EP0821581A1 - Nichtionischer schaumbildner für schäumende kosmetika - Google Patents

Nichtionischer schaumbildner für schäumende kosmetika

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Publication number
EP0821581A1
EP0821581A1 EP96909837A EP96909837A EP0821581A1 EP 0821581 A1 EP0821581 A1 EP 0821581A1 EP 96909837 A EP96909837 A EP 96909837A EP 96909837 A EP96909837 A EP 96909837A EP 0821581 A1 EP0821581 A1 EP 0821581A1
Authority
EP
European Patent Office
Prior art keywords
alkyl
average value
foaming agent
polymer
foaming
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Withdrawn
Application number
EP96909837A
Other languages
English (en)
French (fr)
Other versions
EP0821581A4 (de
Inventor
Takanori Nambu
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Procter and Gamble Co
Original Assignee
Procter and Gamble Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Procter and Gamble Co filed Critical Procter and Gamble Co
Publication of EP0821581A1 publication Critical patent/EP0821581A1/de
Publication of EP0821581A4 publication Critical patent/EP0821581A4/de
Withdrawn legal-status Critical Current

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Classifications

    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K9/00—Medicinal preparations characterised by special physical form
    • A61K9/10—Dispersions; Emulsions
    • A61K9/12—Aerosols; Foams
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/02—Cosmetics or similar toiletry preparations characterised by special physical form
    • A61K8/04—Dispersions; Emulsions
    • A61K8/046—Aerosols; Foams
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/02—Cosmetics or similar toiletry preparations characterised by special physical form
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
    • A61K8/39—Derivatives containing from 2 to 10 oxyalkylene groups
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q5/00—Preparations for care of the hair
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q5/00—Preparations for care of the hair
    • A61Q5/06—Preparations for styling the hair, e.g. by temporary shaping or colouring

Definitions

  • the present invention relates to a foaming agent comprising at least a polyoxyethylene and/or polyoxypropylene type of nonionic surfactant which has a total HLB by Griffin method of at least 12, which provides clear and stable concentrates and voluminous and stable foaming, and smooth and mild touch to foaming cosmetic compositions, with improved less flaking tendency.
  • the present invention relates to leave-on hair mousse products comprising this foaming agent.
  • Cosmetic compositions such as shaving creams, hair mousses, spray foams, foaming lotions and foaming creams are aimed to be dispensed or sprayed as foams and applied on the human skin or hair. These products are described in the present invention as "leave-on foaming cosmetic products”.
  • One common characteristic desired for these leave-on foaming cosmetic products is a foam having favorable characteristics to the consumer such as voluminous and stable foaming, with smooth and mild touch to the skin and hair.
  • Hair mousses Leave-on foaming cosmetic compositions for hair are usually referred to as "mousses", which term will be used in the present invention. Hair mousses were born in Europe in the early 1980s. Hair mousses are fundamentally an aerosol foam, however, non-aerosol foams are also known. The general appeal of hair mousses can be largely attributed to the ease of application and controlled amount of product which are possible from mousse formulations. Hair mousse compositions are generally dispensed by a compressible dispenser or a valve and applied to the user's hand or a specifically designed comb and spread through the hair. Alternatively, hair mousse compositions can be directly applied to the hair by dispensing through nozzles. Hair mousses are formulated for the purpose of styling, setting, and arranging, or for other purposes such as shampooing, conditioning, treating, dyeing, and combinations thereof.
  • alcohol refers to volatile primary alcohols having about 1 to 6 carbons, particularly ethanol. Alcohol is used in mousses for a number of reasons. First, the presence of volatile alcohol can aid styling by decreasing drying time. However, it is assumed that this drying has raised the concerns of some consumers that alcohol is also drying hair. Second, alcohol aids foam breakage as the mousse is spread throughout the hair. It is known that foam breakage is a result of the ability of alcohol to act as a defoaming agent. Third, alcohol itself improves product preservation.
  • alcohol enhances the compatibility of the concentrate with the propellant, and acts as a solubility bridge between the resin and the water base.
  • alcohol is a good solvent for dissolving oil base ingredients such as conditioning fatty alcohols. Consequently, elimination of alcohol from the formulation may affect product performance.
  • foaming agent which can be used in hair mousse compositions with or without alcohol.
  • Preservatives such as DMDM Hydantoin (dimethylol dimethyl hydantoin) and Kathon CG (mixture of methylchloro- isothiazolinone and methyl isothiazolinone) are known as effective preservatives at low levels, however, are not approved for use in leave-on cosmetic products in a number of countries. Phenoxyethanol and EDTA are widely accepted for use, however, are not satisfactorily effective at low levels.
  • Parabens such as methyl paraben, propyl paraben, butyl paraben, and LiquaPar oil (mixture of isobutyl paraben, isopropyl paraben, and butyl paraben) are also widely accepted for use.
  • parabens are lipophilic, they cannot dissolve in water, and thus have some formulation constraints.
  • Methyl paraben and propyl paraben are difficult to formulate at high levels, for they are solid at room temperature.
  • the type of propellents are also • known to affect product performance.
  • fluorohydrocarbons such as difluoroethane 152a (supplied by DuPont) can be used for a wide range of formulations.
  • Propane and dimethyl ether can also be used for a wide range of formulations.
  • propane is relatively combustible.
  • Dimethyl ether when used at high levels can be corrosive.
  • LPG liquefied petroleum gas
  • LPG is a relatively safe propellant, however, have some formulation constraints.
  • Evaluation of product performance for hair mousse compositions vary depending on the purpose and concept of the product. In evaluating the performance of a hair mousse, one generally considers properties seen in three major stages; the properties of the foam upon dispensing from the package, the properties of the foam upon applying to the hair, and properties of the end results to the hair. Properties considered upon dispensing include volume of foam and foam expansion speed. It is known that when foam expansion is slow or delayed, "pooling" of the product occurs. Properties considered upon applying to the hair include stability and breakability of the foam, non-soapiness, smoothness, softness, creaminess, and stickiness. Properties considered on the end results to the hair include style control, dry or wet feel of hair, washability, shine, moisturizing, conditioning, anti-static, and brushing.
  • foaming cosmetic composition such as a hair mousse composition
  • said foaming agent which provides a foam having appropriate foam breakdown (foam breakability) under shear and is easy to spread on hair, has a smooth, soft and creamy texture, and has a mild touch.
  • foaming cosmetic composition such as a hair mousse composition
  • a foaming cosmetic composition such as a hair mousse composition
  • said foaming agent which can be formulated in combination with a wide range of solvents, preservatives, and propellants.
  • It is further an object of the present invention to provide a hair mousse composition comprising said foaming agent which provides good style control, conditioning effect, and good feel to the hair, with less flaking tendency.
  • the present invention relates to a foaming agent comprising at least a polyoxyethylene and/or polyoxypropylene type of nonionic surfactant which has a total HLB by Griffin method of at least 12, which foams by being dispensed or sprayed, and provides improved foaming characteristics to foaming cosmetic compositions.
  • the present invention also relates to a foaming cosmetic composition such as a hair mousse composition comprising the foaming agent and further comprising a polymer such as cationic type of water soluble polymer, but not limited to cationic type, a solvent and a propellant.
  • the hair mousse composition comprises the foaming agent which comprises at least a polyoxyethylene and/or polyoxypropylene type of nonionic surfactants which has a total HLB by Griffin method of at least 12, from 0.005% to 5%, and further comprises a polymer, a solvent, a preservative, and a propellant.
  • the present invention relates to a foaming agent for use in a foaming cosmetic composition which foams by being dispensed or sprayed, comprising at least a polyxyethylene and/or polyoxy propylene type of nonionic surfactant which has and total HLB by Griffin method of at least 12.
  • the present invention relates to a foaming agent for use in a foaming cosmetic composition which foams by being dispensed or sprayed, comprising at least a nonionic surfactant comprises polymer units selected from polyoxyethylene, polyoxypropylene, and mixtures thereof.
  • the present invention also relates to a foaming composition such as a hair mousse composition comprising the foaming agent and further comprising a polymer, a solvent and a propellant.
  • the foaming agent of the present invention comprises at least a polyxyethylene and/or polyoxy propylene type of nonionic surfactant which has a total HLB by Griffin method of at least 12.
  • HLB is measured by Griffin method as follows.
  • HLB is calculated by the following calculated general formula(i):
  • HLB 20(1-S/A) (i) wherein;
  • S is saponification value of esters
  • HLB is acid value of fatty acids
  • E is weight percentage of ethylene oxide
  • HLB weight percentage of polyhydric alcohol
  • E is weight percentage of ethylene oxide.
  • the foaming agent of the present invention When comprised in foaming cosmetic compositions such as hair mousses, the foaming agent of the present invention preferably comprises at least a polyxyethylene and/or polyoxy propylene type of nonionic surfactant which has and total HLB by Griffin method of at least 12, from 0.005% to 5%, more preferably 0.005% to 3%.
  • the foaming agent of the present invention When the foaming agent of the present invention is applied to foaming cosmetic composition, it provides clear and stable concentrates and voluminous and stable foaming, and smooth and mild touch to foaming cosmetic compositions, with improved less flaking tendency.
  • Other components of a foaming agent and include solvents such as water, lower alcohol, polyhydric alcohols, and mixture thereof.
  • Polyoxyethylene alkyl ether is polyethylene glycol ether of alkyl alcohol.
  • the polyoxyethylene alkyl ether surfactant can be the following general structure
  • polyoxyethylene alkenyl ether surfactant can be the following general structure;
  • the polyoxypropylene polyoxyethylene alkyl or alkenyl or iso-alkyl or iso- alkenyl or dimethylpolysiloxane Ether surfactant can be the following general structure;
  • R1 is alkyl alkenyl groups or iso-alkyl alkenyl groups or dimethylpolysiloxane derivatives, x has an average value from 2 to 100, y has an average value from 2 to 100; Polyoxyethylene Long chain alkyl fatty acid or dimethylpolysiloxane or benzene derivatives Ether
  • the polyoxyethylene long chain alkyl fatty acid or benzene derivatives ether surfactant can be the following general structure; (4) a polyoxyethylene Long chain alkyl fatty acid or benzene derivatives ether surfactant having the following general structure (IV):
  • R2 can be selected from the group consisting of castor oil triglyceride castorate, cholesterol, coconut oil triglyceride cocoate, alkyl phenol, glyceryl laurate, glyceryl oleate, glyceryl cocoate, glycer ⁇ l Isostearate, glyceryl stearate, hydrogenated castor oil triglyceride hydrogenated castorate, hydrogenated lanolin, nonyl phenyl and dimethylpolysiloxane derivatives, n has an average value from 2 to 200; Polyoxyethylene Dialkyl. or iso-alkyl. or alkenyl Ether The polyoxyethylene Dialkyl, or iso-alkyl, or alkenyl ether surfactant can be the following general structure;
  • R3 and R4 are respectively selected from the group consisting of alkyl groups, iso-alkyl groups and alkenyl groups, n has an average value from 2 to 200;
  • the polyoxypropylene Alkyl, iso-alkyl, alkenyl or long chain alkyl fatty acid ether surfactant can be the following general structure;
  • R5 is alkyl groups, iso-alkyl groups or alkenyl groups, n has an average value of 2 to 200.
  • a foaming cosmetic composition of the present invention comprises a concentrate which is a foamable liquid which produces a foam when mixed an external source of air or gas, and is dispensed as a foam.
  • a concentrate (by weight) of the foaming cosmetic composition of the present invention comprises 0.005-20%, more preferably 0.005-10%, most preferably 0.005-6%, of the foaming agent.
  • the foaming cosmetic compositions further preferably comprises a solvent for the foaming agent.
  • Solvents used in a foaming cosmetic composition of the present invention are selected depending on variables such as the remainder components, viscosity, and desired foaming characteristic of the composition.
  • the solvent is preferably comprised at a level of 60-99%, more preferably 80-99%, most preferably 85-98% of the concentrate.
  • Non-limiting examples of solvents useful in the present invention are: water, lower alcohols having 1 to 6 carbons such as ethanol and isopropanol, and polyhydric alcohols such as propylene glycol, hexylene glycol, glycerin, and propane diol, and mixtures thereof.
  • solvents useful in the present invention are: water, lower alcohols having 1 to 6 carbons such as ethanol and isopropanol, and polyhydric alcohols such as propylene glycol, hexylene glycol, glycerin, and propane diol, and mixtures thereof.
  • the foaming cosmetic compositions further preferably comprises a propellant so mixing with the concentrate to foam the foam.
  • Propellents when used in a foaming cosmetic composition in the present invention are selected depending on variables such as the remainder components, the package, and how the product is designed to be used (standing or invert).
  • the propellant is preferably comprised at a level of 0-60%, more preferably 0-30% of the entire composition.
  • the hair mousse composition is usually provided in a package equipped with an air or gas mixing device.
  • Non-limiting examples of propellants useful in the present invention are: fluorohydrocarbons such as difluoroethane 152a (supplied by DuPont), dimethyl ether, carbon dioxide, nitrogen, and hydrocarbons such as propane, iso-butane, n-butane, and mixtures of hydrocarbons such as LPG (liquefied petroleum gas).
  • fluorohydrocarbons such as difluoroethane 152a (supplied by DuPont), dimethyl ether, carbon dioxide, nitrogen, and hydrocarbons such as propane, iso-butane, n-butane, and mixtures of hydrocarbons such as LPG (liquefied petroleum gas).
  • the components When used with a propellant, the components usually must be contained under pressure in a suitable vessel, such as a pressed dispensing package which is well known in the art(for example, a package for Vidal Sassoon Styling Mousse Extra Body/ The Procter & Gamble Company).
  • a suitable vessel such as a pressed dispensing package which is well known in the art(for example, a package for Vidal Sassoon Styling Mousse Extra Body/ The Procter & Gamble Company).
  • a suitable vessel such as a pressed dispensing package which is well known in the art(for example, a package for Vidal Sassoon Styling Mousse Extra Body/ The Procter & Gamble Company).
  • a suitable vessel such as a pressed dispensing package which is well known in the art(for example, a package for Vidal Sassoon Styling Mousse Extra Body/ The Procter & Gamble Company).
  • Optional components can be included in the foaming cosmetic compositions of the present invention, depending on the needs of the product.
  • optional components include additional surfactants, ultraviolet and infrared screening and absorbing agents, hair conditioning agents, skin conditioning agents, perfume, color, pH adjusters, polymers, dyes, vitamins, proteins, plant extracts, and nutrients.
  • a foaming cosmetic composition such as a hair mousse compositions can comprise a polymer for hair styling and conditioning, and a preservative, and can further comprise other optional components.
  • a foaming cosmetic composition such as a hair mousse compositions may further comprise a polymer.
  • a polymer comprise cationic, nonionic, anionic, and amphoteric polymers.
  • Polymer is typically included by weight at a level of 0-15%, preferably 0-10% of the concentrate.
  • Polymers suitable for use herein include any polymers soluble or colloidally dispersible in the aqueous phase (if water is the only solvent in the aqueous phase, the polymer should be soluble or dispersible in water; if an optional cosolvent such as ethanol is present the polymer should be soluble or dispersible in the combined solvent system). Solubility/dispersibility is determined at ambient conditions of temperature and pressure (25°C at 1At). Polymers for use in the compositions of the present invention include cationic, anionic, nonionic, and amphoteric resins.
  • Non-limiting examples of cationic polymers useful in the present invention include quaternized cellulose ethers such as Polyquaternium 10 (hydroxyethylcellulose hydroxypropyl trimethylammonium chloride ether) under the trade name Ucare Polymer LR and Polyquaternium 4 (hydroxyethylcellulose dimethyldiallyl ammonium chloride copolymer) under the trade name Celquat, quaternized vinyl pyrrolidone/alkylaminoacrylate or methacrylate copolymers such as Polyquaternium 11 (polyvinylpyrrolidone N,N'-dimethylaminoethylmethacrylic acid copolymer diethyl sulfate salt) under the trade name Gafquat, methylvinylimidazolium vinylpyrrolidone quaternary ammonium copolymers commercially available under the trade name Luviquat, vinylmethyl ether ethyl maleate copolymer (PVM/MA copolymer),
  • cationic polymers include silicone-grafted copolymers (including mixtures of such copolymers), comprising silicone covalently bonded to the polymer backbone (i.e. silicone chains are grafted to the backbone), and are derived by polymerization of a combination of nonionic, nonquatemizable, water soluble monomers and nonionic, quatemizable monomers.
  • the silicone macromers will generally be incorporated into the polymer by conducting the polymerization of the above two types of monomers also in the presence of silicone macromer, i.e. silicone containing monomers.
  • the silicone macromer-grafted copolymers hereof will have a polymeric backbone with a Tg of from about 30°C to about 140°C.
  • the silicone macromer-containing copolymers have an organic polymeric backbone, preferably a vinyl backbone or other carbon-based backbone derived from ethylenically unsaturated polymerizable monomers.
  • the polymers are derived by polymerization of: from about 2% to 15%, by weight, of silicone macromers; from about 5% to 40%, by weight, anionic, quaternizable monomers; and from about 30% to 60%, by weight, of non ⁇ ionic, water soluble, nonquatemizable monomers. At least 5% of the monomers, by weight are quaternized.
  • the quaternizable nonionic monomers hereof include quaternizable, amino-functional ethylenically unsaturated monomers, such as the amino functional derivatives of styrene, acrylamides, methacrylamides, (meth)acrylates such as C1-C5 alkyl esters of acrylic acid and methacrylic acid.
  • Examples of such monomers include: (i) p- dimethylaminomethylstyrene, p-dimethylaminoethylstyrene; (ii) dimethylaminomethyl acrylamide, dimethylaminopropyl acrylamide, dimethylaminopropyl methacrylamide, dimethylaminomethyl methacrylamide, dimethylaminoethyl (meth)acrylate, diethylaminoethyl (meth)acrylate, dimethylaminopropyl (meth)acrylate, and dimethylaminopropyl (meth)acrylamide.
  • nonionic, nonquatemizable, water soluble monomers include acrylamides, methacrylamides, (meth)acrylates, cinamides, vinyl alcohols, vinyl pyrrolidones, vinyl oxazolidones, and derivatives thereof.
  • acrylamide, methacrylamide, mono- and di- C1- C6 alkyl (meth)acrylamides such as dimethylacrylamide, dimethylmethacrylamide, isopropylacrylamide, t-butylacrylamide, isopropylmethacrylamide, diacetone acrylamide, mono- and di- C1-C20 alkyl (meth) acrylamides, such dimethylacrylate, t-butyl acrylate, t-butyl methacrylate, isopropyl methacrylate, stearyl methacrylate, cetyl methacrylate, acrylglycinamide, methacrylglycinamide, vinyl alcohol, vinyl pyrrolidone, vinyl oxazolidone, vinylmethoxazolidone, and poly(ethylene glycol) phenyl ether (meth)acrylate.
  • methacrylamide such as dimethylacrylamide, dimethylmethacrylamide, isopropylacrylamide, t-butylacrylamide
  • cationic polymers are cationic guar gums, for example, hydroxypropyltrimethylammonium guar gum, quaternized cellulose ethers such as copolymers of hydroxyethylcellulose with diallyldimethyl ammonium chloride or with trimethyl ammonium substituted epoxides, homopolymers of lower alkylamino alkyl acrylate or methacrylate monomers (e.g.
  • dimethyl aminoethylmethacrylate and copolymers thereof with compatible monomers such as N-vinylpyrrolidone or with methacrylate derivatives such as methyl, ethyl, abietyl and oleyl methacrylates and mixtures thereof and/or with alkyl acrylates such as methyl and butyl acrylates and mixtures thereof, copolymers of dimethyldiallyl ammonium chloride and acrylamide, homopolymers of dimethyldiallyl ammonium chloride, vinylimidazolium/vinyl pyrrolidone copolymers, and mixtures thereof.
  • compatible monomers such as N-vinylpyrrolidone or with methacrylate derivatives such as methyl, ethyl, abietyl and oleyl methacrylates and mixtures thereof and/or with alkyl acrylates such as methyl and butyl acrylates and mixtures thereof
  • copolymers of dimethyldiallyl ammonium chloride and acrylamide
  • Polycationic hair conditioning polymers can be derived from polymerizable cationic starting monomers, or from polymerizable nonionic monomers which are modified subsequent to polymerization to be of cationic character.
  • Examples of the cationic monomers include: (i) monomers derived from acrylic acid or methacrylic acid, which is referred to hereinafter collectively as (meth)acrylic acid, and a quaternized epihalohydrin product of a trialkyl amine having 1 to 5 carbon atoms in the alkyl group such as (methy)acryloxypropylthmethylammonium choride and
  • (meth)acryloxypropyltriethylammonium bromide (ii) amine derivatives of (meth)acrylic acid or amine derivatives of (meth)acrylamide derived from (meth)acrylic acid or (meth)acrylamide and a dialkylalkanoiamine have C1-C4 alkyl groups such as dimethylaminoethyl (meth)acrylate, diethylaminoethyl (meth)acrylate, dimethylaminopropyl (meth)acrylate, or dimethylaminopropyl (meth)acrylamide; and (iii) derivatives of the products of the group (ii) above by (1 ) neutralization with an inorganic or organic acid, such as hydrochloric acid, or lactic acid, (2) modification with a halogenated alkyl, such as methyl chloride, ethyl chloride, methyl bromide, or ethyl iodide, (3) modification with a halogenated
  • the cationic unsaturated monomers include amine derivatives of allyl compounds such as diallyldimethylammonium chloride and the like as well as vinylimidazolium quaternary ammonium monomers.
  • cationic unsaturated monomers can be polymerized in cationic form, or as an alternative they can be polymerized in the form of their precursors, which are then modified to be cationic, for example, by a quaternizing agent (eg. ethyl monochloroacetate, dimethyl sulfate, etc.)
  • a quaternizing agent eg. ethyl monochloroacetate, dimethyl sulfate, etc.
  • Non-limiting examples of polycationic polymers include cationic polysaccharides, homopolymers of dimethyldiallyl ammonium chloride, copolymers of dimethyldiallyl ammonium chloride and acrylamide, cationic amino-functional homopolymers and copolymers derived from acrylic acid and/or methacrylic acid, especially from alkylaminoalkyl acrylate and methacrylate monomers such as dimethylaminoethyl acrylate and methacrylate, polyalkylene imines and ethoxy polyalkylene imines, vinylimidazolium/vinylpyrrolidone quaternary ammonium copolymers, and mixtures thereof.
  • Non-limiting examples of nonionic monomers are acrylic or methacrylic acid esters of C1-C24 alcohols, such as methanol, ethanol, 1- propanol, 2-propanol, 1-butanol, 2-methyl-1-propanol, 1-pentanol, 2- pentanol, 3-pentanol, 2-methyl-1-butanol, 1-methyl-l-butanol, 3-methyl-1- butanol, 1-methyl-l-pentanol, 2-methyl-1-pentanol, 3-methyl-1-pentanol, t- butanol, cyclohexanol, 2-ethyl-1-butanol, 3-heptanol, benzyl alcohol, 2- octanol, 6-methyl-1-heptanol, 2-ethyl-1-hexanol, 3,5-dimethyl-1-hexanol, 3,5,5-trimethyl-1-hexanol, 1-decanol, 1-d
  • nonionic monomers include acrylate and methacrylate derivatives such as allyl acrylate and methacrylate, cyclohexyl acrylate and methacrylate, oleyl acrylate and methacrylate, benzyl acrylate and methacrylate, tetrahydrofurfuryl acrylate and methacrylate, ethylene glycol di-acrylate and -methacrylate, 1,3- butyleneglycol d-acrylate and -methacrylate, diacetonacrylamide, isobornyl (meth)acrylate, and the like.
  • acrylate and methacrylate derivatives such as allyl acrylate and methacrylate, cyclohexyl acrylate and methacrylate, oleyl acrylate and methacrylate, benzyl acrylate and methacrylate, tetrahydrofurfuryl acrylate and methacrylate, ethylene glycol di-acrylate and -methacrylate
  • Non-limiting examples of polar nonionic monomers include acrylamide, N,N-dimethylacrylamide, methacrylamide, N-t-butyl acrylamide, methacrylonitrile, acrylamide, acrylate alcohols (eg.C2-C ⁇ acrylate alcohols such as hydroxyethyl acrylate, hydroxyproxyl acrylate), hydroxyethyl methacrylate, hydroxypropyl methacrylate, vinyl pyrrolidone, vinyl ethers, such as methyl vinyl ether, acyl lactones and vinyl pyridine, allyl alcohols, vinyl alcohols and vinyl caprolactam.
  • Preservative acrylate alcohols (eg.C2-C ⁇ acrylate alcohols such as hydroxyethyl acrylate, hydroxyproxyl acrylate), hydroxyethyl methacrylate, hydroxypropyl methacrylate, vinyl pyrrolidone, vinyl ethers, such as methyl vinyl ether, acyl lactone
  • Hair mousse compositions can further comprise a preservative.
  • a preservative is preferably included at a level of 0-5%, more preferably 0-3% of the concentrate.
  • Non-limiting examples of preservatives useful in the present invention are DMDM Hydantoin (dimethylol dimethyl hydantoin) Kathon CG, (mixture of methylchloro-isothiazolinone and methyl isothiazolinone), imidazolidinyl urea, phenoxyethanol, EDTA and its salts, benzyl alcohol, and parabens such as methyl paraben, propyl paraben, butyl paraben, and LiquaPar oil (mixture of isobutyl paraben, isopropyl paraben, and butyl paraben).
  • Hair mousse compositions can further comprise additional surfactants.
  • additional surfactants comprise nonionic, cationic, anionic, and other amphoteric surfactants which do not affect the foaming agent of the present invention.
  • additional surfactants include sodium cocoyl isethionate (sodium cocoyl ethyl ester sulfonate), sodium fatty acid sarcosinate, sodium fatty acid methyl amino propionate, and Geropon TC-42 (Na-N-cocoyl N-methyl taurate), lauric acid dimethanolamide.
  • Additional surfactant is typically included at a level of less than 50%, preferably less than 33% of the foaming agent.
  • Hair mousse compositions may further comprise a variety of optional components.
  • optional components include; thickeners and viscosity modifiers such as diethanolamides of long chain fatty acids, sodium chloride, and sodium sulfate, hair conditioning agents such as cetyl alcohol, stearyl alcohol, oleyl alcohol, and panthenol, ultraviolet absorbing agents such as octyl salicylate, pH adjusting agents such as citric acid, succinic acid, sodium hydroxide and triethanolamine, coloring agents, hair oxidizing agents such as hydrogen peroxide, perborate salts and persulfate salts, hair reducing agents such as thioglycolates, perfumes, perfume solubilizing agents such as polyethylene glycol fatty acid esters, sequestering agents, polymer plasticizing agents such as glycerin and propylene glycol, and volatile and non-volatile silicone fluids.
  • Such optional ingredients are typically included at a level of 0.01-20%, preferably from 0.01-10% of the concentrate.
  • Polyquaternium 10 1.00 - - -
  • 21 is an average value of ethylene oxide. * 2 Active of Nikkol BL-4.2, Polyoxyethylene(4.2) lauryl ether
  • Each of the numbers is an average value.
  • compositions shown in Tables 1 , 2 and 3 can be prepared by any conventional method well known in the art.
  • a suitable method is as follows: Polymers and preservatives are added into distilled water under agitation at room temperature. The obtained mixture is heated up to 70-75°C until homogenized. Other optional components are added to the heated mixture, and agitated until homogenized. The obtained mixture is allowed to cool to 30-40°C, and surfactants, perfume and other heat sensitive components are added. The obtained concentrate is packed into cans with propellant.
  • compositions A and B Evaluation of a composition of the present invention has been done according to the following two methods by using the following test products (compositions A and B):
  • Composition A A mousse composition which is an example of the composition of co-pending U. S. application Serial No. 08/154231.
  • Composition B A mousse composition which is an example of the present invention.
  • composition A Scale 3.0
  • Composition B Scale 0.8
  • composition B showed significantly less flaking tendency than composition A.
  • composition A average score is 4.6, Standard Deviation is 0.84.
  • composition B average score is 1.2, standard deviation is 0.79.
  • composition A is significantly clearer than composition B.

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  • Health & Medical Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Animal Behavior & Ethology (AREA)
  • General Health & Medical Sciences (AREA)
  • Public Health (AREA)
  • Veterinary Medicine (AREA)
  • Chemical & Material Sciences (AREA)
  • Epidemiology (AREA)
  • Birds (AREA)
  • Dispersion Chemistry (AREA)
  • Emergency Medicine (AREA)
  • Medicinal Chemistry (AREA)
  • Pharmacology & Pharmacy (AREA)
  • Cosmetics (AREA)
EP96909837A 1995-04-13 1996-03-20 Nichtionischer schaumbildner für schäumende kosmetika Withdrawn EP0821581A4 (de)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
AUPN2395/95 1995-04-13
AUPN2395A AUPN239595A0 (en) 1995-04-13 1995-04-13 Nonionic foaming agent for foaming cosmetic compositions
PCT/US1996/003938 WO1996032093A1 (en) 1995-04-13 1996-03-20 Nonionic foaming agent for foaming cosmetic compositions

Publications (2)

Publication Number Publication Date
EP0821581A1 true EP0821581A1 (de) 1998-02-04
EP0821581A4 EP0821581A4 (de) 1998-09-09

Family

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Family Applications (1)

Application Number Title Priority Date Filing Date
EP96909837A Withdrawn EP0821581A4 (de) 1995-04-13 1996-03-20 Nichtionischer schaumbildner für schäumende kosmetika

Country Status (9)

Country Link
EP (1) EP0821581A4 (de)
JP (1) JPH10509183A (de)
KR (1) KR100251145B1 (de)
CN (1) CN1184419A (de)
AU (1) AUPN239595A0 (de)
BR (1) BR9604915A (de)
CA (1) CA2218117A1 (de)
TW (1) TW365607B (de)
WO (1) WO1996032093A1 (de)

Families Citing this family (10)

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Publication number Priority date Publication date Assignee Title
DE19647765A1 (de) * 1996-11-19 1998-08-20 Wella Ag Haarpflegemittel mit langdauernder Wirkung
JP2000204025A (ja) * 1999-01-11 2000-07-25 Kose Corp 泡沫状整髪料
GB2355014A (en) * 1999-10-05 2001-04-11 Procter & Gamble Foams and compositions containing these foams
DE10330609A1 (de) * 2003-07-07 2005-01-27 Beiersdorf Ag Fixierende Mehrfachgestaltung der Frisur erlaubende kosmetische Zubereitung
EP1762225B1 (de) * 2005-09-08 2009-03-11 KPSS-Kao Professional Salon Services GmbH Aerosol Haarverformungsmittel enthaltend Wachs
EP1762224A1 (de) * 2005-09-08 2007-03-14 KPSS-Kao Professional Salon Services GmbH Aerosol Haarverformungsmittel enthaltend Wachs
JP4886505B2 (ja) 2006-12-28 2012-02-29 花王株式会社 洗浄剤用組成物
DE102009028156A1 (de) * 2009-07-31 2011-02-03 Evonik Stockhausen Gmbh Schäumbare O/W-Emulsion
JP5924982B2 (ja) * 2012-03-05 2016-05-25 大日本除蟲菊株式会社 発泡性洗剤組成物
JP6611440B2 (ja) * 2014-08-22 2019-11-27 花王株式会社 水性毛髪洗浄剤

Citations (2)

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JPS63174919A (ja) * 1987-01-13 1988-07-19 Pola Chem Ind Inc エアゾ−ル型シエ−ビング料
EP0437956A1 (de) * 1989-12-21 1991-07-24 Unilever Plc Kosmetisches Präparat

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US5002680A (en) * 1985-03-01 1991-03-26 The Procter & Gamble Company Mild skin cleansing aerosol mousse with skin feel and moisturization benefits
LU86474A1 (fr) * 1986-06-16 1988-01-20 Oreal Composition tinctoriale pour fibres keratiniques humaines sous forme de mousse,a base de 5,6-dihydroxyindole
FR2665157B1 (fr) * 1990-07-25 1992-10-30 Oreal Composes solubilisants et/ou dispersants du type tensio-actif quaternaire, procede de preparation, utilisation comme additif dans des compositions et compositions cosmetiques ou dermopharmaceutiques en comportant.
JPH0725725A (ja) * 1993-07-09 1995-01-27 Koike Kagaku Kk 発泡型人体用エアゾール製品

Patent Citations (2)

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Publication number Priority date Publication date Assignee Title
JPS63174919A (ja) * 1987-01-13 1988-07-19 Pola Chem Ind Inc エアゾ−ル型シエ−ビング料
EP0437956A1 (de) * 1989-12-21 1991-07-24 Unilever Plc Kosmetisches Präparat

Non-Patent Citations (4)

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Title
DATABASE WPI Derwent Publications Ltd., London, GB; AN 95101760 XP002070412 KOIKE KAGAKU: "foam aerosol products for hair-spray and shaving foam-comprises airtightly sealed container contg aerosol compsn contg nitrogen or condensed air, aliphatic hydrocarbon and nonionic surfactant" & JP 07 025 725 A (KOIKE KAGAKU) , 27 January 1995 *
P.A.SANDERS: "Aerosol Emulsions and Foams" SOAP & CHEMICAL SPECIALTIES, vol. 43, no. 7, 1967, N.Y., pages 68-78, XP002070411 *
PATENT ABSTRACTS OF JAPAN vol. 012, no. 450, 25 November 1988 & JP 63 174919 A (POLA CHEM. IND.), 19 July 1988, *
See also references of WO9632093A1 *

Also Published As

Publication number Publication date
EP0821581A4 (de) 1998-09-09
KR100251145B1 (ko) 2000-05-01
TW365607B (en) 1999-08-01
CN1184419A (zh) 1998-06-10
WO1996032093A1 (en) 1996-10-17
BR9604915A (pt) 1998-07-21
JPH10509183A (ja) 1998-09-08
CA2218117A1 (en) 1996-10-17
KR19980703786A (ko) 1998-12-05
AUPN239595A0 (en) 1995-05-11

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