EP0500770B1 - Verfahren zur herstellung von papier - Google Patents
Verfahren zur herstellung von papier Download PDFInfo
- Publication number
- EP0500770B1 EP0500770B1 EP91900405A EP91900405A EP0500770B1 EP 0500770 B1 EP0500770 B1 EP 0500770B1 EP 91900405 A EP91900405 A EP 91900405A EP 91900405 A EP91900405 A EP 91900405A EP 0500770 B1 EP0500770 B1 EP 0500770B1
- Authority
- EP
- European Patent Office
- Prior art keywords
- silicic acid
- polymeric silicic
- cationic
- process according
- polymeric
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 238000000034 method Methods 0.000 title claims abstract description 23
- 238000004519 manufacturing process Methods 0.000 title claims abstract description 16
- 235000012239 silicon dioxide Nutrition 0.000 claims abstract description 57
- RMAQACBXLXPBSY-UHFFFAOYSA-N silicic acid Chemical compound O[Si](O)(O)O RMAQACBXLXPBSY-UHFFFAOYSA-N 0.000 claims abstract description 47
- 125000002091 cationic group Chemical group 0.000 claims abstract description 44
- 229920002472 Starch Polymers 0.000 claims abstract description 27
- 239000008107 starch Substances 0.000 claims abstract description 27
- 235000019698 starch Nutrition 0.000 claims abstract description 27
- 229920002401 polyacrylamide Polymers 0.000 claims abstract description 25
- 239000000835 fiber Substances 0.000 claims abstract description 17
- 239000000945 filler Substances 0.000 claims abstract description 13
- 239000000725 suspension Substances 0.000 claims abstract description 10
- 229920002678 cellulose Polymers 0.000 claims abstract description 3
- 239000001913 cellulose Substances 0.000 claims abstract description 3
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 32
- 239000000377 silicon dioxide Substances 0.000 claims description 15
- 230000020477 pH reduction Effects 0.000 claims description 12
- 239000000126 substance Substances 0.000 claims description 11
- 239000002253 acid Substances 0.000 claims description 10
- 229910052681 coesite Inorganic materials 0.000 claims description 8
- 229910052906 cristobalite Inorganic materials 0.000 claims description 8
- 229910052682 stishovite Inorganic materials 0.000 claims description 8
- 229910052905 tridymite Inorganic materials 0.000 claims description 8
- NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 claims description 7
- 229920001131 Pulp (paper) Polymers 0.000 claims description 6
- 229920006317 cationic polymer Polymers 0.000 claims description 6
- 235000019353 potassium silicate Nutrition 0.000 claims description 5
- 125000000129 anionic group Chemical group 0.000 claims description 4
- 229910052783 alkali metal Inorganic materials 0.000 claims description 2
- 150000001340 alkali metals Chemical class 0.000 claims description 2
- 150000001768 cations Chemical class 0.000 claims 1
- 230000014759 maintenance of location Effects 0.000 abstract description 13
- 239000000123 paper Substances 0.000 description 16
- 230000000694 effects Effects 0.000 description 9
- 239000002245 particle Substances 0.000 description 9
- 238000007792 addition Methods 0.000 description 6
- 239000003795 chemical substances by application Substances 0.000 description 6
- 238000002360 preparation method Methods 0.000 description 6
- 125000005624 silicic acid group Chemical class 0.000 description 6
- 238000003860 storage Methods 0.000 description 6
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 description 4
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 4
- 229910052782 aluminium Inorganic materials 0.000 description 4
- -1 aluminum modified silica particles Chemical class 0.000 description 4
- 150000001875 compounds Chemical class 0.000 description 4
- 230000001976 improved effect Effects 0.000 description 4
- 239000003456 ion exchange resin Substances 0.000 description 4
- 229920003303 ion-exchange polymer Polymers 0.000 description 4
- 229920003043 Cellulose fiber Polymers 0.000 description 3
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 3
- KKCBUQHMOMHUOY-UHFFFAOYSA-N Na2O Inorganic materials [O-2].[Na+].[Na+] KKCBUQHMOMHUOY-UHFFFAOYSA-N 0.000 description 3
- MUBZPKHOEPUJKR-UHFFFAOYSA-N Oxalic acid Chemical compound OC(=O)C(O)=O MUBZPKHOEPUJKR-UHFFFAOYSA-N 0.000 description 3
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 3
- 229910052910 alkali metal silicate Inorganic materials 0.000 description 3
- 229940037003 alum Drugs 0.000 description 3
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 description 3
- 238000006116 polymerization reaction Methods 0.000 description 3
- 229910021653 sulphate ion Inorganic materials 0.000 description 3
- NWUYHJFMYQTDRP-UHFFFAOYSA-N 1,2-bis(ethenyl)benzene;1-ethenyl-2-ethylbenzene;styrene Chemical compound C=CC1=CC=CC=C1.CCC1=CC=CC=C1C=C.C=CC1=CC=CC=C1C=C NWUYHJFMYQTDRP-UHFFFAOYSA-N 0.000 description 2
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 2
- 150000007513 acids Chemical class 0.000 description 2
- 239000000654 additive Substances 0.000 description 2
- 229910000147 aluminium phosphate Inorganic materials 0.000 description 2
- VSCWAEJMTAWNJL-UHFFFAOYSA-K aluminium trichloride Chemical compound Cl[Al](Cl)Cl VSCWAEJMTAWNJL-UHFFFAOYSA-K 0.000 description 2
- 150000001450 anions Chemical class 0.000 description 2
- 239000007864 aqueous solution Substances 0.000 description 2
- 239000008119 colloidal silica Substances 0.000 description 2
- 238000007796 conventional method Methods 0.000 description 2
- 238000001879 gelation Methods 0.000 description 2
- 229910052500 inorganic mineral Inorganic materials 0.000 description 2
- 150000002500 ions Chemical class 0.000 description 2
- 229920002521 macromolecule Polymers 0.000 description 2
- 239000011707 mineral Substances 0.000 description 2
- 238000002156 mixing Methods 0.000 description 2
- 230000000717 retained effect Effects 0.000 description 2
- 239000000243 solution Substances 0.000 description 2
- 238000006467 substitution reaction Methods 0.000 description 2
- 238000004448 titration Methods 0.000 description 2
- BNGXYYYYKUGPPF-UHFFFAOYSA-M (3-methylphenyl)methyl-triphenylphosphanium;chloride Chemical compound [Cl-].CC1=CC=CC(C[P+](C=2C=CC=CC=2)(C=2C=CC=CC=2)C=2C=CC=CC=2)=C1 BNGXYYYYKUGPPF-UHFFFAOYSA-M 0.000 description 1
- 235000018185 Betula X alpestris Nutrition 0.000 description 1
- 235000018212 Betula X uliginosa Nutrition 0.000 description 1
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 1
- 239000004890 Hydrophobing Agent Substances 0.000 description 1
- 229910020284 Na2SO4.10H2O Inorganic materials 0.000 description 1
- BPQQTUXANYXVAA-UHFFFAOYSA-N Orthosilicate Chemical compound [O-][Si]([O-])([O-])[O-] BPQQTUXANYXVAA-UHFFFAOYSA-N 0.000 description 1
- 235000008331 Pinus X rigitaeda Nutrition 0.000 description 1
- 235000011613 Pinus brutia Nutrition 0.000 description 1
- 241000018646 Pinus brutia Species 0.000 description 1
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 1
- 238000013019 agitation Methods 0.000 description 1
- 239000003513 alkali Substances 0.000 description 1
- AZDRQVAHHNSJOQ-UHFFFAOYSA-N alumane Chemical class [AlH3] AZDRQVAHHNSJOQ-UHFFFAOYSA-N 0.000 description 1
- 150000004645 aluminates Chemical class 0.000 description 1
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 1
- AMVQGJHFDJVOOB-UHFFFAOYSA-H aluminium sulfate octadecahydrate Chemical compound O.O.O.O.O.O.O.O.O.O.O.O.O.O.O.O.O.O.[Al+3].[Al+3].[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O AMVQGJHFDJVOOB-UHFFFAOYSA-H 0.000 description 1
- ZEMWIYASLJTEHQ-UHFFFAOYSA-J aluminum;sodium;disulfate;dodecahydrate Chemical compound O.O.O.O.O.O.O.O.O.O.O.O.[Na+].[Al+3].[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O ZEMWIYASLJTEHQ-UHFFFAOYSA-J 0.000 description 1
- QGZKDVFQNNGYKY-UHFFFAOYSA-O ammonium group Chemical group [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 description 1
- BFNBIHQBYMNNAN-UHFFFAOYSA-N ammonium sulfate Chemical compound N.N.OS(O)(=O)=O BFNBIHQBYMNNAN-UHFFFAOYSA-N 0.000 description 1
- 229910052921 ammonium sulfate Inorganic materials 0.000 description 1
- 239000001166 ammonium sulphate Substances 0.000 description 1
- 235000011130 ammonium sulphate Nutrition 0.000 description 1
- 229910021538 borax Inorganic materials 0.000 description 1
- 239000001569 carbon dioxide Substances 0.000 description 1
- 229910002092 carbon dioxide Inorganic materials 0.000 description 1
- 229920001429 chelating resin Polymers 0.000 description 1
- 150000001805 chlorine compounds Chemical class 0.000 description 1
- 239000000084 colloidal system Substances 0.000 description 1
- 229910052593 corundum Inorganic materials 0.000 description 1
- 238000004132 cross linking Methods 0.000 description 1
- 230000003247 decreasing effect Effects 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 238000005265 energy consumption Methods 0.000 description 1
- 238000011156 evaluation Methods 0.000 description 1
- 239000010419 fine particle Substances 0.000 description 1
- 239000011121 hardwood Substances 0.000 description 1
- 230000001771 impaired effect Effects 0.000 description 1
- 239000003999 initiator Substances 0.000 description 1
- 230000003993 interaction Effects 0.000 description 1
- 229920005610 lignin Polymers 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 238000006386 neutralization reaction Methods 0.000 description 1
- 150000007524 organic acids Chemical class 0.000 description 1
- 235000005985 organic acids Nutrition 0.000 description 1
- 239000011368 organic material Substances 0.000 description 1
- 235000006408 oxalic acid Nutrition 0.000 description 1
- 239000011087 paperboard Substances 0.000 description 1
- 230000008092 positive effect Effects 0.000 description 1
- 229910052700 potassium Inorganic materials 0.000 description 1
- 239000011591 potassium Substances 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 229910001388 sodium aluminate Inorganic materials 0.000 description 1
- RSIJVJUOQBWMIM-UHFFFAOYSA-L sodium sulfate decahydrate Chemical compound O.O.O.O.O.O.O.O.O.O.[Na+].[Na+].[O-]S([O-])(=O)=O RSIJVJUOQBWMIM-UHFFFAOYSA-L 0.000 description 1
- 235000010339 sodium tetraborate Nutrition 0.000 description 1
- 239000011122 softwood Substances 0.000 description 1
- LSNNMFCWUKXFEE-UHFFFAOYSA-L sulfite Chemical compound [O-]S([O-])=O LSNNMFCWUKXFEE-UHFFFAOYSA-L 0.000 description 1
- 150000003467 sulfuric acid derivatives Chemical class 0.000 description 1
- 239000001117 sulphuric acid Substances 0.000 description 1
- 235000011149 sulphuric acid Nutrition 0.000 description 1
- 230000002195 synergetic effect Effects 0.000 description 1
- BSVBQGMMJUBVOD-UHFFFAOYSA-N trisodium borate Chemical compound [Na+].[Na+].[Na+].[O-]B([O-])[O-] BSVBQGMMJUBVOD-UHFFFAOYSA-N 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
- 229910001845 yogo sapphire Inorganic materials 0.000 description 1
Classifications
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H17/00—Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
- D21H17/20—Macromolecular organic compounds
- D21H17/21—Macromolecular organic compounds of natural origin; Derivatives thereof
- D21H17/24—Polysaccharides
- D21H17/28—Starch
- D21H17/29—Starch cationic
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H17/00—Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H17/00—Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
- D21H17/20—Macromolecular organic compounds
- D21H17/33—Synthetic macromolecular compounds
- D21H17/34—Synthetic macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- D21H17/37—Polymers of unsaturated acids or derivatives thereof, e.g. polyacrylates
- D21H17/375—Poly(meth)acrylamide
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H17/00—Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
- D21H17/63—Inorganic compounds
- D21H17/67—Water-insoluble compounds, e.g. fillers, pigments
- D21H17/68—Water-insoluble compounds, e.g. fillers, pigments siliceous, e.g. clays
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H21/00—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties
- D21H21/06—Paper forming aids
- D21H21/10—Retention agents or drainage improvers
Definitions
- the polymeric silicic acid was prepared from water glass (Na2O.3.3SiO2) which was diluted with water to an SiO2 content of 5 per cent by weight.
- the aqueous solution was ion exchanged with ion exchange resin Amberlite IR-120 to a pH of 2.3.
- the specific surface area of the obtained acid polymeric silicic acid was measured by titration according to the method given earlier and was found to be 1450 m2/g.
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Dispersion Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Paper (AREA)
- Polarising Elements (AREA)
Claims (9)
- Verfahren zur Herstellung von Papier aus einer Cellulosefasern enthaltenden Suspension und gegebenenfalls Füllstoffen, wobei ein kationisches Polymer und eine anionische, anorganische Substanz zu der Suspension zugegeben werden und die Suspension auf einem Drahtnetz geformt und entwässert wird, dadurch gekennzeichnet, daß ein kationisches Polyacrylamid, eine kationische Stärke und eine Polykieselsäure mit einer spezifischen Oberfläche von mindestens 1050 m²/g zu der Fasersuspension zugegeben wird.
- Verfahren nach Anspruch 1, dadurch gekennzeichnet, daß die Polykieselsäure eine spezifische Oberfläche im Bereich von 1100 bis 1700 m²/g hat.
- Verfahren nach Anspruch 1 oder 2, dadurch gekennzeichnet, daß die Polykieselsäure durch Ansäuern eines Alkalimetallwasserglases auf einen pH-Wert im Bereich von 1,5 bis 4 hergestellt wurde.
- Verfahren nach Anspruch 1, 2 oder 3, dadurch gekennzeichnet, daß die Polykieselsäure durch Ansäuern unter Verwendung eines sauren Kationenaustauschers hergestellt wurde.
- Verfahren nach einem der vorstehenden Ansprüche, dadurch gekennzeichnet, daß die Polykieselsäure in einer Menge von mindestens 0,01 g/kg (kg/t), berechnet als SiO₂ auf der Basis der trockenen Fasern, gegebenenfalls Füllmaterialien, zugefügt wird.
- Verfahren nach Anspruch 1, dadurch gekennzeichnet, daß das Gewichtsverhältnis der kationischen Stärke und des kationischen Polyacrylamids zu der Polykieselsäure, berechnet als SiO₂ größer als 0,1:1 ist.
- Verfahren nach Anspruch 1, dadurch gekennzeichnet, daß das Gewichtsverhältnis der kationischen Stärke zu dem kationischen Polyacrylamid im Bereich von 0,5:1 bis 200:1 liegt.
- Verfahren nach Anspruch 1, dadurch gekennzeichnet, daß die kationische Stärke vor dem kationischen Polyacrylamid und der Polykieselsäure zu der Fasersuspension zugefügt wird.
- Verfahren nach einem der vorstehenden Ansprüche, dadurch gekennzeichnet, daß der Fasergehalt der Suspension mindestens 25 Gew.-% Fasern aus mechanischer Pulpe und/oder Pulpe von wiederverwerteten Fasern umfaßt.
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
SE8903752A SE8903752D0 (sv) | 1989-11-09 | 1989-11-09 | Foerfarande foer framstaellning av papper |
SE8903752 | 1989-11-09 |
Publications (2)
Publication Number | Publication Date |
---|---|
EP0500770A1 EP0500770A1 (de) | 1992-09-02 |
EP0500770B1 true EP0500770B1 (de) | 1993-09-08 |
Family
ID=20377424
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP91900405A Expired - Lifetime EP0500770B1 (de) | 1989-11-09 | 1990-10-24 | Verfahren zur herstellung von papier |
Country Status (10)
Country | Link |
---|---|
EP (1) | EP0500770B1 (de) |
JP (1) | JPH04505351A (de) |
AT (1) | ATE94231T1 (de) |
AU (1) | AU637850B2 (de) |
CA (1) | CA2069308C (de) |
DE (1) | DE69003249T2 (de) |
ES (1) | ES2046040T3 (de) |
FI (1) | FI100611B (de) |
SE (1) | SE8903752D0 (de) |
WO (1) | WO1991007543A1 (de) |
Families Citing this family (21)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CA2108027C (en) * | 1991-07-02 | 1997-05-27 | Bruno Carre | A process for the production of paper |
BR9205973A (pt) * | 1991-07-02 | 1994-08-02 | Eka Nobel Ab | Processo para a fabricação de papel |
FI920246A0 (fi) * | 1992-01-20 | 1992-01-20 | Kemira Oy | Foerfarande foer tillverkning av papper. |
US5695609A (en) * | 1992-01-20 | 1997-12-09 | Kemira Oy | Process for producing paper |
US5571494A (en) * | 1995-01-20 | 1996-11-05 | J. M. Huber Corporation | Temperature-activated polysilicic acids |
US6033525A (en) * | 1997-10-30 | 2000-03-07 | Moffett; Robert Harvey | Modified cationic starch composition for removing particles from aqueous dispersions |
US5859128A (en) * | 1997-10-30 | 1999-01-12 | E. I. Du Pont De Nemours And Company | Modified cationic starch composition for removing particles from aqueous dispersions |
US5928474A (en) * | 1997-10-30 | 1999-07-27 | E. I. Du Pont De Nemours And Company | Modified starch composition for removing particles from aqueous dispersions |
DE19832241A1 (de) * | 1998-07-17 | 2000-01-27 | Stockhausen Chem Fab Gmbh | Verwendung von modifizierten Stärkeprodukten als Retentionsmittel bei der Papierherstellung |
US6083997A (en) * | 1998-07-28 | 2000-07-04 | Nalco Chemical Company | Preparation of anionic nanocomposites and their use as retention and drainage aids in papermaking |
CN1377436A (zh) * | 1999-10-19 | 2002-10-30 | 韦尔豪泽公司 | 阳离子改性的多糖 |
US6699363B2 (en) | 2001-11-13 | 2004-03-02 | E. I. Du Pont De Nemours And Company | Modified starch and process therefor |
US7955473B2 (en) | 2004-12-22 | 2011-06-07 | Akzo Nobel N.V. | Process for the production of paper |
US20060254464A1 (en) | 2005-05-16 | 2006-11-16 | Akzo Nobel N.V. | Process for the production of paper |
PT1969183E (pt) * | 2005-12-30 | 2015-03-06 | Akzo Nobel Nv | Processo para a produção de papel |
US8273216B2 (en) | 2005-12-30 | 2012-09-25 | Akzo Nobel N.V. | Process for the production of paper |
JP2010528196A (ja) * | 2007-05-23 | 2010-08-19 | アクゾ ノーベル ナムローゼ フェンノートシャップ | セルロース系製造物の製造方法 |
EP2711347A1 (de) * | 2012-09-21 | 2014-03-26 | HeidelbergCement AG | Verfahren und Mittel zur Aufbereitung von Gesteinskörnungen |
FR2998563B1 (fr) | 2012-11-28 | 2014-12-19 | Roquette Freres | Procede d'epaississement ou de deshydratation de boues |
DE102022103082A1 (de) | 2022-02-09 | 2023-08-10 | Jan Reijnvaan | Palettenblöcke und Paletten |
DE102022103081A1 (de) | 2022-02-09 | 2023-08-10 | Jan Reijnvaan | Paletten |
Family Cites Families (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPH0663197B2 (ja) * | 1985-11-07 | 1994-08-17 | 三菱製紙株式会社 | 中性紙の製紙方法 |
GB8621680D0 (en) * | 1986-09-09 | 1986-10-15 | Du Pont | Filler compositions |
-
1989
- 1989-11-09 SE SE8903752A patent/SE8903752D0/xx unknown
-
1990
- 1990-10-24 CA CA002069308A patent/CA2069308C/en not_active Expired - Lifetime
- 1990-10-24 AU AU67328/90A patent/AU637850B2/en not_active Expired
- 1990-10-24 DE DE91900405T patent/DE69003249T2/de not_active Expired - Lifetime
- 1990-10-24 ES ES91900405T patent/ES2046040T3/es not_active Expired - Lifetime
- 1990-10-24 AT AT91900405T patent/ATE94231T1/de not_active IP Right Cessation
- 1990-10-24 JP JP2515828A patent/JPH04505351A/ja active Pending
- 1990-10-24 EP EP91900405A patent/EP0500770B1/de not_active Expired - Lifetime
- 1990-10-24 WO PCT/SE1990/000688 patent/WO1991007543A1/en active IP Right Grant
-
1992
- 1992-05-06 FI FI922055A patent/FI100611B/fi active
Also Published As
Publication number | Publication date |
---|---|
FI100611B (fi) | 1998-01-15 |
CA2069308C (en) | 1996-01-30 |
DE69003249T2 (de) | 1994-03-31 |
ATE94231T1 (de) | 1993-09-15 |
EP0500770A1 (de) | 1992-09-02 |
AU6732890A (en) | 1991-06-13 |
FI922055A0 (fi) | 1992-05-06 |
JPH04505351A (ja) | 1992-09-17 |
FI922055A (fi) | 1992-05-06 |
WO1991007543A1 (en) | 1991-05-30 |
SE8903752D0 (sv) | 1989-11-09 |
ES2046040T3 (es) | 1994-01-16 |
DE69003249D1 (de) | 1993-10-14 |
AU637850B2 (en) | 1993-06-10 |
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