EP0870623A1 - Matériau d'enregistrement pour recevoir des encres de base aqueuse - Google Patents

Matériau d'enregistrement pour recevoir des encres de base aqueuse Download PDF

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Publication number
EP0870623A1
EP0870623A1 EP98105981A EP98105981A EP0870623A1 EP 0870623 A1 EP0870623 A1 EP 0870623A1 EP 98105981 A EP98105981 A EP 98105981A EP 98105981 A EP98105981 A EP 98105981A EP 0870623 A1 EP0870623 A1 EP 0870623A1
Authority
EP
European Patent Office
Prior art keywords
epoxy
recording material
water
receiving layer
layer
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
EP98105981A
Other languages
German (de)
English (en)
Other versions
EP0870623B1 (fr
Inventor
Christoph Dr. Roth
Angela Kuhrt
Ursula Sell
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Emtec Magnetics GmbH
FEW Forschungs- und Entwicklungsgesellschaft Wolfen mbH
Original Assignee
Emtec Magnetics GmbH
FEW Forschungs- und Entwicklungsgesellschaft Wolfen mbH
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Emtec Magnetics GmbH, FEW Forschungs- und Entwicklungsgesellschaft Wolfen mbH filed Critical Emtec Magnetics GmbH
Publication of EP0870623A1 publication Critical patent/EP0870623A1/fr
Application granted granted Critical
Publication of EP0870623B1 publication Critical patent/EP0870623B1/fr
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
    • B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
    • B41M5/00—Duplicating or marking methods; Sheet materials for use therein
    • B41M5/50—Recording sheets characterised by the coating used to improve ink, dye or pigment receptivity, e.g. for ink-jet or thermal dye transfer recording
    • B41M5/52—Macromolecular coatings
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
    • B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
    • B41M5/00—Duplicating or marking methods; Sheet materials for use therein
    • B41M5/50—Recording sheets characterised by the coating used to improve ink, dye or pigment receptivity, e.g. for ink-jet or thermal dye transfer recording
    • B41M5/52—Macromolecular coatings
    • B41M5/5245—Macromolecular coatings characterised by the use of polymers containing cationic or anionic groups, e.g. mordants
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
    • B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
    • B41M5/00—Duplicating or marking methods; Sheet materials for use therein
    • B41M5/50—Recording sheets characterised by the coating used to improve ink, dye or pigment receptivity, e.g. for ink-jet or thermal dye transfer recording
    • B41M5/52—Macromolecular coatings
    • B41M5/5218—Macromolecular coatings characterised by inorganic additives, e.g. pigments, clays
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
    • B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
    • B41M5/00—Duplicating or marking methods; Sheet materials for use therein
    • B41M5/50—Recording sheets characterised by the coating used to improve ink, dye or pigment receptivity, e.g. for ink-jet or thermal dye transfer recording
    • B41M5/52—Macromolecular coatings
    • B41M5/5254—Macromolecular coatings characterised by the use of polymers obtained by reactions only involving carbon-to-carbon unsaturated bonds, e.g. vinyl polymers
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/31504—Composite [nonstructural laminate]
    • Y10T428/31507—Of polycarbonate
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/31504—Composite [nonstructural laminate]
    • Y10T428/31511—Of epoxy ether
    • Y10T428/31515—As intermediate layer
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/31504—Composite [nonstructural laminate]
    • Y10T428/31725—Of polyamide
    • Y10T428/31779—Next to cellulosic
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/31504—Composite [nonstructural laminate]
    • Y10T428/31786—Of polyester [e.g., alkyd, etc.]
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/31504—Composite [nonstructural laminate]
    • Y10T428/31855—Of addition polymer from unsaturated monomers
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/31504—Composite [nonstructural laminate]
    • Y10T428/31855—Of addition polymer from unsaturated monomers
    • Y10T428/3188—Next to cellulosic
    • Y10T428/31884—Regenerated or modified cellulose
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/31504—Composite [nonstructural laminate]
    • Y10T428/31855—Of addition polymer from unsaturated monomers
    • Y10T428/31909—Next to second addition polymer from unsaturated monomers
    • Y10T428/31928—Ester, halide or nitrile of addition polymer
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/31504—Composite [nonstructural laminate]
    • Y10T428/31942—Of aldehyde or ketone condensation product
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/31504—Composite [nonstructural laminate]
    • Y10T428/31942—Of aldehyde or ketone condensation product
    • Y10T428/31949—Next to cellulosic
    • Y10T428/31953—Modified or regenerated cellulose
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/31504—Composite [nonstructural laminate]
    • Y10T428/31971—Of carbohydrate

Definitions

  • the invention relates to a recording material for water-dilutable Inks, especially for use with inkjet printers, and a process for its manufacture.
  • Image recording or reproduction using inkjet printers is a common method because it is direct and fast implementation of electronic image data is possible.
  • Modern printer technology allows image reproduction with a Resolution, which is the resolution of the image displayed with the corresponds to conventional silver halide photography, below Use of various print media such as paper backing or transparent films.
  • the quality of the pictures, in particular The resolution depends on both the possibilities of the used Printer as well as crucial from the properties ds recording material.
  • the recording material further determines the further handling and the possible applications of the finished pictures.
  • the Recording material meets the following requirements: good Ink absorption to achieve high color densities; low Diffusion of the ink (dye solution) in the recording material, to keep the droplet size small and thus high sharpness of contours and good resolution achieve; fast drying and good smudge resistance after the Ink application; low stickiness even with high air humidity; high transparency of the recording material Training as projection screen; and low sensitivity to water and therefore suitability for outdoor applications.
  • ink-receptive layers from water-soluble Polymers, e.g. Polyvinyl alcohol, polyvinyl pyrrolidone, To provide gelatin etc. (US 4,503,111, US 4,680,235, US 4,555,432, DE 4,405,969). These polymers are characterized by a high moisture influence Stickiness and lack of water resistance.
  • the stake of cationic polishing as a binder for fixing the Dyes in a color absorption layer and to increase the Wipe resistance is known from DE 3 707 624 or EP 514 633.
  • Polymer mixtures of polyvinyl alcohol or polyalkylene oxides can also be used can be used with cationic polymers (EP 379 964, EP 634 284, JP 56-84992, JP 59-20696).
  • metal oxide sols as fillers is in the EP 524 626 and DE 4 405 969.
  • silane the binder solutions add to form matrix polymers (see EP 583 141, EP 482 837).
  • EP 233 703 Polyacrylates and polyvinyl pyrrolidone as a color receiving layer to use.
  • the known recording materials meet the above Requirements not. In particular, they are not for Suitable applications where a moisture or Water contact is possible because the swelling or solution Color receiving layer dye extracted from the layer is, so that the color densities achieved and develops poor contour definition.
  • the object of the invention is to provide a new recording material, which has improved moisture and water resistance owns, and a process for its preparation specify.
  • the recording material is intended in particular to have a wider range of applications and practical drying times after ink application.
  • a recording material according to the invention has one Color receiving layer, which contains an epoxy-crosslinkable, carboxylic acid group cationic copolymer, a water-soluble Polymer and an epoxy-containing metal oxide sol contains.
  • the weight fractions are preferably each corresponding to 30 to 60% by weight of the copolymer, 30 to 60 % By weight of the metal oxide and 10 to 40% by weight of the water-soluble Polymer.
  • the component of the crosslinkable polymer can also be a Composition from different polymers according to the general structural formula included.
  • the carboxylic acid-containing monomer unit is acrylic acid, Methacrylic acid or itaconic acid is preferred. In this case the content in the polymer component is preferably 20 to 35 mol%.
  • ethyl acrylate as a comonomer component all known vinyl monomers, e.g. Vinyl pyrrolidone, Styrene, acrylamide or vinyl acetate act. The molecular weight this polymer component is usually 10,000 D to 500000 D.
  • the hydrolysis and condensation can be carried out in the presence of tetraalkoxysilanes, Alkyltrialkoxysilanes or dialkyldialkoxysilanes is carried out, whereby the epoxy content of the Metal oxide brine can be controlled in a targeted manner.
  • metal oxide mixtures can be used by the Sol production alkoxylates of boron, aluminum or titanium as Co building blocks act.
  • the epoxy-containing metal oxide sols react with the free carboxylic acid groups of the polymers and thus result a water-insoluble network of metal oxide and cationic Polymer.
  • the Composition additional epoxy catalysts may be added.
  • epoxy catalysts are triethylamine, dimethylbenzylamine and N-methylimidazole. Based on the epoxy The concentration of metal oxide sol is preferably 1 to 5 % By weight.
  • the second, water-soluble polymer component is preferred a nonionic or cationic water soluble polymer. This can be done, for example, with polyvinyl alcohol, polyvinyl pyrrolidone, Polyacrylamide, cationic polyacrylamide, cationic polyacrylic esters or compositions thereof be formed.
  • the recording material according to the invention can in the color receiving layer furthermore means for controlling the layer uniformity and surface tension included.
  • the layer uniformity and surface tension included are particularly suitable nonionic or cationic surfactants. Hexadecyltrimethylammonium bromide is particularly preferred.
  • the recording material according to the invention can be used as a carrier material contain a flexible support for printing is suitable in an inkjet printer.
  • a flexible support for printing is suitable in an inkjet printer.
  • a carrier material rigid or non-flexible materials such as Use glass or plastic sheets.
  • the carrier material can be essentially flat or any Have body shape, with the application of the color receiving layer possible on any surface of the carrier material is. Finally, it is possible to use the color receiving layer to produce such a thickness that a self-supporting Recording material is formed.
  • the production of a recording material according to the invention is done by applying a coating solution for formation an ink receiving layer on a substrate.
  • the approach the coating solution is made by preparing a Metal oxide sol according to the above composition and addition of the polymer components.
  • the approach is preferably carried out in aqueous-organic solvents, e.g. in one Water-ethanol mixture.
  • the application of the coating solution on the carrier material is done by a casting process like this for example of photochemical coating processes is known.
  • the carrier material can also be used Diving, spraying or a similar application process be coated. Subsequently, the Coating solution on the carrier material, which by a Heat can be accelerated.
  • the recording material according to the invention has the following advantages.
  • the recording material contains one novel ink receiving layer, which is insoluble in water, at Moisture contact does not form a sticky surface and one practical drying time.
  • the ink receiving layer is transparent and therefore for both paper and Suitable film carrier.
  • the ink receiving layer can be with known layers of conventional recording materials combine by using the new color receiving layer as Top layer is used. After a site-specific order from Ink (dye solution) the ink dyes become solid in the crosslinked polymer composition of the ink receiving layer anchored and will not be washed out in contact with water.
  • the use of the recording material is not limited to printing material for inkjet printers, but also possible for outdoor or outdoor use. A bleeding from smallest ink stains do not occur, so that the recording material according to the invention for recording operations (Printing processes) with resolution requirements is suitable for use with modern printing devices Production of overhead projector foils or color prints be made from photographs.
  • the layer is not waterproof.
  • the dye is washed out and also diffuses in the layer.
  • the layer is not waterproof.
  • the dye diffuses in the layer and is washed out considerably.
  • the layer is waterproof. In the case of water contact, none noticeable bleaching of the dye. After drying sharp images will be obtained again.
  • the layer is waterproof. There is no watering significant washout of the dye. After drying sharp images will be obtained again.
  • the layer is waterproof. There is no contact with water significant washout of the dye. After drying sharp images will be obtained.
  • the examples show compared to the conventional comparative examples a high density, constant after contact with water, dry, non-sticky surfaces and high transparency too after contact with water and drying again.
  • the ink receiving layer has a largely non-toxic composition.

Landscapes

  • Chemical & Material Sciences (AREA)
  • Inorganic Chemistry (AREA)
  • Ink Jet Recording Methods And Recording Media Thereof (AREA)
  • Laminated Bodies (AREA)
  • Ink Jet (AREA)
  • Inks, Pencil-Leads, Or Crayons (AREA)
  • Application Of Or Painting With Fluid Materials (AREA)
  • Pens And Brushes (AREA)
  • Paints Or Removers (AREA)
  • Duplication Or Marking (AREA)
EP98105981A 1997-04-11 1998-04-01 Matériau d'enregistrement pour recevoir des encres de base aqueuse Expired - Lifetime EP0870623B1 (fr)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DE19715187 1997-04-11
DE19715187A DE19715187C2 (de) 1997-04-11 1997-04-11 Aufzeichnungsmaterial für wasserverdünnbare Tinten

Publications (2)

Publication Number Publication Date
EP0870623A1 true EP0870623A1 (fr) 1998-10-14
EP0870623B1 EP0870623B1 (fr) 2001-01-03

Family

ID=7826245

Family Applications (1)

Application Number Title Priority Date Filing Date
EP98105981A Expired - Lifetime EP0870623B1 (fr) 1997-04-11 1998-04-01 Matériau d'enregistrement pour recevoir des encres de base aqueuse

Country Status (9)

Country Link
US (1) US6136448A (fr)
EP (1) EP0870623B1 (fr)
JP (1) JPH1134485A (fr)
KR (1) KR19980081115A (fr)
AT (1) ATE198448T1 (fr)
DE (2) DE19715187C2 (fr)
DK (1) DK0870623T3 (fr)
ES (1) ES2154918T3 (fr)
PT (1) PT870623E (fr)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP1422071A1 (fr) * 2002-11-19 2004-05-26 Fuji Photo Film Co., Ltd. Feuille pour l'enregistrement par jet d'encre

Families Citing this family (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE60017872T2 (de) * 1999-11-09 2006-01-26 Koninklijke Philips Electronics N.V. Verfahren zum auftragen einer markierung auf ein trägermaterial
US8158221B2 (en) * 2006-11-22 2012-04-17 Hewlett-Packard Development Company, L.P. Reactive ink and ink-media system for reduced air fade on porous media

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4830911A (en) * 1986-11-04 1989-05-16 Jujo Paper Co., Ltd. Recording sheet for ink jet printers
EP0627324A1 (fr) * 1993-06-03 1994-12-07 Mitsubishi Paper Mills, Ltd. Support d'impression par jet d'encre

Family Cites Families (14)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE3024205C2 (de) * 1980-06-27 1990-11-15 Felix Schoeller jr. GmbH & Co KG, 4500 Osnabrück Aufzeichnungspapier für Tintenspritzaufzeichnungsverfahren
US4503111A (en) * 1983-05-09 1985-03-05 Tektronix, Inc. Hydrophobic substrate with coating receptive to inks
JPS60198285A (ja) * 1984-03-23 1985-10-07 Ricoh Co Ltd インクジエツト記録材
US4555437A (en) * 1984-07-16 1985-11-26 Xidex Corporation Transparent ink jet recording medium
GB8602593D0 (en) * 1986-02-03 1986-03-12 Ici Plc Inkable sheet
JP2633671B2 (ja) * 1989-01-18 1997-07-23 日本製紙 株式会社 インクジェット記録用シート
US5219928A (en) * 1990-10-24 1993-06-15 Minnesota Mining And Manufacturing Company Transparent liquid absorbent materials
US5208092A (en) * 1990-10-24 1993-05-04 Minnesota Mining And Manufacturing Company Transparent liquid absorbent materials for use as ink-receptive layers
DE4116595A1 (de) * 1991-05-22 1992-11-26 Schoeller Felix Jun Papier Aufzeichnungsmaterial fuer das tintenstrahlaufzeichnungsverfahren
EP0524626B1 (fr) * 1991-07-26 1996-12-11 Asahi Glass Company Ltd. Feuille réceptrice pour imprimante par jet d'encre
JPH06135124A (ja) * 1992-08-13 1994-05-17 Canon Inc 事務機用被記録材およびその製造方法
JP3302792B2 (ja) * 1993-07-06 2002-07-15 キヤノン株式会社 記録媒体及びそれを用いたインクジェット記録方法
JP3287706B2 (ja) * 1993-10-20 2002-06-04 キヤノン株式会社 被記録材、これを用いた画像形成方法及び印字物の製造方法
DE4405969C2 (de) * 1994-02-24 1997-06-12 Wolfen Filmfab Gmbh Informationsaufzeichnungsmaterial für Tintenstrahldrucker

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4830911A (en) * 1986-11-04 1989-05-16 Jujo Paper Co., Ltd. Recording sheet for ink jet printers
EP0627324A1 (fr) * 1993-06-03 1994-12-07 Mitsubishi Paper Mills, Ltd. Support d'impression par jet d'encre

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP1422071A1 (fr) * 2002-11-19 2004-05-26 Fuji Photo Film Co., Ltd. Feuille pour l'enregistrement par jet d'encre
US7754297B2 (en) 2002-11-19 2010-07-13 Fujifilm Corporation Ink jet recording sheet

Also Published As

Publication number Publication date
DE19715187C2 (de) 2000-06-29
DE19715187A1 (de) 1998-10-15
EP0870623B1 (fr) 2001-01-03
PT870623E (pt) 2001-06-29
ATE198448T1 (de) 2001-01-15
DK0870623T3 (da) 2001-04-09
JPH1134485A (ja) 1999-02-09
KR19980081115A (ko) 1998-11-25
ES2154918T3 (es) 2001-04-16
DE59800412D1 (de) 2001-02-08
US6136448A (en) 2000-10-24

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