EP0901810B1 - Verfahren und Vorrichtung zur kontinuierlichen Vermischung einer Tröpfchendispersion mit einer Flüssigkeit - Google Patents
Verfahren und Vorrichtung zur kontinuierlichen Vermischung einer Tröpfchendispersion mit einer Flüssigkeit Download PDFInfo
- Publication number
- EP0901810B1 EP0901810B1 EP98115928A EP98115928A EP0901810B1 EP 0901810 B1 EP0901810 B1 EP 0901810B1 EP 98115928 A EP98115928 A EP 98115928A EP 98115928 A EP98115928 A EP 98115928A EP 0901810 B1 EP0901810 B1 EP 0901810B1
- Authority
- EP
- European Patent Office
- Prior art keywords
- flow
- liquid
- vessel
- droplet dispersion
- flow direction
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
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Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01F—MIXING, e.g. DISSOLVING, EMULSIFYING OR DISPERSING
- B01F23/00—Mixing according to the phases to be mixed, e.g. dispersing or emulsifying
- B01F23/40—Mixing liquids with liquids; Emulsifying
- B01F23/45—Mixing liquids with liquids; Emulsifying using flow mixing
- B01F23/451—Mixing liquids with liquids; Emulsifying using flow mixing by injecting one liquid into another
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01F—MIXING, e.g. DISSOLVING, EMULSIFYING OR DISPERSING
- B01F25/00—Flow mixers; Mixers for falling materials, e.g. solid particles
- B01F25/30—Injector mixers
- B01F25/31—Injector mixers in conduits or tubes through which the main component flows
- B01F25/314—Injector mixers in conduits or tubes through which the main component flows wherein additional components are introduced at the circumference of the conduit
Definitions
- a variety of technical processes for the production of fine-particle spherical Polymers or microcapsules is based on the fact that initially a droplet dispersion or cores of finely divided, liquid or with a liquid shell solid material are generated, then by adding another Liquid, e.g. a hardener or an acid or base to change the pH the dispersion the droplets or the liquid surrounding the particles Shell is hardened or stabilized.
- a hardener or an acid or base to change the pH the dispersion the droplets or the liquid surrounding the particles Shell is hardened or stabilized.
- the problem is that the liquid is so gentle in the droplet dispersion to interfere that an agglomeration and coalescence of the droplets and thus a Disruption of the droplet size distribution is avoided.
- the widely used microencapsulation process by coacervation or complex coacervation a droplet dispersion in one aqueous gelatin solution or an aqueous solution of gelatin and gum arabic generated at substantially neutral pH, the droplets with a Gelatin layer can be covered.
- the encapsulation is carried out by adding a copolymer with the addition of an aqueous solution of an inorganic acid, if appropriate with subsequent lowering of the temperature of the dispersion.
- Capsules are already so stable that they can be washed and, if necessary, added of formalin can be hardened with an increase in pH.
- the suspension very sensitive to droplets coated with gelatin before acidification against mechanical stress. The mixture with the acid solution must therefore done very gently.
- the object of the present invention is to provide a method and an apparatus for continuous mixing of a droplet dispersion with a liquid Introducing the liquid into a container through which the droplet dispersion flows to provide, in which the mixing of the liquid is gentle, i.e. if possible low mechanical stress is carried out.
- the droplet dispersion is preferably axial to excite the circulating flow introduced into a cylindrical container, the introduction speed of the Droplet dispersion is 15 to 100 times larger than that due to the throughput average velocity determined by the cylindrical container ("throughflow velocity"). This causes an axial forward flow in the cylindrical container and a peripheral reverse flow with a corresponding flow deflection generated at a distance from the point of introduction for the droplet dispersion by the Droplet is run through several times.
- the flow rate can through the cylindrical container in the range of 0.1 to 0.5 cm / s.
- the introduction point for the droplet dispersion preferably projects axially into the cylindrical one Containers so that the cylindrical container on the back to the discharge point has an annular space in which the return flow is deflected into a forward flow becomes.
- the liquid to be mixed into the droplet dispersion is preferably by the jacket of the cylindrical container is injected into the backflow.
- the cylindrical container jacket has a plane perpendicular to the container axis Large number of nozzles through which the liquid is introduced.
- the introduction speed for the liquid it can typically be 1 to 5 m / s.
- the liquid jets are preferably injected with a directional component against the peripheral backflow of the droplet dispersion, so that the Liquid jets in the area surrounding the introduction point for the droplet dispersion Annulus create a peripheral forward flow.
- the Ring space surrounding the inlet point causes a particularly intensive mass transfer.
- the impulse component introduced by the liquid jets parallel to the container axis can be in the order of magnitude of the momentum input by the droplet dispersion lie, in particular about 1 to 10 times the momentum input by the Droplet dispersion.
- the introduction takes place the droplet dispersion in the cylindrical container from the bottom up when the Droplets have a lower specific gravity than the continuous Phase.
- the droplets experience a buoyancy, which leads to the fact that in the droplet concentration in the annular space surrounding the point of introduction for the droplet dispersion impoverished. Accordingly, the existing in the annulus peripheral upward flow has a reduced droplet concentration. This is particularly important if, for reasons of economy, droplet dispersions used with very high droplet concentrations of 40 to 60 vol% become.
- the liquid is then injected into a droplet dispersion with significantly reduced droplet concentration, so the risk the agglomeration of droplets in the area of the injection is further reduced.
- the flow direction through the cylindrical is preferred Container selected from top to bottom if the droplets have a greater density, than the continuous phase.
- Fig. 1 shows in principle a container 1 in the form of a cylindrical column with a axially arranged inlet pipe 2 for the droplet dispersion.
- the generation of the Droplet dispersion can be carried out by methods known per se. For example can the droplet dispersion by spraying the liquid forming the droplet be produced in an aqueous gelatin solution.
- On a circumferential line perpendicular to Axis 3 of the cylindrical container 1 are a plurality of nozzles 4, for example provided with a diameter of 0.4 mm.
- the number of nozzles can be, for example 12 to 120.
- the nozzles are fed from an annular channel 5, in the the liquid is introduced through one or more supply lines 6.
- the cross-sectional area the inlet tube 2 for the droplet dispersion can 1/12 to 1/45 of Cross-sectional area of the cylindrical container 1 amount.
- Droplet dispersion shear rate below 20 / s, preferably below 10 / s.
- the estimate of the shear rate is double Inflow velocity of the droplet dispersion through half the container radius divided.
- the inlet pipe 2 for the droplet dispersion projects at least over one Length, which corresponds to the radius of the container 1, into this, so that the rear an annular space 7 is formed by the inlet point, in which the return flow 11 is deflected becomes.
- the nozzles 4 are inclined upwards directed so that a peripheral forward flow 13 is excited in the annular space 7 becomes.
- Fig. 2 shows an enlarged view of the flow conditions in the area of Annulus 7, the dashed lines 21 and 22 the boundaries between the Flow areas with a forward component on the one hand and a backflow component otherwise specify.
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Manufacturing Of Micro-Capsules (AREA)
Description
- Fig. 1
- zeigt eine erfindungsgemäße Vorrichtung zur kontinuierlichen Vermischung einer Tröpfchendispersion mit einer Flüssigkeit.
- Fig. 2
- zeigt in vergrößerter Darstellung den Bereich der Einleitung von Tröpfchendispersion und Flüssigkeit mit den dort herrschenden Strömungsverhältnissen.
Claims (10)
- Verfahren zur kontinuierlichen Vermischung einer Tröpfchendispersion mit einer Flüssigkeit durch Einleiten der Flüssigkeit in einen von der Tröpfchendispersion durchströmten Behälter (1), dadurch gekennzeichnet, daß die Flüssigkeit in Form einer Vielzahl feiner Flüssigkeitsstrahlen in die Tröpfchendispersion injiziert wird, so daß die kinetische Energie der Flüssigkeitsstrahlen auf kurze Entfernung von der Injektionsstelle dissipiert und die weitere Vermischung durch eine in dem Behälter (1) erzeugte Umwälzströmung (10,11) mit Schergeschwindigkeiten unterhalb 20/s erfolgt.
- Verfahren nach Anspruch 1, dadurch gekennzeichnet, daß die Tröpfchendispersion axial mit einer Geschwindigkeit, die 15- bis 100-mal größer ist als die Durchströmgeschwindigkeit durch den Behälter (1), in diesen rückströmungsfrei eingeleitet wird.
- Verfahren nach Anspruch 1 oder 2, dadurch gekennzeichnet, daß die Flüssigkeitsstrahlen einen Durchmesser von 0,1 bis 0,8 mm aufweisen.
- Verfahren nach einem der Ansprüche 1 bis 3, dadurch gekennzeichnet, daß die Maximalgeschwindigkeit der Umwälzströmung 5- bis 20-mal größer ist als die Durchströmgeschwindigkeit.
- Verfahren nach einem der Ansprüche 1 bis 4, dadurch gekennzeichnet, daß die Umwälzströmung aus einer axialen Strömung (10) in Durchströmrichtung und einer peripheren Rückströmung (11) besteht.
- Verfahren nach einem der Ansprüche 1 bis 5, dadurch gekennzeichnet, daß die Injektion der Flüssigkeit in einer Ebene, die in bezug auf die Durchströmrichtung etwa in Höhe der Einleitstelle für die Tröpfchendispersion liegt, mit einer Strömungskomponente in Durchströmrichtung erfolgt, so daß unterhalb der Ebene eine periphere Strömung (13) in Durchströmrichtung erzeugt wird.
- Verfahren nach einem der Ansprüche 1 bis 6, dadurch gekennzeichnet, daß die Durchströmrichtung (10) nach oben gerichtet wird, wenn die Tröpfchen spezifisch leichter als das Dispergiermedium sind, bzw. nach unten, wenn die Tröpfchen spezifisch schwerer als das Dispergiermedium sind.
- Vorrichtung zur kontinuierlichen Vermischung einer Flüssigkeit mit einer Tröpfchendispersion enthaltend einen zylindrischen Behälter (1) mit einem zentralen Einlaß (2) für die Tröpfchendispersion und einer Vielzahl von Injektionsdüsen (4) mit geringem Durchmesser, die in einer Schnittebene der Behälterwand senkrecht zur Achse (3) und in Durchströmrichtung (10) etwa in Höhe des Einlasses (2) in den Behälter (1) münden.
- Vorrichtung nach Anspruch 8, wobei die Injektionsdüsen (4) eine Richtungskomponente in Durchströmrichtung aufweisen und der Einlaß als in den Behälter (1) hineinragendes Einlaßrohr (2) ausgebildet ist, so daß der Behälter (1) rückseitig zur Einlaßstelle einen das Einlaßrohr (2) umgebenden Ringraum (7) aufweist.
- Vorrichtung nach Anspruch 8 oder 9, wobei das Einlaßrohr (2) eine Querschnittsfläche von 1/12 bis 1/45 der Behälterquerschrittsfläche aufweist.
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE19738870A DE19738870A1 (de) | 1997-09-05 | 1997-09-05 | Verfahren und Vorrichtung zur kontinuierlichen Vermischung einer Tröpfchendispersion mit einer Flüssigkeit |
DE19738870 | 1997-09-05 |
Publications (3)
Publication Number | Publication Date |
---|---|
EP0901810A2 EP0901810A2 (de) | 1999-03-17 |
EP0901810A3 EP0901810A3 (de) | 2001-02-07 |
EP0901810B1 true EP0901810B1 (de) | 2003-02-12 |
Family
ID=7841320
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP98115928A Expired - Lifetime EP0901810B1 (de) | 1997-09-05 | 1998-08-24 | Verfahren und Vorrichtung zur kontinuierlichen Vermischung einer Tröpfchendispersion mit einer Flüssigkeit |
Country Status (5)
Country | Link |
---|---|
US (2) | US6102309A (de) |
EP (1) | EP0901810B1 (de) |
JP (1) | JPH11137985A (de) |
DE (2) | DE19738870A1 (de) |
HU (1) | HUP9802004A3 (de) |
Families Citing this family (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE10206103A1 (de) * | 2002-02-13 | 2003-08-21 | Basf Ag | Vorrichtung und Verfahren zur Herstellung von Formkörpern aus thermoplastischen Polymeren |
SE525983C2 (sv) * | 2003-10-13 | 2005-06-07 | Metso Paper Inc | Blandningsanordning för inblandning av ett vätskeformigt medium i ett annat vätskeformigt medium |
DE102005056723B4 (de) * | 2005-11-29 | 2012-08-30 | Roland Damann | Vorrichtung zum Vermischen und Reagieren eines Gases und/oder einer Flüssigkeit mit einem flüssigen Medium |
GB201604412D0 (en) * | 2016-03-15 | 2016-04-27 | King S College London | Method and system pressure drop estimation |
NL2023054B1 (en) * | 2019-05-02 | 2020-11-23 | Water Iq Int B V | Mixing device for mixing hydrogen peroxide and water |
Family Cites Families (19)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
GB189627086A (en) * | 1896-05-30 | 1897-01-30 | Stanislas Dominique Gillet | A New or Improved Burner for Lighting by Acetylene or other Gases Rich in Carbon. |
US3242051A (en) * | 1958-12-22 | 1966-03-22 | Ncr Co | Coating by phase separation |
US3234307A (en) * | 1962-10-03 | 1966-02-08 | Dow Chemical Co | Process for preparing pellets of substituted phenols |
BE658300A (de) * | 1964-01-24 | |||
CH519448A (de) * | 1968-04-11 | 1972-02-29 | Inventa Ag | Mischvorrichtung |
US3419082A (en) * | 1967-03-16 | 1968-12-31 | Bliss E W Co | Portable foam nozzle |
JPS5273202A (en) * | 1975-12-13 | 1977-06-18 | Mitsubishi Heavy Ind Ltd | Suction type fluid mixing nozzle |
DE3168828D1 (en) | 1980-12-02 | 1985-03-21 | Shell Int Research | Filler gun suitable for cavity injection |
US4411398A (en) * | 1981-04-20 | 1983-10-25 | General Dynamics, Pomona Division | Double fabric retractable wing construction |
NL8104179A (nl) * | 1981-09-10 | 1983-04-05 | Talmer B V | Werkwijze voor het toevoeren van vezelig isolatiemateriaal, in het bijzonder glaswolvezels, in de spouw van een spouwmuur. |
US4637905A (en) * | 1982-03-04 | 1987-01-20 | Batelle Development Corporation | Process of preparing microcapsules of lactides or lactide copolymers with glycolides and/or ε-caprolactones |
US4545157A (en) * | 1983-10-18 | 1985-10-08 | Mccartney Manufacturing Company | Center feeding water jet/abrasive cutting nozzle assembly |
US4738614A (en) * | 1986-07-25 | 1988-04-19 | Union Carbide Corporation | Atomizer for post-mixed burner |
US5126381A (en) * | 1988-12-19 | 1992-06-30 | Dow Corning Corporation | Bead processor |
US5173007A (en) * | 1989-10-23 | 1992-12-22 | Serv-Tech, Inc. | Method and apparatus for in-line blending of aqueous emulsion |
FR2689418B1 (fr) * | 1992-04-03 | 1994-07-01 | Centre Nat Rech Scient | Procede de preparation de micro-capsules ou de liposomes de tailles controlees par application d'un cisaillement constant sur une phase lamellaire. |
US5637350A (en) * | 1994-05-13 | 1997-06-10 | A.P.I. Asphalt Prilling Inc. | Encapsulation of asphalt prills |
DE4421352C2 (de) * | 1994-06-17 | 1997-03-20 | Specker Helmut | Verfahren und Vorrichtung zum Verdünnen eines Flüssigkonzentrats mit Wasser |
US5645223A (en) * | 1995-10-19 | 1997-07-08 | Hull; Harold L. | Liquid/foam/mixing/aeration adapter apparatus |
-
1997
- 1997-09-05 DE DE19738870A patent/DE19738870A1/de not_active Withdrawn
-
1998
- 1998-08-24 DE DE59807165T patent/DE59807165D1/de not_active Expired - Lifetime
- 1998-08-24 EP EP98115928A patent/EP0901810B1/de not_active Expired - Lifetime
- 1998-08-31 JP JP10259107A patent/JPH11137985A/ja active Pending
- 1998-09-03 US US09/148,021 patent/US6102309A/en not_active Expired - Lifetime
- 1998-09-03 HU HU9802004A patent/HUP9802004A3/hu unknown
-
1999
- 1999-07-27 US US09/361,850 patent/US6170761B1/en not_active Expired - Lifetime
Also Published As
Publication number | Publication date |
---|---|
JPH11137985A (ja) | 1999-05-25 |
US6102309A (en) | 2000-08-15 |
EP0901810A2 (de) | 1999-03-17 |
EP0901810A3 (de) | 2001-02-07 |
DE59807165D1 (de) | 2003-03-20 |
US6170761B1 (en) | 2001-01-09 |
DE19738870A1 (de) | 1999-03-18 |
HUP9802004A3 (en) | 2000-06-28 |
HU9802004D0 (en) | 1998-12-28 |
HUP9802004A2 (hu) | 1999-04-28 |
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