EP0520995B1 - Elektrodenanordnung für elektrolytische zwecke - Google Patents

Elektrodenanordnung für elektrolytische zwecke Download PDF

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Publication number
EP0520995B1
EP0520995B1 EP91903194A EP91903194A EP0520995B1 EP 0520995 B1 EP0520995 B1 EP 0520995B1 EP 91903194 A EP91903194 A EP 91903194A EP 91903194 A EP91903194 A EP 91903194A EP 0520995 B1 EP0520995 B1 EP 0520995B1
Authority
EP
European Patent Office
Prior art keywords
cathodes
electrode arrangement
holding device
arrangement according
cathode
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
EP91903194A
Other languages
German (de)
English (en)
French (fr)
Other versions
EP0520995A1 (de
Inventor
Max Mayr
Wolfgang Blatt
Harri Heinke
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
De Nora Deutschland GmbH
Original Assignee
Heraeus Elektrochemie GmbH
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Heraeus Elektrochemie GmbH filed Critical Heraeus Elektrochemie GmbH
Publication of EP0520995A1 publication Critical patent/EP0520995A1/de
Application granted granted Critical
Publication of EP0520995B1 publication Critical patent/EP0520995B1/de
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
    • C25B9/00—Cells or assemblies of cells; Constructional parts of cells; Assemblies of constructional parts, e.g. electrode-diaphragm assemblies; Process-related cell features
    • C25B9/60—Constructional parts of cells
    • C25B9/63—Holders for electrodes; Positioning of the electrodes
    • C—CHEMISTRY; METALLURGY
    • C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25C—PROCESSES FOR THE ELECTROLYTIC PRODUCTION, RECOVERY OR REFINING OF METALS; APPARATUS THEREFOR
    • C25C7/00—Constructional parts, or assemblies thereof, of cells; Servicing or operating of cells

Definitions

  • the invention relates to an electrode arrangement for an electrolysis cell with at least one anode and with at least two plate-shaped cathodes which are electrically insulated from one another, on one side of the anode and at a distance from one another, each cathode having at least two openings for the electrolyte flow and the cathodes increasing with increasing distance from the anode is at an electrically higher potential.
  • an electrolysis cell for the electrolytic deposition of metals from liquid containing metal ions which has at least one anode and a plurality of planar cathodes arranged parallel to one another in a trough, which are arranged at a distance from one another and each with its own connections are connected to the power supply via connection resistors of different sizes.
  • the electrode plates serving as cathodes are arranged individually in the trough and have sufficient stability; they can also be replaced individually. Due to the wall thicknesses required for the stability of the individual cathodes, there is a comparatively high loss of material with each upcoming change of cathode.
  • an electrolysis cell in which an anode plate is known a plurality of adjacent, spaced-apart cathode plates, but only the most distant cathode plate is connected to the negative potential of the power supply .
  • the cathode plates have openings for a zigzag-shaped ion current, copper itself being deposited on the plates from the solution containing copper ions. After copper deposition, the cathode plates are exchanged for unplated cathode plates.
  • DE-A-2 213 401 discloses an electrolysis device for recovering silver from an upstream photographic fixing bath, in which cathode plates are fastened in parallel to one another at a distance, with spacing rings being interposed, on a common support and are suspended as a cathode package on a housing wall of the device .
  • the rod-shaped anodes provided with a circular cross-section are arranged along the housing wall in a plane which runs perpendicular to the plane of the individual cathode plates.
  • the object of the invention is to create material-saving cathode systems with a large cathode surface, starting from DE-PS 36 40 020, a high current yield being achievable despite the low material and manufacturing costs. In addition, easy handling during operation should also be achieved.
  • the holding device consists of four rods guided through cutouts in the electrode plates, spacer elements being arranged between the electrode plates and the respective outer electrode plates being pressed together by locking means acting on the bolt ends.
  • the spacer elements are either tubular, each comprising the bolt, or they are in the form of pockets, which comprise the electrode plates; the pocket-shaped spacer elements are provided with cutouts for the passage of the bolts and for liquid access to the electrode plates.
  • the holding device is designed like a comb, the spacer elements forming the comb teeth as integral parts of the holding device; several such comb-like holding devices are connected to one another by a web.
  • the electrode plates have a wall thickness in the range from 0.04 to 0.25 mm, the ratio of the wall thickness to the distance between the electrode plates being in the range from 1 to 50 to 1 to 300.
  • a wall thickness of 0.1 mm has proven to be particularly expedient. Their openings are evenly distributed over the electrode surface.
  • contact strips are arranged on the side or top and bottom of the electrode plate, each of which is provided with a plate flag.
  • Electrodes are used as electrode plates, which have a plurality of uniformly distributed openings 14 on their surface.
  • the electrode plates 1, 1 ' have a thickness of approximately 0.05 mm; they consist of a metal adapted to the metal ions to be deposited.
  • they preferably consist of copper or a copper alloy
  • the plate-shaped counterelectrode 17 serving as the anode is arranged outside the holding device and provided with a plate flag 18; it is aligned parallel to the electrode plates 1, 1 '.
  • the electrode arrangement has four electrode plates 1, which are held by four plate-shaped holding devices 2 ', 2''.
  • the planes of the holding devices are arranged perpendicular to the planes of the electrode plates 1, the two outer holding devices 2 'holding the opposite edges of the electrode plates 1, while the middle holding devices 2''arranged between the two outer holding devices 2''hold the middle region of electrodes 1.
  • the electrode plates 1, which are made of expanded metal, for example, are each provided on at least one side with a current collector 3, which is electrically and mechanically firmly connected to a connecting lug 4.
  • the size of the opening 14 is predetermined on the basis of the dimensioning of the machine length, mesh width and web width of the expanded metal.
  • the holding devices 2 ′, 2 ′′ have comb-like recesses 9 for receiving the electrode plates 1, the clear width of the recesses being slightly above the wall thickness of the electrode plates.
  • the spacer elements 15 designed as comb teeth, which are attached directly to a crosspiece 5 as a comb back and form an integral component with it, while the opposite crosspiece 6 is only applied after insertion of the electrode plates 1 so that it is connected to the free ends of the spacer elements are mechanically firmly connected; in this way, the electrode plates 1 are locked on two opposite edges by the transverse webs 5, 6 against lateral displacement or slipping.
  • the holding devices 2 ′, 2 ′′ are mechanically firmly connected to one another at their outer edges in the region of the transverse webs 5, 6 by outer webs 16, so that a coherent electrode package is formed.
  • the plate-shaped counterelectrode 17 serving as the anode is arranged outside the holding device and provided with a plate flag 18; it is aligned parallel to the electrode plates 1.
  • the assembly of the electrode plates to form an electrode packet is carried out in stages by introducing the electrode plates 1 into the outer holding device 2 ', the connecting lugs 4 of all the electrode plates 1 being in the immediate vicinity of the holding device 2'.
  • the middle holding devices 2 ′′ are pushed on and positioned in the middle area of the electrode plates 1; the final completion then takes place by applying the second outer holding device 2 ′′ and the subsequent connection of all holding devices 2 ′, 2 ′′ by the outer webs 16.

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Electrochemistry (AREA)
  • Materials Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Electrolytic Production Of Metals (AREA)
  • Water Treatment By Electricity Or Magnetism (AREA)
  • Electrolytic Production Of Non-Metals, Compounds, Apparatuses Therefor (AREA)
  • Secondary Cells (AREA)
EP91903194A 1990-03-17 1991-01-18 Elektrodenanordnung für elektrolytische zwecke Expired - Lifetime EP0520995B1 (de)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
DE4008684 1990-03-17
DE4008684A DE4008684C1 (ja) 1990-03-17 1990-03-17
PCT/EP1991/000080 WO1991014803A1 (de) 1990-03-17 1991-01-18 Elektrodenanordnung für elektrolytische zwecke

Publications (2)

Publication Number Publication Date
EP0520995A1 EP0520995A1 (de) 1993-01-07
EP0520995B1 true EP0520995B1 (de) 1994-07-20

Family

ID=6402498

Family Applications (1)

Application Number Title Priority Date Filing Date
EP91903194A Expired - Lifetime EP0520995B1 (de) 1990-03-17 1991-01-18 Elektrodenanordnung für elektrolytische zwecke

Country Status (8)

Country Link
US (1) US5324409A (ja)
EP (1) EP0520995B1 (ja)
JP (1) JPH0811836B2 (ja)
AT (1) ATE108839T1 (ja)
CA (1) CA2076862A1 (ja)
DE (2) DE4008684C1 (ja)
ES (1) ES2057863T3 (ja)
WO (1) WO1991014803A1 (ja)

Families Citing this family (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US7494580B2 (en) * 2003-07-28 2009-02-24 Phelps Dodge Corporation System and method for producing copper powder by electrowinning using the ferrous/ferric anode reaction
US7378011B2 (en) * 2003-07-28 2008-05-27 Phelps Dodge Corporation Method and apparatus for electrowinning copper using the ferrous/ferric anode reaction
US20060021880A1 (en) * 2004-06-22 2006-02-02 Sandoval Scot P Method and apparatus for electrowinning copper using the ferrous/ferric anode reaction and a flow-through anode
US7452455B2 (en) * 2004-07-22 2008-11-18 Phelps Dodge Corporation System and method for producing metal powder by electrowinning
US7378010B2 (en) * 2004-07-22 2008-05-27 Phelps Dodge Corporation System and method for producing copper powder by electrowinning in a flow-through electrowinning cell
US7393438B2 (en) * 2004-07-22 2008-07-01 Phelps Dodge Corporation Apparatus for producing metal powder by electrowinning
MX2010007795A (es) 2008-01-17 2011-02-23 Freeport Mcmoran Corp Metodo y aparato para la recuperacion por via electrolitica de cobre usando lixiviacion atmosferica con extraccion por via electrolitica de reaccion de anodo ferroso/ferrico.
US20110054572A1 (en) * 2009-07-29 2011-03-03 A Major Difference, Inc. Therapeutic electrolysis device with replaceable ionizer unit
FI128729B (en) * 2015-12-22 2020-11-13 Outotec Finland Oy ELECTROD MODULE, ELECTRICITY REACTOR, AND WATER TREATMENT DEVICE

Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3956613A (en) * 1975-03-05 1976-05-11 Dart Industries Inc. Base element for an immersible electric coffee maker

Family Cites Families (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE2213401A1 (de) * 1972-03-20 1973-10-04 Paul Syre Verfahren und vorrichtung zur elektrolytischen silberrueckgewinnung aus gebrauchten fotografischen fixierbadfluessigkeiten
US3788965A (en) * 1972-04-07 1974-01-29 2C 2B Corp Hydrometallurgical solubilizer with selective electroplating mechanism
US3953313A (en) * 1972-06-30 1976-04-27 Eastman Kodak Company Electrolytic cell and electrode therefor
DE2345728B2 (de) * 1973-09-11 1977-06-16 Simplex Time Recorder Co., Gardner, Mass. (V.St.A.) Zeitregistriergeraet
DE2659253A1 (de) * 1976-12-28 1978-06-29 Archie Henry Blue Elektrolysegeraet
US4075077A (en) * 1977-05-16 1978-02-21 Pennwalt Corporation Electrolytic cell
CA1124209A (en) * 1978-09-29 1982-05-25 Roy E. Williams Electrode spacer element
FR2490683A1 (fr) * 1980-09-19 1982-03-26 Ugine Kuhlmann Perfectionnement aux reacteurs electrochimiques
FR2569394A1 (fr) * 1984-08-24 1986-02-28 Mercier Dominique Appareil de traitement de l'eau par flux electronique de basse tension qui permet la neutralisation simultanee d'un ou plusieurs sels dissous dans l'eau
US5049252A (en) * 1986-01-21 1991-09-17 Murrell Wilfred A Water cleaning system
DE3640020C1 (de) * 1986-11-24 1988-02-18 Heraeus Elektroden Elektrolysezelle zur elektrolytischen Abscheidung von Metallen

Patent Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3956613A (en) * 1975-03-05 1976-05-11 Dart Industries Inc. Base element for an immersible electric coffee maker

Also Published As

Publication number Publication date
JPH0811836B2 (ja) 1996-02-07
US5324409A (en) 1994-06-28
DE4008684C1 (ja) 1991-02-07
ATE108839T1 (de) 1994-08-15
ES2057863T3 (es) 1994-10-16
EP0520995A1 (de) 1993-01-07
DE59102271D1 (de) 1994-08-25
WO1991014803A1 (de) 1991-10-03
CA2076862A1 (en) 1991-09-18
JPH05504994A (ja) 1993-07-29

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