EP1202115B1 - Photographisches Silberhalogenidmaterial mit einer dauerhaften elektrisch leitenden Haftvermittlungsschicht und einer kratzfesten Rückseitenschicht - Google Patents
Photographisches Silberhalogenidmaterial mit einer dauerhaften elektrisch leitenden Haftvermittlungsschicht und einer kratzfesten Rückseitenschicht Download PDFInfo
- Publication number
- EP1202115B1 EP1202115B1 EP01000511A EP01000511A EP1202115B1 EP 1202115 B1 EP1202115 B1 EP 1202115B1 EP 01000511 A EP01000511 A EP 01000511A EP 01000511 A EP01000511 A EP 01000511A EP 1202115 B1 EP1202115 B1 EP 1202115B1
- Authority
- EP
- European Patent Office
- Prior art keywords
- layer
- light
- sensitive
- processing
- film
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
Classifications
-
- G—PHYSICS
- G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
- G03C—PHOTOSENSITIVE MATERIALS FOR PHOTOGRAPHIC PURPOSES; PHOTOGRAPHIC PROCESSES, e.g. CINE, X-RAY, COLOUR, STEREO-PHOTOGRAPHIC PROCESSES; AUXILIARY PROCESSES IN PHOTOGRAPHY
- G03C1/00—Photosensitive materials
- G03C1/76—Photosensitive materials characterised by the base or auxiliary layers
- G03C1/7614—Cover layers; Backing layers; Base or auxiliary layers characterised by means for lubricating, for rendering anti-abrasive or for preventing adhesion
-
- G—PHYSICS
- G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
- G03C—PHOTOSENSITIVE MATERIALS FOR PHOTOGRAPHIC PURPOSES; PHOTOGRAPHIC PROCESSES, e.g. CINE, X-RAY, COLOUR, STEREO-PHOTOGRAPHIC PROCESSES; AUXILIARY PROCESSES IN PHOTOGRAPHY
- G03C1/00—Photosensitive materials
- G03C1/76—Photosensitive materials characterised by the base or auxiliary layers
- G03C1/825—Photosensitive materials characterised by the base or auxiliary layers characterised by antireflection means or visible-light filtering means, e.g. antihalation
- G03C1/83—Organic dyestuffs therefor
-
- G—PHYSICS
- G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
- G03C—PHOTOSENSITIVE MATERIALS FOR PHOTOGRAPHIC PURPOSES; PHOTOGRAPHIC PROCESSES, e.g. CINE, X-RAY, COLOUR, STEREO-PHOTOGRAPHIC PROCESSES; AUXILIARY PROCESSES IN PHOTOGRAPHY
- G03C1/00—Photosensitive materials
- G03C1/76—Photosensitive materials characterised by the base or auxiliary layers
- G03C1/85—Photosensitive materials characterised by the base or auxiliary layers characterised by antistatic additives or coatings
- G03C1/853—Inorganic compounds, e.g. metals
-
- G—PHYSICS
- G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
- G03C—PHOTOSENSITIVE MATERIALS FOR PHOTOGRAPHIC PURPOSES; PHOTOGRAPHIC PROCESSES, e.g. CINE, X-RAY, COLOUR, STEREO-PHOTOGRAPHIC PROCESSES; AUXILIARY PROCESSES IN PHOTOGRAPHY
- G03C1/00—Photosensitive materials
- G03C1/76—Photosensitive materials characterised by the base or auxiliary layers
- G03C1/91—Photosensitive materials characterised by the base or auxiliary layers characterised by subbing layers or subbing means
-
- G—PHYSICS
- G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
- G03C—PHOTOSENSITIVE MATERIALS FOR PHOTOGRAPHIC PURPOSES; PHOTOGRAPHIC PROCESSES, e.g. CINE, X-RAY, COLOUR, STEREO-PHOTOGRAPHIC PROCESSES; AUXILIARY PROCESSES IN PHOTOGRAPHY
- G03C1/00—Photosensitive materials
- G03C1/76—Photosensitive materials characterised by the base or auxiliary layers
- G03C1/91—Photosensitive materials characterised by the base or auxiliary layers characterised by subbing layers or subbing means
- G03C1/93—Macromolecular substances therefor
-
- G—PHYSICS
- G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
- G03C—PHOTOSENSITIVE MATERIALS FOR PHOTOGRAPHIC PURPOSES; PHOTOGRAPHIC PROCESSES, e.g. CINE, X-RAY, COLOUR, STEREO-PHOTOGRAPHIC PROCESSES; AUXILIARY PROCESSES IN PHOTOGRAPHY
- G03C1/00—Photosensitive materials
- G03C1/76—Photosensitive materials characterised by the base or auxiliary layers
- G03C1/795—Photosensitive materials characterised by the base or auxiliary layers the base being of macromolecular substances
- G03C1/7954—Polyesters
-
- G—PHYSICS
- G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
- G03C—PHOTOSENSITIVE MATERIALS FOR PHOTOGRAPHIC PURPOSES; PHOTOGRAPHIC PROCESSES, e.g. CINE, X-RAY, COLOUR, STEREO-PHOTOGRAPHIC PROCESSES; AUXILIARY PROCESSES IN PHOTOGRAPHY
- G03C1/00—Photosensitive materials
- G03C1/76—Photosensitive materials characterised by the base or auxiliary layers
- G03C1/825—Photosensitive materials characterised by the base or auxiliary layers characterised by antireflection means or visible-light filtering means, e.g. antihalation
- G03C1/83—Organic dyestuffs therefor
- G03C1/832—Methine or polymethine dyes
-
- G—PHYSICS
- G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
- G03C—PHOTOSENSITIVE MATERIALS FOR PHOTOGRAPHIC PURPOSES; PHOTOGRAPHIC PROCESSES, e.g. CINE, X-RAY, COLOUR, STEREO-PHOTOGRAPHIC PROCESSES; AUXILIARY PROCESSES IN PHOTOGRAPHY
- G03C1/00—Photosensitive materials
- G03C1/76—Photosensitive materials characterised by the base or auxiliary layers
- G03C1/7614—Cover layers; Backing layers; Base or auxiliary layers characterised by means for lubricating, for rendering anti-abrasive or for preventing adhesion
- G03C2001/7628—Back layer
-
- G—PHYSICS
- G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
- G03C—PHOTOSENSITIVE MATERIALS FOR PHOTOGRAPHIC PURPOSES; PHOTOGRAPHIC PROCESSES, e.g. CINE, X-RAY, COLOUR, STEREO-PHOTOGRAPHIC PROCESSES; AUXILIARY PROCESSES IN PHOTOGRAPHY
- G03C7/00—Multicolour photographic processes or agents therefor; Regeneration of such processing agents; Photosensitive materials for multicolour processes
- G03C7/30—Colour processes using colour-coupling substances; Materials therefor; Preparing or processing such materials
- G03C7/388—Processes for the incorporation in the emulsion of substances liberating photographically active agents or colour-coupling substances; Solvents therefor
- G03C7/3885—Processes for the incorporation in the emulsion of substances liberating photographically active agents or colour-coupling substances; Solvents therefor characterised by the use of a specific solvent
Definitions
- the anionic acidic polymers used in conjunction with the dispersed polythiophene polymer preferably have a content of anionic groups of more than 2% by weight with respect to said polymer compounds to ensure sufficient stability of the dispersion.
- Suitable acidic polymers or corresponding salts have been described e.g. in DE-A's 25 41 230, 25 41 274 and 28 35 856, in EP-A's 0 014 921 0 069 671 and 0 130 115, and in US-A's 4,147,550; 4,388,403 and 5,006,451.
- the polymeric polyanion compounds may consist of straight-chain, branched chain or cross-linked polymers.
- the support is a polyethylene terephthalate layer provided with subbing layers at both sides, the subbing layer at the light-sensitive comprising the compound(s) providing permanent antistatic properties (electronic conductivity).
- a black and white silver halide motion picture sound recording film may be used, said film comprising a support bearing at least one silver halide emulsion layer, wherein said film is spectrally sensitized both above and below 600 nm as disclosed in US-A 5,955,255, thus being panchromatically sensitized as in GB 449,546 and corresponding FR 784,027.
- Such film may be used for recording multiple optical soundtracks by exposing said film with a first source of radiation having a peak wavelength of less than or equal to 600 nm, recording a second digital soundtrack by exposing said film with a second source of radiation having a peak wavelength of greater than 600 nm, and processing said exposed film to form first and second digital soundtrack silver images.
- Drying was performed during 1 minute at 120°C.
- Both materials were coated with an outermost backing layer comprising acid as an antistatic agent: polystyrene sulfonic acid in an amount of 35 mg/m 2 ; as a binder: a sodium salt latex copolymer of vinyl acetate/maleic acid in an amount of 20 mg/m 2 ; and as a lubricant polyethylene wax in an amount of 12.5 mg/m 2 .
- acid as an antistatic agent: polystyrene sulfonic acid in an amount of 35 mg/m 2 ; as a binder: a sodium salt latex copolymer of vinyl acetate/maleic acid in an amount of 20 mg/m 2 ; and as a lubricant polyethylene wax in an amount of 12.5 mg/m 2 .
Claims (10)
- Ein fotografisches Silberhalogenid-Filmelement, das auf einer lichtempfindlichen Seite eines lichtdurchlässigen Polyesterträgers der Reihe nach eine elektrisch leitende Haftschicht, eine unterliegende Lichthofschutzschicht, eine lichtempfindliche Emulsionsschicht oder Emulsionsschichtenanordnung und eine Schutzdeckschicht und auf einer lichtunempfindlichen Rückschicht auf der gegenüberliegenden Seite der Reihe nach eine ein Gleitmittel enthaltende Haftschicht und eine Deckschicht enthält, dadurch gekennzeichnet, dass die Haftschicht auf der lichtempfindlichen Seite ein Antistatikum, das dem sowohl entwickelten als nichtentwickelten Element einen wesentlichen konstanten elektrischen Widerstand verleiht, enthält, wobei die Unterschiede vor und nach Entwicklung weniger als ein Faktor 100 Ω/□ betragen, während der Reibungskoeffizient der Rückschicht auf der Rückschichtseite, bezogen auf rostfreien Stahl, vor und,nach Entwicklung des Materials unverändert zwischen 0,20 und 0,30 liegt.
- Element nach Anspruch 1, dadurch gekennzeichnet, dass das in der Haftschicht an der lichtempfindlichen Seite enthaltene Antistatikum, das der Haftschicht vor und nach Entwicklung des Materials einen konstanten elektrischen Widerstand verleiht, eine in die Haftschicht(en) eingearbeitete Polythiophenverbindung ist.
- Element nach Anspruch 1, dadurch gekennzeichnet, dass das in der Haftschicht an der lichtempfindlichen Seite enthaltene Antistatikum, das der Haftschicht vor und nach Entwicklung des Materials einen konstanten elektrischen Widerstand verleiht, eine Metalloxidverbindung ist, wobei als Metall Zinn, Indiumzinn, Vanadium, Zink, Mangan, Titan, Indium, Silicium, Magnesium, Barium, Molybdän oder Wolfram verwendet wird.
- Element nach einem der Ansprüche 1 bis 3, dadurch gekennzeichnet, dass der elektrische Widerstand zwischen 1 x 105 und 1 x 1012 Ω/□ liegt, wobei die Messung wie in Research Disclosure Juni 1992, Aufsatz 33840, beschrieben für die Haftschicht als Schicht mit dem niedrigsten elektrischen Widerstand erfolgt.
- Element nach einem der Ansprüche 1 bis 3, dadurch gekennzeichnet, dass der elektrische Widerstand an der Emulsionsseite des Elements oder Materials zwischen 1 x 107 und 1 x 1010 Ω/□ liegt.
- Element nach einem der Ansprüche 1 bis 5, dadurch gekennzeichnet, dass die unterliegende Lichthofschutzschicht einen oder mehrere Farbstoffe, u.a. zumindest einen diffusionsfesten Gelbfarbstoff, der Blaulicht absorbiert und in einem Entwicklungsbad entfernbar ist und/oder sich darin entfärbt und, aus der Gruppe bestehend aus Merostyrylfarbstoffen und Monomethinoxonolfarbstoffen gewählt wird, enthält.
- Element nach Anspruch 6, dadurch gekennzeichnet, dass die unterliegende Lichthofschutzschicht ein hochsiedendes Lösungsmittel enthält.
- Element nach Anspruch 7, dadurch gekennzeichnet, dass das hochsiedende Lösungsmittel in einer Gesamtmenge zwischen 0,1 g/m2 und 0,5 g/m2 enthalten ist.
- Element nach einem der Ansprüche 1 bis 8, dadurch gekennzeichnet, dass das Gleitmittel in zumindest der Haftschicht der lichtunempfindlichen Rückschicht enthalten ist und das Gleitmittel eine Verbindung aus der Gruppe bestehend aus Carnaubawachs, Montanwachs, Polyethylen, einem fluorierten Polymer, einem Silikonpolymer, Estern von Fettsäuren mit höherem Alkohol, höheren Fettsäurecalciumsalzen, Metallstearaten, wasserdispergierbarem.siloxanhaltigem Polyurethan, das aus einem anionische und nicht-anionische hydrophile Gruppen enthaltenden Prepolymer erhalten wird, und Paraffinen ist.
- Element nach einem der Ansprüche 1 bis 9, dadurch gekennzeichnet, dass die Deckschicht der lichtunempfindlichen Rückschicht Polystyrolsulfonsäure in einer Menge zwischen 20 und 50 mg/m2 enthält.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
EP01000511A EP1202115B1 (de) | 2000-10-05 | 2001-09-28 | Photographisches Silberhalogenidmaterial mit einer dauerhaften elektrisch leitenden Haftvermittlungsschicht und einer kratzfesten Rückseitenschicht |
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
EP00203479 | 2000-10-05 | ||
EP00203479 | 2000-10-05 | ||
EP01000511A EP1202115B1 (de) | 2000-10-05 | 2001-09-28 | Photographisches Silberhalogenidmaterial mit einer dauerhaften elektrisch leitenden Haftvermittlungsschicht und einer kratzfesten Rückseitenschicht |
Publications (2)
Publication Number | Publication Date |
---|---|
EP1202115A1 EP1202115A1 (de) | 2002-05-02 |
EP1202115B1 true EP1202115B1 (de) | 2004-03-31 |
Family
ID=26072762
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP01000511A Expired - Lifetime EP1202115B1 (de) | 2000-10-05 | 2001-09-28 | Photographisches Silberhalogenidmaterial mit einer dauerhaften elektrisch leitenden Haftvermittlungsschicht und einer kratzfesten Rückseitenschicht |
Country Status (1)
Country | Link |
---|---|
EP (1) | EP1202115B1 (de) |
Families Citing this family (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN103411968B (zh) * | 2013-07-31 | 2016-07-06 | 南京梅山冶金发展有限公司 | 一种适用于钢渣中全铁含量的检测方法 |
CN105058929B (zh) * | 2015-07-17 | 2018-06-01 | 张家港康得新光电材料有限公司 | 一种多功能屏幕保护膜 |
CN106626678A (zh) * | 2016-11-07 | 2017-05-10 | 深圳市华新龙纸品包装有限公司 | 一种息屏显影保护膜、制备方法以及息屏显影方法 |
CN110790910B (zh) * | 2019-10-15 | 2021-12-28 | 南通大学 | 一种结晶自细化聚酯及其制备方法 |
Family Cites Families (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
ES2014297B3 (es) * | 1986-07-08 | 1990-07-01 | Agfa-Gevaert Nv | Elemento fotografico colorante para proyeccion cinematografica. |
US5679505A (en) * | 1995-11-02 | 1997-10-21 | Eastman Kodak Company | Photographic element useful as a motion picture print film |
US5747232A (en) * | 1997-02-27 | 1998-05-05 | Eastman Kodak Company | Motion imaging film comprising a carbon black-containing backing and a process surviving conductive subbing layer |
US6124083A (en) * | 1998-10-15 | 2000-09-26 | Eastman Kodak Company | Antistatic layer with electrically conducting polymer for imaging element |
-
2001
- 2001-09-28 EP EP01000511A patent/EP1202115B1/de not_active Expired - Lifetime
Also Published As
Publication number | Publication date |
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EP1202115A1 (de) | 2002-05-02 |
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