EP1171926B1 - Fuel cell with cooling system based on direct injection of liquid water - Google Patents

Fuel cell with cooling system based on direct injection of liquid water Download PDF

Info

Publication number
EP1171926B1
EP1171926B1 EP00931060A EP00931060A EP1171926B1 EP 1171926 B1 EP1171926 B1 EP 1171926B1 EP 00931060 A EP00931060 A EP 00931060A EP 00931060 A EP00931060 A EP 00931060A EP 1171926 B1 EP1171926 B1 EP 1171926B1
Authority
EP
European Patent Office
Prior art keywords
stack
water
reactants
flow
cells
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
EP00931060A
Other languages
German (de)
English (en)
French (fr)
Other versions
EP1171926A1 (en
Inventor
Massimo Brambilla
Gabriele Mazzucchelli
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Nuvera Fuel Cells Europe SRL
Original Assignee
Nuvera Fuel Cells Europe SRL
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Nuvera Fuel Cells Europe SRL filed Critical Nuvera Fuel Cells Europe SRL
Publication of EP1171926A1 publication Critical patent/EP1171926A1/en
Application granted granted Critical
Publication of EP1171926B1 publication Critical patent/EP1171926B1/en
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Images

Classifications

    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00—Fuel cells; Manufacture thereof
    • H01M8/02—Details
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00—Fuel cells; Manufacture thereof
    • H01M8/04—Auxiliary arrangements, e.g. for control of pressure or for circulation of fluids
    • H01M8/04007—Auxiliary arrangements, e.g. for control of pressure or for circulation of fluids related to heat exchange
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00—Fuel cells; Manufacture thereof
    • H01M8/02—Details
    • H01M8/0202—Collectors; Separators, e.g. bipolar separators; Interconnectors
    • H01M8/0258—Collectors; Separators, e.g. bipolar separators; Interconnectors characterised by the configuration of channels, e.g. by the flow field of the reactant or coolant
    • H01M8/0263—Collectors; Separators, e.g. bipolar separators; Interconnectors characterised by the configuration of channels, e.g. by the flow field of the reactant or coolant having meandering or serpentine paths
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00—Fuel cells; Manufacture thereof
    • H01M8/02—Details
    • H01M8/0202—Collectors; Separators, e.g. bipolar separators; Interconnectors
    • H01M8/0267—Collectors; Separators, e.g. bipolar separators; Interconnectors having heating or cooling means, e.g. heaters or coolant flow channels
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00—Fuel cells; Manufacture thereof
    • H01M8/04—Auxiliary arrangements, e.g. for control of pressure or for circulation of fluids
    • H01M8/04082—Arrangements for control of reactant parameters, e.g. pressure or concentration
    • H01M8/04089—Arrangements for control of reactant parameters, e.g. pressure or concentration of gaseous reactants
    • H01M8/04119—Arrangements for control of reactant parameters, e.g. pressure or concentration of gaseous reactants with simultaneous supply or evacuation of electrolyte; Humidifying or dehumidifying
    • H01M8/04126—Humidifying
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00—Fuel cells; Manufacture thereof
    • H01M8/24—Grouping of fuel cells, e.g. stacking of fuel cells
    • H01M8/241—Grouping of fuel cells, e.g. stacking of fuel cells with solid or matrix-supported electrolytes
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00—Fuel cells; Manufacture thereof
    • H01M8/24—Grouping of fuel cells, e.g. stacking of fuel cells
    • H01M8/2457—Grouping of fuel cells, e.g. stacking of fuel cells with both reactants being gaseous or vaporised
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00—Fuel cells; Manufacture thereof
    • H01M8/24—Grouping of fuel cells, e.g. stacking of fuel cells
    • H01M8/2465—Details of groupings of fuel cells
    • H01M8/2483—Details of groupings of fuel cells characterised by internal manifolds
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00—Fuel cells; Manufacture thereof
    • H01M8/04—Auxiliary arrangements, e.g. for control of pressure or for circulation of fluids
    • H01M8/04007—Auxiliary arrangements, e.g. for control of pressure or for circulation of fluids related to heat exchange
    • H01M8/04029—Heat exchange using liquids
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00—Fuel cells; Manufacture thereof
    • H01M8/04—Auxiliary arrangements, e.g. for control of pressure or for circulation of fluids
    • H01M8/04082—Arrangements for control of reactant parameters, e.g. pressure or concentration
    • H01M8/04089—Arrangements for control of reactant parameters, e.g. pressure or concentration of gaseous reactants
    • H01M8/04119—Arrangements for control of reactant parameters, e.g. pressure or concentration of gaseous reactants with simultaneous supply or evacuation of electrolyte; Humidifying or dehumidifying
    • H01M8/04126—Humidifying
    • H01M8/04134—Humidifying by coolants
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/30—Hydrogen technology
    • Y02E60/50—Fuel cells

Definitions

  • the present invention relates to a fuel cell, and more precisely a fuel cell using a polymeric membrane as the electrolyte.
  • Fuel cells are electrochemical generators of electric energy in the form of direct current; in other words, they convert the free energy of reaction of a fuel (for example a gaseous mixture containing hydrogen, or a light alcohol such as methanol or ethanol) with an oxidant (for example air or oxygen) without its complete degradation to thermal energy, and therefore without being submitted to the limitation of the Camot cycle.
  • a fuel for example a gaseous mixture containing hydrogen, or a light alcohol such as methanol or ethanol
  • an oxidant for example air or oxygen
  • the fuel is oxidised at the anode of the cell, with the concurrent release of electrons and H + ions, while the oxidant is reduced at the cathode, where H + ions are consumed;
  • the two poles of the generator must be separated by a suitable electrolyte, allowing a continuous flow of H + ions from the anode to the cathode, at the same time hindering the transfer of electrons from one pole to the other, thereby maximising the electrical potential difference between the two electrodes.
  • the fuel cells are considered as an excellent alternative to the traditional systems of electric generation; especially in view of their extremely favourable environmental impact (absence of polluting emissions and noise, formation of water as the only by-product), they are used both in the field of stationary power generation of various sizes (electrical power stations, back-up power generators, etc.) as well as in the field of mobile applications (electric vehicle applications, generation of automotive energy or auxiliary energy for space, submarine and naval applications).
  • the polymeric membrane fuel cells offer, compared with other fuel cells, further advantages, due to their fast start-up and quick achievement of the optimum operation conditions, the high power density, the intrinsic reliability connected both to the lack of moving parts and to the absence of corrosion phenomena and severe thermal cycles; in fact, among all the fuel cells of the prior art, the polymer electrolyte fuel cells exhibit the overall lowest operating temperature (usually, 70-100°C).
  • the polymeric electrolyte used for this purpose is an ion-exchange membrane, and more precisely a cation-exchange membrane, that is a chemically inert polymer, partially functionalised with groups capable of undergoing acid-base hydrolysis leading to a separation of electric charge; said hydrolysis consists more precisely in the release of positive ions (cations) and in the formation of fixed negative charges on the polymer constituting the membrane.
  • Porous electrodes are applied on the surface of the membrane, which allow for the reactants to flow therethrough up to the membrane interface.
  • a catalyst is applied on said interface on the electrode and/or on the membrane side, such as for example platinum black, which favours the corresponding half-reaction of fuel oxidation or oxidant reduction.
  • This arrangement provides also for the continuous flow of cations when a potential gradient is established between the two faces of the membrane and the external electric circuit is concurrently closed; being the H + ion the transported cation in this case, as previously mentioned, the potential difference generated upon feeding a species with a lower electrochemical potential at the anode, and a species with a higher electrochemical potential at the cathode, causes protonic conduction across electron flow (i.e. electric current) across the external circuit, as soon as the latter is closed.
  • the protonic conduction is an essential condition for the operation of a fuel cell and is one of the decisive parameters to assess its efficiency.
  • An insufficient protonic conduction causes a remarkable drop in the potential difference at the poles of the cell (cell voltage drop) once the electric circuit is closed on the external resistive load which exploits the produced electric output. This, in turn, causes an increased degradation of the energy of reaction to thermal energy and the consequent decrease of the fuel conversion efficiency.
  • Operation at high current density in fact involves a decrease in the investment costs for a given power output, but also a decrease in the energy efficiency and the generation of a higher amount of heat.
  • the large amount of heat generated in a fuel cell operating at a current density of practical use (for example between 150 and 1500 mA/cm 2 ) must be efficiently removed to permit the thermal regulation of the system, not only in view of the limited thermal stability of the ion-exchange membrane, usually unfit for operation above 100°C, but also to reduce as much as possible the evaporation of the produced water and its consequent removal by the flow of inerts and unconverted reactants from the cell.
  • This circuit generally provides for pre-humidifying the reactants at the inlet of the anode and cathode compartments of the fuel cells, for example by bubbling in liquid water or by diffusion of water vapour though suitable membranes in auxiliary cells.
  • this second circuit involves an evident increase in weight, volumes and investment costs; moreover, the quantity of water to be fed to the system must be strictly controlled as an excess of liquid in the cell compartments would lead to the dramatic consequence of blocking the access of the gaseous reactants to the surface of the electrodes.
  • the only possibility to achieve a calibration, albeit indirect, of the water supplied by the above system is acting on the temperature of the water itself and thus on its vapour pressure. This in turn brings to the need of thermostating the humidification system of the fuel cell stacks, further complicating the construction design.
  • the time of permanence of water in the cell is too short to ensure at the same time the humidification of the membrane and the cooling of the stack without recurring to auxiliary circuits, especially at a high current density and with stacks comprising a high number of cells.
  • the humidification of the reactants or the addition of atomised water prior to sending said reactants to the inlet manifold may cause some water condensation or droplet formation therein, having the consequence of feeding an excess amount of water to some cells of the stack (typically those closer to the reactants inlet) and an insufficient amount to some other cells (typically those farther from the reactants inlet).
  • the present invention consists in a fuel cell stack comprising a reticulated electrically and thermally conductive material interposed between the bipolar plate and the electrodic surface as described for example in U.S. Patent No. 5,482,792, wherein humidification of the reactants and thermal control are obtained by a single-circuit direct injection of a suitable flow of water which partially evaporates inside the reticulated material exploiting its high surface and its thermal conductivity which allows an efficient extraction of heat from the electrodes.
  • the injection point of the water in the gaseous flow is positioned downstream the reactant inlet manifold.
  • said injection point is positioned in correspondence of the periphery of the reticulated material, in areas physically separated from the ones where the reactants are fed.
  • water is injected in correspondence of depressions formed inside the reticulated material.
  • water is injected in correspondence of serpentine-shaped depressions provided inside the reticulated material and running along the whole surface of the same.
  • water is injected in correspondence of offset double comb-shaped depressions provided inside the reticulated material.
  • each elementary cell (1) which represents the repetitive unit of the modular assembly of the fitter-press arrangement, comprises, proceeding from the inside to the outside, an ion-exchange membrane (2), a pair of porous electrodes (3), a pair of catalytic layers (4) formed at the interface between the membrane (2) and each of the electrodes (3), a pair of electrically conductive reticulated elements (5), a pair of gaskets (6) for the peripheral sealing, a pair of bipolar plates (7) which delimit the boundary of the elementary cell (1).
  • the reticulated elements (5) have a minimum porosity of 50%, and perform the functions of electrically connecting the bipolar plates (7) to the electrodes (3), and distributing the gaseous reactants and the humidification water, finely subdividing the latter through all the thickness of the reticulated element (5) and thus favouring the evaporation inside the whole volume of the chamber delimited by the bipolar plate (7) and the electrode (3).
  • Suitable apertures on the peripheral area of the bipolar plates (7) and of the gaskets (6) form, upon juxtaposition of the above mentioned components, the two upper manifolds (8), only one of which is shown in the figure, which may be used to feed the reactants, and the two lower manifolds (9), which may be used for discharging the produced water, the gaseous inerts and the non-converted portion of the reactants, only one of which is shown in the figure.
  • the lower manifolds (9) may be used as feeding ducts and the upper manifolds (8) as discharge ducts.
  • each elementary cell (1') which constitutes the repetitive unit of the modular assembly of the filter-press arrangement, comprises, proceeding from the inside to the outside, an ion-exchange membrane (2'), a pair of porous electrodes (3').
  • bipolar plates (7') which delimit the boundary of the elementary cell (1').
  • the bipolar plates (7') have a ribbed profile (11). the projecting part of which ensures the electrical continuity through the stack, while the depressed part allows the circulation of gases and water.
  • Suitable apertures in the peripheral area of the bipolar plates (7') form, upon juxtaposition of the above mentioned components, the two upper manifolds (8'), only one of which is shown in the figure, which may be used to feed the reactants, and the two lower manifolds (9'), which may be used for discharging the produced water, the gaseous inerts and the non-converted portion of the reactants, only one of which is shown in the figure. Also in this case it is possible to invert the function of the lower and upper manifolds.
  • gaskets (6) which comprise an upper hole (12), which forms the upper manifold (8), by juxtaposition in a filter-press arrangement, a lower note (13), which forms the lower manifold (9) by juxtaposition in a filter-press arrangement, the housing (14) for the reticulated element (5) and, optionally, one or more channels for the injection of water (15).
  • reticulated element (5) made of a flattened expanded sheet having a rhomboidal mesh is shown; in fig. 7B, a planar fine net, having a square mesh is shown.
  • reticulated elements (5) are shown, made of a deformable metallic material, such as a metal foam; in the embodiments of figs. 9 and 10, depressions (16) acting as preferential channels for injecting water, are formed inside said metallic material, for example by cold-pressing.
  • the stacks were connected, through suitable fittings mounted on one of the end plates (10), to the gaseous reactants supplies and to an external circuit where demineralized water, thermostated at the desired temperature by means of a heat exchanger, was circulated.
  • the stacks were fed with a mixture containing 70% of hydrogen at the negative pole (anode), and with air at the positive pole (cathode), by means of the upper manifolds (8), obtained by the juxtaposition in a filter-press configuration of the upper holes (12) and the corresponding apertures in the bipolar plates (7).
  • the same manifolds (8) were fed with a stream of demineralized water from the corresponding circuit, the flow-rate of which was regulated as needed, according to the dynamic responses of the system.
  • the stacks were not provided with auxiliary cooling in addition to the one supplied by the evaporation of the water injected into the manifolds (8).
  • the stacks were operated for 12 hours at a current density of 300 mA/cm 2 , regulating the temperature of the cells at 70°C, and monitoring the voltage of the single cells.
  • the water flow-rate was manually regulated so as to maximise the voltage of the single cells.
  • a voltage comprised between 715 and 745 mV was detected on each cell of both stacks.
  • the cells having the lowest voltage values were statistically distributed farther away from the end plate connected to the reactants and water inlets (tail cells); after the first hour of operation, the voltage of the single cells tended to remain generally constant.
  • the resistive load applied to the end plates (10) was then varied in order to draw a current density of 600 mA/cm 2 from to the two stacks; the 15 cell stack maintained a stable operation condition, with single cell voltages comprised between 600 and 670 mV, the lowest values being statistically distributed among the tail cells; the 30 cell stack was shut-down after about one hour, as the voltages exhibited by the end cells were continuously decreasing, most probably as a consequence of local overheating.
  • a 15 fuel cell stack was made according to the prior art teachings, following the scheme of fig. 2.
  • the stack was equipped with the following components:
  • the stack was connected, by suitable fittings provided on one of the end plates (10'), to the feeding circuit of the gaseous reactants and to an external circuit where demineralized water, thermostated at the desired temperature by means of a heat exchanger was circulated.
  • the stacks were fed with a mixture containing 70% of hydrogen at the negative pole (anode), and with air at the positive pole (cathode), through the upper manifolds (8'); a flow of demineralized water was fed from the corresponding circuit to the same manifolds (8').
  • the stacks were not equipped with auxiliary cooling in addition to the one provided by the evaporation of the water injected into the manifolds (8').
  • Example 1 The two stacks of Example 1 were fed with the gaseous reactants and with water through the lower manifolds (9), using the upper manifolds (8) for discharging. Under these conditions, it was possible to operate also the 30 cell stack at 600 mA/cm 2 , even though the voltages of the five tail cells remained below 600 mV. At the same current density, the voltages of the 15 cell stack were distributed in a range comprised between 650 and 670 mV; although the maximum values were close to those relative to the previous test, where injection was carried out through the upper manifolds, the distribution of the cell voltage values resulted much more homogeneous.
  • the explanation resides in the fact that when a plurality of cells are fed in parallel through a manifold positioned at a higher level, it is possible that part of the water be collected on the bottom of the manifold itself, subsequently falling through the inlet of the group of cells closer to the water injection point. In the case of injection from the bottom, water does not fall into the cells being instead suctioned by the inlet gas, providing a more uniform flow inside each single cell.
  • Example 1 and 2 were repeated feeding pure hydrogen as the fuel, closing the outlet manifold on the anode side and injecting water only to the air inlet manifold. In both cases it has been observed that the performances of the stacks were substantially the same as in the previous cases, the detected slight increases in the cells voltages being due to the increase of the fuel molar fraction. Furthermore, it has been observed that in the case of total consumption of a pure fuel at the anode (dead-end operation), it is sufficient to humidify only the flow of the oxidant. In this case, the upstream atomisation of water with the ultrasonic aerosol generator did not produce any positive effect.
  • the 30 cell stack of the previous examples was rotated by 35° with respect to its main axis, so that for each of the gaskets (6) fed with air, the lower hole (13) was placed at a lower level with respect to its initial position, and consequently the whole lower manifold (9) on the air side was at a lower level with respect to its initial level.
  • the stack was then fed with air from the corresponding lower manifold (9), where water was injected as in the previous examples. Pure hydrogen was fed from the corresponding lower manifold (9) to total consumption, without any humidification and closing the relevant upper manifold (8), according to a dead-end mode operation.
  • a 45 fuel cell stack was manufactured according to the prior art teachings, following the scheme of fig. 1, equipped with the following components:
  • the stack was connected, through suitable fittings provided on one of the end plates (10), to the feeding circuit of the gaseous reactants and to an external circuit where demineralized water, thermostated at the desired temperature by means of a heat exchanger, was circulated.
  • the stacks were fed with pure hydrogen at the negative pole (anode), and with air at the positive pole (cathode), by means of the lower manifolds (9) obtained by juxtaposing the lower holes (13) and the corresponding holes, in the bipolar plates (7) in a filter-press configuration.
  • the stack was not equipped with auxiliary cooling in addition to the one provided by the evaporation of the water fed to the injection channels (15).
  • the stack was operated for 12 hours at a current density of 700 mA/cm 2 , regulating the cell temperature at 75°C and monitoring the voltages of the single cells.
  • the water flow rate was manually regulated up to maximising the single cell voltages.
  • all the cells of the stack displayed a voltage comprised between 680 and 700 mV, which remained stable with time.
  • This test permitted to verify that, compared to the type of gasket used in the previous examples, which determined the mixing of gas and water in the inlet manifold, the use of the gasket shown in fig. 4, wherein the mixing of the two fluids occurs in a smaller duct, downstream the inlet manifold, is more advantageous.
  • a 45 fuel cell stack was assembled, similar to the one of the previous example with the only exception of the gaskets which corresponded to those of fig. 5.
  • This type of design provides a separate feeding, in mutually parallel directions, of the gas and water streams, which are mixed only after the insertion into the reticulated element (5), ensuring an even more uniform distribution of water inside the single cells.
  • This stack operated at 700 mA/cm 2 under the same operating conditions of Example 5, displayed cell voltage values comprised between 700 and 715 mV.
  • a 45 fuel cell stack was assembled, similar to the one of the previous example with the only exception of the gaskets, which corresponded to those of fig. 6, and the reticulated element (5), which was made of a nickel foam similar to that of Example 1.
  • the stack was connected so as to feed the reactants from the upper manifolds (8) and to discharge the same from the lower manifolds (9).
  • the injected gas and water streams besides being separated until after insertion into the reticulated element (5), mix in mutually orthogonal directions.
  • the water flow was split so as to enter to a large extent into the channels (15), and to a minor extent into the upper manifolds (8), used for feeding the cells.
  • the portion of water injected into the channels (15) was set around 90% of the total, and in any case not below 80%.
  • This stack operated at 700 mA/cm 2 under the same operating conditions of the Examples 5 and 6, displayed cell voltage values comprised between 710 and 730 mV.
  • a 45 fuel cell stack was assembled, similar to the one of Example 6 with the only exception of the reticulated element (5), which was made of a nickel foam as shown in fig. 9.
  • the deformability of the metal foam was exploited to produce two small channels or depressions (16) for the preferential distribution of water in a substantially parallel direction with respect to the gas flow; said channels were in the form of serpentines which crossed the whole surface of the foam.
  • a 45 fuel cell stack was assembled, similar to the one of Example 7 with the only exception of the gaskets (6), which corresponded to those of fig. 6 and the reticulated element (5), which was made of the nickel foam illustrated in fig. 10. Also in this case, the permanent deformability of the metal foam was exploited to produce two small channels for the preferential distribution of water; in this case, however, an offset double comb-shaped geometry was chosen to create a series of parallel ducts which were fed with water in a substantially orthogonal direction with respect to the direction of the gas flow.
  • This stack operated at 700 mA/cm 2 under the same operating conditions of Examples 5, 6 and 7, displayed cell voltage values comprised between 730 and 740 mV.

Landscapes

  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Manufacturing & Machinery (AREA)
  • Sustainable Development (AREA)
  • Sustainable Energy (AREA)
  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Electrochemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Fuel Cell (AREA)
  • Electric Propulsion And Braking For Vehicles (AREA)
  • Thermotherapy And Cooling Therapy Devices (AREA)
EP00931060A 1999-04-21 2000-04-10 Fuel cell with cooling system based on direct injection of liquid water Expired - Lifetime EP1171926B1 (en)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
ITMI990829 1999-04-21
IT1999MI000829A IT1312198B1 (it) 1999-04-21 1999-04-21 Cella a combustibile raffreddata mediante iniezione diretta di acqualiquida
PCT/EP2000/003171 WO2000063992A1 (en) 1999-04-21 2000-04-10 Fuel cell with cooling system based on direct injection of liquid water

Publications (2)

Publication Number Publication Date
EP1171926A1 EP1171926A1 (en) 2002-01-16
EP1171926B1 true EP1171926B1 (en) 2003-12-17

Family

ID=11382779

Family Applications (1)

Application Number Title Priority Date Filing Date
EP00931060A Expired - Lifetime EP1171926B1 (en) 1999-04-21 2000-04-10 Fuel cell with cooling system based on direct injection of liquid water

Country Status (15)

Country Link
US (1) US6835477B1 (zh)
EP (1) EP1171926B1 (zh)
JP (1) JP4954375B2 (zh)
KR (1) KR100778648B1 (zh)
CN (1) CN1185741C (zh)
AT (1) ATE256919T1 (zh)
AU (1) AU756163B2 (zh)
BR (1) BR0009888A (zh)
CA (1) CA2368895C (zh)
DE (1) DE60007299T2 (zh)
DK (1) DK1171926T3 (zh)
ES (1) ES2213016T3 (zh)
IT (1) IT1312198B1 (zh)
TW (1) TW499779B (zh)
WO (1) WO2000063992A1 (zh)

Families Citing this family (40)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
IT1314256B1 (it) 1999-12-03 2002-12-06 Nora Fuel Cells S P A De Batteria di celle a combustibile a membrana polimerica.
US6916564B2 (en) 2000-05-31 2005-07-12 Nuvera Fuel Cells, Inc. High-efficiency fuel cell power system with power generating expander
CA2440884C (en) * 2001-03-16 2012-05-22 Alza Corporation Transdermal patch for administering fentanyl
DE10139047A1 (de) * 2001-08-08 2003-02-20 Daimler Chrysler Ag Verfahren zur Inbetriebnahme einer Polymer-Elektrolyt-Membran-Brennstoffzelle
CA2469401A1 (en) * 2001-12-05 2003-06-19 Lawrence G. Clawson High efficiency otto cycle engine with power generating expander
DE10217712A1 (de) * 2002-04-20 2003-11-13 Daimler Chrysler Ag Elektrodenplatte mit Befeuchtungsbereich
ITMI20021338A1 (it) 2002-06-17 2003-12-17 Nuvera Fuel Cells Europ Srl Generatore elettrochimico a membrana con iniezione diretta di acqua liquida nei agenti gassosi
ITMI20021859A1 (it) * 2002-08-28 2004-02-29 Nuvera Fuel Cells Europ Srl Generatore elettrochimico a membrana con migliorato
SE523665C2 (sv) * 2002-09-20 2004-05-11 Volvo Technology Corp Bränslecell och bränslecellsstack
ITMI20022637A1 (it) * 2002-12-16 2004-06-17 Nuvera Fuel Cells Europ Srl Generatore elettrochimico e metodo per il suo utilizzo
ITMI20031881A1 (it) * 2003-10-01 2005-04-02 Nuvera Fuel Cells Europ Srl Separatore bipolare per batteria di celle a combustibile.
JP4887600B2 (ja) 2003-11-10 2012-02-29 トヨタ自動車株式会社 燃料電池、その分解方法およびそのセパレータ
ITMI20032531A1 (it) * 2003-12-19 2005-06-20 Nuvera Fuel Cells Europ Srl Cella a combustione a membrana alimentata in
GB2409763B (en) * 2003-12-31 2007-01-17 Intelligent Energy Ltd Water management in fuel cells
JP2005209470A (ja) * 2004-01-22 2005-08-04 Equos Research Co Ltd 燃料電池
JP4218569B2 (ja) * 2004-03-30 2009-02-04 株式会社エクォス・リサーチ セパレータ及びそれを用いた燃料電池
EP1786725A2 (en) 2004-06-11 2007-05-23 Nuvera Fuel Cells, Inc. Fuel fired hydrogen generator
JP4992188B2 (ja) * 2005-03-11 2012-08-08 株式会社エクォス・リサーチ セパレータユニット及び燃料電池スタック
JP4887639B2 (ja) * 2005-03-11 2012-02-29 株式会社エクォス・リサーチ セパレータユニット及び燃料電池スタック
JP4506552B2 (ja) * 2005-05-12 2010-07-21 株式会社エクォス・リサーチ 燃料電池
IL173539A0 (en) * 2006-02-05 2006-07-05 Rami Noach Flow distributor plate
CA2577766A1 (en) * 2006-02-17 2007-08-17 Nuvera Fuel Cells, Inc. Method of cleaning fuel cell
US7914944B2 (en) * 2006-12-07 2011-03-29 Canon Kabushiki Kaisha Atmosphere open type fuel cell
JP5361127B2 (ja) * 2006-12-07 2013-12-04 キヤノン株式会社 燃料電池
DE102007016905A1 (de) * 2007-04-02 2008-10-09 Staxera Gmbh Interkonnektoranordnung und Verfahren zur Herstellung einer Kontaktanordnung für einen Brennstoffzellenstapel
WO2010047693A1 (en) * 2008-10-22 2010-04-29 Utc Fuel Cells, Llc Porous flow field plate for moisture distribution control in a fuel cell
WO2010061703A1 (ja) 2008-11-28 2010-06-03 日産自動車株式会社 固体高分子形燃料電池
US8889314B2 (en) * 2009-01-13 2014-11-18 GM Global Technology Operations LLC Bipolar plate for a fuel cell stack
JP5409142B2 (ja) * 2009-06-30 2014-02-05 株式会社日立製作所 燃料電池
CN102308419B (zh) * 2009-09-01 2014-09-17 松下电器产业株式会社 膜电极接合体及其制造方法、以及燃料电池
CN102969519B (zh) * 2011-09-01 2016-06-08 上海恒劲动力科技有限公司 一种燃料电池加湿器
AU2015259213A1 (en) * 2014-05-15 2016-11-24 Nuvera Fuel Cells, LLC Flow fields for use with an electrochemical cell
US10158128B2 (en) * 2017-03-07 2018-12-18 GM Global Technology Operations LLC Fuel cell stack break-in procedures and break-in conditioning systems
DE102018100765A1 (de) * 2018-01-15 2019-07-18 Atlas Elektronik Gmbh Unterwasservorrichtung zum Einsatz unter Wasser mit einer Energieerzeugungseinrichtung
US11211619B2 (en) 2019-10-11 2021-12-28 GM Global Technology Operations LLC Fuel cell architectures, aftertreatment systems, and control logic for exhaust water extraction
DE102019218425A1 (de) * 2019-11-28 2021-06-02 Robert Bosch Gmbh Bipolarplatte
US11728496B2 (en) 2021-03-09 2023-08-15 GM Global Technology Operations LLC Propulsion battery packs with integrated fuel tank mounting systems
DE102021112492A1 (de) 2021-05-12 2022-11-17 MTU Aero Engines AG Luftbefeuchtungsvorrichtung, Verfahren zum Betreiben einer Luftbefeuchtungsvorrichtung und System, aufweisend zumindest eine Luftbefeuchtungsvorrichtung
US11735751B1 (en) 2022-03-21 2023-08-22 GM Global Technology Operations LLC Intelligent fuel cell systems and control logic for smart use of anode header drain valves for FCS bleed and drainage
US11713734B1 (en) * 2023-02-01 2023-08-01 GM Global Technology Operations LLC Thermally conditioned noise / vibration attenuating fuel rail chamber

Family Cites Families (14)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4795683A (en) * 1987-07-23 1989-01-03 United Technologies Corporation High power density evaporatively cooled ion exchange membrane fuel cell
US4769297A (en) * 1987-11-16 1988-09-06 International Fuel Cells Corporation Solid polymer electrolyte fuel cell stack water management system
US4824741A (en) 1988-02-12 1989-04-25 International Fuel Cells Corporation Solid polymer electrolyte fuel cell system with porous plate evaporative cooling
US5635039A (en) * 1993-07-13 1997-06-03 Lynntech, Inc. Membrane with internal passages to permit fluid flow and an electrochemical cell containing the same
JP3203150B2 (ja) * 1995-05-18 2001-08-27 三洋電機株式会社 固体高分子型燃料電池及び固体高分子型燃料電池システム
IT1284072B1 (it) * 1996-06-26 1998-05-08 De Nora Spa Cella elettrochimica a membrana provvista di elettrodi a diffusione gassosa contattati da portacorrente metallici lisci e porosi a
US6146780A (en) * 1997-01-24 2000-11-14 Lynntech, Inc. Bipolar separator plates for electrochemical cell stacks
US5798888A (en) 1997-04-09 1998-08-25 Iomega Corporation Disk hub for a removable cartridge and spindle motor for using same
JP2001519080A (ja) * 1997-04-10 2001-10-16 マグネート−モートア、ゲゼルシャフト、フュール、マグネートモートリシェ、テヒニク、ミット、ベシュレンクテル、ハフツング ポリマー電解質燃料電池の冷却および増湿
WO1999060640A2 (de) * 1998-05-14 1999-11-25 Siemens Aktiengesellschaft Pem-brennstoffzelle und verfahren zum betreiben eines pem- brennstoffzellensystems mit flüssiger befeuchtung und/oder kühlung
US6015633A (en) 1998-10-07 2000-01-18 Plug Power, L.L.C. Fluid flow plate for water management, method for fabricating same, and fuel cell employing same
WO2000074165A1 (fr) * 1999-05-28 2000-12-07 Matsushita Electric Industrial Co., Ltd. Pile a combustible a electrolyte polymere et utilisation de celle-ci
CA2401915C (en) * 2001-09-11 2007-01-09 Matsushita Electric Industrial Co., Ltd. Polymer elecrolyte fuel cell
EP1291946A3 (en) * 2001-09-11 2006-03-08 Matsushita Electric Industrial Co., Ltd. Polymer electrolyte fuel cell and conductive separator plate thereof

Also Published As

Publication number Publication date
IT1312198B1 (it) 2002-04-09
JP2002542591A (ja) 2002-12-10
CA2368895C (en) 2010-06-01
ES2213016T3 (es) 2004-08-16
JP4954375B2 (ja) 2012-06-13
AU4912900A (en) 2000-11-02
ATE256919T1 (de) 2004-01-15
CN1185741C (zh) 2005-01-19
EP1171926A1 (en) 2002-01-16
AU756163B2 (en) 2003-01-09
KR20020020881A (ko) 2002-03-16
WO2000063992A1 (en) 2000-10-26
KR100778648B1 (ko) 2007-11-27
CA2368895A1 (en) 2000-10-26
DK1171926T3 (da) 2004-04-19
ITMI990829A1 (it) 2000-10-21
CN1347575A (zh) 2002-05-01
DE60007299D1 (de) 2004-01-29
US6835477B1 (en) 2004-12-28
BR0009888A (pt) 2002-01-22
TW499779B (en) 2002-08-21
DE60007299T2 (de) 2004-09-16

Similar Documents

Publication Publication Date Title
EP1171926B1 (en) Fuel cell with cooling system based on direct injection of liquid water
EP1181730B1 (en) Humidification device for polymeric membrane fuel cells
US7465515B2 (en) Solid polymer electrolyte fuel cell assembly, fuel cell stack, and method of operating cell assembly
US7749634B2 (en) Flow control for multiple stacks
US6936362B2 (en) Variable pressure drop stack
US6632556B2 (en) Manifold assembly for a fuel cell power plant
US20190260062A1 (en) High-voltage fuel-cell stack
WO2010080080A1 (en) Multiple transition flow field and method
US8012639B2 (en) Fuel cell stack
KR101119479B1 (ko) 연료 전지 스택용 양극성 분리기
US20030054223A1 (en) Fuel cell stack and a method of supplying reactant gases to the fuel cell stack
KR20050085680A (ko) 전기화학 발전기 및 이의 사용방법
KR100627749B1 (ko) 연료 전지
US20040038103A1 (en) Solid polymer electrolyte fuel cell assembly
KR101118666B1 (ko) 세퍼레이터 및 이를 이용한 연료 전지 스택
US9196913B2 (en) Multiple transition flow field and method
US20030170528A1 (en) Moldable separator plate for electrochemical devices and cells
CN111971831A (zh) 电化学电池堆的阴极流场分布
CN201122629Y (zh) 一种质子交换膜燃料电池
KR20060105861A (ko) 연료전지용 혼합탱크 및 이를 구비한 연료전지 시스템

Legal Events

Date Code Title Description
PUAI Public reference made under article 153(3) epc to a published international application that has entered the european phase

Free format text: ORIGINAL CODE: 0009012

17P Request for examination filed

Effective date: 20011018

AK Designated contracting states

Kind code of ref document: A1

Designated state(s): AT BE CH CY DE DK ES FI FR GB GR IE IT LI LU MC NL PT SE

GRAH Despatch of communication of intention to grant a patent

Free format text: ORIGINAL CODE: EPIDOS IGRA

GRAS Grant fee paid

Free format text: ORIGINAL CODE: EPIDOSNIGR3

GRAA (expected) grant

Free format text: ORIGINAL CODE: 0009210

AK Designated contracting states

Kind code of ref document: B1

Designated state(s): AT BE CH CY DE DK ES FI FR GB GR IE IT LI LU MC NL PT SE

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: FI

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20031217

Ref country code: CY

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20031217

REG Reference to a national code

Ref country code: GB

Ref legal event code: FG4D

REG Reference to a national code

Ref country code: CH

Ref legal event code: EP

REG Reference to a national code

Ref country code: IE

Ref legal event code: FG4D

REF Corresponds to:

Ref document number: 60007299

Country of ref document: DE

Date of ref document: 20040129

Kind code of ref document: P

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: SE

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20040317

Ref country code: GR

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20040317

REG Reference to a national code

Ref country code: CH

Ref legal event code: NV

Representative=s name: FIAMMENGHI-FIAMMENGHI

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: LU

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20040410

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: IE

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20040412

REG Reference to a national code

Ref country code: DK

Ref legal event code: T3

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: MC

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20040430

REG Reference to a national code

Ref country code: ES

Ref legal event code: FG2A

Ref document number: 2213016

Country of ref document: ES

Kind code of ref document: T3

ET Fr: translation filed
PLBE No opposition filed within time limit

Free format text: ORIGINAL CODE: 0009261

STAA Information on the status of an ep patent application or granted ep patent

Free format text: STATUS: NO OPPOSITION FILED WITHIN TIME LIMIT

26N No opposition filed

Effective date: 20040920

REG Reference to a national code

Ref country code: IE

Ref legal event code: MM4A

PGFP Annual fee paid to national office [announced via postgrant information from national office to epo]

Ref country code: DK

Payment date: 20070412

Year of fee payment: 8

PGFP Annual fee paid to national office [announced via postgrant information from national office to epo]

Ref country code: AT

Payment date: 20070413

Year of fee payment: 8

Ref country code: CH

Payment date: 20070413

Year of fee payment: 8

Ref country code: NL

Payment date: 20070413

Year of fee payment: 8

PGFP Annual fee paid to national office [announced via postgrant information from national office to epo]

Ref country code: BE

Payment date: 20070502

Year of fee payment: 8

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: PT

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20040517

BERE Be: lapsed

Owner name: *NUVERA FUEL CELLS EUROPE S.R.L.

Effective date: 20080430

REG Reference to a national code

Ref country code: CH

Ref legal event code: PL

REG Reference to a national code

Ref country code: DK

Ref legal event code: EBP

NLV4 Nl: lapsed or anulled due to non-payment of the annual fee

Effective date: 20081101

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: LI

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20080430

Ref country code: CH

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20080430

Ref country code: NL

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20081101

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: AT

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20080410

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: BE

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20080430

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: DK

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20080430

REG Reference to a national code

Ref country code: FR

Ref legal event code: PLFP

Year of fee payment: 17

REG Reference to a national code

Ref country code: FR

Ref legal event code: PLFP

Year of fee payment: 18

REG Reference to a national code

Ref country code: FR

Ref legal event code: PLFP

Year of fee payment: 19

PGFP Annual fee paid to national office [announced via postgrant information from national office to epo]

Ref country code: IT

Payment date: 20190225

Year of fee payment: 20

Ref country code: FR

Payment date: 20190307

Year of fee payment: 20

Ref country code: GB

Payment date: 20190307

Year of fee payment: 20

PGFP Annual fee paid to national office [announced via postgrant information from national office to epo]

Ref country code: DE

Payment date: 20190312

Year of fee payment: 20

Ref country code: ES

Payment date: 20190524

Year of fee payment: 20

REG Reference to a national code

Ref country code: DE

Ref legal event code: R071

Ref document number: 60007299

Country of ref document: DE

REG Reference to a national code

Ref country code: GB

Ref legal event code: PE20

Expiry date: 20200409

REG Reference to a national code

Ref country code: ES

Ref legal event code: FD2A

Effective date: 20200721

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: GB

Free format text: LAPSE BECAUSE OF EXPIRATION OF PROTECTION

Effective date: 20200409

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: ES

Free format text: LAPSE BECAUSE OF EXPIRATION OF PROTECTION

Effective date: 20200411