EP0609284A1 - Filtre de cigarette. - Google Patents
Filtre de cigarette.Info
- Publication number
- EP0609284A1 EP0609284A1 EP92921347A EP92921347A EP0609284A1 EP 0609284 A1 EP0609284 A1 EP 0609284A1 EP 92921347 A EP92921347 A EP 92921347A EP 92921347 A EP92921347 A EP 92921347A EP 0609284 A1 EP0609284 A1 EP 0609284A1
- Authority
- EP
- European Patent Office
- Prior art keywords
- cellulose
- acetate
- diameter
- cable
- fibers
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 235000019504 cigarettes Nutrition 0.000 title claims description 9
- 229920002472 Starch Polymers 0.000 claims abstract description 5
- 229920002301 cellulose acetate Polymers 0.000 claims abstract description 5
- 238000000034 method Methods 0.000 claims abstract description 5
- 239000008107 starch Substances 0.000 claims abstract description 5
- 235000019698 starch Nutrition 0.000 claims abstract description 5
- 239000000654 additive Substances 0.000 claims abstract description 4
- 229920001353 Dextrin Polymers 0.000 claims abstract description 3
- 239000004375 Dextrin Substances 0.000 claims abstract description 3
- 229920000881 Modified starch Polymers 0.000 claims abstract description 3
- 235000019425 dextrin Nutrition 0.000 claims abstract description 3
- 235000019426 modified starch Nutrition 0.000 claims abstract description 3
- 150000001875 compounds Chemical class 0.000 claims abstract 4
- 231100000252 nontoxic Toxicity 0.000 claims abstract 3
- 230000003000 nontoxic effect Effects 0.000 claims abstract 3
- 239000002904 solvent Substances 0.000 claims abstract 3
- 150000002894 organic compounds Chemical class 0.000 claims abstract 2
- 229920002678 cellulose Polymers 0.000 claims description 9
- 239000001913 cellulose Substances 0.000 claims description 9
- 239000000835 fiber Substances 0.000 claims description 8
- QTBSBXVTEAMEQO-UHFFFAOYSA-M Acetate Chemical compound CC([O-])=O QTBSBXVTEAMEQO-UHFFFAOYSA-M 0.000 claims description 7
- 238000009987 spinning Methods 0.000 claims description 3
- 238000004519 manufacturing process Methods 0.000 abstract description 2
- ZAMLGGRVTAXBHI-UHFFFAOYSA-N 3-(4-bromophenyl)-3-[(2-methylpropan-2-yl)oxycarbonylamino]propanoic acid Chemical compound CC(C)(C)OC(=O)NC(CC(O)=O)C1=CC=C(Br)C=C1 ZAMLGGRVTAXBHI-UHFFFAOYSA-N 0.000 abstract 1
- 229940081735 acetylcellulose Drugs 0.000 abstract 1
- 230000015556 catabolic process Effects 0.000 description 5
- 238000006731 degradation reaction Methods 0.000 description 3
- 244000005700 microbiome Species 0.000 description 3
- 239000010865 sewage Substances 0.000 description 3
- TWRXJAOTZQYOKJ-UHFFFAOYSA-L Magnesium chloride Chemical compound [Mg+2].[Cl-].[Cl-] TWRXJAOTZQYOKJ-UHFFFAOYSA-L 0.000 description 2
- CSNNHWWHGAXBCP-UHFFFAOYSA-L Magnesium sulfate Chemical compound [Mg+2].[O-][S+2]([O-])([O-])[O-] CSNNHWWHGAXBCP-UHFFFAOYSA-L 0.000 description 2
- 241000208125 Nicotiana Species 0.000 description 2
- 235000002637 Nicotiana tabacum Nutrition 0.000 description 2
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 description 2
- 238000009264 composting Methods 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 230000000813 microbial effect Effects 0.000 description 2
- 239000004848 polyfunctional curative Substances 0.000 description 2
- 239000000779 smoke Substances 0.000 description 2
- 235000002639 sodium chloride Nutrition 0.000 description 2
- 239000002195 soluble material Substances 0.000 description 2
- URAYPUMNDPQOKB-UHFFFAOYSA-N triacetin Chemical compound CC(=O)OCC(OC(C)=O)COC(C)=O URAYPUMNDPQOKB-UHFFFAOYSA-N 0.000 description 2
- ITQJMPLOCOOZQS-UHFFFAOYSA-N 1,4-dihydrotriazete Chemical compound C1NN=N1 ITQJMPLOCOOZQS-UHFFFAOYSA-N 0.000 description 1
- OVOUKWFJRHALDD-UHFFFAOYSA-N 2-[2-(2-acetyloxyethoxy)ethoxy]ethyl acetate Chemical compound CC(=O)OCCOCCOCCOC(C)=O OVOUKWFJRHALDD-UHFFFAOYSA-N 0.000 description 1
- 229920000742 Cotton Polymers 0.000 description 1
- PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 description 1
- 150000001242 acetic acid derivatives Chemical class 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 150000007513 acids Chemical class 0.000 description 1
- 239000003513 alkali Substances 0.000 description 1
- 239000012736 aqueous medium Substances 0.000 description 1
- 235000013339 cereals Nutrition 0.000 description 1
- 238000003912 environmental pollution Methods 0.000 description 1
- 235000013312 flour Nutrition 0.000 description 1
- 239000012634 fragment Substances 0.000 description 1
- 235000013773 glyceryl triacetate Nutrition 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- 229910052500 inorganic mineral Inorganic materials 0.000 description 1
- 229910001629 magnesium chloride Inorganic materials 0.000 description 1
- 235000011147 magnesium chloride Nutrition 0.000 description 1
- 229910052943 magnesium sulfate Inorganic materials 0.000 description 1
- 235000019341 magnesium sulphate Nutrition 0.000 description 1
- 230000002906 microbiologic effect Effects 0.000 description 1
- 239000011707 mineral Substances 0.000 description 1
- 235000010755 mineral Nutrition 0.000 description 1
- 150000002989 phenols Chemical class 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 239000011780 sodium chloride Substances 0.000 description 1
- 229910052938 sodium sulfate Inorganic materials 0.000 description 1
- 235000011152 sodium sulphate Nutrition 0.000 description 1
- 239000002689 soil Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 229960002622 triacetin Drugs 0.000 description 1
- 150000004043 trisaccharides Chemical class 0.000 description 1
Classifications
-
- A—HUMAN NECESSITIES
- A24—TOBACCO; CIGARS; CIGARETTES; SIMULATED SMOKING DEVICES; SMOKERS' REQUISITES
- A24D—CIGARS; CIGARETTES; TOBACCO SMOKE FILTERS; MOUTHPIECES FOR CIGARS OR CIGARETTES; MANUFACTURE OF TOBACCO SMOKE FILTERS OR MOUTHPIECES
- A24D3/00—Tobacco smoke filters, e.g. filter-tips, filtering inserts; Filters specially adapted for simulated smoking devices; Mouthpieces for cigars or cigarettes
- A24D3/06—Use of materials for tobacco smoke filters
- A24D3/14—Use of materials for tobacco smoke filters of organic materials as additive
-
- A—HUMAN NECESSITIES
- A24—TOBACCO; CIGARS; CIGARETTES; SIMULATED SMOKING DEVICES; SMOKERS' REQUISITES
- A24D—CIGARS; CIGARETTES; TOBACCO SMOKE FILTERS; MOUTHPIECES FOR CIGARS OR CIGARETTES; MANUFACTURE OF TOBACCO SMOKE FILTERS OR MOUTHPIECES
- A24D3/00—Tobacco smoke filters, e.g. filter-tips, filtering inserts; Filters specially adapted for simulated smoking devices; Mouthpieces for cigars or cigarettes
- A24D3/06—Use of materials for tobacco smoke filters
- A24D3/08—Use of materials for tobacco smoke filters of organic materials as carrier or major constituent
- A24D3/10—Use of materials for tobacco smoke filters of organic materials as carrier or major constituent of cellulose or cellulose derivatives
-
- A—HUMAN NECESSITIES
- A24—TOBACCO; CIGARS; CIGARETTES; SIMULATED SMOKING DEVICES; SMOKERS' REQUISITES
- A24D—CIGARS; CIGARETTES; TOBACCO SMOKE FILTERS; MOUTHPIECES FOR CIGARS OR CIGARETTES; MANUFACTURE OF TOBACCO SMOKE FILTERS OR MOUTHPIECES
- A24D3/00—Tobacco smoke filters, e.g. filter-tips, filtering inserts; Filters specially adapted for simulated smoking devices; Mouthpieces for cigars or cigarettes
- A24D3/06—Use of materials for tobacco smoke filters
- A24D3/067—Use of materials for tobacco smoke filters characterised by functional properties
- A24D3/068—Biodegradable or disintegrable
-
- A—HUMAN NECESSITIES
- A24—TOBACCO; CIGARS; CIGARETTES; SIMULATED SMOKING DEVICES; SMOKERS' REQUISITES
- A24D—CIGARS; CIGARETTES; TOBACCO SMOKE FILTERS; MOUTHPIECES FOR CIGARS OR CIGARETTES; MANUFACTURE OF TOBACCO SMOKE FILTERS OR MOUTHPIECES
- A24D3/00—Tobacco smoke filters, e.g. filter-tips, filtering inserts; Filters specially adapted for simulated smoking devices; Mouthpieces for cigars or cigarettes
- A24D3/06—Use of materials for tobacco smoke filters
- A24D3/16—Use of materials for tobacco smoke filters of inorganic materials
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F1/00—General methods for the manufacture of artificial filaments or the like
- D01F1/02—Addition of substances to the spinning solution or to the melt
- D01F1/10—Other agents for modifying properties
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F2/00—Monocomponent artificial filaments or the like of cellulose or cellulose derivatives; Manufacture thereof
- D01F2/24—Monocomponent artificial filaments or the like of cellulose or cellulose derivatives; Manufacture thereof from cellulose derivatives
- D01F2/28—Monocomponent artificial filaments or the like of cellulose or cellulose derivatives; Manufacture thereof from cellulose derivatives from organic cellulose esters or ethers, e.g. cellulose acetate
Definitions
- Modern cigarette filters are almost exclusively made from cellulose (2.5) acetate. Compared to the paper and cotton filters used previously, this material offers the advantage that the cable used for filter production can be manufactured in a variety of specifications, in particular with regard to the fiber cross section, and is easy to process into filters, which in turn are used for snowing cigarette makers generating machines can be used.
- the filters made from cellulose acetate also look good when smoked.
- the "hardener" triazetin (glycerol triacetate) or triethylene glycol diacetate added to the cable (not already the fibers) when producing the filter rods give the filter a high selectivity towards some health-threatening ingredients of tobacco smoke, such as phenols and N-nitrosamines.
- Di- and trisaccharides, alkali and alkaline earth salts of organic and some mineral acids e.g. magnesium chloride, magnesium sulfate, sodium chloride, sodium sulfate, etc.
- organic and some mineral acids e.g. magnesium chloride, magnesium sulfate, sodium chloride, sodium sulfate, etc.
- starch chemical or biologically partially degraded starch, starch derivatives, starch-containing products such as cereal flour, dextrins are suspended in the spinning solution, these additives are broken down by soil microorganisms in sewage treatment plants, etc.
- soil microorganisms in sewage treatment plants, etc.
- the structure of the individual fibers of the smoked cigarette filters is destroyed and the further microbiological degradation of the remaining cellulose (2,5) acetate is facilitated and accelerated.
Landscapes
- Engineering & Computer Science (AREA)
- Chemical & Material Sciences (AREA)
- Materials Engineering (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Textile Engineering (AREA)
- General Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Manufacturing & Machinery (AREA)
- Biodiversity & Conservation Biology (AREA)
- Inorganic Chemistry (AREA)
- Cigarettes, Filters, And Manufacturing Of Filters (AREA)
- Artificial Filaments (AREA)
- Polysaccharides And Polysaccharide Derivatives (AREA)
- Spinning Methods And Devices For Manufacturing Artificial Fibers (AREA)
- Filtering Materials (AREA)
Abstract
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
AT2101/91 | 1991-10-22 | ||
AT0210191A AT396862B (de) | 1991-10-22 | 1991-10-22 | Verfahren zur herstellung eines zelluloseazetat-kabels und zigarettenfilter daraus |
PCT/AT1992/000126 WO1993007771A1 (fr) | 1991-10-22 | 1992-10-16 | Filtre de cigarette |
Publications (2)
Publication Number | Publication Date |
---|---|
EP0609284A1 true EP0609284A1 (fr) | 1994-08-10 |
EP0609284B1 EP0609284B1 (fr) | 1996-03-27 |
Family
ID=3527777
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP92921347A Expired - Lifetime EP0609284B1 (fr) | 1991-10-22 | 1992-10-16 | Filtre de cigarette |
Country Status (15)
Country | Link |
---|---|
EP (1) | EP0609284B1 (fr) |
JP (1) | JPH07500385A (fr) |
KR (1) | KR100264527B1 (fr) |
CN (1) | CN1053563C (fr) |
AT (2) | AT396862B (fr) |
CA (1) | CA2121136C (fr) |
DE (1) | DE59205875D1 (fr) |
DK (1) | DK0609284T3 (fr) |
ES (1) | ES2085650T3 (fr) |
GE (1) | GEP19991509B (fr) |
GR (1) | GR3019451T3 (fr) |
RU (1) | RU2083146C1 (fr) |
UA (1) | UA27822C2 (fr) |
WO (1) | WO1993007771A1 (fr) |
ZA (1) | ZA928128B (fr) |
Families Citing this family (16)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP0622407A1 (fr) * | 1993-04-28 | 1994-11-02 | Hoechst Celanese Corporation | Mélange de polymères composé d'acétate de cellulose et d'acétate d'amidon, utilisé pour former des fibres, des films et des matériaux plastiques; procédé pour préparer ce mélange |
DE4322967C1 (de) * | 1993-07-09 | 1994-10-13 | Rhodia Ag Rhone Poulenc | Filtertow aus Celluloseacetat, dessen Herstellung und Verwendung als Tabakrauchfilterelement |
DE4322965C1 (de) * | 1993-07-09 | 1994-10-06 | Rhodia Ag Rhone Poulenc | Filtertow und Verfahren zu dessen Herstellung sowie dessen Verwendung als Tabakrauchfilterelement |
EP0783841A4 (fr) * | 1995-08-04 | 1998-08-26 | Mitsubishi Rayon Co | Materiau filtrant et filtre de cigarette realise avec ce materiau |
DE19536505A1 (de) * | 1995-09-29 | 1997-04-10 | Biotec Biolog Naturverpack | Biologisch abbaubares Filtermaterial und Verfahren zu seiner Herstellung |
US5922110A (en) * | 1998-01-21 | 1999-07-13 | Dcv, Inc. | Water-soluble, biodegradable filter, and process of using same |
DK1167589T3 (da) | 1999-03-11 | 2007-10-29 | Japan Tobacco Inc | Bionedbrydelige artikler af celluloseacetat samt filter for tobaksrög |
EP1756023B1 (fr) | 2004-05-24 | 2012-04-11 | British American Tobacco (Investments) Limited | Polymeres a empreintes moleculaires selectifs des nitrosamines et procedes d'utilisation desdits polymeres |
CN1301076C (zh) * | 2004-05-26 | 2007-02-21 | 长沙卷烟厂 | 高分子聚合物卷烟滤嘴添加剂及应用 |
US7585441B2 (en) * | 2004-06-25 | 2009-09-08 | Celanese Acetate, Llc | Process of making cellulose acetate tow |
DE102008051579A1 (de) | 2008-10-14 | 2010-04-15 | Rhodia Acetow Gmbh | Biologisch abbaubarer Kunststoff und Verwendung desselben |
JP5192982B2 (ja) * | 2008-10-22 | 2013-05-08 | ピジョン株式会社 | 不織布および衛生用品 |
JP5192981B2 (ja) * | 2008-10-22 | 2013-05-08 | ピジョン株式会社 | 不織布および衛生用品 |
US8434498B2 (en) | 2009-08-11 | 2013-05-07 | R. J. Reynolds Tobacco Company | Degradable filter element |
EP3072405A1 (fr) * | 2015-03-27 | 2016-09-28 | Cordenka GmbH & Co. KG | Filtre de cigarette |
RU2693531C1 (ru) * | 2019-03-06 | 2019-07-03 | Сергей Николаевич Ким | Способ изготовления фильтрующего штранга из ацетат-целлюлозного волокна |
Family Cites Families (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
GB8712617D0 (en) * | 1987-05-28 | 1987-07-01 | British American Tobacco Co | Tobacco smoke filters |
US4964426A (en) * | 1988-09-28 | 1990-10-23 | Eastman Kodak Company | Tobacco smoke filters and process for production thereof |
-
1991
- 1991-10-22 AT AT0210191A patent/AT396862B/de not_active IP Right Cessation
-
1992
- 1992-10-16 JP JP5507272A patent/JPH07500385A/ja not_active Expired - Lifetime
- 1992-10-16 UA UA94005431A patent/UA27822C2/uk unknown
- 1992-10-16 RU RU9294021652A patent/RU2083146C1/ru active
- 1992-10-16 AT AT92921347T patent/ATE135892T1/de active
- 1992-10-16 DE DE59205875T patent/DE59205875D1/de not_active Expired - Lifetime
- 1992-10-16 EP EP92921347A patent/EP0609284B1/fr not_active Expired - Lifetime
- 1992-10-16 WO PCT/AT1992/000126 patent/WO1993007771A1/fr active IP Right Grant
- 1992-10-16 CA CA002121136A patent/CA2121136C/fr not_active Expired - Lifetime
- 1992-10-16 GE GEAP19922490A patent/GEP19991509B/en unknown
- 1992-10-16 ES ES92921347T patent/ES2085650T3/es not_active Expired - Lifetime
- 1992-10-16 DK DK92921347.8T patent/DK0609284T3/da active
- 1992-10-16 KR KR1019940701133A patent/KR100264527B1/ko not_active IP Right Cessation
- 1992-10-21 CN CN92112850A patent/CN1053563C/zh not_active Expired - Lifetime
- 1992-10-21 ZA ZA928128A patent/ZA928128B/xx unknown
-
1996
- 1996-03-28 GR GR960400815T patent/GR3019451T3/el unknown
Non-Patent Citations (1)
Title |
---|
See references of WO9307771A1 * |
Also Published As
Publication number | Publication date |
---|---|
CN1053563C (zh) | 2000-06-21 |
EP0609284B1 (fr) | 1996-03-27 |
GR3019451T3 (en) | 1996-06-30 |
ES2085650T3 (es) | 1996-06-01 |
CN1072580A (zh) | 1993-06-02 |
KR100264527B1 (ko) | 2000-09-01 |
DK0609284T3 (da) | 1996-05-20 |
CA2121136A1 (fr) | 1993-04-29 |
KR940702696A (ko) | 1994-09-17 |
ATA210191A (de) | 1993-05-15 |
WO1993007771A1 (fr) | 1993-04-29 |
JPH07500385A (ja) | 1995-01-12 |
RU2083146C1 (ru) | 1997-07-10 |
ATE135892T1 (de) | 1996-04-15 |
DE59205875D1 (de) | 1996-05-02 |
GEP19991509B (en) | 1999-03-05 |
UA27822C2 (uk) | 2000-10-16 |
AT396862B (de) | 1993-12-27 |
CA2121136C (fr) | 2001-03-06 |
ZA928128B (en) | 1993-05-04 |
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