EP0655208A1 - Applicator device for liquids - Google Patents
Applicator device for liquids Download PDFInfo
- Publication number
- EP0655208A1 EP0655208A1 EP94402607A EP94402607A EP0655208A1 EP 0655208 A1 EP0655208 A1 EP 0655208A1 EP 94402607 A EP94402607 A EP 94402607A EP 94402607 A EP94402607 A EP 94402607A EP 0655208 A1 EP0655208 A1 EP 0655208A1
- Authority
- EP
- European Patent Office
- Prior art keywords
- dispensing
- dome
- valve
- liquid
- support
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
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Classifications
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B65—CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
- B65D—CONTAINERS FOR STORAGE OR TRANSPORT OF ARTICLES OR MATERIALS, e.g. BAGS, BARRELS, BOTTLES, BOXES, CANS, CARTONS, CRATES, DRUMS, JARS, TANKS, HOPPERS, FORWARDING CONTAINERS; ACCESSORIES, CLOSURES, OR FITTINGS THEREFOR; PACKAGING ELEMENTS; PACKAGES
- B65D83/00—Containers or packages with special means for dispensing contents
- B65D83/14—Containers or packages with special means for dispensing contents for delivery of liquid or semi-liquid contents by internal gaseous pressure, i.e. aerosol containers comprising propellant for a product delivered by a propellant
- B65D83/28—Nozzles, nozzle fittings or accessories specially adapted therefor
- B65D83/285—Nozzles, nozzle fittings or accessories specially adapted therefor for applying the contents, e.g. brushes, rollers, pads, spoons, razors, scrapers
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- A—HUMAN NECESSITIES
- A45—HAND OR TRAVELLING ARTICLES
- A45D—HAIRDRESSING OR SHAVING EQUIPMENT; EQUIPMENT FOR COSMETICS OR COSMETIC TREATMENTS, e.g. FOR MANICURING OR PEDICURING
- A45D34/00—Containers or accessories specially adapted for handling liquid toiletry or cosmetic substances, e.g. perfumes
- A45D34/04—Appliances specially adapted for applying liquid, e.g. using roller or ball
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- A—HUMAN NECESSITIES
- A45—HAND OR TRAVELLING ARTICLES
- A45D—HAIRDRESSING OR SHAVING EQUIPMENT; EQUIPMENT FOR COSMETICS OR COSMETIC TREATMENTS, e.g. FOR MANICURING OR PEDICURING
- A45D2200/00—Details not otherwise provided for in A45D
- A45D2200/10—Details of applicators
- A45D2200/1009—Applicators comprising a pad, tissue, sponge, or the like
- A45D2200/1018—Applicators comprising a pad, tissue, sponge, or the like comprising a pad, i.e. a cushion-like mass of soft material, with or without gripping means
Definitions
- the present invention relates to an applicator device for liquid and in particular a device usable for the application, topically, to the skin of a product with cosmetic or dermopharmaceutical action, such as a deodorant for example.
- the use of aerosol distribution involves the ejection into the atmosphere, together with the liquid particles of the aerosol, of the pressurizing gas; if pressurization is carried out with a non-liquefied compressed gas, for example with air, the distribution pressure decreases as the tank is discharged, so that at the end of distribution the particles of l are too large; if pressurization is carried out with a partially liquefied chlorofluoroalkane, air pollution is generated; if, finally, the pressurization is ensured with butane or partially liquefied propane, the product can in no case be considered hypoallergenic, given the risk run by certain subjects when inhaling the propellant.
- an applicator device for liquid comprising a container of the liquid to be applied to a surface to be treated and a dispensing dome connected to said container by a dispensing head, the dispensing dome being made of a porous material suitable for applying the liquid by simple rubbing of the external face of said dome on the surface to be treated, the container being a pressurized tank equipped with a dispensing valve, the dispensing dome being carried by a support, which constitutes an element of the dispensing head and is mechanically linked to a nozzle capable of cooperating with said valve to cause it to open under the action mechanical stress exerted on the dispensing dome, the liquid ejected from the reservoir during said opening being channeled through said nozzle towards the face of the dispensing dome, which is opposite to the external face of said dome, the dispensing head comprising a member hooking for securing said head with the tank and the hooking member being
- Such a device has the advantage of not requiring any reversal prior to application; however, its use is not easy: on the one hand, the dispensing dome is guided along the axis of the stem of the dispensing valve which it is necessary to actuate along this axis for its opening while a transverse movement must be given to the device for spreading the product over the surface to be treated, and, on the other hand, this axial force of opening the valve is carried out against the elastic means specific to the dispensing valve and it is difficult to adjust or dose the distribution of the product.
- the object of the present invention is to propose an applicator device of the above type, which eliminates all the above-mentioned drawbacks and which can be produced for a reduced cost price.
- the device according to the invention can be used for the distribution of cosmetic or dermopharmaceutical products but is in no way limited to this type of application: it can be used in all cases where it is desired to spread a liquid over a surface by means of an applicator.
- the device according to the invention therefore has the advantage of not requiring any reversal prior to the application, which constitutes an additional advantage for the user, in particular for the application of deodorants or antiperspirants to the armpits.
- a flexible element connects said attachment member and the support of the dispensing dome.
- the rigid skirt is connected in the vicinity of its upper edge to a cylindrical wall, which constitutes the flexible element.
- the dispensing head is made in one piece by molding of plastic material.
- the applicator device according to the invention can simultaneously include the three above characteristics.
- the support of the dispensing dome is a cup having, on at least one zone, a depression capable of collecting an excess of liquid ejected by the valve.
- the reservoir is a cylindrical container, the top of which is shaped as a warhead and carries the dispensing valve, a latching groove being provided in the connection zone of the cylindrical wall and the warped wall, the rigid skirt being cylindrical and carrying in the vicinity of one of its edges a latching means able to cooperate with said latching groove.
- the flexible element connects the zone of the rigid skirt, which is furthest from the latching zone, at the periphery of the support of the dispensing dome; the rigid skirt and the flexible element may consist of a continuous wall surrounding the dispensing valve when the dispensing head is snapped onto the reservoir; but the flexible element could also be produced in discontinuous form by a plurality of successive sectors.
- the dispensing head is, apart from the means (s) for attaching the dispensing dome, a part of revolution about an axis.
- the dispensing valve comprises an emerging rod, which is partially inserted, in a sealed manner, in an internal pipe of the end piece; the nozzle can be arranged in the central area of the support of the dispensing dome, said nozzle having a cylindrical shape along the axis of which is formed its internal pipe.
- valve dispensing valve is an opening valve by lateral tilting of its emerging stem.
- the dispensing dome may be made of a ceramic or plastic sintered material, in particular of a material obtained by compression of plastic particles; for example, one can use a sinter obtained by compression of calibrated polyethylene beads, said sinter having a porosity between 10 microns and 500 microns.
- the choice of porosity is generally made taking into account two parameters, on the one hand, the desired flow rate for the liquid to be applied and, on the other hand, the surface condition of the porous dome, which must be compatible with the surface to be treated that we are considering.
- the flow rate of a liquid is measured through a given thickness of the frit under a predetermined pressure difference and the equivalent section of a pipe deducing the same flow rate is deduced therefrom. conditions and therefore, the average diameter of a pore when we statistically know the number of pores per unit area of the dome.
- the distributor dome is made of a plastic frit, it can be constituted by synthetic resins such as high or low density polyethylenes, polypropylenes or polyvinyl fluorides, the preferred porosity range extending from 10 to 200 microns.
- the dispensing dome of the device according to the invention can also be produced by means of an open cell foam, for example a polyethylene foam; this foam can be covered with a canvas for the comfort of the application.
- an open cell foam for example a polyethylene foam
- the dispensing dome is made of a non-deformable material.
- the application face of the dispensing dome has a roughness such that the average Ra of the roughness differences is between 0.5 ⁇ m and 100 ⁇ m, preferably between 6 ⁇ m and 50 ⁇ m.
- Another advantage of the device according to the invention comes from the fact that at the opening of the valve, the liquid is ejected in the direction of the dispensing dome by the pressurizing agent, but since it is not a question of aerosol dispensing, the pressurizing agent can remain entirely inside the container: there is therefore no risk of atmospheric pollution and no destruction of the possibly hypoallergenic nature of the liquid to be dispensed.
- the distribution is done without generating a cloud of liquid particles capable of being inhaled by the user with a sternutatory effect.
- the device according to the invention presents no risk of leakage since the dead volumes below the dispensing dome are extremely reduced; in case of distribution excessive instantaneous liquid, the liquid collects in the area of the dispensing dome, which occupies the depressions in the cup where said dispensing dome is placed. It is possible for the user to carry out a voluntary overdose by pressing with a finger on the surface of the dispensing dome before carrying out the application on the surface to be treated.
- This reservoir is a cylindrical container of circular cross section, the top of which is shaped like a warhead 2, which carries, at its upper part, a valve cup secured to the container by a crimping bead 3.
- the valve cup carries, according to its axis, a distribution valve 4 which, in the case of this example, is a valve comprising an emerging rod 5; the valve 4 is opened by lateral tilting of the emerging rod 5; the valve may be of the type sold by the company "COSTER" under the reference "TR 120-40".
- a peripheral snap groove 6 has been produced in the junction zone of the warhead 2 with the cylindrical wall of the reservoir 1, a peripheral snap groove 6 has been produced.
- a liquid for distribution has been pressurized.
- This liquid can be a liquid composition of body deodorant having a viscosity of approximately 0.003 Pa.s.
- Pressurization can be carried out either by bringing the liquid directly into contact with the propellant gas, or by separating the liquid and the propellant gas by a movable piston or by a flexible deformable pocket, which releases, in the latter case, from the obligation to use the device in a determined position, either valve at the top or valve at the bottom.
- butane was used as the propellant, the liquid being separated from the butane by a movable piston.
- a dispensing head which comprises, on the one hand, a rigid skirt 7, on the other hand, a cup 8, which constitutes the support of a dispensing dome 9 and, finally, a flexible element 10, which connects the cup 8 and the rigid skirt 7.
- the rigid skirt 7 has internally, at its base, an annular latching bead 11, which is intended to cooperate with the latching groove 6
- the rigid skirt 7 is connected in the vicinity of its upper edge 7 a to a cylindrical wall, which constitutes the flexible element 10, the connection being effected in a rounded zone 10 a , the convexity of which is turned towards the latching bead 11.
- the rigid skirt 7 and the flexible element 10 have a generally cylindrical shape and constitute coaxial cylinders.
- the cup 8 Along its border, which is opposite the zone 10 to the flexible element 10, is connected to the cup 8; said cup 8 has an annular depression 8 a at the bottom of which there are projections 12 which constitute attachment means for the dispensing dome 9.
- the cup 8 In its central zone, the cup 8 is secured to a nozzle 13 of cylindrical shape, said nozzle having along its axis a pipe 14, the lower part 14 a has an enlarged diameter, said part opening to the outside by a frustoconical mouth 14 b .
- the free end of the emerging rod 5 of the valve 4 is forcibly engaged over a few millimeters in order to obtain a sealed connection between the rod 5 and the end piece 13.
- the dispensing dome 9 has been put in place, which is constituted by a polyethylene frit having a porosity of 40 microns.
- the roughness of the distributor dome is such that the average Ra of the roughness differences is of the order of 15 ⁇ m; Ra is the arithmetic mean of the deviations of the real surface from the median surface; this arithmetic mean Ra is given by the formula: in which f (x) is the measurement of the distance from the real surface to the median surface at a point of abscissa x over a length l m , measured using a "SURFTEST 301" device sold by the company "MITUTOYO".
- the user applies the external surface 9a of the dome 9 against the surface treat, for example the skin of an armpit if the liquid conditioned in the reservoir 1 is a deodorant liquid. It then moves the device laterally relative to the armpit, from which a friction force results, which causes the deformation of the flexible element 10, and, consequently, a substantially radial displacement of the cup 8 relative to the tank 1 and therefore relative to the axis of the valve 4. There follows a lateral tilting of the emerging rod 5 and therefore an opening of the valve 4 with simultaneous ejection of the pressurized liquid in the tank 1.
- the liquid arrives on the internal face 9b of the dispensing dome 9; it is distributed over this entire internal face and, under the effect of the distribution pressure, it passes through the sinter constituting the distributor dome 9 so as to come flush with the external face 9 a of said dome.
- the liquid is then distributed by friction on the support to be treated, in this case the armpit skin; if there is an excess of liquid, the friction force decreases, which causes the valve 4 to close under the effect of the elastic return, which exists inside said valve.
- the device which has just been described, has an extremely reduced cost price because, the whole of the dispensing head constituted by the skirt 7, the flexible element 10 and the cup 8 can be produced. in one piece by plastic molding.
- the use of this device is particularly reliable since there can be no leakage.
- the approval of a topical application by means of this device is very satisfactory because the user feels a soft and non-greasy application with a freshness effect and the application can be carried out directly without prior turning over of the device.
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- Chemical & Material Sciences (AREA)
- Dispersion Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- Containers And Packaging Bodies Having A Special Means To Remove Contents (AREA)
- Coating Apparatus (AREA)
- Closures For Containers (AREA)
Abstract
Description
La présente invention concerne un dispositif applicateur pour liquide et notamment un dispositif utilisable pour l'application, par voie topique, sur la peau d'un produit à action cosmétique ou dermopharmaceutique, tel qu'un déodorant par exemple.The present invention relates to an applicator device for liquid and in particular a device usable for the application, topically, to the skin of a product with cosmetic or dermopharmaceutical action, such as a deodorant for example.
Dans le cas particulier de produits tels qu'un déodorant ou un antiperspirant, on a déjà proposé d'assurer l'application au moyen d'un bâton solide, dit "raisin", contenant l'actif à appliquer sur la peau de l'utilisateur ; un tel raisin peut avoir, en section droite, diverses formes choisies en fonction de l'utilisation et il est conditionné dans un étui permettant son déplacement au fur et à mesure de la consommation du raisin. L'inconvénient d'une telle présentation est, d'une part, qu'elle nécessite pour le conditionnement du produit des outillages spéciaux et onéreux et, d'autre part, que la conservation du raisin n'est généralement pas parfaitement assurée, car la composition solide utilisée contient un important pourcentage d'alcool et le conditionnement n'est généralement pas suffisamment étanche pour empêcher l'évaporation de l'alcool. En outre, le confort de l'utilisateur n'est pas parfaitement satisfaisant car l'application d'un raisin sur la peau donne, avec les compositions connues, une impression d'application grasse alors que l'utilisateur souhaite une application non grasse avec un effet rafraichissant.In the particular case of products such as a deodorant or an antiperspirant, it has already been proposed to ensure application by means of a solid stick, called "grape", containing the active ingredient to be applied to the skin of the user; such a grape can have, in cross section, various shapes chosen according to the use and it is packaged in a case allowing its movement as and when the grapes are consumed. The disadvantage of such a presentation is, on the one hand, that it requires for the packaging of the product special and expensive tools and, on the other hand, that the conservation of the grapes is generally not perfectly ensured, because the solid composition used contains a large percentage of alcohol and the packaging is generally not sufficiently tight to prevent evaporation of the alcohol. In addition, the comfort of the user is not perfectly satisfactory because the application of a grape to the skin gives, with the known compositions, an impression of oily application while the user wishes a non-oily application with a refreshing effect.
On a déjà proposé de surmonter ces inconvénients en proposant un applicateur qui met en oeuvre une composition liquide contenue dans un flacon sur lequel est fixée une tête de distribution portant un dôme distributeur réalisé en un matériau solide poreux. Ce type de réalisation a été décrit, par exemple, dans le brevet US-A-5 230 579 ou dans le brevet français FR-89-06490. L'inconvénient de ce type de conditionnement est double : d'une part, pour assurer la fermeture du flacon lorsque le produit n'est pas utilisé, il est nécessaire de prévoir une tête de distribution relativement compliquée, ce qui augmente de façon importante le coût du conditionnement ; et d'autre part, pour utiliser le produit, il est nécessaire d'effectuer une action préalable amenant le liquide dans le dôme poreux avec lequel on va assurer l'application : dans le cas des deux brevets antérieurs susmentionnés, cette action est un retournement préalable du flacon pour que le liquide descende par gravité dans le dôme poreux.It has already been proposed to overcome these drawbacks by proposing an applicator which implements a liquid composition contained in a bottle on which is fixed a dispensing head carrying a dispensing dome made of a porous solid material. This type of embodiment has been described, for example, in US-A-5,230,579 or in French patent FR-89-06490. The disadvantage of this type of packaging is twofold: firstly, to ensure the closure of the bottle when the product is not used, it is necessary to provide a relatively complicated dispensing head, which significantly increases the cost of packaging; and on the other hand, to use the product, it is necessary to perform a prior action bringing the liquid into the porous dome with which we will ensure the application: in the case of the two aforementioned prior patents, this action is a reversal the bottle so that the liquid descends by gravity into the porous dome.
On a également proposé d'appliquer les produits de ce type sous forme d'aérosol, auquel cas la composition liquide distribuée est parfaitement préservée pendant son stockage puisqu'elle se trouve à l'intérieur d'un récipient pressurisé fermé par une valve. Cependant, ce mode d'application présente des inconvénients importants : en effet, l'application, même lorsqu'elle est bien ciblée, génère un nuage de particules liquides qui est partiellement inhalé par l'utilisateur, d'où il résulte souvent un effet sternutatoire particulièrement désagréable, notamment lors de la toilette du matin dans la salle de bains, voire des réactions plus graves lorsqu'il s'agit de sujets asthmatiques particulièrement sensibles à l'inhalation de particules aérosols. En outre, l'utilisation d'une distribution par aérosol implique l'éjection dans l'atmosphère, en même temps que les particules liquides de l'aérosol, du gaz pressuriseur ; si l'on assure la pressurisation par un gaz comprimé non liquéfié, par exemple par de l'air, la pression de distribution décroît au fur et à mesure de la décharge du réservoir, de sorte qu'en fin de distribution les particules de l'aérosol sont trop grosses ; si l'on assure la pressurisation avec un chlorofluoroalcane partiellement liquéfié, on génère une pollution atmosphérique ; si, enfin, on assure la pressurisation avec du butane ou du propane partiellement liquéfié, le produit ne peut en aucun cas être considéré comme hypoallergénique, étant donné le risque encouru par certains sujets à l'inhalation du propulseur.It has also been proposed to apply products of this type in the form of an aerosol, in which case the dispensed liquid composition is perfectly preserved during its storage since it is inside a pressurized container closed by a valve. However, this mode of application has significant drawbacks: indeed, the application, even when it is well targeted, generates a cloud of liquid particles which is partially inhaled by the user, from which it often results particularly unpleasant sternutatory, especially during the morning toilet in the bathroom, or even more serious reactions in the case of asthmatic subjects particularly sensitive to the inhalation of aerosol particles. In addition, the use of aerosol distribution involves the ejection into the atmosphere, together with the liquid particles of the aerosol, of the pressurizing gas; if pressurization is carried out with a non-liquefied compressed gas, for example with air, the distribution pressure decreases as the tank is discharged, so that at the end of distribution the particles of l are too large; if pressurization is carried out with a partially liquefied chlorofluoroalkane, air pollution is generated; if, finally, the pressurization is ensured with butane or partially liquefied propane, the product can in no case be considered hypoallergenic, given the risk run by certain subjects when inhaling the propellant.
Dans le but de supprimer les inconvénients mentionnés ci-dessus, on a proposé, selon EP-A-0 374 339, un dispositif applicateur pour liquide comportant un conteneur du liquide à appliquer sur une surface à traiter et un dôme distributeur relié audit conteneur par une tête de distribution, le dôme distributeur étant réalisé en un matériau poreux adapté à l'application du liquide par simple frottement de la face externe dudit dôme sur la surface à traiter, le conteneur étant un réservoir pressurisé équipé d'une valve de distribution, le dôme distributeur étant porté par un support, qui constitue un élément de la tête de distribution et est mécaniquement lié à un embout apte à coopérer avec ladite valve pour provoquer son ouverture sous l'action d'une sollicitation mécanique exercée sur le dôme distributeur, le liquide éjecté hors du réservoir pendant ladite ouverture étant canalisé à travers ledit embout vers la face du dôme distributeur, qui est opposée à la face externe dudit dôme, la tête de distribution comportant un organe d'accrochage permettant de solidariser ladite tête avec le réservoir et l'organe d'accrochage étant une jupe rigide fixée sur le réservoir par encliquetage d'une zone d'encliquetage. Un tel dispositif présente l'intérêt de ne nécessiter aucun retournement préalable à l'application ; toutefois, son utilisation n'est pas aisée : d'une part, le dôme distributeur est guidé selon l'axe de la tige de la valve de distribution qu'il est nécessaire d'actionner selon cet axe pour son ouverture tandis qu'un mouvement transversal doit être donné au dispositif pour l'étalement du produit sur la surface à traiter, et, d'autre part, cet effort axial d'ouverture de la valve est effectué à l'encontre des moyens élastiques propres à la valve de distribution et il est difficile de régler ou doser la distribution du produit.In order to eliminate the drawbacks mentioned above, there has been proposed, according to EP-A-0 374 339, an applicator device for liquid comprising a container of the liquid to be applied to a surface to be treated and a dispensing dome connected to said container by a dispensing head, the dispensing dome being made of a porous material suitable for applying the liquid by simple rubbing of the external face of said dome on the surface to be treated, the container being a pressurized tank equipped with a dispensing valve, the dispensing dome being carried by a support, which constitutes an element of the dispensing head and is mechanically linked to a nozzle capable of cooperating with said valve to cause it to open under the action mechanical stress exerted on the dispensing dome, the liquid ejected from the reservoir during said opening being channeled through said nozzle towards the face of the dispensing dome, which is opposite to the external face of said dome, the dispensing head comprising a member hooking for securing said head with the tank and the hooking member being a rigid skirt fixed to the tank by snap-fastening of a snap-on area. Such a device has the advantage of not requiring any reversal prior to application; however, its use is not easy: on the one hand, the dispensing dome is guided along the axis of the stem of the dispensing valve which it is necessary to actuate along this axis for its opening while a transverse movement must be given to the device for spreading the product over the surface to be treated, and, on the other hand, this axial force of opening the valve is carried out against the elastic means specific to the dispensing valve and it is difficult to adjust or dose the distribution of the product.
La présente invention a pour but de proposer un dispositif applicateur du type ci-dessus, qui supprime tous les inconvénients ci-dessus mentionnés et qui peut être réalisé pour un prix de revient réduit. Le dispositif selon l'invention peut être utilisé pour la distribution de produits à action cosmétique ou dermopharmaceutique mais n'est aucunement limité à ce type d'application : il peut être utilisé dans tous les cas où l'on veut étaler un liquide sur une surface au moyen d'un applicateur. Dans le cas où il s'agit d'une application topique sur la peau d'un utilisateur, le dispositif selon l'invention présente donc l'intérêt de ne nécessiter aucun retournement préalable à l'application, ce qui constitue un avantage supplémentaire pour l'utilisateur, notamment pour l'application des déodorants ou antiperspirants au niveau des aisselles.The object of the present invention is to propose an applicator device of the above type, which eliminates all the above-mentioned drawbacks and which can be produced for a reduced cost price. The device according to the invention can be used for the distribution of cosmetic or dermopharmaceutical products but is in no way limited to this type of application: it can be used in all cases where it is desired to spread a liquid over a surface by means of an applicator. In the case where it is a topical application on the skin of a user, the device according to the invention therefore has the advantage of not requiring any reversal prior to the application, which constitutes an additional advantage for the user, in particular for the application of deodorants or antiperspirants to the armpits.
Selon une première caractéristique du dispositif selon l'invention, un élément souple relie ledit organe d'accrochage et le support du dôme distributeur.According to a first characteristic of the device according to the invention, a flexible element connects said attachment member and the support of the dispensing dome.
Selon une autre caractéristique du dispositif selon l'invention, la jupe rigide est reliée au voisinage de sa bordure supérieure à une paroi cylindrique, qui constitue l'élément souple.According to another characteristic of the device according to the invention, the rigid skirt is connected in the vicinity of its upper edge to a cylindrical wall, which constitutes the flexible element.
Selon encore une autre caractéristique du dispositif selon l'invention, la tête de distribution est réalisée en une seule pièce par moulage de matière plastique.According to yet another characteristic of the device according to the invention, the dispensing head is made in one piece by molding of plastic material.
Bien entendu, le dispositif applicateur selon l'invention peut comporter simultanément les trois caractéristiques ci-dessus.Of course, the applicator device according to the invention can simultaneously include the three above characteristics.
Dans un mode préféré de réalisation, le support du dôme distributeur est une coupelle présentant, sur au moins une zone, une dépression susceptible de recueillir un excès de liquide éjecté par la valve.In a preferred embodiment, the support of the dispensing dome is a cup having, on at least one zone, a depression capable of collecting an excess of liquid ejected by the valve.
Selon une réalisation intéressante, le réservoir est un bidon cylindrique, dont le sommet est conformé en ogive et porte la valve de distribution, une gorge d'encliquetage étant prévue dans la zone de raccordement de la paroi cylindrique et de la paroi en ogive, la jupe rigide étant cylindrique et portant au voisinage d'une de ses bordures un moyen d'encliquetage apte à coopérer avec ladite gorge d'encliquetage.According to an interesting embodiment, the reservoir is a cylindrical container, the top of which is shaped as a warhead and carries the dispensing valve, a latching groove being provided in the connection zone of the cylindrical wall and the warped wall, the rigid skirt being cylindrical and carrying in the vicinity of one of its edges a latching means able to cooperate with said latching groove.
De préférence, l'élément souple relie la zone de la jupe rigide, qui est la plus éloignée de la zone d'encliquetage, à la périphérie du support du dôme distributeur ; la jupe rigide et l'élément souple peuvent être constitués d'une paroi continue entourant la valve de distribution quand la tête de distribution est encliquetée sur le réservoir; mais l'élément souple pourrait également être réalisé sous forme discontinue par une pluralité de secteurs successifs. Avantageusement, la tête de distribution est, hormis le(s) moyen(s) d'accrochage du dôme distributeur, une pièce de révolution autour d'un axe.Preferably, the flexible element connects the zone of the rigid skirt, which is furthest from the latching zone, at the periphery of the support of the dispensing dome; the rigid skirt and the flexible element may consist of a continuous wall surrounding the dispensing valve when the dispensing head is snapped onto the reservoir; but the flexible element could also be produced in discontinuous form by a plurality of successive sectors. Advantageously, the dispensing head is, apart from the means (s) for attaching the dispensing dome, a part of revolution about an axis.
On préfère que la valve de distribution comporte une tige émergente, qui est partiellement enfoncée, de façon étanche, dans une canalisation interne de l'embout ; l'embout peut être disposé dans la zone centrale du support du dôme distributeur, ledit embout ayant une forme cylindrique selon l'axe de laquelle est ménagée sa canalisation interne.It is preferred that the dispensing valve comprises an emerging rod, which is partially inserted, in a sealed manner, in an internal pipe of the end piece; the nozzle can be arranged in the central area of the support of the dispensing dome, said nozzle having a cylindrical shape along the axis of which is formed its internal pipe.
Dans le cas d'un dispositif applicateur destiné à l'application sur la peau d'un produit cosmétique ou dermopharmaceutique, on peut avantageusement prévoir que la valve de distribution soit une valve à ouverture par basculement latéral de sa tige émergente.In the case of an applicator device intended for the application to the skin of a cosmetic or dermopharmaceutical product, it can advantageously be provided that the valve dispensing valve is an opening valve by lateral tilting of its emerging stem.
Le dôme distributeur peut être constitué d'un matériau fritté céramique ou plastique, notamment d'un matériau obtenu par compression de particules de matière plastique ; par exemple, on peut utiliser un fritté obtenu par compression de billes calibrées de polyéthylène, ledit fritté ayant une porosité comprise entre 10 microns et 500 microns. Le choix de la porosité est généralement effectué en tenant compte de deux paramètres, d'une part, le débit de passage désiré pour le liquide à appliquer et, d'autre part, I'état de surface du dôme poreux, qui doit être compatible avec la surface à traiter que l'on envisage. Pour définir la porosité, de façon connue, on mesure le débit de passage d'un liquide à travers une épaisseur donnée du fritté sous une différence de pression prédéterminée et on en déduit la section équivalente d'une canalisation assurant le même débit dans les mêmes conditions et donc, le diamètre moyen d'un pore quand on connait statistiquement le nombre de pores par unité de surface du dôme. Lorsque le dôme distributeur est réalisé en un fritté de matière plastique, il peut être constitué par des résines synthétiques telles que des polyéthylènes à haute ou basse densité, des polypropylènes ou des fluorures de polyvinyle, la gamme de porosité préférée s'étendant de 10 à 200 microns.The dispensing dome may be made of a ceramic or plastic sintered material, in particular of a material obtained by compression of plastic particles; for example, one can use a sinter obtained by compression of calibrated polyethylene beads, said sinter having a porosity between 10 microns and 500 microns. The choice of porosity is generally made taking into account two parameters, on the one hand, the desired flow rate for the liquid to be applied and, on the other hand, the surface condition of the porous dome, which must be compatible with the surface to be treated that we are considering. To define the porosity, in a known manner, the flow rate of a liquid is measured through a given thickness of the frit under a predetermined pressure difference and the equivalent section of a pipe deducing the same flow rate is deduced therefrom. conditions and therefore, the average diameter of a pore when we statistically know the number of pores per unit area of the dome. When the distributor dome is made of a plastic frit, it can be constituted by synthetic resins such as high or low density polyethylenes, polypropylenes or polyvinyl fluorides, the preferred porosity range extending from 10 to 200 microns.
Le dôme distributeur du dispositif selon l'invention peut également être réalisé au moyen d'une mousse à cellules ouvertes par exemple une mousse de polyéthylène ; cette mousse peut être recouverte d'une toile pour le confort de l'application.The dispensing dome of the device according to the invention can also be produced by means of an open cell foam, for example a polyethylene foam; this foam can be covered with a canvas for the comfort of the application.
Avantageusement, le dôme distributeur est constitué d'un matériau non déformable.Advantageously, the dispensing dome is made of a non-deformable material.
On peut prévoir de ménager des canaux sensiblement radiaux entre la face interne du support et la face inférieure du dôme distributeur, lesdits canaux pouvant être réalisés dans le dôme distributeur lui-même et/ou dans la paroi du support : ces canaux ont l'avantage d'assurer une bonne répartition du liquide à distribuer pour que la face externe du dôme distributeur soit uniformément alimentée par ledit liquide. Par ailleurs, on peut aussi prévoir de disposer, en vis-à-vis de l'extrémité du canal interne de l'embout, un obstacle jouant le rôle de brise-jet et visant le même but que celui ci-dessus indiqué pour les éventuels canaux sensiblement radiaux.Provision may be made for substantially radial channels between the internal face of the support and the underside of the distributor dome, said channels being able to be produced in the distributor dome itself and / or in the wall of the support: these channels have the advantage ensure good distribution of the liquid to be dispensed so that the external face of the dispensing dome is uniformly supplied with said liquid. Furthermore, it is also possible to provide, facing the end of the internal channel of the end piece, an obstacle playing the role of jet breaker and aiming at the same goal as that indicated above for the possible substantially radial channels.
Il convient de noter que, dans le cas où on utilise une valve à ouverture par basculement latéral, l'éjection du liquide hors du réservoir s'effectue en raison de la friction entre le dôme distributeur, d'une part, et la surface à traiter, d'autre part ; on peut régler l'importance de la friction déclenchant l'ouverture de la valve en jouant sur la déformabilité de l'élément souple qui, dans la tête de distribution, relie la jupe rigide et le support du dôme distributeur. En outre, il convient de noter que, si la face externe du dôme distributeur porte une pellicule de liquide, la force de friction entre le dôme distributeur et la surface à traiter sera faible, ce qui permettra de consommer la pellicule de liquide avant toute ouverture ultérieure de la valve de distribution. On pourra utiliser un élément souple plus ou moins facilement déformable, pour qu'en fonctionnement, la pression d'appui du dôme distributeur sur la surface à traiter soit celle qui est désirable pour l'application visée.It should be noted that, in the case where a valve with opening by lateral tilting is used, the ejection of the liquid out of the reservoir takes place due to the friction between the distributor dome, on the one hand, and the surface to be treat, on the other hand; we can adjust the amount of friction triggering the opening of the valve by playing on the deformability of the flexible element which, in the dispensing head, connects the rigid skirt and the support of the dispensing dome. In addition, it should be noted that, if the external face of the dispensing dome carries a film of liquid, the friction force between the dispensing dome and the surface to be treated will be low, which will make it possible to consume the film of liquid before any opening. distribution valve. We can use a flexible element more or less easily deformable, so that in operation, the support pressure of the dispensing dome on the surface to be treated is that which is desirable for the intended application.
Avantageusement, la face d'application du dôme distributeur a une rugosité telle que la moyenne Ra des écarts de rugosité est comprise entre 0,5 µm et 100 µm, de préférence entre 6 µm et 50 µm.Advantageously, the application face of the dispensing dome has a roughness such that the average Ra of the roughness differences is between 0.5 μm and 100 μm, preferably between 6 μm and 50 μm.
Un autre avantage du dispositif selon l'invention provient du fait qu'à l'ouverture de la valve, le liquide est éjecté en direction du dôme distributeur par l'agent de pressurisation mais qu'étant donné qu'il ne s'agit pas d'une distribution aérosol, l'agent de pressurisation peut rester entièrement à l'intérieur du conteneur : il n'y a donc aucun risque de pollution atmosphérique et aucune destruction du caractère éventuellement hypoallergénique du liquide à distribuer. En outre, la distribution se fait sans générer un nuage de particules liquides susceptibles d'être inhalé par l'utilisateur avec effet sternutatoire.Another advantage of the device according to the invention comes from the fact that at the opening of the valve, the liquid is ejected in the direction of the dispensing dome by the pressurizing agent, but since it is not a question of aerosol dispensing, the pressurizing agent can remain entirely inside the container: there is therefore no risk of atmospheric pollution and no destruction of the possibly hypoallergenic nature of the liquid to be dispensed. In addition, the distribution is done without generating a cloud of liquid particles capable of being inhaled by the user with a sternutatory effect.
Il convient, en outre, de noter que la détente du liquide à la sortie du réservoir pressurisé génère, en cas d'application topique, une impression de fraîcheur particulièrement agréable pour l'utilisateur.It should also be noted that the expansion of the liquid at the outlet of the pressurized reservoir generates, in the case of topical application, an impression of freshness which is particularly pleasant for the user.
Au surplus, le dispositif selon l'invention ne présente aucun risque de fuite étant donné que les volumes morts au-dessous du dôme distributeur sont extrêmement réduits ; en cas de distribution instantanée excessive du liquide, le liquide se rassemble dans la zone du dôme distributeur, qui occupe les dépressions de la coupelle où est mis en place ledit dôme distributeur. Il est possible à l'utilisateur d'effectuer un surdosage volontaire en appuyant avec un doigt sur la surface du dôme distributeur avant d'effectuer l'application sur la surface à traiter.Furthermore, the device according to the invention presents no risk of leakage since the dead volumes below the dispensing dome are extremely reduced; in case of distribution excessive instantaneous liquid, the liquid collects in the area of the dispensing dome, which occupies the depressions in the cup where said dispensing dome is placed. It is possible for the user to carry out a voluntary overdose by pressing with a finger on the surface of the dispensing dome before carrying out the application on the surface to be treated.
Pour mieux faire comprendre l'objet de l'invention, on va en décrire maintenant, à titre d'exemple purement illustratif et non limitatif, un mode de réalisation représenté sur le dessin annexé.To better understand the object of the invention, we will now describe, by way of purely illustrative and non-limiting example, an embodiment shown in the accompanying drawing.
Sur ce dessin : la figure unique représente, en coupe axiale, un dispositif applicateur selon l'invention.In this drawing: the single figure represents, in axial section, an applicator device according to the invention.
En se référant au dessin, on voit que l'on a désigné par 1 le réservoir pressurisé du dispositif selon l'invention. Ce réservoir est un bidon cylindrique de section droite circulaire, dont le sommet est conformé en une ogive 2, qui porte, à sa partie supérieure, une coupelle de valve solidarisée du bidon par un bourrelet de sertissage 3. La coupelle de valve porte, selon son axe, une valve de distribution 4 qui, dans le cas de cet exemple, est une valve comportant une tige émergente 5 ; l'ouverture de la valve 4 s'effectue par basculement latéral de la tige émergente 5 ; la valve peut être du type commercialisé par la société "COSTER" sous la référence "TR 120-40". Dans la zone de jonction de l'ogive 2 avec la paroi cylindrique du réservoir 1, on a réalisé une gorge d'encliquetage périphérique 6.Referring to the drawing, it can be seen that the pressure vessel of the device according to the invention has been designated by 1. This reservoir is a cylindrical container of circular cross section, the top of which is shaped like a warhead 2, which carries, at its upper part, a valve cup secured to the container by a
Dans le réservoir 1, on a conditionné sous pression un liquide à distribuer. Ce liquide peut être une composition liquide de déodorant corporel ayant une viscosité d'environ 0,003 Pa.s. La pressurisation peut être réalisée soit en mettant directement le liquide en contact avec le gaz propulseur, soit en séparant le liquide et le gaz propulseur par un piston mobile ou par une poche souple déformable, ce qui libère, dans ce dernier cas, de l'obligation d'utiliser le dispositif dans une position déterminée, soit valve en haut, soit valve en bas. Dans l'exemple décrit, on a utilisé comme gaz propulseur le butane, le liquide étant séparé du butane par un piston mobile.In the tank 1, a liquid for distribution has been pressurized. This liquid can be a liquid composition of body deodorant having a viscosity of approximately 0.003 Pa.s. Pressurization can be carried out either by bringing the liquid directly into contact with the propellant gas, or by separating the liquid and the propellant gas by a movable piston or by a flexible deformable pocket, which releases, in the latter case, from the obligation to use the device in a determined position, either valve at the top or valve at the bottom. In the example described, butane was used as the propellant, the liquid being separated from the butane by a movable piston.
Sur le réservoir qui vient d'être décrit, on a fixé une tête de distribution, qui comporte, d'une part, une jupe rigide 7, d'autre part, une coupelle 8, qui constitue le support d'un dôme distributeur 9 et, enfin un élément souple 10, qui relie la coupelle 8 et la jupe rigide 7. La jupe rigide 7 comporte intérieurement, à sa base, un bourrelet d'encliquetage annulaire 11, qui est destiné à coopérer avec la gorge d'encliquetage 6. La jupe rigide 7 est reliée au voisinage de sa bordure supérieure 7a à une paroi cylindrique, qui constitue l'élément souple 10, la liaison étant effectuée selon une zone arrondie 10a, dont la convexité est tournée vers le bourrelet d'encliquetage 11. La jupe rigide 7 et l'élément souple 10 ont une forme générale cylindrique et constituent des cylindres coaxiaux. Le long de sa bordure, qui est opposée à la zone 10a l'élément souple 10 se raccorde à la coupelle 8 ; ladite coupelle 8 comporte une dépression annulaire 8a au fond de laquelle se trouve des saillies 12 qui constituent des moyens d'accrochage pour le dôme distributeur 9. Dans sa zone centrale, la coupelle 8 est solidaire d'un embout 13 de forme cylindrique, ledit embout comportant selon son axe une canalisation 14, dont la partie inférieure 14a a un diamètre élargi, ladite partie débouchant à l'extérieur par une embouchure tronconique 14b. Dans la partie 14a de la canalisation 14, on engage à force, sur quelques millimètres, I'extrémité libre de la tige émergente 5 de la valve 4 pour obtenir un raccordement étanche entre la tige 5 et l'embout 13.On the tank which has just been described, a dispensing head has been fixed, which comprises, on the one hand, a rigid skirt 7, on the other hand, a cup 8, which constitutes the support of a dispensing
A l'intérieur de la coupelle 8, on a mis en place le dôme distributeur 9, qui est constitué par un fritté de polyéthylène ayant une porosité de 40 microns. La rugosité du dôme distributeur est telle que la moyenne Ra des écarts de rugosité est de l'ordre de 15 µm ; Ra est la moyenne arithmétique des écarts de la surface réelle par rapport à la surface médiane ; cette moyenne arithmétique Ra est donnée par la formule :
dans laquelle f(x) est la mesure de la distance de la surface réelle à la surface médiane en un point d'abscisse x sur une longueur ℓm, mesurée à l'aide d'un appareil "SURFTEST 301" commercialisé par la société "MITUTOYO".Inside the cup 8, the dispensing
in which f (x) is the measurement of the distance from the real surface to the median surface at a point of abscissa x over a length ℓ m , measured using a "SURFTEST 301" device sold by the company "MITUTOYO".
Pour mettre en oeuvre le dispositif ci-dessus décrit, l'utilisateur applique la face externe 9a du dôme 9 contre la surface à traiter, par exemple la peau d'une aisselle si le liquide conditionné dans le réservoir 1 est un liquide déodorant. Il déplace alors latéralement le dispositif par rapport à l'aisselle, d'où il résulte une force de friction, qui entraîne la déformation de l'élément souple 10, et, par conséquent, un déplacement sensiblement radial de la coupelle 8 par rapport au réservoir 1 et donc par rapport à l'axe de la valve 4. Il s'en suit un basculement latéral de la tige émergente 5 et donc une ouverture de la valve 4 avec éjection simultanée du liquide conditionné sous pression dans le réservoir 1. Le liquide arrive sur la face interne 9b du dôme distributeur 9 ; il se répartit sur toute cette face interne et, sous l'effet de la pression de distribution, il traverse le fritté constitutif du dôme distributeur 9 pour venir affleurer sur la face externe 9a dudit dôme. Le liquide est alors distribué par friction sur le support à traiter, en l'occurrence la peau de l'aisselle ; s'il y a un excès de liquide, la force de friction diminue, ce qui entraîne la fermeture de la valve 4 sous l'effet du rappel élastique, qui existe à l'intérieur de ladite valve.To implement the device described above, the user applies the
On constate que le dispositif, qui vient d'être décrit, est d'un prix de revient extrêmement réduit car, l'ensemble de la tête de distribution constitué par la jupe 7, I'élément souple 10 et la coupelle 8 peut être réalisé en une seule pièce par moulage de matière plastique. L'utilisation de ce dispositif est particulièrement fiable étant donné qu'il ne peut y avoir aucune fuite. Enfin, I'agrément d'une application topique au moyen de ce dispositif est très satisfaisant car l'utilisateur ressent une application douce et non grasse avec un effet de fraîcheur et l'application peut être effectuée directement sans retournement préalable du dispositif.It can be seen that the device, which has just been described, has an extremely reduced cost price because, the whole of the dispensing head constituted by the skirt 7, the
Claims (18)
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
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EP98202441A EP0875168B1 (en) | 1993-11-29 | 1994-11-17 | Applicator device for liquids |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
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FR9314235A FR2713060B1 (en) | 1993-11-29 | 1993-11-29 | Applicator device for liquid. |
FR9314235 | 1993-11-29 |
Related Child Applications (1)
Application Number | Title | Priority Date | Filing Date |
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EP98202441A Division EP0875168B1 (en) | 1993-11-29 | 1994-11-17 | Applicator device for liquids |
Publications (2)
Publication Number | Publication Date |
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EP0655208A1 true EP0655208A1 (en) | 1995-05-31 |
EP0655208B1 EP0655208B1 (en) | 1999-07-14 |
Family
ID=9453312
Family Applications (2)
Application Number | Title | Priority Date | Filing Date |
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EP98202441A Expired - Lifetime EP0875168B1 (en) | 1993-11-29 | 1994-11-17 | Applicator device for liquids |
EP94402607A Expired - Lifetime EP0655208B1 (en) | 1993-11-29 | 1994-11-17 | Applicator device for liquids |
Family Applications Before (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP98202441A Expired - Lifetime EP0875168B1 (en) | 1993-11-29 | 1994-11-17 | Applicator device for liquids |
Country Status (6)
Country | Link |
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US (1) | US5567073A (en) |
EP (2) | EP0875168B1 (en) |
CA (1) | CA2136585C (en) |
DE (2) | DE69432872T2 (en) |
ES (2) | ES2133510T3 (en) |
FR (1) | FR2713060B1 (en) |
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DE2017009A1 (en) * | 1970-04-09 | 1971-10-21 | Fritz, Victor, 6500 Mainz | Applicator for containers with cleaning liquids of all kinds |
US4089609A (en) * | 1976-10-15 | 1978-05-16 | Gring Frank M | Combination applicator and closure cap means for shaving cream containers |
EP0037903A1 (en) * | 1980-03-18 | 1981-10-21 | Lechner + Bek GmbH | Device for applying a pasty substance to a surface |
US4603992A (en) * | 1985-01-23 | 1986-08-05 | Kavoussi James P | Aerosol shaving brush |
EP0374339A1 (en) * | 1988-12-22 | 1990-06-27 | Artebel, S.A. | Actuator for a liquid-applicator |
FR2647034A1 (en) * | 1989-05-18 | 1990-11-23 | Oreal | APPLICATOR DEVICE FOR LIQUID, COMPRISING A DOME OF POROUS MATERIAL |
US5230579A (en) * | 1991-06-19 | 1993-07-27 | Carter-Wallace, Inc. | Porous dome applicator with push/pull cap |
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US3256549A (en) * | 1964-04-01 | 1966-06-21 | Seaquist Valve Co | Applicator-scrubber |
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US3663113A (en) * | 1970-08-14 | 1972-05-16 | John J Frain | Fluid applicator assembly |
US3685913A (en) * | 1970-09-22 | 1972-08-22 | Roger D Pass | Cream and lather applicator |
US3792802A (en) * | 1972-09-11 | 1974-02-19 | K Gores | Aerosol-can dispensing cap |
FR2391927A2 (en) * | 1975-12-03 | 1978-12-22 | Aerosol Inventions Dev | DISTRIBUTION KIT FOR AEROSOL CONTAINER |
US4050826A (en) * | 1976-02-11 | 1977-09-27 | Bristol-Myers Company | Liquid applicator |
US4277004A (en) * | 1979-10-15 | 1981-07-07 | Barlics John J | Cover and aerosol activator for aerosol spray can |
DE3475746D1 (en) * | 1983-09-02 | 1989-02-02 | American Cyanamid Co | Dispensing container having capillary pressure compensating valve |
GB2198035B (en) * | 1986-12-03 | 1990-10-24 | Mitsubishi Pencil Co | Writing or painting instrument |
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- 1993-11-29 FR FR9314235A patent/FR2713060B1/en not_active Expired - Fee Related
-
1994
- 1994-11-17 ES ES94402607T patent/ES2133510T3/en not_active Expired - Lifetime
- 1994-11-17 EP EP98202441A patent/EP0875168B1/en not_active Expired - Lifetime
- 1994-11-17 DE DE69432872T patent/DE69432872T2/en not_active Expired - Lifetime
- 1994-11-17 DE DE69419481T patent/DE69419481T2/en not_active Expired - Lifetime
- 1994-11-17 ES ES98202441T patent/ES2196478T3/en not_active Expired - Lifetime
- 1994-11-17 EP EP94402607A patent/EP0655208B1/en not_active Expired - Lifetime
- 1994-11-24 CA CA002136585A patent/CA2136585C/en not_active Expired - Lifetime
- 1994-11-28 US US08/348,983 patent/US5567073A/en not_active Expired - Lifetime
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US3345673A (en) * | 1965-10-19 | 1967-10-10 | Schwartzman Gilbert | Brush-type applicator |
CH466176A (en) * | 1968-04-04 | 1968-11-30 | Baumann Ag | Aerosol can for foam products |
DE2017009A1 (en) * | 1970-04-09 | 1971-10-21 | Fritz, Victor, 6500 Mainz | Applicator for containers with cleaning liquids of all kinds |
US4089609A (en) * | 1976-10-15 | 1978-05-16 | Gring Frank M | Combination applicator and closure cap means for shaving cream containers |
EP0037903A1 (en) * | 1980-03-18 | 1981-10-21 | Lechner + Bek GmbH | Device for applying a pasty substance to a surface |
US4603992A (en) * | 1985-01-23 | 1986-08-05 | Kavoussi James P | Aerosol shaving brush |
EP0374339A1 (en) * | 1988-12-22 | 1990-06-27 | Artebel, S.A. | Actuator for a liquid-applicator |
FR2647034A1 (en) * | 1989-05-18 | 1990-11-23 | Oreal | APPLICATOR DEVICE FOR LIQUID, COMPRISING A DOME OF POROUS MATERIAL |
US5230579A (en) * | 1991-06-19 | 1993-07-27 | Carter-Wallace, Inc. | Porous dome applicator with push/pull cap |
Cited By (10)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP0775641A1 (en) * | 1995-11-23 | 1997-05-28 | L'oreal | Dispensing device for fluid or solid products |
FR2741600A1 (en) * | 1995-11-23 | 1997-05-30 | Oreal | APPLICATION ASSEMBLY OF A FLUID OR SOLID PRODUCT |
US5876139A (en) * | 1995-11-23 | 1999-03-02 | L'oreal | Assembly for the application of a fluid or semi-solid product onto a surface |
EP0786421A1 (en) | 1996-01-29 | 1997-07-30 | L'oreal | Storage, dispensing and applying device for gel or foam |
FR2744104A1 (en) * | 1996-01-29 | 1997-08-01 | Oreal | DEVICE FOR PACKAGING, DISPENSING AND APPLYING A GEL OR FOAM |
US5813785A (en) * | 1996-01-29 | 1998-09-29 | L'oreal | Device for the packaging, dispensing and application of a gel or foam |
EP1002736A2 (en) * | 1998-11-18 | 2000-05-24 | Beiersdorf Aktiengesellschaft | Device for dispensing liquid substances onto the skin |
DE19853253A1 (en) * | 1998-11-18 | 2000-05-25 | Beiersdorf Ag | Device for applying liquid media to the skin |
EP1002736A3 (en) * | 1998-11-18 | 2001-07-11 | Beiersdorf Aktiengesellschaft | Device for dispensing liquid substances onto the skin |
EP1050473A1 (en) | 1999-05-05 | 2000-11-08 | Beiersdorf AG | Device for applying viscous media |
Also Published As
Publication number | Publication date |
---|---|
ES2196478T3 (en) | 2003-12-16 |
EP0655208B1 (en) | 1999-07-14 |
FR2713060B1 (en) | 1996-02-02 |
EP0875168B1 (en) | 2003-06-25 |
FR2713060A1 (en) | 1995-06-09 |
DE69419481D1 (en) | 1999-08-19 |
DE69432872T2 (en) | 2003-12-18 |
US5567073A (en) | 1996-10-22 |
EP0875168A2 (en) | 1998-11-04 |
DE69419481T2 (en) | 1999-11-18 |
EP0875168A3 (en) | 2000-02-23 |
DE69432872D1 (en) | 2003-07-31 |
CA2136585C (en) | 1999-02-02 |
ES2133510T3 (en) | 1999-09-16 |
CA2136585A1 (en) | 1995-05-30 |
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