EP0628623A1 - Composition lubrifiante pour différentiel à glissement limité d'une voiture - Google Patents
Composition lubrifiante pour différentiel à glissement limité d'une voiture Download PDFInfo
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- EP0628623A1 EP0628623A1 EP94107732A EP94107732A EP0628623A1 EP 0628623 A1 EP0628623 A1 EP 0628623A1 EP 94107732 A EP94107732 A EP 94107732A EP 94107732 A EP94107732 A EP 94107732A EP 0628623 A1 EP0628623 A1 EP 0628623A1
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- Prior art keywords
- lubricant composition
- composition according
- weight
- amine salt
- range
- Prior art date
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M141/00—Lubricating compositions characterised by the additive being a mixture of two or more compounds covered by more than one of the main groups C10M125/00 - C10M139/00, each of these compounds being essential
- C10M141/10—Lubricating compositions characterised by the additive being a mixture of two or more compounds covered by more than one of the main groups C10M125/00 - C10M139/00, each of these compounds being essential at least one of them being an organic phosphorus-containing compound
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- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M133/00—Lubricating compositions characterised by the additive being an organic non-macromolecular compound containing nitrogen
- C10M133/52—Lubricating compositions characterised by the additive being an organic non-macromolecular compound containing nitrogen having a carbon chain of 30 or more atoms
- C10M133/56—Amides; Imides
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- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M135/00—Lubricating compositions characterised by the additive being an organic non-macromolecular compound containing sulfur, selenium or tellurium
- C10M135/02—Sulfurised compounds
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- C10M135/00—Lubricating compositions characterised by the additive being an organic non-macromolecular compound containing sulfur, selenium or tellurium
- C10M135/02—Sulfurised compounds
- C10M135/06—Esters, e.g. fats
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- C10M135/00—Lubricating compositions characterised by the additive being an organic non-macromolecular compound containing sulfur, selenium or tellurium
- C10M135/20—Thiols; Sulfides; Polysulfides
- C10M135/22—Thiols; Sulfides; Polysulfides containing sulfur atoms bound to acyclic or cycloaliphatic carbon atoms
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- C10M137/00—Lubricating compositions characterised by the additive being an organic non-macromolecular compound containing phosphorus
- C10M137/02—Lubricating compositions characterised by the additive being an organic non-macromolecular compound containing phosphorus having no phosphorus-to-carbon bond
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- C10M137/00—Lubricating compositions characterised by the additive being an organic non-macromolecular compound containing phosphorus
- C10M137/02—Lubricating compositions characterised by the additive being an organic non-macromolecular compound containing phosphorus having no phosphorus-to-carbon bond
- C10M137/04—Phosphate esters
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- C10M2223/041—Triaryl phosphates
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- C10N2040/00—Specified use or application for which the lubricating composition is intended
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Definitions
- the present invention relates to a lubricant composition for a limited slip differential (LSD) of a car. More specifically, it relates to a lubricant composition for LSD which is excellent in oxidation stability and the prevention ability of the chattering (abnormal noise) of an LSD device incorporated in the differential of a car and which can be suitably applied to LSD of a studless tires-carrying car whose demand increases mainly in cold districts.
- LSD limited slip differential
- a wet multiplate clutch is used, and its differential controlling force is maintained by the frictional force of a metallic plate.
- a lubricant for this LSD is required to have extreme-pressure properties of a GL-5 class, and thus the lubricants containing a sulfurphosphorus additive and a friction modifier have been heretofore used.
- a lubricant composition having the desired characteristics can be obtained by adding a phosphate amine salt and a borated ashless dispersant to a base oil, and then adjusting a ratio between a nitrogen content and a phosphorus content and a ratio between a nitrogen content and a boron content.
- the present invention has been completed on the basis of such a knowledge.
- the present invention is directed to a lubricant composition for LSD of a car which is obtained by adding a phosphate amine salt and a borated ashless dispersant to a base oil comprising a mineral oil and/or a synthetic oil, a ratio (N/P) of a nitrogen content (N) to a phosphorus content (P) in the composition being 0.5 or more, and a ratio (N/B) of the nitrogen content (N) to a boron content (B) in the composition being 4 to 10.
- a lubricant composition for LSD of a car which is obtained by adding a phosphate amine salt and a borated ashless dispersant to a base oil comprising a mineral oil and/or a synthetic oil, a ratio (N/P) of a nitrogen content (N) to a phosphorus content (P) in the composition being 0.5 or more, and a ratio (N/B) of the nitrogen content (N) to a boron content (B) in the composition
- the base oil for the lubricant composition of the present invention there can be used conventional lubricating oils for LSD, various kinds of mineral oils and synthetic oils, and mixed oils thereof. No particular restriction is put on the kind and properties of base oil, but preferable are the mineral oils and/or the synthetic oils in which a kinematic viscosity at 100°C is in the range of 1 to 50 cSt.
- the suitable mineral oil and/or synthetic oil can be suitably selected in compliance with a use and the like from the various kinds of them.
- the mineral oils include paraffinic mineral oils and naphthenic mineral oils
- suitable examples of the synthetic oils include polymers and copolymers of olefins, esters of dibasic acids, polyglycols and hindered esters.
- the lubricant composition of the present invention can be obtained by blending the above-mentioned base oil with a phosphate amine salt and a borated ashless dispersant.
- the phosphate amine salt various kinds of compounds are present, but preferable examples of the phosphate amine salt include amine salts of phosphates and amine salts of phosphites.
- Typical examples of the phosphate amine salt include amine salts of alkyl acid phosphates having an alkyl group of 10 to 20 carbon atoms (e.g., amine salts of oleyl acid phosphates and amine salts of lauryl acid phosphates), and amine salts of alkyl hydrogenphosphites.
- the borated ashless dispersant various kinds of compounds can be used, but preferable examples of the borated ashless dispersant include reaction products (e.g., a reaction product of polybutenylsuccinimide and boric acid) of alkenylsuccinimides or alkenylsuccinamides having an alkenyl group of, preferably, 20 to 250 carbon atoms, more preferably 35 to 180 carbon atoms and boron compounds (e.g., boric acid and borates).
- reaction products e.g., a reaction product of polybutenylsuccinimide and boric acid
- boron compounds e.g., boric acid and borates
- the amounts of the phosphate amine salt and the borated ashless dispersant are determined so that a ratio (N/P) of a nitrogen content (N) to a phosphorus content (P) in the composition may be 0.5 or more, preferably 0.7 to 1.0 and so that a ratio (N/B) of a nitrogen content (N) to a boron content (B) in the composition may be 4 to 10, preferably 6 to 9.
- the weight ratio of N/P is less than 0.5, the lubricant composition are poor in frictional properites, and chattering is liable to occur and the abrasion of a friction plate increases. Furthermore, if the weight ratio of N/B is more than 10, heat resistance deteriorates and sludge is liable to be generated. Conversely, the weight ratio of N/B is less than 4, the frictional properites deteriorate.
- the amounts of the respective components in the lubricant composition of the present invention are determined so as to be in the above-mentioned ranges, but in addition to meeting the above-mentioned ranges, it is more preferable that the amount of the phosphate amine salt is in the range of 1 to 10% by weight, preferably 3 to 8% by weight based on the weight of the composition, and the amount of the borated ashless dispersant is in the range of 0.1 to 2% by weight, preferably 0.5 to 1.5% by weight based on the weight of the composition.
- the desired performance can be further effectively exerted by meeting these requirements and determining the amounts of the elements in the lubricant composition in the following ranges.
- a sulfur content to 1.5-5.0% by weight, a phosphorus content to 0.15-0.40% by weight, a nitrogen content to 0.08-0.30% by weight and a boron content to 0.01-0.04% by weight, respectively.
- the lubricant composition of the present invention comprises the above-mentioned essential components, but if necessary, various kinds of additives can be added to the lubricant composition.
- the additives include an extreme pressure agent (an olefin sulfide, sulfurized fats and oils or the like), an abrasion-resistant agent (a phosphate, a phosphite or the like), an antioxidant (phenol or the like), a defoaming agent (an organic silicone compound or the like), an ashless dispersant (succinimide or the like), a viscosity index improver (polymethacrylate or the like), a pour point depressant (polymethacrylate or the like) and a corrosion inhibitor (a sulfur compound, a nitrogen compound or the like).
- an extreme pressure agent an olefin sulfide, sulfurized fats and oils or the like
- an abrasion-resistant agent a phosphate, a phosphite or the like
- the lubricant composition When a lubricant composition of the present invention is applied to LSD of a car, the lubricant composition is excellent in frictional properties as the fresh oil and oxidation stability, chattering can be inhibited, change of frictional properties with the lapse of time is small, and abrasion on a metallic friction plate can also be minimized.
- the lubricant composition of the present invention can be considered to be very valuable as the lubricant for LSD of cars.
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Organic Chemistry (AREA)
- Lubricants (AREA)
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP122218/93 | 1993-05-25 | ||
JP5122218A JP2859083B2 (ja) | 1993-05-25 | 1993-05-25 | 自動車リミテッドスリップデファレンシャル用潤滑油組成物 |
Publications (1)
Publication Number | Publication Date |
---|---|
EP0628623A1 true EP0628623A1 (fr) | 1994-12-14 |
Family
ID=14830477
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP94107732A Withdrawn EP0628623A1 (fr) | 1993-05-25 | 1994-05-19 | Composition lubrifiante pour différentiel à glissement limité d'une voiture |
Country Status (3)
Country | Link |
---|---|
US (1) | US5547596A (fr) |
EP (1) | EP0628623A1 (fr) |
JP (1) | JP2859083B2 (fr) |
Cited By (8)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP1057882A1 (fr) * | 1999-06-04 | 2000-12-06 | Idemitsu Kosan Co., Ltd. | Composition d'huile lubrifiante pour matériau de friction humide à base de cellulose |
EP1131390A1 (fr) * | 1998-10-19 | 2001-09-12 | The Lubrizol Corporation | Compositions lubrifiantes presentant une stabilite thermique et une efficacite de glissement ameliorees |
WO2006107435A1 (fr) * | 2005-03-31 | 2006-10-12 | Exxonmobil Chemical Patents Inc. | Fluides pour une protection amelioree d'engrenages |
WO2006107441A1 (fr) * | 2005-03-31 | 2006-10-12 | Exxonmobil Chemical Patents Inc. | Systeme d'additifs pour lubrifiant |
WO2009073390A1 (fr) * | 2007-12-06 | 2009-06-11 | The Lubrizol Corporation | Composition lubrifiante contenant un phospholipide bore |
WO2010077630A1 (fr) * | 2008-12-09 | 2010-07-08 | The Lubrizol Corporation | Composition lubrifiante contenant un composé issu d'un acide hydroxycarboxylique |
WO2011034829A1 (fr) * | 2009-09-16 | 2011-03-24 | The Lubrizol Corporation | Composition lubrifiante contenant un ester |
WO2013151911A1 (fr) * | 2012-04-04 | 2013-10-10 | The Lubrizol Corporation | Lubrifiants pour paliers pour matériel de pulvérisation |
Families Citing this family (12)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US20040192564A1 (en) * | 2003-03-25 | 2004-09-30 | Vasudevan Balasubramaniam | Bimodal gear lubricant formulation |
US7648948B2 (en) * | 2005-04-08 | 2010-01-19 | Exxonmobil Chemical Patents Inc. | Additive system for lubricants |
JP2008537008A (ja) * | 2005-04-22 | 2008-09-11 | エクソンモービル・ケミカル・パテンツ・インク | 潤滑組成物のための改良された腐食抑制方法 |
US7803332B2 (en) * | 2005-05-31 | 2010-09-28 | Exxonmobil Chemical Patents Inc. | Reactor temperature control |
US7833339B2 (en) | 2006-04-18 | 2010-11-16 | Franklin Industrial Minerals | Mineral filler composition |
US7651559B2 (en) | 2005-11-04 | 2010-01-26 | Franklin Industrial Minerals | Mineral composition |
US20070167334A1 (en) * | 2006-01-17 | 2007-07-19 | Sullivan William T | Lubricating fluids |
US20070164259A1 (en) * | 2006-01-17 | 2007-07-19 | Sullivan William T | Additive system for lubricating fluids |
US20110111992A1 (en) * | 2006-01-17 | 2011-05-12 | The Lubrizol Corporation | Lubricating fluids |
JP5459874B2 (ja) * | 2008-10-23 | 2014-04-02 | ザ ルブリゾル コーポレイション | 金属カルボン酸塩を含む潤滑組成物 |
KR101674702B1 (ko) | 2009-05-13 | 2016-11-09 | 더루우브리졸코오포레이션 | 말산 유도체를 함유하는 윤활 조성물 |
EP2576740B1 (fr) | 2010-05-24 | 2015-11-11 | The Lubrizol Corporation | Composition lubrifiante |
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US3901932A (en) * | 1973-04-11 | 1975-08-26 | Sakai Chemical Industry Co | Novel sulfur-containing organic phosphorus compounds and their production and use |
JPH0232195A (ja) * | 1988-07-20 | 1990-02-01 | Toyota Motor Corp | 終減速機用潤滑油組成物 |
EP0430624A1 (fr) * | 1989-11-27 | 1991-06-05 | Ethyl Petroleum Additives, Inc. | Huiles pour engrenage et additifs pour celles-ci |
EP0448207A1 (fr) * | 1990-02-16 | 1991-09-25 | Ethyl Petroleum Additives, Inc. | Compositions lubrifiantes |
EP0459656A1 (fr) * | 1990-05-17 | 1991-12-04 | Ethyl Petroleum Additives, Inc. | Compositions lubrifiantes |
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US4118328A (en) * | 1977-12-08 | 1978-10-03 | Chevron Research Company | Amine phosphate salts |
US4472288A (en) * | 1980-08-29 | 1984-09-18 | Chevron Research Company | Lubricant composition containing alkali metal borate and an oil-soluble amine salt of a phosphorus compound |
US4599191A (en) * | 1984-05-01 | 1986-07-08 | Mobil Oil Corporation | Friction reducing additives and compositions thereof |
US5089156A (en) * | 1990-10-10 | 1992-02-18 | Ethyl Petroleum Additives, Inc. | Ashless or low-ash synthetic base compositions and additives therefor |
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- 1993-05-25 JP JP5122218A patent/JP2859083B2/ja not_active Expired - Fee Related
-
1994
- 1994-05-19 EP EP94107732A patent/EP0628623A1/fr not_active Withdrawn
- 1994-05-20 US US08/246,745 patent/US5547596A/en not_active Expired - Fee Related
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US3901932A (en) * | 1973-04-11 | 1975-08-26 | Sakai Chemical Industry Co | Novel sulfur-containing organic phosphorus compounds and their production and use |
JPH0232195A (ja) * | 1988-07-20 | 1990-02-01 | Toyota Motor Corp | 終減速機用潤滑油組成物 |
EP0430624A1 (fr) * | 1989-11-27 | 1991-06-05 | Ethyl Petroleum Additives, Inc. | Huiles pour engrenage et additifs pour celles-ci |
EP0448207A1 (fr) * | 1990-02-16 | 1991-09-25 | Ethyl Petroleum Additives, Inc. | Compositions lubrifiantes |
EP0459656A1 (fr) * | 1990-05-17 | 1991-12-04 | Ethyl Petroleum Additives, Inc. | Compositions lubrifiantes |
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Cited By (13)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP1131390A1 (fr) * | 1998-10-19 | 2001-09-12 | The Lubrizol Corporation | Compositions lubrifiantes presentant une stabilite thermique et une efficacite de glissement ameliorees |
EP1131390A4 (fr) * | 1998-10-19 | 2005-08-03 | Lubrizol Corp | Compositions lubrifiantes presentant une stabilite thermique et une efficacite de glissement ameliorees |
EP1057882A1 (fr) * | 1999-06-04 | 2000-12-06 | Idemitsu Kosan Co., Ltd. | Composition d'huile lubrifiante pour matériau de friction humide à base de cellulose |
US8034754B2 (en) | 2005-03-31 | 2011-10-11 | The Lubrizol Corporation | Fluids for enhanced gear protection |
WO2006107441A1 (fr) * | 2005-03-31 | 2006-10-12 | Exxonmobil Chemical Patents Inc. | Systeme d'additifs pour lubrifiant |
US7531486B2 (en) | 2005-03-31 | 2009-05-12 | Exxonmobil Chemical Patents Inc. | Additive system for lubricant |
WO2006107435A1 (fr) * | 2005-03-31 | 2006-10-12 | Exxonmobil Chemical Patents Inc. | Fluides pour une protection amelioree d'engrenages |
WO2009073390A1 (fr) * | 2007-12-06 | 2009-06-11 | The Lubrizol Corporation | Composition lubrifiante contenant un phospholipide bore |
US8445417B2 (en) | 2007-12-06 | 2013-05-21 | The Lubrizol Corporation | Lubricating composition containing borated phospholipid |
WO2010077630A1 (fr) * | 2008-12-09 | 2010-07-08 | The Lubrizol Corporation | Composition lubrifiante contenant un composé issu d'un acide hydroxycarboxylique |
WO2011034829A1 (fr) * | 2009-09-16 | 2011-03-24 | The Lubrizol Corporation | Composition lubrifiante contenant un ester |
WO2013151911A1 (fr) * | 2012-04-04 | 2013-10-10 | The Lubrizol Corporation | Lubrifiants pour paliers pour matériel de pulvérisation |
AU2013243735B2 (en) * | 2012-04-04 | 2017-07-13 | The Lubrizol Corporation | Bearing lubricants for pulverizing equipment |
Also Published As
Publication number | Publication date |
---|---|
JP2859083B2 (ja) | 1999-02-17 |
JPH06330069A (ja) | 1994-11-29 |
US5547596A (en) | 1996-08-20 |
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