EP1188816B1 - Produits de lavage et de nettoyage à base de mélanges d'oligoglycosides d'alkyle et/ou d'alcenyle et d'alcools gras - Google Patents

Produits de lavage et de nettoyage à base de mélanges d'oligoglycosides d'alkyle et/ou d'alcenyle et d'alcools gras Download PDF

Info

Publication number
EP1188816B1
EP1188816B1 EP01121509A EP01121509A EP1188816B1 EP 1188816 B1 EP1188816 B1 EP 1188816B1 EP 01121509 A EP01121509 A EP 01121509A EP 01121509 A EP01121509 A EP 01121509A EP 1188816 B1 EP1188816 B1 EP 1188816B1
Authority
EP
European Patent Office
Prior art keywords
alkyl
acid
alcohol
weight
carbon atoms
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
EP01121509A
Other languages
German (de)
English (en)
Other versions
EP1188816A1 (fr
Inventor
Rainer Dr. Eskuchen
Ditmar Kischkel
Manfred Dr. Weuthen
Michael Dr. Köhler
Werner Leinemann
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
BASF Personal Care and Nutrition GmbH
Original Assignee
Cognis Deutschland GmbH and Co KG
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Cognis Deutschland GmbH and Co KG filed Critical Cognis Deutschland GmbH and Co KG
Publication of EP1188816A1 publication Critical patent/EP1188816A1/fr
Application granted granted Critical
Publication of EP1188816B1 publication Critical patent/EP1188816B1/fr
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66—Non-ionic compounds
    • C11D1/825—Mixtures of compounds all of which are non-ionic
    • C11D1/8255—Mixtures of compounds all of which are non-ionic containing a combination of compounds differently alcoxylised or with differently alkylated chains
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66—Non-ionic compounds
    • C11D1/662—Carbohydrates or derivatives
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/20—Organic compounds containing oxygen
    • C11D3/2003—Alcohols; Phenols
    • C11D3/2006—Monohydric alcohols
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66—Non-ionic compounds
    • C11D1/72—Ethers of polyoxyalkylene glycols
    • C11D1/721—End blocked ethers
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66—Non-ionic compounds
    • C11D1/722—Ethers of polyoxyalkylene glycols having mixed oxyalkylene groups; Polyalkoxylated fatty alcohols or polyalkoxylated alkylaryl alcohols with mixed oxyalkylele groups

Definitions

  • a preferred embodiment according to the invention means a fatty alcohol polyethylene glycol / polypropylene glycol ethers of formula (III) in which R 3 is an aliphatic, saturated, linear or branched alkyl radical having 8 to 16 carbon atoms, n is a number from 1 to 10, and m represents 0 and R 4 represents hydrogen . These are addition products of 1 to 10 moles of ethylene oxide with monofunctional alcohols.
  • the alcohols described above, such as fatty alcohols, oxo alcohols and Guerbet alcohols, are suitable as alcohols.
  • nonionic surfactants are fatty alcohol polyglycol ethers, alkylphenol polyglycol ethers, Fatty acid polyglycol ester, fatty acid amide polyglycol ether, fatty amine polyglycol ether, alkoxylated triglycerides, mixed ethers or mixed formals, alk (en) yl oligoglycosides, fatty acid N-alkyl glucamides, Protein hydrolyzates (especially vegetable products based on wheat), polyol fatty acid esters, Sugar esters, sorbitan esters, polysorbates and amine oxides.
  • nonionic surfactants Containing polyglycol ether chains these can be conventional, but preferably one have narrow homolog distribution.
  • Alkyl and / or Alkenyl oligoglycosides (different from those according to the invention), further alkoxylated alkanols, Hydroxy mixed ether, fatty acid lower alkyl esters and amine oxides used.
  • Hydroxy mixed ethers are known nonionic surfactants with an asymmetrical ether structure and polyalkylene glycol components, which can be obtained, for example, by subjecting olefin epoxides to a ring-opening reaction with fatty alcohol polyglycol ethers.
  • HME Hydroxy mixed ethers
  • Corresponding products and their use in the field of cleaning hard surfaces is the subject of, for example, European patent EP-B1 0693049 and international patent application WO 94/22800 (Olin) and the documents mentioned therein.
  • R 7 represents a linear or branched alkyl radical having 2 to 18, preferably 10 to 16 carbon atoms
  • R 2 represents hydrogen or a linear or branched alkyl radical having 2 to 18 carbon atoms
  • R 3 represents hydrogen or methyl
  • R 10 represents a linear or branched, alkyl and / or alkenyl radical having 6 to 22, preferably 12 to 18 carbon atoms
  • e represents numbers from 1 to 50, preferably 2 to 25 and in particular 5 to 15, with the proviso that the sum of the carbon atoms in the radicals R 7 and R 8 is at least 4 and preferably 12 to 18.
  • the HME ring opening products can be either from internal olefins (R 8 not equal to hydrogen) or terminal olefins (R 8 equal to hydrogen), the latter being preferred in view of the easier preparation and the more advantageous application properties.
  • the polar part of the molecule can be a polyethylene glycol (PE) or a polypropylene glycol chain (PP); Mixed chains of PE and PP units are also suitable, be it in statistical or block distribution.
  • the products are usually prepared by inserting the alkylene oxides into the carbonyl ester bond in the presence of special catalysts, such as, for example, calcined hydrotalcite. Reaction products of an average of 5 to 10 moles of ethylene oxide into the ester linkage of technical coconut fatty acid methyl esters are particularly preferred.
  • the preparation of the amine oxides of the formula (VII) starts from tertiary fatty amines which have at least one long alkyl radical and is oxidized in the presence of hydrogen peroxide.
  • R 16 represents a linear or branched alkyl radical having 6 to 22, preferably 12 to 18 carbon atoms, and R 14 and R 15 independently of one another are R 16 or, if appropriate hydroxy-substituted alkyl radical with 1 to 4 carbon atoms.
  • washing and cleaning agents characterized in that they contain anionic surfactants selected from the group consisting of alkyl and / or alkenyl sulfates, alkyl ether sulfates, alkyl benzene sulfonates, soaps, monoglyceride (ether) sulfates and alkane sulfonates.
  • anionic surfactants selected from the group consisting of alkyl and / or alkenyl sulfates, alkyl ether sulfates, alkyl benzene sulfonates, soaps, monoglyceride (ether) sulfates and alkane sulfonates.
  • anionic surfactants are soaps, alkyl benzene sulfonates, secondary alkane sulfonates, olefin sulfonates, alkyl ether sulfonates, glycerin ether sulfonates, ⁇ -methyl ester sulfonates, sulfo fatty acids, alkyl and / or alkenyl sulfates, alkyl ether sulfates, glycerin ether sulfates, mono- ether sulfate sulfates , hydroxymischogether sulfate, fatty acid ether sulfate sulfates, Mono- and dialkylsulfosuccinates, mono- and dialkylsulfosuccinamates, sulfotriglycerides, amide soaps, ether carboxylic acids and their salts, fatty acid isethionates, fatty acid
  • Alkyl and / or alkenyl sulfates which are also often referred to as fatty alcohol sulfates, are to be understood as the sulfation products of primary alcohols which follow the formula (IX) R 40 O-SO 3 X in which R 40 represents a linear or branched, aliphatic alkyl and / or alkenyl radical having 6 to 22, preferably 12 to 18 carbon atoms and X represents an alkali and / or alkaline earth metal, ammonium, alkylammonium, alkanolammonium or glucammonium.
  • alkyl sulfates which can be used in the context of the invention are the sulfation products of capron alcohol, caprylic alcohol, capric alcohol, 2-ethylhexyl alcohol, lauryl alcohol, myristyl alcohol, cetyl alcohol, palmoleyl alcohol, stearyl alcohol, isostearyl alcohol, oleyl alcohol, aryl selenyl alcohol, elaidyl alcohol, Behenyl alcohol and erucyl alcohol as well as their technical mixtures, which are obtained by high pressure hydrogenation of technical methyl ester fractions or aldehydes from Roelen's oxosynthesis.
  • ether sulfates are known anionic surfactants which are produced on an industrial scale by SO 3 - or chlorosulfonic acid (CSA) sulfation of fatty alcohol or oxo alcohol polyglycol ethers and subsequent neutralization.
  • SO 3 - or chlorosulfonic acid (CSA) sulfation of fatty alcohol or oxo alcohol polyglycol ethers and subsequent neutralization.
  • ether sulfates are suitable which follow the formula (X) R 17 O- (CH 2 CH 2 O) a SO 3 X in which R 17 represents a linear or branched alkyl and / or alkenyl radical with 6 to 22 carbon atoms, a for numbers from 1 to 10 and X for an alkali and / or alkaline earth metal, ammonium, alkylammonium, alkanolammonium or glucammonium.
  • Typical examples are the sulfates of addition products with an average of 1 to 10 and in particular 2 to 5 moles of ethylene oxide with capron alcohol, caprylic alcohol, 2-ethylhexyl alcohol, capric alcohol, lauryl alcohol, isotridecyl alcohol, myristyl alcohol, cetyl alcohol, palmoleyl alcohol, stearyl alcohol, isostearyl alcohol, oleyl alcohol, oleyl alcohol, oleyl alcohol, oleyl alcohol, oleyl alcohol, oleyl alcohol, oleyl alcohol, oleyl alcohol, oleyl alcohol, oleyl alcohol, oleyl alcohol, oleyl alcohol, oleyl alcohol, oleyl alcohol, oleyl alcohol, oleyl alcohol, oleyl alcohol, oleyl alcohol, eleyl alcohol, oleyl alcohol, eleyl alcohol, Gadoleyl alcohol, behenyl alcohol, erucyl alcohol and brassidyl
  • Alkylbenzenesulfonates preferably follow the formula (XI) , R 18 -Ph-SO 3 X in which R 18 is a branched, but preferably linear alkyl radical having 10 to 18 carbon atoms, Ph is a phenyl radical and X is an alkali and / or alkaline earth metal, ammonium, alkylammonium, alkanolammonium or glucammonium.
  • Dodecylbenzenesulfonates, tetradecylbenzenesulfonates, hexadecylbenzenesulfonates and their technical mixtures in the form of the sodium salts are preferably used.
  • Monoglyceride sulfates and monoglyceride ether sulfates are known anionic surfactants which can be obtained by the relevant methods of preparative organic chemistry.
  • the usual starting point for their production is triglycerides, which, if appropriate, are transesterified to the monoglycerides after ethoxylation and subsequently sulfated and neutralized.
  • suitable sulfating agents preferably gaseous sulfur trioxide or chlorosulfonic acid [cf. EP 0561825 B1, EP 0561999 B1 (Henkel)].
  • the neutralized substances can be subjected to ultrafiltration in order to reduce the electrolyte content to a desired level [DE 4204700 A1 (Henkel)].
  • Overviews of the chemistry of the monoglyceride sulfates are, for example, by AK Biswas et al. in J.Am.Oil.Chem.Soc. 37 , 171 (1960) and FU Ahmed J.Am.Oil.Chem.Soc. 67 , 8 (1990) .
  • Typical examples of monoglyceride (ether) sulfates suitable for the purposes of the invention are the reaction products of lauric acid monoglyceride, coconut fatty acid monoglyceride, palmitic acid monoglyceride, stearic acid monoglyceride, oleic acid monoglyceride and tallow fatty acid monoglyceride as well as their ethylene oxide adducts or their formulated with sulfuric acid trioxide.
  • Monoglyceride sulfates of the formula (XII) are preferably used, in which R 19 CO stands for a linear acyl radical having 8 to 18 carbon atoms.
  • soaps are to be understood as meaning fatty acid salts of the formula (XIV) R 41 CO-OX in which R 41 CO represents a linear or branched, saturated or unsaturated acyl radical having 6 to 22 and preferably 12 to 18 carbon atoms and X represents alkali and / or alkaline earth metal, ammonium, alkylammonium or alkanolammonium.
  • quaternized fatty acid triethanolamine ester salts of the formula (XV) , in which R 44 CO stands for an acyl radical with 6 to 22 carbon atoms, R 45 and R 46 independently of one another for hydrogen or R 14 CO, R 15 for an alkyl radical with 1 to 4 carbon atoms or a (CH 2 CH 2 O) m4 H- Group, m1, m2 and m3 in total for 0 or numbers from 1 to 12, m4 for numbers from 1 to 12 and Y for halide, alkyl sulfate or alkyl phosphate.
  • R 44 CO stands for an acyl radical with 6 to 22 carbon atoms
  • R 45 and R 46 independently of one another for hydrogen or R 14 CO
  • R 15 for an alkyl radical with 1 to 4 carbon atoms or a (CH 2 CH 2 O) m4 H- Group
  • m1, m2 and m3 in total for 0 or numbers from 1 to 12
  • quaternized fatty acid triethanolamine ester salts of the formula (VIII) have proven to be particularly advantageous in which R 44 CO for an acyl radical having 16 to 18 carbon atoms, R 45 for R 45 CO, R 46 for hydrogen, R 17 for a methyl group, m1 , m2 and m3 stands for 0 and Y for methyl sulfate.
  • the detergents can be anionic, nonionic and / or amphoteric or zwitterionic Surfactants in amounts of 0.5 to 50, preferably 5 to 25 and in particular 10 to 20% by weight - based on the detergent - included.
  • Another object of the invention is the use of the mixture of components a and b in detergents and cleaning agents to increase washing performance at low temperatures, preferably at 30 to 40 ° C.
  • the detergents and cleaning agents can be in various dosage forms available.
  • Suitable substitutes or partial substitutes for phosphates and zeolites are crystalline, layered sodium silicates of the general formula NaMSi x O 2x + 1 .yH 2 O, where M is sodium or hydrogen, x is a number from 1.9 to 4 and y is a number from 0 to 20 and preferred values for x are 2, 3 or 4.
  • Such crystalline layered silicates are described, for example, in European patent application EP 0164514 A1 .
  • Preferred crystalline layered silicates of the formula given are those in which M represents sodium and x assumes the values 2 or 3.
  • Such so-called X-ray amorphous silicates which also have a delay in dissolution compared to conventional water glasses, are described, for example, in German patent application DE 4400024 A. 1. Particularly preferred are compressed / compacted amorphous silicates, compounded amorphous silicates and over-dried X-ray amorphous silicates.
  • dextrins for example oligomers or polymers of carbohydrates, which can be obtained by partial hydrolysis of starches.
  • the hydrolysis can be carried out by customary, for example acid or enzyme-catalyzed, processes. They are preferably hydrolysis products with average molecular weights in the range from 400 to 500,000.
  • DE dextrose equivalent
  • the relative molecular weight, based on free acids, is generally 5,000 to 200,000, preferably 10,000 to 120,000 and in particular 50,000 to 100,000 (measured in each case against polystyrene sulfonic acid).
  • the (co) polymeric polycarboxylates can be used either as a powder or as an aqueous solution, with 20 to 55% by weight aqueous solutions being preferred.
  • Granular polymers are usually subsequently mixed into one or more basic granules.
  • biodegradable polymers composed of more than two different monomer units, for example those which, according to DE 4300772 A1, are salts of acrylic acid and maleic acid, as well as vinyl alcohol or vinyl alcohol derivatives, or, according to DE 4221381 C2, are monomer salts of acrylic acid and the 2-alkylallylsulfonic acid and sugar derivatives.
  • Further preferred copolymers are those which are described in German patent applications DE 4303320 A1 and DE 4417734 A1 and which preferably contain acrolein and acrylic acid / acrylic acid salts or acrolein and vinyl acetate as monomers.
  • polymeric aminodicarboxylic acids are also to be mentioned as further preferred builder substances. Polyaspartic acids or their salts and derivatives are particularly preferred.
  • Enzyme mixtures for example of protease and amylase or Protease and lipase or lipolytic enzymes or protease and cellulase or from Cellulase and lipase or lipolytically active enzymes or from protease, amylase and lipase or lipolytic enzymes or protease, lipase or lipolytic enzymes and Cellulase, in particular, however, mixtures or mixtures containing protease and / or lipase lipolytic enzymes of particular interest.
  • lipolytically active Enzymes are the well-known cutinases. Peroxidases or oxidases have also been found in some cases proven suitable.
  • Graying inhibitors have the task of removing the dirt detached from the fiber in the liquor to keep suspended and thus prevent the dirt from re-opening.
  • they are water soluble Colloids mostly of an organic nature are suitable, for example the water-soluble salts polymeric carboxylic acids, glue, gelatin, salts of ether carboxylic acids or ether sulfonic acids Starch or cellulose or salts of acidic sulfuric acid esters of cellulose or starch.
  • Water-soluble polyamides containing acidic groups are also suitable for this purpose.
  • Farther soluble starch preparations and starch products other than those mentioned above can be used, e.g. degraded starch, aldehyde starches, etc.
  • Polyvinylpyrrolidone can also be used.
  • Preferred polymers are those with molar ratios of ethylene terephthalate / polyethylene glycol terephthalate from about 65:35 to about 90:10, preferably from about 70:30 to 80:20. Also preferred are those polymers that have linking polyethylene glycol units with a molecular weight of 750 to 5000, preferably from 1000 to about 3000 and a molecular weight of the polymer of about 10,000 to about 50,000.
  • Milease® products are examples of commercially available polymers T (ICI) or Repelotex® SRP 3 (Rhône-Poulenc).
  • Suitable paraffin waxes generally represent a complex mixture of substances without a sharp melting point. For characterization, one usually determines its melting range by differential thermal analysis (DTA), as described in "The Analyst” 87 (1962), 420 , and / or its solidification point , This is the temperature at which the paraffin changes from the liquid to the solid state by slow cooling. Paraffins which are completely liquid at room temperature, that is to say those having a solidification point below 25 ° C., cannot be used according to the invention.
  • the soft waxes which have a melting point in the range from 35 to 50 ° C., preferably include the group of petrolates and their hydrogenation products.
  • the ethers include, for example, benzyl ethyl ether, the aldehydes e.g. the linear alkanals with 8-18 C atoms, citral, citronellal, citronellyloxyacetaldehyde, cyclamenaldehyde, Hydroxycitronellal, Lilial and Bourgeonal, to the ketones e.g.

Landscapes

  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Molecular Biology (AREA)
  • Emergency Medicine (AREA)
  • Detergent Compositions (AREA)

Claims (9)

  1. Produits de lavage et de nettoyage contenant un système d'agents tensioactifs dans lequel ce système d'agents tensioactifs est constitué au moins des composants suivants :
    a) des alkyl et/ou alkényloligoglycosides de formule (I) R1O-[G]p dans laquelle R1 représente un reste alkyle et/ou alkényle, ayant de 4 à 22 atomes de carbone, G représente un reste de sucre ayant 5 ou 6 atomes de carbone et p représente des nombres allant de 1 à 10, et
    b) un alcool gras de formule (II) R1OH dans laquelle R1 représente un reste alkyle et/ou alkényle ayant de 4 à 22 atomes de carbone et
    c) des éthers d'alcool gras et de polyéthylèneglycol/polypropylèneglycol de formule (III) R3O(CH2CH2O)n[CH2(CH3)CHO]mR4 dans laquelle R3 représente un reste alkyle et/ou alkylène ayant de 8 à 22 atomes de carbone, R4 représente H ou un reste alkyle ayant de 1 à 8 atomes de carbone, n représente un nombre allant de 1 à 40, de préférence de 1 à 30, en particulier de 1 à 15 et m représente 0 ou un nombre allant de 1 à 10,
    et/ou un éther d'alcool gras et de polypropylèneglycol/polyéthylèneglycol de formule (IV) R5O[CH2(CH3)CHO]q(CH2CH2O)rR6 dans laquelle R5 représente un reste alkyle et/ou alkylène ayant de 8 à 22 atomes de carbone, R6 représente H ou un reste alkyle ayant de 1 à 8 atomes de carbone, q un nombre allant de 1 à 5, et r un nombre allant de 0 à 15,
    caractérisés en ce que
    le composant b est présent en quantités de 5 à 35 % en poids rapporté à la substance active alkyl et/ou alkényloligoglycoside.
  2. Produits de lavage et de nettoyage selon la revendication 1,
    caractérisés en ce que
    des alcools gras de formule (II) et/ou des alcools gras ayant des restes alkyle et/ou alkényle (R2) différents de R1, sont présents.
  3. Produits de lavage et de nettoyage selon l'une des revendications 1 à 2,
    caractérisés en ce que
    le mélange des composants a) et b) renferme au maximum 2 % en poids d'eau.
  4. Produits de lavage et de nettoyage selon l'une des revendications 1 à 3,
    caractérisé en ce que
    d'autres alcools et/ou oxydes d'alkylène - de préférence l'éthanol, le n-butanol, le n-propanol, l'isopropanol, ainsi que des mono-, oligo- et polyglycols à base d'éthylènediol, de propylènediol, de butylènediol -, en particulier le 1,2-propanediol et le 1,3-propanediol et leurs éthers méthyliques, éthyliques, et butyliques, sont présents.
  5. Produits de lavage et de nettoyage selon l'une des revendications 1 à 4,
    caractérisés en ce que
    d'autres agents tensioactifs non ioniques sont présents, choisis dans le groupe formé des alkyl- et/ou alkénylglycosides (différents de ceux conformes à l'invention), d'autres alcanols alkoxylés, des éthers mixtes hydroxylés, des esters d'alkyle inférieur d'acide gras et des oxydes d'amine.
  6. Produits de lavage et de nettoyage selon l'une des revendications 1 à 5,
    caractérisés en ce que
    des agents tensioactifs anioniques sont présents choisis dans le groupe formé d'alkyl- et/ou d'alkénylsulfates, d'alkyléthersulfates, d'alkylbenzènesulfonates, de savons, de monoglycéride(éther) sulfates et d'alcane sulfonates.
  7. Produits de lavage et de nettoyage selon l'une des revendications 1 à 6,
    caractérisés en ce que
    des agents tensioactifs cationiques, amphotères ou zwitterioniques sont présents, choisis dans le groupe formé des esters d'ammonium quaternaire, d'alkylbétaïnes, amidoaminebétaïnes et imidazoliniumbetaïnes.
  8. Produits de lavage et de nettoyage selon les revendications 1 à 7,
    contenant 0,5 à 25 % en poids, de préférence 1 à 15 % en poids, en particulier 2 à 10 % en poids - d'alkyl et/ou d'alkényloligoglycosides - rapporté à la substance active de la formulation.
  9. Utilisation du mélange des composants a) et b) dans les produits de lavage et de nettoyage selon l'une des revendications 1 à 8, en vue de l'augmentation de la force de lavage aux basses températures - de préférence à 30 à 40°C.
EP01121509A 2000-09-19 2001-09-08 Produits de lavage et de nettoyage à base de mélanges d'oligoglycosides d'alkyle et/ou d'alcenyle et d'alcools gras Expired - Lifetime EP1188816B1 (fr)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DE10046251A DE10046251A1 (de) 2000-09-19 2000-09-19 Wasch- und Reinigungsmittel auf Basis von Alkyl- und/oder Alkenyloligoglycosiden und Fettalkoholen
DE10046251 2000-09-19

Publications (2)

Publication Number Publication Date
EP1188816A1 EP1188816A1 (fr) 2002-03-20
EP1188816B1 true EP1188816B1 (fr) 2004-09-08

Family

ID=7656730

Family Applications (1)

Application Number Title Priority Date Filing Date
EP01121509A Expired - Lifetime EP1188816B1 (fr) 2000-09-19 2001-09-08 Produits de lavage et de nettoyage à base de mélanges d'oligoglycosides d'alkyle et/ou d'alcenyle et d'alcools gras

Country Status (4)

Country Link
US (1) US6723135B2 (fr)
EP (1) EP1188816B1 (fr)
DE (2) DE10046251A1 (fr)
ES (1) ES2225371T3 (fr)

Families Citing this family (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE10046251A1 (de) * 2000-09-19 2002-03-28 Cognis Deutschland Gmbh Wasch- und Reinigungsmittel auf Basis von Alkyl- und/oder Alkenyloligoglycosiden und Fettalkoholen
DE10046250A1 (de) * 2000-09-19 2002-03-28 Cognis Deutschland Gmbh Verfahren zur Herstellung von hellfarbigen Alkyl-und/oder Alkenyloligoglycosid-Mischungen und deren Verwendung in Wasch-, Spül-und Reinigungsmittel
US20040214737A1 (en) * 2003-04-25 2004-10-28 John Billman Foamy composition for pretreatment of stains on fabrics
EP1754778A1 (fr) * 2005-08-19 2007-02-21 The Procter and Gamble Company Composition détèrgente solide pour lavage comprenant un sulphonate d'alkylbenzene comme un système détersive anionique et un système chelant
US7964551B2 (en) * 2006-03-31 2011-06-21 Isp Investments Inc. Cleaning tablet
EP3458561B1 (fr) 2016-05-17 2020-10-14 Unilever PLC Compositions détergentes liquides pour blanchisserie

Family Cites Families (86)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE309931C (fr)
ZA734721B (en) 1972-07-14 1974-03-27 Procter & Gamble Detergent compositions
GB1455873A (en) 1973-08-24 1976-11-17 Procter & Gamble Textile-softening detergent compositions
DE2553900A1 (de) 1975-12-01 1977-06-08 Konrad Ruckstuhl Verfahren und vorrichtungen zur aufbereitung von gepressten zuckerrohrbagasse-ballen
EP0026529B2 (fr) 1979-09-29 1992-08-19 THE PROCTER & GAMBLE COMPANY Compositions détergentes
DE3066202D1 (en) 1979-11-03 1984-02-23 Procter & Gamble Granular laundry compositions
US4524009A (en) 1984-01-31 1985-06-18 A. E. Staley Manufacturing Company Detergent builder
CA1238917A (fr) 1984-01-31 1988-07-05 Vivian B. Valenty Adjuvant pour detergent
DE3413571A1 (de) 1984-04-11 1985-10-24 Hoechst Ag, 6230 Frankfurt Verwendung von kristallinen schichtfoermigen natriumsilikaten zur wasserenthaertung und verfahren zur wasserenthaertung
US4639325A (en) 1984-10-24 1987-01-27 A. E. Staley Manufacturing Company Detergent builder
DE3526405A1 (de) 1985-07-24 1987-02-05 Henkel Kgaa Schichtsilikate mit beschraenktem quellvermoegen, verfahren zu ihrer herstellung und ihre verwendung in wasch- und reinigungsmitteln
FR2597473B1 (fr) 1986-01-30 1988-08-12 Roquette Freres Procede d'oxydation de di-, tri-, oligo- et polysaccharides en acides polyhydroxycarboxyliques, catalyseur mis en oeuvre et produits ainsi obtenus.
GB8629837D0 (en) 1986-12-13 1987-01-21 Interox Chemicals Ltd Bleach activation
DE3706036A1 (de) 1987-02-25 1988-09-08 Basf Ag Polyacetale, verfahren zu deren herstellung aus dialdehyden und polyolcarbonsaeuren und verwendung der polyacetale
DE3723826A1 (de) 1987-07-18 1989-01-26 Henkel Kgaa Verfahren zur herstellung von alkylglykosiden
DE3732947A1 (de) 1987-09-30 1989-04-13 Henkel Kgaa Zur verwendung in wasch- und reinigungsmitteln geeignetes schaumregulierungsmittel
DE3833780A1 (de) 1988-10-05 1990-04-12 Henkel Kgaa Verfahren zur direkten herstellung von alkylglykosiden
US5576425A (en) 1988-10-05 1996-11-19 Henkel Kommanditgesellschaft Auf Aktien Process for the direct production of alkyl glycosides
JP2571117B2 (ja) * 1989-02-03 1997-01-16 花王株式会社 洗浄剤組成物
GB8908416D0 (en) 1989-04-13 1989-06-01 Unilever Plc Bleach activation
US5707957A (en) * 1989-09-22 1998-01-13 Colgate-Palmolive Co. Liquid crystal compositions
DK0427349T3 (da) 1989-11-10 1995-11-20 Tno Fremgangsmåde til fremstilling af polydicarboxysaccharider, og erstatninger for phosphater i detergenter baseret på polydicarboxsaccharider
YU221490A (sh) 1989-12-02 1993-10-20 Henkel Kg. Postupak za hidrotermalnu izradu kristalnog natrijum disilikata
GB9003741D0 (en) 1990-02-19 1990-04-18 Unilever Plc Bleach activation
US5041232A (en) 1990-03-16 1991-08-20 Lever Brothers Company, Division Of Conopco, Inc. Sulfonimines as bleach catalysts
US5047163A (en) 1990-03-16 1991-09-10 Lever Brothers Company, Division Of Conopco, Inc. Activation of bleach precursors with sulfonimines
ES2100925T3 (es) 1990-05-21 1997-07-01 Unilever Nv Activacion de blanqueador.
IT1249883B (it) 1990-08-13 1995-03-30 Ferruzzi Ricerca & Tec Agenti sequestranti del calcio a base di carboidrati ossidati e loro impiego come builder per detergenti
JPH06503060A (ja) 1990-12-01 1994-04-07 ヘンケル・コマンディットゲゼルシャフト・アウフ・アクチェン 結晶性二珪酸ナトリウムの水熱製造方法
DE4038478A1 (de) 1990-12-03 1992-06-04 Henkel Kgaa Verfahren zur herstellung von partialglyceridsulfaten
DE4038477A1 (de) 1990-12-03 1992-06-04 Henkel Kgaa Verfahren zur kontinuierlichen herstellung von partialglyceridsulfaten
GB9027414D0 (en) * 1990-12-18 1991-02-06 Unilever Plc Detergent compositions
GB9101606D0 (en) 1991-01-24 1991-03-06 Dow Corning Sa Detergent foam control agents
IT1245063B (it) 1991-04-12 1994-09-13 Ferruzzi Ricerca & Tec Procedimento per l'ossidazione di carboidrati
ATE155165T1 (de) 1991-07-31 1997-07-15 Ausimont Spa Verfahren zur erhöhung der bleichwirksamkeit eines inorganischen persalzes
DE4134914A1 (de) 1991-10-23 1993-04-29 Henkel Kgaa Wasch- und reinigungsmittel mit ausgewaehlten builder-systemen
EP0542496B1 (fr) 1991-11-14 1998-05-20 The Procter & Gamble Company Amidon oxydé à C6/C2-C3 utilisé comme ingrédient pour détergent
CA2083661A1 (fr) 1991-11-26 1993-05-27 Rudolf J. Martens Compositions pour detersif
US5194416A (en) 1991-11-26 1993-03-16 Lever Brothers Company, Division Of Conopco, Inc. Manganese catalyst for activating hydrogen peroxide bleaching
CA2085642A1 (fr) 1991-12-20 1993-06-21 Ronald Hage Activation de blanchiment
GB9127060D0 (en) 1991-12-20 1992-02-19 Unilever Plc Bleach activation
DE4221381C1 (de) 1992-07-02 1994-02-10 Stockhausen Chem Fab Gmbh Pfropf-Copolymerisate von ungesättigten Monomeren und Zuckern, Verfahren zu ihrer Herstellung und ihre Verwendung
DE4203923A1 (de) 1992-02-11 1993-08-12 Henkel Kgaa Verfahren zur herstellung von polycarboxylaten auf polysaccharid-basis
DE4204700A1 (de) 1992-02-17 1993-08-19 Henkel Kgaa Verfahren zur abtrennung anorganischer salze
DE69320040T2 (de) 1992-05-08 1998-12-10 Buckman Labor Inc Halogenierte 4'-methoxyacetophenone als mikrobizide und konservierungsmittel
JPH05339896A (ja) 1992-06-03 1993-12-21 Arakawa Chem Ind Co Ltd 紙用サイズ剤および紙サイジング方法
DE4300772C2 (de) 1993-01-14 1997-03-27 Stockhausen Chem Fab Gmbh Wasserlösliche, biologisch abbaubare Copolymere auf Basis von ungesättigten Mono- und Dicarbonsäuren, Verfahren zu ihrer Herstellung und ihre Verwendung
DE4303320C2 (de) 1993-02-05 1995-12-21 Degussa Waschmittelzusammensetzung mit verbessertem Schmutztragevermögen, Verfahren zu dessen Herstellung und Verwendung eines geeigneten Polycarboxylats hierfür
US5576281A (en) 1993-04-05 1996-11-19 Olin Corporation Biogradable low foaming surfactants as a rinse aid for autodish applications
DE69412092T2 (de) 1993-05-20 1999-04-01 Procter & Gamble Bleichmittel, welche einen substituierten benzoyl caprolactam bleichaktivator enthalten
JP3347734B2 (ja) 1993-05-20 2002-11-20 ザ、プロクター、エンド、ギャンブル、カンパニー Ｎ−アシルカプロラクタム活性剤を含む漂白組成物
CN1065563C (zh) 1993-05-20 2001-05-09 普罗格特-甘布尔公司 用于手洗或其它低水洗涤体系的包括n－酰基己内酰胺的漂白组合物
DE4317089A1 (de) 1993-05-21 1994-11-24 Henkel Kgaa Nichtionische Emulgatoren
DE4317519A1 (de) 1993-05-26 1994-12-01 Henkel Kgaa Herstellung von Polycarboxylaten auf Polysaccharid-Basis
US5405413A (en) 1993-06-24 1995-04-11 The Procter & Gamble Co. Bleaching compounds comprising acyl valerolactam bleach activators
NL194919C (nl) 1993-09-07 2003-07-04 Tno Werkwijze voor het oxideren van koolhydraten.
DE4335781C2 (de) 1993-10-20 1998-02-19 Henkel Kgaa Fettalkohole auf pflanzlicher Basis und Verfahren zu Ihrer Herstellung
FR2712595B1 (fr) * 1993-11-19 1995-12-22 Seppic Sa Un concentré comportant des alkylglycosides et ses utilisations.
DE4400024A1 (de) 1994-01-03 1995-07-06 Henkel Kgaa Silikatische Builder und ihre Verwendung in Wasch- und Reinigungsmitteln sowie Mehrstoffgemische für den Einsatz auf diesem Sachgebiet
DE4402851A1 (de) 1994-01-31 1995-08-03 Henkel Kgaa Wirbelschicht-Oxidationsverfahren zur Herstellung von Polycarboxylaten auf Polysaccharid-Basis
DE4416438A1 (de) 1994-05-10 1995-11-16 Basf Ag Ein- oder mehrkernige Metall-Komplexe und ihre Verwendung als Bleich- und Oxidationskatalysatoren
DE4417734A1 (de) 1994-05-20 1995-11-23 Degussa Polycarboxylate
EP0693550B1 (fr) 1994-07-21 2004-06-16 Ciba SC Holding AG Composition de blanchiment de tissu
GB9419091D0 (en) 1994-09-22 1994-11-09 Cerestar Holding Bv Process for decreasing the build up of inorganic incrustations on textiles and detergent composition used in such process
DE4443177A1 (de) 1994-12-05 1996-06-13 Henkel Kgaa Aktivatormischungen für anorganische Perverbindungen
JPH08319496A (ja) * 1995-03-22 1996-12-03 New Japan Chem Co Ltd 洗浄剤組成物
DE19529905A1 (de) 1995-08-15 1997-02-20 Henkel Kgaa Aktivatorkomplexe für Persauerstoffverbindungen
DE19536082A1 (de) 1995-09-28 1997-04-03 Henkel Kgaa Aktivatorkomplexe für Persauerstoffverbindungen
US5795978A (en) * 1995-11-15 1998-08-18 Henkel Kommanditgesellschaft Auf Aktien Emulsifiers
US5981452A (en) * 1995-12-04 1999-11-09 Henkel Kommanditgesellschaft Auf Aktien Syndet soaps comprising alkyl and/or alkenyl oligoglycosides
DE19600018A1 (de) 1996-01-03 1997-07-10 Henkel Kgaa Waschmittel mit bestimmten oxidierten Oligosacchariden
DE19605688A1 (de) 1996-02-16 1997-08-21 Henkel Kgaa Übergangsmetallkomplexe als Aktivatoren für Persauerstoffverbindungen
DE19613103A1 (de) 1996-04-01 1997-10-02 Henkel Kgaa Übergangsmetallkomplex-haltige Systeme als Aktivatoren für Persauerstoffverbindungen
DE19620411A1 (de) 1996-04-01 1997-10-02 Henkel Kgaa Übergangsmetallamminkomplexe als Aktivatoren für Persauerstoffverbindungen
DE19616767A1 (de) 1996-04-26 1997-11-06 Henkel Kgaa Bleichaktivatoren für Wasch- und Reinigungsmittel
DE19616769A1 (de) 1996-04-26 1997-11-06 Henkel Kgaa Acylacetale als Bleichaktivatoren für Wasch- und Reinigungsmittel
DE19616770A1 (de) 1996-04-26 1997-11-06 Henkel Kgaa Acyllactame als Bleichaktivatoren für Wasch- und Reinigungsmittel
DE19616693A1 (de) 1996-04-26 1997-11-06 Henkel Kgaa Enolester als Bleichaktivatoren für Wasch- und Reinigungsmittel
DE19620267A1 (de) 1996-05-20 1997-11-27 Henkel Kgaa Katalytisch wirksame Aktivatorkomplexe mit N¶4¶-Liganden für Persauerstoffverbindungen
DE19708605A1 (de) * 1997-03-03 1998-09-10 Henkel Kgaa Geformte Syndetmasse
DE19709991C2 (de) 1997-03-11 1999-12-23 Rettenmaier & Soehne Gmbh & Co Waschmittelpreßling und Verfahren zu seiner Herstellung
DE19710153C1 (de) * 1997-03-12 1998-02-12 Henkel Kgaa Verfahren zur Herstellung neutraler Zuckertensidgranulate
DE19710254A1 (de) 1997-03-13 1998-09-17 Henkel Kgaa Wasch- oder reinigungsaktive Formkörper für den Gebrauch im Haushalt
DE19951598A1 (de) * 1999-10-27 2001-05-03 Cognis Deutschland Gmbh Verfahren zur Herstellugn von festen Zuckertensiden
DE10019405A1 (de) * 2000-04-19 2001-10-25 Cognis Deutschland Gmbh Verfahren zur Herstellung von Waschmittelgranulaten
DE10046251A1 (de) * 2000-09-19 2002-03-28 Cognis Deutschland Gmbh Wasch- und Reinigungsmittel auf Basis von Alkyl- und/oder Alkenyloligoglycosiden und Fettalkoholen

Also Published As

Publication number Publication date
ES2225371T3 (es) 2005-03-16
US6723135B2 (en) 2004-04-20
US20020058602A1 (en) 2002-05-16
DE50103521D1 (de) 2004-10-14
DE10046251A1 (de) 2002-03-28
EP1188816A1 (fr) 2002-03-20

Similar Documents

Publication Publication Date Title
EP1240290B1 (fr) Granulats de tensioactifs presentant une plus grande vitesse de dissolution
EP1240287B1 (fr) Pastilles de detergent
EP1106675B1 (fr) Utilisation de polyglycolethers de glycerides partiels
WO2001048133A1 (fr) Detergent solide
EP1274822B1 (fr) Detergents et nettoyants
WO2001057170A1 (fr) Melange tensioactif contenant des alcoxylats d'alcools gras a base de matieres vegetales
EP1186649A1 (fr) Tablettes détergentes
EP1188816B1 (fr) Produits de lavage et de nettoyage à base de mélanges d'oligoglycosides d'alkyle et/ou d'alcenyle et d'alcools gras
EP1188819A1 (fr) Tablettes détergentes
WO2001027238A1 (fr) Pastilles detergentes
WO2001048134A1 (fr) Corps moules d"agents de lavage et de nettoyage presentant des proprietes de decomposition ameliorees
EP1375633B1 (fr) Compositions détergentes contenant des polymères
EP1212401B1 (fr) Detergent en pastilles
EP1205536A2 (fr) Utilisation des mélanges tensioactifs
EP1228180A1 (fr) Granules d'antimousse
DE10002010A1 (de) Tablettensprengmittel
DE10002008A1 (de) Verfahren zur Herstellung von Tablettensprengmitteln
EP1212400B1 (fr) Detergent en pastilles
EP1207193A1 (fr) Utilisation d'un mélange d'agents tensioactif pour la préparation de compositions détergentes et de lavage
EP1249489A1 (fr) Corps moules d'agents de lavage et de nettoyage présentant des proprietés de décomposition améliorées
EP1090982A1 (fr) Article moulé ayant une solubilité dans l'eau améliorée
WO2001027237A1 (fr) Pastilles detergentes
WO2001027231A1 (fr) Detergents
EP1228186A1 (fr) Corps fa onnes presentant une solubilite dans l'eau amelioree
EP1314722A1 (fr) Esters de polyglycol d'acides sulphoniques aromatiques

Legal Events

Date Code Title Description
PUAI Public reference made under article 153(3) epc to a published international application that has entered the european phase

Free format text: ORIGINAL CODE: 0009012

17P Request for examination filed

Effective date: 20010908

AK Designated contracting states

Kind code of ref document: A1

Designated state(s): DE ES FR GB IT SE

Kind code of ref document: A1

Designated state(s): AT BE CH CY DE DK ES FI FR GB GR IE IT LI LU MC NL PT SE TR

AX Request for extension of the european patent

Free format text: AL;LT;LV;MK;RO;SI

RAP1 Party data changed (applicant data changed or rights of an application transferred)

Owner name: COGNIS DEUTSCHLAND GMBH & CO. KG

17Q First examination report despatched

Effective date: 20020805

AKX Designation fees paid

Free format text: DE ES FR GB IT SE

GRAP Despatch of communication of intention to grant a patent

Free format text: ORIGINAL CODE: EPIDOSNIGR1

GRAS Grant fee paid

Free format text: ORIGINAL CODE: EPIDOSNIGR3

GRAA (expected) grant

Free format text: ORIGINAL CODE: 0009210

AK Designated contracting states

Kind code of ref document: B1

Designated state(s): DE ES FR GB IT SE

REG Reference to a national code

Ref country code: GB

Ref legal event code: FG4D

Free format text: NOT ENGLISH

REG Reference to a national code

Ref country code: IE

Ref legal event code: FG4D

Free format text: GERMAN

REF Corresponds to:

Ref document number: 50103521

Country of ref document: DE

Date of ref document: 20041014

Kind code of ref document: P

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: SE

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20041208

GBT Gb: translation of ep patent filed (gb section 77(6)(a)/1977)

Effective date: 20050124

REG Reference to a national code

Ref country code: ES

Ref legal event code: FG2A

Ref document number: 2225371

Country of ref document: ES

Kind code of ref document: T3

RAP2 Party data changed (patent owner data changed or rights of a patent transferred)

Owner name: COGNIS DEUTSCHLAND GMBH & CO. KG

ET Fr: translation filed
PLBE No opposition filed within time limit

Free format text: ORIGINAL CODE: 0009261

STAA Information on the status of an ep patent application or granted ep patent

Free format text: STATUS: NO OPPOSITION FILED WITHIN TIME LIMIT

26N No opposition filed

Effective date: 20050609

REG Reference to a national code

Ref country code: FR

Ref legal event code: TP

REG Reference to a national code

Ref country code: GB

Ref legal event code: 732E

Free format text: REGISTERED BETWEEN 20090514 AND 20090520

REG Reference to a national code

Ref country code: FR

Ref legal event code: PLFP

Year of fee payment: 15

PGFP Annual fee paid to national office [announced via postgrant information from national office to epo]

Ref country code: GB

Payment date: 20150930

Year of fee payment: 15

PGFP Annual fee paid to national office [announced via postgrant information from national office to epo]

Ref country code: FR

Payment date: 20150928

Year of fee payment: 15

PGFP Annual fee paid to national office [announced via postgrant information from national office to epo]

Ref country code: IT

Payment date: 20150925

Year of fee payment: 15

Ref country code: DE

Payment date: 20151130

Year of fee payment: 15

PGFP Annual fee paid to national office [announced via postgrant information from national office to epo]

Ref country code: ES

Payment date: 20151027

Year of fee payment: 15

REG Reference to a national code

Ref country code: DE

Ref legal event code: R119

Ref document number: 50103521

Country of ref document: DE

GBPC Gb: european patent ceased through non-payment of renewal fee

Effective date: 20160908

REG Reference to a national code

Ref country code: FR

Ref legal event code: ST

Effective date: 20170531

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: GB

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20160908

Ref country code: FR

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20160930

Ref country code: DE

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20170401

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: IT

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20160908

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: ES

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20160909

REG Reference to a national code

Ref country code: ES

Ref legal event code: FD2A

Effective date: 20181126