EP0607402B1 - Form zum herstellen von flüssigkeitshaltigen pressteilen - Google Patents
Form zum herstellen von flüssigkeitshaltigen pressteilen Download PDFInfo
- Publication number
- EP0607402B1 EP0607402B1 EP93917716A EP93917716A EP0607402B1 EP 0607402 B1 EP0607402 B1 EP 0607402B1 EP 93917716 A EP93917716 A EP 93917716A EP 93917716 A EP93917716 A EP 93917716A EP 0607402 B1 EP0607402 B1 EP 0607402B1
- Authority
- EP
- European Patent Office
- Prior art keywords
- layer
- sintered
- ceramic material
- pore
- foamed ceramic
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 239000007788 liquid Substances 0.000 title claims abstract description 18
- 238000004519 manufacturing process Methods 0.000 title abstract description 10
- 238000000465 moulding Methods 0.000 title abstract description 3
- 229910010293 ceramic material Inorganic materials 0.000 claims abstract description 51
- 239000000463 material Substances 0.000 claims abstract description 26
- 239000011148 porous material Substances 0.000 claims abstract description 24
- 239000004927 clay Substances 0.000 claims abstract description 16
- 239000011381 foam concrete Substances 0.000 claims abstract description 16
- 229910052751 metal Inorganic materials 0.000 claims description 7
- 239000002184 metal Substances 0.000 claims description 7
- MCMNRKCIXSYSNV-UHFFFAOYSA-N ZrO2 Inorganic materials O=[Zr]=O MCMNRKCIXSYSNV-UHFFFAOYSA-N 0.000 claims description 6
- 229910052593 corundum Inorganic materials 0.000 claims description 6
- 239000010431 corundum Substances 0.000 claims description 6
- RVTZCBVAJQQJTK-UHFFFAOYSA-N oxygen(2-);zirconium(4+) Chemical compound [O-2].[O-2].[Zr+4] RVTZCBVAJQQJTK-UHFFFAOYSA-N 0.000 claims description 6
- HBMJWWWQQXIZIP-UHFFFAOYSA-N silicon carbide Chemical compound [Si+]#[C-] HBMJWWWQQXIZIP-UHFFFAOYSA-N 0.000 claims description 6
- 229910010271 silicon carbide Inorganic materials 0.000 claims description 6
- 229910000831 Steel Inorganic materials 0.000 claims description 5
- 229910001220 stainless steel Inorganic materials 0.000 claims description 5
- 239000010935 stainless steel Substances 0.000 claims description 5
- 239000010959 steel Substances 0.000 claims description 5
- 229910052581 Si3N4 Inorganic materials 0.000 claims description 4
- KZHJGOXRZJKJNY-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Si]=O.O=[Al]O[Al]=O.O=[Al]O[Al]=O.O=[Al]O[Al]=O KZHJGOXRZJKJNY-UHFFFAOYSA-N 0.000 claims description 4
- 229910052863 mullite Inorganic materials 0.000 claims description 4
- HQVNEWCFYHHQES-UHFFFAOYSA-N silicon nitride Chemical compound N12[Si]34N5[Si]62N3[Si]51N64 HQVNEWCFYHHQES-UHFFFAOYSA-N 0.000 claims description 4
- 239000004744 fabric Substances 0.000 claims description 3
- 238000000034 method Methods 0.000 claims description 3
- 239000000654 additive Substances 0.000 claims description 2
- 238000009826 distribution Methods 0.000 claims description 2
- 238000010894 electron beam technology Methods 0.000 claims description 2
- 238000005058 metal casting Methods 0.000 claims description 2
- 239000002923 metal particle Substances 0.000 claims description 2
- 230000003647 oxidation Effects 0.000 claims description 2
- 238000007254 oxidation reaction Methods 0.000 claims description 2
- 238000007569 slipcasting Methods 0.000 claims description 2
- 239000006261 foam material Substances 0.000 claims 1
- 230000002787 reinforcement Effects 0.000 claims 1
- 229910052602 gypsum Inorganic materials 0.000 abstract description 12
- 239000010440 gypsum Substances 0.000 abstract description 12
- 239000010410 layer Substances 0.000 description 52
- 239000011505 plaster Substances 0.000 description 11
- 239000011449 brick Substances 0.000 description 8
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 8
- 238000005299 abrasion Methods 0.000 description 5
- 238000011161 development Methods 0.000 description 5
- 230000018109 developmental process Effects 0.000 description 5
- 238000003825 pressing Methods 0.000 description 4
- 239000000919 ceramic Substances 0.000 description 3
- 238000005507 spraying Methods 0.000 description 3
- 239000011230 binding agent Substances 0.000 description 2
- 238000001704 evaporation Methods 0.000 description 2
- 238000012986 modification Methods 0.000 description 2
- 230000004048 modification Effects 0.000 description 2
- 239000011347 resin Substances 0.000 description 2
- 229920005989 resin Polymers 0.000 description 2
- 238000007789 sealing Methods 0.000 description 2
- 239000000853 adhesive Substances 0.000 description 1
- 230000001070 adhesive effect Effects 0.000 description 1
- 239000012790 adhesive layer Substances 0.000 description 1
- 238000011001 backwashing Methods 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 238000005266 casting Methods 0.000 description 1
- 230000001186 cumulative effect Effects 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 239000000945 filler Substances 0.000 description 1
- 239000011268 mixed slurry Substances 0.000 description 1
- 230000001590 oxidative effect Effects 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
Images
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B28—WORKING CEMENT, CLAY, OR STONE
- B28B—SHAPING CLAY OR OTHER CERAMIC COMPOSITIONS; SHAPING SLAG; SHAPING MIXTURES CONTAINING CEMENTITIOUS MATERIAL, e.g. PLASTER
- B28B7/00—Moulds; Cores; Mandrels
- B28B7/36—Linings or coatings, e.g. removable, absorbent linings, permanent anti-stick coatings; Linings becoming a non-permanent layer of the moulded article
- B28B7/368—Absorbent linings
Definitions
- the invention relates to a mold for the production of liquid-containing pressed parts, such as roof tiles made of clay, a clay-like or similar material.
- Roof tiles in the form of pressed roof tiles are usually made of clay, clay or similar material with a very specific water content; the clay or the clay-containing material is applied to a negative mold made of gypsum, which is accommodated in a steel frame and serves as the lower mold, and is finally pressed into a raw brick of the desired shape in a press by means of a negative mold made of gypsum which also serves as the upper mold .
- a negative mold made of gypsum which also serves as the upper mold.
- the top of the plaster mold serving as the lower mold is modeled on the surface of the underside of the bricks to be produced, while the downward-facing upper surface of the negative mold made of plaster serving as the upper mold corresponds to the visible outer surface of a brick.
- porous mold for the pressure casting of ceramic shaped pieces with a porous inner layer and a coarse-porous outer layer covering the back of the porous inner layer.
- the porous inner layer has an average pore diameter of at most 20 ⁇ m and a thickness of 5 to 40mm.
- an adhesive is applied, on which a porous Is applied outer layer, which consists of liquid resin and a filler with a grain size of 0.1 to 5mm and a thickness of 5 to 30mm and a pore diameter of at least 100 microns.
- This outer layer is sealed by a resin adhesive layer.
- EP-A-0 121 929 discloses a permeable mold for forming three-dimensional moldings, the inner layer of which is made from a mixed slurry which contains metallic grains, ceramic grains and a liquid binder with an evaporating or consumable component. A support layer of unsintered metal and ceramic powder is applied to this layer sintered in an oxidizing atmosphere. Due to the evaporating or consumable component of the liquid binder in the inner layer, openings with a porosity of 5 to 60% are created in the mold.
- the two known forms described above have in particular the disadvantage that they do not withstand the high contact pressure which is necessary when producing roof tiles in order to squeeze the liquid contained in the material to be pressed out of the clay, the clay-containing or similar material. Furthermore, the forms described above have the disadvantage that they have only a low resistance to abrasion.
- the negative molds made of gypsum used as the upper and lower mold undergo considerable abrasion, so that after an approximately known, not too high number of pressings, the wear, in particular on the negative mold made of gypsum as the upper mold, is so great due to the abrasion that the specified tolerances, in particular with regard to the permissible minimum thickness of the finished brick, can no longer be met.
- the plaster mold serving as the upper mold must therefore after about 600 to 800, at best 1000 brick pressings can be exchanged for a new, provided upper mold.
- the press must be replaced with a new, unused gypsum mold after half an hour at the latest, this process on average 5 to max. Takes 10min. Replacing the plaster mold serving as the upper mold takes 1 to 1.5 hours with a ten-hour shift, so that the brick press stops 10 to 15% of the time per shift.
- the old used gypsum molds are generally employed by three workers in each shift.
- the object of the invention is therefore to provide a mold for the production of liquid-containing pressed parts, such as clay roof tiles, a clay-containing or similar material, which has a very high wear resistance and durability. According to the invention, this is achieved in a mold for the production of liquid-containing pressed parts, such as roof tiles made of clay, a clay-containing or similar material, by the features in the characterizing part of claim 1 or 15. Advantageous further developments are the subject of to claim 1 or 15 directly or indirectly subordinate claims.
- a layer which comes into contact with the material to be pressed consists of fine-pored, sintered or foamed ceramic material, while the layer below is coarse-pored, sintered or foamed ceramic material or foamed concrete.
- the fine-pored, sintered or foamed ceramic material has a porosity of the order of 10 ⁇ (10. 10 -10 m) to 30 ⁇ m and the proportion of porosity is between 5 and 60% depending on the material to be pressed.
- additives such as corundum, mullite, silicon carbide, silicon nitride, zirconium dioxide and the like are added to the fine-pored, sintered or foamed ceramic material.
- the fine-pored, sintered or foamed ceramic material consists of corundum, mullite, silicon carbide, silicon nitride or zirconium dioxide. Since zirconium dioxide is electrically conductive, if zirconium dioxide is added to the fine-pored, sintered or foamed ceramic material, demolding can be carried out more easily, or the adhesion between the mold and the pressed material is considerably reduced by the application of direct current.
- the same effect can also be achieved in that the surface of the layer of fine-pored, sintered or foamed material has a metallized or an oxidation layer.
- metal particles can be embedded in the fine-pored, sintered or foamed ceramic material to increase the conductivity.
- the layer of foamed ceramic material preferably has a thickness on the order of 0.1 to 2.0 mm.
- a Stainless steel mesh can be introduced.
- such a fabric made of stainless steel is accommodated in an area corresponding to the sealing labyrinth of the finished brick in the form of strip-shaped or web-like projections running in the longitudinal direction of a brick, which protrude outwards from the layer of fine-pored ceramic material; this largely prevents the web-like or strip-like projections in the layer of fine-pored, sintered or foamed material from breaking off.
- a mold according to the invention Because of the high abrasion resistance of fine-pored, sintered or foamed ceramic material, its wear during pressing is minimal compared to the abrasion with the plaster molds commonly used, so that a mold according to the invention has a service life of one depending on the material used for the production of roof tiles can have half to a year and more.
- the daily downtimes of the press in the order of 1 hour to 1.5 hours, which were previously required for spraying out used plaster molds and for inserting new, provided plaster molds, are thus eliminated. This means that the personnel involved in the manufacture, provision and spraying of new gypsum molds are no longer required, and the entire cost of gypsum is also eliminated.
- the layer consists of coarse-pored, sintered or foamed ceramic material, preferably of silicon carbide or corundum and, in order to enable backwashing with solvents or water, has a porosity that is 3 to 20 times greater than the porosity of the layer of fine-pored, sintered or foamed ceramic material.
- the layer of the layer arranged below is preferably made in the region facing away from the layer of fine-pored, sintered or foamed ceramic material coarse-pored, sintered or foamed ceramic material or foamed concrete a number of tubular channels for draining the liquid in the form of water are formed.
- cavities are formed in the layer of coarse-pore ceramic material or foamed concrete with supporting intermediate webs left between them.
- the cavities in the layer of large-pore, sintered or foamed ceramic material preferably have a cross-sectional area of the order of magnitude of 100 mm 2 , while the supporting intermediate webs have a thickness of 4 to 5 mm.
- the formation of the cavities in the layer of large-pore material saves a considerable amount of material, at the same time the distance and thus the time required for the liquid to be pressed out of the material to be processed in the form of water is reduced in order to keep the relatively thin layer thickness above the penetrate numerous cavities in the layer of coarse-pored, sintered or foamed ceramic material. Liquid entering the cavities can be sucked off through tubular channels running transversely thereto or, as was previously the case, by means of negative pressure.
- a porous connecting layer can be provided between the layer of fine-pored, sintered or foamed ceramic material and the layer of coarse-pored, sintered or foamed ceramic material to increase the adhesion.
- the mold according to the invention can also be used for slip casting or metal casting with and without vacuum application.
- the layer that comes into contact with the material to be pressed is a metal plate that has a large number of the finest Holes are penetrated, a layer of large-pore, sintered or foamed ceramic material or foamed concrete is again provided under this plate.
- the holes in the metal plate are flared to the underlying layer of coarse-pored, sintered or foamed ceramic material or foamed concrete, so that the water squeezed out of the clay reaches the underlying layer of foamed concrete or of coarse-pored, sintered or foamed ceramic material more quickly .
- the holes that widen conically to form a layer of coarse-pored, sintered or foamed ceramic material or foamed concrete run approximately perpendicular to the surface of the metal plate. If necessary, the holes are arranged in a different distribution density and / or with different diameters in different areas according to a further advantageous development of the invention.
- the conically widening holes are produced, for example, by means of laser or electron beam processes.
- FIG. 1 A first exemplary embodiment of a mold 1 according to the invention is shown schematically and to scale in FIG.
- An upper layer 10 in FIG. 1 consists of fine-pored, sintered or foamed ceramic material, while underneath another layer 11 of coarse-pored, sintered or foamed ceramic material or foamed concrete is provided.
- tubular channels 110 are provided, via which the liquid is drained from the clay, clayey or similar material in the form of water during the production of pressed roof tiles.
- Layer 10 preferably has a thickness of 1.5 mm. Furthermore, both layers 10 and 11 are preferably colored continuously, so that the appearance of the color of the underlying layer 11 alone is an indication that the layer 10 made of fine-pored, sintered or foamed ceramic material is used.
- protrusions 100 are shown on the upper side of the layer 10 made of fine-pored, sintered or foamed ceramic material in section outwards (upwards in FIG. 2), which in a direction perpendicular to the plane of the drawing are strip-shaped or web-like projections running parallel to one another, which in the negative form correspond to the sealing labyrinth provided in the lateral region of each roof tile.
- a steel mesh 20 made of preferably stainless steel is accommodated in the region of such projections 100 the sectional view of Figures 1 and 2 can only be seen as points.
- the steel mesh 20 is expediently also provided in the entire layer of fine-pored, sintered or foamed ceramic material.
- cavities 111 are formed in the layer 11 from coarse-pored, sintered or foamed ceramic material or from foamed concrete, between which supporting webs 112 have been left.
- the cavities 111 have a cross-sectional area on the order of 100 mm 2 , while the supporting intermediate webs 112 have a thickness on the order of preferably 4 to 5 mm.
- the provision of the cavities 111 in the layer 11 achieves considerable material savings and, at the same time, the liquid emerging from the layer 10 generally only has to penetrate a considerably thinner layer above the individual cavities in the form of water. The liquid which has escaped into the cavities can be drained from these, for example, through corresponding channels through the tubular channels 110 in FIG.
- FIG. 3 shows a modification of a mold 1 'according to the invention.
- a steel plate 30 is arranged over the layer 11 made of coarse-pored, sintered or foamed ceramic material or made of foamed concrete, which are penetrated by a large number of holes 300.
- the holes 300 shown in section are flared to the layer 11 provided there, made of foamed concrete or of coarse-pored, sintered or foamed ceramic material.
- the respective center axes are indicated by dash-dotted lines in the individual holes 300.
- the conical holes 300 have a diameter of 10 ⁇ m to 400 ⁇ m.
Landscapes
- Engineering & Computer Science (AREA)
- Manufacturing & Machinery (AREA)
- Chemical & Material Sciences (AREA)
- Ceramic Engineering (AREA)
- Mechanical Engineering (AREA)
- Press-Shaping Or Shaping Using Conveyers (AREA)
- Moulds, Cores, Or Mandrels (AREA)
- Physical Or Chemical Processes And Apparatus (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
- Producing Shaped Articles From Materials (AREA)
- Moulds For Moulding Plastics Or The Like (AREA)
- Casting Or Compression Moulding Of Plastics Or The Like (AREA)
- Medicines That Contain Protein Lipid Enzymes And Other Medicines (AREA)
- Medicines Containing Antibodies Or Antigens For Use As Internal Diagnostic Agents (AREA)
- Closures For Containers (AREA)
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE4225412A DE4225412C1 (enrdf_load_stackoverflow) | 1992-07-31 | 1992-07-31 | |
DE4225412 | 1992-07-31 | ||
PCT/EP1993/002048 WO1994003313A1 (de) | 1992-07-31 | 1993-07-30 | Form zum herstellen von flüssigkeitshaltigen pressteilen |
Publications (2)
Publication Number | Publication Date |
---|---|
EP0607402A1 EP0607402A1 (de) | 1994-07-27 |
EP0607402B1 true EP0607402B1 (de) | 1997-11-12 |
Family
ID=6464613
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP93917716A Expired - Lifetime EP0607402B1 (de) | 1992-07-31 | 1993-07-30 | Form zum herstellen von flüssigkeitshaltigen pressteilen |
Country Status (9)
Families Citing this family (10)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
ES2132717T3 (es) * | 1994-11-02 | 1999-08-16 | Portec Ag | Dispositivo de circulacion de un fluido entre un volumen delimitado por una superficie solida y un canal, y procedimiento de fabricacion de este dispositivo. |
ATE353274T1 (de) * | 1999-10-28 | 2007-02-15 | Attenberger Keramik | Verfahren zur herstellung von ziegeln oder fussbodenplatten aus ton |
ITRE20010022A1 (it) * | 2001-03-09 | 2002-09-09 | Sacmi | Elemento di stampo per la formatura d'oggetti mediante colatura ad impasto umido d'argilla e simili e metodo per la sua fabbricazione |
DE102004056975B3 (de) * | 2004-11-25 | 2006-07-06 | Dorst Technologies Gmbh & Co. Kg | Druckgussform und Verfahren zum Herstellen einer Druckgussform |
DE102005007909A1 (de) * | 2005-02-08 | 2006-08-10 | Rennebeck, Klaus, Dr. | Vorrichtung zur Herstellung von Formteilen aus Keramik |
DE102007045806A1 (de) | 2007-09-25 | 2009-04-02 | Dorst Technologies Gmbh & Co. Kg | Gießformkomponente und Verfahren zum Herstellen einer Gießformkomponente |
DE102008008968A1 (de) | 2008-02-13 | 2009-08-20 | Schlickenrieder, Klaus, Dr. Ing. | Form zum Herstellen von flüssigkeitshaltigen Teilen |
DE102009007670A1 (de) | 2009-02-05 | 2010-08-12 | Dorst Technologies Gmbh & Co. Kg | Gießformkomponente, Gießform und Verwendung einer solchen Gießform |
DE102011106218B3 (de) | 2011-06-07 | 2012-10-04 | Etex Holding GmbH | Tondachziegel-Nasspressform und Verfahren zur Herstellung einer Form für das Herstellen von Tondachziegeln durch Nasspressung |
CN111361002A (zh) * | 2020-03-10 | 2020-07-03 | 广西矿建集团有限公司 | 一种整体预制钢筋砼楼板的长方形钢模架及其构筑方法 |
Family Cites Families (21)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
GB191406751A (en) * | 1914-03-17 | 1915-03-17 | Samuel Davidson | Improvements in and relating to the Manufacture of Artificial Stone, Tiles and the like Moulded Ceramic and similar Products. |
FR538169A (fr) * | 1920-08-18 | 1922-06-06 | Arthur Muller Bauten Und Indus | Procédé et appareil pour l'exécution de plaques de moule pour la fabrication de tuiles en ciment dans des machines à plaques de frappe |
GB283894A (en) * | 1927-01-19 | 1929-07-16 | William Joseph Miller | Improvements in moulds for use in pottery manufacture |
US1993047A (en) * | 1933-02-14 | 1935-03-05 | Ontario Research Foundation | Process for the manufacture of ceramic ware |
US2026940A (en) * | 1934-12-13 | 1936-01-07 | Harbison Walker Refractories | Shaping refractory articles |
FR52514E (fr) * | 1942-07-24 | 1945-04-17 | Procédé de traitement et de séchage de la tourbe | |
DE910154C (de) * | 1951-01-10 | 1954-04-29 | Gottfried Cremer Dr | Pressform |
US2809898A (en) * | 1954-02-16 | 1957-10-15 | Gen Electric | Porous ceramic mold and method of making same |
US2800072A (en) * | 1954-04-28 | 1957-07-23 | American Viscose Corp | Cylindrical press assembly |
US2984887A (en) * | 1958-01-30 | 1961-05-23 | Gen Electric | Apparatus for manufacturing ceramics |
DE2104080A1 (en) * | 1971-01-29 | 1972-08-03 | Metallgesellschaft Ag, 6000 Frankfurt | Porous absorptive shapes contg silicon nitride - for refractory ceramic use |
FR2196602A5 (en) * | 1972-08-18 | 1974-03-15 | Bonnetot Henri | Pneumatically stripped moulds - with porous metallic lining giving long mould life |
CA1266159A (en) * | 1983-04-09 | 1990-02-27 | Takeo Nakagawa | Composite and durable forming model with permeability |
JPS6096585A (ja) * | 1983-10-28 | 1985-05-30 | バブコツク日立株式会社 | 多層構造セラミツクス部材とその製造方法 |
JPS61220809A (ja) * | 1985-03-27 | 1986-10-01 | Munekata Kk | 金型 |
JPS6321105A (ja) * | 1986-07-15 | 1988-01-28 | トヨタ自動車株式会社 | 2層構造のセラミツクス成形用多孔質成形型の製造方法 |
JPS6331710A (ja) * | 1986-07-26 | 1988-02-10 | 東陶機器株式会社 | 陶磁器加圧成形用多孔質型の製法 |
FR2602708B1 (fr) * | 1986-08-05 | 1990-08-24 | Elmetherm Sa | Procede de fabrication de moules destines a la realisation de pieces en matiere ceramique |
FR2602504B1 (fr) * | 1986-08-07 | 1992-02-14 | Desmarquest Ceramiques Tech | Procede de fabrication de materiaux de nitrure de silicium a porosite ouverte et application a des moules poreux |
JPH03290202A (ja) * | 1990-04-06 | 1991-12-19 | Kawasaki Steel Corp | 湿式成形用型 |
FR2674172B1 (fr) * | 1991-03-21 | 1993-06-18 | Ind Regionale Batiment | Moule de pressage pour la realisation d'articles obtenus a partir d'un materiau moulable sous forme de pate humide. |
-
1992
- 1992-07-31 DE DE4225412A patent/DE4225412C1/de not_active Expired - Fee Related
-
1993
- 1993-07-30 CA CA002120157A patent/CA2120157A1/en not_active Abandoned
- 1993-07-30 WO PCT/EP1993/002048 patent/WO1994003313A1/de active IP Right Grant
- 1993-07-30 TR TR00681/93A patent/TR28181A/xx unknown
- 1993-07-30 EP EP93917716A patent/EP0607402B1/de not_active Expired - Lifetime
- 1993-07-30 AU AU47056/93A patent/AU666968B2/en not_active Ceased
- 1993-07-30 AT AT93917716T patent/ATE160105T1/de not_active IP Right Cessation
- 1993-07-30 ZA ZA935514A patent/ZA935514B/xx unknown
- 1993-07-31 CN CN93117645A patent/CN1088150A/zh active Pending
Also Published As
Publication number | Publication date |
---|---|
EP0607402A1 (de) | 1994-07-27 |
ATE160105T1 (de) | 1997-11-15 |
CN1088150A (zh) | 1994-06-22 |
AU666968B2 (en) | 1996-02-29 |
CA2120157A1 (en) | 1994-02-17 |
TR28181A (tr) | 1996-02-06 |
DE4225412C1 (enrdf_load_stackoverflow) | 1993-04-29 |
AU4705693A (en) | 1994-03-03 |
WO1994003313A1 (de) | 1994-02-17 |
ZA935514B (en) | 1994-09-20 |
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