EP1104447B1 - Pigmentpräparation - Google Patents
Pigmentpräparation Download PDFInfo
- Publication number
- EP1104447B1 EP1104447B1 EP99927949A EP99927949A EP1104447B1 EP 1104447 B1 EP1104447 B1 EP 1104447B1 EP 99927949 A EP99927949 A EP 99927949A EP 99927949 A EP99927949 A EP 99927949A EP 1104447 B1 EP1104447 B1 EP 1104447B1
- Authority
- EP
- European Patent Office
- Prior art keywords
- pigment
- preparation according
- pigment preparation
- weight
- granules
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Revoked
Links
Classifications
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09C—TREATMENT OF INORGANIC MATERIALS, OTHER THAN FIBROUS FILLERS, TO ENHANCE THEIR PIGMENTING OR FILLING PROPERTIES ; PREPARATION OF CARBON BLACK ; PREPARATION OF INORGANIC MATERIALS WHICH ARE NO SINGLE CHEMICAL COMPOUNDS AND WHICH ARE MAINLY USED AS PIGMENTS OR FILLERS
- C09C3/00—Treatment in general of inorganic materials, other than fibrous fillers, to enhance their pigmenting or filling properties
- C09C3/04—Physical treatment, e.g. grinding, treatment with ultrasonic vibrations
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J3/00—Processes of treating or compounding macromolecular substances
- C08J3/20—Compounding polymers with additives, e.g. colouring
- C08J3/22—Compounding polymers with additives, e.g. colouring using masterbatch techniques
- C08J3/226—Compounding polymers with additives, e.g. colouring using masterbatch techniques using a polymer as a carrier
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/02—Printing inks
- C09D11/03—Printing inks characterised by features other than the chemical nature of the binder
- C09D11/037—Printing inks characterised by features other than the chemical nature of the binder characterised by the pigment
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D17/00—Pigment pastes, e.g. for mixing in paints
- C09D17/004—Pigment pastes, e.g. for mixing in paints containing an inorganic pigment
- C09D17/007—Metal oxide
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/36—Pearl essence, e.g. coatings containing platelet-like pigments for pearl lustre
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2471/00—Characterised by the use of polyethers obtained by reactions forming an ether link in the main chain; Derivatives of such polymers
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/29—Coated or structually defined flake, particle, cell, strand, strand portion, rod, filament, macroscopic fiber or mass thereof
- Y10T428/2982—Particulate matter [e.g., sphere, flake, etc.]
- Y10T428/2991—Coated
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/29—Coated or structually defined flake, particle, cell, strand, strand portion, rod, filament, macroscopic fiber or mass thereof
- Y10T428/2982—Particulate matter [e.g., sphere, flake, etc.]
- Y10T428/2991—Coated
- Y10T428/2993—Silicic or refractory material containing [e.g., tungsten oxide, glass, cement, etc.]
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/29—Coated or structually defined flake, particle, cell, strand, strand portion, rod, filament, macroscopic fiber or mass thereof
- Y10T428/2982—Particulate matter [e.g., sphere, flake, etc.]
- Y10T428/2991—Coated
- Y10T428/2998—Coated including synthetic resin or polymer
Definitions
- the invention relates to a non-dusting, homogeneous pigment preparation, and their use as precursors for printing inks.
- pigments are often not considered dry powders used as these dust, resulting in increased requirements in terms leads to job security. Furthermore, in the introduction of Powders in plastics, basecoat systems, etc. often an agglomeration of the pigment powder. A homogeneous distribution of the pigment in the respective matrix is often difficult or even impossible to reach.
- the components of the preparation / paste should be chosen that the preparation as well as possible on the other components of the is coordinated with each coating system and after the Introduction slightly homogeneously distributed.
- pigment preparations In addition to a good compatibility with the other components of the Coating system, pigment preparations must have high stability that is, they must not be prone to phase separation. These Demand is particularly important on pigment granules based platelet-shaped pigments, since these due to their structure in the Phase separation tend to "cake up" and only with difficulty can be stirred. Pigments based on platelet-shaped Substrates are problematic in terms of handling, as the pigments due to their size and density settle easily and then can cake to a very firm sediment cake. This Cake is usually difficult to re-stir. This is especially true in the storage of paints, inks and printing inks, as well as in the Processing the same.
- the object of the present invention was therefore to provide a pigment preparation, in particular in the form of pastes and Dry preparations that work very well in aqueous coating systems can be used, has high stability, easily redispersed leaves and at the same time by a high compatibility with the other components of the coating system.
- the pigment preparation of the invention should also for the production of Dry preparations, e.g. in the form of pellets, granules, etc., well suited be.
- the preparation according to the invention is dependent on the moisture content a flowable paste or a moistened, free-flowing powder. Both are very good for the preparation of dry preparations, e.g. Pellets, granules, Briquettes, suitable.
- the from the pigment preparation of the invention Prepared dry preparations are also the subject of Invention.
- effect pigments such as aluminum flakes, eg Stapa-Alupaste® or standard from BASF, Paliochrom® from BASF, platelet-shaped iron oxide, BiOCl, holographic pigments and pigments based on platelet-shaped, transparent or semitransparent substrates of, for example, sheet silicates
- effect pigments such as mica, synthetic mica, SiO 2 flakes, TiO 2 flakes, Al 2 O 3 flakes, glass flakes, graphite flakes, talc, sericite, kaolin, or other siliceous materials used with colored or colorless metal oxides such as As TiO 2 , titanium suboxides, Titanoxinitride, Fe 2 O 3 , Fe 3 O 4 , SnO 2 , Cr 2 O 3 , ZnO, CuO, NiO and other metal oxides alone or in admixture in a uniform layer or in successive layers (multilayer pigments) are coated.
- Pearlescent pigments are known, for example, from German patents and patent applications 14 67 468, 19 59 998, 20 09 566, 22 14 454, 22 15 191, 22 44 298, 23 13 331, 25 22 572, 31 37 808, 31 37 809, 31 51 343, 31 51 354, 31 51 355, 32 11 602, 32 35 017 and P 38 42 330 known and commercially available, for example under the trade name Iriodin® Fa. Merck KGaA, Darmstadt, Germany.
- Particularly preferred pigment granules contain TiO 2 / mica, Fe 2 O 3 / mica and / or TiO 2 / Fe 2 O 3 mica pigments.
- the coating of the SiO 2 flakes can, for. Example, as described in WO 93/08237 (wet-chemical coating) or DE-OS 196 14 637 (CVD method).
- the pigment preparations of the invention may contain one or more effect pigments. In many cases, by using at least two different effect pigments special color and gloss effects can be achieved.
- Preferred pigment granules contain one or more effect pigments based on mica and / or SiO 2 flakes. It is also possible to admix conventional (organic or inorganic) colored pigments and carbon black and / or TiO 2 .
- the pigment preparation according to the invention preferably contains 50-95 % By weight of effect pigments, in particular 60-80% by weight. Most notably preferred are pigment granules containing effect pigments of more than 50% by weight.
- the pigment preparation according to the invention contains a polyalkylene glycol or a corresponding derivative in quantities from 0.5 to 60% by weight, preferably 5 to 40% by weight, in particular 10 to 30% by weight.
- All polyalkylene glycols known to the person skilled in the art or their Derivatives can be used. Particularly suitable are polyethylene glycol, Polypropylene glycol and their esters and ethers, as z. In “Encyclopedia of Polymer Science and Engineering", Wiley-Interscience Publication, John Wiley & Sons.
- hydroxyl-rich is often recommended Resins, e.g. Cellulose products such as carboxycellulose, ethers and esters, Polyvinyl alcohol, polysaccharides, polyvinyl acetate in quantities of 0-50% by weight. All known to the expert hydroxyl-rich Resins are suitable, especially those described in Karsten Lackrohstofftabellen, 8th edition 1987, to be mentioned.
- the pigment preparation of the invention a redispersing aid, preferably spherical particles, a polyacrylate or polymethacrylate or fibrous particles having a fiber length of 0.1-20 ⁇ m, in amounts of 0 to 10% by weight, preferably 0.05 up to 5% by weight, in particular 0.01 to 3% by weight, based on the pigment, contain.
- suitable Particles are in particular all synthetic fibers, e.g. made of polyethylene, polyacrylates, Polypropylene, polyamides, cellulose fibers, inorganic Fibers here preferably silicon compounds, glass fibers and in particular the condensation products of modified isocyanates and Mono- and diamines.
- Suitable spherical materials are in particular glass, wax or polymer hollow spheres of vinyl resins, nylon, silicone, epoxy resins, olefin resins, polystyrenes and inorganic materials such as TiO 2 , SiO 2 or ZrO 2 .
- Preference is given to using hollow spheres, and also solid spheres, having a particle size of 0.05 to 150 ⁇ m.
- Particular preference is given to using glass, wax or hollow polymer spheres in the pigment granules according to the invention.
- Spherical particles based on SiO 2 in a particle range of 3-10 ⁇ m are known, for example, as materials for high-pressure liquid chromatography and are marketed, for example, as LiChrospher® by Merck KGaA, Darmstadt, Germany. Such materials are preferably used in monodisperse form, ie with a particle size which is as uniform as possible. Such monodisperse spherical particles based on SiO 2 , TiO 2 and ZrO 2 are known . Monodisperse SiO 2 can be prepared, for example, according to DE 36 16 133. Glass hollow spheres are sold, for example, under the trade name Q-CEL by the company PQ Corporation, USA or Scotchlite by the company 3M, Frankfurt, Germany.
- the preparation may contain surface active substances, such as alkyl silanes, which may also contain another functional group, unsaturated or saturated fatty acids or fluorosurfactants.
- Suitable silane compounds are, for example, n-hexyldecyltriethoxysilane and n-octyldecyltriethoxysilane (Si 116 or Si 118 from Degussa AG, Frankfurt, FRG) and the corresponding fluoroalkylsilanes.
- the saturated and unsaturated fatty acids e.g. Caproic acid, caprylic acid, capric acid, Lauric, myristic, palmitic, stearic, oleic, Linoleic acid and fatty acid mixtures are used.
- the pigment preparation additionally contains in addition to the silane a surfactant or a fatty acid.
- a surfactant or a fatty acid for the surfactant reagent it can also be a mixture of silane, fatty acids and / or Tensides act.
- the pigment preparation can be from 0.1 to 5% by weight, preferably 0.2 to 3 wt.% And in particular 0.5 to 2 wt.% Of surface-active Substances based on the pigment.
- the pigment preparation of the invention may additionally be 0 to 40 % By weight of water or of an organic solvent or solvent mixture, preferably 5 to 35% by weight, in particular 10 to 30 Wt.%, Included.
- the solvent component in the pigment preparation according to the invention must be matched to the polyalkylene glycol used professionally become.
- Suitable solvents are z.
- Aromatic solvents e.g. Toluene, gasolines, mineral oils, Hydrocarbons, esters, long-chain amines, vegetable oils, monovalent aliphatic alcohols, such as those having 2 to 4 carbon atoms, e.g. Ethanol, butanol or isopropanol or ketones, e.g. Acetone or methyl ethyl ketone or glycol ethers, e.g.
- Propylene glycol monoethyl ether, or Diols e.g. Ethylene glycol and propylene glycol or polyether diols, aliphatic triols and tetrols having 2 to 6 carbon atoms, such as trimethylolethane, Trimethylolpropane, glycerol, 1,2,4-butanetriol, 1,2,6-hexanetriol and pentaerythritol, as well as all other solvents of other classes of compounds or the mixtures of the abovementioned solvents.
- solvents are used in karsts, lacquer raw material tables, 8th edition, 1987, are listed.
- the preparation of the pigment preparation according to the invention takes place in that to the effect pigment or effect pigment mixture, the Polyalkylene glycol and / or the polyalkylene glycol derivative, optionally Water, the redispersing agent and optionally further additives, be added simultaneously or in succession, and that these Mixture in a mixer, gently homogenized.
- the mixers are not critical, but especially come Dispermaten, Granuliermischer and paddle mixer in question.
- the pigment is initially charged and initially with stirring the solvent containing the polyalkylene glycol and optionally already the redispersant, pasted; subsequently, if appropriate the addition of another solution consisting of solvent, Additives and the Redispergiertosstoffs.
- the Drying temperature between 80 ° and 150 ° C may be.
- the pigment preparation according to the invention can during or after the Preparation of other conventional additives are added, such. pH controller, Defoamer, wetting agent, anti-settling agent, leveling agent, siccative or Thixotropic agents. These are common in the paint industry Excipients which in the pigment preparation according to the invention in a Amount of 0 to 10 wt.% May be included.
- the resulting pigment preparation according to the invention is a homogeneous powder or good flowable pastes with a relatively high content of effect pigments. Because of the particularly high Compatibility of the hydroxy resin is the pigment preparation according to the invention also well compatible with commercial systems.
- the preparation is characterized by the absence of dust, the good Dispersibility and redispersibility, high storage stability and a good processability and is thus conventional pigment preparations clearly superior.
- the flowable pigment preparation is very suitable for filling of tubes as well as for extruding.
- the pigment granules of the invention are extruded or in other ways known to those skilled in a compact Particle form compacted, z. B. by tableting, briquetting, pelleting, Granulating, spray granulating or extruding, and optionally then dried.
- pigment granules on plates or drums can be beneficial on a case-by-case basis with only a minimum of co-solvent or to use water.
- the used as starting material for this Pigment preparations are usually moistened powders, some of them may also already be granulated and with the further process step just how the desired defined particles are needed.
- the first produced by way of pressing through a perforated plate Additionally, particles may be subsequently pelletized or Granulierens be reshaped. A tableting or briquetting is done by pressing the paste in appropriate forms.
- the drying process usually takes place at temperatures of 20 ° C to 150 ° C and lasts between 0.5 and 4 h and may possibly be under reduced pressure.
- the dry preparation is optionally classified or comminuted.
- the granules thus obtained are also non-dusting and have particle sizes in the range of 0.1-150 mm, preferably 0.1-20 mm, in particular 0.1-2 mm.
- the storage and the Transport of dry preparations are less restricted and therefore very unproblematic.
- the dry preparations have the further advantage that they are loaded with little or no liquid and therefore one have increased stability and compatibility.
- the dry preparation may also be in the absence of water and / or Solvents are made by the resins and other components with the pigment under the influence of temperature to a flowable or flowable melt are processed and from it by dripping, Spinning or use in granulation plates or drums, Granules are produced.
- the pigment granules may also be added substances that decompose and accelerate or dissolve the pigment granules, z.
- substances that decompose and accelerate or dissolve the pigment granules, z As bulky spherical particles, such as hollow spheres, hemispheres or such Substances that dissolve very quickly in the application medium, or swelling and thus "blasting" the granules.
- dry preparations can be used in all binders known to those skilled in the art be incorporated for paints, inks and inks, in particular these are aqueous solvent-free (UV) as well as solvent-based systems.
- binders known to those skilled in the art be incorporated for paints, inks and inks, in particular these are aqueous solvent-free (UV) as well as solvent-based systems.
- UV aqueous solvent-free
- Binder resins Due to the good compatibility of the polyalkylene glycols or derivatives Binder resins come into question, as they are usually the colors and Paints are added, and e.g. in Karsten, Lackrohstofftabellen, 8th edition, 1987. As binders are all commonly suitable for printing inks binder or binder mixtures into consideration, e.g.
- the improved deagglomeration of dry preparations incorporated in a binder shows up already with low Amounts of spherical particles in the pigment granules. So already when using granules containing 0.5% by weight on spherical particles based on the dry pigment, the dissolution rate significantly increased and the stability of the ink faster achieved (viscosity / hue).
- the preparation according to the invention as a paste or as a dry granulate can be used for a variety of applications. It is preferred in Coating systems in the printing, in particular offset, Flexo and gravure printing, printing varnish and screen printing used.
- the granules as a precursor for coating compositions any substrate materials, for example metals such as iron, steel, Aluminum, copper, bronze, brass and metal foils but also metal-coated Surfaces of glass, ceramics and concrete, as well as on wood, e.g. Furniture, clay, textile, paper, packaging materials, e.g. Plastic containers Foils or cardboard, or too decorative on other materials and / or protective purposes.
- the invention thus also relates to the use of the pigment preparation, as a paste or dry preparation, in formulations like Paints, varnishes, printing inks and plastics.
- Polyethylene glycol 4000 (Merck KGaA), demineralized water and Iriodin® 123 (Merck) (TiO 2 / mica pigment particle size 5 to 20 microns from Merck KGaA) are homogeneously mixed in the mixing unit R02 (5 min., Composition as in experiment 1) and then continuously granulated on a plate granulator TR4. The resulting granules are dried in a fluidized bed and then classified on a sieve. This gives coarse material (> 2 mm) 7.25%, fine material (> 10 ⁇ m) 0.43% and good grain 92.75%. Coarse and fine grains can be returned to the process.
- the volume is reduced to about 1/3 of the original volume. This gives advantages in logistics (storage and shipping).
- the granules are well dosed compared to the powder, good free-flowing and not dusting. They can be incorporated in a comparable time and achieve in contrast to the powder mixture immediately a color balance (constant viscosity).
- the foaming behavior is optimal.
- the Saueressig proofs show a very good homogeneous print image significantly less structure compared to the use of the pigment powder shows.
- the printed sheets obtained have the required values for the Fastness, adhesion and abrasion resistance.
- Example 2 300 g of polyethylene glycol 2000 (Merck KGaA, Darmstadt), 300 g of demineralized water and 1000 g Iriodin® 100 (TiO 2 / mica pigment particle size 10-60 microns) homogeneously mixed, granulated, wet classified to upper limit and dried in a fluidized bed to a residual moisture content of 0.5%.
- the granules obtained are rapidly dissolvable in aqueous, solvent-free (UV) and solvent-containing binders and immediately gives a stable formulation with optimum pearlescent effect.
- the granules are not dusty and flow well.
- Example 2 2000 g of Stapa Offset 2000 silver (Fa. Eckart Maschinene, Princeth, a preparation in white spirit with a metal content of 63% by weight) with a solution of 70 g of polyethylene glycol 2000 (Merck KGaA) mixed in 70 g of methyl ethyl ketone, granulated and under Vacuum dried to a residual moisture content of 0.5%.
- the granules obtained is free-flowing and easy to dose and can be very well in solvent-containing and incorporate solvent-free (UV) ink systems.
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- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Inorganic Chemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Paints Or Removers (AREA)
- Inks, Pencil-Leads, Or Crayons (AREA)
- Pigments, Carbon Blacks, Or Wood Stains (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE19826624 | 1998-06-18 | ||
DE19826624A DE19826624A1 (de) | 1998-06-18 | 1998-06-18 | Pigmentpräparation |
PCT/EP1999/004016 WO1999065995A1 (de) | 1998-06-18 | 1999-06-11 | Pigmentpräparation |
Publications (2)
Publication Number | Publication Date |
---|---|
EP1104447A1 EP1104447A1 (de) | 2001-06-06 |
EP1104447B1 true EP1104447B1 (de) | 2005-05-11 |
Family
ID=7870943
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP99927949A Revoked EP1104447B1 (de) | 1998-06-18 | 1999-06-11 | Pigmentpräparation |
Country Status (15)
Country | Link |
---|---|
US (1) | US6547870B1 (zh) |
EP (1) | EP1104447B1 (zh) |
JP (2) | JP4482231B2 (zh) |
KR (1) | KR100699311B1 (zh) |
CN (1) | CN1163550C (zh) |
AU (1) | AU4511199A (zh) |
BR (1) | BR9911269A (zh) |
CA (1) | CA2335226A1 (zh) |
CZ (1) | CZ20004687A3 (zh) |
DE (2) | DE19826624A1 (zh) |
ES (1) | ES2243060T3 (zh) |
IN (1) | IN206175B (zh) |
MX (1) | MXPA00012585A (zh) |
TW (1) | TW467945B (zh) |
WO (1) | WO1999065995A1 (zh) |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE102007061701A1 (de) | 2007-12-19 | 2009-06-25 | Eckart Gmbh | Metalleffektpigmente, Verfahren zu deren Herstellung sowie Verwendung derselben und Pulverlack |
DE102008031901A1 (de) | 2008-07-08 | 2010-01-14 | Eckart Gmbh | Metalleffektpigmente, Verfahren zu deren Herstellung sowie Verwendung derselben und Pulverlack |
Families Citing this family (46)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE19826624A1 (de) * | 1998-06-18 | 1999-12-23 | Merck Patent Gmbh | Pigmentpräparation |
DE10046152A1 (de) * | 2000-09-15 | 2002-03-28 | Merck Patent Gmbh | Pigmentpräparation in Granulatform |
DE10002559B4 (de) * | 2000-01-21 | 2004-07-15 | Brockhues Gmbh & Co. Kg | Pigmentgranulat zur Einfärbung von Baustoffen und Verfahren zu dessen Herstellung |
JP2002012795A (ja) * | 2000-06-27 | 2002-01-15 | Kyodo Printing Co Ltd | 改質真珠光沢顔料の製造方法および該改質真珠光沢顔料を用いた光輝性塗料 |
DE10319483A1 (de) | 2003-04-30 | 2004-11-18 | Brockhues Gmbh & Co. Kg | Schnell zerfallendes Pigmentkonzentrat |
DE10344660A1 (de) * | 2003-09-25 | 2005-04-28 | Merck Patent Gmbh | Verkapselte Pigmente |
DE10350719A1 (de) * | 2003-10-30 | 2005-06-16 | Basf Coatings Ag | Effektpigmente enthaltende Pigmentpasten, Verfahren zu ihrer Herstellung und ihre Verwendung |
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US7590454B2 (en) * | 2004-03-12 | 2009-09-15 | Boston Scientific Neuromodulation Corporation | Modular stimulation lead network |
US20050203600A1 (en) | 2004-03-12 | 2005-09-15 | Scimed Life Systems, Inc. | Collapsible/expandable tubular electrode leads |
US7286879B2 (en) | 2004-07-16 | 2007-10-23 | Boston Scientific Scimed, Inc. | Method of stimulating fastigium nucleus to treat neurological disorders |
US7763359B2 (en) | 2004-08-30 | 2010-07-27 | Bunge Fertilizantes S.A. | Aluminum phosphate, polyphosphate and metaphosphate particles and their use as pigments in paints and method of making same |
BRPI0403713B1 (pt) | 2004-08-30 | 2021-01-12 | Universidade Estadual De Campinas - Unicamp | processo de fabricação de um pigmento branco baseado na síntese de partículas ocas de ortofosfato ou polifosfato de alumínio |
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-
1998
- 1998-06-18 DE DE19826624A patent/DE19826624A1/de not_active Withdrawn
-
1999
- 1999-06-11 EP EP99927949A patent/EP1104447B1/de not_active Revoked
- 1999-06-11 TW TW088109839A patent/TW467945B/zh not_active IP Right Cessation
- 1999-06-11 IN IN65KO2001 patent/IN206175B/en unknown
- 1999-06-11 CN CNB998073822A patent/CN1163550C/zh not_active Expired - Fee Related
- 1999-06-11 AU AU45111/99A patent/AU4511199A/en not_active Abandoned
- 1999-06-11 WO PCT/EP1999/004016 patent/WO1999065995A1/de active IP Right Grant
- 1999-06-11 US US09/719,479 patent/US6547870B1/en not_active Expired - Fee Related
- 1999-06-11 CZ CZ20004687A patent/CZ20004687A3/cs unknown
- 1999-06-11 BR BR9911269-8A patent/BR9911269A/pt not_active IP Right Cessation
- 1999-06-11 ES ES99927949T patent/ES2243060T3/es not_active Expired - Lifetime
- 1999-06-11 JP JP2000554807A patent/JP4482231B2/ja not_active Expired - Fee Related
- 1999-06-11 CA CA002335226A patent/CA2335226A1/en not_active Abandoned
- 1999-06-11 KR KR1020007014311A patent/KR100699311B1/ko not_active IP Right Cessation
- 1999-06-11 DE DE59912048T patent/DE59912048D1/de not_active Revoked
-
2000
- 2000-12-15 MX MXPA00012585 patent/MXPA00012585A/es unknown
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2008
- 2008-12-17 JP JP2008321563A patent/JP2009132930A/ja active Pending
Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
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DE102007061701A1 (de) | 2007-12-19 | 2009-06-25 | Eckart Gmbh | Metalleffektpigmente, Verfahren zu deren Herstellung sowie Verwendung derselben und Pulverlack |
DE102008031901A1 (de) | 2008-07-08 | 2010-01-14 | Eckart Gmbh | Metalleffektpigmente, Verfahren zu deren Herstellung sowie Verwendung derselben und Pulverlack |
US8304077B2 (en) | 2008-07-08 | 2012-11-06 | Eckart Gmbh | Metal effect pigments, method for the production and the use thereof and powder coating |
Also Published As
Publication number | Publication date |
---|---|
CA2335226A1 (en) | 1999-12-23 |
MXPA00012585A (es) | 2001-05-01 |
CZ20004687A3 (cs) | 2001-04-11 |
CN1163550C (zh) | 2004-08-25 |
US6547870B1 (en) | 2003-04-15 |
KR100699311B1 (ko) | 2007-03-23 |
EP1104447A1 (de) | 2001-06-06 |
TW467945B (en) | 2001-12-11 |
CN1305514A (zh) | 2001-07-25 |
DE19826624A1 (de) | 1999-12-23 |
DE59912048D1 (de) | 2005-06-16 |
JP2002518541A (ja) | 2002-06-25 |
ES2243060T3 (es) | 2005-11-16 |
IN2001KO00065A (zh) | 2006-02-03 |
BR9911269A (pt) | 2001-03-13 |
JP2009132930A (ja) | 2009-06-18 |
KR20010052938A (ko) | 2001-06-25 |
IN206175B (zh) | 2007-04-20 |
AU4511199A (en) | 2000-01-05 |
JP4482231B2 (ja) | 2010-06-16 |
WO1999065995A1 (de) | 1999-12-23 |
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