EP0710731A2 - Utilisation d'un alliage ferreux contenant de l'azote pour pièces de machine soumises à une friction de surface coulissante - Google Patents

Utilisation d'un alliage ferreux contenant de l'azote pour pièces de machine soumises à une friction de surface coulissante Download PDF

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Publication number
EP0710731A2
EP0710731A2 EP95890181A EP95890181A EP0710731A2 EP 0710731 A2 EP0710731 A2 EP 0710731A2 EP 95890181 A EP95890181 A EP 95890181A EP 95890181 A EP95890181 A EP 95890181A EP 0710731 A2 EP0710731 A2 EP 0710731A2
Authority
EP
European Patent Office
Prior art keywords
iron
max
based alloy
pref
alloy according
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Ceased
Application number
EP95890181A
Other languages
German (de)
English (en)
Other versions
EP0710731A3 (fr
Inventor
Gerhard Dr. Hackl
Günter Dr. Hochörtler
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Voestalpine Boehler Edelstahl GmbH
Original Assignee
Boehler Edelstahl GmbH
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Boehler Edelstahl GmbH filed Critical Boehler Edelstahl GmbH
Publication of EP0710731A2 publication Critical patent/EP0710731A2/fr
Publication of EP0710731A3 publication Critical patent/EP0710731A3/fr
Ceased legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C38/00Ferrous alloys, e.g. steel alloys
    • C22C38/18Ferrous alloys, e.g. steel alloys containing chromium
    • C22C38/24Ferrous alloys, e.g. steel alloys containing chromium with vanadium
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C38/00Ferrous alloys, e.g. steel alloys
    • C22C38/18Ferrous alloys, e.g. steel alloys containing chromium
    • C22C38/22Ferrous alloys, e.g. steel alloys containing chromium with molybdenum or tungsten

Definitions

  • the invention relates to the use of an iron-based alloy according to the Preamble of claim 1. Furthermore, the invention relates to a Plunger and / or a piston ring.
  • Machine parts that function as high or main Stress caused by sliding friction, especially surface friction are preferably made of cast materials.
  • Cast parts have the advantage that they are essentially isometric Experience changes in shape when the temperature changes, therefore in practice Use does not look bad, a largely undirected structure have a homogeneous microhard particle distribution, for example Carbide distribution, and have such a soft matrix configuration.
  • Such a structure has a particularly advantageous effect on friction surfaces reduces the frictional forces as well as the material removal in particular inadequate or low and / or imperfect lubricant deposits Surface.
  • plain bearings, cylinder liners, piston rings and similar machine parts that are subjected to high stress Exposed to sliding friction, mainly from cast or sintered Materials, especially iron-based alloys.
  • deformed material i.e. materials, who may have a line-shaped deformation structure.
  • deformed parts i.e. those with a micro-texture, mostly corresponded at least partially the requirements placed on them in practical operation; at the manufacture, however, involves a large number of complex process steps necessary for a shape or dimension required for the use and set the desired material properties.
  • Piston rings made of deformed materials can be manufactured be by essentially after rolling and optionally drawing of a profile wire, this is tempered and wound into a spiral or cold-formed becomes. It is advantageous if at least after a necessary annealing partial reduction of the cold forming stresses or hardening of them spiral preform of the profile wire to a piston ring spiral, if necessary with smaller radius adapted to the respective piston ring diameter, is wrapped or further deformed, whereupon, preferably after another Relaxation treatment or annealing, a slicing, essentially in Direction of a generator, which may be out of round spiral and the individual rings formed are then processed.
  • a slicing essentially in Direction of a generator, which may be out of round spiral and the individual rings formed are then processed.
  • An out of round Shape of the piston rings in the relaxed state can be chosen to in their Working position in the cylinder pressed radially inwards on all sides around an inside substantially equal specific contact pressure of the outer ring surface to the Reach cylinder wall.
  • the piston rings should have a hardness of 35 HRC to 45 HRC, especially over 40 HRC.
  • the invention aims to overcome the disadvantages of the materials used to date for the production of machine parts that function as high Avoid exposure to sliding surface friction and the use of an alloy, which is high hardness and high Bending toughness with improved performance properties and great Propose economy in the manufacture of the parts.
  • the invention is also based on the object of being corrosion-resistant Plunger and piston rings with improved properties in the to create practical use.
  • This goal is achieved by using an iron based alloy containing the Elements carbon, silicon, manganese, nitrogen, chromium, molybdenum and vanadium and optionally aluminum, cobalt, nickel, tungsten, niobium and titanium Provided that the sum of the concentration of carbon and nitrogen one Value of at least 0.5 and at most 1.2, preferably at least 0.61, but at most 0.95, results, the rest iron and melting-related Additives for the production of machine parts that function as a exposed to high stresses caused by sliding surface friction.
  • the advantages achieved by the invention can be seen essentially in the fact that by alloying an iron base alloy with both carbon and Nitrogen in a certain ratio and within a certain Concentration range the performance characteristics of a manufactured Machine part, especially with regard to high stress sliding surface friction, are surprisingly significantly improved synergistically.
  • a high material hardness is due to both elements, i.e. carbon and Nitrogen causes so that the absolute carbon content of the proposed Alloy lowered and thereby the bending toughness are increased. Is natural this also reduces the carbide content, in particular the Cr carbide content, which increases the Cr concentration in the matrix and the corrosion resistance of the material can be significantly improved. Due to the nitrogen content also causes a special fine grain structure and grain growth largely hindered even at high temperatures.
  • the Iron-based alloy used according to the invention at least partially with a Surface nitriding layer is provided.
  • Nitriding the finished part to Example of a piston ring can be done during a tempering treatment and is therefore particularly economical to carry out. It is convenient if the Alloy contains aluminum because this promotes nitriding layer formation. Nitriding causes an increase in volume of the Material, which causes the tensile stresses on the surface of the bend stressed part reduced, reduced or converted into compressive stresses and the risk of crack initiation is largely eliminated.
  • the Friction surface of the part with at least a depth of 0.05 mm, preferably of greater than 0.2 mm, nitrided or carbonitrided, high surface hardness and also achieved extremely low sliding friction values.
  • a plunger in particular for the displacement of corrosive media characterized in that it is made of an iron-based alloy according to claim 1 and consists of a layer applied by the PVD or CVD process Carbide and / or nitride of the elements Al and / or Ti carries.
  • a piston ring according to the invention in particular for internal combustion engines, is characterized in that it is made of an iron-based alloy Claim 1 is formed and optionally at least partially, in particular of the surface mainly exposed to friction, a nitriding layer with a Thickness of at least 0.05 mm, preferably greater than 0.2 mm.

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Mechanical Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Pistons, Piston Rings, And Cylinders (AREA)
EP95890181A 1994-11-04 1995-10-11 Utilisation d'un alliage ferreux contenant de l'azote pour pièces de machine soumises à une friction de surface coulissante Ceased EP0710731A3 (fr)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
AT0205194A AT402224B (de) 1994-11-04 1994-11-04 Verwendung einer eisenbasislegierung sowie plungerkolben und kolbenring
AT2051/94 1994-11-04

Publications (2)

Publication Number Publication Date
EP0710731A2 true EP0710731A2 (fr) 1996-05-08
EP0710731A3 EP0710731A3 (fr) 1996-11-27

Family

ID=3526724

Family Applications (1)

Application Number Title Priority Date Filing Date
EP95890181A Ceased EP0710731A3 (fr) 1994-11-04 1995-10-11 Utilisation d'un alliage ferreux contenant de l'azote pour pièces de machine soumises à une friction de surface coulissante

Country Status (3)

Country Link
US (1) US5916517A (fr)
EP (1) EP0710731A3 (fr)
AT (1) AT402224B (fr)

Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE19924515A1 (de) * 1999-05-28 2000-11-30 Edelstahl Witten Krefeld Gmbh Sprühkompaktierter Stahl, Verfahren zu seiner Herstellung und Verbundwerkstoff
EP1304393A1 (fr) * 2000-07-17 2003-04-23 Kabushiki Kaisha Riken Segment de piston presentant une resistance elevee a l'erosion, a la fissuration et a la fatigue, procede permettant de produire ce segment et combinaison segment de piston et bloc-cylindres
DE19808276C2 (de) * 1998-02-27 2003-12-24 Stahlwerk Ergste Westig Gmbh Stahllegierung für Gleitelemente
DE102006007148A1 (de) * 2006-02-16 2007-08-30 Volkswagen Ag Kolben für Verbrennungsmotoren und Verfahren zur Herstellung eines Kolbens für Verbrennungsmotoren
EP2810737A4 (fr) * 2012-01-31 2016-03-23 Kobe Steel Ltd Pièce mécanique soudée par un matériau de recouvrement de soudure et un métal de recouvrement de soudure
DE102019120611A1 (de) * 2019-07-31 2020-05-28 Schaeffler Technologies AG & Co. KG Hebelartiger Nockenfolger und dessen Verwendung

Families Citing this family (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
TW477821B (en) * 1998-12-24 2002-03-01 Nisshin Steel Co Ltd An abrasion-resistant steel and a weaving machine member make of an abrasion-resistant
DE10014515C2 (de) * 2000-03-23 2003-03-13 Federal Mogul Burscheid Gmbh Kolbenring mit Verschleißschutzschicht sowie Verschleißschutzschicht für einen Kolbenring
US6485026B1 (en) 2000-10-04 2002-11-26 Dana Corporation Non-stainless steel nitrided piston ring, and method of making the same
DE20104270U1 (de) * 2001-03-13 2002-07-18 Bosch Gmbh Robert Verbindung zweier koaxial hintereinander angeordneter Elemente einer Kraftstoffversorgungsanlage einer Brennkraftmaschine
JP4427790B2 (ja) * 2004-06-04 2010-03-10 大同特殊鋼株式会社 マルテンサイト系ステンレス鋼
CN106636895A (zh) * 2016-11-30 2017-05-10 重庆材料研究院有限公司 特种轴承钢及其制造方法

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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3990892A (en) * 1972-03-28 1976-11-09 Kabushiki Kaisha Fujikoshi Wear resistant and heat resistant alloy steels
US3969109A (en) * 1974-08-12 1976-07-13 Armco Steel Corporation Oxidation and sulfidation resistant austenitic stainless steel
US4150978A (en) * 1978-04-24 1979-04-24 Latrobe Steel Company High performance bearing steels
JPS55134159A (en) * 1979-04-06 1980-10-18 Daido Steel Co Ltd Vortex combustion chamber member for diesel engine and mouthpiece material thereof
AT392485B (de) * 1985-05-21 1991-04-10 Boehler Gmbh Werkstoff zur herstellung von stanz- und gegenplatten
EP0295111B1 (fr) * 1987-06-11 1994-11-02 Aichi Steel Works, Ltd. Acier présentant une résistance élevée à l'usure
JPH0577308A (ja) * 1991-04-24 1993-03-30 Hitachi Metals Ltd 合成樹脂成形用スクリユ
DE4212966C2 (de) * 1992-04-18 1995-07-13 Ver Schmiedewerke Gmbh Verwendung eines martensitischen Chrom-Stahls
JPH0665639A (ja) * 1992-08-19 1994-03-08 Nippon Steel Corp 均一微細な炭化物組織を有し衝撃靭性に優れた高炭素含有ステンレス鋼帯の製造方法
FR2708939B1 (fr) * 1993-08-11 1995-11-03 Sima Sa Acier martensitique à l'azote à faible teneur en carbone et son procédé de fabrication.
AT401387B (de) * 1994-06-29 1996-08-26 Boehler Ybbstalwerke Korrosionsbeständige legierung und verfahren zur herstellung korrosionsbeständiger schneidwaren

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
None

Cited By (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE19808276C2 (de) * 1998-02-27 2003-12-24 Stahlwerk Ergste Westig Gmbh Stahllegierung für Gleitelemente
DE19924515A1 (de) * 1999-05-28 2000-11-30 Edelstahl Witten Krefeld Gmbh Sprühkompaktierter Stahl, Verfahren zu seiner Herstellung und Verbundwerkstoff
EP1304393A1 (fr) * 2000-07-17 2003-04-23 Kabushiki Kaisha Riken Segment de piston presentant une resistance elevee a l'erosion, a la fissuration et a la fatigue, procede permettant de produire ce segment et combinaison segment de piston et bloc-cylindres
EP1304393A4 (fr) * 2000-07-17 2005-08-03 Riken Kk Segment de piston presentant une resistance elevee a l'erosion, a la fissuration et a la fatigue, procede permettant de produire ce segment et combinaison segment de piston et bloc-cylindres
DE102006007148A1 (de) * 2006-02-16 2007-08-30 Volkswagen Ag Kolben für Verbrennungsmotoren und Verfahren zur Herstellung eines Kolbens für Verbrennungsmotoren
EP2810737A4 (fr) * 2012-01-31 2016-03-23 Kobe Steel Ltd Pièce mécanique soudée par un matériau de recouvrement de soudure et un métal de recouvrement de soudure
DE102019120611A1 (de) * 2019-07-31 2020-05-28 Schaeffler Technologies AG & Co. KG Hebelartiger Nockenfolger und dessen Verwendung

Also Published As

Publication number Publication date
EP0710731A3 (fr) 1996-11-27
ATA205194A (de) 1996-07-15
AT402224B (de) 1997-03-25
US5916517A (en) 1999-06-29

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