction computing model 6.
  • the pickling process is regulated on the basis of parameters of the coil 2 and / or the metal strip 1 that have been determined and / or measured with actuators before the metal strip 1 enters the pickling part 3 within the machine 5.
  • a scale determination 10 On the basis of a first variant according to FIG. 2, in addition to the presetting of the pickling parameters, additionally measured values about the deposits or the scale are processed in a scale determination 10 with a measurement sensor M in the control computing model 8.
  • the pickling process is preset in each case (FIGS. 1 to 5) on the basis of the built-up computing model 6 with measured values of the coil 2 and is regulated on the basis of the regulating computing model 8, which takes into account at least measured values for scale, bath temperature, pickling medium temperature and / or acid concentration.
  • the additionally measured values for scale deposits in front of the pickling part 3 are used to regulate or readjust the actuators in the machine 5.
  • a pretreatment unit H which influences the pickling time.
  • the slow and fast actuators of the pickling part 3 are readjusted in the comparison of measured or calculated values from the control computing model 8, in particular taking into account the changed pickling times.
  • a third variant additional measured values for scale deposits or deposits are recorded in parallel by the measurement sensor M of the scale detector 10 in the direction of movement 9 in front of the pickling part 3 and for the adjustment of the members of the pickling part 3 and / or used in the comparison of measured or calculated values.
  • the pickling times are regulated on the basis of strip input information from coil 2 and the machine setting.
  • the measured values recorded on the deposits or the scale are used to regulate a pretreatment unit H upstream of the pickling part 3.
  • the pre-treatment unit H and the actuators of the pickling part 3 are readjusted in comparison with the measured or calculated values.
  • an induction heater W is switched on between the pickling part 3 and the pretreatment unit H in addition to the scale detection 10 and the pretreatment unit H.
  • the pickling time is defined as the contact time between the surface to be cleaned and the pickling medium, which is necessary to reliably remove the dirt from the metal strip 1.
  • the pretreatment unit H can also accommodate the preheating unit in the form of the induction heater W.
  • the pretreatment unit H basically has a mechanical, abrasive, hydromechanical, laser-optical or vibration-technical descaler.
  • An inductive preheating of the metal strip 1 by the induction heater W is installed in front of the pickling part 3 and serves to quickly regulate the metal strip and the pickling medium temperature.

Landscapes

  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Mechanical Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Cleaning And De-Greasing Of Metallic Materials By Chemical Methods (AREA)
  • ing And Chemical Polishing (AREA)
EP01919285A 2000-02-16 2001-02-15 Verfahren und einrichtung zum beizen von gewalztem metall-, insbesondere von stahlband Withdrawn EP1257687A2 (de)

Applications Claiming Priority (5)

Application Number Priority Date Filing Date Title
DE10007080 2000-02-16
DE10007080 2000-02-16
DE10062869 2000-12-16
DE10062869A DE10062869A1 (de) 2000-02-16 2000-12-16 Verfahren und Einrichtung zum Beizen von gewalztem Metall-, insbesondere von Stahlband
PCT/EP2001/001683 WO2001061073A2 (de) 2000-02-16 2001-02-15 Verfahren und einrichtung zum beizen von gewalztem metall-, insbesondere von stahlband

Publications (1)

Publication Number Publication Date
EP1257687A2 true EP1257687A2 (de) 2002-11-20

Family

ID=26004374

Family Applications (1)

Application Number Title Priority Date Filing Date
EP01919285A Withdrawn EP1257687A2 (de) 2000-02-16 2001-02-15 Verfahren und einrichtung zum beizen von gewalztem metall-, insbesondere von stahlband

Country Status (12)

Country Link
US (1) US20030015259A1 (pt)
EP (1) EP1257687A2 (pt)
JP (1) JP2003528978A (pt)
CN (1) CN1401015A (pt)
AU (2) AU4643601A (pt)
BR (1) BR0107950A (pt)
CA (1) CA2399754A1 (pt)
CZ (1) CZ20022770A3 (pt)
PL (1) PL362146A1 (pt)
RU (1) RU2002124590A (pt)
SK (1) SK11852002A3 (pt)
WO (1) WO2001061073A2 (pt)

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Publication number Priority date Publication date Assignee Title
DE10031978A1 (de) * 2000-06-30 2002-01-10 Sms Demag Ag Verfahren und Vorrichtung zur automatischen Zundererkennung aus Oberflächen von metallischem Bandgut, insbesondere von warmgewalztem Stahlband und Edelstahlband
KR100899687B1 (ko) * 2002-08-23 2009-05-28 주식회사 포스코 열연강판의 산세방법
WO2010006895A1 (de) * 2008-07-16 2010-01-21 Siemens Aktiengesellschaft Betriebsverfahren für eine ein metallband bearbeitende bearbeitungseinrichtung und anlage zum bearbeiten eines metallbandes
CN102220595A (zh) * 2011-05-31 2011-10-19 马鞍山钢铁股份有限公司 热轧钢带酸洗的感应加热方法及其装置
CN106238470A (zh) * 2015-06-09 2016-12-21 宝山钢铁股份有限公司 考虑拉矫破鳞效果的酸洗时间预报方法
ES2826411T3 (es) 2015-07-22 2021-05-18 Kolene Corp Procedimiento de acondicionamiento de incrustaciones para aleaciones de acero al carbono avanzado de alta resistencia
CN105648460B (zh) * 2016-03-14 2018-02-13 佛山市网冠金属制品有限公司 一种智能喷涂系统及方法
CN106825080A (zh) * 2017-01-11 2017-06-13 首钢京唐钢铁联合有限责任公司 一种去除汽车板用钢红锈缺陷的方法
IT201700056336A1 (it) * 2017-05-24 2018-11-24 Danieli Off Mecc Impianto di pulizia per prodotti metallici
DE102018117475A1 (de) * 2018-07-19 2020-01-23 Sms Group Gmbh Beizanlage zur Oberflächenbehandlung von Bandstahl
WO2020216959A1 (de) * 2019-04-25 2020-10-29 Hydro Aluminium Rolled Products Gmbh Oberflächenbehandlung von flachprodukten aus aluminiumlegierungen umfassend farbmessungen
CN115135805A (zh) * 2020-02-18 2022-09-30 株式会社Posco 工艺控制系统及其操作方法
CN111519194B (zh) * 2020-03-27 2022-02-11 佛山津西金兰冷轧板有限公司 一种冷轧板制造工艺
CN115044917B (zh) * 2022-06-21 2023-10-03 北京首钢冷轧薄板有限公司 热轧带钢酸洗速度确定方法及装置

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US4325746A (en) * 1979-10-01 1982-04-20 Olin Corporation System for cleaning metal strip
KR900007072B1 (ko) * 1985-03-15 1990-09-28 신닛뽄 세이데쓰 가부시끼가이샤 냉간압연 강스트립의 제조방법 및 장치
US5175502A (en) * 1990-09-14 1992-12-29 Armco Steel Company, L.P. Method and apparatus for determining acid concentration
JPH05202419A (ja) * 1992-01-27 1993-08-10 Kawasaki Steel Corp けい素鋼熱延板の脱スケール方法
FR2701410B1 (fr) * 1993-02-12 1995-05-05 Clecim Sa Installation de décapage d'une bande métallique.
AT404030B (de) * 1995-02-15 1998-07-27 Andritz Patentverwaltung Verfahren zur beize von materialien aus stahl, insbesondere edelstahl
KR100464580B1 (ko) * 1997-03-03 2005-02-28 가부시끼가이샤 히다치 세이사꾸쇼 산세정플랜트의제어방법과그산세정플랜트
DE19743022A1 (de) * 1997-09-29 1999-04-01 Siemens Ag Verfahren und Einrichtung zum Beizen eines Metallbandes
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Also Published As

Publication number Publication date
RU2002124590A (ru) 2004-03-20
JP2003528978A (ja) 2003-09-30
CA2399754A1 (en) 2001-08-23
CZ20022770A3 (cs) 2003-03-12
PL362146A1 (en) 2004-10-18
WO2001061073A3 (de) 2002-04-25
BR0107950A (pt) 2004-01-06
CN1401015A (zh) 2003-03-05
WO2001061073A2 (de) 2001-08-23
US20030015259A1 (en) 2003-01-23
AU4643601A (en) 2001-08-27
AU2001246436A2 (en) 2001-08-27
SK11852002A3 (sk) 2002-12-03

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