EP0888225B1 - Etiquette imprimee par transfert - Google Patents

Etiquette imprimee par transfert Download PDF

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Publication number
EP0888225B1
EP0888225B1 EP97903262A EP97903262A EP0888225B1 EP 0888225 B1 EP0888225 B1 EP 0888225B1 EP 97903262 A EP97903262 A EP 97903262A EP 97903262 A EP97903262 A EP 97903262A EP 0888225 B1 EP0888225 B1 EP 0888225B1
Authority
EP
European Patent Office
Prior art keywords
layer
protective film
substrate
transfer label
adhesive
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Revoked
Application number
EP97903262A
Other languages
German (de)
English (en)
Other versions
EP0888225A1 (fr
Inventor
Hans-Peter Ast
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Steinbeis PPL GmbH
Original Assignee
Steinbeis PPL GmbH
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Family has litigation
First worldwide family litigation filed litigation Critical https://patents.darts-ip.com/?family=8019361&utm_source=google_patent&utm_medium=platform_link&utm_campaign=public_patent_search&patent=EP0888225(B1) "Global patent litigation dataset” by Darts-ip is licensed under a Creative Commons Attribution 4.0 International License.
Application filed by Steinbeis PPL GmbH filed Critical Steinbeis PPL GmbH
Publication of EP0888225A1 publication Critical patent/EP0888225A1/fr
Application granted granted Critical
Publication of EP0888225B1 publication Critical patent/EP0888225B1/fr
Anticipated expiration legal-status Critical
Revoked legal-status Critical Current

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Classifications

    • G—PHYSICS
    • G09—EDUCATION; CRYPTOGRAPHY; DISPLAY; ADVERTISING; SEALS
    • G09F—DISPLAYING; ADVERTISING; SIGNS; LABELS OR NAME-PLATES; SEALS
    • G09F3/00—Labels, tag tickets, or similar identification or indication means; Seals; Postage or like stamps
    • G09F3/08—Fastening or securing by means not forming part of the material of the label itself
    • G09F3/10—Fastening or securing by means not forming part of the material of the label itself by an adhesive layer
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B44—DECORATIVE ARTS
    • B44C—PRODUCING DECORATIVE EFFECTS; MOSAICS; TARSIA WORK; PAPERHANGING
    • B44C1/00—Processes, not specifically provided for elsewhere, for producing decorative surface effects
    • B44C1/16—Processes, not specifically provided for elsewhere, for producing decorative surface effects for applying transfer pictures or the like
    • B44C1/165—Processes, not specifically provided for elsewhere, for producing decorative surface effects for applying transfer pictures or the like for decalcomanias; sheet material therefor
    • B44C1/17—Dry transfer
    • B44C1/1712—Decalcomanias applied under heat and pressure, e.g. provided with a heat activable adhesive
    • B44C1/172—Decalcomanias provided with a layer being specially adapted to facilitate their release from a temporary carrier

Definitions

  • the invention relates to a transfer label, with a carrier material layer, one detachable on the carrier material layer arranged, attachable to an object by means of adhesive Imprint layer and one between the carrier material layer and the print layer arranged from the Carrier material layer removable protective layer.
  • a label of this type is known from W090 / 05088.
  • a high gloss coated substrate and a layer of release material for the layers to be transferred to the substrate provided which in the transfer of the Labels on the item are activated by heat in this way is that they detach the layers to be transferred from the carrier material. If this separating material layer is missing, the carrier material can not be from the still heated Peel off the label.
  • an additional protective layer is applied to the object, and then it is hardened under UV radiation. This post-curing process takes a relatively long time Running distance and is mechanically complex. This is especially true if the items are beverage glass bottles acts to reduce friction in crowded areas of bottle filling systems covered with a plastic layer which are to be spared with UV radiation.
  • a transfer label is known from US Pat. No. 4,529,624 Outer layer over a meltable during transmission Paraffin layer is connected to the carrier material. The Paraffin layer remains on the label after transfer, residues may remain on the carrier. The transfer is therefore not always complete.
  • the paraffin layer is smoothed by subsequent flame treatment and therefore more transparent and shiny and less visible.
  • the object of the invention is therefore to provide a transfer label, that can be transferred without residue to an object is and does not require after-treatment.
  • the parting line between carrier material and protective film is special precisely defined, so that the label is targeted from the carrier material peel off and apply smoothly.
  • the interaction the adjoining surfaces of protective film and Backing material is based on adhesive forces, such as electrostatic Powers. After separating the label from the Backing material and transfer to the object now remains the exposed surface of the protective film is independent of temperature not adhesive.
  • the protective film is hard and scratch-resistant.
  • the carrier material layer and the protective film preferably form a material pairing with essentially temperature-independent predetermined holding force.
  • the carrier material layer can be made of consist of several sub-layers.
  • the carrier material layer is preferably present at least on the one facing the protective film Polypropylene side, the protective film Side is preferably untreated.
  • the thickness of the substrate can be 20 to 100 microns, preferably 35 to 60 microns. So that the combination of carrier material layer and transfer labels can easily unwind from a roll, the side of the carrier material layer that repels the protective film have a non-stick finish, such as siliconized or Separating varnish.
  • the protective film is preferably made of radiation curing Lacquer, especially cationically cold-crosslinked, under ultraviolet light curing lacquer formed. Cold-curing Cationic UV varnish hardens under UV radiation out. The chain reaction begins with UV light. The networking and curing takes place completely without further UV exposure. The protective film remains after curing non-sticky.
  • An electron beam hardener is also an option Paint.
  • the paint used should be heat stable so that it is Properties under the influence of heat application in the Transmission does not change.
  • the protective film consists of non-sticky paints.
  • the protective film is thinner than the carrier material layer, preferred by a factor of 2 to a factor of 100, particularly preferred 10 to 20.
  • the protective film is preferably 1 to 10 ⁇ m thick, particularly preferably 2.5 to 5 ⁇ m. The thinner the protective film the lower the label transfer required Thermal energy and the lower the thermal load of the object. This is of particular concern, though the object is a slide with plastic coated beverage glass bottle.
  • the Protective film can be stretched, with an elongation at break in the range of about 50-400%, preferably about 100-300%, preferred 150-250%, preferably about 200%.
  • a PE or PP protective layer also comes in as a protective film Question (polyethylene or polypropylene), which by adhesion does not adhere to the substrate layer.
  • the Protective film can be co-extruded with the backing material layer his.
  • the print layers can be made from solvent-based lacquers consist. They are preferably water-insoluble, heat-resistant, colourfast, tonal stable, opaque and heat stable.
  • the print layer and Protective film it can happen that the print layers only adhere poorly directly to the protective film, for example if it contains solvents Layers on a cationically UV-cured Protective film should be printed. Recommended in these cases a suitable one before printing on the printing layers Print the primer layer on the protective film.
  • the primer layer acts as an adhesion promoter.
  • the primer layer can be single-layer and have non-adhesive properties also as a barrier against immigration from solvents the print layer act in the protective film.
  • the primer layer can have a protective film-side adhesive layer and on top have an additional barrier layer, or from the protective film starting an adhesive layer, a barrier layer and another adhesive layer, on which the printed layers are then placed to be printed.
  • the elasticity of the print layer and possibly the primer layer, the barrier layer and the adhesive layer (s) can be adapted to that of the protective film, the extensibility of the individual layers from the adhesive side to the protective film side can decrease. This allows damage-free Transfer the label to the item at the same time high protective effect of the protective film.
  • the adhesive layer can consist of a pressure sensitive adhesive, a first After a single heat exposure, permanently adhesive thermo-activatable Glue or just sticky during heating thermosensitive adhesive can be formed.
  • thermo-activatable adhesive can be a two-component adhesive be a component or a reactant is in microcapsules that are exposed to heat burst and then a mixture of the two components and this causes a curing reaction.
  • the usage such two-component adhesives when gluing of labels on objects is independent of the construction of the label.
  • the object When sticking the label on the object should use a thermally activated adhesive is the object be preheated as precisely as possible to that temperature at which is to be warmed up during application.
  • the Temperature should be in a range where a friction-reducing Plastic coating of a label Glass bottle is not damaged.
  • the label is produced by printing on the respective one Layers in succession on the carrier material layer, wherein the protective film and the print or color layers and if necessary the primer is essentially the same shape on the substrate layer be printed on.
  • the protective film can protect the edges of the color layers overlap them.
  • the adhesive layer also has the same contour as the layers of paint and printed on the protective film.
  • a carrier material 1 the multi-layer of coextruded Polypropylene or polyethylene on a paper backing can be formed and have a thickness of 20 to 100 microns has a low-adhesion surface 1a of the polypropylene with low surface energy. With coextrusion several thermoplastic materials are common extruded. The result is multilayer films that face each other simple foils have the advantage that the individual Layers can have different functions (e.g. smooth outer layer for good printing or inner layers with adhesive surface for low blocking effect).
  • the polypropylene or polyethylene is untreated so that it has a low surface energy or surface tension from e.g. 28-32 mN / m.
  • On this little sticky surface 1a is contoured a preferably prepolymerized protective layer printed on.
  • the protective layer is closed polymerized through a protective film that no longer through Dissolution of its cohesion is plastifiable.
  • the immediately superimposed surfaces 1 a of the carrier material 1 and 3a of the protective film adhere through physical adhesion on each other, such as electrostatic forces. By adhesion the protective film 3 adheres only slightly to the carrier material 1, does not stick relatively firmly, such as with pressure sensitive adhesives.
  • the adhesive effect is independent of temperature.
  • the protective film 3 consists preferably of cationically cold-crosslinking, under UV radiation curing varnish, which is a chain reaction due to UV light starts and cures completely and after curing remains non-sticky.
  • the thickness of the protective film is 1 to 10 ⁇ m, preferably 2.5 - 2 ⁇ m.
  • the protective film for absorbing tensile and crushing forces as well as distortions during the transmission process elastic on the object, for example with an elasticity in the Range of about 50-400%, about 100-300%, in particular about 150 - 250%, preferably about 200% according to DIN 53455 (elongation at break of the protective film material).
  • the UV-curing agent preferably contains Protective film in its basic composition acrylic acid polymers, about 40% by weight polyurethane-acrylate polymer mixture, approx. 20% by weight of monofunctional octyl decyl acrylate and about 35 wt% tri-propylene glycol di-acrylate (TPGDA), and the rest additives.
  • a color layer 5 of preferably solvent-based Lacquer printed On the protective film 3, its contours are essentially following, a color layer 5 of preferably solvent-based Lacquer printed.
  • This paint is - like the protective film also - heat stable. Furthermore, the color layer is insoluble in water, heat-resistant, colourfast, tonal value and opaque.
  • the color layer 5 Cold-adhesive or heat-activated adhesive layer 7 printed with the same contour with ink layer 5 and protective film 3.
  • the thickness of the adhesive layer 7 is 2 to 40 microns.
  • Prefers is the elasticity of the color layer 5 on that of Adapted protective film and is in particular larger than that of Protective film.
  • the surface of an object G is preferably the object preheated to the adhesive temperature of the adhesive layer 7. Then the carrier material with the adhesive adhering to it Label on the item using a hot plate or Heat roller pressed on, so that the adhesive layer 7 sticky and with it the contour-like color layer 5 and protective film layer 3 stick to the object. Then it will be the carrier material in the parting plane designated T in FIG. 1 peeled and removed from the protective film 3.
  • the stripping of the carrier material - for example when using a transfer roller, also just before sticking the label on the object, or if, for example, the label on the Object must be massaged, even after sticking.
  • the elasticity of the carrier tape material is significantly less than that of the label layers 3, 5 and 7, preferably 50 - 150%.
  • the UV-hardened protective film layer 3 protects the label against scratching. As a result of the adhesive bond after the separation of the carrier material 1 is neither this still the protective film 3 sticky.
  • the contours of the protective film can match those of the color and Overlap the adhesive layer a little so that when transferred Label the protective film also the contour edges of color and covers and protects adhesive layer.
  • FIG. 2 shows a further embodiment of a transfer label. Layers corresponding to the above embodiment are the same Provide reference numbers, increased by the number 100.
  • a primer layer 109 is printed on the protective film 103, which can simultaneously form a barrier against it leaking solvents to be printed on color layers.
  • the primer layer can have several sublayers, for Example an adhesion promoting layer 109a on the protective film 103, a barrier layer 109b against migrating solvents and then an adhesive layer 109c for the color layers 105 printed thereon.
  • Five layers of color 105a to 105e are shown. Of course, any other number of layers of paint conceivable.
  • the color layers are like above around solvent-based paints that are heat-stable, insoluble in water, colourfast, tonal value stable and opaque.
  • the extensibility of the primer layer (s) 109a-c and here the Color layer (s) 105a-e can each be attached to that of the protective film 103 be adapted.
  • the stretchability of the Primer layer (s) between that of the protective film 103 and the the color layer (s) 105a-e can be adapted.
  • the last color layer 105e then has the same shape Protective film 103, primer layer 109 and the at least one Color layer 105 is a thermally activated adhesive layer 107 printed on, which are designed as in the first embodiment can be.
  • the carrier material 101 faces the protective film 103 repellent side an adhesive layer 101b Silicone or release varnish, which prevents that when wound Carrier tape material 101 having a plurality thereon adhesive labels, the adhesive layer 107 of the next Position of labels in the roll on the carrier tape material 101 sticks.
  • the extensibility of the carrier tape material 101 is significantly less than that of the label layers 103, 105, 109 and is about 50-150%.

Claims (15)

  1. Étiquette de transfert, comportant une couche de matériau substrat (1), une couche d'impression (5) placée de manière amovible sur la couche de matériau substrat et pouvant se fixer sur un objet au moyen d'un adhésif (7), et une couche de protection (3) placée entre la couche de matériau substrat (1) et la couche d'impression (5) et pouvant se détacher de la couche de matériau substrat (1),
       caractérisée en ce que
       la couche de protection est conformée en film protecteur (3) pour l'essentiel non plastifiable, tenant directement par adhérence à la couche de matériau substrat (1), mais pouvant se détacher d'une manière sensiblement indépendante de la température de l'étiquette et composée d'un matériau entièrement polymérisé.
  2. Étiquette de transfert selon la revendication 1, caractérisée en ce que la couche de matériau substrat (1) et le film protecteur (3) forment une paire de matériaux présentant une force de fixation prédéterminée pour l'essentiel indépendante de la température.
  3. Étiquette de transfert selon la revendication 1 ou 2, caractérisée en ce que la couche de matériau substrat (1) se compose, au moins sur sa face tournée vers le film protecteur (3), de polypropylène dont la face (la) portant le film protecteur (3) est de préférence dépourvue de traitement préalable.
  4. Étiquette de transfert selon l'une des revendications précédentes, caractérisée en ce que le film protecteur (3) se compose d'une laque durcissant par irradiation, en particulier une laque réticulée à froid par voie cationique et durcissant sous de la lumière ultraviolette.
  5. Étiquette de transfert selon l'une des revendications précédentes, caractérisée en ce que la couche d'impression (5) au nombre d'au moins une est formée d'une laque à solvants.
  6. Étiquette de transfert selon l'une des revendications précédentes, caractérisée en ce que la couche d'impression (105) au nombre d'au moins une tient sur le film protecteur (103) au moyen d'une couche de primaire (109).
  7. Étiquette de transfert selon la revendication 6, caractérisée en ce que la couche de primaire (109) présente au moins une sous-couche d'adhérence (109a, 109c) et une sous-couche barrière (109b) contre la migration des solvants dans le film protecteur (103).
  8. Étiquette de transfert selon l'une des revendications précédentes, caractérisée en ce que la couche d'adhésif (7) est formée d'un adhésif d'adhérence ou d'un adhésif ne collant durablement qu'après une application unique de chaleur ou d'un adhésif thermoactivable ou d'un adhésif thermosensible ne collant que pendant le chauffage.
  9. Étiquette de transfert selon l'une des revendications précédentes, caractérisée en ce que le film protecteur (3), la couche d'impression (5) au nombre d'au moins une et la couche d'adhésif (7) sont imprimée les uns après les autres sensiblement selon les mêmes contours sur la couche de matériau substrat.
  10. Étiquette de transfert selon l'une des revendications précédentes, caractérisée en ce que le film protecteur (3) est extensible, en particulier avec une extensibilité comprise entre 50 et 400 %, de préférence entre 100 et 300 %, de préférence entre 150 et 250 %, de plus grande préférence 200 %.
  11. Étiquette de transfert selon l'une des revendications précédentes, caractérisée en ce que le film protecteur (3) comprend, dans sa composition de base, des polymères de l'acide acrylique, de préférence environ 40 % de mélange de polymère polyuréthane-acrylate, 20 % d'octyl-décyl-acrylate monofonctionnel et 35 % de tri-propylène-glycol-diacrylate, et le reste sous forme d'additifs.
  12. Étiquette de transfert selon l'une des revendications 6 à 11, caractérisée en ce que l'extensibilité de la couche d'impression (5, 105) et, le cas échéant, l'extensibilité de la couche de primaire (109), sont adaptées à l'extensibilité du film protecteur (3, 103).
  13. Étiquette de transfert selon l'une des revendications précédentes, caractérisée en ce que l'extensibilité respective des couches à transférer (3, 5, 7 ; 103, 109, 105, 107) de l'étiquette décroít du côté de l'adhésif au côté de la couche protectrice.
  14. Étiquette de transfert selon l'une des revendications précédentes, caractérisée en ce que l'extensibilité de la couche de matériau substrat (1, 101) est inférieure à l'extensibilité des couches à transférer (3, 5, 7 ; 103, 109, 105, 107) de l'étiquette.
  15. Procédé de fabrication d'une étiquette de transfert, en particulier selon la revendication 1, caractérisé par les étapes suivantes :
    1) préparation d'une couche de matériau substrat (1),
    2) impression en contours d'une couche de protection composée d'un matériau à réticuler directement sur la couche de matériau substrat (1),
    3) polymérisation complète de la couche de protection pour former un film protecteur (3) pour l'essentiel non plastifiable qui, par adhérence, tient sur la couche de matériau substrat (1) pour l'essentiel indépendamment de la température de l'étiquette, d'une manière détachable de la couche de matériau substrat (1),
    4) impression en contours d'au moins une couche d'impression (5) sur le film protecteur (3),
    5) impression en contours d'adhésif (7) sur la couche d'impression (5).
EP97903262A 1996-02-12 1997-02-12 Etiquette imprimee par transfert Revoked EP0888225B1 (fr)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
DE1996202430 DE29602430U1 (de) 1996-02-12 1996-02-12 Transferetikett
DE29602430U 1996-02-12
PCT/EP1997/000642 WO1997028974A1 (fr) 1996-02-12 1997-02-12 Etiquette imprimee par transfert

Publications (2)

Publication Number Publication Date
EP0888225A1 EP0888225A1 (fr) 1999-01-07
EP0888225B1 true EP0888225B1 (fr) 2000-05-10

Family

ID=8019361

Family Applications (1)

Application Number Title Priority Date Filing Date
EP97903262A Revoked EP0888225B1 (fr) 1996-02-12 1997-02-12 Etiquette imprimee par transfert

Country Status (5)

Country Link
EP (1) EP0888225B1 (fr)
DE (2) DE29602430U1 (fr)
ES (1) ES2146979T3 (fr)
HK (1) HK1015325A1 (fr)
WO (1) WO1997028974A1 (fr)

Families Citing this family (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6893717B1 (en) 1999-07-08 2005-05-17 Kuolih Tsai Heat-transfer label including non-wax release coating
DE10208427B4 (de) * 2002-02-27 2013-02-28 Securasta Gmbh Klebesiegel und Träger dafür
US20040076775A1 (en) * 2002-10-18 2004-04-22 Giraud Jean Pierre Method and composition for a durable in-mold label
DE102005016541A1 (de) * 2005-04-08 2006-10-12 Henkel Kgaa Klebeband und Verfahren zu seiner Herstellung

Family Cites Families (18)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3287192A (en) * 1963-07-25 1966-11-22 Pohlenz Armin Method of producing self-adhesive labels, letters, characters and symbols
US3516904A (en) * 1966-04-07 1970-06-23 Diamond Int Corp Heat transfer decalcomania for application to plastic bottles made from a laminate of a polyamide adhesive,a printed layer,and a wax like heat release layer
BE759486A (fr) * 1969-11-28 1971-04-30 Avery Products Corp Decalcomanies a sec
GB1320842A (en) * 1971-05-12 1973-06-20 Letraset International Ltd Transfer materials
US4308310A (en) * 1979-09-04 1981-12-29 Advanced Graphic Technology Dry transfer decal
US4421816A (en) * 1981-11-18 1983-12-20 Advanced Graphic Technology Dry transfer decal and method of manufacture
US4454179A (en) * 1982-05-10 1984-06-12 Minnesota Mining And Manufacturing Company Dry transfer article
US4529624A (en) * 1982-06-28 1985-07-16 Dennison Manufacturing Co. Discoloration resistant heat transfer labeling
JPS62130873A (ja) * 1985-12-03 1987-06-13 Canon Inc プリント保護部材
US4704310A (en) * 1986-08-25 1987-11-03 Dennison Manufacturing Company Heat transferable laminate
ATE293825T1 (de) * 1988-11-07 2005-05-15 Heineken Tech Services Anbringen eines etikettmehrschichtenverbunds an einen behälter
CA2011648A1 (fr) * 1989-03-31 1990-09-30 Dennis O. Falaas Ruban permeable de decalage et decalque obtenu par recours a ce ruban
US5104719A (en) * 1989-08-30 1992-04-14 Revlon, Inc. Heat activated, quick release decals and associated methods
EP0461796A1 (fr) * 1990-06-04 1991-12-18 Arthur W. Maynard Méthode et appareil pour former une couche transférable portant un dessin pour transfert sur un substrat
JPH085277B2 (ja) * 1990-10-05 1996-01-24 秀雄 浜田 転写シート
EP0489960A1 (fr) * 1990-12-13 1992-06-17 SCHREINER ETIKETTEN UND SELBSTKLEBETECHNIK GMBH & CO. Procédé pour la fabrication d'étiquettes thermosoudables et étiquette obtenue par ce procédé
DE4119416A1 (de) * 1991-06-13 1992-12-17 Roland Judex Informationstraeger zum auftragen von informationen, verfahren zum herstellen des informationstraegers und verfahren zum aufbringen einer information mit dem informationstraeger
EP0716633B1 (fr) * 1993-09-03 1999-12-08 Rexam Graphics Inc. Procede de production d'image a jet d'encre et element d'enregistrement

Also Published As

Publication number Publication date
HK1015325A1 (en) 1999-10-15
EP0888225A1 (fr) 1999-01-07
ES2146979T3 (es) 2000-08-16
DE29602430U1 (de) 1997-07-03
WO1997028974A1 (fr) 1997-08-14
DE59701652D1 (de) 2000-06-15

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