EP1205403B1 - Unit for storing and dispensing a product under pressure - Google Patents
Unit for storing and dispensing a product under pressure Download PDFInfo
- Publication number
- EP1205403B1 EP1205403B1 EP01402589A EP01402589A EP1205403B1 EP 1205403 B1 EP1205403 B1 EP 1205403B1 EP 01402589 A EP01402589 A EP 01402589A EP 01402589 A EP01402589 A EP 01402589A EP 1205403 B1 EP1205403 B1 EP 1205403B1
- Authority
- EP
- European Patent Office
- Prior art keywords
- dispensing
- nozzle
- cap
- valve
- product
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
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Classifications
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B65—CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
- B65D—CONTAINERS FOR STORAGE OR TRANSPORT OF ARTICLES OR MATERIALS, e.g. BAGS, BARRELS, BOTTLES, BOXES, CANS, CARTONS, CRATES, DRUMS, JARS, TANKS, HOPPERS, FORWARDING CONTAINERS; ACCESSORIES, CLOSURES, OR FITTINGS THEREFOR; PACKAGING ELEMENTS; PACKAGES
- B65D83/00—Containers or packages with special means for dispensing contents
- B65D83/14—Containers or packages with special means for dispensing contents for delivery of liquid or semi-liquid contents by internal gaseous pressure, i.e. aerosol containers comprising propellant for a product delivered by a propellant
- B65D83/40—Closure caps
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B65—CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
- B65D—CONTAINERS FOR STORAGE OR TRANSPORT OF ARTICLES OR MATERIALS, e.g. BAGS, BARRELS, BOTTLES, BOXES, CANS, CARTONS, CRATES, DRUMS, JARS, TANKS, HOPPERS, FORWARDING CONTAINERS; ACCESSORIES, CLOSURES, OR FITTINGS THEREFOR; PACKAGING ELEMENTS; PACKAGES
- B65D83/00—Containers or packages with special means for dispensing contents
- B65D83/14—Containers or packages with special means for dispensing contents for delivery of liquid or semi-liquid contents by internal gaseous pressure, i.e. aerosol containers comprising propellant for a product delivered by a propellant
- B65D83/16—Containers or packages with special means for dispensing contents for delivery of liquid or semi-liquid contents by internal gaseous pressure, i.e. aerosol containers comprising propellant for a product delivered by a propellant characterised by the actuating means
- B65D83/20—Containers or packages with special means for dispensing contents for delivery of liquid or semi-liquid contents by internal gaseous pressure, i.e. aerosol containers comprising propellant for a product delivered by a propellant characterised by the actuating means operated by manual action, e.g. button-type actuator or actuator caps
- B65D83/205—Actuator caps, or peripheral actuator skirts, attachable to the aerosol container
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B65—CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
- B65D—CONTAINERS FOR STORAGE OR TRANSPORT OF ARTICLES OR MATERIALS, e.g. BAGS, BARRELS, BOTTLES, BOXES, CANS, CARTONS, CRATES, DRUMS, JARS, TANKS, HOPPERS, FORWARDING CONTAINERS; ACCESSORIES, CLOSURES, OR FITTINGS THEREFOR; PACKAGING ELEMENTS; PACKAGES
- B65D83/00—Containers or packages with special means for dispensing contents
- B65D83/14—Containers or packages with special means for dispensing contents for delivery of liquid or semi-liquid contents by internal gaseous pressure, i.e. aerosol containers comprising propellant for a product delivered by a propellant
- B65D83/44—Valves specially adapted therefor; Regulating devices
- B65D83/46—Tilt valves
Definitions
- the present invention relates to a device for conditioning and dispensing under pressure of a product according to the preamble of claim 1, in particular cosmetic.
- a product can be in the form of a liquid, a foam, or a more viscous consistency, especially in the form of a cream or a gel.
- the invention can be used especially for the packaging and distribution of a care product, a make-up product, a hair product or personal hygiene product, or a skin protection product against the effects of sun radiation.
- the product may be pressurized at medium of a propellant gas, liquefied or not.
- the gas can be conditioned, directly in contact with the product, or separately via a piston or pocket with soft walls.
- Patent Application FR-A-2,635,085 describes a pump-type dispenser or valve comprising a container containing the product.
- the container is topped of a valve, and a dispensing head for actuating the pump or the valve, and dispensing the product via at least one dispensing orifice.
- a cap is mounted clamping on the dispensing tip between two uses.
- the dispensing orifice in the mounted position of the hood, is not closed by waterproof way.
- the dispensing orifice as well as the channel opening onto the dispensing orifice are subject to fouling, which risks make the device totally unusable, especially after a long period not in use.
- the residual product in the canal and in the vicinity of the opening is likely to deteriorate, in particular by oxidation, and to be unattractive appearance.
- the hood configuration is changed so that in the mounted position on the dispensing nozzle, the dispensing orifice is closed sealingly by a corresponding portion of the hood, in particular by its bottom, then the risks are even greater for that, by mounting the hood on the device, it an inadvertent actuation of the dispensing element occurs.
- US-A-2 767 888 discloses a device in which a cap is screwed on a dispensing nozzle, the latter being mounted on a valve stem.
- a cap is screwed on a dispensing nozzle, the latter being mounted on a valve stem.
- Such a design suffers from several disadvantages. The first is the fact that there is no coupling in rotation between the tip and the mounting hoop. Of this fact, it is not excluded that the cap may not be screwed so sufficient. In addition, if the cap were to be screwed sufficiently, then is not excluded that during the unscrewing movement, the tip turns with the hood, making the removal of the latter impossible. The risk is all the more higher than, after use, a residue of product may flow along the tip and come soil the thread, to the point of causing the bonding with the cap thread. The risk of contamination of the thread is increased by the fact that the tip is relatively short and cylindrical, and that the thread is located on a portion of the tip section similar to the section of the rest of the
- a device for packaging and distribution under pressure of a product in particular cosmetic container comprising a container containing the product, said container being surmounted by a distribution element, in particular a valve, and a head of distribution for the actuation of the distribution element, and the distribution of the produced via at least one dispensing orifice
- the dispensing head comprising: a) a mounting band, integral with the container; b) a dispensing nozzle forming a channel opening on said dispensing orifice, said nozzle being immobile in rotation with respect to the mounting band and being fit, in response to an actuating command, to move in such a way as to provoke actuation of the dispensing element; and (c) a hood screwed onto the mouthpiece distribution, and having means adapted, in the screwed position of the hood, to prevent actuation of the dispensing element.
- the cover being screwed directly on the end piece, the risks of actuation unexpectedly the distribution element are reduced significantly, the screwing movement generating substantially no constraint suitable for cause such inadvertent actuation.
- screwing the hood on the dispensing tip tends to pull the latter away from the valve.
- the risks of inadvertent activation are removed from the means provided for this purpose on the hood, which interact with a at least part of the mounting band.
- Such a configuration makes it possible to produce a dispensing head whose aesthetics is similar to that fitted to the containers in the form of tubes.
- This characteristic is advantageous when the product to conditioning is in the form of a care cream or a gel, traditionally conditioned in a tube.
- the screwing of the cover can also be as tight as possible, thus improving sealing at closure, and further reducing the risks of inadvertent actuation of the distribution element when the device is in storage position.
- the tip is fixed in rotation compared to the hood, which can be removed easily regardless of the degree of screwing.
- the thread of the tip is on a portion of the mouthpiece of section larger than the section of the free end of the tip at the level of which is formed the dispensing orifice.
- the threaded portion of the tip is separated from the free end of the tip by at least a portion of section gradually increasing towards the threaded portion.
- the threaded portion of the tip can be separated from the free end of the endpiece by one or more bearings, the function of these bearings or other incrementally increasing portion portions being to delay, see to prevent, the moment when the product reaches the thread.
- this feature makes it easier to design the hood by allowing the provision of the bonnet thread on the inner surface of its side wall outside, without requiring an intermediate inner wall.
- the dispensing nozzle is formed of a separate part of the collar mounting.
- the term "distinct" reflects the fact that the dispensing tip and the mounting fret are formed of two pieces, which at least after the first use, are, apart from their coupling in rotation, independent of each other, that is to say connected by no material bridge, in particular in the form of a hinge film.
- the two pieces are molded separately.
- the two parts can be connected by material bridges that are broken during the first use, and which, as a result, constitute indicators of inviolability.
- This arrangement in which the dispensing tip consists of a piece distinct from the hoop facilitates to a large extent the mounting of the head of distribution on the container, and in particular, significantly reduces the risks inadvertent actuation of the valve during this assembly.
- this characteristic is advantageous compared to a solution according to which the endpiece of distribution would be connected to the hoop by a film hinge to the extent that, particularly in the case of a toggle valve, actuation of the valve regardless of the angular position of the point of exercise of the lateral force aiming to provoke such a changeover.
- the dispensing element consists of a valve, the product being pressurized inside the container.
- a valve because of its low stroke actuation, facilitates the distribution of the product.
- the valve is of the tilting type, suitable for be actuated in response to a pressure transverse to an axis of said valve. So, with this configuration, the product distribution can be made directly on the surface where the product is to be applied, simply by putting the distribution in engagement with the surface to be treated, and moving the tip distribution relative to said surface.
- the valve is of the recess type, suitable for be actuated in response to a pressure axially oriented to said valve.
- the mounting collar can be fixedly mounted on the container, in particular by snap fastening. Alternatively, it can be screwed onto the container.
- the dispensing nozzle can be immobilized in rotation relative to the ferrule of mounting, by means of one or more notches, formed by the mounting band (respectively, the tip), and able (s) to engage in a corresponding number grooves formed by the dispensing nozzle (respectively, the hoop of mounting).
- the assembly operation of the dispensing head, and in particular the setting concordance of the notches with the grooves, is all the easier to obtain than their number is large. As an indicative example, their number ranges from 2 to 6, and preferably from 2 to 4.
- the dispensing nozzle may comprise an element, in particular in the form of a ring collar, which, in cooperation with a corresponding portion of the frette, forbidden to separate the dispensing tip from the rest of the head of distribution.
- this annular element when actuating the element of tipping distribution, may come into engagement with said portion corresponding to the fret, and act in the manner of a lever arm. We facilitate still the distribution of the product.
- the suitable means in the targeted position of the hood, to prevent the actuation of the distribution element, may consist of an edge, in particular an annular edge, and which, in the screwed position of the hood on the dispensing nozzle, is substantially in contact with the mounting band.
- the term "substantially” reflects the fact that the existing clearance between the annular edge of the hood and the mounting band is less than the stroke necessary to cause the opening of the distribution element.
- Such play, when the dispensing element is a valve may be of the order of 0.5 mm.
- the hood is configured so that, in the screwed-on position the tip, a portion of the cover is in engagement with the dispensing orifice to seal the latter tightly. Because the hood is screwed directly on the dispensing nozzle, the risks of inadvertent actuation of the distribution element when mounting the hood on the latter, are reduced by sensitive manner and regardless of the degree of commitment of the hood with dispensing orifice. Thus, the problem associated with manufacturing tolerances of parts.
- the device according to the invention can be used in particular for conditioning and the distribution under pressure of a cosmetic product, in particular of care, makeup, personal hygiene, hair care or skin protection against harmful effects of solar radiation.
- FIGS 1, 2, 3A-3C to which reference is now made represent different views of a packaging and dispensing device 1 according to a first embodiment of the invention.
- the device 1 comprises a pressurized container 2, aluminum or tinplate, containing the product and a suitable gas to pressurize the product.
- the container 2 is surmounted by a valve 11 of the type to failover.
- the valve 11 comprises a valve stem 12 emerging outside of the valve.
- the container 2 is equipped with a dispensing head 10 for the actuation of the valve 11 and the distribution of the product under pressure.
- the dispensing head 10 comprises a mounting band 13 mounted by snap fastening on the crimping bead 14 of the valve 11.
- the hoop assembly 13 mainly comprises a cylindrical skirt 15 with one end is open, and the other end has an annular flange 16 delimiting an opening 17.
- the inner surface of the skirt 15 is provided with a bead detent 18 of the hoop 13 on the crimping bead 14 of the valve.
- a dispensing nozzle 20 crossed by a channel 21 disposed in the axis X of the valve 11.
- the channel 21, in its end opposite the valve stem 12 opens on a dispensing orifice 22.
- the tip 20 is of section gradually increasing between the orifice of distribution 22 and the thread 31 provided opposite the dispensing orifice.
- the dispensing nozzle 20 is coupled in rotation with the mounting band 13 via an arrangement consisting of a plurality of notches 23 formed on the inner surface of the mounting band 13, and able to engage in grooves 24 of corresponding geometry, formed by the outer surface of the dispensing nozzle 20.
- the dispensing nozzle 20, at its end opposite the dispensing orifice 22 forms a transverse flange 25 turned towards the outside, and whose diameter maximum is greater than the inside diameter of the annular flange 16 of the ferrule 13.
- the collar 25 prevents the dispensing tip 20 from being able to be disconnected from the rest of the dispensing head.
- a cover 30 of flared profile similar to the profile of the dispensing nozzle 20.
- the nozzle of distribution 20 has on its outer surface, near its end opposite to the orifice 22, a thread 31 capable of cooperating with a thread corresponding 32 formed on the inner surface of the hood 30, in the vicinity of its open end.
- a bead 34 formed by the bottom 35 of the hood is in sealed engagement with the orifice of distribution 22 of the dispensing nozzle 20, thus avoiding between two uses, any risk of clogging of the dispensing orifice 22 or the channel 21 by the product residual at this location.
- This characteristic is particularly advantageous for products of high viscosity.
- this waterproof closure of the dispensing orifice 22 by means of the bead 34 avoids the deterioration of any residual product inside the channel 21.
- the user unscrews the hood 30. She puts the dispensing orifice 22 on the surface to be treated, and moves the device 1 relative to said surface. Such support causes the switchover of the valve stem 12, the opening of the valve 11, and the outlet of the product through the orifice 22, via the axial channel 21.
- Such an open configuration of the valve 11, in tilted position of the tip 20 and the valve stem 12, is shown in FIG. Figure 3B.
- FIGS. 4A and 4B differs from the embodiment previous in that the valve 11 is of the depression type.
- the tip of distribution 20 form two "ears" 26, 27 so as to allow actuation of the valve by an axial displacement of the nozzle 20 towards the container 2 (see Figure 4B).
- the profile of the cover is different from the profile of the cover of the preceding embodiment so that, when screwing the cover on the endpiece 20 ( Figure 4A), the cover 30 does not come into engagement with the ears of the tip 20, which engagement would be likely to cause a inadvertent actuation of the valve 11.
- the device 1 is also in all respects identical to that of the mode of previous realization.
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- Chemical & Material Sciences (AREA)
- Dispersion Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- Closures For Containers (AREA)
- Containers And Packaging Bodies Having A Special Means To Remove Contents (AREA)
- Containers And Plastic Fillers For Packaging (AREA)
- Vending Machines For Individual Products (AREA)
Abstract
Description
La présente invention a trait à un dispositif pour le conditionnement et la
distribution sous pression d'un produit selon la préambule de la revendication 1, notamment cosmétique. Un tel produit peut
être sous forme d'un liquide, d'une mousse, ou de consistance plus visqueuse,
notamment sous forme d'une crème ou d'un gel. L'invention peut être utilisée
notamment pour le conditionnement et la distribution d'un produit de soin, d'un
produit de maquillage, d'un produit capillaire ou d'hygiène corporelle, ou d'un
produit de protection de la peau contre les effets des rayonnements du soleil.The present invention relates to a device for conditioning and
dispensing under pressure of a product according to the preamble of
Dans le cas d'un dispositif utilisant une valve, le produit peut être pressurisé au moyen d'un gaz propulseur, liquéfié ou non. Le gaz peut être conditionné, directement au contact du produit, ou de manière séparée via un piston ou une poche à parois souples.In the case of a device using a valve, the product may be pressurized at medium of a propellant gas, liquefied or not. The gas can be conditioned, directly in contact with the product, or separately via a piston or pocket with soft walls.
La demande de brevet FR-A-2 635 085 décrit un distributeur du type à pompe ou à valve comprenant un récipient contenant le produit. Le récipient est surmonté d'une valve, et d'une tête de distribution pour l'actionnement de la pompe ou de la valve, et la distribution du produit via au moins un orifice de distribution. Un capot est monté serrant sur l'embout de distribution entre deux utilisations.Patent Application FR-A-2,635,085 describes a pump-type dispenser or valve comprising a container containing the product. The container is topped of a valve, and a dispensing head for actuating the pump or the valve, and dispensing the product via at least one dispensing orifice. A cap is mounted clamping on the dispensing tip between two uses.
Les problèmes se posant avec une telle configuration sont multiples. Le premier tient au fait qu'en montant le capot sur le dispositif, les risques sont grands pour qu'il se produise un actionnement intempestif de l'élément de distribution, en particulier lorsqu'il s'agit d'une valve dont la course d'actionnement est très faible.The problems with such a configuration are many. The first the fact that by mounting the hood on the device, the risks are great for unintentional actuation of the distribution element, particularly when it is a valve whose actuating stroke is very low.
En outre, en position montée du capot, l'orifice de distribution n'est pas obturé de manière étanche. De ce fait, en particulier pour certains produits dont la tendance à se colmater en séchant est forte, l'orifice de distribution ainsi que le canal débouchant sur l'orifice de distribution, sont sujets à encrassement, ce qui risque de rendre le dispositif totalement inutilisable, notamment après une longue période d'inutilisation. De plus le produit résiduel dans le canal et au voisinage de l'ouverture, est susceptible de se dégrader, notamment par oxydation, et être d'aspect peu attractif. In addition, in the mounted position of the hood, the dispensing orifice is not closed by waterproof way. As a result, especially for certain products whose tendency is to clog when drying is strong, the dispensing orifice as well as the channel opening onto the dispensing orifice, are subject to fouling, which risks make the device totally unusable, especially after a long period not in use. In addition, the residual product in the canal and in the vicinity of the opening, is likely to deteriorate, in particular by oxidation, and to be unattractive appearance.
Si l'on modifie la configuration du capot de manière à ce que, en position montée sur l'embout de distribution, l'orifice de distribution soit obturé de manière étanche par une portion correspondante du capot, notamment par son fond, alors les risques sont encore plus grands pour que, en montant le capot sur le dispositif, il se produise un actionnement intempestif de l'élément de distribution.If the hood configuration is changed so that in the mounted position on the dispensing nozzle, the dispensing orifice is closed sealingly by a corresponding portion of the hood, in particular by its bottom, then the risks are even greater for that, by mounting the hood on the device, it an inadvertent actuation of the dispensing element occurs.
Le document US-A-2 767 888 décrit un dispositif dans lequel un capuchon est vissé sur un embout de distribution, ce dernier étant monté sur une tige de valve. Une telle conception souffre de plusieurs inconvénients. Le premier tient au fait qu'il n'y a pas de couplage en rotation entre l'embout et la frette de montage. De ce fait, il n'est pas exclu que le capuchon puisse ne pas être vissé de manière suffisante. En outre, si le capuchon devait être vissé de manière suffisante, alors il n'est pas exclu que lors du mouvement de dévissage, l'embout tourne avec le capuchon, rendant l'enlèvement de ce dernier impossible. Le risque est d'autant plus élevé que, après utilisation, un reliquat de produit peut s'écouler le long de l'embout et vienne souiller le filetage, au point d'en provoquer le collage avec le filetage du capuchon. Le risque de souillure du filetage est accru par le fait que l'embout est relativement court et cylindrique, et que le filetage se situe sur une portion de l'embout de section similaire à la section du reste de l'embout.US-A-2 767 888 discloses a device in which a cap is screwed on a dispensing nozzle, the latter being mounted on a valve stem. Such a design suffers from several disadvantages. The first is the fact that there is no coupling in rotation between the tip and the mounting hoop. Of this fact, it is not excluded that the cap may not be screwed so sufficient. In addition, if the cap were to be screwed sufficiently, then is not excluded that during the unscrewing movement, the tip turns with the hood, making the removal of the latter impossible. The risk is all the more higher than, after use, a residue of product may flow along the tip and come soil the thread, to the point of causing the bonding with the cap thread. The risk of contamination of the thread is increased by the fact that the tip is relatively short and cylindrical, and that the thread is located on a portion of the tip section similar to the section of the rest of the tip.
Aussi, est-ce un des objets de l'invention que de réaliser un dispositif de conditionnement et de distribution sous pression d'un produit, notamment cosmétique, et qui permette de s'affranchir en tout ou partie, des problèmes évoqués ci-avant en référence aux brevets FR-A-2 635 085 et US-A-2 767 888.Also, is it an object of the invention to provide a device for packaging and distribution under pressure of a product, in particular cosmetics, and which makes it possible to get rid of all or part of the problems mentioned above with reference to patents FR-A-2,635,085 and US-A-2,767,888.
C'est en particulier un objet de invention que de fournir un tel dispositif pour lequel les risques d'actionnement intempestif de l'élément de distribution sont réduits de manière sensible.It is in particular an object of invention to provide such a device for which the risks of inadvertent actuation of the distribution element are reduced significantly.
C'est un autre objet de l'invention que de fournir un tel dispositif pour lequel les risques de colmatage et d'encrassement de l'orifice de distribution et/ou du canal débouchant sur ce dernier, sont réduits de manière substantielle. It is another object of the invention to provide such a device for which the risk of clogging and fouling of the dispensing orifice and / or the channel leading to the latter, are reduced substantially.
C'est encore un autre objet de l'invention que de réaliser un tel dispositif dans lequel le capuchon de protection peut être vissé/dévissé de manière aisée et satisfaisante sur l'embout de distribution, et pour lequel les risques de souillure du filetage de l'embout sont réduits de manière sensible.It is yet another object of the invention to provide such a device in which the protective cap can be screwed / unscrewed easily and satisfactory on the dispensing nozzle, and for which the risk of contamination of the threading of the tip are reduced significantly.
C'est encore un autre objet de fournir un dispositif qui puisse être fabriqué et monté de manière économique, et qui soit simple d'utilisation.It is yet another object to provide a device that can be manufactured and economically mounted and easy to use.
D'autres objets encore apparaítront dans la description détaillée qui suit.Still other objects will appear in the following detailed description.
Selon l'invention, ces objets sont atteints en réalisant un dispositif de conditionnement et de distribution sous pression d'un produit, notamment cosmétique, comprenant un récipient contenant le produit, ledit récipient étant surmonté d'un élément de distribution, notamment d'une valve, et d'une tête de distribution pour l'actionnement de l'élément de distribution, et la distribution du produit via au moins un orifice de distribution, la tête de distribution comprenant : a) une frette de montage, solidaire du récipient ; b) un embout de distribution formant un canal débouchant sur ledit orifice de distribution, ledit embout étant immobile en rotation par rapport à la frette de montage et étant apte, en réponse à une commande d'actionnement, à se déplacer de manière à provoquer l'actionnement de l'élément de distribution ; et c) un capot vissé sur l'embout de distribution, et comportant des moyens aptes, en position vissée du capot, à empêcher l'actionnement de l'élément de distribution.According to the invention, these objects are achieved by producing a device for packaging and distribution under pressure of a product, in particular cosmetic container comprising a container containing the product, said container being surmounted by a distribution element, in particular a valve, and a head of distribution for the actuation of the distribution element, and the distribution of the produced via at least one dispensing orifice, the dispensing head comprising: a) a mounting band, integral with the container; b) a dispensing nozzle forming a channel opening on said dispensing orifice, said nozzle being immobile in rotation with respect to the mounting band and being fit, in response to an actuating command, to move in such a way as to provoke actuation of the dispensing element; and (c) a hood screwed onto the mouthpiece distribution, and having means adapted, in the screwed position of the hood, to prevent actuation of the dispensing element.
Ainsi, le capot étant vissé directement sur l'embout, les risques d'actionnement intempestifs de l'élément de distribution sont réduits de manière sensible, le mouvement de vissage ne générant sensiblement aucune contrainte apte à provoquer un tel actionnement intempestif. Au contraire, le vissage du capot sur l'embout de distribution tend à tirer ce dernier à l'opposé de la valve. En outre, en position de stockage, les risques d'actionnement intempestifs sont supprimés du fait des moyens prévus à cet effet sur le capot, lesquels interagissent avec une portion au moins de la frette de montage. Thus, the cover being screwed directly on the end piece, the risks of actuation unexpectedly the distribution element are reduced significantly, the screwing movement generating substantially no constraint suitable for cause such inadvertent actuation. On the contrary, screwing the hood on the dispensing tip tends to pull the latter away from the valve. In addition, storing position, the risks of inadvertent activation are removed from the means provided for this purpose on the hood, which interact with a at least part of the mounting band.
Une telle configuration permet de réaliser une tête de distribution dont l'esthétique est similaire à celle équipant les récipients sous forme de tubes. Cette caractéristique, d'un point de vue marketing, est avantageuse lorsque le produit à conditionner est sous forme d'une crème de soin ou d'un gel, traditionnellement conditionné dans un tube.Such a configuration makes it possible to produce a dispensing head whose aesthetics is similar to that fitted to the containers in the form of tubes. This characteristic, from a marketing point of view, is advantageous when the product to conditioning is in the form of a care cream or a gel, traditionally conditioned in a tube.
L'embout de distribution étant fixe en rotation, le vissage du capot peut être aussi serré que possible, améliorant ainsi l'étanchéité à la fermeture, et réduisant encore les risques d'actionnement intempestifs de l'élément de distribution lorsque le dispositif est en position de stockage. A l'ouverture, l'embout est fixe en rotation par rapport au capot, lequel peut être enlevé facilement quelque soit le degré de vissage.The dispensing endpiece being fixed in rotation, the screwing of the cover can also be as tight as possible, thus improving sealing at closure, and further reducing the risks of inadvertent actuation of the distribution element when the device is in storage position. At the opening, the tip is fixed in rotation compared to the hood, which can be removed easily regardless of the degree of screwing.
De préférence, le filetage de l'embout se trouve sur une portion de l'embout de section plus importante que la section de l'extrémité libre de l'embout au niveau de laquelle est formé l'orifice de distribution. De préférence, la portion filetée de l'embout est séparée de l'extrémité libre de l'embout par au moins une portion de section augmentant progressivement en direction de la portion filetée. Alternativement, la portion filetée de l'embout peut être séparée de l'extrémité libre de l'embout par un ou plusieurs paliers, la fonction de ces paliers ou autres portions de section augmentant progressivement étant de retarder, voir d'empêcher, le moment où le produit atteint le filetage. En outre, cette caractéristique permet de faciliter la conception du capot en autorisant la disposition du filetage du capot sur la surface interne de sa paroi latérale extérieure, sans requérir de paroi intérieure intermédiaire.Preferably, the thread of the tip is on a portion of the mouthpiece of section larger than the section of the free end of the tip at the level of which is formed the dispensing orifice. Preferably, the threaded portion of the tip is separated from the free end of the tip by at least a portion of section gradually increasing towards the threaded portion. Alternatively, the threaded portion of the tip can be separated from the free end of the endpiece by one or more bearings, the function of these bearings or other incrementally increasing portion portions being to delay, see to prevent, the moment when the product reaches the thread. In addition, this feature makes it easier to design the hood by allowing the provision of the bonnet thread on the inner surface of its side wall outside, without requiring an intermediate inner wall.
De préférence, l'embout de distribution est formé d'une pièce distincte de la frette de montage. Le terme "distincte" traduit le fait que l'embout de distribution et la frette de montage sont formés de deux pièces, qui au moins après la première utilisation, sont, hormis leur couplage en rotation, indépendantes l'une de l'autre, c'est à dire reliées par aucun pont de matière, notamment sous forme d'une charnière film. De préférence, les deux pièces sont moulées séparément. Alternativement, lors du moulage, les deux pièces peuvent être reliés par des ponts de matière qui sont rompus lors de la première utilisation, et qui, de ce fait, constituent des indicateurs d'inviolabilité.Preferably, the dispensing nozzle is formed of a separate part of the collar mounting. The term "distinct" reflects the fact that the dispensing tip and the mounting fret are formed of two pieces, which at least after the first use, are, apart from their coupling in rotation, independent of each other, that is to say connected by no material bridge, in particular in the form of a hinge film. Preferably, the two pieces are molded separately. Alternatively, during molding, the two parts can be connected by material bridges that are broken during the first use, and which, as a result, constitute indicators of inviolability.
Cette disposition dans laquelle l'embout de distribution est constitué d'une pièce distincte de la frette facilite dans une large mesure le montage de la tête de distribution sur le récipient, et en particulier, réduit de manière sensible les risques d'actionnement intempestif de la valve lors de ce montage. En outre, cette caractéristique est avantageuse par rapport à une solution selon laquelle l'embout de distribution serait relié à la frette par une charnière film dans la mesure où, notamment dans le cas d'une valve à basculement, on permet l'actionnement de la valve quelle que soit la position angulaire du point d'exercice de la force latérale visant à provoquer un tel basculement.This arrangement in which the dispensing tip consists of a piece distinct from the hoop facilitates to a large extent the mounting of the head of distribution on the container, and in particular, significantly reduces the risks inadvertent actuation of the valve during this assembly. In addition, this characteristic is advantageous compared to a solution according to which the endpiece of distribution would be connected to the hoop by a film hinge to the extent that, particularly in the case of a toggle valve, actuation of the valve regardless of the angular position of the point of exercise of the lateral force aiming to provoke such a changeover.
De préférence, l'élément de distribution est constitué d'une valve, le produit étant pressurisé à l'intérieur du récipient. Une telle valve, en raison de sa faible course d'actionnement, permet de faciliter la distribution du produit.Preferably, the dispensing element consists of a valve, the product being pressurized inside the container. Such a valve, because of its low stroke actuation, facilitates the distribution of the product.
Selon un premier mode de réalisation, la valve est du type à basculement, apte à être actionnée en réponse à une pression transversale à un axe de ladite valve. Ainsi, avec cette configuration, la distribution du produit peut être faite directement sur la surface où le produit doit être appliqué, simplement en mettant l'embout de distribution en engagement avec la surface à traiter, et en déplaçant l'embout de distribution par rapport à ladite surface.According to a first embodiment, the valve is of the tilting type, suitable for be actuated in response to a pressure transverse to an axis of said valve. So, with this configuration, the product distribution can be made directly on the surface where the product is to be applied, simply by putting the distribution in engagement with the surface to be treated, and moving the tip distribution relative to said surface.
Selon un second mode de réalisation, la valve est du type à enfoncement, apte à être actionnée en réponse à une pression orientée axialement à ladite valve.According to a second embodiment, the valve is of the recess type, suitable for be actuated in response to a pressure axially oriented to said valve.
La frette de montage peut être montée fixement sur le récipient, notamment par encliquetage serrant. Alternativement, elle peut être vissée sur le récipient.The mounting collar can be fixedly mounted on the container, in particular by snap fastening. Alternatively, it can be screwed onto the container.
L'embout de distribution peut être immobilisé en rotation par rapport à la frette de montage, au moyen d'un ou plusieurs crans, formé(s) par la frette de montage (respectivement, l'embout), et apte(s) à s'engager dans un nombre correspondant de rainures formée(s) par l'embout de distribution (respectivement, la frette de montage). L'opération de montage de la tête de distribution, et notamment la mise en concordance des crans avec les rainures, est d'autant plus facile à obtenir que leur nombre est grand. A titre d'exemple indicatif, leur nombre va de 2 à 6, et de préférence, de 2 à 4.The dispensing nozzle can be immobilized in rotation relative to the ferrule of mounting, by means of one or more notches, formed by the mounting band (respectively, the tip), and able (s) to engage in a corresponding number grooves formed by the dispensing nozzle (respectively, the hoop of mounting). The assembly operation of the dispensing head, and in particular the setting concordance of the notches with the grooves, is all the easier to obtain than their number is large. As an indicative example, their number ranges from 2 to 6, and preferably from 2 to 4.
L'embout de distribution peut comporter un élément, notamment sous forme d'une collerette annulaire, qui, en coopération avec une portion correspondante de la frette, interdit de désolidariser l'embout de distribution du reste de la tête de distribution. En outre, cet élément annulaire, lors de l'actionnement de l'élément de distribution par basculement, peut venir en engagement avec ladite portion correspondante de la frette, et agir à la manière d'un bras de levier. On facilite encore la distribution du produit.The dispensing nozzle may comprise an element, in particular in the form of a ring collar, which, in cooperation with a corresponding portion of the frette, forbidden to separate the dispensing tip from the rest of the head of distribution. In addition, this annular element, when actuating the element of tipping distribution, may come into engagement with said portion corresponding to the fret, and act in the manner of a lever arm. We facilitate still the distribution of the product.
Les moyens aptes, en position visée du capot, à empêcher l'actionnement de l'élément de distribution, peuvent être constitués d'un bord, notamment annulaire, et qui, en position vissée du capot sur l'embout de distribution, est sensiblement au contact de la frette de montage. Le terme "sensiblement" traduit la fait que le jeu existant entre le bord annulaire du capot et la frette de montage est inférieur à la course nécessaire pour provoquer l'ouverture de l'élément de distribution. Un tel jeu, lorsque l'élément de distribution est une valve, peut être de l'ordre de 0,5 mm.The suitable means, in the targeted position of the hood, to prevent the actuation of the distribution element, may consist of an edge, in particular an annular edge, and which, in the screwed position of the hood on the dispensing nozzle, is substantially in contact with the mounting band. The term "substantially" reflects the fact that the existing clearance between the annular edge of the hood and the mounting band is less than the stroke necessary to cause the opening of the distribution element. Such play, when the dispensing element is a valve, may be of the order of 0.5 mm.
De préférence, le capot est configuré de sorte que, en position vissée sur l'embout, une portion du capot soit en engagement avec l'orifice de distribution afin d'obturer ce dernier de manière étanche. Du fait que le capot est vissé directement sur l'embout de distribution, les risques d'actionnement intempestif de l'élément de distribution lors du montage du capot sur ce dernier, sont réduits de manière sensible et ce, indépendamment du degré de mise en engagement du capot avec l'orifice de distribution. On s'affranchit ainsi du problème lié aux tolérances de fabrication des pièces.Preferably, the hood is configured so that, in the screwed-on position the tip, a portion of the cover is in engagement with the dispensing orifice to seal the latter tightly. Because the hood is screwed directly on the dispensing nozzle, the risks of inadvertent actuation of the distribution element when mounting the hood on the latter, are reduced by sensitive manner and regardless of the degree of commitment of the hood with dispensing orifice. Thus, the problem associated with manufacturing tolerances of parts.
Le dispositif selon l'invention peut être utilisé notamment pour le conditionnement et la distribution sous pression d'un produit cosmétique, notamment de soin, de maquillage, d'hygiène corporelle, capillaire ou de protection de la peau contre les effets néfastes des rayonnements solaires. The device according to the invention can be used in particular for conditioning and the distribution under pressure of a cosmetic product, in particular of care, makeup, personal hygiene, hair care or skin protection against harmful effects of solar radiation.
L'invention consiste, mises à part les dispositions exposées ci-dessus, en un certain nombre d'autres dispositions qui seront explicitées ci-après, à propos d'exemples de réalisation non limitatifs, décrits en référence aux figures annexées, parmi lesquelles :
- les figures 1, 2, 3A-3C sont relatives à un premier mode de réalisation du dispositif selon l'invention; et
- les figures 4A-4B sont relatives à un second mode de réalisation du dispositif selon l'invention.
- Figures 1, 2, 3A-3C relate to a first embodiment of the device according to the invention; and
- FIGS. 4A-4B relate to a second embodiment of the device according to the invention.
Les figures 1, 2, 3A-3C auxquelles il est maintenant fait référence représentent
différentes vues d'un dispositif de conditionnement et de distribution 1 selon un
premier mode de réalisation de l'invention.Figures 1, 2, 3A-3C to which reference is now made represent
different views of a packaging and dispensing
Selon ce mode de réalisation, le dispositif 1 comprend un bidon pressurisé 2,
notamment en aluminium ou en fer blanc, contenant le produit ainsi qu'un gaz apte
à pressuriser le produit. Le récipient 2 est surmonté d'une valve 11 du type à
basculement. La valve 11 comprend une tige de valve 12 émergeant à l'extérieur
de la valve. Le récipient 2 est équipé d'une tête de distribution 10 pour
l'actionnement de la valve 11 et la distribution du produit sous pression.According to this embodiment, the
La tête de distribution 10 comprend une frette de montage 13 montée par
encliquetage serrant sur le bourrelet de sertissage 14 de la valve 11. La frette de
montage 13 comporte principalement une jupe cylindrique 15 dont une extrémité
est ouverte, et dont l'autre extrémité comporte un rebord annulaire 16 délimitant
une ouverture 17. La surface interne de la jupe 15 est pourvue d'un bourrelet
d'encliquetage 18 de la frette 13 sur le bourrelet de sertissage 14 de la valve.The dispensing
Sur la tige de valve 12, est monté de façon serrante, un embout de distribution 20
traversé par un canal 21 disposé dans l'axe X de la valve 11. Le canal 21, en son
extrémité opposée à la tige de valve 12 débouche sur un orifice de distribution 22.
L'embout 20 est de section augmentant progressivement entre l'orifice de
distribution 22 et le filetage 31 prévu à l'opposé de l'orifice de distribution. On the
Comme il apparaít clairement sur la vue éclatée de la figure 2 ainsi que sur la vue
de détail de la figure 3C, l'embout de distribution 20 est couplé en rotation avec la
frette de montage 13 via un arrangement constitué d'une pluralité de crans 23
formés sur la surface interne de frette de montage 13, et aptes à s'engager dans
des rainures 24 de géométrie correspondante, formées par la surface extérieure
de l'embout de distribution 20.As it clearly appears on the exploded view of Figure 2 as well as on the view
detail of FIG. 3C, the dispensing
L'embout de distribution 20, en son extrémité opposée à l'orifice de distribution 22
forme une collerette transversale 25 tournée vers l'extérieur, et dont le diamètre
maximal est supérieur au diamètre intérieur du rebord annulaire 16 de la frette de
montage 13. Ainsi, la collerette 25 empêche l'embout de distribution 20 de pouvoir
être désolidarisé du reste de la tête de distribution.The dispensing
Directement sur l'embout de distribution 20 est vissé un capot 30 de profil évasé,
similaire au profil de l'embout de distribution 20. A cet effet, l'embout de
distribution 20 comporte sur sa surface extérieure, au voisinage de son extrémité
opposée à l'orifice 22, un filetage 31, apte à coopérer avec un filetage
correspondant 32 formé sur la surface intérieure du capot 30, au voisinage de son
extrémité ouverte.Directly on the dispensing
En position vissée du capot, telle que représentée aux figures 1 et 3A, le bord 33
délimitant l'extrémité ouverte du capot 30, est quasiment au contact du rebord
annulaire 16 de la frette de montage 13, de sorte que, dans cette position montée
du capot 30, celui-ci ne puisse basculer de manière sensible autour de l'axe X de
la valve 11, évitant ainsi tout risque d'actionnement intempestif de la valve 11
lorsque le dispositif est en position de stockage ou de transport.In the screwed position of the hood, as shown in FIGS. 1 and 3A, the
En position vissée du capot 30 sur l'embout de distribution 20, un bourrelet 34
formé par le fond 35 du capot, est en engagement étanche avec l'orifice de
distribution 22 de l'embout de distribution 20, évitant ainsi entre deux utilisations,
tout risque de colmatage de l'orifice de distribution 22 ou du canal 21 par le produit
résiduel à cet endroit. Cette caractéristique est tout particulièrement avantageuse
pour des produits de viscosité importante. En outre, cette fermeture étanche de
l'orifice de distribution 22 au moyen du bourrelet 34, dans le cas de produits
facilement oxydables, évite la détérioration de tout produit résiduel à l'intérieur du
canal 21.In the screwed position of the
En vue d'utiliser le dispositif selon l'invention, l'utilisatrice dévisse le capot 30. Elle
met l'orifice de distribution 22 en appui sur la surface à traiter, et déplace le
dispositif 1 relativement à ladite surface. Un tel appui provoque le basculement de
la tige de valve 12, l'ouverture de la valve 11, et la sortie du produit au travers de
l'orifice 22, via le canal axial 21. Une telle configuration ouverte de la valve 11, en
position basculée de l'embout 20 et de la tige de valve 12, est représentée à la
figure 3B.In order to use the device according to the invention, the user unscrews the
Après utilisation, elle revisse le capot 30 sur l'embout de distribution 20, le
mouvement de vissage ne générant aucune contrainte susceptible de provoquer
le basculement de la tige de valve 12. Le vissage se poursuit jusqu'à ce que le
bord 33 du capot 30 arrive au proche voisinage du rebord annulaire 16 de la frette
de montage (figure 3A). Le vissage complet du capot 30 sur l'embout de
distribution 20 est facilité par le couplage en rotation de l'embout de distribution 20
et de la frette de montage 13, laquelle est elle même immobile en rotation par
rapport au récipient 2.After use, it adjusts the
Le mode de réalisation des figures 4A et 4B se distingue du mode de réalisation
précédent en ce que la valve 11 est du type à enfoncement. L'embout de
distribution 20 forme deux "oreilles" 26, 27 de manière à permettre l'actionnement
de la valve par un déplacement axial de l'embout 20 en direction du récipient 2
(voir figure 4B). Le profil du capot est différent du profil du capot du mode de
réalisation précédent de manière à ce que, lors du vissage du capot sur l'embout
de distribution 20 (figure 4A), le capot 30 ne vienne pas en engagement avec les
oreilles de l'embout 20, lequel engagement serait susceptible de provoquer un
actionnement intempestif de la valve 11.The embodiment of FIGS. 4A and 4B differs from the embodiment
previous in that the
Le dispositif 1 est par ailleurs en tous points identique à celui du mode de
réalisation précédent. The
En particulier, lors du vissage du capot 30 sur l'embout de distribution 20, il n'y a
sensiblement aucun risque d'actionnement intempestif de la valve 11, aucune
contrainte générée par le mouvement de vissage n'étant susceptible de provoquer
un tel actionnement. Le couplage en rotation de la frette 13 et de l'embout de
distribution 20 autorise un serrage important du capot 30 sur l'embout 20, lequel
serrage est garant d'une bonne étanchéité à la fermeture. En position vissée du
capot 30 sur l'embout 20, le bord 33 du capot 30 est sensiblement au contact de la
collerette 16 de la frette 13, rendant encore une fois impossible l'actionnement de
la valve 11.In particular, when the
Dans la description détaillée qui précède, il a été fait référence à des modes de réalisation préférés de l'invention. Il est évident que des variantes peuvent y être apportées sans s'écarter de l'invention telle que revendiquée ci-après.In the above detailed description, reference has been made to modes of preferred embodiment of the invention. It is obvious that variants can be without departing from the invention as claimed hereinafter.
Claims (14)
- Device (1) for packaging and dispensing a product, particularly a cosmetic product, under pressure, comprising a receptacle (2) containing the product, said receptacle being surmounted by a dispensing element (11), particularly a valve, and by a dispensing head (10) for the actuation of the dispensing element, and the dispensing of the product via at least one dispensing orifice (22), the dispensing head comprising: a) an assembly band (13), integral with the receptacle; b) a dispensing nozzle (20) forming a channel (21) emerging on said dispensing orifice, said nozzle (20) being capable, in response to an actuation command, of being displaced so as to give rise to the actuation of the dispensing element (11); and c) a cap (30) screwed onto the dispensing nozzle and comprising means (33) capable, in the screwed-on position of the cap, of preventing the actuation of the dispensing element (11), characterized in that the nozzle (20) is immovable in rotation relative to the assembly band (13).
- Device (1) according to Claim 1, characterized in that the dispensing nozzle (20) includes a thread (31) capable of interacting with a corresponding thread (32) of the cap (30), said thread (31) being formed on a portion of the nozzle of larger cross section than the cross section of a free end of the nozzle where the dispensing orifice (22) emerges.
- Device (1) according to Claim 2, characterized in that the thread (31) of the nozzle (20) is separated from the dispensing orifice (22) by at least a portion with a cross section which increases progressively in the direction of the thread (31) and/or by at least one shoulder.
- Device (1) according to any one of Claims 1 to 3, characterized in that the thread (32) of the cap (30) is provided on the inner surface of an outer lateral wall of the cap (30).
- Device (1) according to any one of Claims 1 to 4, characterized in that the dispensing nozzle (20) is formed from a piece distinct from the assembly band (13).
- Device (1) according to any one of Claims 1 to 5, characterized in that the dispensing element consists of a valve (11), the product being pressurized inside the receptacle (2).
- Device (1) according to Claim 6, characterized in that the valve (11) is of the rocking type, capable of being actuated in response to a pressure transverse to a longitudinal axis (X) of said valve.
- Device (1) according to Claim 6,
characterized in that the valve (11) is of the push-in type, capable of being actuated in response to a pressure oriented axially relative to said valve (11). - Device (1) according to any one of Claims 1 to 8, characterized in that the assembly band (13) is mounted securely on the receptacle (2), particularly by clamping snap-fitting.
- Device (1) according to any one of Claims 1 to 9, characterized in that the dispensing nozzle (20) is immobilized in rotation relative to the assembly band by means of one or more notches (23) formed by the assembly band (13), or the nozzle (20), respectively, and capable of engaging in a corresponding number of grooves (24) formed by the dispensing nozzle (20), or the assembly band (13), respectively.
- Device (1) according to any one of Claims 1 to 10, characterized in that the means which are capable, in the screwed-on position of the cap, of preventing the actuation of the dispensing element consist of an edge (33) of the cap (30), particularly an annular edge, which, in the screwed-on position of the cap (30) on the dispensing nozzle, is in contact with the assembly band (13).
- Device (1) according to any one of the preceding claims, characterized in that the cap (30) is configured such that, in the screwed-on position on the nozzle (20), a portion (34) of the cap is in engagement with the dispensing orifice (22) in order to close off the latter in a leaktight manner.
- Device (1) according to any one of the preceding claims, characterized in that the dispensing nozzle (20) includes an element (25), particularly in the form of an annular collar, which, in interaction with a corresponding portion (16) of the band (13), prevents detachment of the dispensing nozzle (20) from the rest of the dispensing head (10).
- Use of a device (1) according to any one of the preceding claims for the packaging and dispensing of a cosmetic product, particularly a care, make-up, body-hygiene, hair-care or sun-screen product, under pressure.
Applications Claiming Priority (2)
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FR0014253 | 2000-11-07 | ||
FR0014253A FR2816290B1 (en) | 2000-11-07 | 2000-11-07 | PRESSURE PACKAGING AND DISPENSING DEVICE |
Publications (2)
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EP1205403A1 EP1205403A1 (en) | 2002-05-15 |
EP1205403B1 true EP1205403B1 (en) | 2005-05-18 |
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EP01402589A Expired - Lifetime EP1205403B1 (en) | 2000-11-07 | 2001-10-08 | Unit for storing and dispensing a product under pressure |
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EP (1) | EP1205403B1 (en) |
JP (1) | JP2002238658A (en) |
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US4944429A (en) * | 1987-08-28 | 1990-07-31 | Schering Corporation | Manually-operable spray dispenser with locking mechanism |
FR2626254B1 (en) * | 1988-01-27 | 1990-07-06 | Valois Sa | PUSH-BAG WITH GUARANTEE SYSTEM |
FR2635085B3 (en) * | 1988-08-08 | 1990-11-02 | Sofab | TAMPER-FREE MOUTHPIECE DISPENSER |
US5722568A (en) * | 1996-09-13 | 1998-03-03 | Summit Packaging Systems, Inc. | Tamper-evident aerosol cap |
-
2000
- 2000-11-07 FR FR0014253A patent/FR2816290B1/en not_active Expired - Fee Related
-
2001
- 2001-10-08 DE DE60110881T patent/DE60110881T2/en not_active Expired - Lifetime
- 2001-10-08 ES ES01402589T patent/ES2242717T3/en not_active Expired - Lifetime
- 2001-10-08 EP EP01402589A patent/EP1205403B1/en not_active Expired - Lifetime
- 2001-10-08 AT AT01402589T patent/ATE295814T1/en not_active IP Right Cessation
- 2001-10-31 CA CA002360912A patent/CA2360912C/en not_active Expired - Fee Related
- 2001-11-07 JP JP2001342598A patent/JP2002238658A/en not_active Ceased
- 2001-11-07 US US09/986,028 patent/US6439440B1/en not_active Expired - Lifetime
Also Published As
Publication number | Publication date |
---|---|
EP1205403A1 (en) | 2002-05-15 |
FR2816290A1 (en) | 2002-05-10 |
US6439440B1 (en) | 2002-08-27 |
DE60110881T2 (en) | 2006-04-27 |
ES2242717T3 (en) | 2005-11-16 |
JP2002238658A (en) | 2002-08-27 |
FR2816290B1 (en) | 2003-01-10 |
CA2360912C (en) | 2005-12-06 |
CA2360912A1 (en) | 2002-05-07 |
US20020056733A1 (en) | 2002-05-16 |
DE60110881D1 (en) | 2005-06-23 |
ATE295814T1 (en) | 2005-06-15 |
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