EP0969958A1 - Tuyau en plastique a plusieurs couches - Google Patents

Tuyau en plastique a plusieurs couches

Info

Publication number
EP0969958A1
EP0969958A1 EP98913738A EP98913738A EP0969958A1 EP 0969958 A1 EP0969958 A1 EP 0969958A1 EP 98913738 A EP98913738 A EP 98913738A EP 98913738 A EP98913738 A EP 98913738A EP 0969958 A1 EP0969958 A1 EP 0969958A1
Authority
EP
European Patent Office
Prior art keywords
layer
tube
barrier layer
protective layer
plastic tube
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Withdrawn
Application number
EP98913738A
Other languages
German (de)
English (en)
Inventor
Franz-Josef Riesselmann
Harald Eichner
Josef BRÜNEN
Paul Wolters
Nils Wehmeier
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Uponor Innovation AB
Original Assignee
Hewing GmbH
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Hewing GmbH filed Critical Hewing GmbH
Priority to DE29824837U priority Critical patent/DE29824837U1/de
Publication of EP0969958A1 publication Critical patent/EP0969958A1/fr
Withdrawn legal-status Critical Current

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B1/00—Layered products having a non-planar shape
    • B32B1/08—Tubular products
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00—Layered products comprising a layer of synthetic resin
    • B32B27/06—Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material
    • B32B27/08—Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material of synthetic resin
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B3/00—Layered products comprising a layer with external or internal discontinuities or unevennesses, or a layer of non-planar shape; Layered products comprising a layer having particular features of form
    • B32B3/26—Layered products comprising a layer with external or internal discontinuities or unevennesses, or a layer of non-planar shape; Layered products comprising a layer having particular features of form characterised by a particular shape of the outline of the cross-section of a continuous layer; characterised by a layer with cavities or internal voids ; characterised by an apertured layer
    • B32B3/28—Layered products comprising a layer with external or internal discontinuities or unevennesses, or a layer of non-planar shape; Layered products comprising a layer having particular features of form characterised by a particular shape of the outline of the cross-section of a continuous layer; characterised by a layer with cavities or internal voids ; characterised by an apertured layer characterised by a layer comprising a deformed thin sheet, i.e. the layer having its entire thickness deformed out of the plane, e.g. corrugated, crumpled
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B7/00—Layered products characterised by the relation between layers; Layered products characterised by the relative orientation of features between layers, or by the relative values of a measurable parameter between layers, i.e. products comprising layers having different physical, chemical or physicochemical properties; Layered products characterised by the interconnection of layers
    • B32B7/04—Interconnection of layers
    • B32B7/12—Interconnection of layers using interposed adhesives or interposed materials with bonding properties
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F16—ENGINEERING ELEMENTS AND UNITS; GENERAL MEASURES FOR PRODUCING AND MAINTAINING EFFECTIVE FUNCTIONING OF MACHINES OR INSTALLATIONS; THERMAL INSULATION IN GENERAL
    • F16L—PIPES; JOINTS OR FITTINGS FOR PIPES; SUPPORTS FOR PIPES, CABLES OR PROTECTIVE TUBING; MEANS FOR THERMAL INSULATION IN GENERAL
    • F16L11/00—Hoses, i.e. flexible pipes
    • F16L11/04—Hoses, i.e. flexible pipes made of rubber or flexible plastics
    • F16L11/045—Hoses, i.e. flexible pipes made of rubber or flexible plastics with four or more layers without reinforcement
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F16—ENGINEERING ELEMENTS AND UNITS; GENERAL MEASURES FOR PRODUCING AND MAINTAINING EFFECTIVE FUNCTIONING OF MACHINES OR INSTALLATIONS; THERMAL INSULATION IN GENERAL
    • F16L—PIPES; JOINTS OR FITTINGS FOR PIPES; SUPPORTS FOR PIPES, CABLES OR PROTECTIVE TUBING; MEANS FOR THERMAL INSULATION IN GENERAL
    • F16L11/00—Hoses, i.e. flexible pipes
    • F16L11/04—Hoses, i.e. flexible pipes made of rubber or flexible plastics
    • F16L11/11—Hoses, i.e. flexible pipes made of rubber or flexible plastics with corrugated wall
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F16—ENGINEERING ELEMENTS AND UNITS; GENERAL MEASURES FOR PRODUCING AND MAINTAINING EFFECTIVE FUNCTIONING OF MACHINES OR INSTALLATIONS; THERMAL INSULATION IN GENERAL
    • F16L—PIPES; JOINTS OR FITTINGS FOR PIPES; SUPPORTS FOR PIPES, CABLES OR PROTECTIVE TUBING; MEANS FOR THERMAL INSULATION IN GENERAL
    • F16L9/00—Rigid pipes
    • F16L9/12—Rigid pipes of plastics with or without reinforcement
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00—Properties of the layers or laminate
    • B32B2307/70—Other properties
    • B32B2307/724—Permeability to gases, adsorption
    • B32B2307/7242—Non-permeable
    • B32B2307/7244—Oxygen barrier
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2597/00—Tubular articles, e.g. hoses, pipes
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F02—COMBUSTION ENGINES; HOT-GAS OR COMBUSTION-PRODUCT ENGINE PLANTS
    • F02M—SUPPLYING COMBUSTION ENGINES IN GENERAL WITH COMBUSTIBLE MIXTURES OR CONSTITUENTS THEREOF
    • F02M35/00—Combustion-air cleaners, air intakes, intake silencers, or induction systems specially adapted for, or arranged on, internal-combustion engines
    • F02M35/10—Air intakes; Induction systems
    • F02M35/10091—Air intakes; Induction systems characterised by details of intake ducts: shapes; connections; arrangements
    • F02M35/10137—Flexible ducts, e.g. bellows or hoses
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F16—ENGINEERING ELEMENTS AND UNITS; GENERAL MEASURES FOR PRODUCING AND MAINTAINING EFFECTIVE FUNCTIONING OF MACHINES OR INSTALLATIONS; THERMAL INSULATION IN GENERAL
    • F16L—PIPES; JOINTS OR FITTINGS FOR PIPES; SUPPORTS FOR PIPES, CABLES OR PROTECTIVE TUBING; MEANS FOR THERMAL INSULATION IN GENERAL
    • F16L11/00—Hoses, i.e. flexible pipes
    • F16L11/04—Hoses, i.e. flexible pipes made of rubber or flexible plastics
    • F16L2011/047—Hoses, i.e. flexible pipes made of rubber or flexible plastics with a diffusion barrier layer
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S138/00—Pipes and tubular conduits
    • Y10S138/01—Adhesive

Definitions

  • PE Polyethylene
  • the plastics used are permeable to oxygen, which is why they are provided with a (oxygen) diffusion barrier layer, which generally surrounds the base pipe carrying the fluid from the outside.
  • the oxygen barrier property of the EVOH layer material is strongly dependent on the moisture in the vicinity of the pipe. This is because the higher the moisture absorption of the EVOH material, the lower its barrier property. If the pipe is connected to a connector, edges of the connector may damage the EVOH layer if handled improperly. - There are also connection techniques that require expanding the pipe. This type of connection technology is gaining increasing acceptance on the market because its handling and manufacturing costs are simple and cheap. When expanding a plastic pipe provided with an EVOH barrier layer, however, there is a risk that the EVOH layer will tear, since its stretching behavior cannot be reproduced with sufficient reliability.
  • the invention has for its object to provide a multilayer plastic tube with an oxygen diffusion barrier layer, which is protected against mechanical damage, the plastic can insert material tube comparatively easily and without excessive force in an outer tube.
  • a lubricant is added to the material for the protective layer, which, mixed with the other material of the protective layer, is extruded onto the barrier layer.
  • the lubricant migrates to the surface of the protective layer where it becomes effective, i.e. where it gives the multilayer plastic tube its sliding properties.
  • the lubricant is therefore, in particular, a material based on oleic acid, erucic acid amide.
  • materials based on silicone oil or tetrafluoroethylene can also be used.
  • the material of the protective layer which is preferably a
  • the multilayer plastic tube according to the invention is given not only the mechanical protective function of the barrier layer but also sliding properties which result in the insertion of the multilayer plastic tube in an empty tube simplify.
  • the combination of a plastic material and a sliding material for the production of plastic objects is known, for example, from the packaging industry of sliding films.
  • the lubricants used there can also be used in approximately the same concentrations for the protective layers of plastic tubes. This cannot be expected without further ado because the manufacturing processes of foils and plastic tubes differ significantly and plastic foils in particular have a significantly larger surface area in relation to the volume of material used than is the case with plastic tubes.
  • lubricant in the context of this invention, this also means a lubricant in the form of a so-called antiblocking agent which, by changing the surface structure, enables two objects to rub easily against one another.
  • Antiblocking agents of this type are known, for example, from plastic film production and processing.
  • the base tube is preferably located in an outer tube which is at a distance from the outer protective layer of the base tube.
  • the outer tube is made of plastic and is designed in particular as a corrugated tube.
  • this is provided with a base pipe, a barrier layer surrounding the base tube, which is impermeable to oxygen, a protective layer applied to the barrier layer to protect the barrier layer from damage and an outer tube in which the base tube is arranged and which surrounds the protective layer of the base tube with play, the inside of the outer tube being a Has lubricant.
  • an adhesion promoter layer composed of an adhesion promoter is arranged between the latter and the base tube.
  • the material for this coupling agent is preferably modified linear LDPE.
  • Protective layer made of EVOH to protect the barrier layer from damage, wherein the adhesion promoter consists of a modified linear LDPE material with a density less than 926 kg / m 3 and wherein the protective layer consists of a modified linear LDPE material with a density greater than
  • the barrier layer is formed from EVOH, while the adhesion promoter and the protective layer each consist of differently modified linear LDPE materials.
  • the modifications are chosen such that the adhesion of the protective layer to the EVOH barrier layer is greater than to the adhesion promoter layer and thus the base tube.
  • the density of the linear LDPE material of the adhesion promoter layer is less than 926 kg / m 3 and greater than 916 kg / m 3 .
  • the density of the modified linear LDPE material of the protective layer is preferably greater than 928 kg / m 3 and less than 940 kg / m 3 .
  • the choice of material for the protective layer is advantageous in that the protective layer is tough enough on the one hand to protect the brittle EVOH barrier layer arranged underneath from mechanical damage and on the other hand hard enough is to give the pipe sufficient sliding properties.
  • the protective layer consequently has sliding properties, and so far consists entirely of a material having such a property, namely the modified linear LDPE material.
  • the barrier layer lies outside the neutral zone of the multilayer plastic tube, i. H. outside the middle of the wall thickness extension of the multilayer plastic pipe.
  • All components of the multilayer plastic tube according to the invention are extruded, the barrier layer being extruded onto the extruded base tube first, in order to then subsequently extrude the protective layer onto it.
  • the layer thickness of the adhesion promoter is advantageously between 10 ⁇ m and 70 ⁇ m.
  • the thickness of the protective layer should not be less than 40 ⁇ m, so it is preferably between 40 ⁇ m and 100 ⁇ m.
  • the thickness of the protective layer influences the overall properties of the multilayer plastic pipe.
  • the protective layer should not be thinner than 40 ⁇ m.
  • the protective layer should consist of a comparatively tough material in order to be able to optimally use its protective function for the barrier layer.
  • a linear LDPE is therefore suitable as a material for the protective layer.
  • the tube surrounded from the outside with such a protective layer becomes relatively blunt and consequently can no longer be inserted into a corrugated tube or the like over the desired lengths. Insert the outer tube.
  • a protective layer made of a relatively tough material gives the entire tube a comparatively soft surface, which in turn leads to deformations in particular when the tube is wound up. Appearances appear like flattened outer surface areas. This has a negative influence on the optical quality of the pipe, and under certain circumstances there may also be disadvantages during assembly with regard to the requirement for a tight seal, for example a connector on the outside of the pipe.
  • the problem of the relatively high pipe friction resistance can be solved according to the invention by adding a lubricant, while the problem of the risk of deformation is counteracted according to the invention by using high-density plastics based on metallocene.
  • the total combination of the material compositions of the three around the base tube Layers arranged around it, namely the adhesive layer, the EVOH barrier layer and the protective layer bring about the following properties: good adhesion of the EVOH layer, - high toughness of the material forming the outer surface of the tube, high resistance to crack propagation, high rigidity of the outer surface of the tube forming material in order to avoid deformations, good sliding properties in order to be able to push the tube into the desired lengths in outer tubes, in particular corrugated tubes.
  • Fig. 1 shows a longitudinal section through a tube-in-tube combination consisting of a gas- or fluid-carrying inner tube and an outer corrugated tube, and
  • Fig. 2 and 3 schematically illustrate the process steps for, for example, automatically pushing the outer tube and the inner tube into one another.
  • the inner tube 12 has a base tube 16 made of PE, to which an adhesion promoter layer 18, also based on PE, is applied.
  • a lubricant based on oleic acid is added to this material.
  • the outer tube 14 designed as a corrugated tube also consists of polyethylene.
  • the plastic inner tube 12 having the above structure can be prefabricated as a tube-in-tube combination 10 because of its good sliding properties over a very long length.
  • the frictional resistance of the outer surface 24 of the inner tube 12 and the inner surface 26 of the corrugated tube 14 is reduced, so that when the two tubes are pushed together according to FIGS. 2 and 3 significantly lower forces are required than in the case in which no lubricant is added to the material of the protective layer 22.
  • the modification of the LDPE material of the base tube 16 was chosen in such a way that the adhesion of the base tube 16 to the barrier layer 20 was specifically set, but was not optimal.
  • the modification of the LDPE material of the protective layer 22 was chosen such that the protective layer 22 was in contact with the EVOH barrier layer 20 with great adhesion.
  • the density of the LDPE material of the protective layer 22 was greater than the density of the LDPE material of the base tube 16.
  • the density of the LDPE material of the base tube 16 was between 918 and 924 kg / m 3
  • the density of the LDPE material was Protective layer 22 was between 929 and 936 kg / m 3 .
  • the choice of material for the protective layer 22 ensures good mechanical protection of the brittle barrier layer 20 with a sufficiently high resistance to surface deformation and secondly good sliding properties of the inner tube 12, so that this can be inserted into the external plastic corrugated pipe 14 without excessive frictional forces hindering this manufacturing process for pipe-in-pipe line systems.

Landscapes

  • Engineering & Computer Science (AREA)
  • General Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • Rigid Pipes And Flexible Pipes (AREA)
  • Laminated Bodies (AREA)

Abstract

L'invention concerne un tuyau en plastique à plusieurs couches comportant un tuyau de base (16) et une couche de jonction (20) entourant le tuyau de base (16) et imperméable à l'oxygène, ainsi qu'une couche de protection (22) appliquée sur la couche de jonction (20) pour protéger cette dernière des dégradations, le matériau de la couche de protection (22) contenant un lubrifiant.
EP98913738A 1997-03-29 1998-03-27 Tuyau en plastique a plusieurs couches Withdrawn EP0969958A1 (fr)

Priority Applications (1)

Application Number Priority Date Filing Date Title
DE29824837U DE29824837U1 (de) 1997-03-29 1998-03-27 Mehrschicht-Kunststoffrohr

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
DE29705681U 1997-03-29
DE29705681 1997-03-29
PCT/EP1998/001822 WO1998043806A1 (fr) 1997-03-29 1998-03-27 Tuyau en plastique a plusieurs couches

Publications (1)

Publication Number Publication Date
EP0969958A1 true EP0969958A1 (fr) 2000-01-12

Family

ID=8038222

Family Applications (1)

Application Number Title Priority Date Filing Date
EP98913738A Withdrawn EP0969958A1 (fr) 1997-03-29 1998-03-27 Tuyau en plastique a plusieurs couches

Country Status (3)

Country Link
US (1) US6279614B1 (fr)
EP (1) EP0969958A1 (fr)
WO (1) WO1998043806A1 (fr)

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Also Published As

Publication number Publication date
WO1998043806A1 (fr) 1998-10-08
US6279614B1 (en) 2001-08-28

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