EP1146108A3 - Copolymermischungen und ihre Verwendung als Additiv zur Verbesserung der Kaltfliesseigenschaften von Mitteldestillaten - Google Patents

Copolymermischungen und ihre Verwendung als Additiv zur Verbesserung der Kaltfliesseigenschaften von Mitteldestillaten Download PDF

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EP1146108A3
EP1146108A3 EP01104847A EP01104847A EP1146108A3 EP 1146108 A3 EP1146108 A3 EP 1146108A3 EP 01104847 A EP01104847 A EP 01104847A EP 01104847 A EP01104847 A EP 01104847A EP 1146108 A3 EP1146108 A3 EP 1146108A3
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EP1146108A2 (de
EP1146108B1 (de
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Matthias Dr. Krull
Thomas Dr. Volkmer
Werner Dr. Reimann
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Clariant Produkte Deutschland GmbH
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    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00—Liquid carbonaceous fuels
    • C10L1/10—Liquid carbonaceous fuels containing additives
    • C10L1/14—Organic compounds
    • C10L1/18—Organic compounds containing oxygen
    • C10L1/192—Macromolecular compounds
    • C10L1/195—Macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00—Liquid carbonaceous fuels
    • C10L1/10—Liquid carbonaceous fuels containing additives
    • C10L1/14—Organic compounds
    • C10L1/146—Macromolecular compounds according to different macromolecular groups, mixtures thereof
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00—Liquid carbonaceous fuels
    • C10L1/10—Liquid carbonaceous fuels containing additives
    • C10L1/14—Organic compounds
    • C10L1/18—Organic compounds containing oxygen
    • C10L1/192—Macromolecular compounds
    • C10L1/195—Macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds
    • C10L1/196—Macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds derived from monomers containing a carbon-to-carbon unsaturated bond and a carboxyl group or salts, anhydrides or esters thereof homo- or copolymers of compounds having one or more unsaturated aliphatic radicals each having one carbon bond to carbon double bond, and at least one being terminated by a carboxyl radical or of salts, anhydrides or esters thereof
    • C10L1/1963—Macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds derived from monomers containing a carbon-to-carbon unsaturated bond and a carboxyl group or salts, anhydrides or esters thereof homo- or copolymers of compounds having one or more unsaturated aliphatic radicals each having one carbon bond to carbon double bond, and at least one being terminated by a carboxyl radical or of salts, anhydrides or esters thereof mono-carboxylic
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00—Liquid carbonaceous fuels
    • C10L1/10—Liquid carbonaceous fuels containing additives
    • C10L1/14—Organic compounds
    • C10L1/18—Organic compounds containing oxygen
    • C10L1/192—Macromolecular compounds
    • C10L1/195—Macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds
    • C10L1/196—Macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds derived from monomers containing a carbon-to-carbon unsaturated bond and a carboxyl group or salts, anhydrides or esters thereof homo- or copolymers of compounds having one or more unsaturated aliphatic radicals each having one carbon bond to carbon double bond, and at least one being terminated by a carboxyl radical or of salts, anhydrides or esters thereof
    • C10L1/1966—Macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds derived from monomers containing a carbon-to-carbon unsaturated bond and a carboxyl group or salts, anhydrides or esters thereof homo- or copolymers of compounds having one or more unsaturated aliphatic radicals each having one carbon bond to carbon double bond, and at least one being terminated by a carboxyl radical or of salts, anhydrides or esters thereof poly-carboxylic
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00—Liquid carbonaceous fuels
    • C10L1/10—Liquid carbonaceous fuels containing additives
    • C10L1/14—Organic compounds
    • C10L1/18—Organic compounds containing oxygen
    • C10L1/192—Macromolecular compounds
    • C10L1/195—Macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds
    • C10L1/197—Macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds derived from monomers containing a carbon-to-carbon unsaturated bond and an acyloxy group of a saturated carboxylic or carbonic acid
    • C10L1/1973—Macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds derived from monomers containing a carbon-to-carbon unsaturated bond and an acyloxy group of a saturated carboxylic or carbonic acid mono-carboxylic
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00—Liquid carbonaceous fuels
    • C10L1/10—Liquid carbonaceous fuels containing additives
    • C10L1/14—Organic compounds
    • C10L1/22—Organic compounds containing nitrogen
    • C10L1/234—Macromolecular compounds
    • C10L1/236—Macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds derivatives thereof
    • C10L1/2364—Macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds derivatives thereof homo- or copolymers derived from unsaturated compounds containing amide and/or imide groups

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  • Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Emergency Medicine (AREA)
  • Liquid Carbonaceous Fuels (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Compositions Of Macromolecular Compounds (AREA)

Abstract

Gegenstand der Erfindung sind Additive zur Verbesserung der Kaltfließeigenschaften von Mitteldestillaten, enthaltend 10 bis 95 Gew.-% Copolymere A), 5 bis 90 Gew.-% Copolymere B) und gegebenenfalls 0 bis 70 Gew.-% Copolymere C), die folgenden Formeln entsprechen
  • A) Copolymere aus niederen Olefinen und Vinylestern, enthaltend
  • A1) 85 bis 97 mol-% bivalente Struktureinheiten der Formel - CH2 - CR1R2 - worin R1 und R2 unabhängig voneinander Wasserstoff oder Methyl bedeuten, und
  • A2) mindestens 3 mol-% bivalente Struktureinheiten der Formel
    Figure 80000001
    worin R3 gesättigtes, verzweigtes C6-C16-Alkyl bedeutet, das ein tertiäres Kohlenstoffatom aufweist, dadurch gekennzeichnet, dass R3 mit seinem tertiären Kohlenstoffatom an die Carboxylfunktion gebunden ist,
  • B) Copolymere, umfassend
  • B1) 40 bis 60 mol-% bivalente Struktureinheiten der Formel
    Figure 80000002
  • mit X = O oder N - R4,
  • worin a, b = 0 oder 1 und a + b = 1 sind, und
  • B2) 35 bis 53 mol-% bivalente Struktureinheiten der Formel - H2C - CHR5 - und gegebenenfalls
  • B3) 0 bis 20 mol-%, bivalente Struktureinheiten, die sich von Polyolefinen ableiten, wobei die Polyolefine aus Monoolefinen mit 3 bis 5 Kohlenstoffatomen ableitbar sind, und worin
  • a) R4 einen Alkyl- oder Alkenylrest mit 10 bis 40 Kohlenstoffatomen oder einen Alkoxyalkylrest mit 1 bis 100 Alkoxyeinheiten und 1 bis 30 Kohlenstoffatomen im Alkylrest, und
  • b) R5 einen Alkylrest mit 10 bis 50 Kohlenstoffatomen bedeutet, und
  • c) die Zahl der Kohlenstoffatome der den Struktureinheiten B3) zugrunde liegenden Polyolefinmoleküle zwischen 35 und 350 beträgt, und gegebenenfalls
  • C) ein weiteres von A) und B) verschiedenes Copolymer aus Ethylen und einem oder mehreren Vinyl- oder Acrylester, das allein Wirksamkeit als Kaltfließverbesserer für Mitteldestillate aufweist.
    •
    EP01104847A 2000-03-14 2001-02-28 Copolymermischungen und ihre Verwendung als Additiv zur Verbesserung der Kaltfliesseigenschaften von Mitteldestillaten Expired - Lifetime EP1146108B1 (de)

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    Application Number Priority Date Filing Date Title
    DE10012267A DE10012267B4 (de) 2000-03-14 2000-03-14 Copolymermischungen und ihre Verwendung als Additiv zur Verbesserung der Kaltfließeigenschaften von Mitteldestillaten
    DE10012267 2000-03-14

    Publications (3)

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    EP1146108A2 EP1146108A2 (de) 2001-10-17
    EP1146108A3 true EP1146108A3 (de) 2002-08-07
    EP1146108B1 EP1146108B1 (de) 2006-09-20

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    US (1) US6565616B1 (de)
    EP (1) EP1146108B1 (de)
    JP (1) JP2001288484A (de)
    BR (1) BR0100233B1 (de)
    CA (1) CA2340524A1 (de)
    DE (2) DE10012267B4 (de)
    ES (1) ES2272366T3 (de)
    NO (1) NO20011254L (de)
    PT (1) PT1146108E (de)

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    CA2431746C (en) * 2002-07-09 2011-11-01 Clariant Gmbh Cold flow improvers for fuel oils of vegetable or animal origin
    DE10245737C5 (de) * 2002-10-01 2011-12-08 Clariant Produkte (Deutschland) Gmbh Verfahren zur Herstellung von Additivmischungen für Mineralöle und Mineralöldestillate
    JP2004193756A (ja) * 2002-12-09 2004-07-08 Canon Inc 電子透かし埋め込み方法
    DE10349851B4 (de) * 2003-10-25 2008-06-19 Clariant Produkte (Deutschland) Gmbh Kaltfließverbesserer für Brennstofföle pflanzlichen oder tierischen Ursprungs
    DE10349850C5 (de) 2003-10-25 2011-12-08 Clariant Produkte (Deutschland) Gmbh Kaltfließverbesserer für Brennstofföle pflanzlichen oder tierischen Ursprungs
    DE10357878C5 (de) * 2003-12-11 2013-07-25 Clariant Produkte (Deutschland) Gmbh Brennstofföle aus Mitteldestillaten und Ölen pflanzlichen oder tierischen Ursprungs mit verbesserten Kälteeigenschaften
    DE10357880B4 (de) * 2003-12-11 2008-05-29 Clariant Produkte (Deutschland) Gmbh Brennstofföle aus Mitteldestillaten und Ölen pflanzlichen oder tierischen Ursprungs mit verbesserten Kälteeigenschaften
    DE10357877B4 (de) * 2003-12-11 2008-05-29 Clariant Produkte (Deutschland) Gmbh Brennstofföle aus Mitteldestillaten und Ölen pflanzlichen oder tierischen Ursprungs mit verbesserten Kälteeigenschaften
    US7326453B2 (en) * 2004-02-04 2008-02-05 3M Innovative Properties Company Article with selectively activated adhesive
    DE102006016588A1 (de) * 2006-04-06 2007-10-18 Rohmax Additives Gmbh Kraftstoffzusammensetzungen umfassend nachwachsende Rohstoffe
    DE102006022720B4 (de) * 2006-05-16 2008-10-02 Clariant International Limited Kaltfließverbesserer für pflanzliche oder tierische Brennstofföle
    DE102006033149A1 (de) * 2006-07-18 2008-01-31 Clariant International Limited Additive zur Verbesserung der Kälteeigenschaften von Brennstoffölen
    DE102006033151B4 (de) 2006-07-18 2014-11-20 Clariant International Limited Additive zur Verbesserung der Kälteeigenschaften von Brennstoffölen
    DE102006033150B4 (de) * 2006-07-18 2008-10-16 Clariant International Limited Additive zur Verbesserung der Kälteeigenschaften von Brennstoffölen
    ES2382420T3 (es) 2009-09-25 2012-06-08 Evonik Rohmax Additives Gmbh Una composición para mejorar las propiedades de fluidez en frío de aceites combustibles
    US9012583B2 (en) 2010-02-10 2015-04-21 Nof Corporation Flow improver for oils and fats
    JP5634302B2 (ja) * 2011-02-28 2014-12-03 株式会社Adeka 脂肪酸メチルエステル用低温流動性向上剤
    CN103370400B (zh) 2011-03-25 2016-12-14 赢创油品添加剂有限公司 用于改进燃料油氧化稳定性的组合物
    WO2013075300A1 (zh) * 2011-11-23 2013-05-30 Xiong Liang 一种用于柴油低温流动性改进剂的共聚物及其合成方法
    US20130212931A1 (en) * 2012-02-16 2013-08-22 Baker Hughes Incorporated Biofuel having improved cold flow properties
    CA2884715A1 (en) 2012-09-13 2014-03-20 Evonik Oil Additives Gmbh A composition to improve low temperature properties and oxidation stability of vegetable oils and animal fats
    CN104968768B (zh) 2013-02-04 2017-03-08 赢创油品添加剂有限公司 在矿物柴油、生物柴油及其共混物中具有宽的应用性的冷流动改进剂
    CN104830387B (zh) * 2015-05-29 2016-05-04 马健 一种减排柴油防冻剂

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    EP0214786A1 (de) * 1985-08-28 1987-03-18 Exxon Chemical Patents Inc. Mitteldestillat-Zusammensetzungen mit für niedrige Temperaturen verbesserten Eigenschaften
    EP0320766A2 (de) * 1987-12-16 1989-06-21 Hoechst Aktiengesellschaft Polymermischungen für die Verbesserung der Fliessfähigkeit von Mineralöldestillaten in der Kälte
    EP0807642A1 (de) * 1996-05-18 1997-11-19 Hoechst Aktiengesellschaft Terpolymerisate des Ethylens, ihre Herstellung und ihre Verwendung als Additive für Mineralöldestillate
    EP0890589A2 (de) * 1997-07-08 1999-01-13 Clariant GmbH Copolymere auf Basis von Olefinen und ungesättigten Carbonsäureestern und ihre Verwendung als Mineralöladditive
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    Also Published As

    Publication number Publication date
    PT1146108E (pt) 2007-01-31
    EP1146108A2 (de) 2001-10-17
    NO20011254L (no) 2001-09-17
    NO20011254D0 (no) 2001-03-13
    ES2272366T3 (es) 2007-05-01
    JP2001288484A (ja) 2001-10-16
    CA2340524A1 (en) 2001-09-14
    EP1146108B1 (de) 2006-09-20
    US6565616B1 (en) 2003-05-20
    BR0100233A (pt) 2001-11-06
    DE50111031D1 (de) 2006-11-02
    DE10012267A1 (de) 2001-10-11
    DE10012267B4 (de) 2005-12-15
    BR0100233B1 (pt) 2011-05-03

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