EP0941299B1 - Formulation de produit de lavage pour textiles a base de glycine-nitriles quaternises, d'agents blanchissants, de tensioactifs non ioniques et/ou anioniques et de composes sequestrant les ions calcium et/ou magnesium - Google Patents

Formulation de produit de lavage pour textiles a base de glycine-nitriles quaternises, d'agents blanchissants, de tensioactifs non ioniques et/ou anioniques et de composes sequestrant les ions calcium et/ou magnesium Download PDF

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Publication number
EP0941299B1
EP0941299B1 EP97952779A EP97952779A EP0941299B1 EP 0941299 B1 EP0941299 B1 EP 0941299B1 EP 97952779 A EP97952779 A EP 97952779A EP 97952779 A EP97952779 A EP 97952779A EP 0941299 B1 EP0941299 B1 EP 0941299B1
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EP
European Patent Office
Prior art keywords
weight
detergent formulation
textile detergent
acid
bis
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
EP97952779A
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German (de)
English (en)
Other versions
EP0941299A2 (fr
Inventor
Dieter BÖCKH
Gregor Schürmann
Klaus Mundinger
Michael SCHÖNHERR
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BASF SE
Original Assignee
BASF SE
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Publication date
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Publication of EP0941299A2 publication Critical patent/EP0941299A2/fr
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Classifications

    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/39—Organic or inorganic per-compounds
    • C11D3/3902—Organic or inorganic per-compounds combined with specific additives
    • C11D3/3905—Bleach activators or bleach catalysts
    • C11D3/3907—Organic compounds
    • C11D3/3917—Nitrogen-containing compounds
    • C11D3/3925—Nitriles; Isocyanates or quarternary ammonium nitriles
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66—Non-ionic compounds
    • C11D1/83—Mixtures of non-ionic with anionic compounds

Definitions

  • Suitable amorphous or crystalline silicates are mainly amorphous and crystalline disilicates Disilicates such as the layered silicate SKS-6 (manufacturer Fa. Maximum).
  • the silicates can be in the form of their alkali metal, alkaline earth metal or ammonium salts can be used. Preferably Na, Li and Mg silicates are used.
  • Suitable modifying Monomers are the above group monomers (ii) and (iii).
  • nonionic surfactants are alkoxylated C 8 to C 22 alcohols, such as fatty alcohol alkoxylates or oxo alcohol alkoxylates.
  • the alkoxylation can be carried out using ethylene oxide, propylene oxide and / or butylene oxide. All alkoxylated alcohols which contain at least two molecules of an alkylene oxide mentioned above can be used as the surfactant.
  • block polymers of ethylene oxide, propylene oxide and / or butylene oxide come into consideration or addition products which contain the alkylene oxides mentioned in a statistical distribution.
  • 2 to 50, preferably 3 to 20 mol of at least one alkylene oxide are used per mol of alcohol.
  • Ethylene oxide is preferably used as the alkylene oxide.
  • the alcohols preferably have 10 to 18 carbon atoms.
  • the invention Textile detergent formulation usual color transfer inhibitors in the usual amounts for this (about 0.1 to 2 wt .-%).
  • Phosphate-free compact detergents have the following composition, for example: 15 to 70% Zeolites, layered silicates, polycarboxylate or aminopolycarboxylates or mixtures thereof 5 to 35% Surfactants 0.5 to 6% quaternized glycine nitriles 10 to 25% inorganic peroxo compounds as bleach ad 100 other ingredients. Detergents of this type are usually dosed with 2.5 to 7 g / l.

Claims (7)

  1. Formulation de détergent pour textiles, comprenant
    (A) de 0,1 à 10 % en poids d'au moins un glycine-nitrile quaternisé du groupe comprenant l'acétonitrileméthylsulfate, l'acétonitrilesulfate et l'acétonitrilehydrogénosulfate de N-méthylmorpholinium, éventuellement en combinaison avec d'autres activateurs de blanchiment, les glycine-nitriles quaternisés représentant au moins 5 % en poids du total de l'ensemble des activateurs de blanchiment,
    (B) de 0,5 à 40 % en poids d'agents de blanchiment sous forme de composés peroxo et/ou de peracides,
    (C) de 0,5 à 50 % en poids de tensioactifs non-ioniques et/ou anioniques, et
    (D) de 5 à 85 % en poids d'au moins un composé séquestrant les ions calcium et/ou magnésium ayant une fonction d'adjuvant ou de co-adjuvant.
  2. Formulation de détergent textile selon la revendication 1, contenant
    (A) de 0,5 à 7 % en poids d'au moins un glycine-nitrile quaternisé (A),
    (B) de 5 à 30 % en poids d'agents de blanchiment sous forme de composés peroxo et/ou de peracides,
    (C) de 5 à 30 % en poids de tensioactifs non-ioniques et/ou anioniques, et
    (D) de 10 à 70 % en poids d'au moins un composé séquestrant les ions calcium et/ou magnésium, ayant une fonction d'adjuvant ou de co-adjuvant.
  3. Formulation de détergent textile selon la revendication 1 ou 2, contenant le composant (A) sous forme d'un mélange ou de granulés des glycine-nitriles (A) avec des matériaux supports poreux inertes appropriés.
  4. Formulation de détergent textile selon les revendications 1 à 3, contenant en tant que composant (D) des zéolites, des silicates, des phosphates de métaux alcalins, des polycarboxylates et/ou des aminopolycarboxylates.
  5. Formulation de détergent textile selon les revendications 1 à 4 sous forme d'une poudre ou d'un granulé, ayant une masse volumique apparente de 200 à 1100 g/l.
  6. Utilisation de la formulation de détergent textile selon les revendications 1 à 5 à une dose supérieure à 2 g par litre de lessive, de préférence à une dose de 2,5 à 15 g par litre de lessive, pour laver des textiles en utilisation domestique et industrielle.
  7. Utilisation de la formulation de détergent textile selon la revendication 6 pour un rapport de bain article textile:lessive de 1:10 à 1:2, de préférence de 1:5 à 1:3.
EP97952779A 1996-11-29 1997-11-18 Formulation de produit de lavage pour textiles a base de glycine-nitriles quaternises, d'agents blanchissants, de tensioactifs non ioniques et/ou anioniques et de composes sequestrant les ions calcium et/ou magnesium Expired - Lifetime EP0941299B1 (fr)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
DE19649384 1996-11-29
DE19649384A DE19649384A1 (de) 1996-11-29 1996-11-29 Textilwaschmittel-Formulierung auf Basis von quaternierten Glycinnitrilen, Bleichmitteln, nichtionischen und/oder anionischen Tensiden und Calcium- und/oder Magnesiumionen sequestierenden Verbindungen
PCT/EP1997/006429 WO1998023718A2 (fr) 1996-11-29 1997-11-18 Formulation de produit de lavage pour textiles a base de glycine-nitriles quaternises, d'agents blanchissants, de tensioactifs non ioniques et/ou anioniques et de composes sequestrant les ions calcium et/ou magnesium

Publications (2)

Publication Number Publication Date
EP0941299A2 EP0941299A2 (fr) 1999-09-15
EP0941299B1 true EP0941299B1 (fr) 2001-08-29

Family

ID=7813064

Family Applications (1)

Application Number Title Priority Date Filing Date
EP97952779A Expired - Lifetime EP0941299B1 (fr) 1996-11-29 1997-11-18 Formulation de produit de lavage pour textiles a base de glycine-nitriles quaternises, d'agents blanchissants, de tensioactifs non ioniques et/ou anioniques et de composes sequestrant les ions calcium et/ou magnesium

Country Status (11)

Country Link
US (1) US6174853B1 (fr)
EP (1) EP0941299B1 (fr)
JP (1) JP2001504882A (fr)
AT (1) ATE204901T1 (fr)
AU (1) AU5653998A (fr)
BR (1) BR9713457A (fr)
CA (1) CA2272271A1 (fr)
DE (2) DE19649384A1 (fr)
DK (1) DK0941299T3 (fr)
ES (1) ES2162687T3 (fr)
WO (1) WO1998023718A2 (fr)

Families Citing this family (12)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6010994A (en) * 1995-06-07 2000-01-04 The Clorox Company Liquid compositions containing N-alkyl ammonium acetonitrile salts
US6211130B1 (en) * 1997-08-21 2001-04-03 Henkel Kommanditgesellschaft Auf Aktien Use of quaternary acetonitrile compounds as activators for detergents
DE19914811A1 (de) * 1999-03-31 2000-10-05 Henkel Kgaa Enzym- und bleichaktivatorhaltige Wasch- und Reinigungsmittel
US20010046951A1 (en) * 2000-02-02 2001-11-29 Kao Corporation Bleaching detergent composition
DE10057045A1 (de) * 2000-11-17 2002-05-23 Clariant Gmbh Teilchenförmige Bleichaktivatoren auf der Basis von Acetonitrilen
US20020137659A1 (en) * 2000-12-18 2002-09-26 Gross Stephen F. Reaction products of polycarboxylic acids derivatives thereof
DE10211389A1 (de) * 2002-03-15 2003-09-25 Clariant Gmbh Ammoniumnitrile und deren Verwendung als hydrophobe Bleichaktivatoren
AU2003231107A1 (en) * 2002-05-02 2003-11-17 The Procter And Gamble Company Detergent compositions and components thereof
ATE373073T1 (de) * 2002-12-24 2007-09-15 Dalli Werke Gmbh & Co Kg Optimiertes wasch- und reinigungsmittelsystem für eine verbesserte bleichwirkung bei niedrigeren temperaturen
ES2249175B1 (es) * 2004-09-08 2008-06-01 M. Jose Roldan Herrero Composicion de jabon para lavar con poder suavizante.
EP2029690B1 (fr) * 2006-05-24 2013-09-25 Harald Weirich Méthode de préparation de liants modifiés à l'aide d'huiles végétales et de dérivés d'huiles végétales et adjuvants et utilisation des liants modifiés et adjuvants préparés.
US11713435B2 (en) 2018-01-30 2023-08-01 Eastman Chemical Company Aminocarboxylate chelating agents and detergent compositions containing them

Family Cites Families (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB9011618D0 (en) * 1990-05-24 1990-07-11 Unilever Plc Bleaching composition
DE4431212A1 (de) * 1994-09-02 1996-03-07 Basf Ag Verfahren zur Herstellung von quaternierten Glycinnitrilen
US5739327A (en) * 1995-06-07 1998-04-14 The Clorox Company N-alkyl ammonium acetonitrile bleach activators
DE19605526A1 (de) * 1996-02-15 1997-08-21 Hoechst Ag Ammoniumnitrile und deren Verwendung als Bleichaktivatoren

Also Published As

Publication number Publication date
ATE204901T1 (de) 2001-09-15
CA2272271A1 (fr) 1998-06-04
WO1998023718A2 (fr) 1998-06-04
DE59704478D1 (de) 2001-10-04
BR9713457A (pt) 2000-03-28
US6174853B1 (en) 2001-01-16
WO1998023718A3 (fr) 1998-08-06
ES2162687T3 (es) 2002-01-01
JP2001504882A (ja) 2001-04-10
DK0941299T3 (da) 2001-10-08
AU5653998A (en) 1998-06-22
DE19649384A1 (de) 1998-06-04
EP0941299A2 (fr) 1999-09-15

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