EP0589807A1 - Aluminium-Legierung für Hohlkörper für Druckbehälter - Google Patents

Aluminium-Legierung für Hohlkörper für Druckbehälter Download PDF

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Publication number
EP0589807A1
EP0589807A1 EP93420377A EP93420377A EP0589807A1 EP 0589807 A1 EP0589807 A1 EP 0589807A1 EP 93420377 A EP93420377 A EP 93420377A EP 93420377 A EP93420377 A EP 93420377A EP 0589807 A1 EP0589807 A1 EP 0589807A1
Authority
EP
European Patent Office
Prior art keywords
alloy
stage
hollow bodies
income
resistance
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
EP93420377A
Other languages
English (en)
French (fr)
Other versions
EP0589807B1 (de
Inventor
Jean-Christophe Ehrström
Marc Anagnostidis
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Metallurgigue de Gerzat
Original Assignee
Metallurgigue de Gerzat
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Metallurgigue de Gerzat filed Critical Metallurgigue de Gerzat
Publication of EP0589807A1 publication Critical patent/EP0589807A1/de
Application granted granted Critical
Publication of EP0589807B1 publication Critical patent/EP0589807B1/de
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22FCHANGING THE PHYSICAL STRUCTURE OF NON-FERROUS METALS AND NON-FERROUS ALLOYS
    • C22F1/00Changing the physical structure of non-ferrous metals or alloys by heat treatment or by hot or cold working
    • C22F1/04Changing the physical structure of non-ferrous metals or alloys by heat treatment or by hot or cold working of aluminium or alloys based thereon
    • C22F1/053Changing the physical structure of non-ferrous metals or alloys by heat treatment or by hot or cold working of aluminium or alloys based thereon of alloys with zinc as the next major constituent
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C21/00Alloys based on aluminium
    • C22C21/10Alloys based on aluminium with zinc as the next major constituent
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F17STORING OR DISTRIBUTING GASES OR LIQUIDS
    • F17CVESSELS FOR CONTAINING OR STORING COMPRESSED, LIQUEFIED OR SOLIDIFIED GASES; FIXED-CAPACITY GAS-HOLDERS; FILLING VESSELS WITH, OR DISCHARGING FROM VESSELS, COMPRESSED, LIQUEFIED, OR SOLIDIFIED GASES
    • F17C1/00Pressure vessels, e.g. gas cylinder, gas tank, replaceable cartridge
    • F17C1/14Pressure vessels, e.g. gas cylinder, gas tank, replaceable cartridge constructed of aluminium; constructed of non-magnetic steel
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F17STORING OR DISTRIBUTING GASES OR LIQUIDS
    • F17CVESSELS FOR CONTAINING OR STORING COMPRESSED, LIQUEFIED OR SOLIDIFIED GASES; FIXED-CAPACITY GAS-HOLDERS; FILLING VESSELS WITH, OR DISCHARGING FROM VESSELS, COMPRESSED, LIQUEFIED, OR SOLIDIFIED GASES
    • F17C2201/00Vessel construction, in particular geometry, arrangement or size
    • F17C2201/05Size
    • F17C2201/058Size portable (<30 l)
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F17STORING OR DISTRIBUTING GASES OR LIQUIDS
    • F17CVESSELS FOR CONTAINING OR STORING COMPRESSED, LIQUEFIED OR SOLIDIFIED GASES; FIXED-CAPACITY GAS-HOLDERS; FILLING VESSELS WITH, OR DISCHARGING FROM VESSELS, COMPRESSED, LIQUEFIED, OR SOLIDIFIED GASES
    • F17C2203/00Vessel construction, in particular walls or details thereof
    • F17C2203/06Materials for walls or layers thereof; Properties or structures of walls or their materials
    • F17C2203/0634Materials for walls or layers thereof
    • F17C2203/0636Metals
    • F17C2203/0646Aluminium
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F17STORING OR DISTRIBUTING GASES OR LIQUIDS
    • F17CVESSELS FOR CONTAINING OR STORING COMPRESSED, LIQUEFIED OR SOLIDIFIED GASES; FIXED-CAPACITY GAS-HOLDERS; FILLING VESSELS WITH, OR DISCHARGING FROM VESSELS, COMPRESSED, LIQUEFIED, OR SOLIDIFIED GASES
    • F17C2203/00Vessel construction, in particular walls or details thereof
    • F17C2203/06Materials for walls or layers thereof; Properties or structures of walls or their materials
    • F17C2203/0634Materials for walls or layers thereof
    • F17C2203/0636Metals
    • F17C2203/0648Alloys or compositions of metals
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F17STORING OR DISTRIBUTING GASES OR LIQUIDS
    • F17CVESSELS FOR CONTAINING OR STORING COMPRESSED, LIQUEFIED OR SOLIDIFIED GASES; FIXED-CAPACITY GAS-HOLDERS; FILLING VESSELS WITH, OR DISCHARGING FROM VESSELS, COMPRESSED, LIQUEFIED, OR SOLIDIFIED GASES
    • F17C2209/00Vessel construction, in particular methods of manufacturing
    • F17C2209/23Manufacturing of particular parts or at special locations
    • F17C2209/232Manufacturing of particular parts or at special locations of walls
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F17STORING OR DISTRIBUTING GASES OR LIQUIDS
    • F17CVESSELS FOR CONTAINING OR STORING COMPRESSED, LIQUEFIED OR SOLIDIFIED GASES; FIXED-CAPACITY GAS-HOLDERS; FILLING VESSELS WITH, OR DISCHARGING FROM VESSELS, COMPRESSED, LIQUEFIED, OR SOLIDIFIED GASES
    • F17C2260/00Purposes of gas storage and gas handling
    • F17C2260/01Improving mechanical properties or manufacturing
    • F17C2260/011Improving strength
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F17STORING OR DISTRIBUTING GASES OR LIQUIDS
    • F17CVESSELS FOR CONTAINING OR STORING COMPRESSED, LIQUEFIED OR SOLIDIFIED GASES; FIXED-CAPACITY GAS-HOLDERS; FILLING VESSELS WITH, OR DISCHARGING FROM VESSELS, COMPRESSED, LIQUEFIED, OR SOLIDIFIED GASES
    • F17C2260/00Purposes of gas storage and gas handling
    • F17C2260/05Improving chemical properties
    • F17C2260/053Reducing corrosion
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F17STORING OR DISTRIBUTING GASES OR LIQUIDS
    • F17CVESSELS FOR CONTAINING OR STORING COMPRESSED, LIQUEFIED OR SOLIDIFIED GASES; FIXED-CAPACITY GAS-HOLDERS; FILLING VESSELS WITH, OR DISCHARGING FROM VESSELS, COMPRESSED, LIQUEFIED, OR SOLIDIFIED GASES
    • F17C2270/00Applications
    • F17C2270/07Applications for household use
    • F17C2270/0745Gas bottles

Definitions

  • the invention relates to an Al alloy which can be used for the manufacture of hollow bodies under pressure, and in particular, metal bottles for compressed gases.
  • the alloys according to the invention therefore have the following weight composition (in%): Rest: AI
  • the Mg content is preferably kept below 2%, and even 1.95%, and the Zr content is preferably between 0.10 and 0.18%, the Fe + Si contents being ⁇ 0, 25% with Fe Z 0.12%, an Mn Z content 0.10% and / or the Zn content - 6.75.
  • the structure is recrystallized, but with large grains.
  • the manufacturing and control process are similar to those described in EP-A-0257167, but preferably the treatment of final income type T73 is replaced by an income in 3 stages, the 1st stage being carried out between 105 and 120 °. C for 6 to 12 h, the 2nd step being carried out between 170 and 190 ° C for 0.5 to 20 h and the 3rd step being carried out between 105 and 120 ° C, for 12 to 36 h.
  • durations and temperatures actually used are chosen by a person skilled in the art so as to obtain both a high electrical conductivity (corresponding to good resistance to corrosion under tension) and a high elastic limit.
  • Example 1 Replacement of Cr by Zr for two-phase income type T73.
  • the burst characteristics are correct (longitudinal crack for the most part, unbranched, limited to a sector of angle ⁇ 90 ° around the main crack, limited towards the bottom and towards the neck at areas whose thickness is less than 1.5 times the thickness of the body), the developed length of the crack was noted as a good indication of the ability to burst: the longer the crack, the more approximates the conditions for which the burst would be bad.
  • the mechanical resistance and the resistance to corrosion under stress are linked in a one-to-one way, which makes it better to speak of a loss on the compromise mechanical resistance / resistance to corrosion under stress.
  • the replacement of chromium by zirconium negatively affects the corrosion resistance or the mechanical resistance, depending on the duration of the maintenance at the second level which one chooses.
  • the following example shows the gain that can be obtained by performing an income in three stages on the bottles manufactured in alloy 2 according to the range of the previous example.
  • Electrical conductivity is taken as an indicator of resistance to stress corrosion, in accordance with standard practice. All values in the table below are averages of 3 individual values.

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • Materials Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Physics & Mathematics (AREA)
  • Thermal Sciences (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • General Engineering & Computer Science (AREA)
  • Heat Treatment Of Steel (AREA)
  • Superconductors And Manufacturing Methods Therefor (AREA)
  • Filling Or Discharging Of Gas Storage Vessels (AREA)
  • Shaping Metal By Deep-Drawing, Or The Like (AREA)
  • Catalysts (AREA)
  • Materials For Medical Uses (AREA)
  • Metal Extraction Processes (AREA)
  • Press Drives And Press Lines (AREA)
  • Air Bags (AREA)
  • Forging (AREA)
  • Pressure Vessels And Lids Thereof (AREA)
EP93420377A 1992-09-22 1993-09-20 Verwendung einer Aluminium-Legierung zur Herstellung von Gasflaschen Expired - Lifetime EP0589807B1 (de)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
FR9211502A FR2695942B1 (fr) 1992-09-22 1992-09-22 Alliage d'aluminium pour corps creux sous pression.
FR9211502 1992-09-22

Publications (2)

Publication Number Publication Date
EP0589807A1 true EP0589807A1 (de) 1994-03-30
EP0589807B1 EP0589807B1 (de) 1998-06-10

Family

ID=9433935

Family Applications (1)

Application Number Title Priority Date Filing Date
EP93420377A Expired - Lifetime EP0589807B1 (de) 1992-09-22 1993-09-20 Verwendung einer Aluminium-Legierung zur Herstellung von Gasflaschen

Country Status (10)

Country Link
EP (1) EP0589807B1 (de)
JP (1) JPH06256882A (de)
AT (1) ATE167237T1 (de)
AU (1) AU670114B2 (de)
BR (1) BR9303846A (de)
CA (1) CA2106320C (de)
DE (1) DE69319051T2 (de)
DK (1) DK0589807T3 (de)
ES (1) ES2118209T3 (de)
FR (1) FR2695942B1 (de)

Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2805282A1 (fr) * 2000-02-23 2001-08-24 Gerzat Metallurg Procede de fabrication de corps creux sous pression en alliage a1znmgcu
WO2005001149A2 (fr) * 2003-06-24 2005-01-06 Pechiney Rhenalu Produits en alliages al-zn-mg-cu a compromis caracteristiques mecaniques statiques/tolerance aux dommages ameliore
EP1544315A1 (de) * 2003-12-16 2005-06-22 Pechiney Rhenalu Knetprodukt und Strukturbauteil für Flugzeug aus Al-Zn-Cu-Mg-Legierung
EP2541119A1 (de) * 2011-06-29 2013-01-02 L'air Liquide, Societe Anonyme Pour L'etude Et L'exploitation Des Procedes Georges Claude Befüllungsverfahrung in Aluminiumflaschen für NO/N2 Gasgemische
EP2541120A1 (de) * 2011-06-29 2013-01-02 L'air Liquide, Societe Anonyme Pour L'etude Et L'exploitation Des Procedes Georges Claude Aluminiumflasche für Gasgemische aus Stickstoffmonoxid/Stickstoff, und ihr Einsatz zur Behandlung von Gefäßverengungen in der Lunge
FR3068370A1 (fr) * 2017-07-03 2019-01-04 Constellium Issoire Alliages al- zn-cu-mg et procede de fabrication

Families Citing this family (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
ES2292075T5 (es) 2005-01-19 2010-12-17 Otto Fuchs Kg Aleacion de aluminio no sensible al enfriamiento brusco, asi como procedimiento para fabricar un producto semiacabado a partir de esta aleacion.
JP5276341B2 (ja) * 2008-03-18 2013-08-28 株式会社神戸製鋼所 耐水素脆化特性に優れた高圧ガス容器用アルミニウム合金材
EP3670690A1 (de) 2018-12-20 2020-06-24 Constellium Issoire Al-zn-cu-mg-legierungen und deren herstellungsverfahren
CN111876639A (zh) * 2020-08-06 2020-11-03 北部湾大学 一种汽车立柱用7000系铝合金及其板材的制造方法

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2409320A1 (fr) * 1977-11-21 1979-06-15 Pechiney Aluminium Procede de traitement thermique de produits epais en alliages d'aluminium de la serie 7000 contenant du cuivre
EP0070790A1 (de) * 1981-07-22 1983-01-26 Societe Metallurgique De Gerzat Verfahren zur Herstellung von Hohlkörpern für Druckbehälter aus einer Aluminiumlegierung
EP0081441A1 (de) * 1981-12-03 1983-06-15 Societe Metallurgique De Gerzat Verfahren zur Herstellung von extrudierten Werkstücken aus hochfesten Legierungen des Typs Al-Zn-Mg-Cu, mit Zähigkeit in Querrichtung
EP0257167A1 (de) * 1986-07-24 1988-03-02 Societe Metallurgique De Gerzat Legierung auf Aluminiumbasis für Hohlkörper für Druckbehälter

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2409320A1 (fr) * 1977-11-21 1979-06-15 Pechiney Aluminium Procede de traitement thermique de produits epais en alliages d'aluminium de la serie 7000 contenant du cuivre
EP0070790A1 (de) * 1981-07-22 1983-01-26 Societe Metallurgique De Gerzat Verfahren zur Herstellung von Hohlkörpern für Druckbehälter aus einer Aluminiumlegierung
EP0081441A1 (de) * 1981-12-03 1983-06-15 Societe Metallurgique De Gerzat Verfahren zur Herstellung von extrudierten Werkstücken aus hochfesten Legierungen des Typs Al-Zn-Mg-Cu, mit Zähigkeit in Querrichtung
EP0257167A1 (de) * 1986-07-24 1988-03-02 Societe Metallurgique De Gerzat Legierung auf Aluminiumbasis für Hohlkörper für Druckbehälter

Non-Patent Citations (2)

* Cited by examiner, † Cited by third party
Title
P.K. BALASUBRAMANIAN: "Extrusion of Al-Zn-Mg-Cu-Zr Alloys", MATERIALS SCIENCE AND TECHNOLOGY, vol. 1, no. 6, 1985, LONDON GB, pages 470 - 474 *
W. HUFNAGEL: "ALUMINIUM-TASCHENBUCH", 1986, ALUMINIUM VERLAG, DUESSELDORF, DE *

Cited By (13)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2805282A1 (fr) * 2000-02-23 2001-08-24 Gerzat Metallurg Procede de fabrication de corps creux sous pression en alliage a1znmgcu
EP1127952A1 (de) * 2000-02-23 2001-08-29 Société Métallurgique de Gerzat Verfahren zur Herstellung von Hohlkörpern für Druckbehälter aus AlZnMgCu-Legierung
WO2005001149A2 (fr) * 2003-06-24 2005-01-06 Pechiney Rhenalu Produits en alliages al-zn-mg-cu a compromis caracteristiques mecaniques statiques/tolerance aux dommages ameliore
WO2005001149A3 (fr) * 2003-06-24 2005-05-26 Pechiney Rhenalu Produits en alliages al-zn-mg-cu a compromis caracteristiques mecaniques statiques/tolerance aux dommages ameliore
US7452429B2 (en) 2003-06-24 2008-11-18 Pechiney Rhenalu Products made of Al-Zn-Mg-Cu alloys with an improved compromise between static mechanical characteristics and damage tolerance
EP1544315A1 (de) * 2003-12-16 2005-06-22 Pechiney Rhenalu Knetprodukt und Strukturbauteil für Flugzeug aus Al-Zn-Cu-Mg-Legierung
EP2541119A1 (de) * 2011-06-29 2013-01-02 L'air Liquide, Societe Anonyme Pour L'etude Et L'exploitation Des Procedes Georges Claude Befüllungsverfahrung in Aluminiumflaschen für NO/N2 Gasgemische
EP2541120A1 (de) * 2011-06-29 2013-01-02 L'air Liquide, Societe Anonyme Pour L'etude Et L'exploitation Des Procedes Georges Claude Aluminiumflasche für Gasgemische aus Stickstoffmonoxid/Stickstoff, und ihr Einsatz zur Behandlung von Gefäßverengungen in der Lunge
FR2977297A1 (fr) * 2011-06-29 2013-01-04 Air Liquide Bouteille en aluminium pour melange gazeux no/azote
FR2977298A1 (fr) * 2011-06-29 2013-01-04 Air Liquide Bouteille en aluminium pour melange gazeux no/azote
FR3068370A1 (fr) * 2017-07-03 2019-01-04 Constellium Issoire Alliages al- zn-cu-mg et procede de fabrication
WO2019007817A1 (en) * 2017-07-03 2019-01-10 Constellium Issoire AL-ZN-CU-MG ALLOYS AND PROCESS FOR PRODUCING THE SAME
US11976347B2 (en) 2017-07-03 2024-05-07 Constellium Issoire Al—Zn—Cu—Mg alloys and their manufacturing process

Also Published As

Publication number Publication date
FR2695942B1 (fr) 1994-11-18
DE69319051T2 (de) 1998-12-10
AU4751193A (en) 1994-03-31
ATE167237T1 (de) 1998-06-15
CA2106320A1 (fr) 1994-03-23
ES2118209T3 (es) 1998-09-16
AU670114B2 (en) 1996-07-04
CA2106320C (fr) 2003-11-18
BR9303846A (pt) 1994-03-29
DK0589807T3 (da) 1999-03-22
FR2695942A1 (fr) 1994-03-25
JPH06256882A (ja) 1994-09-13
EP0589807B1 (de) 1998-06-10
DE69319051D1 (de) 1998-07-16

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