EP1029974B1 - Sheathed synthetic fibre rope - Google Patents
Sheathed synthetic fibre rope Download PDFInfo
- Publication number
- EP1029974B1 EP1029974B1 EP00100815A EP00100815A EP1029974B1 EP 1029974 B1 EP1029974 B1 EP 1029974B1 EP 00100815 A EP00100815 A EP 00100815A EP 00100815 A EP00100815 A EP 00100815A EP 1029974 B1 EP1029974 B1 EP 1029974B1
- Authority
- EP
- European Patent Office
- Prior art keywords
- strands
- synthetic
- sheath
- fiber
- anchoring means
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 229920002994 synthetic fiber Polymers 0.000 title claims description 35
- 239000000835 fiber Substances 0.000 claims abstract description 12
- 239000000463 material Substances 0.000 claims abstract description 10
- 238000004519 manufacturing process Methods 0.000 claims abstract description 6
- 238000002844 melting Methods 0.000 claims abstract description 4
- 230000008018 melting Effects 0.000 claims abstract description 4
- 238000004873 anchoring Methods 0.000 claims description 46
- 239000012209 synthetic fiber Substances 0.000 claims description 34
- 229920006231 aramid fiber Polymers 0.000 claims description 23
- 238000000034 method Methods 0.000 claims description 8
- 239000004760 aramid Substances 0.000 claims description 7
- 229920003023 plastic Polymers 0.000 abstract description 2
- 239000004033 plastic Substances 0.000 abstract description 2
- 229920002635 polyurethane Polymers 0.000 description 14
- 239000004814 polyurethane Substances 0.000 description 14
- 229920006306 polyurethane fiber Polymers 0.000 description 6
- 230000008901 benefit Effects 0.000 description 5
- 238000010276 construction Methods 0.000 description 5
- 239000000853 adhesive Substances 0.000 description 3
- 230000001070 adhesive effect Effects 0.000 description 3
- 229920003235 aromatic polyamide Polymers 0.000 description 3
- 238000004026 adhesive bonding Methods 0.000 description 2
- 238000005452 bending Methods 0.000 description 2
- 239000003795 chemical substances by application Substances 0.000 description 2
- 238000010438 heat treatment Methods 0.000 description 2
- 238000005304 joining Methods 0.000 description 2
- 239000006223 plastic coating Substances 0.000 description 2
- 239000007921 spray Substances 0.000 description 2
- 229930091051 Arenine Natural products 0.000 description 1
- 229910000831 Steel Inorganic materials 0.000 description 1
- 239000004433 Thermoplastic polyurethane Substances 0.000 description 1
- 238000005299 abrasion Methods 0.000 description 1
- 239000011230 binding agent Substances 0.000 description 1
- 230000005540 biological transmission Effects 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 230000000052 comparative effect Effects 0.000 description 1
- 230000001447 compensatory effect Effects 0.000 description 1
- 230000000994 depressogenic effect Effects 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 238000005530 etching Methods 0.000 description 1
- 230000009969 flowable effect Effects 0.000 description 1
- 230000004927 fusion Effects 0.000 description 1
- 238000005065 mining Methods 0.000 description 1
- 230000006855 networking Effects 0.000 description 1
- 229920000728 polyester Polymers 0.000 description 1
- 238000002203 pretreatment Methods 0.000 description 1
- 238000007639 printing Methods 0.000 description 1
- 230000001681 protective effect Effects 0.000 description 1
- 238000009420 retrofitting Methods 0.000 description 1
- 239000010959 steel Substances 0.000 description 1
- 239000000758 substrate Substances 0.000 description 1
- 229920002803 thermoplastic polyurethane Polymers 0.000 description 1
- 238000003466 welding Methods 0.000 description 1
Images
Classifications
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- D—TEXTILES; PAPER
- D07—ROPES; CABLES OTHER THAN ELECTRIC
- D07B—ROPES OR CABLES IN GENERAL
- D07B1/00—Constructional features of ropes or cables
- D07B1/16—Ropes or cables with an enveloping sheathing or inlays of rubber or plastics
- D07B1/162—Ropes or cables with an enveloping sheathing or inlays of rubber or plastics characterised by a plastic or rubber enveloping sheathing
-
- D—TEXTILES; PAPER
- D07—ROPES; CABLES OTHER THAN ELECTRIC
- D07B—ROPES OR CABLES IN GENERAL
- D07B1/00—Constructional features of ropes or cables
- D07B1/02—Ropes built-up from fibrous or filamentary material, e.g. of vegetable origin, of animal origin, regenerated cellulose, plastics
- D07B1/025—Ropes built-up from fibrous or filamentary material, e.g. of vegetable origin, of animal origin, regenerated cellulose, plastics comprising high modulus, or high tenacity, polymer filaments or fibres, e.g. liquid-crystal polymers
-
- D—TEXTILES; PAPER
- D07—ROPES; CABLES OTHER THAN ELECTRIC
- D07B—ROPES OR CABLES IN GENERAL
- D07B1/00—Constructional features of ropes or cables
- D07B1/16—Ropes or cables with an enveloping sheathing or inlays of rubber or plastics
- D07B1/165—Ropes or cables with an enveloping sheathing or inlays of rubber or plastics characterised by a plastic or rubber inlay
-
- D—TEXTILES; PAPER
- D07—ROPES; CABLES OTHER THAN ELECTRIC
- D07B—ROPES OR CABLES IN GENERAL
- D07B1/00—Constructional features of ropes or cables
- D07B1/16—Ropes or cables with an enveloping sheathing or inlays of rubber or plastics
- D07B1/165—Ropes or cables with an enveloping sheathing or inlays of rubber or plastics characterised by a plastic or rubber inlay
- D07B1/167—Ropes or cables with an enveloping sheathing or inlays of rubber or plastics characterised by a plastic or rubber inlay having a predetermined shape
-
- D—TEXTILES; PAPER
- D07—ROPES; CABLES OTHER THAN ELECTRIC
- D07B—ROPES OR CABLES IN GENERAL
- D07B2201/00—Ropes or cables
- D07B2201/10—Rope or cable structures
- D07B2201/1028—Rope or cable structures characterised by the number of strands
- D07B2201/1036—Rope or cable structures characterised by the number of strands nine or more strands respectively forming multiple layers
-
- D—TEXTILES; PAPER
- D07—ROPES; CABLES OTHER THAN ELECTRIC
- D07B—ROPES OR CABLES IN GENERAL
- D07B2201/00—Ropes or cables
- D07B2201/20—Rope or cable components
- D07B2201/2001—Wires or filaments
- D07B2201/201—Wires or filaments characterised by a coating
- D07B2201/2012—Wires or filaments characterised by a coating comprising polymers
-
- D—TEXTILES; PAPER
- D07—ROPES; CABLES OTHER THAN ELECTRIC
- D07B—ROPES OR CABLES IN GENERAL
- D07B2201/00—Ropes or cables
- D07B2201/20—Rope or cable components
- D07B2201/2015—Strands
- D07B2201/2042—Strands characterised by a coating
- D07B2201/2044—Strands characterised by a coating comprising polymers
-
- D—TEXTILES; PAPER
- D07—ROPES; CABLES OTHER THAN ELECTRIC
- D07B—ROPES OR CABLES IN GENERAL
- D07B2201/00—Ropes or cables
- D07B2201/20—Rope or cable components
- D07B2201/2071—Spacers
- D07B2201/2074—Spacers in radial direction
-
- D—TEXTILES; PAPER
- D07—ROPES; CABLES OTHER THAN ELECTRIC
- D07B—ROPES OR CABLES IN GENERAL
- D07B2201/00—Ropes or cables
- D07B2201/20—Rope or cable components
- D07B2201/2083—Jackets or coverings
- D07B2201/2087—Jackets or coverings being of the coated type
-
- D—TEXTILES; PAPER
- D07—ROPES; CABLES OTHER THAN ELECTRIC
- D07B—ROPES OR CABLES IN GENERAL
- D07B2205/00—Rope or cable materials
- D07B2205/20—Organic high polymers
- D07B2205/2003—Thermoplastics
-
- D—TEXTILES; PAPER
- D07—ROPES; CABLES OTHER THAN ELECTRIC
- D07B—ROPES OR CABLES IN GENERAL
- D07B2205/00—Rope or cable materials
- D07B2205/20—Organic high polymers
- D07B2205/2046—Polyamides, e.g. nylons
- D07B2205/205—Aramides
-
- D—TEXTILES; PAPER
- D07—ROPES; CABLES OTHER THAN ELECTRIC
- D07B—ROPES OR CABLES IN GENERAL
- D07B2205/00—Rope or cable materials
- D07B2205/20—Organic high polymers
- D07B2205/2064—Polyurethane resins
-
- D—TEXTILES; PAPER
- D07—ROPES; CABLES OTHER THAN ELECTRIC
- D07B—ROPES OR CABLES IN GENERAL
- D07B2401/00—Aspects related to the problem to be solved or advantage
- D07B2401/20—Aspects related to the problem to be solved or advantage related to ropes or cables
- D07B2401/205—Avoiding relative movement of components
Definitions
- the invention relates to a sheathed synthetic fiber rope, preferably made of aromatic polyamide, according to the preamble of claim 1 and a method for its production the preamble of claim 8.
- Running ropes are in conveyor technology, especially at Elevators, in crane building and mining, an important strong stressed machine element. It is particularly complex Stress on driven or over rope pulleys deflected ropes, such as those used in elevator construction and can be used for cable cars. There are big ones Ropes are necessary and it is for energy reasons the demand for the smallest possible masses.
- high-strength Synthetic fiber ropes for example made from aromatic polyamides or aramids with highly oriented molecular chains meet these requirements better than steel cables.
- Such a sheathed synthetic fiber rope is known from EP 0 672 781 A1 has become known to the applicant.
- the strands lead to the bending of the rope on the Pulley or pulley under certain conditions Compensatory movements by leading to relative movements of the strands different strand layers can lead. These movements are the largest in the outermost strand layer and can especially if the drive torque is frictionally locked over the each over the wrap angle on the sheave adjacent rope sheath section is stamped on the rope cause the casing to lift off prematurely and Upsets forms.
- Such a change in rope construction is undesirable because it has a short lifespan Rope can lead.
- the invention has for its object a coated Synthetic fiber rope with a longer service life and a method for Manufacture to specify such.
- the advantages achieved by the invention are one permanent anchoring of the sheathing in the extreme Strand.
- the sheathing is according to the invention with Anchoring means connected above the structural Structure are anchored in the outermost strand layer.
- the Binding forces between the casing and the Anchoring means correspond in particular to one one-piece connection of the material strength of the Anchoring means and thus exceed conventional ones Adhesive forces many times over.
- the anchoring means and the casing made of weldable or vulcanizable materials educated.
- This choice of materials enables the Anchoring means and the sheathing without additional Binder.
- the joint is permanent, shows same material behavior as the joining partners themselves and comes as a one-piece formation of anchoring means and sheathing the same.
- The is particularly homogeneous Joining point when the anchoring means and the sheath are made identical material are formed.
- the present Uniform material parameters simplify connection with uniform molecular connection of the parts to be joined.
- the manufacture according to the invention is more encased Synthetic fiber ropes simple and with little adjustment conventional stranding machines.
- the inside of the rope is made in the outermost strand layer load-bearing fiber strands stranded with anchoring agents. Latter are then thermally or chemically pretreated before the Plastic coating is applied and go one molecular connection with the anchoring means.
- Apart from adjustment work is conventional Stranding machines retrofitting a pre-treatment station already sufficient.
- the anchoring means and the sheathing together welded is essentially a heater for Heating the anchoring means to provide it when Extrude the sheath into a permanent fusion of the cover with the anchoring means.
- Another preferred method variant provides that Vulcanize sheathing on the outermost strand layer. at this version is made using a suitable pretreatment station a substrate is applied to the anchoring means, which etches them and thus for molecular networking with the extruded casing prepared.
- the anchoring means are preferred Embodiment of the invention in the form of one or more Anchor strands formed, which together with load-bearing Aramid fiber strands are stranded to the outermost strand layer.
- the sheathing can be anchored by the number of the stranded wires stranded in the outer layer can be set. A particularly good form fit is at this embodiment achieved when the anchoring strands a smaller diameter than the load-bearing aramid fiber strands exhibit.
- the anchoring strand is in the circumferential direction each between two larger diameter aramid fiber strands pinched and thereby anchored in the strand layer.
- Prefabricated anchor strands can be used together with the Aramid fiber strands processed by the same stranding machine become.
- the anchoring means can also be in the form of Anchoring fibers can be formed, which with aramid fibers load-bearing strands for the outermost strand layer with each other are twisted and fixed.
- the anchoring fibers are in the outermost fiber layer of the strands are arranged and in turn in one piece with the subsequently extruded casing connected.
- With a variety of such anchoring fibers results there is a large total connection area between the sheathing and anchoring them, which strengthens the connection and again the rope life increases.
- the thin Anchoring fibers in a short time and with comparative low energy expenditure can be heated to the melting temperature, which is why this embodiment has advantages in continuous Extruding the rope sheath offers.
- the synthetic fiber rope according to the invention offers, for example Elevator systems benefits where there is one cabin frame in one Elevator shaft guided cabin with a counterweight combines. To lift and close the cabin and counterweight lower, the rope runs over a traction sheave by one Drive motor is driven. When running over the traction sheave takes place in the inventive synthetic fiber rope between the Rope sheath and the outermost strand layer no relative movement instead of.
- FIG. 1 shows a first embodiment of a Rope covered according to the invention 1.
- the rope 1 is constructed from a core strand 2, around which in a first lay direction 3 five identical synthetic fiber strands 4 of a first strand layer 5 are helical, and with which ten Synthetic fiber strands 4, 6 a second strand layer 7 in Parallel strike under a balanced ratio between Fiber and strand lay twist are stranded.
- the number of stranded strands can meet the respective requirements be chosen accordingly differently and is not on that of this embodiment set.
- For the rope 1 load-bearing synthetic fiber strands 2,4,6,9 are used individual aramid fibers twisted or beaten and with a die Aramid fiber protective impregnating agent, for example treated with polyurethane solution.
- the intermediate sheath 12 is immediately before the stranding outermost strand layer 11 extruded onto the rope core 8. He prevents contact between the outermost strand layer 11 and the second strand layer 7 and thus wear the Synthetic fiber strands 4, 6 and 9 by rubbing against each other when the rope 1 runs over the traction sheave and thereby Relative movement of the synthetic fiber strands 4, 6, 9 among themselves.
- the intermediate jacket 12 serves the inner Torque transmission between rope core 8 and outermost Strand layer 11.
- the outermost strand layer 11 is in the first lay direction 3 stranded opposite second lay direction 10. She builds under longitudinal load of the rope 1 to that of parallel stranded rope core 8 oppositely directed Torque on.
- a sheath 14 made of polyurethane envelops the outermost one Strand layer 11 and ensures the desired coefficient of friction Traction sheave. Furthermore, the polyurethane is so resistant to abrasion that no damage when the rope 1 runs over the traction sheave occur.
- the casing 14 is in one piece with Anchoring strands 13 made of polyurethane, for example Welding, vulcanizing or bonding.
- the Anchor strands 13 are form-fitting in the outermost one Strand layer 11 anchored. For example, here are nine of them Polyurethane strands 13 alternating with nine aramid fiber strands 9, in each case between two adjacent aramid fiber strands 9 stranded together to form the outermost strand layer 11.
- the aramid fiber strands 9 and Polyurethane strands 13 shown the same thickness, but can Form fit of the polyurethane strands 13 with the outermost Strand layer 11 can be further improved if the Polyurethane strands 13 are thinner than the aramid fiber strands 9.
- the thinner polyurethane strands 13 are in the circumferential direction between the adjacent larger diameter aramid fiber strands 9 clamped and in the radial direction on the Intermediate jacket 12 depressed.
- the casing 14 is passed to the outermost Strand layer 11 extruded. With the spray printing process, this is flowable plastic material in all gaps of the Surface of the outermost strand layer, so that a large adhesive surface is formed.
- the polyurethane strands 13 Before extruding the Sheathing 14, the polyurethane strands 13 on Melting temperature heated so that when extruding the Jacket 14 and the polyurethane strands 13 together be welded.
- the permanent created by it one-piece connection gives the casing 14 permanent fastening on the high-strength rope 1 over the improved form locking of the polyurethane strands with the outermost strand layer 11.
- FIG. 2 shows one Cross-sectional view of a second embodiment of a according to the invention sheathed rope 20.
- the rope core 21 and the Intermediate jacket 22 firmly adhering to it correspond with regard to function and structure corresponding parts of the First embodiment described above.
- On the Cable sheath 22 is an outermost strand layer 23 from seventeen Aramid fiber strands 24 stranded.
- Each individual aramid fiber strand 24 is made with a separate, all-round wrapping 25 Provided with polyurethane.
- the so far described Aramid fiber rope 20 is covered with a sheath 26.
- the Sheath 26 is made like sheath 25 of aramid fiber strands 24 made of thermoplastic polyurethane and is in one piece along the respective outer surface of the Cover 25 welded to the cover strand layer 23. About these permanent molecular connections is the sheath 26 positively connected to the aramid fiber strand 24. Also at In this embodiment, anchoring means are first in Form of the envelope 25 in the rope structure form-fitting anchored and immediately prior to extruding the sheath 26 by heating, gluing or etching or vulcanizing permanently connected to the casing 26.
- FIG 3 is a third embodiment of the invention an aramid fiber rope 30 is shown.
- the construction of the rope core 31, the this enveloping intermediate jacket 32 and the number of Synthetic fiber strands 33 of the outermost strand layer 34 are again same as for the two described above Embodiments.
- a cable sheath 37 surrounds the outermost one Strand 34 with which he is positively connected.
- Polyurethane fibers 35 are in the outermost fiber layer together with aramid fibers 36 arranged, i.e. on the outer surface of the jacket Synthetic fiber strands 33. Since the synthetic fiber strands 33 are wound helically around the intermediate jacket 32, it is ensured that the polyurethane fibers 35 at least in sections on the one adjacent to the casing 37 Surface come to rest.
- the polyurethane fibers 35 are just before extruding the jacket 37 and heated merge with the tightly pressed casing 37. As The polyurethane fibers are part of the synthetic fiber strands 33 35 form-fitting with the strand structure of the outermost Strand layer 34 connected. Consequently, it is also in one piece the sheath 37 connected to the polyurethane fibers 35 via a A large number of such polyurethane fibers 35 via this positive connection permanently anchored to the aramid fibers 36.
- the described embodiments of the invention can also can be combined with each other to create a desired one Form fixation of the jacket.
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- Chemical & Material Sciences (AREA)
- Crystallography & Structural Chemistry (AREA)
- Ropes Or Cables (AREA)
- Lift-Guide Devices, And Elevator Ropes And Cables (AREA)
Abstract
Description
Die Erfindung betrifft ein ummanteltes Kunstfaserseil ,
vorzugsweise aus aromatischem Polyamid, nach dem Oberbegriff
des Anspruchs 1 und ein Verfahren zu dessen Herstellung nach
dem Oberbegriff des Anspruchs 8.The invention relates to a sheathed synthetic fiber rope,
preferably made of aromatic polyamide, according to the preamble
of
Laufende Seile sind in der Fördertechnik, insbesondere bei Aufzügen, im Kranbau und im Bergbau, ein wichtiges stark beanspruchtes Maschinenelement. Besonders vielschichtig ist die Beanspruchung von getriebenen oder von über Seilrollen umgelenkten Seilen, wie sie beispielsweise im Aufzugsbau und bei Kabinenseilbahnen verwendet werden. Dort sind grosse Seillängen notwendig und es besteht aus energetischen Gründen die Forderung nach möglichst kleinen Massen. Hochfeste Kunstfaserseile, beispielsweise aus aromatischen Polyamiden oder Aramiden mit hochgradig orientierten Molekülketten erfüllen diese Anforderungen besser als Stahlseile.Running ropes are in conveyor technology, especially at Elevators, in crane building and mining, an important strong stressed machine element. It is particularly complex Stress on driven or over rope pulleys deflected ropes, such as those used in elevator construction and can be used for cable cars. There are big ones Ropes are necessary and it is for energy reasons the demand for the smallest possible masses. high-strength Synthetic fiber ropes, for example made from aromatic polyamides or aramids with highly oriented molecular chains meet these requirements better than steel cables.
Ein solches ummanteltes Kunstfaserseil ist aus der EP 0 672 781 A1 der Anmelderin bekannt geworden. Dort ist die Kunststoffummantelung im Druckspritzverfahren so aufgebracht, dass eine grosse Haltefläche zu den Litzen hin gebildet wird. Allerdings führen die Litzen bei der Biegung des Seils auf der Seilscheibe oder einer Seilrolle unter bestimmten Bedingungen Ausgleichsbewegungen durch, die zu Relativbewegungen der Litzen unterschiedlicher Litzenlagen führen können. Diese Bewegungen sind in der äussersten Litzenlage am grössten und können besonders wenn das Antriebsmoment unter Reibschluss über den jeweils über den Umschlingungswinkel auf der Seilscheibe anliegenden Seilmantelabschnitt dem Seil aufgeprägt wird, dazu führen, dass sich die Ummantelung vorzeitig abhebt und Aufstauchungen bildet. Eine solche Veränderung des Seilaufbaus ist unerwünscht, weil sie zu einer geringen Lebensdauer des Seils führen kann. Dasselbe trifft für auf Trommeln aufgewickelte Seile, wie sie im Aufzugsbau verwendet werden zu. Such a sheathed synthetic fiber rope is known from EP 0 672 781 A1 has become known to the applicant. There is the Plastic coating applied in a pressure spray process so that a large holding surface is formed towards the strands. However, the strands lead to the bending of the rope on the Pulley or pulley under certain conditions Compensatory movements by leading to relative movements of the strands different strand layers can lead. These movements are the largest in the outermost strand layer and can especially if the drive torque is frictionally locked over the each over the wrap angle on the sheave adjacent rope sheath section is stamped on the rope cause the casing to lift off prematurely and Upsets forms. Such a change in rope construction is undesirable because it has a short lifespan Rope can lead. The same applies to drums coiled ropes as used in elevator construction.
Der Erfindung liegt die Aufgabe zugrunde, ein ummanteltes Kunstfaserseil mit höherer Lebensdauer sowie ein Verfahren zur Herstellung eines solchen anzugeben.The invention has for its object a coated Synthetic fiber rope with a longer service life and a method for Manufacture to specify such.
Diese Aufgabe wird erfindungsgemäss durch ein Kunstfaserseil mit
den im Anspruch 1 angegebenen Merkmalen gelöst. Eine Lösung zur
Herstellung eines Kunstfaserseils ist durch die Merkmale des
Anspruchs 8 gegeben.According to the invention, this object is achieved with a synthetic fiber rope
solved the features specified in
Die durch die Erfindung erzielten Vorteile bestehen in einer dauerhaften Verankerung der Ummantelung in der äussersten Litzenlage. Zusätzlich zu der bisherigen haftenden Bindung auf einer möglichst grossen Kontaktfläche der äussersten Litzenlage, ist die Ummantelung erfindungsgemäss mit Verankerungsmitteln verbunden, welche über den strukturellen Aufbau in der äussersten Litzenlage verankert sind. Die Bindekräfte zwischen der Ummantelung und den Verankerungsmitteln entsprechen insbesondere bei einer einstückigen Anbindung der Materialfestigkeit der Verankerungsmittel und übersteigen damit herkömmliche Haftkräfte um ein Vielfaches. Sind die Verankerungsmittel formschlüssig mit der äussersten Litzenlage verbunden, dann ist ein Ablösen der Ummantelung gar nur unter Beschädigung der Aramidfaserlitzen möglich.The advantages achieved by the invention are one permanent anchoring of the sheathing in the extreme Strand. In addition to the previous adhesive bond the largest possible contact area of the outermost Stranded layer, the sheathing is according to the invention with Anchoring means connected above the structural Structure are anchored in the outermost strand layer. The Binding forces between the casing and the Anchoring means correspond in particular to one one-piece connection of the material strength of the Anchoring means and thus exceed conventional ones Adhesive forces many times over. Are the anchoring means then positively connected to the outermost strand layer a detachment of the casing only with damage to the Aramid fiber strands possible.
Als weiterer Vorteil der Einbindung der Verankerungsmittel in die Seilstruktur der Aussenlitzenlage kombiniert mit der einstückigen Anbindung, beispielsweise durch Kleben, an die Ummantelung folgen die Verankerungsmittel der Bewegung bzw. der Verformung der äussersten Litzenlage beim Lauf des Seils über die Treibscheibe. Bei entsprechender Wahl eines Materials mit geeigneter elastischer Verformbarkeit können die in der Aramidfaserlage und die aufgrund der Biegebelastung in der Ummantelung wirkenden Kräfte wechselseitig vergleichmässigt werden und damit Relativbewegungen zwischen Ummantelung und Litzenlage verhindert werden.Another advantage of incorporating the anchoring means in the rope structure of the outer strand layer combined with the one-piece connection, for example by gluing, to the Sheathing the anchoring means follow the movement or the Deformation of the outermost strand layer when the rope runs over the traction sheave. With a corresponding choice of material with suitable elastic deformability can in the Aramid fiber layer and the due to the bending load in the Sheathing forces mutually equalized and thus relative movements between the casing and Strand position can be prevented.
In Weiterbildung der Erfindung sind die Verankerungsmittel und die Ummantelung aus schweiss- oder vulkanisierbaren Werkstoffen ausgebildet. Diese Werkstoffwahl ermöglicht ein Verbinden der Verankerungsmittel und der Ummantelung ohne zusätzliche Bindemittel. Gleichzeitig ist die Fügestelle dauerhaft, zeigt gleichartiges Materialverhalten, wie die Fügepartner selbst und kommt so einer einstückigen Ausbildung von Verankerungsmitteln und Ummantelung gleich. Besonders homogen gestaltet sich die Fügestelle, wenn die Verankerungsmittel und die Ummantelung aus identischem Material gebildet sind. Die dabei vorliegenden einheitlichen Materialparameter vereinfachen ein Verbinden mit gleichmässiger molekularer Verbindung der zu fügenden Teile.In a further development of the invention, the anchoring means and the casing made of weldable or vulcanizable materials educated. This choice of materials enables the Anchoring means and the sheathing without additional Binder. At the same time, the joint is permanent, shows same material behavior as the joining partners themselves and comes as a one-piece formation of anchoring means and sheathing the same. The is particularly homogeneous Joining point when the anchoring means and the sheath are made identical material are formed. The present Uniform material parameters simplify connection with uniform molecular connection of the parts to be joined.
Neben den mit der Erfindung erzielten funktionellen Vorteilen, gestaltet sich die Herstellung erfindungsgemäss ummantelter Kunstfaserseile einfach und mit geringfügiger Anpassung herkömmlicher Verseilmaschinen. Auf ein in bekannter Weise hergestelltes Seilinneres werden in der äussersten Litzenlage tragende Faserlitzen mit Verankerungsmitteln verseilt. Letztere werden dann thermisch oder chemisch vorbehandelt bevor die Kunststoffummantelung aufgebracht wird und gehen dabei eine molekulare Verbindung mit den Verankerungsmitteln ein. Abgesehen von Einstellarbeiten ist bei herkömmlichen Verseilmaschinen ein Nachrüsten einer Vorbehandlungsstation bereits ausreichend.In addition to the functional advantages achieved with the invention, the manufacture according to the invention is more encased Synthetic fiber ropes simple and with little adjustment conventional stranding machines. In a known way The inside of the rope is made in the outermost strand layer load-bearing fiber strands stranded with anchoring agents. Latter are then thermally or chemically pretreated before the Plastic coating is applied and go one molecular connection with the anchoring means. Apart from adjustment work is conventional Stranding machines retrofitting a pre-treatment station already sufficient.
Werden die Verankerungsmittel und die Ummantelung miteinander verschweisst, ist im wesentlichen eine Heizeinrichtung zum Erhitzen der Verankerungsmittel vorzusehen, damit es beim Extrudieren der Ummantelung zu einer dauerhaften Verschmelzung des Deckmantels mit den Verankerungsmittel kommt.The anchoring means and the sheathing together welded, is essentially a heater for Heating the anchoring means to provide it when Extrude the sheath into a permanent fusion of the cover with the anchoring means.
Eine weitere bevorzugte Verfahrensvariante sieht vor, die Ummantelung auf die äusserste Litzenlage zu vulkanisieren. Bei dieser Ausführung wird mittels geeigneter Vorbehandlungsstation ein Substrat auf die Verankerungsmittel aufgebracht, welches diese anäzt und so für ein molekulares Vernetzen mit der extrudierten Ummantelung vorbereitet.Another preferred method variant provides that Vulcanize sheathing on the outermost strand layer. at this version is made using a suitable pretreatment station a substrate is applied to the anchoring means, which etches them and thus for molecular networking with the extruded casing prepared.
Die Verankerungsmittel sind bei einer bevorzugten Ausführungsform der Erfindung in Form von einer oder mehreren Verankerungslitzen ausgebildet, welche zusammen mit tragenden Aramidfaserlitzen zu der äussersten Litzenlage verseilt sind. Durch das schraubenlinienförmige Umeinanderdrehen der Litzen ergibt sich bereits durch den gedrehten Seilaufbau auf einfache Weise ein Formschluss der Verankerungslitze in der äussersten Litzenlage. Die Verankerung der Ummantelung kann über die Anzahl der in der Aussenlage mitverseilten Verankerungslitzen eingestellt werden. Ein besonders guter Formschluss wird bei dieser Ausführungsform erreicht, wenn die Verankerungslitzen einen kleineren Durchmesser als die tragenden Aramidfaserlitzen aufweisen. Die Verankerungslitze wird in Umfangsrichtung jeweils zwischen zwei druchmessergrösseren Aramidfaserlitzen eingeklemmt und dadurch in der Litzenlage verankert. Vorgefertigte Verankerungslitzen können zusammen mit den Aramidfaserlitzen von derselben Verseilmaschine verarbeitet werden.The anchoring means are preferred Embodiment of the invention in the form of one or more Anchor strands formed, which together with load-bearing Aramid fiber strands are stranded to the outermost strand layer. By turning the strands helically around each other results from the twisted rope construction on simple Form a positive connection of the anchoring strand in the outermost Strand. The sheathing can be anchored by the number of the stranded wires stranded in the outer layer can be set. A particularly good form fit is at this embodiment achieved when the anchoring strands a smaller diameter than the load-bearing aramid fiber strands exhibit. The anchoring strand is in the circumferential direction each between two larger diameter aramid fiber strands pinched and thereby anchored in the strand layer. Prefabricated anchor strands can be used together with the Aramid fiber strands processed by the same stranding machine become.
Die Verankerungsmittel können ferner in Form von Verankerungsfasern ausgebildet sein, welche mit Aramidfasern zu tragenden Litzen für die äusserste Litzenlage miteinander verdreht und fixiert sind. Die Verankerungsfasern sind in der äussersten Faserlage der Litzen angeordnet und werden wiederum einstückig mit der nachträglich aufextrudierten Ummantelung verbunden. Mit einer Vielzahl solcher Verankerungsfasern ergibt sich eine grosse Gesamtverbindungsfläche zwischen Ummantelung und deren Verankerung, was die Verbindung stärkt und wiederum die Seillebensdauer erhöht. Ferner können die dünnen Verankerungsfasern in kurzer Zeit und mit vergleichsweise geringem Energeiaufwand auf Schmelztemperatur erhitzt werden, weshalb diese Ausführungsform Vorteile beim kontinuierlichen Aufextrudieren des Seilmantels bietet.The anchoring means can also be in the form of Anchoring fibers can be formed, which with aramid fibers load-bearing strands for the outermost strand layer with each other are twisted and fixed. The anchoring fibers are in the outermost fiber layer of the strands are arranged and in turn in one piece with the subsequently extruded casing connected. With a variety of such anchoring fibers results there is a large total connection area between the sheathing and anchoring them, which strengthens the connection and again the rope life increases. Furthermore, the thin Anchoring fibers in a short time and with comparative low energy expenditure can be heated to the melting temperature, which is why this embodiment has advantages in continuous Extruding the rope sheath offers.
Das erfindungsgemässe Kunstfaserseil bietet beispielsweise bei Aufzugsanlagen Vorteile, wo es den Kabinenrahmen einer in einem Aufzugsschacht geführten Kabine mit einem Gegengewicht verbindet. Um die Kabine und das Gegengewicht zu heben und zu senken, läuft das Seil über eine Treibscheibe, die von einem Antriebsmotor angetrieben wird. Beim Lauf über die Treibscheibe findet bei dem erfindungsgemässen Kunstfaserseil zwischen dem Seilmantel und der äussersten Litzenlage keine Relativbewegung statt.The synthetic fiber rope according to the invention offers, for example Elevator systems benefits where there is one cabin frame in one Elevator shaft guided cabin with a counterweight combines. To lift and close the cabin and counterweight lower, the rope runs over a traction sheave by one Drive motor is driven. When running over the traction sheave takes place in the inventive synthetic fiber rope between the Rope sheath and the outermost strand layer no relative movement instead of.
Weitere Einzelheiten der Erfindung sind nachfolgend anhand der in der Zeichnung dargestellten drei Ausführungsbeispiele der Erfindung näher beschrieben. Es zeigen:
Figur 1,- eine perspektivische Darstellung eines ersten Ausführungsbeispiels des erfindungsgemässen Treibseils mit Verankerungslitzen,
Figur 2,- eine Querschnittsansicht eines zweiten Ausführungsbeispiels des erfindungsgemässen Treibseils mit Umhüllung der Litzen,
Figur 3,- eine Querschnittsansicht eines dritten Ausführungsbeispiels der Erfindung mit Verankerungsfasern.
- Figure 1,
- 1 shows a perspective illustration of a first exemplary embodiment of the drive cable according to the invention with anchoring strands,
- Figure 2,
- 2 shows a cross-sectional view of a second exemplary embodiment of the drive cable according to the invention with the strands being covered,
- Figure 3,
- a cross-sectional view of a third embodiment of the invention with anchoring fibers.
Figur 1 zeigt ein erstes Ausführungsbeispiel eines
erfindungsgemäss ummantelten Seils 1. Das Seil 1 ist aufgebaut
aus einer Kernlitze 2 , um die in einer ersten Schlagrichtung 3
fünf gleiche Kunstfaserlitzen 4 einer ersten Litzenlage 5
schraubenlinienförmig gelegt sind, und mit denen zehn
Kunstfaserlitzen 4, 6 einer zweiten Litzenlage 7 im
Parallelschlag unter einem ausgewogenen Verhältnis zwischen
Faser- und Litzenschlagdrehung verseilt sind. Die Anzahl der
verseilten Litzen kann den jeweiligen Anforderungen
entsprechend unterschiedlich gewählt werden und ist nicht auf
diejenige dieses Ausführungsbeispiels festgelegt. Für das Seil 1
verwendete tragende Kunstfaserlitzen 2,4,6,9 werden aus
einzelnen Aramidfasern gedreht oder geschlagen und mit einem die
Aramidfasern schützenden Imprägnierungsmittel, beispielsweise
mit Polyurethanlösung, behandelt.Figure 1 shows a first embodiment of a
Rope covered according to the
Den Seilkern 8 umgibt ein Zwischenmantel 12 aus Polyurethan oder
Polyester, auf den eine äusserste Litzenlage 11 verseilt ist.
Der Zwischenmantel 12 wird unmittelbar vor dem Verseilen der
äussersten Litzenlage 11 auf den Seilkern 8 aufextrudiert. Er
verhindert einen Kontakt zwischen der äussersten Litzenlage 11
und der zweiten Litzenlage 7 und damit Verschleiss der
Kunstfaserlitzen 4, 6 und 9 durch gegenseitiges Aneinanderreiben
beim Lauf des Seils 1 über die Treibscheibe und der dabei
auftretenden Relativbewegung der Kunstfaserlitzen 4, 6, 9
untereinander. Ausserdem dient der Zwischenmantel 12 der inneren
Momentenübertragung zwischen Seilkern 8 und äusserster
Litzenlage 11.An
Die äusserste Litzenlage 11 ist in zur ersten Schlagrichtung 3
entgegengesetzter zweiten Schlagrichtung 10 verseilt. Sie baut
unter Längsbelastung des Seils 1 ein zu demjenigen des
parallelverseilten Seilkerns 8 entgegengesetzt gerichtetes
Drehmoment auf. The outermost strand layer 11 is in the
Eine Ummantelung 14 aus Polyurethan umhüllt die äusserste
Litzenlage 11 und gewährleistet den gewünschten Reibwert zur
Treibscheibe. Ferner ist das Polyurethan so abriebfest, dass
beim Lauf des Seils 1 über die Treibscheibe keine Beschädigungen
auftreten. Die Ummantelung 14 ist einstückig mit
Verankerungslitzen 13 aus Polyurethan beispielsweise durch
Schweissen, Vulkanisieren oder Kleben verbunden. Die
Verankerungslitzen 13 sind formschlüssig in der äussersten
Litzenlage 11 verankert. Beispielsweise sind hier neun dieser
Polyurethanlitzen 13 abwechselnd mit neun Aramidfaserlitzen
9, jeweils zwischen zwei benachbarten Aramidfaserlitzen 9
liegend miteinander zu der äussersten Litzenlage 11 verseilt.A
In Figur 1 sind die Aramidfaserlitzen 9 und die
Polyurethanlitzen 13 gleich dick dargestellt, doch kann der
Formschluss der Polyurethanlitzen 13 mit der äussersten
Litzenlage 11 weiter verbessert werden, wenn die
Polyurethanlitzen 13 dünner sind als die Aramidfaserlitzen 9.
Die dünneren Polyurethanlitzen 13 werden in Umfangsrichtung
zwischen den benachbarten durchmessergrösseren Aramidfaserlitzen
9 eingeklemmt und dabei in radialer Richtung auf den
Zwischenmantel 12 niedergedrückt.In Figure 1, the
Die Ummantelung 14 wird im Durchlauf auf die äusserste
Litzenlage 11 extrudiert. Bei dem Spritzdruckverfahren wird das
fliessfähige Kunststoffmaterial in sämtliche Zwischenräume der
Oberfläche der äussersten Litzenlage gepresst, so dass eine
grosse Haftfläche gebildet wird. Vor dem Extrudieren der
Ummantelung 14 werden die Polyurethanlitzen 13 auf
Schmelztemperatur erhitzt, so dass beim Extrudieren der
Ummantelung 14 und die Polyurethanlitzen 13 miteinander
verschweisst werden. Die dadurch geschaffene dauerhafte
einstückige Verbindung verleiht der Ummantelung 14
eine dauerhafte Besfestigung auf dem hochfesten Seil 1 über den
verbesserten Formschluss der Polyurethanlitzen mit der
äussersten Litzenlage 11.The
Der Seilmantel 14 kann auch in zwei Schichten extrudiert werden.
Die vorstehende Beschreibung trifft dann identisch auf die
zuerst aufgebrachte Mantelschicht zu. Figur 2 zeigt eine
Querschnittsansicht eines zweiten Ausführungsbeispiels eines
erfindungsgemäss ummantelten Seils 20. Der Seilkern 21 und der
fest auf ihm haftende Zwischenmantel 22 entsprechen
hinsichtlich Funktion und Aufbau entsprechenden Teilen des
zuvor beschriebenen ersten Ausführungsbeispiels. Auf den
Seilmantel 22 ist eine äusserste Litzenlage 23 aus siebzehn
Aramidfaserlitzen 24 verseilt. Jede einzelne Aramidfaserlitze 24
ist mit einer separaten, ringsum geschlossenen Umhüllung 25 aus
Polyurethan versehen. Das insoweit beschriebene
Aramidfaserseil 20 ist mit einer Ummantelung 26 umhüllt. Die
Ummantelung 26 besteht, wie die Umhüllung 25 der Aramidfaserlitzen 24
aus thermoplastisch formbarem Polyurethan und ist
werkstoffeinstückig entlang der jeweiligen Aussenoberfläche der
Umhüllung 25 mit der Decklitzenlage 23 verschweisst. Über diese
dauerhafte molekulare Verbindungen ist die Ummantelung 26
formschlüssig mit dem Aramidfaserlitze 24 verbunden. Auch bei
diesem Ausführungsbeispiel werden zunächst Verankerungsmittel in
Form der Umhüllung 25 in der Seilstruktur formschlüssig
verankert und unmittelbar vor dem Extrudieren der Ummantelung 26
durch Erhitzen, Kleben oder Ätzen bzw. Vulkanisieren dauerhaft
mit der Ummantelung 26 verbunden.The
In Figur 3 ist als ein drittes Ausführungsbeispiel der Erfindung
ein Aramidfaserseil 30 dargestellt. Der Aufbau des Seilkerns 31, der
diesen umhüllende Zwischenmantel 32 und die Anzahl der
Kunstfaserlitzen 33 der äussersten Litzenlage 34 sind wiederum
gleich, wie bei den beiden vorstehend beschriebenen
Ausführungsbeispielen. Ein Seilmantel 37 umgibt die äusserste
Litzenlage 34, mit der er
formschlüssig verbunden ist. Polyurethanfasern 35 sind in
der äussersten Faserlage zusammen mit Aramidfasern 36
angeordnet, d.h. an der Mantelaussenfläche der
Kunstfaserlitzen 33. Da die Kunstfaserlitzen 33
schraubenlinienförmig um den Zwischenmantel 32 gewickelt sind,
ist sichergestellt, dass die Polyurethanfasern 35 wenigstens
abschnittsweise an der an der Ummantelung 37 angrenzenden
Oberfläche zum Liegen kommen. Die Polyurethanfasern 35 werden
kurz vor dem Extrudieren der Ummantelung 37 erhitzt und
verschmelzen mit der dicht aufgepressten Ummantelung 37. Als
Bestandteil der Kunstfaserlitzen 33 sind die Polyurethanfasern
35 formschlüssig mit der Litzenstruktur der äussersten
Litzenlage 34 verbunden. Folglich ist auch die einstückig mit
den Polyurethanfasern 35 verbundene Ummantelung 37 über eine
Vielzahl solcher Polyurethanfasern 35 über diesen Formschluss
dauerhaft auf den Aramidfasern 36 verankert. Die
beschriebenen Ausführungsbeispiele der Erfindung können ferner
miteinander kombiniert werden, um gezielt eine gewünschte
Fixierung des Mantels auszubilden.In Figure 3 is a third embodiment of the invention
an
Claims (10)
- Synthetic-fiber rope composed of load-bearing synthetic-fiber strands (2, 4, 6, 9, 24, 33) which are laid together and arranged in several layers, with a sheath (14, 26, 37) which is joined to and surrounds an outermost layer of strands (11, 23, 34) characterized in that
the outermost layer of strands (11, 23, 34) has anchoring means (13, 25, 35) which are permanently fastened to the sheath (14, 26, 37) and which sheath (14, 26, 37) can only be separated from the outermost layer of strands (11, 23,34) by damaging the synthetic-fiber strands (9, 24, 33). - Synthetic-fiber rope according to Claim 1,
characterized in that
the anchoring means (13, 25, 35) and the sheath (14, 26, 37) are joined together in one piece. - Synthetic-fiber rope according to Claim 1 or 2,
characterized in that
the anchoring means (13, 25, 35) and the sheath (14, 26, 37) are made of materials which can be welded or vulcanized. - Synthetic-fiber rope according to one of Claims 1 to 3,
characterized in that
the anchoring means (13, 25, 35) are bonded with form fit to the outermost layer of strands (11, 23, 34). - Synthetic-fiber rope according to Claim 1 or 4,
characterized in that
the anchoring means take the form of at least one anchoring strand (13) laid in the outermost layer of strands (11) with load-bearing synthetic-fiber strands (9). - Synthetic-fiber rope according to Claim 1 or 4,
characterized in that
the anchoring means take the form of a jacket (25) which surrounds at least one synthetic-fiber strand (24) of the outermost layer of strands (23). - Synthetic-fiber rope according to Claim 1 or 4,
characterized in that
the anchoring means take the form of at least one anchoring fiber (35) which in the outermost layer of strands (34) is laid together with aramid fibers (36) to form load-bearing synthetic-fiber strands (33), the anchoring fiber (35) being arranged on at least some sections of the surface adjoining the sheath (37). - Process for manufacturing a synthetic-fiber rope composed of load-bearing synthetic-fiber strands (2, 4, 6, 9, 24, 33) which are laid together and arranged in several layers, with a sheath (14, 26, 37) which is joined to and surrounds an outermost layer of strands (11, 23, 34), characterized in that
the synthetic-fiber strands (9, 24, 33) of the outermost layer of strands are laid with anchoring means (13, 25, 35), that the anchoring means (13, 25, 35) are pre-treated and when the sheath (14, 26, 37) is applied they enter into a molecular bond by which they are permanently bonded to the sheath (14, 26, 37), which sheath (14, 26, 37) can only be separated from the outermost layer of strands (11, 23, 34) by damaging the synthetic-fiber strands (9, 24, 33). - Process according to Claim 8,
characterized in that
the anchoring means (13, 25, 35) are heated to melting temperature before the sheath (14, 26, 37) is extruded onto, and welded to, the anchoring means (13, 23, 34). - Process according to Claim 8,
characterized in that
the anchoring means (13, 25, 35) are chemically pre-treated before the sheath (14, 26, 37) is vulcanized onto the outermost layer of strands (11, 23, 34).
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
EP00100815A EP1029974B1 (en) | 1999-01-22 | 2000-01-17 | Sheathed synthetic fibre rope |
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
EP99810050 | 1999-01-22 | ||
EP99810050 | 1999-01-22 | ||
EP00100815A EP1029974B1 (en) | 1999-01-22 | 2000-01-17 | Sheathed synthetic fibre rope |
Publications (2)
Publication Number | Publication Date |
---|---|
EP1029974A1 EP1029974A1 (en) | 2000-08-23 |
EP1029974B1 true EP1029974B1 (en) | 2004-03-24 |
Family
ID=8242644
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP00100815A Expired - Lifetime EP1029974B1 (en) | 1999-01-22 | 2000-01-17 | Sheathed synthetic fibre rope |
Country Status (13)
Country | Link |
---|---|
US (1) | US6321520B1 (en) |
EP (1) | EP1029974B1 (en) |
JP (1) | JP4495816B2 (en) |
CN (1) | CN1130486C (en) |
AT (1) | ATE262610T1 (en) |
CA (1) | CA2297520C (en) |
DE (1) | DE50005757D1 (en) |
ES (1) | ES2218001T3 (en) |
HK (1) | HK1030246A1 (en) |
IL (1) | IL133721A (en) |
MY (1) | MY121133A (en) |
NO (1) | NO317522B1 (en) |
SG (1) | SG78407A1 (en) |
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1999
- 1999-12-23 SG SG1999006627A patent/SG78407A1/en unknown
- 1999-12-24 IL IL13372199A patent/IL133721A/en not_active IP Right Cessation
- 1999-12-30 MY MYPI99005800A patent/MY121133A/en unknown
-
2000
- 2000-01-06 JP JP2000000838A patent/JP4495816B2/en not_active Expired - Fee Related
- 2000-01-17 DE DE50005757T patent/DE50005757D1/en not_active Expired - Lifetime
- 2000-01-17 EP EP00100815A patent/EP1029974B1/en not_active Expired - Lifetime
- 2000-01-17 AT AT00100815T patent/ATE262610T1/en not_active IP Right Cessation
- 2000-01-17 ES ES00100815T patent/ES2218001T3/en not_active Expired - Lifetime
- 2000-01-20 CN CN00100389A patent/CN1130486C/en not_active Expired - Lifetime
- 2000-01-20 US US09/488,290 patent/US6321520B1/en not_active Expired - Lifetime
- 2000-01-20 CA CA002297520A patent/CA2297520C/en not_active Expired - Fee Related
- 2000-01-21 NO NO20000333A patent/NO317522B1/en not_active IP Right Cessation
-
2001
- 2001-02-16 HK HK01101128A patent/HK1030246A1/en not_active IP Right Cessation
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
USRE47035E1 (en) | 1998-12-31 | 2018-09-11 | Otis Elevator Company | Wedge clamp type termination for elevator tension member |
Also Published As
Publication number | Publication date |
---|---|
CN1130486C (en) | 2003-12-10 |
DE50005757D1 (en) | 2004-04-29 |
SG78407A1 (en) | 2001-02-20 |
NO20000333L (en) | 2000-07-24 |
CA2297520C (en) | 2007-04-10 |
MY121133A (en) | 2005-12-30 |
JP4495816B2 (en) | 2010-07-07 |
US6321520B1 (en) | 2001-11-27 |
IL133721A (en) | 2003-06-24 |
ATE262610T1 (en) | 2004-04-15 |
HK1030246A1 (en) | 2001-04-27 |
IL133721A0 (en) | 2001-04-30 |
NO20000333D0 (en) | 2000-01-21 |
EP1029974A1 (en) | 2000-08-23 |
CA2297520A1 (en) | 2000-07-22 |
NO317522B1 (en) | 2004-11-08 |
ES2218001T3 (en) | 2004-11-16 |
CN1262358A (en) | 2000-08-09 |
JP2000220083A (en) | 2000-08-08 |
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