EP0764546A1 - Matériau d'enregistrement convenable pour le procédé d'impression par jet d'encre - Google Patents

Matériau d'enregistrement convenable pour le procédé d'impression par jet d'encre Download PDF

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Publication number
EP0764546A1
EP0764546A1 EP96114450A EP96114450A EP0764546A1 EP 0764546 A1 EP0764546 A1 EP 0764546A1 EP 96114450 A EP96114450 A EP 96114450A EP 96114450 A EP96114450 A EP 96114450A EP 0764546 A1 EP0764546 A1 EP 0764546A1
Authority
EP
European Patent Office
Prior art keywords
gelatin
recording material
ink
pigment
modified
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
EP96114450A
Other languages
German (de)
English (en)
Other versions
EP0764546B1 (fr
Inventor
Horst Westfal
Andreas Diekmann
Sonja Lönker
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Felix Schoeller Jr Foto und Spezialpapiere GmbH
Original Assignee
Felix Schoeller Jr Foto und Spezialpapiere GmbH
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Felix Schoeller Jr Foto und Spezialpapiere GmbH filed Critical Felix Schoeller Jr Foto und Spezialpapiere GmbH
Publication of EP0764546A1 publication Critical patent/EP0764546A1/fr
Application granted granted Critical
Publication of EP0764546B1 publication Critical patent/EP0764546B1/fr
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
    • B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
    • B41M5/00—Duplicating or marking methods; Sheet materials for use therein
    • B41M5/50—Recording sheets characterised by the coating used to improve ink, dye or pigment receptivity, e.g. for ink-jet or thermal dye transfer recording
    • B41M5/52—Macromolecular coatings
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
    • B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
    • B41M5/00—Duplicating or marking methods; Sheet materials for use therein
    • B41M5/50—Recording sheets characterised by the coating used to improve ink, dye or pigment receptivity, e.g. for ink-jet or thermal dye transfer recording
    • B41M5/52—Macromolecular coatings
    • B41M5/5218—Macromolecular coatings characterised by inorganic additives, e.g. pigments, clays
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
    • B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
    • B41M5/00—Duplicating or marking methods; Sheet materials for use therein
    • B41M5/50—Recording sheets characterised by the coating used to improve ink, dye or pigment receptivity, e.g. for ink-jet or thermal dye transfer recording
    • B41M5/52—Macromolecular coatings
    • B41M5/5236—Macromolecular coatings characterised by the use of natural gums, of proteins, e.g. gelatins, or of macromolecular carbohydrates, e.g. cellulose
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
    • B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
    • B41M5/00—Duplicating or marking methods; Sheet materials for use therein
    • B41M5/50—Recording sheets characterised by the coating used to improve ink, dye or pigment receptivity, e.g. for ink-jet or thermal dye transfer recording
    • B41M5/52—Macromolecular coatings
    • B41M5/5245—Macromolecular coatings characterised by the use of polymers containing cationic or anionic groups, e.g. mordants
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/25—Web or sheet containing structurally defined element or component and including a second component containing structurally defined particles
    • Y10T428/256—Heavy metal or aluminum or compound thereof
    • Y10T428/257—Iron oxide or aluminum oxide
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/31504—Composite [nonstructural laminate]
    • Y10T428/31725—Of polyamide
    • Y10T428/31768—Natural source-type polyamide [e.g., casein, gelatin, etc.]
    • Y10T428/31772—Next to cellulosic
    • Y10T428/31775—Paper

Definitions

  • the invention relates to a recording material for the multicolored ink jet printing process (ink jet process).
  • droplets of a recording liquid are applied to the surface of the carrier material using various techniques.
  • a recording material for the multicolored ink jet printing process generally consists of a support and a receiving layer arranged thereon. Materials such as paper and foils are suitable as carriers.
  • the receiving layer usually consists of a binder / pigment mixture.
  • the pigments increase the whiteness of the substrate and lead to better retention of the dyes on the surface of the sheet.
  • a high pigment concentration leads to high porosity (DE-PS 30 24 205) and thus good smudge resistance.
  • dyes are drawn from the ink into the interior of the recording material and thus the color density of the image deteriorates.
  • Binders for the receiving layers are, for example, gelatin, polyvinyl alcohol, polyvinyl pyrrolidone, starch and acrylates.
  • DE-PS 22 34 823 describes a gelatin-coated paper for ink jet printing.
  • the gelatin coating is said to improve the smudge resistance and increase the dissolving power. It is disadvantageous that the symbols applied are not sufficiently smudge-proof in the desired short time, but only after more than 10 seconds. Another disadvantage is the long drying time, which is usually more than 15 minutes for gelatin layers.
  • Japanese published patent application JP 61-261 089 describes as a binder in the receiving layer a mixture of polyvinyl alcohol, polyvinyl pyrolidone and a cationic resin. This mixture is said to ensure quick drying and high image sharpness. The wet rub resistance is poor with this binder mixture.
  • the recording material should, if possible, be used for all types of printers and inks.
  • a recording material which consists of a support and an ink-receiving layer containing gelatin and pigment, the ink-receiving layer containing a carbonyl-modified gelatin.
  • a gelatin modified with maleic or phthalic anhydride can be used.
  • An acid digested pork rind gelatin is particularly preferred.
  • the residual content of free amino groups in the gelatin according to the invention is 1 to 50 mol%, preferably 2 to 30 mol% and in a particularly preferred embodiment 2 to 20 mol%.
  • the proportion of gelatin is between 95% by weight and 30% by weight, in a preferred form between 90% by weight and 70% by weight, based on the solids content of the ink-receiving layer. It was surprising that the use of a gelatin without a combination with another binder resulted in such a short drying time and high color density, especially since the use of gelatin alone according to the prior art did not lead to the expectation of corresponding results.
  • a colloidal aluminum-modified silica is used as the pigment.
  • the proportion of the pigment is between 5% by weight and 70% by weight, in a preferred form between 10% by weight and 30% by weight, based on the solids content.
  • inorganic and organic pigments can also be used as the pigment, such as CaCO 3 , TiO 2 , BaSO 4 , polymethyl methacrylate and polystyrene.
  • a dye-fixing agent is used, with one cationic dicyandiamide copolymer proved to be particularly suitable.
  • constituents of the receiving layer can be hardening agents (chrome alum, TAF / formaldehyde), wetting agents, dye-fixing agents and other auxiliaries.
  • the application quantity of the receiving layer is 1 g to 15 g. In a preferred form, it is 2 g to 7 g.
  • the aqueous coating composition can vary in the following amounts by weight: % By weight gelatin 28.50 - 90.25 aluminum modified silica 3.04 - 44.27 Auxiliaries 0.00 - 10.00 water Rest up to 100.0
  • the coating composition can be applied using all common application and metering methods, such as roller application, engraving or nipping processes and air brush or roller doctor metering.
  • the carrier material is preferably paper coated on both sides with synthetic resin and having a weight per unit area of 50 to 250 g / m 2 .
  • Polyolefins or polyester, for example, are used as the synthetic resin.
  • the application amount of the synthetic resin coating is at least 5 g / m 2 and pigments, dyes and other auxiliaries can also be contained in this coating.
  • An uncoated or coated base paper is also suitable as a carrier material.
  • the front of a polyethylene-coated base paper was coated with the following coating compositions: Table 1 Components B1 B2 B3 B4 B5 B6 Demineralized water 10.70 10.70 7.55 4.35 13.20 8.70 modif. Gelatin 1) 20% 66.50 66.50 76.00 85.50 68.00 66.50 Al-modif. Silicic acid 2) 30% 19.00 19.00 12.65 6.35 11.35 19.00 Cat. Dicyandiamide cop.
  • the back of the base paper was coated with an LDPE ("low density" polyethylene) with an optical brightener content of 0.6% by weight.
  • the application weight was 22 g / m 2 .
  • the application weight was 19 g / m 2 .
  • the gelatin with a gel strength of 220 g Bloom is a normal, acid-digested bone gelatin.
  • the gelatin with a gel strength of 280 g Bloom is a normal, unmodified pork rind gelatin.
  • the test conditions are comparable to those of Examples B1-B6.
  • the recording material was printed with a commercially available ink jet color printer from Hewlett Packard, HP 550C, and the corresponding inks.
  • the printed images were examined for smear resistance, color density, image sharpness (color gradient), color transfer and gloss. The results are summarized in Tables 3-5.
  • the color density was measured with a Gretag densitometer on the colors cyan, magenta, yellow and black.
  • the print image was covered with a PTS base paper and loaded with a 10 kg weight for 24 hours.
  • the Fab transfer from the ink-receiving layer to the PTS base paper was then assessed visually with the marks 1-5.
  • Grade 1 means no color transfer
  • grade 5 means very strong color transfer. It also specifies the colors that are involved in the transfer.
  • the gloss measurement was carried out using a three-angle gloss meter from Dr. Long with a measuring angle of 60 °.

Landscapes

  • Ink Jet Recording Methods And Recording Media Thereof (AREA)
  • Paper (AREA)
  • Ink Jet (AREA)
  • Duplication Or Marking (AREA)
EP96114450A 1995-09-21 1996-09-10 Matériau d'enregistrement convenable pour le procédé d'impression par jet d'encre Expired - Lifetime EP0764546B1 (fr)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DE19535072A DE19535072C3 (de) 1995-09-21 1995-09-21 Aufzeichnungsmaterial für das Ink-Jet-Druckverfahren
DE19535072 1995-09-21

Publications (2)

Publication Number Publication Date
EP0764546A1 true EP0764546A1 (fr) 1997-03-26
EP0764546B1 EP0764546B1 (fr) 2000-04-26

Family

ID=7772762

Family Applications (1)

Application Number Title Priority Date Filing Date
EP96114450A Expired - Lifetime EP0764546B1 (fr) 1995-09-21 1996-09-10 Matériau d'enregistrement convenable pour le procédé d'impression par jet d'encre

Country Status (7)

Country Link
US (1) US6114030A (fr)
EP (1) EP0764546B1 (fr)
JP (1) JPH09226232A (fr)
AT (1) ATE192085T1 (fr)
DE (2) DE19535072C3 (fr)
DK (1) DK0764546T3 (fr)
ES (1) ES2147879T3 (fr)

Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0830952A2 (fr) * 1996-09-19 1998-03-25 Konica Corporation Feuille pour l'enregistrement par jet d'encre
DE19721238A1 (de) * 1997-05-21 1998-11-26 Stoess & Co Gelatine Verwendung von modifizierter Gelatine
WO1998052765A1 (fr) * 1997-05-23 1998-11-26 Nashua Corporation Papier brillant pour imprimantes a jet d'encre
WO2000020221A1 (fr) * 1998-10-02 2000-04-13 Cabot Corporation Dispersion de silice, composition de revetement et support d'enregistrement
EP1034940A1 (fr) * 1999-03-09 2000-09-13 Konica Corporation Feuille pour l'enregistrement par jet d'encre contenant des copolymères à base de dicyandiamide
WO2005063900A2 (fr) * 2003-12-22 2005-07-14 Gelita Ag Chitosane et son utilisation comme fixateur de couleurs dans des materiaux pour impression a jet d'encre

Families Citing this family (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2002067475A (ja) * 2000-08-23 2002-03-05 Mitsubishi Paper Mills Ltd インクジェット用記録材料
US20070059652A1 (en) * 2005-09-15 2007-03-15 Kitchin Jonathan P Repositionable glossy photo media
US20070059631A1 (en) * 2005-09-15 2007-03-15 Kitchin Jonathan P Repositionable glossy photo media
US20070059613A1 (en) * 2005-09-15 2007-03-15 Kitchin Jonathan P Repositionable photo card
US20070089832A1 (en) * 2005-09-15 2007-04-26 Kitchin Jonathan P Repositionable matte photo media
US20070059472A1 (en) * 2005-09-15 2007-03-15 3M Innovative Properties Company Repositionable photo media and photographs
US20080003383A1 (en) * 2005-09-15 2008-01-03 3M Innovative Properties Company Repositionable photo paper

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4474847A (en) * 1980-06-27 1984-10-02 Felix Schoeller, Jr. Gmbh & Co. K.G. Recording paper for ink jet recording processes
US4946741A (en) * 1988-03-07 1990-08-07 Fuji Photo Film Co., Ltd. Ink recording sheet
EP0445327A1 (fr) * 1990-03-07 1991-09-11 Felix Schoeller jr. Papierfabrik GmbH & Co. KG Support pour procédé d'impression par jet d'encre
WO1994020303A2 (fr) * 1993-03-02 1994-09-15 Mitsubishi Paper Mills Limited Feuilles pour impression a jet d'encre
EP0636489A1 (fr) * 1993-07-30 1995-02-01 Canon Kabushiki Kaisha Elément d'enregistrement, méthode d'enregistrement à jet d'encre en utilisant cela, empreinte obtenue selon cela, et dispersion et procédé de production d'élément d'enregistrement en utilisant la dispersion

Family Cites Families (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS62263084A (ja) * 1986-05-09 1987-11-16 Honshu Paper Co Ltd インクジエツト記録用透明シ−ト
US4976997A (en) * 1987-06-15 1990-12-11 Chemco Technologies, Inc. Surface composition for a substrate and method of preparation
EP0298424B1 (fr) * 1987-07-07 1994-12-07 Asahi Glass Company Ltd. Milieu support pour une matière colorante
US5045432A (en) * 1990-07-17 1991-09-03 Eastman Kodak Company Radiation-sensitive composition containing both a poly(N-acylalkyleneimine) and an unsaturated polyester and use thereof in lithographic printing plates
JP3198164B2 (ja) * 1992-09-09 2001-08-13 三菱製紙株式会社 インクジェット記録用シート
JPH06340165A (ja) * 1993-06-03 1994-12-13 Oriental Photo Ind Co Ltd 記録シートの製造方法

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4474847A (en) * 1980-06-27 1984-10-02 Felix Schoeller, Jr. Gmbh & Co. K.G. Recording paper for ink jet recording processes
DE3024205C2 (de) * 1980-06-27 1990-11-15 Felix Schoeller jr. GmbH & Co KG, 4500 Osnabrück Aufzeichnungspapier für Tintenspritzaufzeichnungsverfahren
US4946741A (en) * 1988-03-07 1990-08-07 Fuji Photo Film Co., Ltd. Ink recording sheet
EP0445327A1 (fr) * 1990-03-07 1991-09-11 Felix Schoeller jr. Papierfabrik GmbH & Co. KG Support pour procédé d'impression par jet d'encre
WO1994020303A2 (fr) * 1993-03-02 1994-09-15 Mitsubishi Paper Mills Limited Feuilles pour impression a jet d'encre
EP0636489A1 (fr) * 1993-07-30 1995-02-01 Canon Kabushiki Kaisha Elément d'enregistrement, méthode d'enregistrement à jet d'encre en utilisant cela, empreinte obtenue selon cela, et dispersion et procédé de production d'élément d'enregistrement en utilisant la dispersion

Cited By (12)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0830952A2 (fr) * 1996-09-19 1998-03-25 Konica Corporation Feuille pour l'enregistrement par jet d'encre
EP0830952A3 (fr) * 1996-09-19 1998-04-29 Konica Corporation Feuille pour l'enregistrement par jet d'encre
DE19721238A1 (de) * 1997-05-21 1998-11-26 Stoess & Co Gelatine Verwendung von modifizierter Gelatine
DE19721238C2 (de) * 1997-05-21 2000-08-03 Stoess & Co Gelatine Aufzeichnungspapier für Tintenstrahldrucker
WO1998052765A1 (fr) * 1997-05-23 1998-11-26 Nashua Corporation Papier brillant pour imprimantes a jet d'encre
WO2000020221A1 (fr) * 1998-10-02 2000-04-13 Cabot Corporation Dispersion de silice, composition de revetement et support d'enregistrement
US6420039B1 (en) 1998-10-02 2002-07-16 Cabot Corporation Recording medium
EP1034940A1 (fr) * 1999-03-09 2000-09-13 Konica Corporation Feuille pour l'enregistrement par jet d'encre contenant des copolymères à base de dicyandiamide
US6492005B1 (en) 1999-03-09 2002-12-10 Konica Corporation Ink jet recording sheet
WO2005063900A2 (fr) * 2003-12-22 2005-07-14 Gelita Ag Chitosane et son utilisation comme fixateur de couleurs dans des materiaux pour impression a jet d'encre
DE10361247A1 (de) * 2003-12-22 2005-07-28 Deutsche Gelatine-Fabriken Stoess Ag Chitosan und dessen Verwendung als Farbfixierungsmittel in Ink-Jet-Aufzeichnungsmaterialien
WO2005063900A3 (fr) * 2003-12-22 2005-09-29 Stoess & Co Gelatine Chitosane et son utilisation comme fixateur de couleurs dans des materiaux pour impression a jet d'encre

Also Published As

Publication number Publication date
DE19535072C3 (de) 2002-01-24
DE19535072A1 (de) 1997-03-27
DE59605029D1 (de) 2000-05-31
JPH09226232A (ja) 1997-09-02
ATE192085T1 (de) 2000-05-15
DE19535072C2 (de) 1997-12-11
EP0764546B1 (fr) 2000-04-26
US6114030A (en) 2000-09-05
ES2147879T3 (es) 2000-10-01
DK0764546T3 (da) 2000-08-28

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