EP1127706B1 - Matériau d'enregistrement par jet d'encre - Google Patents

Matériau d'enregistrement par jet d'encre Download PDF

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Publication number
EP1127706B1
EP1127706B1 EP01000012A EP01000012A EP1127706B1 EP 1127706 B1 EP1127706 B1 EP 1127706B1 EP 01000012 A EP01000012 A EP 01000012A EP 01000012 A EP01000012 A EP 01000012A EP 1127706 B1 EP1127706 B1 EP 1127706B1
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EP
European Patent Office
Prior art keywords
ink jet
jet recording
recording element
element according
ink
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
EP01000012A
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German (de)
English (en)
Other versions
EP1127706A1 (fr
EP1127706B2 (fr
Inventor
Dirk Quintens
Horst Friedel
Huub Van Aert
Jan Gilleir
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Agfa NV
Original Assignee
Agfa Gevaert NV
Agfa Gevaert AG
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Application filed by Agfa Gevaert NV, Agfa Gevaert AG filed Critical Agfa Gevaert NV
Priority to DE60111587T priority Critical patent/DE60111587T3/de
Priority to EP01000012.3A priority patent/EP1127706B2/fr
Publication of EP1127706A1 publication Critical patent/EP1127706A1/fr
Publication of EP1127706B1 publication Critical patent/EP1127706B1/fr
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Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
    • B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
    • B41M5/00—Duplicating or marking methods; Sheet materials for use therein
    • B41M5/50—Recording sheets characterised by the coating used to improve ink, dye or pigment receptivity, e.g. for ink-jet or thermal dye transfer recording
    • B41M5/52—Macromolecular coatings
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
    • B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
    • B41M5/00—Duplicating or marking methods; Sheet materials for use therein
    • B41M5/50—Recording sheets characterised by the coating used to improve ink, dye or pigment receptivity, e.g. for ink-jet or thermal dye transfer recording
    • B41M5/502—Recording sheets characterised by the coating used to improve ink, dye or pigment receptivity, e.g. for ink-jet or thermal dye transfer recording characterised by structural details, e.g. multilayer materials
    • B41M5/506—Intermediate layers
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
    • B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
    • B41M5/00—Duplicating or marking methods; Sheet materials for use therein
    • B41M5/50—Recording sheets characterised by the coating used to improve ink, dye or pigment receptivity, e.g. for ink-jet or thermal dye transfer recording
    • B41M5/502—Recording sheets characterised by the coating used to improve ink, dye or pigment receptivity, e.g. for ink-jet or thermal dye transfer recording characterised by structural details, e.g. multilayer materials
    • B41M5/508—Supports
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
    • B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
    • B41M5/00—Duplicating or marking methods; Sheet materials for use therein
    • B41M5/50—Recording sheets characterised by the coating used to improve ink, dye or pigment receptivity, e.g. for ink-jet or thermal dye transfer recording
    • B41M5/52—Macromolecular coatings
    • B41M5/5218—Macromolecular coatings characterised by inorganic additives, e.g. pigments, clays
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
    • B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
    • B41M5/00—Duplicating or marking methods; Sheet materials for use therein
    • B41M5/50—Recording sheets characterised by the coating used to improve ink, dye or pigment receptivity, e.g. for ink-jet or thermal dye transfer recording
    • B41M5/52—Macromolecular coatings
    • B41M5/5245—Macromolecular coatings characterised by the use of polymers containing cationic or anionic groups, e.g. mordants
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
    • B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
    • B41M5/00—Duplicating or marking methods; Sheet materials for use therein
    • B41M5/50—Recording sheets characterised by the coating used to improve ink, dye or pigment receptivity, e.g. for ink-jet or thermal dye transfer recording
    • B41M5/52—Macromolecular coatings
    • B41M5/5254—Macromolecular coatings characterised by the use of polymers obtained by reactions only involving carbon-to-carbon unsaturated bonds, e.g. vinyl polymers
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
    • B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
    • B41M5/00—Duplicating or marking methods; Sheet materials for use therein
    • B41M5/50—Recording sheets characterised by the coating used to improve ink, dye or pigment receptivity, e.g. for ink-jet or thermal dye transfer recording
    • B41M5/52—Macromolecular coatings
    • B41M5/529—Macromolecular coatings characterised by the use of fluorine- or silicon-containing organic compounds

Definitions

  • the present invention relates to the field of recording media for ink jet printing.
  • ink jet printing has become a popular technique because of its simplicity, convenience and low cost. Especially in those instances where a limited edition of the printed matter is needed ink jet printing has become a technology of choice.
  • a recent survey on progress and trends in ink jet printing technology is given by Hue P. Le in Journal of Imaging Science and Technology Vol. 42 (1), Jan/Febr 1998.
  • ink jet printing tiny drops of ink fluid are projected directly onto an ink receptor surface without physical contact between the printing device and the receptor.
  • the printing device stores the printing data electronically and controls a mechanism for ejecting the drops image-wise. Printing is accomplished by moving the print head across the paper or vice versa.
  • Early patents on ink jet printers include US 3,739,393, US 3,805,273 and US 3,891,121.
  • the jetting of the ink droplets can be performed in several different ways.
  • a continuous droplet stream is created by applying a pressure wave pattern. This process is known as continuous ink jet printing.
  • the droplet stream is divided into droplets that are electrostatically charged, deflected and recollected, and into droplets that remain uncharged, continue their way undeflected, and form the image.
  • the charged deflected stream forms the image and the uncharged undeflected jet is recollected.
  • several jets are deflected to a different degree and thus record the image (multideflection system).
  • the ink droplets can be created “on demand” (“DOD” or “drop on demand” method) whereby the printing device ejects the droplets only when they are used in imaging on a receiver thereby avoiding the complexity of drop charging, deflection hardware, and ink recollection.
  • DOD on demand
  • the ink droplet can be formed by means of a pressure wave created by a mechanical motion of a piezoelectric transducer (so-called “piezo method”), or by means of discrete thermal pushes (so-called “bubble jet” method, or “thermal jet” method).
  • Ink compositions for ink jet typically include following ingredients : dyes or pigments, water and/or organic solvents, humectants such as glycols, detergents, thickeners, polymeric binders, preservatives, etc.. It will be readily understood that the optimal composition of such an ink is dependent on the ink jetting method used and on the nature of the substrate to be printed.
  • the ink compositions can be roughly divided in :
  • Pigments and particles have also been described in patent applications including DE 2,925,769, GB 2,050,866, US-P 4,474,850, US-P 4,547,405, US-P 4,578,285, WO 88 06532, US-P 4,849,286, EP 339604, EP 400681, EP 407881, EP 411638 and US-P 5,045,864 (non-exhaustive list).
  • binders of which the most common types such as gelatin, polyvinyl alcohol, polyvinyl pyrrolidone, and various types of cellulose derivatives. These conventional binders are mentioned in numerous patent documents.
  • JP 62-62-259882A discloses Ink jet recording medium, with regard to ink jet recording mediums that have an aqueous ink absorption layer placed on top of a support, having as distinctive feature that the ink absorption layer consists of (1) a first layer, which consists of pigment that has synthetic amorphous silica as main component and polyvinyl alcohol type polymer that has a silanol group inside the molecule, alone or a mixture with other adhesive agents, and (2) a second layer, which consists of pigment that has synthetic amorphous silica as main component, 2 weight parts or less of polyvinyl alcohol type polymer that has a silanol group inside the molecule, with regard to 100 weight parts of pigment, other adhesive agents, and cationic resin.
  • EP-A 0 600 245 discloses an ink jet recording sheet which comprises a support comprising a wood pulp and 10% by weight or more of a pigment and one ink-receiving layer on one side of the support, and one back-coat layer coated on the other side of the support, wherein the ratio of gas permeability P according to JIS P8117 to density D according to JIS P8118 of the recording sheet (P/D ratio) is in the range 150-2000.
  • EP-A 0 600 245 further discloses EP-A 0 600 245 discloses an ink jet recording sheet which comprises a support comprising a wood pulp and 10% by weight or more of a pigment and one ink-receiving layer on one side of the support, and has no back-coat layer on the other side of the support, wherein the ratio of gas permeability P according to JIS P8117 to density D according to JIS P8118 of the recording sheet (P/D ratio) is in the range 25-200.
  • a suitable material is disclosed in EP 487350 which describes a receiver coating comprising a pigment, polyvinyl alcohol, and an additional binder selected from the group consisting of styrene-butadiene latices, cationic polymers, styrene-vinyl pyrrolidone copolymers, styrene-maleic anhydride copolymers, and mixtures thereof.
  • styrene-butadiene latices cationic polymers
  • styrene-vinyl pyrrolidone copolymers styrene-maleic anhydride copolymers
  • mixtures thereof it turns out that using conventional polyvinyl alcohol as binder not all types of pigments are dispersed in a perfectly stable way. In particular, with some types of silica partial or total flocculation can occur giving rise to turbid coated layers.
  • the present invention extends the teachings on ink jet recording materials and is particularly directed to an improved material for outdoor use.
  • an ink jet recording element comprising a support and an ink receiving layer wherein said ink receiving layer comprises (a) a pigment, (b) a silanol modified polyvinyl alcohol, and (c) a film-forming polymer having a glass transition temperature lower than 50°C, characterized in that said support is selected from the group consisting of polymeric type supports well-known from photographic technology,
  • the recording element may further contain an adhesive undercoat between the support and the ink receiving layer.
  • the principal ingredients of the ink receiving layer in connection with the present invention being the pigment, the silanol modified polyvinyl alcohol, and the film-forming polymer.
  • the pigment present in the ink receiving layer may be chosen from organic material such as polystyrene, polymethylmethacrylate, silicones, urea-formaldehyde condensation polymers, polyesters and polyamides.
  • organic material such as polystyrene, polymethylmethacrylate, silicones, urea-formaldehyde condensation polymers, polyesters and polyamides.
  • it is an inorganic porous pigment, such as silica, talc, clay, koalin, diatomaceous earth, calcium carbonate, magnesium carbonate, aluminium hydroxide, aluminium oxide, titanium oxide, zinc oxide, barium sulfate, calcium sulfate, zinc sulfide, satin white, boehmite and pseudo-boehmite.
  • the preferred pigment is a silica type, more particularly an amorphous silica having a average particle size ranging from 1 ⁇ m to 15 ⁇ m, most preferably from 2 to 10 ⁇ m.
  • a silica type more particularly an amorphous silica having a average particle size ranging from 1 ⁇ m to 15 ⁇ m, most preferably from 2 to 10 ⁇ m.
  • non-colloidal silica types in ink jet receiver formulations is known for long time, e.g. from old references such as JP-A 55-051583, JP-A 56-000157, US-P 4,474,850 and DE 3410828.
  • a most useful commercial compound is the amorphous precipitated silica type SIPERNAT 570, trade name from Degussa Co. It is preferably present in the receiving layer in an amount ranging from 5 g/m 2 to 30 g/m 2 .
  • the pigment is dispersed into the binder solution by mechanically mixing for about 15 minutes. It is essential to the present invention that this binder is silanol modified polyvinyl alcohol. Most useful commercially available silanol modified polyvinyl alcohols can be found in the POVAL R polymer series, trade name of Kuraray Co., Japan.
  • the silanol modified polyvinyl alcohol has a silanol modification degree between 0.1% and 10% and a viscosity of a 4% aqueous solution between 1 and 25 mPa.s.
  • a silanol modified polyvinyl alcohol may be obtained via copolymerisation or by modification of the polyvinyl alcohol using silanes.
  • Copolymerisation of vinyl acetate with monomers like vinyltrimethoxysilane, methacroyloxypropyl trimethoxysilane, triisopropoxyvinylsilane, and methacrylamidopropyl triethoxysilane can result in useful precursor polymers.
  • the polyvinyl alcohol may also be modified using silanes.
  • Alkoxy silanes like ⁇ -3,4-epoxycyclohexylethyltriethoxysilane, ⁇ -glycidyloxypropyltrimethoxysilane or isocyanatopropyl triethoxysilane are suitable for this purpose.
  • Typical binders include hydroxyethyl cellulose; hydroxypropyl cellulose; hydroxyethylmethyl cellulose; hydroxypropyl methyl cellulose; hydroxybutylmethyl cellulose; methyl cellulose; sodium carboxymethyl cellulose; sodium carboxymethylhydroxethyl cellulose; water soluble ethylhydroxyethyl cellulose; cellulose sulfate; polyvinyl alcohol; vinylalcohol copolymers; polyvinyl acetate; polyvinylacetal; polyvinyl pyrrolidone; polyacrylamide; acrylamide/acrylic acid copolymer; styrene/acrylic acid copolymer; ethylene-vinylacetate copolymer; vinylmethyl ether/maleic acid copolymer; poly(2-acrylamido
  • the binder or binder mixture is preferably present in the receiving layer in a weight ratio from 30 % to 60 % to the total coating weight of the layer.
  • the third essential ingredient of the receiving layer according to the present invention is a film-forming polymer having a glass transition temperature (T g ) lower than 50 °C, more preferably lower than 20°C. It is added whilst stirring to the dispersion of the pigment in the binder.
  • T g glass transition temperature
  • Representative polymers obeying this definition include conjugated diene polymers such as styrene-butadiene copolymers and methyl methacrylate-butadiene copolymers, acrylic polymers, for example, homopolymers and copolymers of acrylic acid esters and methacrylic acid esters, vinyl polymers, e.g.
  • vinylester polymers for example, polyvinyl acetate, ethylene-vinyl acetate copolymers; vinylacetate-acrylate copolymers, vinylacetate-maleate copolymers; modification reaction products of the above-mentioned polymers and copolymers, for example, modified with a carboxyl and/or cationic groups; water-soluble or dispersible resins, for example, melamine-formaldehyde resins and urea-formaldehyde resins; water-insoluble adhesive resins, for example, maleic anhydride copolymer resins, polyacrylamide resins, polymethyl methacrylate resins, polyurethane resins, unsaturated polyester resins, polyvinyl butyral resins, and alkyd resins.
  • vinylester polymers for example, polyvinyl acetate, ethylene-vinyl acetate copolymers; vinylacetate-acrylate copolymers, vinylacetate-maleate copolymers; modification reaction products
  • the film-forming polymer is a latex.
  • the most preferred latices are copoly(styrene-butadiene) latices, (co)polyvinylester latices, and (co)polyacrylate latices.
  • latices include aqueous aliphatic urethane dispersions; vinylacetate, and copolymers, such as copoly(vinylacetate-butylmaleate), copoly(vinylacetate-acrylate), copoly(vinylacetate-ethylene), and vinylacetate-vinylidenechloride; and copoly(acrylonitrile-butadiene).
  • the film-forming polymer is incorporated in the ink-receiving layer in a preferred weight % range from 5 to 20%.
  • the total dry coating weight of the receiving layer is preferably comprised between 10 and 40 g/m 2 .
  • a cationic substance acting as mordant may be present in the ink receiving layer.
  • Such substances increase the capacity of the layer for fixing and holding the dye of the ink droplets.
  • a particularly suited compound is a poly(diallyldimethylammonium chloride) or, in short, a poly(dadmac). These compounds are commercially available from several companies, e.g. Aldrich, Calgon, Clariant, BASF and EKA Chemicals.
  • CYPRO 514/515/516, SUPERFLOC 507/521/567 cationic cellulose derivatives such as CELQUAT L-200, H-100, SC-240C, SC-230M, trade names of Starch & Chemical Co., and QUATRISOFT LM200, UCARE polymers JR125, JR400, LR400, JR30M, LR30M and UCARE polymer LK; trivalent aluminum, boron, and zirconium ions; polyethyleneimine and copolymers, e.g. LUPASOL, trade name of BASF AG; triethanolamine-titanium-chelate, e.g.
  • TYZOR trade name of Du Pont Co.
  • copolymers of vinylpyrrolidone such as VIVIPRINT 111, trade name of ISP, a methacrylamido propyl dimethylamine copolymer; with dimethylaminoethylmethacrylate such as COPOLYMER 845 and COPOLYMER 937, trade names of ISP
  • vinylimidazole e.g.
  • LUVIQUAT CARE, LUVITEC 73W, LUVITEC VPI55 K18P, LUVITEC VP155 K72W, LUVIQUAT FC905, LUVIQUAT FC550, LUVIQUAT HM522, and SOKALAN HP56 all trade names of BASF AG; polyamidoamines, e.g. RETAMINOL and NADAVIN, trade marks of Bayer AG; and phosphonium compounds such as disclosed in EP 609930.
  • the cationic substance is not incorporated in the ink receiving layer itself but in a separate thin top layer.
  • this layer is coated from an aqueous medium. Its dry coverage is preferably comprised between 0.5 and 5 g/m 2 .
  • an extra adhesive layer may be applied between the support and the ink receiving layer.
  • This layer is then coated from an aqueous medium containing any of the numerous known adhesive polymers.
  • the adhesive polymer is a styrene-butadiene latex, a vinylester latex or an acrylate latex, with an ethylacrylate-hydroxyethylmethacrylate copolymer being particularly preferred.
  • the dry coating weight of this undercoat layer when present is preferably comprised between 0.5 and 10 g/m 2 .
  • the ink receiving layer and the optional top- and undercoat layers may further contain well-known conventional ingredi ⁇ nts, such as surfactants serving as coating aids, hardening agents plasticizers, whitening agents and matting agents.
  • Surfactants may be incorporated in the ink-receiving layer of the present invention. They can be any of the cationic, anionic, amphoteric, and nonionic ones as described in JP-A 62-280068 (1987).
  • the surfactants are N-alkylamino acid salts, alkylether carboxylic acid salts, acylated peptides, alkylsulfonic acid salts, alkylbenzene and alkylnaphthalene sulfonic acid salts, sulfosuccinic acid salts, ⁇ -olefin sulfonic acid salts, N-acylsulfonic acid salts, sulfonated oils, alkylsulfonic acid salts, alkylether sulfonic acid salts, alkylallylethersulfonic acid salts, alkylamidesulfonic acid salts, alkylphosphoric acid salts, alkyletherphosphoric acid salts, alkylally
  • These surfactants are commercially available from DuPont and 3M.
  • the concentration of the surfactant component in the ink-receiving layer is typically in the range of 0.1 to 2 %, preferably in the range of 0.4 to 1.5 % and is most preferably 0.75 % by weight based on the total dry weight of the layer.
  • the ink-receiving layer according to this invention is preferably crosslinked to provide such desired features as waterfastness and non-blocking characteristics.
  • the crosslinking is also useful in providing abrasion resistance and resistance to the formation of fingerprints on the element as a result of handling.
  • crosslinking agents also known as hardening agents - that will function to crosslink film forming materials, and they are commonly used in the photographic industry to harden gelatin emulsion layers and other layers of photographic silver halide elements.
  • Hardening agents can be used individually or in combination and in free or in blocked form.
  • a great many hardeners, useful for the present invention are known, including formaldehyde and free dialdehydes, such as succinaldehyde and glutaraldehyde, blocked dialdehydes, active esters, sulfonate esters, active halogen compounds, isocyanate or blocked isocyanates, polyfunctional isocyanates, melamine derivatives, s-triazines and diazines, epoxides, active olefins having two or more active bonds, carbodiimides, isoxazolium salts unsubsituted in the 3-position, esters of 2-alkoxy-N-carboxy-dihydroquinoline, N-carbamoylpyridinium salts, hardeners of mixed function, such as halogen-substituted aldehyde acids (e.g.
  • mucochloric and mucobromic acids onium substituted acroleins and vinyl sulfones and polymeric hardeners, such as dialdehyde starches and copoly(acroleinmethacrylic acid), and oxazoline functional polymers, e.g. EPOCROS WS-500, and EPOCROS K-1000 series.
  • Matting agents may be added such as polymethylmethacrylate beads. They are usually added to the receiving layer in a range of 0.4 to 1.2 g/m 2 and preferably in a range of 0.40 to 0.90 g/m 2 with 0.50 g/m 2 being most preferred.
  • the ink-receiving layer of the invention may contain a whitening agent.
  • TiO 2 rutile or anatase
  • the ink-receiving layer of the invention may contain a whitening agent.
  • the ink-receiving layer of the present invention may also comprise a plasticizer such as ethylene glycol, diethylene glycol, propylene glycol, polyethylene glycol, glycerol monomethylether, glycerol monochlorohydrin, ethylene carbonate, propylene carbonate, tetrachlorophthalic anhydride, tetrabromophthalicanhydride, urea phosphate, triphenylphosphate, glycerolmonostearate, propylene glycol monostearate, tetramethylene sulfone, n-methyl-2-pyrrolidone, n-vinyl-2-pyrrolidone.
  • a plasticizer such as ethylene glycol, diethylene glycol, propylene glycol, polyethylene glycol, glycerol monomethylether, glycerol monochlorohydrin, ethylene carbonate, propylene carbonate, tetrachlorophthalic anhydride, tetrabromo
  • the ink receiving layer and the optional supplementary layers can be coated onto the support by any conventional coating technique, such as dip coating, knife coating, extrusion coating, spin coating, slide hopper coating and curtain coating.
  • the support for use in the present invention is optionally opaque and can be chosen from polyethylene coated paper, polypropylene coated paper PVC with an adhesive backing, canvas and the polymeric type support well-known from photographic technology.
  • Polyester film supports and especially polyethylene terephthalate are preferred because of their excellent properties of dimensional stability.
  • a subbing layer must be employed to improve the bonding of the ink-receiving layer to the support.
  • Useful subbing layers for this purpose are well known in the photographic art and include, for example, polymers of vinylidene chloride such as vinylidene chloride /acrylonitrile /acrylic acid terpolymers or vinylidene chloride /methyl acrylate /itaconic acid terpolymers.
  • Typical supports for outdoor use include subbed PET, PVC with an adhesive backing and canvas.
  • silica type SIPERNAT 570 trade mark of Degussa Co., was added to solutions of the different polyvinyl alcohol types in amounts represented in table 2. Dispersions were prepared using a pendraulic dissolver for about 15 minutes.
  • the solution were prepared by adding 916 g of each dispersion to 84 g of the styrene-butadiene latex DL379, trade name of Dow Co. After addition of an anionic surfactant the solutions were coated on a subbed polyester base at a wet thickness of abour 120 ⁇ m.

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  • Ink Jet Recording Methods And Recording Media Thereof (AREA)
  • Ink Jet (AREA)

Claims (16)

  1. Élément d'enregistrement par jet d'encre comprenant un support et une couche de réception d'encre, ladite couche de réception d'encre comprenant (a) un pigment, (b) un alcool polyvinylique modifié par un groupe silanol, et (c) un polymère filmogène dont la température de transition vitreuse Tg est inférieure à 50 °C, caractérisé en ce que ledit support est choisi parmi le groupe constitué par des supports de type polymère bien connus dans la technologie photographique, du papier couché au polyéthylène, du papier couché au polypropylène, du PVC comprenant une couche dorsale adhésive, et un canevas.
  2. Élément d'enregistrement par jet d'encre selon la revendication 1, dans lequel ledit pigment est un pigment inorganique poreux.
  3. Élément d'enregistrement par jet d'encre selon la revendication 2, dans lequel ledit pigment inorganique poreux est une silice.
  4. Élément d'enregistrement par jet d'encre selon l'une quelconque des revendications 1 à 3, dans lequel ladite silice est une silice amorphe possédant une granulométrie moyenne entre 1 µm et 15 µm.
  5. Élément d'enregistrement par jet d'encre selon l'une quelconque des revendications 1 à 4, dans lequel ledit alcool polyvinylique modifié par un groupe silanol possède un degré de modification de type silanol entre 0,1 % et 10 % et une viscosité d'une solution aqueuse à 4 % entre 1 et 25 mPa.s.
  6. Élément d'enregistrement par jet d'encre selon l'une quelconque des revendications 1 à 5, dans lequel ledit polymère filmogène dont la température de transition vitreuse Tg est inférieure à 50 °C est un latex.
  7. Élément d'enregistrement par jet d'encre selon la revendication 6, dans lequel ledit latex est un latex constitué d'un copolymère de styrène-butadiène.
  8. Élément d'enregistrement par jet d'encre selon la revendication 6, dans lequel ledit latex est un latex à base d'acrylate.
  9. Élément d'enregistrement par jet d'encre selon l'une quelconque des revendications précédentes, dans lequel ladite couche de réception d'encre comprend en outre une substance cationique ou bien ladite couche de réception d'encre est recouverte d'une couche de recouvrement comprenant une substance cationique.
  10. Élément d'enregistrement par jet d'encre selon la revendication 9, dans lequel ladite substance cationique est un polymère de chlorure de diallyldiméthylammonium ou un copolymère de diméthylamine-épichlorhydrine.
  11. Élément d'enregistrement par jet d'encre selon l'une quelconque des revendications 1 à 10, dans lequel ledit élément comprend en outre une couche sous-jacente adhésive contenant un polymère adhésif entre ledit support et ladite couche de réception d'encre.
  12. Élément d'enregistrement par jet d'encre selon la revendication 11, dans lequel ledit polymère adhésif est un latex constitué d'un copolymère de styrène-butadiène.
  13. Élément d'enregistrement par jet d'encre selon la revendication 11, dans lequel ledit polymère adhésif est un latex à base d'acrylate.
  14. Élément d'enregistrement par jet d'encre selon la revendication 13, dans lequel ledit latex à base d'acrylate est un copolymère d'acrylate d'éthyle - méthacrylate d'hydroxyéthyle.
  15. Élément d'enregistrement par jet d'encre selon la revendication 11, dans lequel ledit polymère adhésif est un latex à base d'ester vinylique.
  16. Élément d'enregistrement par jet d'encre selon l'une quelconque des revendications 1 à 15, dans lequel ledit support est un support opaque.
EP01000012.3A 2000-02-22 2001-02-12 Matériau d'enregistrement par jet d'encre Expired - Lifetime EP1127706B2 (fr)

Priority Applications (2)

Application Number Priority Date Filing Date Title
DE60111587T DE60111587T3 (de) 2000-02-22 2001-02-12 Tintenstrahlaufzeichnungsmaterial
EP01000012.3A EP1127706B2 (fr) 2000-02-22 2001-02-12 Matériau d'enregistrement par jet d'encre

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
EP00200600 2000-02-22
EP00200600 2000-02-22
EP01000012.3A EP1127706B2 (fr) 2000-02-22 2001-02-12 Matériau d'enregistrement par jet d'encre

Publications (3)

Publication Number Publication Date
EP1127706A1 EP1127706A1 (fr) 2001-08-29
EP1127706B1 true EP1127706B1 (fr) 2005-06-22
EP1127706B2 EP1127706B2 (fr) 2013-10-02

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DE10232665C1 (de) * 2002-07-18 2003-10-02 Wacker Polymer Systems Gmbh Silan-modifizierte Polyvinylalkohol-Mischungen, Verfahren zu deren Herstellung, sowie deren Verwendung
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JP4510801B2 (ja) 2003-05-08 2010-07-28 ワッカー ケミー アクチエンゲゼルシャフト 粉末塗料組成物
DE102005054913A1 (de) 2005-11-17 2007-05-24 Wacker Polymer Systems Gmbh & Co. Kg Silan-modifizierte Polyvinylalkohole
JP5889909B2 (ja) 2010-10-25 2016-03-22 ヒューレット−パッカード デベロップメント カンパニー エル．ピー．Ｈｅｗｌｅｔｔ‐Ｐａｃｋａｒｄ Ｄｅｖｅｌｏｐｍｅｎｔ Ｃｏｍｐａｎｙ， Ｌ．Ｐ． ラテックスインク造膜助剤を含む印刷媒体
KR102573207B1 (ko) 2015-05-19 2023-08-31 코닝 인코포레이티드 시트와 캐리어의 결합을 위한 물품 및 방법
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