EP1127940A1 - Weichgriffmittel für Textilien auf Cyclodextrinbasis - Google Patents
Weichgriffmittel für Textilien auf Cyclodextrinbasis Download PDFInfo
- Publication number
- EP1127940A1 EP1127940A1 EP00104047A EP00104047A EP1127940A1 EP 1127940 A1 EP1127940 A1 EP 1127940A1 EP 00104047 A EP00104047 A EP 00104047A EP 00104047 A EP00104047 A EP 00104047A EP 1127940 A1 EP1127940 A1 EP 1127940A1
- Authority
- EP
- European Patent Office
- Prior art keywords
- component
- composition according
- mixture
- weight
- cyclodextrin
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Withdrawn
Links
Classifications
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/01—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with natural macromolecular compounds or derivatives thereof
- D06M15/03—Polysaccharides or derivatives thereof
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/38—Cationic compounds
- C11D1/65—Mixtures of anionic with cationic compounds
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/22—Carbohydrates or derivatives thereof
- C11D3/222—Natural or synthetic polysaccharides, e.g. cellulose, starch, gum, alginic acid or cyclodextrin
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/10—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
- D06M13/184—Carboxylic acids; Anhydrides, halides or salts thereof
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/10—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
- D06M13/184—Carboxylic acids; Anhydrides, halides or salts thereof
- D06M13/188—Monocarboxylic acids; Anhydrides, halides or salts thereof
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/322—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing nitrogen
- D06M13/46—Compounds containing quaternary nitrogen atoms
- D06M13/463—Compounds containing quaternary nitrogen atoms derived from monoamines
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/04—Carboxylic acids or salts thereof
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/38—Cationic compounds
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M2200/00—Functionality of the treatment composition and/or properties imparted to the textile material
- D06M2200/50—Modified hand or grip properties; Softening compositions
Definitions
- the invention relates to compositions comprising a cyclodextrin, a carboxylic acid and a contain cationic surfactant. It further relates to the use of such compositions for the treatment of fiber materials, in particular of textile fabrics.
- the present invention has for its object to provide compositions for the Treatment of fiber materials, in particular of non-ready-made textile Fabrics that provide the benefits of cyclodextrins Retain formulations while giving a very soft feel.
- compositions according to the invention are preferably carried out so that the compositions in the form of aqueous dispersions of these Compositions are used.
- the dispersions can be applied to the fiber materials by known methods be, e.g. by means of a padding process.
- the used in the padding Liquor to a level customary in textile finishing and to the desired pH set.
- the compositions according to the invention, their aqueous dispersions and the fleets used for padding can, in addition to the above-mentioned components A, B and C, other products included.
- Such other products may be in textile equipment commonly used ingredients such as flame retardants, polyolefins next to it Silicones and fluoropolymers for oil and / or water repellent equipment.
- compositions of the invention or their aqueous dispersions in addition known cellulose crosslinkers such as e.g. Dimethyloldihydroxiethylenurea included.
- cellulose crosslinkers such as e.g. Dimethyloldihydroxiethylenurea included.
- compositions according to the invention for textile treatment retain the known benefits of cyclodextrins. This includes on the one hand the possibility Body sweat or volatile or gaseous products absorb and thus Reduce odor nuisance. Furthermore, cyclodextrins can be known to do so serve to store active ingredients such as perfumes in their cavities and controlled in small quantities Release cans again. In this way it is possible to give textiles a pleasant smell to rent.
- the perfume is combined by known methods with cyclodextrin.
- inventive Compositions a very pleasant soft touch and a controllable level Achieve hydrophilicity.
- Aqueous dispersions of compositions according to the invention can also be used advantageously in exhaust for textile treatment.
- the hydrophilicity of Textiles can be controlled via the relative amounts of components A, B and C, or over Addition of non-ionic dispersants, which is described below.
- compositions according to the invention can achieve a distinct, synergistic effect on the softness of textiles treated therewith.
- the handle to be achieved with compositions of the invention is softer than the handle associated with each of components A, B and C alone results.
- the pronounced hydrophilic properties imparted to the fiber materials in a known manner by cyclodextrins are not or only to an acceptable extent worsened by the addition of longer chain fatty acids. With compositions according to the invention, therefore, the fiber materials can be given distinctively hydrophilic properties and a very soft feel.
- compositions of the invention contain at least the three following in more detail Components A, B and C described above may be added Contain ingredients.
- Component A is an unsubstituted cyclodextrin or a mixture of such cyclodextrins.
- Cyclodextrins are understood to mean cyclically closed oligosaccharides which consist of 6, 7 or 8 ⁇ -1,4-glycosidically linked D-glucopyranose units, as defined in HR Christen et al, "Organic Chemistry, From the Foundations to Research" , Volume II, page 549, 1st edition 1990, Otto-Salle-Verlag, Frankfurt / M.
- ⁇ -cyclodextrin, ⁇ -cyclodextrin or y-cyclodextrin mean the compounds with 6, 7 or 8 units.
- Cyclodextrins are formed by the degradation of starch by bacteria.
- Particularly preferred compositions according to the invention contain at least ⁇ -cyclodextrin.
- they may additionally contain ⁇ - and / or ⁇ -cyclodextrin.
- Cyclodextrins are commercial products, e.g. available from Wacker Chemie, Germany.
- Component B is an aliphatic carboxylic acid having 8 to 24 carbon atoms or a Mixture of such carboxylic acids. Can be used linear or branched, saturated or unsaturated acids such as e.g. Oleic acid. Furthermore, component B can be monovalent or contain polybasic carboxylic acids. Preferred as component B are saturated, unbranched, monovalent carboxylic acids (monocarboxylic acids) such as e.g. Stearic acid or Behenic acid. Normally, component B consists of a mixture for cost reasons technical carboxylic acids with a usual chain length distribution.
- Further suitable anions X ⁇ are, for example, the anion of acetic acid, propionic acid, glycolic acid or lactic acid.
- R 1 is a linear or branched alkyl radical having 8 to 20 carbon atoms. If R 2 or R 3 are also an alkyl radical, this alkyl radical contains 1 to 6 carbon atoms and may be linear or branched.
- component A, B or C consist of mixtures, then these amounts refer in each case to the sum of all ingredients of these mixtures. By varying these proportions, the handle and hydrophilicity of finished textiles can be selectively influenced.
- compositions according to the invention or aqueous dispersions of these compositions additionally contain a nonionic surfactant or a mixture of such surfactants.
- a nonionic surfactant are ethoxylated carboxylic acids and ethoxylated alcohols.
- silicones having polyoxyethylene groups or amino groups in side chains can be used, either alone or in combination with the above-mentioned nonionic surfactants.
- Suitable for this purpose are known from the literature N-methylol compounds, but also so-called “formaldehyde-free” or “low-formaldehyde” crosslinkers.
- Suitable cellulose crosslinkers are available from Ciba Spezialitätenchemie Pfersee GmbH, for example products of the KNITTEX® series.
- the cellulose crosslinker if appropriate together with crosslinking catalyst, is normally added to the aqueous dispersions or finishing liquors which comprise compositions according to the invention. After application of such dispersions on fiber materials and drying, a conventional thermal treatment, for example at 160 ° C followed to effect crosslinking with the cellulosic material. After this treatment, increased permanence of the effects achieved with compositions according to the invention results.
- compositions according to the invention are preferably in the form of aqueous dispersions, which consist of 10 to 40% by weight of these compositions.
- the rest exists either only water or water and other ingredients, e.g. the above
- aqueous dispersions can be prepared by generally known methods be prepared, e.g. Presentation of water, adding the individual components of a Composition according to the invention in any order and under homogenization mechanical movement at a temperature of 40 ° to 100 ° C.
- a preformed composition according to the invention without the use of water and these Composition are stirred in water.
- compositions according to the invention in the form of aqueous dispersions containing the compositions for the treatment of non-ready-made textile fabrics in the form of woven or knitted fabrics.
- This treatment therefore preferably takes place in the operation of the Textilausrüsters and not on the ready-made items in the household.
- the fiber materials which are preferably present as non-ready-made woven or knitted fabrics, can be further processed into articles of clothing. They may consist of natural fibers such as wool or cotton, of regenerated fibers such as viscose or synthetic fibers such as polyamide or polyester or mixtures of these types of fibers.
- a dispersion 2 was prepared by the same method as dispersion 1.
- Dispersions 1 and 2 had the compositions given in the table below.
- Dispersions 1 and 2 both of which were stable, became different tissues and knitted fabrics of cotton, cotton / polyester, polyester and polyamide (Foulard) and dried. Subsequently, the grip was judged and the hydrophilicity of the textile Sheets determined. This determination was made by measuring the time taken Water droplets needed to penetrate into the fabric.
Landscapes
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Molecular Biology (AREA)
- Emergency Medicine (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
Abstract
Description
Die US 5 234 611 beschreibt Gewebeweichmachungsmittel, welche in Polymeren eingeschlossene, verkapselte Cyclodextrine enthalten. Sie dienen zur Anwendung in Haushaltswäschen.
Ferner war es überraschend, daß die ausgesprochen hydrophilen Eigenschaften, welche den Fasermaterialien in bekannter Weise durch Cyclodextrine verliehen werden, durch den Zusatz von längerkettigen Fettsäuren nicht oder nur in einem akzeptablen Ausmaß verschlechtert werden. Mit erfindungsgemäßen Zusammensetzungen können also den Fasermaterialien ausgeprägt hydrophile Eigenschaften und ein sehr weicher Griff verliehen werden.
Bevorzugte erfindungsgemäße Zusammensetzungen sind dadurch gekennzeichnet, daß Komponente C ein Tensid der allgemeinen Formel (I) enthält. wobei
wobei
- R1 ein Alkylrest mit 8 bis 20 Kohlenstoffatomen ist,
- R2 und R3 unabhängig voneinander für Wasserstoff, einen Alkylrest mit 1 bis 6 Kohlenstoffatomen oder für einen Rest der Formel
und wobei XΘ für ein einwertiges Anion einer anorganischen oder organischen Säure steht.
Durch Variation dieser Mengenverhältnisse lassen sich Griff und Hydrophilie ausgerüsteter Textilien gezielt beeinflussen.
Insbesondere dann, wenn mit erfindungsgemäßen Zusammensetzungen textile Flächengebilde behandelt werden sollen, die ganz oder zu einem wesentlichen Teil aus Cellulosefasern bestehen, ist es häufig von Vorteil, wenn ein Cellulosevernetzer mitverwendet wird. Hierfür geeignet sind aus der Literatur bekannte N-Methylolverbindungen, aber auch sogenannte "formaldehydfreie" oder "formaldehydarme" Vernetzer. Geeignete Cellulosevernetzer sind von der Fa. Ciba Spezialitätenchemie Pfersee GmbH beziehbar, z.B. Produkte der KNITTEX® -Serie. Der Cellulosevernetzer, ggf. zusammen mit Vernetzungskatalysator wird im Normalfall den wäßrigen Dispersionen bzw. Ausrüstflotten zugefügt, welche erfindungsgemäße Zusammensetzungen enthalten. Nach Aufbringen solcher Dispersionen auf Fasermaterialien und Trocknung schließt sich eine übliche thermische Behandlung z.B. bei 160°C an, um die Vernetzung mit dem Cellulosematerial zu bewirken. Nach dieser Behandlung resultiert eine erhöhte Permanenz der Effekte, die mit erfindungsgemäßen Zusammensetzungen erreicht werden.
Die Fasermaterialien, die bevorzugt als nicht-konfektionierte Gewebe oder Gewirke vorliegen, können zu Bekleidungsartikeln weiterverarbeitet werden. Sie können aus natürlichen Fasern wie Wolle oder Baumwolle, aus regenerierten Fasern wie Viskose oder synthetischen Fasern wie Polyamid oder Polyester oder aus Gemischen der genannten Faserarten bestehen.
- Komponente a) =
- β-Cyclodextrin (= Komponente A von Anspruch 1)
- Komponente b) =
- technische gesättigte Monocarbonsäure mit durchschnittlich 20 C-Atomen (= Komponente B von Anspruch 1)
- Komponente c) =
- quatemäres Ammoniumsalz aus ethoxiliertem Stearylamin und Glykolsäure (Komponente C von Anspruch 1)
- Komponente d) =
- Bis (acyloxyethyl)methyl-hydroxyethyl-ammoniummethylsulfat (Komponente C von Anspruch 1)
- Komponente e) =
- ethoxilierter C16 - C18-Alkohol
- Komponente f) =
- modifiziertes Polydimethylsiloxan mit Polyoxyethylengruppen in Seitenketten
- Komponente g) =
- Wasser
Die Dispersionen 1 und 2 besaßen die in der nachfolgenden Tabelle angegebenen Zusammensetzungen.
Dispersion | Gew.-teile Komponente a | Gew.-teile Komponente b | Gew.-teile Komponente c | Gew.-teile Komponente d | Gew.-teile Komponente e | Gew.-teile Komponente f | Gew.-teile Komponente g |
1 | 2,2 | 6,2 | 5,3 | 3,2 | 0,7 | 0,4 | 82,0 |
2 | 2,2 | 0 | 5,3 | 3,2 | 0,7 | 0,4 | 82,0 |
Claims (8)
- Zusammensetzung, welche mindestens folgende Komponenten enthältA) ein unsubstituiertes Cyclodextrin oder ein Gemisch solcher CyclodextrineB) eine aliphatische Carbonsäure mit 8 bis 24 Kohlenstoffatomen oder ein Gemisch solcher CarbonsäurenC) ein kationisches Tensid oder ein Gemisch solcher Tenside
- Zusammensetzung nach Anspruch 1, dadurch gekennzeichnet, daß Komponente A mindestens β-Cyclodextrin enthält.
- Zusammensetzung nach Anspruch 1 oder 2, dadurch gekennzeichnet, daß Komponente B eine gesättigte, unverzweigte Monocarbonsäure oder ein Gemisch solcher Säuren enthält.
- Zusammensetzung nach einem oder mehreren der Ansprüche 1 bis 3, dadurch gekennzeichnet, daß Komponente C ein Tensid der allgemeinen Formel (I) enthält wobeim = 0 oder 1n eine Zahl von 1 bis 8p = 1 oder 2q = 0, 1 oder 2r = 0, 1 oder 2q + r = 2 oder 3
wobeiR1 ein Alkylrest mit 8 bis 20 Kohlenstoffatomen ist,R2 und R3 unabhängig voneinander für Wasserstoff, einen Alkylrest mit 1 bis 6 Kohlenstoffatomen oder für einen Rest der Formel
und wobei XΘ für ein einwertiges Anion einer anorganischen oder organischen Säure steht. - Zusammensetzung nach einem oder mehreren der Ansprüche 1 bis 4, dadurch gekennzeichnet, daß sie die Komponenten A, B und C in folgenden Mengenverhältnissen relativ zueinander enthält:A): 10 bis 20 GewichtsteileB): 25 bis 80 GewichtsteileC): 25 bis 150 Gewichtsteile
- Wäßrige Dispersion, welche zu 10 bis 40 Gew% aus einer Zusammensetzung nach einem oder mehreren der Ansprüche 1 bis 5 besteht.
- Verwendung einer Zusammensetzung nach einem oder mehreren der Ansprüche 1 bis 5 oder einer Dispersion nach Anspruch 6 zur Behandlung von Fasermaterialien.
- Verwendung nach Anspruch 7, dadurch gekennzeichnet, daß die Fasermaterialien nicht-konfektionierte textile Flächengebilde in Form von Geweben oder Gewirken sind.
Priority Applications (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
EP00104047A EP1127940A1 (de) | 2000-02-26 | 2000-02-26 | Weichgriffmittel für Textilien auf Cyclodextrinbasis |
US09/790,759 US20020007517A1 (en) | 2000-02-26 | 2001-02-22 | Cyclodextrin-based soft-hand compositions for textiles |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
EP00104047A EP1127940A1 (de) | 2000-02-26 | 2000-02-26 | Weichgriffmittel für Textilien auf Cyclodextrinbasis |
Publications (1)
Publication Number | Publication Date |
---|---|
EP1127940A1 true EP1127940A1 (de) | 2001-08-29 |
Family
ID=8167969
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP00104047A Withdrawn EP1127940A1 (de) | 2000-02-26 | 2000-02-26 | Weichgriffmittel für Textilien auf Cyclodextrinbasis |
Country Status (2)
Country | Link |
---|---|
US (1) | US20020007517A1 (de) |
EP (1) | EP1127940A1 (de) |
Cited By (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2005001192A1 (en) * | 2003-06-26 | 2005-01-06 | Ciba Specialty Chemicals Holding Inc. | Aqueous liquid compositions of cyclodextrine or cyclodextrine derivatives and a process using the said composition |
DE102004035898A1 (de) * | 2004-07-23 | 2006-02-09 | Cht R. Beitlich Gmbh | Textilausrüstungsmittel enthaltend einen Komplex aus gamma-Cyclodextrin und alpha-Tocopherol |
US7125833B2 (en) | 2003-03-24 | 2006-10-24 | Wacker Chemie Ag | Cyclodextrin laundry detergent additive complexes and compositions containing same |
DE102010023790A1 (de) | 2010-06-15 | 2011-12-15 | Heinrich-Heine-Universität Düsseldorf | Waschaktive Zusammensetzung |
CN103703180A (zh) * | 2011-03-31 | 2014-04-02 | 基亚尼斯有限公司 | 粘合剂及制备含所述粘合剂固定的环糊精的织物的方法 |
Families Citing this family (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US6861520B1 (en) | 2003-04-30 | 2005-03-01 | Dan River, Inc. | Process for chemically bonding an odor-encapsulating agent to textiles and textiles formed by the process |
DE102014105001A1 (de) * | 2014-04-08 | 2015-10-08 | Technische Universität Dortmund | Verfahren zur Luftraumüberwachung |
WO2017122162A1 (en) * | 2016-01-15 | 2017-07-20 | Next Technology Tecnotessile Societa' Nazionale Di Ricerca R.L. | Functionalized fabric |
Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US5470492A (en) * | 1993-09-10 | 1995-11-28 | The Procter & Gamble Company | Dryer-activated fabric conditioning articles with soft polyester substrate |
EP0839899A1 (de) * | 1996-10-30 | 1998-05-06 | The Procter & Gamble Company | Gewebeweichmacherzusammensetzungen |
US5804219A (en) * | 1992-11-16 | 1998-09-08 | The Procter & Gamble Company | Fabric softening compositions with dye transfer inhibitors for improved fabric appearance |
US5905067A (en) * | 1997-02-10 | 1999-05-18 | Procter & Gamble Company | System for delivering hydrophobic liquid bleach activators |
US6025321A (en) * | 1996-03-29 | 2000-02-15 | The Procter & Gamble Company | Dryer-added fabric softener composition to provide color and other fabric benefits in package in association with instructions for use |
-
2000
- 2000-02-26 EP EP00104047A patent/EP1127940A1/de not_active Withdrawn
-
2001
- 2001-02-22 US US09/790,759 patent/US20020007517A1/en not_active Abandoned
Patent Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US5804219A (en) * | 1992-11-16 | 1998-09-08 | The Procter & Gamble Company | Fabric softening compositions with dye transfer inhibitors for improved fabric appearance |
US5470492A (en) * | 1993-09-10 | 1995-11-28 | The Procter & Gamble Company | Dryer-activated fabric conditioning articles with soft polyester substrate |
US6025321A (en) * | 1996-03-29 | 2000-02-15 | The Procter & Gamble Company | Dryer-added fabric softener composition to provide color and other fabric benefits in package in association with instructions for use |
EP0839899A1 (de) * | 1996-10-30 | 1998-05-06 | The Procter & Gamble Company | Gewebeweichmacherzusammensetzungen |
US5905067A (en) * | 1997-02-10 | 1999-05-18 | Procter & Gamble Company | System for delivering hydrophobic liquid bleach activators |
Cited By (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US7125833B2 (en) | 2003-03-24 | 2006-10-24 | Wacker Chemie Ag | Cyclodextrin laundry detergent additive complexes and compositions containing same |
WO2005001192A1 (en) * | 2003-06-26 | 2005-01-06 | Ciba Specialty Chemicals Holding Inc. | Aqueous liquid compositions of cyclodextrine or cyclodextrine derivatives and a process using the said composition |
DE102004035898A1 (de) * | 2004-07-23 | 2006-02-09 | Cht R. Beitlich Gmbh | Textilausrüstungsmittel enthaltend einen Komplex aus gamma-Cyclodextrin und alpha-Tocopherol |
DE102004035898B4 (de) * | 2004-07-23 | 2008-04-24 | Cht R. Beitlich Gmbh | Textilausrüstungsmittel enthaltend einen Komplex aus gamma-Cyclodextrin und alpha-Tocopherol |
DE102010023790A1 (de) | 2010-06-15 | 2011-12-15 | Heinrich-Heine-Universität Düsseldorf | Waschaktive Zusammensetzung |
CN103703180A (zh) * | 2011-03-31 | 2014-04-02 | 基亚尼斯有限公司 | 粘合剂及制备含所述粘合剂固定的环糊精的织物的方法 |
Also Published As
Publication number | Publication date |
---|---|
US20020007517A1 (en) | 2002-01-24 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
DE4035378C2 (de) | Textiles Material sowie Verfahren zur Herstellung eines derartigen textilen Materials | |
DE69908910T2 (de) | Verfahren zum verleihen einem stoff antimikrobiellen eigenschaften von grosser lebensdauer; so hergestellte fasern, textilie oder stoff | |
DE69629795T2 (de) | Verfahren zur Herstellung von Gegenständen aus einem regenerierte Chitin-Chitosan enthaltenden Material und erhaltene Gegenstände | |
EP2776619B1 (de) | Vlies enthaltend eine cellulosefaser mit wasserabweisenden eigenschaften und hoher weichheit | |
EP1194434A1 (de) | Antimikrobielle siloxanquat-formulierungen, deren herstellung und verwendung | |
AT2256U1 (de) | Verfahren zur behandlung von cellulosischen formkörpern | |
DE68909268T2 (de) | Verfahren zur Modifizierung der Oberfläche eines festen Kunststoffes. | |
EP1127940A1 (de) | Weichgriffmittel für Textilien auf Cyclodextrinbasis | |
DE2923218A1 (de) | Verfahren zum herstellen wasserunloeslicher zink-azetat-peroxidkomplexe und bakteriostatischer buegelfreier baumwollgewebe und zum bakteriostatischmachen von zellulosehaltigen und/oder polyesterhaltigen textilien sowie bakteriostatische zusammensetzung | |
WO2002081791A2 (de) | Bioaktive faserprodukte | |
DE2724816C2 (de) | ||
DE3706664A1 (de) | Fluessige textilbehandlungsmittel | |
DE1593950A1 (de) | Behandlung von Textilien | |
AT413988B (de) | Verfahren zur behandlung von cellulosischen formkörpern | |
DE939683C (de) | Verfahren zur Herstellung von haltbaren, mechanisch erzeugten Appretureffekten auf Cellulosematerial bzw. Seide | |
DE2430502A1 (de) | Baumwoll-faserverbindung mit gesteigerter saugfaehigkeit | |
EP0863249B1 (de) | Verfahren zur Behandlung von Wolle enthaltenden Geweben, insbesondere Kleidungsstücken | |
DE2000432B2 (de) | Mittel zum weichmachen von fasern und gewebtem oder ungewebtem textilgut | |
DE2243806C3 (de) | Wässriges Mittel zum Weichmachen von Textilgut | |
EP3115502A1 (de) | Waschbeständig hydrophobierte cellolusefasern und verfahren zum waschbeständigen hydrophobieren von cellolusefasern | |
EP0039783A2 (de) | Verfahren zum Dimensionsstabilisieren von flächenförmigen Textilmaterialien | |
DE102004035898B4 (de) | Textilausrüstungsmittel enthaltend einen Komplex aus gamma-Cyclodextrin und alpha-Tocopherol | |
DD300605A7 (de) | Zusammensetzung zur behandlung von textilem material | |
DE930746C (de) | Verfahren zur Behandlung von Textilstoffen, insbesondere aus regenerierter Cellulose | |
DE2412175B2 (de) | Verfahren zum Appretieren von Textilien während der Chemischreinigung |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
PUAI | Public reference made under article 153(3) epc to a published international application that has entered the european phase |
Free format text: ORIGINAL CODE: 0009012 |
|
AK | Designated contracting states |
Kind code of ref document: A1 Designated state(s): AT BE CH CY DE DK ES FI FR GB GR IE IT LI LU MC NL PT SE |
|
AX | Request for extension of the european patent |
Free format text: AL;LT;LV;MK;RO;SI |
|
17P | Request for examination filed |
Effective date: 20011212 |
|
AKX | Designation fees paid |
Free format text: AT BE CH CY DE DK ES FI FR GB GR IE IT LI LU MC NL PT SE |
|
GRAP | Despatch of communication of intention to grant a patent |
Free format text: ORIGINAL CODE: EPIDOSNIGR1 |
|
STAA | Information on the status of an ep patent application or granted ep patent |
Free format text: STATUS: THE APPLICATION IS DEEMED TO BE WITHDRAWN |
|
18D | Application deemed to be withdrawn |
Effective date: 20050901 |