EP1102894A1 - Utilisation d'amidons modifies en tant qu'agents de retention dans la fabrication de papier - Google Patents

Utilisation d'amidons modifies en tant qu'agents de retention dans la fabrication de papier

Info

Publication number
EP1102894A1
EP1102894A1 EP99938266A EP99938266A EP1102894A1 EP 1102894 A1 EP1102894 A1 EP 1102894A1 EP 99938266 A EP99938266 A EP 99938266A EP 99938266 A EP99938266 A EP 99938266A EP 1102894 A1 EP1102894 A1 EP 1102894A1
Authority
EP
European Patent Office
Prior art keywords
starch
use according
units
weight
paper
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
EP99938266A
Other languages
German (de)
English (en)
Other versions
EP1102894B1 (fr
Inventor
Johann Schulte
Joachim Werres
Ulrich Fischer
Hans-Georg Hartan
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Stockhausen GmbH and Co KG
Original Assignee
Stockhausen GmbH and Co KG
Chemische Fabrik Stockhausen GmbH
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Stockhausen GmbH and Co KG, Chemische Fabrik Stockhausen GmbH filed Critical Stockhausen GmbH and Co KG
Publication of EP1102894A1 publication Critical patent/EP1102894A1/fr
Application granted granted Critical
Publication of EP1102894B1 publication Critical patent/EP1102894B1/fr
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • DTEXTILES; PAPER
    • D21PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21HPULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H21/00Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties
    • D21H21/06Paper forming aids
    • D21H21/10Retention agents or drainage improvers
    • DTEXTILES; PAPER
    • D21PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21HPULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H17/00Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
    • D21H17/20Macromolecular organic compounds
    • D21H17/21Macromolecular organic compounds of natural origin; Derivatives thereof
    • D21H17/24Polysaccharides
    • D21H17/28Starch
    • DTEXTILES; PAPER
    • D21PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21HPULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H17/00Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
    • D21H17/20Macromolecular organic compounds
    • D21H17/33Synthetic macromolecular compounds
    • D21H17/34Synthetic macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • D21H17/37Polymers of unsaturated acids or derivatives thereof, e.g. polyacrylates

Definitions

  • EP-A-0 703 314 and WO 97/04168 propose the use of special cationic amylopectin starches to improve retention with the optional use of colloidal silica, anionic polyacrylamides or bentonite.
  • EP-B-0 227465 describes a process for the production of paper in which, in complex sub-steps, first the fibrous material and, separately, the mineral filler with a synthetic polyelectrolyte each have the same charge and then the treated filler with a polymeric polyelectrolyte with opposite charge is treated.
  • EP-B-0 282 761, WO 96/05373 and WO 96/13525 describe the modification of starch with ionic, especially cationic, polyelectrolytes.
  • cationic polymers of diallyldimethylammonium chloride, N-vinylamine or N-vinylimidazoline are heated with native or already digested potato starch, while according to WO 96/05373 cationic polymers with preferably anionic starch and preferably according to WO 96/13525 are hydrolyzed , cationic polymers of N-vinylformamide, polyethyleneimines or polyalkylamines with starch of any kind are implemented.
  • These starch products like starches modified with copolymers of (meth) acrylamide and dialkylamioalkyl (meth) acrylamide, are only recommended as dry strength agents for papermaking.
  • modified starch which is obtained by digesting starch, starch derivatives and / or their degradation products in aqueous solution in the presence of at least one cationic polymer, built up from at least 20% by weight of polymerized di-alkylaminoalkyl (meth) acrylic acid amide -Units, which are present in protonated, preferably quaternized form, and with the addition of at least one particulate additive based on an inorganic mineral, obtained before, during or after digestion, as retention agents for pigments, inorganic fillers and fines in papermaking.
  • native starch such as potato starch, wheat starch, cereal flour, maize starch, tapioca starch, sago starch and starch with an increased hydrolysis content, rice starch, pea starch and / or their mixtures
  • starch degradation products in particular dextrins or oxidized starches, such as dialdehyde starch, starch derivatives, such as chemically modified derivatives Starches, especially anionic starches, such as carboxy starch and starch degraded by persulfate, anionic starch esters, such as.
  • anionic starch esters such as.
  • anionic starch esters such as.
  • N-containing starch ethers especially starches with primary or secondary amino or imino groups and tertiary amino groups, which are positively charged by protonation with acids and contain quaternized ammonium groups.
  • Cationic polymers used are homo- or copolymers of dialkylaminoalkyl (meth) acrylic acid amides which contain at least 20% by weight polymerized units of amides of (meth) acrylic acid and / or acrylic acid and preferably di-C 1 -C 2 -alkylamino-C 2 - Contain C 6 alkylamines, each of which is present in protonated or quaternized form.
  • Their manufacture is, for example, in EP-A-0 013416 or in EP-A-0 113 038, the corresponding
  • Such polymerized units are preferably derived from protonated or quaternized N-dialkyl-substituted (meth) acrylic acid amides, such as, for example, dimethylaminoethyl acrylamide or methacrylamide, dimethylaminopropyl acrylamide or methacrylamide, diethylaminopropyl acrylamide or methacrylamide, diethylaminoethyl acrylamide or methacrylamide, diethylaminomethyl acrylamide or methacrylamide and N ', N', dimethylamino-2,2-dimethylpropyl acrylamide or methacrylamide or mixtures thereof, which have been reacted with known quaternizing agents.
  • suitable quaternizing agents are dimethyl sulfate, diethyl sulfate, methyl chloride, ethyl chloride, preferably dimethyl sulfate or methyl chloride.
  • the copolymers can contain to a limited extent, preferably up to 10% by weight, sparingly water-soluble and / or water-insoluble, simply ethylenically unsaturated monomers, such as (meth) acrylic acid alkyl esters and vinyl acetate, provided the solubility of the copolymers is retained in water.
  • the polymers to be used according to the invention preferably have a molecular weight MG (g / mol) in the range from 1.0 ⁇ 10 5 to 40 ⁇ 10 6 , particularly preferably in the range from 2.0 ⁇ 10 6 to 15 ⁇ 10 6 and very particularly preferably from 5 x 10 6 to 15 x 10 6 .
  • the viscosity was determined using a 1% polymer solution in one
  • particulate additives based on inorganic minerals can also consist of clay, preferably swellable, silica, preferably silica sol and / or with aluminum-modified polysilicates, polyorthosilicic acid, with aluminum-modified polysilicates or polyorthosilicic acid, bentonite, titanium dioxide or talc.
  • clay preferably swellable, silica, preferably silica sol and / or with aluminum-modified polysilicates, polyorthosilicic acid, with aluminum-modified polysilicates or polyorthosilicic acid, bentonite, titanium dioxide or talc.
  • Bentonite, talc, titanium dioxide or silica sol is particularly preferably used.
  • additives based on inorganic minerals in amounts of 0.1 to 15% by weight, preferably 3 to 15% by weight, particularly preferably 5 to 13% by weight, based on the modified starch component, before the preparation of the modified starch components the starch digestion or during the starch digestion, preferably before the modifying reaction and the digestion with the cationic homo- or copolymer, results in a retention agent with improved effectiveness in the retention capacity of fillers and fines. ?
  • the aqueous dispersion of the starch component which has not yet been digested and used for the modification preferably has a content of 0.5 to 20% by weight, preferably 0.5 to 10% by weight and particularly preferably 2.0 to 10% by weight of the starch component .
  • the aqueous solution of the polyelectrolyte used for the modification has a content of 0.1 to 2.0% by weight, preferably 0.1 to 0.5% by weight and particularly preferably 0.1 to 0.3% by weight, of cationic homo - or copolymers.
  • the weight ratio of starch component to cationic polyelectrolyte in the modification is in the range from 4: 1 to 25: 1, preferably in the range from 10: 1 to 25: 1 and particularly preferably in the range from 14: 1 to 20: 1.
  • the retention agent according to the invention is added to the aqueous paper pulp dispersion in an amount of 0.1 to 10% by weight solids, preferably 0.5 to 5% by weight and particularly preferably 1.0 to 3% by weight, based on the dry matter or Pulp, added before the headbox of the paper machine, preferably as an aqueous solution with stirring. It is added to the aqueous dispersion, which already contains or has been added as fillers calcium carbonate, kaolin, aluminum silicate and oxide hydrates, satin white, talc, gypsum, barite, calcium silicate and lithopone, diatomaceous earth and synthetic, organic fillers from the recycling material.
  • the retention agent according to the invention is advantageously added to the material dispersion in the machine chest, before the vertical classifier and before or after the material pump before the sheet formation.
  • the retention agent according to the invention based on modified starch and inorganic additives achieves excellent retention of the fillers and surprisingly prevents the strength values from being impaired despite the increase in the filler and thus the ash content of the paper. This applies in particular to the use of paper pulp dispersions which contain or consist of portions of waste paper or wood pulps such as wood pulp and thermomechanical material (TMP).
  • a mixed water-soluble cationic polymer provided with different amounts of bentonite or with the addition of talc and heated to a temperature of 95 to 100 ° C.
  • no mineral was added. The mixture was held in this temperature range for 15 to 20 minutes, then cooled and used as a retention aid.
  • Copolymers of trimethylammonium propylacrylamide chloride and acrylamide with a quaternized monomer content of 70% by weight were used as water-soluble cationic polymers.
  • test sheets with a basis weight of approx. 100 g / m 2 were produced in the laboratory according to the Rapid Koethen method in accordance with DIN 54358 with the sheet forming device model 20-12 MC from Haage. The leaves were dried and overnight under normal conditions at 23 ° C and 50% rel. Humidity stored.
  • the total retention gives the ratio of the amount of dry substance used for paper production to that remaining in the finished paper Amount of substance again. This can be determined by weighing the respective quantities of substance.
  • the ash retention represents the ratio of the ash content of the (dry) amount of material used for paper production to the ash content of the finished paper. This is determined by determining the respective ash content.
  • the fines retention shows the ratio of the fines content of the (dry) amount of paper used for paper production to the fines content of the finished paper.
  • the corresponding fines content is determined using a Britt Dynamic Drainage Jar as follows:
  • the coarse fraction corresponds to the amount of fiber that is on the filter.

Landscapes

  • Paper (AREA)
  • Polysaccharides And Polysaccharide Derivatives (AREA)
EP99938266A 1998-07-17 1999-07-15 Utilisation d'amidons modifies en tant qu'agents de retention dans la fabrication de papier Expired - Lifetime EP1102894B1 (fr)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
DE19832241A DE19832241A1 (de) 1998-07-17 1998-07-17 Verwendung von modifizierten Stärkeprodukten als Retentionsmittel bei der Papierherstellung
DE19832241 1998-07-17
PCT/EP1999/005054 WO2000004229A1 (fr) 1998-07-17 1999-07-15 Utilisation d'amidons modifies en tant qu'agents de retention dans la fabrication de papier

Publications (2)

Publication Number Publication Date
EP1102894A1 true EP1102894A1 (fr) 2001-05-30
EP1102894B1 EP1102894B1 (fr) 2002-10-23

Family

ID=7874449

Family Applications (1)

Application Number Title Priority Date Filing Date
EP99938266A Expired - Lifetime EP1102894B1 (fr) 1998-07-17 1999-07-15 Utilisation d'amidons modifies en tant qu'agents de retention dans la fabrication de papier

Country Status (10)

Country Link
EP (1) EP1102894B1 (fr)
JP (1) JP2002520510A (fr)
CN (1) CN1309737A (fr)
AT (1) ATE226663T1 (fr)
AU (1) AU5283599A (fr)
BR (1) BR9912832A (fr)
CA (1) CA2336660A1 (fr)
DE (2) DE19832241A1 (fr)
NO (1) NO20010286L (fr)
WO (1) WO2000004229A1 (fr)

Families Citing this family (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP1176254A1 (fr) 2000-07-24 2002-01-30 The Dow Chemical Company Utilisation de dispersions d'amidon reticulé dans la fabrication du papier
DE10121418A1 (de) * 2001-05-02 2003-01-23 Stockhausen Chem Fab Gmbh Verfahren zur Herstellung von Faserformkörpern
JP4712322B2 (ja) * 2004-06-30 2011-06-29 日本製紙株式会社 印刷適性向上剤およびこれを塗布した紙
CN100572434C (zh) * 2007-06-05 2009-12-23 内江市春江纸业有限公司 一种改性淀粉组合物的制备方法
CN102852038A (zh) * 2012-09-24 2013-01-02 济南晨光纸业有限公司 一种提高彩色羊皮纸鲜艳度并有效防止掉色的方法
CN105964887A (zh) * 2016-06-22 2016-09-28 马鞍山市创诚铸造有限公司 一种以热塑性氧化淀粉改性动物胶作为粘接剂的高透气性型砂及其制备方法
CN107217528B (zh) * 2017-06-21 2018-06-29 合肥龙发包装有限公司 一种抗油脂食品包装纸
CN115818655B (zh) * 2022-11-01 2024-03-26 江西广源化工有限责任公司 一种片状滑石粉及其制备方法和在制备淋膜原纸中的应用

Family Cites Families (12)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4097427A (en) * 1977-02-14 1978-06-27 Nalco Chemical Company Cationization of starch utilizing alkali metal hydroxide, cationic water-soluble polymer and oxidant for improved wet end strength
FR2396831A1 (fr) * 1977-07-04 1979-02-02 Scholten Honig Research Nv Perfectionnement aux charges minerales utilisees dans la fabrication du papier et du carton
SE432951B (sv) * 1980-05-28 1984-04-30 Eka Ab Pappersprodukt innehallande cellulosafibrer och ett bindemedelssystem som omfattar kolloidal kiselsyra och katjonisk sterkelse samt forfarande for framstellning av pappersprodukten
GB8602121D0 (en) * 1986-01-29 1986-03-05 Allied Colloids Ltd Paper & paper board
US5185206A (en) * 1988-09-16 1993-02-09 E. I. Du Pont De Nemours And Company Polysilicate microgels as retention/drainage aids in papermaking
SE8903752D0 (sv) * 1989-11-09 1989-11-09 Eka Nobel Ab Foerfarande foer framstaellning av papper
GB9123683D0 (en) * 1991-11-07 1992-01-02 Sandoz Ltd Improvements in or relating to organic compounds
DE4438708A1 (de) * 1994-10-29 1996-05-02 Basf Ag Verfahren zur kationischen Modifizierung von Stärke und Verwendung der kationisch modifizierten Stärke
JPH09291103A (ja) * 1996-04-25 1997-11-11 Sanwa Kosan Kk 製紙用澱粉
DE19701523A1 (de) * 1997-01-17 1998-07-23 Basf Ag Polymermodifizierte anionische Stärke, Verfahren zu ihrer Herstellung und ihre Verwendung
DE19701524A1 (de) * 1997-01-17 1998-07-23 Basf Ag Polymermodifizierte Stärke, Verfahren zu ihrer Herstellung und ihre Verwendung
US5859128A (en) * 1997-10-30 1999-01-12 E. I. Du Pont De Nemours And Company Modified cationic starch composition for removing particles from aqueous dispersions

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
See references of WO0004229A1 *

Also Published As

Publication number Publication date
JP2002520510A (ja) 2002-07-09
BR9912832A (pt) 2001-05-02
NO20010286D0 (no) 2001-01-17
AU5283599A (en) 2000-02-07
WO2000004229A1 (fr) 2000-01-27
CA2336660A1 (fr) 2000-01-27
ATE226663T1 (de) 2002-11-15
EP1102894B1 (fr) 2002-10-23
NO20010286L (no) 2001-01-17
DE19832241A1 (de) 2000-01-27
CN1309737A (zh) 2001-08-22
DE59903194D1 (de) 2002-11-28

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