EP0923628A1 - Composition de carburant comprenant des composes oxygenes pour moteurs diesel - Google Patents
Composition de carburant comprenant des composes oxygenes pour moteurs dieselInfo
- Publication number
- EP0923628A1 EP0923628A1 EP98929517A EP98929517A EP0923628A1 EP 0923628 A1 EP0923628 A1 EP 0923628A1 EP 98929517 A EP98929517 A EP 98929517A EP 98929517 A EP98929517 A EP 98929517A EP 0923628 A1 EP0923628 A1 EP 0923628A1
- Authority
- EP
- European Patent Office
- Prior art keywords
- fuel composition
- carbon atoms
- composition according
- formula
- atoms
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
- C10L1/00—Liquid carbonaceous fuels
- C10L1/10—Liquid carbonaceous fuels containing additives
- C10L1/14—Organic compounds
- C10L1/18—Organic compounds containing oxygen
- C10L1/185—Ethers; Acetals; Ketals; Aldehydes; Ketones
- C10L1/1852—Ethers; Acetals; Ketals; Orthoesters
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
- C10L1/00—Liquid carbonaceous fuels
- C10L1/02—Liquid carbonaceous fuels essentially based on components consisting of carbon, hydrogen, and oxygen only
- C10L1/026—Liquid carbonaceous fuels essentially based on components consisting of carbon, hydrogen, and oxygen only for compression ignition
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
- C10L1/00—Liquid carbonaceous fuels
- C10L1/10—Liquid carbonaceous fuels containing additives
- C10L1/14—Organic compounds
- C10L1/18—Organic compounds containing oxygen
- C10L1/185—Ethers; Acetals; Ketals; Aldehydes; Ketones
- C10L1/1852—Ethers; Acetals; Ketals; Orthoesters
- C10L1/1855—Cyclic ethers, e.g. epoxides, lactides, lactones
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
- C10L1/00—Liquid carbonaceous fuels
- C10L1/10—Liquid carbonaceous fuels containing additives
- C10L1/14—Organic compounds
- C10L1/18—Organic compounds containing oxygen
- C10L1/192—Macromolecular compounds
- C10L1/198—Macromolecular compounds obtained otherwise than by reactions involving only carbon-to-carbon unsaturated bonds homo- or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon to carbon double bond, and at least one being terminated by an acyloxy radical of a saturated carboxylic acid, of carbonic acid
- C10L1/1985—Macromolecular compounds obtained otherwise than by reactions involving only carbon-to-carbon unsaturated bonds homo- or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon to carbon double bond, and at least one being terminated by an acyloxy radical of a saturated carboxylic acid, of carbonic acid polyethers, e.g. di- polygylcols and derivatives; ethers - esters
Definitions
- the present invention relates to a new fuel composition
- a new fuel composition comprising oxygenated compounds improving the combustion of fuel, in particular compounds which can improve the cetane number of fuel bases such as middle distillates used in the composition of gas oils for diesel engines.
- a fuel base is generally constituted by a physical mixture of several middle distillates or petroleum fractions resulting from the refining of crude oils originating from all walks of the world. These petroleum fractions come from a large number of separations by atmospheric or vacuum distillation and from chemical transformations of some of these distilled cuts by hydrodesulfurization and or catalytic cracking. By an appropriate mixture of these different refined cuts, a large variety of fuel bases with relatively different physicochemical properties is obtained. Finally, diesel or diesel fuels usable in combustion engines are prepared by a complex mixture of these bases. However, to obtain fuels that meet current legal specifications, refiners must develop increasingly complicated formulations that favor crude oils with a high concentration of distillates and fuel bases with a high cetane number.
- the additives that is to say the compounds introduced at low contents into the refined cuts
- nitrates or organic peroxides which it is known that they have a limited effectiveness in fuel bases or gas oils naturally having a low cetane number.
- the organic peroxides decompose irreversibly as a function of time, which leads to a deterioration in the characteristics of the diesel fuel stored both in terms of quality and of cetane number.
- Refiners have long been looking for other sources of compounds which can make it possible to improve the cetane number of fuel bases and diesel fuels, in particular among oxygenated compounds such as ethers, polyethers or even acetals.
- oxygenated compounds such as ethers, polyethers or even acetals.
- the addition of oxygenated compounds in diesel fuels makes it possible to reduce the emission of pollutants, in particular the emission of particles (EP 14.992).
- US Pat. No. 5,308,365 claims the addition of 1 to 30% by weight of dialkylated and trialkylated derivatives of glycerin, obtained by adding an olefin such as isobutene to glycerol, in a gas oil having a range of use between 160 ° C and 370 ° C and a sulfur content less than or equal to 500 ppm.
- Patent JP 0725 8661 claims a formulation comprising 20 to 94% of a diesel cut having a distillation range between 130 ° C and 400 ° C, 5 to 40% of a hydrocracked diesel cut commonly called LCO and 1 to 40 % of a monoether of formula R 1 OR 2 in which R ⁇ and R 2 are alkyl chains of 3 to 12 carbon atoms.
- Patent JP 0701 8271 claims gas oils containing ether glycols of formula R 1 - (OA) n -R 2 in which R is an alkyl chain of 1 to 10 carbon atoms, R 2 represents the hydrogen atom or a alkyl chain comprising from 1 to 10 carbon atoms, A is of ethylene or trimethylene structure optionally substituted and n is an integer varying from 1 to 10.
- Patent JP 0634 0886 claims the addition to a diesel of 0.05% to 20% by weight of a compound of general formula Ri-O- (EO) n - (PO) m -R 2 in which R x and R 2 represent independently the hydrogen atom or an alkyl chain comprising from 1 to 20 carbon atoms, EO and PO representing respectively the oxyethylene and oxyisopropylene groups, and, m and n are integers between 0 and 15.
- Ri-O- (EO) n - (PO) m -R 2 in which R x and R 2 represent independently the hydrogen atom or an alkyl chain comprising from 1 to 20 carbon atoms, EO and PO representing respectively the oxyethylene and oxyisopropylene groups, and, m and n are integers between 0 and 15.
- patent FR 2,544,738 claims, as a component of diesel fuels, acetals of formula C 4 Hg-0-CR 1 R2-0-C H9 R- j _ and R which may be hydrogen or an alkyl group.
- the present invention relates to the use of a new family of oxygenated compounds in diesel fuels, which make it possible to increase the cetane index, to provide greater flexibility in the formulation of diesel fuels for a lower cost and also make it possible to limit the aromatic and sulfur compounds responsible for the emission of particles.
- the present invention therefore relates to a fuel composition comprising a major part of at least one fuel base and a minor part of at least one oxygenated compound characterized in that it contains at least 0.05% by weight of at least one trialkoxyalkane of general formula (I) below:
- X corresponds to a divalent hydrocarbon group C H of which n is equal to 1, 2 or 3, each hydrogen atom being optionally substituted by a hydrocarbon residue,
- R, R 'and R'' are identical or different linear or branched alkyl groups comprising from 1 to 10 carbon atoms and optionally at least one oxygen atom, two of the groups R ⁇ , R' i and R '' ⁇ being optionally linked to form a heterocycle of 5 to 6 atoms;
- R being a hydrogen atom or a linear alkyl radical comprising from 1 to 4 carbon atoms, R possibly even forming, by bond with a hydrocarbon residue of X, a ring comprising from 5 to 6 carbon atoms.
- this fuel composition contains from 60 to 99.95% by weight of at least one fuel base and from 0.05 to 40% by weight of trialkoxyalkane of formula (I).
- fuel base any petroleum cut after refining, either by distillation or by treatment of these distilled cuts.
- the trialkoxyalkane is chosen from the trialkoxypropanes of formula (II) below:
- R- j _, R ' Q _ and R'' ⁇ are linear or branched alkyl groups, identical or different comprising from 1 to 10 carbon atoms and optionally at least one oxygen atom, two of the groups R 1 # R'-L and R'' ⁇ being optionally linked to form a heterocycle of 5 to 6 atoms;
- R2, R3, R4 and R'4 are identical or different groups representing hydrogen or a linear alkyl radical comprising from 1 to 4 carbon atoms, R possibly even forming, by bond with R or R ' 4, a ring comprising 5 to 6 carbon atoms.
- R 2 , R 3 , R 4 and R ' 4 are the hydrogen atom.
- R 1 , R'- L and R '' are identical and are chosen from alkyl groups comprising from 1 to 4 carbon atoms.
- trialkoxyalkane compounds thus obtained of the invention are chosen from the group consisting of trimethoxypropane, triethoxypropane, tripropoxypropane, tributoxypropane.
- R l ' R ' l and R '' l comprise from 1 to 4 carbons and at least one oxygen atom.
- R 1 is an alkyl group comprising from 1 to 4 carbon atoms and R ' ] _ and R''i are linked and constitute a link of 2 to 3 carbons so as to form with the two oxygen atoms a heterocycle of 5 to 6 atoms.
- R 1 is an alkyl group comprising from 1 to 4 carbon atoms and R ' ] _ and R''i are linked and constitute a link of 2 to 3 carbons so as to form with the two oxygen atoms a heterocycle of 5 to 6 atoms.
- 2- (2-hydroxyethyl) ethoxy-1,3,3-dioxolane is preferred.
- R 4 is an alkyl group of 1 to 4 carbon atoms
- R 2 , R 3 and R ' 4 are hydrogen atoms and RL
- R'-L and R '' 1 are alkyl groups comprising from 1 to 5 carbon atoms.
- 1, 1, 3-trimethoxybutane, 1, 1, 3-triethoxybutane, 1,1,3-tripropoxybutane and 1, 1, 3-tributoxybutane are preferred.
- R 2 or R 3 is an alkyl group comprising
- R 4 , R ' 4 and, R 2 or R 3 are hydrogen atoms
- R 1 ( R'-L and R' are alkyl groups comprising from 1 to 5 atoms carbon.
- R 3 and R 4 are hydrogen atoms
- R 2 and R ' 4 are linked to form a saturated ring comprising from 5 to 6 atoms of carbon
- R ] _, R'-L and R '' i are alkyl groups comprising from 1 to 5 carbon atoms.
- 1, 1, 3-triethoxycyclohexane is preferred.
- the fuel bases are chosen from refined cuts distilling between 170 and 370 ° C. containing at most 50% by weight of aromatics, and less than 0.2% by weight of sulfur-containing compounds.
- the cetane number of the 1,3,3-triethoxypropane prepared according to example 1 was measured according to standard ASTM D613, as a 20% mixture in two gas oils whose characteristics are indicated below:
- a compound having a cetane number greater than 70, and a boiling point of at least 160 ° C and a very low solubility in water can be considered as an ideal component usable in diesel.
Landscapes
- Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Emergency Medicine (AREA)
- Liquid Carbonaceous Fuels (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Solid Fuels And Fuel-Associated Substances (AREA)
Description
Claims
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
FR9707119A FR2764301B1 (fr) | 1997-06-09 | 1997-06-09 | Composition de carburant comprenant des composes oxygenes pour moteurs diesel |
FR9707119 | 1997-06-09 | ||
PCT/FR1998/001168 WO1998056879A1 (fr) | 1997-06-09 | 1998-06-08 | Composition de carburant comprenant des composes oxygenes pour moteurs diesel |
Publications (2)
Publication Number | Publication Date |
---|---|
EP0923628A1 true EP0923628A1 (fr) | 1999-06-23 |
EP0923628B1 EP0923628B1 (fr) | 2003-01-15 |
Family
ID=9507765
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP98929517A Expired - Lifetime EP0923628B1 (fr) | 1997-06-09 | 1998-06-08 | Composition de carburant comprenant des composes oxygenes pour moteurs diesel |
Country Status (10)
Country | Link |
---|---|
US (1) | US6113661A (fr) |
EP (1) | EP0923628B1 (fr) |
JP (1) | JP2000516991A (fr) |
AT (1) | ATE231179T1 (fr) |
DE (1) | DE69810746T2 (fr) |
DK (1) | DK0923628T3 (fr) |
ES (1) | ES2189188T3 (fr) |
FR (1) | FR2764301B1 (fr) |
NO (1) | NO990578L (fr) |
WO (1) | WO1998056879A1 (fr) |
Families Citing this family (16)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
FR2764301B1 (fr) * | 1997-06-09 | 1999-07-30 | Elf Antar France | Composition de carburant comprenant des composes oxygenes pour moteurs diesel |
US6843813B1 (en) * | 2000-06-07 | 2005-01-18 | Hugh Frederick Collins | Rejuvenation and/or cleaning of catalysts |
GB2368594A (en) * | 2000-08-17 | 2002-05-08 | Shell Int Research | Fuel compositions with reduced soot emissions |
US6514299B1 (en) * | 2000-11-09 | 2003-02-04 | Millennium Fuels Usa, Llc | Fuel additive and method therefor |
ATE376044T1 (de) * | 2001-09-18 | 2007-11-15 | Southwest Res Inst | Brennstoffe für homogen geladene verdichtungsgezündete maschinen |
FR2833607B1 (fr) * | 2001-12-19 | 2005-02-04 | Inst Francais Du Petrole | Compositions de carburants diesel contenant des acetals de glycerol |
BRPI0411849A (pt) * | 2003-06-24 | 2006-08-08 | Michiel Arjaan Kousemaker | processo para a fabricação de um composto contendo oxigênio como aditivo em combustìveis, em particular, em combustìveis a diesel, gasolina e ester metìlico de colza |
US20090090048A1 (en) * | 2007-10-05 | 2009-04-09 | Board Of Trustees Of Michigan State University | Fuel compositions with mono- or di- butyl succinate and method of use thereof |
CA2729659C (fr) * | 2008-07-16 | 2015-11-24 | Michio Ikura | Conversion du glycerol en composes oxygenes de type naphta |
DE102009055928A1 (de) * | 2009-11-27 | 2011-06-01 | Technische Universität Dortmund | Verfahren zur kontinuierlichen Herstellung von Glycerintertiärbutylethern |
AU2011269085B2 (en) * | 2010-06-22 | 2014-09-18 | Shell Internationale Research Maatschappij B.V. | Diesel fuel formulation |
EP2514804A1 (fr) * | 2011-04-19 | 2012-10-24 | Top-Biofuel GmbH & Co. KG | Utilisation de 1,1-dialkoxyalkanes pour l'augmentation du pouvoir antidétonant de l'essence |
US8679202B2 (en) | 2011-05-27 | 2014-03-25 | Seachange Group Llc | Glycerol containing fuel mixture for direct injection engines |
FI20110300A0 (fi) * | 2011-09-11 | 2011-09-11 | Neste Oil Oyj | Bensiinikoostumukset ja menetelmä niiden valmistamiseksi |
WO2015175876A1 (fr) | 2014-05-15 | 2015-11-19 | Seachange Group Llc | Mélanges de carburants à base de biodiesel et d'émulsion de glycérol |
CN116536091A (zh) * | 2022-06-15 | 2023-08-04 | 浙江吉利控股集团有限公司 | 一种汽油甲醇灵活燃料互溶防腐剂 |
Family Cites Families (16)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
FR868233A (fr) * | 1940-12-20 | 1941-12-24 | Carburants pour moteurs à combustion interne à injection | |
US2842432A (en) * | 1953-12-07 | 1958-07-08 | Texas Co | Supplementary fuel mixture for cold starting diesel engines |
US2897068A (en) * | 1955-07-21 | 1959-07-28 | Gulf Research Development Co | Motor fuel |
BR8000889A (pt) * | 1979-02-21 | 1980-10-21 | Basf Ag | Composicoes carburantes para motores diesel |
DE2911411C2 (de) * | 1979-03-23 | 1983-10-20 | Chemische Werke Hüls AG, 4370 Marl | Verwendung vov 1,1-Di-n-ethoxiethan als Dieselkraftstoff |
US4541837A (en) * | 1979-12-11 | 1985-09-17 | Aeci Limited | Fuels |
US4395267A (en) * | 1980-03-26 | 1983-07-26 | Texaco, Inc. | Novel method of extending a hydrocarbon fuel heavier than gasoline |
DE3231498A1 (de) * | 1982-08-25 | 1984-03-01 | Basf Ag, 6700 Ludwigshafen | Verfahren zur herstellung von harten, bruchfesten katalysatoren aus zeolith-pulver |
US5268008A (en) * | 1982-12-27 | 1993-12-07 | Union Oil Company Of California | Hydrocarbon fuel composition |
FR2544738B1 (fr) * | 1983-04-21 | 1986-02-28 | Inst Francais Du Petrole | Nouveaux constituants de carburants pour moteurs automobile ou diesel |
IT1177380B (it) * | 1984-12-11 | 1987-08-26 | Anic Spa | Estensori di gasolio per autotrazione e loro metodo di produzione |
US5262550A (en) * | 1992-04-30 | 1993-11-16 | Arco Chemical Technology, L.P. | Epoxidation process using titanium-rich silicalite catalysts |
JP3200149B2 (ja) * | 1992-05-08 | 2001-08-20 | 三菱レイヨン株式会社 | メタクリル酸合成用触媒の製造法 |
US5308365A (en) * | 1993-08-31 | 1994-05-03 | Arco Chemical Technology, L.P. | Diesel fuel |
FR2764301B1 (fr) * | 1997-06-09 | 1999-07-30 | Elf Antar France | Composition de carburant comprenant des composes oxygenes pour moteurs diesel |
US5746785A (en) * | 1997-07-07 | 1998-05-05 | Southwest Research Institute | Diesel fuel having improved qualities and method of forming |
-
1997
- 1997-06-09 FR FR9707119A patent/FR2764301B1/fr not_active Expired - Fee Related
-
1998
- 1998-06-08 DE DE69810746T patent/DE69810746T2/de not_active Expired - Fee Related
- 1998-06-08 EP EP98929517A patent/EP0923628B1/fr not_active Expired - Lifetime
- 1998-06-08 WO PCT/FR1998/001168 patent/WO1998056879A1/fr active IP Right Grant
- 1998-06-08 US US09/147,658 patent/US6113661A/en not_active Expired - Fee Related
- 1998-06-08 DK DK98929517T patent/DK0923628T3/da active
- 1998-06-08 JP JP11501763A patent/JP2000516991A/ja not_active Ceased
- 1998-06-08 ES ES98929517T patent/ES2189188T3/es not_active Expired - Lifetime
- 1998-06-08 AT AT98929517T patent/ATE231179T1/de not_active IP Right Cessation
-
1999
- 1999-02-08 NO NO990578A patent/NO990578L/no not_active Application Discontinuation
Non-Patent Citations (1)
Title |
---|
See references of WO9856879A1 * |
Also Published As
Publication number | Publication date |
---|---|
ES2189188T3 (es) | 2003-07-01 |
EP0923628B1 (fr) | 2003-01-15 |
DK0923628T3 (da) | 2003-05-05 |
DE69810746D1 (de) | 2003-02-20 |
US6113661A (en) | 2000-09-05 |
FR2764301A1 (fr) | 1998-12-11 |
WO1998056879A1 (fr) | 1998-12-17 |
NO990578L (no) | 1999-04-06 |
ATE231179T1 (de) | 2003-02-15 |
JP2000516991A (ja) | 2000-12-19 |
NO990578D0 (no) | 1999-02-08 |
DE69810746T2 (de) | 2003-11-20 |
FR2764301B1 (fr) | 1999-07-30 |
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