EP0737097A1 - Emulsions eau/huile et eau/huile/eau a phase interne elevee - Google Patents

Emulsions eau/huile et eau/huile/eau a phase interne elevee

Info

Publication number
EP0737097A1
EP0737097A1 EP95905467A EP95905467A EP0737097A1 EP 0737097 A1 EP0737097 A1 EP 0737097A1 EP 95905467 A EP95905467 A EP 95905467A EP 95905467 A EP95905467 A EP 95905467A EP 0737097 A1 EP0737097 A1 EP 0737097A1
Authority
EP
European Patent Office
Prior art keywords
concentrate
oil
water
emulsion
phase
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Withdrawn
Application number
EP95905467A
Other languages
German (de)
English (en)
Other versions
EP0737097A4 (fr
Inventor
Timothy J. Young
Emanuel J. Mcginley
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
FMC Corp
Original Assignee
FMC Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by FMC Corp filed Critical FMC Corp
Publication of EP0737097A1 publication Critical patent/EP0737097A1/fr
Publication of EP0737097A4 publication Critical patent/EP0737097A4/fr
Withdrawn legal-status Critical Current

Links

Classifications

    • A—HUMAN NECESSITIES
    • A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23G—COCOA; COCOA PRODUCTS, e.g. CHOCOLATE; SUBSTITUTES FOR COCOA OR COCOA PRODUCTS; CONFECTIONERY; CHEWING GUM; ICE-CREAM; PREPARATION THEREOF
    • A23G9/00—Frozen sweets, e.g. ice confectionery, ice-cream; Mixtures therefor
    • A23G9/32—Frozen sweets, e.g. ice confectionery, ice-cream; Mixtures therefor characterised by the composition containing organic or inorganic compounds
    • A23G9/327—Frozen sweets, e.g. ice confectionery, ice-cream; Mixtures therefor characterised by the composition containing organic or inorganic compounds characterised by the fatty product used, e.g. fat, fatty acid, fatty alcohol, their esters, lecithin, glycerides
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
    • C09K23/00—Use of substances as emulsifying, wetting, dispersing, or foam-producing agents
    • C09K23/34—Higher-molecular-weight carboxylic acid esters
    • A—HUMAN NECESSITIES
    • A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23C—DAIRY PRODUCTS, e.g. MILK, BUTTER OR CHEESE; MILK OR CHEESE SUBSTITUTES; MAKING THEREOF
    • A23C9/00—Milk preparations; Milk powder or milk powder preparations
    • A23C9/152—Milk preparations; Milk powder or milk powder preparations containing additives
    • A23C9/1528—Fatty acids; Mono- or diglycerides; Petroleum jelly; Paraffine; Phospholipids; Derivatives thereof
    • A—HUMAN NECESSITIES
    • A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23D—EDIBLE OILS OR FATS, e.g. MARGARINES, SHORTENINGS, COOKING OILS
    • A23D7/00—Edible oil or fat compositions containing an aqueous phase, e.g. margarines
    • A23D7/01—Other fatty acid esters, e.g. phosphatides
    • A23D7/011—Compositions other than spreads
    • A—HUMAN NECESSITIES
    • A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23D—EDIBLE OILS OR FATS, e.g. MARGARINES, SHORTENINGS, COOKING OILS
    • A23D9/00—Other edible oils or fats, e.g. shortenings, cooking oils
    • A23D9/007—Other edible oils or fats, e.g. shortenings, cooking oils characterised by ingredients other than fatty acid triglycerides
    • A23D9/013—Other fatty acid esters, e.g. phosphatides
    • A—HUMAN NECESSITIES
    • A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23G—COCOA; COCOA PRODUCTS, e.g. CHOCOLATE; SUBSTITUTES FOR COCOA OR COCOA PRODUCTS; CONFECTIONERY; CHEWING GUM; ICE-CREAM; PREPARATION THEREOF
    • A23G3/00—Sweetmeats; Confectionery; Marzipan; Coated or filled products
    • A23G3/34—Sweetmeats, confectionery or marzipan; Processes for the preparation thereof
    • A23G3/346—Finished or semi-finished products in the form of powders, paste or liquids
    • A—HUMAN NECESSITIES
    • A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23L—FOODS, FOODSTUFFS, OR NON-ALCOHOLIC BEVERAGES, NOT COVERED BY SUBCLASSES A21D OR A23B-A23J; THEIR PREPARATION OR TREATMENT, e.g. COOKING, MODIFICATION OF NUTRITIVE QUALITIES, PHYSICAL TREATMENT; PRESERVATION OF FOODS OR FOODSTUFFS, IN GENERAL
    • A23L2/00—Non-alcoholic beverages; Dry compositions or concentrates therefor; Their preparation
    • A23L2/52—Adding ingredients
    • A23L2/62—Clouding agents; Agents to improve the cloud-stability
    • A—HUMAN NECESSITIES
    • A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23L—FOODS, FOODSTUFFS, OR NON-ALCOHOLIC BEVERAGES, NOT COVERED BY SUBCLASSES A21D OR A23B-A23J; THEIR PREPARATION OR TREATMENT, e.g. COOKING, MODIFICATION OF NUTRITIVE QUALITIES, PHYSICAL TREATMENT; PRESERVATION OF FOODS OR FOODSTUFFS, IN GENERAL
    • A23L27/00—Spices; Flavouring agents or condiments; Artificial sweetening agents; Table salts; Dietetic salt substitutes; Preparation or treatment thereof
    • A23L27/60—Salad dressings; Mayonnaise; Ketchup
    • A—HUMAN NECESSITIES
    • A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23L—FOODS, FOODSTUFFS, OR NON-ALCOHOLIC BEVERAGES, NOT COVERED BY SUBCLASSES A21D OR A23B-A23J; THEIR PREPARATION OR TREATMENT, e.g. COOKING, MODIFICATION OF NUTRITIVE QUALITIES, PHYSICAL TREATMENT; PRESERVATION OF FOODS OR FOODSTUFFS, IN GENERAL
    • A23L29/00—Foods or foodstuffs containing additives; Preparation or treatment thereof
    • A23L29/10—Foods or foodstuffs containing additives; Preparation or treatment thereof containing emulsifiers
    • A—HUMAN NECESSITIES
    • A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23L—FOODS, FOODSTUFFS, OR NON-ALCOHOLIC BEVERAGES, NOT COVERED BY SUBCLASSES A21D OR A23B-A23J; THEIR PREPARATION OR TREATMENT, e.g. COOKING, MODIFICATION OF NUTRITIVE QUALITIES, PHYSICAL TREATMENT; PRESERVATION OF FOODS OR FOODSTUFFS, IN GENERAL
    • A23L33/00—Modifying nutritive qualities of foods; Dietetic products; Preparation or treatment thereof
    • A23L33/20—Reducing nutritive value; Dietetic products with reduced nutritive value
    • A23L33/21—Addition of substantially indigestible substances, e.g. dietary fibres
    • A23L33/25—Synthetic polymers, e.g. vinylic or acrylic polymers
    • A23L33/26—Polyol polyesters, e.g. sucrose polyesters; Synthetic sugar polymers, e.g. polydextrose
    • A—HUMAN NECESSITIES
    • A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23L—FOODS, FOODSTUFFS, OR NON-ALCOHOLIC BEVERAGES, NOT COVERED BY SUBCLASSES A21D OR A23B-A23J; THEIR PREPARATION OR TREATMENT, e.g. COOKING, MODIFICATION OF NUTRITIVE QUALITIES, PHYSICAL TREATMENT; PRESERVATION OF FOODS OR FOODSTUFFS, IN GENERAL
    • A23L35/00—Food or foodstuffs not provided for in groups A23L5/00 – A23L33/00; Preparation or treatment thereof
    • A23L35/10—Emulsified foodstuffs
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K47/00—Medicinal preparations characterised by the non-active ingredients used, e.g. carriers or inert additives; Targeting or modifying agents chemically bound to the active ingredient
    • A61K47/06—Organic compounds, e.g. natural or synthetic hydrocarbons, polyolefins, mineral oil, petrolatum or ozokerite
    • A61K47/08—Organic compounds, e.g. natural or synthetic hydrocarbons, polyolefins, mineral oil, petrolatum or ozokerite containing oxygen, e.g. ethers, acetals, ketones, quinones, aldehydes, peroxides
    • A61K47/14—Esters of carboxylic acids, e.g. fatty acid monoglycerides, medium-chain triglycerides, parabens or PEG fatty acid esters
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K9/00—Medicinal preparations characterised by special physical form
    • A61K9/0012—Galenical forms characterised by the site of application
    • A61K9/0014—Skin, i.e. galenical aspects of topical compositions
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K9/00—Medicinal preparations characterised by special physical form
    • A61K9/10—Dispersions; Emulsions
    • A61K9/107—Emulsions ; Emulsion preconcentrates; Micelles
    • A61K9/113—Multiple emulsions, e.g. oil-in-water-in-oil
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
    • C09K23/00—Use of substances as emulsifying, wetting, dispersing, or foam-producing agents
    • A—HUMAN NECESSITIES
    • A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23G—COCOA; COCOA PRODUCTS, e.g. CHOCOLATE; SUBSTITUTES FOR COCOA OR COCOA PRODUCTS; CONFECTIONERY; CHEWING GUM; ICE-CREAM; PREPARATION THEREOF
    • A23G2200/00—COCOA; COCOA PRODUCTS, e.g. CHOCOLATE; SUBSTITUTES FOR COCOA OR COCOA PRODUCTS; CONFECTIONERY; CHEWING GUM; ICE-CREAM; PREPARATION THEREOF containing organic compounds, e.g. synthetic flavouring agents
    • A23G2200/08—COCOA; COCOA PRODUCTS, e.g. CHOCOLATE; SUBSTITUTES FOR COCOA OR COCOA PRODUCTS; CONFECTIONERY; CHEWING GUM; ICE-CREAM; PREPARATION THEREOF containing organic compounds, e.g. synthetic flavouring agents containing cocoa fat if specifically mentioned or containing products of cocoa fat or containing other fats, e.g. fatty acid, fatty alcohol, their esters, lecithin, paraffins

Definitions

  • the present invention relates to lipid coated water droplets which can function as a fat mimetic in lowfat food products and are also useful as 5 clouding agents for beverages, and in cosmetic and pharmaceutical compositions. More particularly, the invention relates to a stable, high internal water phase water/oil (sometimes referred to as "w/o") emulsion concentrate of lipid coated water droplets which is readily dispersible lipid coated water droplets which is readily dispersible in water, and to a method 0 of preparing such a concentrate. The invention also relates to w/o/o (water/oil/water) emulsions prepared from such concentrates.
  • w/o/o water/oil/water
  • compositions of the present invention provide an equivalent oil surface area and volume to that of a full fat system but with a greatly reduced oil or fat content.
  • the present invention provides a stable water in oil emulsion concentrate comprising from 80 to 95 weight percent of an aqueous phase, which may contain from 0 to 30 weight percent of a water soluble additive, dispersed in a continuous oil phase.
  • This continuous oil phase comprises a lipid, typically a vegetable or mineral oil, that is liquid at 20°C-50°C and includes from 0.5 to 3% by weight, based on the weight of the lipid, of an emulsifier dissolved in the lipid.
  • the emulsifier is a polyglycerol ester of polycondensed ricinoleic acid, having the formula (I) :
  • n 2 to 12
  • , R 2 , and R3 is independently H or polycondensed ricinoleic acid having the formula (II), provided that at least one of R- ] , R , and R3 is a polycondensed ricinoleic acid of formula (II) :
  • Another embodiment of this invention comprises a stable w/o/w emulsion having reduced lipid content which has particular utility comprising a concentrate as described above dispersed in an aqueous outer phase.
  • this invention provides a method for preparing a stable w/o emulsion concentrate as described above.
  • the method comprises dissolving from 0.5 to 3 weight % of the emulsifier in an oil phase, heating the oil phase to a selected temperature in the range of 45 to 80°C, heating the aqueous phase to approximately the same selected temperature as the oil phase temperature, adding from 3.5 to 19 parts by weight of an aqueous phase to one part of the oil phase under moderate stirring at a rate of from 1 ,00 to 10,000 rpm and continuing stirring for from 1 to 5 minutes.
  • the present invention provides a novel method for stabilizing w/o/w systems by controlling the specific gravity of the water in the internal aqueous phase of the w/o emulsion concentrate used to form the w/o/w system.
  • One application of this embodiment is the provision of novel clouding agents for beverages comprising w/o emulsion concentrates in accordance with the present invention.
  • the oil phase In order to obtain a fluid w/o emulsion suitable for redispersion as a lowfat mimetic, the oil phase must have a liquid surfactant dissolved in the oil and remain liquid at room temperature.
  • Balance of 2-10, preferably 5 7 , will provide stability to the dispersed w/o emulsion. Also the surfactant must permit the incorporation of large amounts of water and be effective at relatively low concentrations (0.5 to 3%, preferably 1-2.5% based on the oil phase).
  • the flexibility of the internal water droplet and the affinity of the polymeric surfactant for the surface of that droplet enables us to produce a superior fat mimetic - a stable lipid coated water droplet which simulates the physical and sensory properties of oil globules in water.
  • the surfactant we employ in the compositions of the present invention is a polyglycerol ester of polycondensed ricinoleic acid having the formula (I) :
  • n 2 to 12
  • each R-j , R 2 , and R3 is independently H or polycondensed ricinoleic acid having the formula (II), provided that at least one of R-
  • the length of the glycerol chain is from 3 to 10, more preferably 2 to 3 glycerol units.
  • the level of condensation of the ricinoleic acid chains is between 2 and 7. More preferably, m is 4 to 6.
  • esters are known in the art and are prepared by condensation of ricinoleic acid with glycerol.
  • polyglycerol polyricinoleate is prepared in the following steps. 1. Polyglycerol is manufactured by heating glycerol under vacuum with dilute sodium hydroxide as a catalyst. The duration of the reaction determines the degree of polymerization. Excess glycerol is removed by distillation. 2. Polyricinoleic acid is prepared by interesterification of castor oil fatty acids at controlled temperature in the absence of air. 3. The polyricinoleic acid is then condensed with the polyglycerol at temperatures near 200°C.
  • Preferred polyglycerol esters of polycondensed ricinoleic acid for use in the compositions of this invention that are available commercially include Triodan R90 (manufactured by Grindsted) and Admul WOL (manufactured by Quest).
  • Triodan R90 manufactured by Grindsted
  • Admul WOL manufactured by Quest
  • the surfactant will be sufficiently hydrophilic to anchor to the oil-water interface.
  • the glycerol chain is preferably between three and six units. The range of two to six appears optimal for the degree of ricinoleic acid condensation.
  • the commercially available surfactants of this type mentioned above have glycerol chains of between 2 and 4 units and a degree of condensation of ricinoleic acid of about 4 to 6 units.
  • the oil phase comprises a liquid lipid, preferably a vegetable oil or a mineral oil, and a surfactant of Formula (I).
  • the vegetable oil may be selected from peanut oil, corn oil, soybean oil, canola oil, safflower oil, olive oil, cottonseed oil, coconut oil, palm oil, castorbean oil, butter oil and melted hydrogenated counterparts of the preceding. It may contain any triglyceride or combination of triglycerides. It may contain an animal fat such as lard, beef tallow and fish oil. It may contain hydrocarbons from petroleum distillates, mineral oil, long chain alcohols and acids or esters of long chain carboxylic acids and salts of long chain carboxylic acids for use in cosmetic emollients. Fat substitute oils such as carbohydrate fatty acid polyesters, malonate esters, esterified propoxylated glycerol, trialkoxytricarballate, polyorganosiloxanes and jojoba oils may also be used.
  • the surfactant is dissolved in the oil at a concentration of between 0.5 and 3% by weight, preferably between 1 and 2.5% based on the weight of the oil.
  • the oil phase may contain up to 30% by weight of "crystalline fats", i.e. lipids that are normally solid at room temperature, including animal fats, hydrogenated oils and other highly saturated fats.
  • crystalline fats i.e. lipids that are normally solid at room temperature, including animal fats, hydrogenated oils and other highly saturated fats.
  • An additional non-ionic surfactant for example, a surfactant selected from distilled monoglycerides or diglycerides, sucrose esters of fatty acids, citric acid esters of fatty acids, lactic acid esters of fatty acids, lecithin, acetylated lecithin, sorbitan esters of fatty acids, Diacetyl Tartaric Acid i esters of Mono and Diglycerides (Datem) emulsifiers, polysorbates, and fatty acid esters of propylene glycol, may be added to the oil phase or the water phase to enhance the water solubilizing capacity of the oil phase as needed in a particular application.
  • a surfactant selected from distilled monoglycerides or diglycerides, sucrose esters of fatty acids, citric acid esters of fatty acids, lactic acid esters of fatty acids, lecithin, acetylated lecithin, sorbitan esters of fatty acids, Diacetyl Tartaric Acid
  • hydrocolloids such as maltodextrin, carrageenan, gelatin, xanthan gum, guar gum, alginate esters may be added to both aqueous phases (internal and external) or to either one to enhance stability by acting as an auxiliary emulsifier.
  • fats that melt at temperatures above room temperature should not comprise more than 30 wt. % of the oil phase, and the mixture should be heated until all components are melted. In any event, prior to emulsification, the oil phase is preferably heated to between 45 and 80°C.
  • the internal aqueous phase preferable includes from 0.1 % to 2% by weight of an electrolyte as hereinafter defined and may also contain one or more ingredients selected from antioxidants, flavoring agents, medicinal agents, nutritive agents, soluble fibers, colors, ultraviolet absorbers, additional non-ionic emulsifiers and other water soluble or dispersible compounds
  • This aqueous phase may also contain one or more water gelling or water structuring or thickening agents, for example, starch, maltodextrin, gelatin, carrageenan, konjac, microcrystalline cellulose, cellulose ethers and esters, xanthan gum, gum arabic, agarose, glycerine, locust bean gum, pectin, propylene glycol, polypropylene glycol and the like.
  • These structuring or thickening agents help to provide an enhanced oil-like sensory property which may be necessary in some applications.
  • These structuring agents may be dispersed into the aqueous phase prior to emulsification or after the aqueous phase has been emulsified, depending upon the particular end use application.
  • the catalyst may be added after the emulsion concentrate is prepared.
  • aqueous phase comprises between about 80% and 95% by weight of the total water-in-oil emulsion.
  • the ratio of water to oil in the w/o concentrate is between about 3.5:1 and 19:1.
  • the high internal phase w/o concentrate is prepared by introducing the aqueous phase to the oil phase under constant shear at between 45 and 80°C.
  • the shearing device may be a homogenizer, a colloid milling device, a head or ball milling system, a Silverson mill-type mixer or a propeller blade mixer operating at rates of between 1 ,000 and 20,000 rpm.
  • the preferred shearing device is ' the propeller mixer operated at 1 ,500-5,000 rpm, more preferably at 1 ,500-3,000 rpm.
  • the emulsion may be prepared in one to two minutes. The emulsification is complete when the viscosity increases suddenly and dramatically from between 100 and 1 ,000 cp to >8,000 cp. The droplet size will decrease to the 1 - ⁇ 5 micron range at this point, and no further decrease will be observed.
  • the concentrate is then ready for redispersion into an external aqueous phase (to form a w/o/w e
  • High internal phase ratios may be obtained in the w/o/w emulsions by adding electrolytes to the internal aqueous phase prior to emulsification and by forming the emulsion at lower internal phase ratios.
  • the internal aqueous phase will swell to between 75% and 95% water, depending on the excess electrolyte concentration in the internal phase, after shearing for one to two hours in the external aqueous phase.
  • the electrolyte may be univalent, such as NaCI or KCI, it may contain a divalent cation such as Ca 2+ or MG 2"1" , or it may contain a trivalent cation such as A
  • CaCI 2 or Na3P ⁇ 4 will give a vastly increased swelling rate over NaCI. This phenomenon may be utilized to provide controlled release of flavors or medicinal compounds.
  • the anion may be a halogen ion, an acetate ion, or a polyvalent anion such as PO ⁇ -, CO3 2 - or citrate, or a protonated form of such ion for example, HPO ⁇ -, H 2 P ⁇ 4 _ . HCO3.
  • HCit 2- , H Cit ' ' " in which case the electrolyte will serve as a buffer in cases where necessary in an application, for example, to control microbial growth or to neutralize a flavor component or to prevent curdling in a dairy product.
  • solutes in the internal and external phase may be manipulated to control the water amount in the internal phase.
  • water will migrate from the external phase through the oil layer into the internal phase. This will cause the oil continuous emulsion to swell.
  • excess salt (or other solute) in the internal phase the emulsion may be added at 70 wt. percent water and during processing, increase to 85% water. This constitutes a doubling of actual emulsion volume (from 30% fat to 15%).
  • vinegar is added in excess to the external phase, swelling of the w/o emulsion occurs as well. This phenomenon can also be exploited to control the degree of fat replacement by water. This would be particularly useful in an oil/vinegar salad dressing.
  • the emulsion concentrate may also serve as a controlled release vehicle for water soluble flavors or medicinal compounds.
  • the w/o emulsion concentrate of the invention is a high internal phase water in oil emulsion with a volume fraction of 0.67 - 0.95 as water and 0.05- 0.33 as the oil phase which ensheathes the water. As such, it is viscous but highly flexible such that it may be sheared to a very small doplet size and still retain its oil continuous characteristics without losing the internal water core.
  • the emulsion does not conduct electricity. It possesses long term staiblity to phase separation.
  • These emulsion concentrates are stable for greater than 8 months both as concentrate and in dispersed form. Because the emulsion concentrate is oil continuous, evaporation is retarded. The water core is so finely dispersed that microbial growth and activity is minimal.
  • the emulsion has a sensory quality that mimics that of a high oil or fat containing system.
  • the density of the emulsion depends largely on the composition of the internal phase.
  • the internal phase may contain a hydrocolloid which will bind water and increase the density of the emulsion to the equivalent of (or greater than) that of the external phase. This increases the stability of the emulsion to creaming and will allow the emulsion to serve as a clouding agent. This is significant because of the current need for such systems for use in beverages requiring a high degree of opacity. Presently, brominated oils are used, which may be questionable from a health safety standpoint. It is also possible to increase the density of the emulsion by incorporating an electrolyte into the internal phase in high concentrations, but it must be taken into account that the internal phase weight fraction will increase, requiring a smaller beginning volume fraction.
  • the droplets are somewhat hydrophobic and, like fats and oils, having a tendency to coalesce in the aqueous environment unless they are suspended by the incorporation in the internal aqueous phase of solutes, as mentioned above, or sheared to a very small size (10-100 microns), or a thickening or gelling agent is incorporated in the external phase, such as carrageenan in combination with calcium caseinate, in the case of a lowfat milk substitute, or a gum such as xanthan, propylene glycol alginate, locust bean gum, gum arabic and the like.
  • the emulsions of the invention have a tendency to coat glass and adhere to glass and plastic surfaces to a greater degree than even fats and oils, and they are difficult to wash off a surface to which they are adhered. This can be overcome, if desired, by incorporating small quantities of gums or carrageenan into the external, continuous aqueous medium in which the oil-mimetic concentrate is dispersed.
  • the aqueous dispersing medium for a w/o/w emulsion of the invention may contain any desired flavoring agent, salt, vinegar, protein, antioxidant compounds, emulsifier, viscosity enhancer, gelling agent structuring agent, hydrocolloid or dispersed crystalline material, milk, egg or other solids.
  • the pH range is unimportant to the stability of the emulsion.
  • the droplet size is a function of the shear method and rate during dispersion of the concentrate in the aqueous (outer phase) dispersing medium when preparing a w/o/w emulsion of the invention. It may range from 5 to 500 microns. The preferred range to provide optimal fat simulation is 5-50 microns, and will depend on the food system into which it is incorporated.
  • the temperature of the concentrate and of the continuous medium is unimportant so long as 100°C is not greatly exceeded or sustained for a long period.
  • the concentrate may be added at any desired concentration with respect to the aqueous dispersing medium.
  • concentration level the higher the degree of the organoleptic property of density or fattiness.
  • the level will be 10-20%, but may contain as little as 1-2% real fat.
  • the level may be 4-8%, but the actual fat level may be as low as 0.5%, depending on the volume fraction of the internal phase of the concentrate.
  • the emulsion concentrate is formed by adding the aqueous phase to a surfactant containing oil phase using moderate shear at > 50°C, as follows:
  • modified microcrystalline cellulose (Avicel® RC-591 , FMC) is added to 396 gm of distilled deionized water and dispersed with a Silverson mixer. The dispersion is heated to 60°C.
  • step 3 The solution from step 2 is added to the solution from step 1 at a rate of 150 ml/min under constant mixing using a Caframo propeller mixer at 2000 rpm.
  • the emulsion is mixed for an additional 2 minutes after all the water is added.
  • the emulsion is cooled to room temperature and mixed again at 2000 rpm for 2 minutes.
  • the resulting emulsion can be redispersed in an aqueous solution containing a gelling hydrocolloid or other thickening agent, using a propeller mixer or a mill type mixer.
  • the resulting emulsion possesses fat mimetic organoleptic properties similar to an o/w emulsion.
  • An inversion resistant oil continuous emulsion containing 15% Oil (6.7:1 w/o) An emulsion is formed which may be used in water rich food systems and is temperature stable as follows:
  • step 3 The solution from step 2 is added to the solution from step 1 at the rate of 150 m/min under constant mixing with a Caframo mixer at 2,000 rpm. The emulsion is mixed for 3 minutes after the water is added. The emulsion is cooled slowly to room temperature and stirred for 3 more minutes at 2,000 rpm.
  • the resulting emulsion is creamy, smooth and heat stable. Its viscosity decreases on heating but is recovered on cooling. It is a stable, heat thinning, high internal phase w/o emulsion.
  • the emulsion may be redispersed into water or an aqueous mixture to form a w/o/w emulsion.
  • Mayonnaise is an oil-in-water emulsion.
  • the oil phase is replaced by a w/o emulsion containing 80 wt. % water.
  • the w/o emulsion is prepared by adding 320 gm water at 60°C at a rate of 100 gm per minute to 80 gm of liquid soybean oil containing 3 gm of egg yolk solids and 1.6 gm of polyglycerol polyricinoleate (Triodan R90, Grindsted) also at 60°C under constant agitation with a lightnin mixer at 4,000 rpm.
  • the emulsion is rapidly cooled to room temperature in an ice bath and mixed for 15 seconds with a lightnin mixer at 2,000 rpm.
  • a low fat oil-in-vinegar dressing A low fat oil-in-vinegar dressing
  • French dressing contains coarsely dispersed oil at levels above 35% in an acidic aqueous medium.
  • a w/o emulsion is used to replace the oil, resulting in an 80% fat reduction.
  • a w/o emulsion is prepared by adding 320 gm of water at 60°C to 80 gm of liquid vegetable oil + 1.6 gm of polyglycerol polyricinoleate at 60°C while agitating at 4,000 rpm with a propeller mixer.
  • the external water phase is prepared by mixing 100 gm of cider vinegar, 54 gm of water, 40 gm of sugar, 15 gm of salt, 15 gm of Worcestershire sauce, 20 gm of paprika, 3 gm of mustard, 3 gm of garlic, 3 gm of onion, 0.5 gm of white pepper, 2 gm of gum arabic, and 2 gm of dried egg yolk solids.
  • step 3 160 gm of the w/o emulsion prepared in step 1 is added to the mixture of step 2 using moderate stirring under a Silverson mixer for 2 minutes.
  • the resulting dressing contains 7% fat rather than 35% fat.
  • a lowfat milk with enhanced fat organoleptic characteristics is treated with a high internal phase w/o emulsion to increase its creaminess as follows:
  • a w/o emulsion is formed by adding 320 gm of water containing 15% maltodextrin 15 DE at 60°C to 80 gm of butter oil containing 1.6 gm of polyglycerol ester of ricinoleate at 60°C under constant agitation with a propeller mixer at 3,000-4,000 rpm.
  • a high internal phase w/o emulsion containing a water binding hydrocolloid in the internal aqueous phase is stabilized gravitationally in a continuous aqueous phase soft drink as follows:
  • a w/o emulsion is prepared by adding 400g of a 16 wt.% aqueous maltodextrin solution to 100g of liquid vegetable oil containing 2% polyglycerol polyricinoleate at 60°C under constant shear with a propeller mixer at 4,000 rpm. The emulsion is sheared once more for one minute after cooling to room temperature.
  • Example 7 One gram of the emulsion is then added, while shearing at 10,000 rpm, to 1 ,000 g of a carbonated orange drink containing 5% sugar, color and orange flavoring. The resulting soft drink will possess a stable, opaque appearance.
  • Example 7
  • An effective shortening must comprise a plastic solid at ambient temperatures and must therefore contain solid fats.
  • a shortening is prepared with 20% fat.
  • a w/o emulsion concentrate is prepared by adding 320 g of at 16% aqueous solution of maltodextrin 15 DE to 80g of liquid vegetable oil containing 2% polyglycerol polyricinoleate (Admul WOL, Quest) and 2% polysorbate 80 (Tween 80, ICI) in a Silverson mixer and shearing for two minutes.
  • the resulting suspension can be added at a level of 1g/ounce to coffee or tea to provide whitening and a dense fat like mouthfeel.
  • a reduced fat ice cream The w/o concentrate is prepared by adding 320g of an aqueous phase, which contains 1-% glycerol, to 80g of a fat phase containing 1.6 gm of Admul WOL and 78.4g of milkfat, both phases being at 60°C. 10 g of the concentrate is dispersed into skim milk at 5,000 rpm in a Silverson mixer. The modified milk may then be sued to make ice cream in the standard way. The ice cream will have comparable flavor mouthfeel of a full fat ice cream.
  • the glycerol lends freeze - thaw stability to the HIP emulsion.
  • a waterproof skincream for use as a sunblock and moisturizer is prepared as follows:
  • a skin cream is formed containing mineral oils of a variety of molecular weights as the external phase as follows. 400g water which contains 1% dispersed colloidal titanium dioxide as a UVA and UVB absorber is heated to 50°C and added in a Silverson mixer to 80 gm of an oil phase containing 78.4g mineral oil and 1% Triodan R90 (Grindstead). The ointment will not wash off in water without a strong soap and, because the emulsion is mostly water, it is a more effective skin moisturize than an ordinary oil. This is because the tendency of the oil to retard water evaporation from the skin is not as great as that of systems which contain large amounts of solubilized water.

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Abstract

La présente invention concerne des concentrés d'émulsion eau/huile stables, susceptibles de remise en suspension et à phase interne élevée. Lesdits concentrés présentent une phase huileuse dans un rapport allant d'environ 3,5 pour 1 à environ 19 pour 1 avec un faible cisaillement, et en utilisant comme émulsifiant à raison de 0,5 à 3% de poids de la phase huileuse un ester polyglycérolique d'acide ricinoléique polycondensé. Ces concentrés peuvent être utilisés par exemple comme imitateurs de corps gras dans l'industrie alimentaire, comme agent de turbidité pour la préparation de boissons, et dans des compositions cosmétiques et pharmaceutiques. Ces concentrés peuvent en outre intervenir dans des émulsions eau/huile/eau ou inclure de telles émulsions.
EP95905467A 1993-12-30 1994-12-27 Emulsions eau/huile et eau/huile/eau a phase interne elevee Withdrawn EP0737097A4 (fr)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US17677893A 1993-12-30 1993-12-30
US176778 1993-12-30
PCT/US1994/014884 WO1995017953A1 (fr) 1993-12-30 1994-12-27 Emulsions eau/huile et eau/huile/eau a phase interne elevee

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EP0737097A1 true EP0737097A1 (fr) 1996-10-16
EP0737097A4 EP0737097A4 (fr) 1997-04-09

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EP (1) EP0737097A4 (fr)
JP (1) JPH09501100A (fr)
AU (1) AU1407395A (fr)
CA (1) CA2180335A1 (fr)
MX (1) MX9500133A (fr)
WO (1) WO1995017953A1 (fr)

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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE19509301A1 (de) * 1995-03-15 1996-09-19 Henkel Kgaa Multiple W/O/W-Emulsionen
EP0769292A1 (fr) * 1995-09-29 1997-04-23 Sara Lee/DE N.V. Produits pour les soins dermatologiques et cosmétiques
DE19602619C2 (de) * 1996-01-25 1998-08-27 Beiersdorf Ag Stabile kosmetische und dermatologische Lichtschutzzubereitungen in Form von W/O-Emulsionen, enthaltend ein Triazinderivat, einen oder mehrere spezielle(n) W/O-Emulgator(en) und/oder weitere Komponenten
KR19980067138A (ko) * 1997-01-31 1998-10-15 박원훈 유전자 또는 생물학적 활성 약물을 세포내로 효과적으로 전달하는 지방 유제 및 그것의 제조방법
DE19715842B4 (de) * 1997-04-16 2006-03-16 Beiersdorf Ag Kosmetische und dermatologische Lichtschutzformulierungen mit einem Gehalt an Triazinderivaten und grenzflächenaktiven Substanzen sowie deren Verwendung
FR2768337B1 (fr) * 1997-09-16 1999-10-15 Oreal Emulsions triples du type e/h/e contenant un systeme photoprotecteur capable de filtrer les rayons uv; leurs utilisations en cosmetique
GB9900298D0 (en) * 1999-01-07 1999-02-24 Medical Res Council Optical sorting method
FR2793165B1 (fr) * 1999-05-07 2002-09-27 Amora Maille Nouvelles emulsions eau-dans-huile ou huile-dans-eau-dans-huile
FR2798601B1 (fr) * 1999-09-20 2001-12-21 Centre Nat Rech Scient Emulsion double polydisperse, emulsion double monodisperse correspondante et procede de preparation de l'emulsion monodisperse
JP2001149032A (ja) * 1999-11-25 2001-06-05 Kao Corp 食材組成物
KR100724326B1 (ko) * 2003-01-17 2007-06-04 타이요 카가꾸 가부시키가이샤 코엔자임 ｑ10 함유 조성물
US8506956B2 (en) * 2005-10-31 2013-08-13 Kaneka Corporation Method for stabilizing reduced coenzyme Q10
ES2373967T3 (es) * 2006-07-06 2012-02-10 Nestec S.A. Emulsión agua - en - aceite para productos de confitería, con un débil contenido en grasa.
US20120077880A1 (en) * 2010-09-24 2012-03-29 Conopco, Inc., D/B/A Unilever Highly Concentrated, Spherical Biopolymer Gel Particle Suspensions Prepared by HIPE-Gelation Process
US20130090392A1 (en) * 2011-10-07 2013-04-11 Tata Consultancy Services Limited One step method for the preparation of water/oil/water type multiple emulsion
JP5648770B1 (ja) * 2013-05-01 2015-01-07 キユーピー株式会社 Ｗ／ｏ／ｗ型乳化調味料
JP6557947B2 (ja) * 2014-07-11 2019-08-14 味の素株式会社 Ｗ／ｏ／ｗ型乳化物
KR102022778B1 (ko) * 2017-10-30 2019-09-18 이현경 식용유의 제조 방법
MX2020012398A (es) * 2018-05-18 2021-02-09 Unilever Ip Holdings B V Composicion alimenticia emulsionada.

Family Cites Families (2)

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Publication number Priority date Publication date Assignee Title
JPS60199833A (ja) * 1984-03-26 1985-10-09 Meiji Milk Prod Co Ltd 医薬品、化粧品等用ｗ／ｏ／ｗ型複合エマルジヨンの製造法
GB8813161D0 (en) * 1988-06-03 1988-07-06 Unilever Plc Emulsions

Non-Patent Citations (2)

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Title
No further relevant documents disclosed *
See also references of WO9517953A1 *

Also Published As

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EP0737097A4 (fr) 1997-04-09
WO1995017953A1 (fr) 1995-07-06
MX9500133A (es) 1997-03-29
AU1407395A (en) 1995-07-17
CA2180335A1 (fr) 1995-07-06
JPH09501100A (ja) 1997-02-04

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