EP1100617B1 - Doppelmetallcyanid-katalysatoren für die herstellung von polyetherpolyolen - Google Patents

Doppelmetallcyanid-katalysatoren für die herstellung von polyetherpolyolen Download PDF

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Publication number
EP1100617B1
EP1100617B1 EP99941446A EP99941446A EP1100617B1 EP 1100617 B1 EP1100617 B1 EP 1100617B1 EP 99941446 A EP99941446 A EP 99941446A EP 99941446 A EP99941446 A EP 99941446A EP 1100617 B1 EP1100617 B1 EP 1100617B1
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Prior art keywords
catalyst
metal cyanide
dmc
iii
butanol
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EP99941446A
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German (de)
English (en)
French (fr)
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EP1100617A1 (de
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Pieter Ooms
Jörg Hofmann
Pramod Gupta
Walter Schäfer
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Covestro Deutschland AG
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Bayer MaterialScience AG
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    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G65/00Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule
    • C08G65/02Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring
    • C08G65/26Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring from cyclic ethers and other compounds
    • C08G65/2642Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring from cyclic ethers and other compounds characterised by the catalyst used
    • C08G65/2645Metals or compounds thereof, e.g. salts
    • C08G65/2663Metal cyanide catalysts, i.e. DMC's
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J27/00Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • B01J27/24Nitrogen compounds
    • B01J27/26Cyanides

Definitions

  • the invention relates to new double metal cyanide (DMC) catalysts for the Production of polyether polyols by polyaddition of alkylene oxides to active ones Starter compounds containing hydrogen atoms.
  • DMC double metal cyanide
  • Double metal cyanide (DMC) catalysts for the polyaddition of alkylene oxides to starter compounds having active hydrogen atoms are known (see, for example, US Pat. Nos. 3,440,109, 3,829,505, 3,941,849 and 5,158,922).
  • the use of these DMC catalysts for the production of polyether polyols leads in particular to a reduction in the proportion of monofunctional polyethers with terminal double bonds, so-called monools, compared to the conventional production of polyether polyols using alkali catalysts, such as alkali metal hydroxides.
  • the polyether polyols thus obtained can be processed into high-quality polyurethanes (eg elastomers, foams, coatings).
  • DMC catalysts are usually obtained by reacting an aqueous solution of a metal salt with the aqueous solution of a metal cyanide salt in the presence of an organic complex ligand, for example an ether.
  • an organic complex ligand for example an ether.
  • aqueous solutions of zinc chloride (in excess) and potassium hexacyanocobaltate are mixed and then dimethoxyethane (glyme) is added to the suspension formed.
  • an active catalyst of the general formula Zn 3 [Co (CN) 6 ] 2 • x ZnCl 2 • yH 2 O • z glyme obtained (see for example EP 700 949).
  • DMC catalysts From JP 4 145 123, US 5 470 813, EP 700 949, EP 743 093, EP 761 708 and WO 97/40086 are known DMC catalysts, which by using tert-butanol as organic complex ligand (alone or in combination with a polyether (EP 700 949, EP 761 708, WO 97/40086)) the proportion of monofunctional polyethers with terminal double bonds in the production of polyether polyols to reduce.
  • tert-butanol organic complex ligand
  • a polyether EP 700 949, EP 761 708, WO 97/40086
  • the use of these DMC catalysts Induction time in the polyaddition reaction of the alkylene oxides with corresponding ones Starter compounds reduced and the catalyst activity increased.
  • the object of the present invention was to further improve DMC catalysts for the polyaddition of alkylene oxides to corresponding starter compounds
  • DMC catalysts for the polyaddition of alkylene oxides to corresponding starter compounds
  • This is done by shortening the Alkoxylation times for an improved economy of the manufacturing process of polyether polyols.
  • the increased activity of the catalyst then used in such low concentrations (25 ppm or less) that the very complex separation of the catalyst from the product is no longer necessary is, and the product can be used directly for polyurethane production.
  • DMC catalysts which are known as an alkyl polyglycoside Contain complex ligands, greatly increased in the production of polyether polyol Possess activity.
  • water preferably 1 to 10% by weight and / or e) one or more water-soluble metal salts, preferably 5 to 25% by weight, of the formula (I) M (X) n from the Preparation of the double metal cyanide compounds a) may be included.
  • M is selected from the metals Zn (II), Fe (II), Ni (II), Mn (II), Co (II), Sn (II), Pb (II), Fe (III) , Mo (IV), Mo (VI), Al (III), V (V), V (IV), Sr (II), W (IV), W (VI), Cu (II) and Cr (III) , Zn (II), Fe (II), Co (II) and Ni (II) are particularly preferred.
  • X are the same or different, preferably the same and an anion, preferably selected from the group of halides, hydroxides, sulfates, carbonates, cyanates, thiocyanates, isocyanates, isothiocyanates, carboxylates, oxalates or nitrates.
  • the value for n is 1, 2, or 3.
  • the double metal cyanide compounds contained in the catalysts according to the invention a) are the reaction products of water-soluble metal salts and water soluble metal cyanide salts.
  • Water-soluble metal salts suitable for the preparation of double metal cyanide compounds a) preferably have the general formula (I) M (X) n , where M is selected from the metals Zn (II), Fe (II), Ni (II), Mn (II ), Co (II), Sn (II), Pb (II), Fe (III), Mo (IV), Mo (VI), Al (III), V (V), V (IV), Sr (II ), W (IV), W (VI), Cu (II) and Cr (III). Zn (II), Fe (II), Co (II) and Ni (II) are particularly preferred.
  • X are the same or different, preferably the same and an anion, preferably selected from the group of halides, hydroxides, sulfates, carbonates, cyanates, thiocyanates, isocyanates, isothiocyanates, carboxylates, oxalates or nitrates.
  • the value for n is 1, 2, or 3.
  • water-soluble metal salts examples include zinc chloride, zinc bromide, Zinc acetate, zinc acetylacetonate, zinc benzoate, zinc nitrate, iron (II) sulfate, iron (II) bromide, Iron (II) chloride, cobalt (II) chloride, cobalt (II) thiocyanate, nickel (II) chloride and nickel (II) nitrate. Mixtures of various water-soluble metal salts can also be used be used.
  • Water-soluble metal cyanide salts suitable for the preparation of double metal cyanide compounds a) preferably have the general formula (II) (Y) a M '(CN) b (A) c , where M' is selected from the metals Fe (II), Fe (III ), Co (II), Co (III), Cr (II), Cr (III), Mn (II), Mn (III), Ir (III), Ni (II), Rh (III), Ru (II ), V (IV) and V (V). M 'is particularly preferably selected from the metals Co (II), Co (III), Fe (II), Fe (III), Cr (III), Ir (III) and Ni (II).
  • the water-soluble metal cyanide salt can contain one or more of these metals.
  • Y are the same or different, preferably the same, and an alkali metal ion or an alkaline earth metal ion.
  • A are the same or different, preferably the same, and an anion selected from the group of halides, hydroxides, sulfates, carbonates, cyanates, thiocyanates, isocyanates, isothiocyanates, carboxylates, oxalates or nitrates.
  • Both a, and b and c are integers, the values for a, b and c being chosen so that the electroneutrality of the metal cyanide salt is given; a is preferably 1, 2, 3 or 4; b is preferably 4, 5 or 6; c preferably has the value 0.
  • suitable water-soluble metal cyanide salts are potassium hexacyanocobaltate (III), potassium hexacyanoferrate (II), potassium hexacyanoferrate (III), calcium hexacyanocobaltate (III) and lithium hexacyanocobaltate (III).
  • Preferred double metal cyanide compounds a) which are contained in the catalysts according to the invention are compounds of the general formula (III) M x [M ' x , (CN) y ] z , where M is as in formula (I) and M 'is as defined in formula (II), and x, x ', y and z are integers and are selected so that the electron neutrality of the double metal cyanide compound is given.
  • Suitable double metal cyanide compounds a) are zinc hexacyanocobaltate (III), Zinc hexacyanoiridate (III), zinc hexacyanoferrate (III) and cobalt (II) hexacyanocobaltate (III). Further examples of suitable double metal cyanide compounds are e.g. US 5 158 922 (column 8, lines 29-66). Particularly preferred Zinc hexacyanocobaltate (III) is used.
  • organic complex ligands contained in the DMC catalysts according to the invention b) are known in principle and are described in detail in the prior art (See e.g. US 5 158 922 in particular column 6, lines 9-65, US 3 404 109, US 3 829 505, US 3 941 849, EP 700 949, EP 761 708, JP 4 145 123, US 5 470 813, EP 743 093 and WO 97/40086).
  • Preferred organic complex ligands are water-soluble, organic compounds with heteroatoms, such as Oxygen, nitrogen, phosphorus or sulfur with the double metal cyanide compound a) Can form complexes. Suitable organic complex ligands are e.g.
  • organic complex ligands are water-soluble aliphatic alcohols, such as ethanol, isopropanol, n-butanol, iso-butanol, sec-butanol and tert-butanol. Tert-butanol is particularly preferred.
  • the organic complex ligand is generated either during the catalyst preparation added or immediately after the precipitation of the double metal cyanide compound a).
  • the organic complex ligand is usually used in excess.
  • the DMC catalysts according to the invention contain the double metal cyanide compounds a) in amounts of 20 to 90 wt .-%, preferably 25 to 80 wt .-%, based on the amount of the finished catalyst, and the organic complex ligands b) in amounts of 0.5 to 30, preferably 1 to 25 wt .-%, based on the amount of finished catalyst.
  • the DMC catalysts according to the invention usually contain 5 - 80 wt .-%, preferably 10 to 60 wt .-%, based on the amount of finished catalyst, on glycoside.
  • Glycosides suitable for the preparation of the catalysts according to the invention are composed of carbohydrates (sugars) and non-sugars (aglycons) in which the aglycon is bonded to the full acetal by an oxygen atom via a glycosidic bond with a hemiacetal carbon atom of the carbohydrate.
  • Suitable sugar components are monosaccharides such as glucose, galactose, mannose, fructose, arabinose, xylose or ribose, disaccharides such as sucrose or maltose and oligo- or polysaccharides such as starch.
  • Suitable non-sugar components are C 1 -C 30 -hydrocarbon radicals, such as aryl, aralkyl and alkyl radicals, preferably aralkyl and alkyl radicals, particularly preferably alkyl radicals having 1 to 30 carbon atoms.
  • Glycosides used are the so-called alkyl polyglycosides, which are usually obtained by reacting carbohydrates with alcohols such as methanol, ethanol, propanol and butanol or by transacetalizing short-chain alkyl glycosides with fatty alcohols with 8 to 20 C atoms in the presence of acids.
  • Alkyl polyglycosides with glucose as the repeating unit in the chain, with alkyl chain lengths of C 8 to C 16 and average degrees of polymerization between 1 and 2 are particularly preferred.
  • glycosides are generally well known, for example described in detail in "Kirk-Othmer, Encyclopedia of Chemical Technology", Volume 4, 4th edition, 1992, p. 916 ff .; “Römpp, Lexikon Chemie”, 10th edition, Stuttgart / New York, 1996; Angewandte Chemie 110, pp. 1394-1412 (1998).
  • the analysis of the catalyst composition is usually carried out using elemental analysis, Thermogravimetry or extractive removal of the alkyl polyglycoside portion with subsequent gravimetric determination.
  • the catalysts of the invention can be crystalline, semi-crystalline or amorphous his.
  • the crystallinity is usually analyzed by powder X-ray diffractometry.
  • the DMC catalysts according to the invention are usually produced in aqueous solution by reacting ⁇ ) metal salts, especially of formula (I) with metal cyanide salts, in particular of the formula (II) ⁇ ) of organic Complex ligands b) other than glycoside and ⁇ ) alkyl polyglycoside.
  • the aqueous solutions of the metal salt e.g. Zinc chloride, used in a stoichiometric excess (at least 50 mol% based on the metal cyanide salt)
  • the metal cyanide salt e.g. potassium hexacyanocobaltate
  • the organic complex ligand b) e.g. tert-butanol
  • the organic complex ligand b) can be in the aqueous solution of the metal salt and / or the metal cyanide salt, or it will be after precipitation the double metal cyanide compound a) suspension obtained immediately added. It has proven advantageous to use the aqueous solutions and the to mix organic complex ligands b) with vigorous stirring. The educated Suspension is then usually treated with the alkyl polyglycoside c). The Glycoside c) is preferred in a mixture with water and organic Complex ligands b) used.
  • the catalyst is then isolated from the suspension by known means Techniques such as centrifugation or filtration.
  • the isolated catalyst is then washed with an aqueous solution of the organic complex ligand b) washed (e.g. by resuspending and subsequent re-isolation by filtration or centrifugation).
  • an aqueous solution of the organic complex ligand b) washed e.g. by resuspending and subsequent re-isolation by filtration or centrifugation.
  • water-soluble by-products such as potassium chloride
  • the amount of the organic complex ligand b) is preferably in the aqueous Washing solution between 40 and 80 wt .-%, based on the total solution. It is also advantageous to add some alkyl polyglycoside, preferably in the aqueous washing solution Add range between 0.5 and 5 wt .-%, based on the total solution.
  • the washed catalyst is then, optionally after pulverization, at temperatures of generally 20-100 ° C and at pressures of in general Dried 0.1 mbar to normal pressure (1013 mbar).
  • Another object of the present invention is the use of the invention DMC catalysts in a process for the production of polyether polyols by polyaddition of alkylene oxides to active hydrogen atoms having starter connections.
  • Preferred alkylene oxides are ethylene oxide, propylene oxide, butylene oxide and their mixtures are used.
  • the structure of the polyether chains through Alkoxylation can e.g. only with a monomeric epoxy or also statistically or in blocks with 2 or 3 different monomers Epoxies are made. "Ullmann's Encyclopedia of Industrial Chemistry” English edition, 1992, volume A21, pages 670 - 671.
  • Starter compounds having active hydrogen atoms are preferred Compounds with molecular weights from 18 to 2000 and 1 to 8 Hydroxyl groups used. Examples include: ethylene glycol, Diethylene glycol, triethylene glycol, 1,2-propylene glycol, 1,4-butanediol, hexamethylene glycol, Bisphenol A, trimethylolpropane, glycerin, pentaerythritol, sorbitol, Cane sugar, degraded starch or water.
  • Such active hydrogen atoms are advantageously starter compounds used, e.g. by conventional alkali analysis from the aforementioned low molecular starters were produced and oligomeric alkoxylation products represent with molecular weights from 200 to 2000.
  • the polyaddition catalyzed by the catalysts of the invention Alkylene oxides are carried out on starter compounds having active hydrogen atoms generally at temperatures of 20 to 200 ° C, preferably in the range of 40 up to 180 ° C, particularly preferably at temperatures from 50 to 150 ° C.
  • the reaction can be carried out at total pressures from 0 to 20 bar.
  • the polyaddition can be in bulk or an inert, organic solvent such as toluene and / or THF.
  • the amount of solvent is usually 10 to 30 wt .-%, based on the amount of the polyether polyol to be produced.
  • the catalyst concentration is chosen so that under the given reaction conditions good mastery of the polyaddition reaction is possible.
  • the catalyst concentration is generally in the range from 0.0005% by weight 1% by weight, preferably in the range from 0.001% by weight to 0.1% by weight, particularly preferably in the range of 0.001 to 0.0025 wt .-%, based on the amount of to be produced Polyether polyol.
  • Polyether polyols are in the range from 500 to 100,000 g / mol, preferably in the range from 1000 to 50,000 g / mol, particularly preferably in the range from 2000 to 20000 g / mol.
  • the polyaddition can be continuous or discontinuous, e.g. in a batchoder be carried out in a semi-batch process.
  • the alkoxylation times are reduced by using the DMC catalysts according to the invention in polyether polyol production compared to previously known Typically, DMC catalysts with tert-butanol and starch as ligands 55-85% reduced.
  • the induction times in polyether polyol production are typically reduced by 25-50%. This leads to a reduction in the overall reaction time of polyether polyol production and thus to improved economy of the process.
  • the catalysts of the invention can because of their significantly increased Activity in very low concentrations (25 ppm and less, based on the amount of polyether polyol to be produced).
  • polyether polyols for Manufacture of polyurethanes used plastics handbook, vol. 7, polyurethanes, 3rd ed., 1993, pp. 25-32 and 57-67
  • polyether polyol can be based on removal of the catalyst the polyether polyol can be dispensed with, without the product qualities of obtained polyurethane are adversely affected.
  • a solution of 12.5 g (91.5 mmol) of zinc chloride in 20 ml of distilled water is added to a solution of 4 g (12 mmol) of potassium hexacyanocobaltate in 70 ml of distilled water with vigorous stirring (24000 rpm).
  • a mixture of 50 g of tert-butanol and 50 g of distilled water is added to the suspension formed and then stirred vigorously for 10 minutes (24,000 rpm).
  • a mixture of 1 g of a C 8-14 alkyl polyglucoside ®Glucopon 650 EC (Henkel), 1 g of tert-butanol and 100 g of distilled water is then added and the mixture is stirred for 3 minutes (1,000 rpm).
  • the solid is isolated by filtration, then stirred for 10 minutes with a mixture of 70 g of tert-butanol, 30 g of distilled water and 1 g of the above alkyl polyglucoside (10,000 rpm) and filtered again. Finally, the mixture is stirred again for 10 minutes with a mixture of 100 g of tert-butanol and 0.5 g of the above alkyl polyglucoside (10,000 rpm). After filtration, the catalyst is dried to constant weight at 50 ° C. and normal pressure.
  • Example 2 The procedure was as in Example 1, but the alkyl polyglycoside used was C 12-14 alkyl polyglucoside ®Glucopon 600 CS UP (Henkel) instead of the alkyl polyglucoside from Example 1.
  • Example 2 The procedure was as in Example 1, but the alkyl polyglycoside used was C 8-10 -alkyl polyglucoside ®Glucopon 215 CS UP (Henkel) instead of the alkyl polyglucoside from Example 1.
  • the solid will isolated by filtration, then 10 min with a mixture of 70 g of tert-butanol, 30 g of distilled water and 1 g of starch were stirred (10,000 rpm) and filtered again. Finally, another 10 minutes with a mixture of 100 g of tert-butanol and stirred 0.5 g of starch (10,000 rpm). After filtration, the catalyst becomes 50 ° C and normal pressure dried to constant weight.
  • the polyether polyols obtained were determined by determining the OH numbers and the double bond contents and characterized the viscosities.
  • the course of the reaction was based on time-conversion curves (propylene oxide consumption [g] vs. Response time [min]) followed. From the intersection of the tangent the steepest point of the time-sales curve with the extended baseline of the curve the induction time was determined.
  • Propoxylation times correspond to the period between catalyst activation (End of induction period) and end of propylene oxide metering.
  • the Total reaction time is the sum of induction and propoxylation time.
  • Example 9 shows that the new DMC catalysts according to the invention are due to their significantly increased activity in polyether polyol production in so little Concentrations can be used that a separation of the Catalyst from which the polyol can be dispensed with.

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EP99941446A 1998-07-31 1999-07-20 Doppelmetallcyanid-katalysatoren für die herstellung von polyetherpolyolen Expired - Lifetime EP1100617B1 (de)

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DE19834572 1998-07-31
DE19834572A DE19834572A1 (de) 1998-07-31 1998-07-31 Doppelmetallcyanid-Katalysatoren für die Herstellung von Polyetherpolyolen
PCT/EP1999/005149 WO2000007720A1 (de) 1998-07-31 1999-07-20 Doppelmetallcyanid-katalysatoren für die herstellung von polyetherpolyolen

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EP1100617B1 true EP1100617B1 (de) 2004-10-06

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US (1) US6391820B1 (pt)
EP (1) EP1100617B1 (pt)
JP (1) JP2002522566A (pt)
KR (1) KR100593770B1 (pt)
CN (1) CN1134300C (pt)
AT (1) ATE278464T1 (pt)
AU (1) AU5505899A (pt)
BR (1) BR9912607A (pt)
CA (1) CA2338698A1 (pt)
DE (2) DE19834572A1 (pt)
ES (1) ES2230882T3 (pt)
HK (1) HK1039913B (pt)
HU (1) HUP0102709A3 (pt)
ID (1) ID27157A (pt)
PT (1) PT1100617E (pt)
WO (1) WO2000007720A1 (pt)

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JP6227549B2 (ja) 2011-12-20 2017-11-08 バイエル・インテレクチュアル・プロパティ・ゲゼルシャフト・ミット・ベシュレンクテル・ハフツングBayer Intellectual Property GmbH ヒドロキシ−アミノポリマーおよびその製造方法
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US10766998B2 (en) 2017-11-21 2020-09-08 Covestro Llc Flexible polyurethane foams
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CN113195591B (zh) * 2018-12-21 2024-05-07 陶氏环球技术有限责任公司 聚醚聚合方法
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WO2000007720A1 (de) 2000-02-17
PT1100617E (pt) 2005-01-31
CN1311715A (zh) 2001-09-05
EP1100617A1 (de) 2001-05-23
KR100593770B1 (ko) 2006-06-30
BR9912607A (pt) 2001-05-02
CN1134300C (zh) 2004-01-14
HK1039913A1 (en) 2002-05-17
DE59910764D1 (de) 2004-11-11
CA2338698A1 (en) 2000-02-17
ES2230882T3 (es) 2005-05-01
HUP0102709A2 (hu) 2001-11-28
ID27157A (id) 2001-03-08
US6391820B1 (en) 2002-05-21
JP2002522566A (ja) 2002-07-23
AU5505899A (en) 2000-02-28
HUP0102709A3 (en) 2003-03-28
ATE278464T1 (de) 2004-10-15
DE19834572A1 (de) 2000-02-03
HK1039913B (zh) 2004-12-03
KR20010074789A (ko) 2001-08-09

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