EP0461641A2 - Zusammensetzungen und Verfahren zur Herstellung von lösungsmittelbeständigen Verbindern - Google Patents

Zusammensetzungen und Verfahren zur Herstellung von lösungsmittelbeständigen Verbindern Download PDF

Info

Publication number
EP0461641A2
EP0461641A2 EP91109659A EP91109659A EP0461641A2 EP 0461641 A2 EP0461641 A2 EP 0461641A2 EP 91109659 A EP91109659 A EP 91109659A EP 91109659 A EP91109659 A EP 91109659A EP 0461641 A2 EP0461641 A2 EP 0461641A2
Authority
EP
European Patent Office
Prior art keywords
weight
parts
amount
front insulator
mixture
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Withdrawn
Application number
EP91109659A
Other languages
English (en)
French (fr)
Other versions
EP0461641A3 (de
Inventor
Sal Abtahi
Robert Wilson Sherman
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
MATRIX SCIENCE CORP
Original Assignee
MATRIX SCIENCE CORP
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by MATRIX SCIENCE CORP filed Critical MATRIX SCIENCE CORP
Publication of EP0461641A2 publication Critical patent/EP0461641A2/de
Publication of EP0461641A3 publication Critical patent/EP0461641A3/xx
Withdrawn legal-status Critical Current

Links

Images

Classifications

    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01B—CABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
    • H01B3/00—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties
    • H01B3/18—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances
    • H01B3/28—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances natural or synthetic rubbers
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01R—ELECTRICALLY-CONDUCTIVE CONNECTIONS; STRUCTURAL ASSOCIATIONS OF A PLURALITY OF MUTUALLY-INSULATED ELECTRICAL CONNECTING ELEMENTS; COUPLING DEVICES; CURRENT COLLECTORS
    • H01R13/00—Details of coupling devices of the kinds covered by groups H01R12/70 or H01R24/00 - H01R33/00
    • H01R13/46—Bases; Cases
    • H01R13/533—Bases, cases made for use in extreme conditions, e.g. high temperature, radiation, vibration, corrosive environment, pressure
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01R—ELECTRICALLY-CONDUCTIVE CONNECTIONS; STRUCTURAL ASSOCIATIONS OF A PLURALITY OF MUTUALLY-INSULATED ELECTRICAL CONNECTING ELEMENTS; COUPLING DEVICES; CURRENT COLLECTORS
    • H01R13/00—Details of coupling devices of the kinds covered by groups H01R12/70 or H01R24/00 - H01R33/00
    • H01R13/46—Bases; Cases
    • H01R13/502—Bases; Cases composed of different pieces
    • H01R13/504—Bases; Cases composed of different pieces different pieces being moulded, cemented, welded, e.g. ultrasonic, or swaged together

Definitions

  • the present invention relates to chemical-stabile compositions useful for fabricating connectors resistant to solvents commonly used in aircraft operation in both military and commercial applications, connectors fabricated from such compositions, and processes used to fabricate such connectors.
  • fluids such as for example, hydraulic fluids, lubricating oils and the like are used in the aircraft industry.
  • Such fluids may be based on products such as petroleum or may have a synthetic base.
  • Concomitantly the chemical reactivity of the petroleum or synthetic based fluids with materials used to make connectors and the like must be resistant or substantially inert to the fluids that may come in contact with the connectors to ensure the connector will function properly and suitable for the purpose intended.
  • the present aviation specifications approved for use by all departments and agencies of the U.S. Department of Defense for electrical connectors include requirements for environmental tests.
  • the present military standards require electrical connectors to be resistant to petroleum based aviation hydraulic fluids for use in temperatures -54°C to 135°C (65°F to 275°F) and synthetic based lubricating oils for aircraft turbine engines.
  • Some commercial aviation specifications require connectors to be resistant to synthetic based aviation hydraulic fluids.
  • military applications is to be understood to include those aviation specifications requiring resistance to petroleum based aviation hydraulic fluids.
  • commercial applications is understood to include those aviation specifications requiring resistance to synthetic based aviation hydraulic fluids.
  • the term "connectors” means electrical connectors commonly used in the environment of aircraft operation and generally exposed to a variety of temperatures and corrosive solvents. Specifically, the connectors include those environment resisting, quick disconnect, miniature, circular electrical connectors and may contain hermetic receptacles.
  • solvent means solvents commonly used in aircraft operation, in both military and commercial applications.
  • solvent is also understood to mean herein.
  • resistant as used with reference to compositions and connectors means the ability to resist swelling when subjected to solvent under the Solvent Resistant Test described below.
  • compositions and connectors are resistant to hydraulic fluids having a petroleum base as well as aviation hydraulic fluids having a synthetic phosphate ester base. Additionally the connectors must be resistant to fluids encountered in jet aircraft operation including, inter alia , aircraft turbine engine lubricating oils having a synthetic base. The purpose of the test is to identify compositions and connectors having durable and lasting resistance to those solvents normally used in aircraft operation that causes swelling to the connectors and prevent it from proper functioning.
  • Electrical connectors and their coupling assemblies find wide use in military and commercial applications. Such connectors are designed to operate in extreme environmental conditions such as extreme temperature and a variety of corrosive solvents used in high altitude flight. The connectors are sealed to withstand such conditions as moisture condensation, corona, flashover and vibrations, providing a completely environmentally resistant assembly when the connector's plug and receptacle assembly halves are mated.
  • the present invention provides chemical-stabile compositions useful for fabricating connectors resistant to solvents commonly used in aircraft operation in both military and commercial applications.
  • the present invention specifically provides chemical-stabile compositions useful for fabricating connectors resistant to hydraulic fluids having either a petroleum or synthetic base and lubricating oils having either petroleum or synthetic base.
  • the present invention provides compositions useful for fabricating the grommets of both the plug and the receptacle inserts of the connector resistant to solvents and has a Shore A hardness of about 50-60 wherein the composition comprises a mixture of halogenated polyolefins and/or olefins, and activator, a release agent, a plasticizer, preferably a vulcanizer, preferably a cross-linking agent, preferably a filler, preferably a colorant or optionally a whitener.
  • the present invention also provides novel compositions useful for fabricating the socket of the plug insert of the connector, resistant to solvents and with a Shore A hardness of about 65-75 wherein the composition comprises a mixture of halogenated polyolefins and/or olefins, an activator, a release agent, a plasticizer, a vulcanizer, a cross-linking agent, preferably a filler, preferably a colorant or optionally a whitener.
  • the present invention also provides novel compositions useful for fabricating the socket of the receptacle insert of the connector resistant to solvents and with a Shore A hardness of about 65-75 wherein the composition comprises a mixture of halogenated olefins and/or olefins, an accelerator, a vulcanizer, a release agent, a processing aid agent, preferably a filler, preferably a colorant or optionally a whitener.
  • the present invention further provides connectors resistant to solvents commonly used in military and commercial aircraft operation, wherein the compositions of the grommets and sockets of the connectors are as described above.
  • the present invention provides a method of fabricating connectors as described above, wherein during the fabricating process, the material does not stick to the mold. Also having good hot tear-strength, the demolding capability of this material is outstanding.
  • FIGS. 1 and 2 show a connector assembly which are used in both military and commercial applications.
  • the connector assembly comprises a plug assembly 10 and a receptacle shell 100 that is coupled and disengaged by twisting the plug assembly 10 along a helical pathway X around the receptacle shell 100 by means of a coupling system, preferably of the bayonet type or which can be of the threaded type.
  • the receptacle shell 100 is integral with a receptacle plate 102 for mounting on an instrument control panel or other wall mounting.
  • Three fixed bayonet pins 104 extend radially outward from the outer surface 106 of the receptacle shell 100.
  • a receptacle insert assembly 108 is then bonded to the receptacle shell 100.
  • the bonding can be performed by any conventional method, but preferably by means of epoxy bonding.
  • the plug assembly 10 is provided with a coupling nut subassembly 11 on the front and a plug insert assembly 30 is bonded to the plug assembly 10.
  • the connector plug shell 10 is polarized to align in a preferred orientation within the inner surface of the receptacle shell 100 as shown in Figures 1 and 2.
  • the receptacle insert 108 is shown to have a 3-ply sandwich construction with a socket front insulator 112, a center hard dielectric insert subassembly socket 114 with contact retaining clip 115 and a back resilient grommet 116 and strain relief clamp (not shown).
  • the socket front insulator 112 is shown to have socket contact 118 positioned in the front end thereof.
  • the front end of the socket contact extends forward from the front surface of the inner resilient insert.
  • a conductor 120 which normally is soldered or crimped to the socket 118, extends rearwardly in the insulator 112. While only one socket contact 118 and one conductor 120 are shown, it should be understood, of course, that a plurality of sockets and associated conductors are normally mounted in the insulator 112.
  • the plug insert 30 adapted to be mated with the receptacle insert 108 is shown to have a similar 3-ply sandwich construction with a pin front insulator 32, a center hard dielectric pin insert subassembly 34 with contact retaining clip 35 and a back resilient grommet 36.
  • the pin front insulator 32 is shown to have a pin contact 38 at the front end with a forwardly extending portion adapted to be mated with the socket contact 118.
  • a conductor 40 which may be soldered or crimped to the pin contact 38, is positioned in the rear of the pin front insulator 34.
  • the pin contact 38 is inserted in the socket contact 118.
  • the receptacle shell 100 is positioned between the outer surface of the plug assembly 10 and the coupling nut subassembly 11. The coupling nut 11 is rotated so that the apertures engage the bayonet pins 104 in the outer surface of the receptacle shell 100.
  • the same composition is used for both the grommets of the insert for the receptacle shell and the plug assembly of the connector.
  • the halogenated polyolefins used in the grommet composition may be of any type, but is preferably of the non-reactive type and preferably has, as halogens, chlorine.
  • exemplary halogenated polyolefin compounds include TYRINETM chlorinated polyethylene elastomers, such as TYRINETM 566 sold by the Dow Chemical Company, Specialty Plastics Department, Midland, Michigan.
  • the halogenated polyolefins may be used alone in the composition or as a mixture with other compounds, such as a different halogenated polyolefin or olefins.
  • Olefins used in the grommet composition can be of any type, but is preferably of the ethylene-propylene type, such as the commercially available DPSYN 40A base rubber terpolymer sold by Copolymer Rubber Corporation, Baton Rouge, Louisiana.
  • activators/stabilizers appropriate to promote and stabilize the curing of the present grommet compositions may be used.
  • activators/stabilizers include lead oxide, sold as T(HRL) D90 available commercially from Rhein Chemi, Trenton, New Jersey.
  • Other lead compounds such as basic silicate of white lead, litharge, and red lead, and magnesium oxide or hydroxide may be used.
  • the grommet compositions are preferably filled, and more preferably contain loadings of about 30-100 parts of filler per hundred parts of halogenated polyolefin/olefin mixtures.
  • the filler may comprise one or more of the several conventional fillers such as clays, calcium carbonates, and silicas.
  • filled grommet compositions wherein the filler is predominantly mistron vapor (MV TALC), a magnesium silicate filler sold by Cyprus Industrial Minerals Corporation, Englewood, Colorado.
  • MV TALC mistron vapor
  • Other fillers are preferably employed in lesser amounts in combination with MV TALC as the filler.
  • grommet compositions of the present invention also contain a colorant such as carbon black, pigments, dyes and the like. Colorants such as red or yellow iron oxide are preferable.
  • grommet compositions also may include a cross-linking or vulcanization agent, and especially commercial peroxides including dicumyl peroxide, ⁇ , ⁇ -bis (t-butyl peroxy), di-isopropyl benzene, and butyl-4-4-bis (t-butyl peroxy) valerate.
  • a co-agent such as triallyl trimellitate, triallylcyanurate, triallylisocyanurate and trimethylolpropane trimethylacrylate, is preferably being used with the peroxide to improve modulus, to increase the rate of curing, and to increase crosslinking density.
  • the plasticizers used in the grommet composition may be of any type, but is preferably of the liquid plasticization materials common to the rubber industry including esters, epoxidized soybean oils and chlorinated paraffins.
  • Exemplary of plasticizers are di-isonono phthalate, di-ethylhexyl adipate or the like.
  • Mold release agents that is, lubricants
  • lubricants are generally included in the grommet compositions of the present invention.
  • exemplary are carnauba wax, montanic acid ester wax, polyethylene wax, polytetrafluoroethylene wax, glycerol monostearate, calcium, zinc and other metallic stearates, paraffin waxes and the like.
  • Grommet compositions of the present invention may be prepared by any conventional method.
  • the ingredients may be readily processed either in internal mixers of the Banbury type or on two-roll mills.
  • Banbury mixing with an up-side down mixing procedure is used.
  • the ingredients (or any portion of them) may be prepared in a dry, discrete-particle, crumb form, fed directly into a compounding devices such as an extruder or prepared as a premix of raw materials. If less than all of the ingredients are present in the initial form, the remainder of the ingredients can be added prior to or during densification.
  • Densification can be by mechanical compacting (with, for example, a performer or a combining mill) in the case of a fine powder, and can be an extruder or differential roll mill in the case of fine powders, direct feed or premix.
  • These compositions may be molded into various connectors by application of the requisite temperature and pressure.
  • molding conditions for the connector grommet of the present invention may range from about 300-400° F, for a total cycle time, including cure time, injection time and cleaning time, ranging from about 1-20 minutes, preferably 2-15 minutes depending on the size of the connector to be molded.
  • Any suitable molding apparatus may be employed, such as a compression or injection molding machine equipped with the appropriate mold.
  • the ratio between the various ingredients may vary widely.
  • all parts by weight of the ingredients are in reference to the total weight of the halogenated polyolefin/olefin elastomer component (i.e. the total weight of the halogenated polyolefin/olefin is taken to by 100 parts by weight) used in the composition.
  • the ratio of the weight of the halogenated polyolefin to the weight of the olefin used will be between about 3 - 7, preferably between about 3.5 - 5.
  • activators/stabilizers are generally applied at levels sufficient to provide processing stability and improve long-term high heat exposure of the grommet molding composition under anticipated molding conditions. Generally, amounts between about 25 - 35 parts by weight are sufficient, preferably about 30 parts by weight.
  • the total amount of filler used may vary from 0 up to about 50 parts by weight.
  • the filler comprises a total of between about 20 - 45 parts by weight and preferably between about 30 - 40 parts by weight.
  • a silica filler such as MV TALC.
  • Colorants if employed, are generally in amounts sufficient to give connectors the desired color which in many cases is brown.
  • cross-linking or vulcanization agent is generally applied at levels sufficient to cross-link or vulcanize the grommet molding composition under anticipated molding conditions. Usually amount between about 1 - 10 parts by weight. Preferably, the cross-linking or vulcanization agent is applied at about 2 - 5 parts by weight.
  • the plasticizer used is generally in an amount sufficient to give the desired plasticizing efficiency and performance under anticipated molding conditions. Usually amounts between about 35 - 70 parts by weight are sufficient. Preferably, the plasticizer is applied at about 45 - 65 parts by weight.
  • the mold release agent will be used in amounts sufficient to give good release from the mold.
  • Lubricant proportions between about 5 - 15 parts by weight, preferably between about 8 - 12 parts by weight, can be employed.
  • a composition similar to that used in the grommets of both the receptacle shell insert and the plug assembly insert of the connector is used for the pin front insulator of the plug assembly insert.
  • the critical difference is that a lower parts by weight, preferably less than 30 parts, of plasticizer is used in the pin front insulator composition so that the pin front insulator of the plug assembly insert has a hardness of 70 Shore A for better mating with the socket front insulator of the receptacle insert.
  • the present invention also relates to compositions useful for fabricating the socket front insulator of the receptacle insert for the connectors resistant to solvents commonly used in aircraft operation in both military and commercial applications.
  • the halogenated polyolefin/olefin copolymer used in the composition of the socket front insulator of the receptacle insert may be of any type, but is preferably of the non-reactive type and preferably the polyolefin has, as halogens, fluorine.
  • Exemplary halogenated polyolefin/olefin copolymers include the AFLASTM FA 100S or FA150E sold by the 3M Industrial Chemical Products Division, St. Paul, Minnesota.
  • the halogenated polyolefins/olefin copolymer may be used alone in the composition or as a mixture with other compounds, such as another halogenated polyolefin/olefin copolymer.
  • Olefins used in the composition of the socket front insulator of the receptacle insert can be of any type, but is preferably of the ethylene propylene type, such as the commercially available TRILENETM 65 base liquid polymer sold by Uniroyal Chemical Division of Uniroyal Incorporated, Nanagatuck, Connecticut.
  • cross-linking or vulcanization agents appropriate to promote and stabilize the curing of the compositions of the present socket front insulator of the receptacle insert may be used.
  • Such cross-linking or vulcanization agents include commercial peroxides such as dicumyl peroxide, ⁇ , ⁇ -bis (t-butyl peroxy) di-isopropyl benzene, and butyl-4-4-bis (t-butyl peroxy) valerate.
  • a butylperoxy vulcanizer is used.
  • a co-agent such as triallyltrimellitate, triallylcyanurate, triallylisocyanurate and trimethylolpropane trimethylacrylate, is preferably being used with the peroxide to improve modulus, to increase the rate of curing, and to increase cross-linking density. Most preferably, a triallyl isocyanurate co-agent is used.
  • the compositions of the socket front insulator of the receptacle insert are preferably filled, and more preferably contain loadings of about 20 - 45 parts of filler per hundred parts of halogenated polyolefin/olefin mixtures.
  • the filler may comprise one or more of the several conventional fillers such as clays, calcium carbonates and silicas.
  • filled socket compositions wherein the filler is predominant a fumed silica filler sold commercially as MIN-U-SILTM 5 Micro available from Summit Chemical, Akron, Ohio.
  • compositions for the socket front insulator of the receptacle insert of the present invention also contain a colorant such as carbon black, pigments, dyes and the like. Colorants such as red or yellow iron oxide are preferable.
  • Mold release agents or lubricants are generally included in the compositions for the socket front insulator of the receptacle insert of the present invention.
  • Exemplary are carnauba wax, montanic acid ester wax, polyethylene wax, polytetrafluoroethylene wax, glycerol monostearate, calcium, zinc and other metallic stearates, paraffin waxes and the like.
  • a processing aid/dispersing agent such as low molecular weight olefinic oil sold commercially as SPAN-60TM available from Emulsion Engineering, Wilmington, Delaware and DYNAMARTM PPA-790 available from 3M Industrial Chemical, Products Division can be added to the compositions for the socket front insulator of the receptacle insert to improve flow rates for extrusion or molding applications.
  • compositions for the socket front insulator of the receptacle insert of the present invention may be prepared by any conventional method.
  • the ingredients may be readily processed like any other rubber part by compression, transfer or injection molding. Compositions are mixed on open mills or internal mixers. More generally, the ingredients (or any portion of them) may be prepared in a dry, discrete-particle, crumb form, fed directly into a compounding devices such as an extruder or prepared as a premix of raw materials. If less than all of the ingredients are present in the initial form, the remainder of the ingredients can be added prior to or during densification.
  • Densification can be by mechanical compacting (with for example a performer or a combining mill) in the case of a fine powder, and can be by an extruder or differential roll mill in the case of fine powders, direct feed or premix.
  • These compositions may be molded into various socket front insulators of the receptacle insert by application of the requisite temperature and pressure.
  • molding conditions for the connector socket front insulator of the receptacle insert of the present invention may range from about 300 - 450° F, preferably about 340 - 360°, for a total cycle time ranging from about 1 - 20 minutes, preferably 2 - 15 minutes, depending upon the size of the connector to be molded.
  • Any suitable molding apparatus may be employed, such as a compression or injection molding machine equipped with the appropriate mold.
  • the ratio between the various ingredients may vary widely.
  • a mixture of halogenated polyolefin such as AFLASTM FA100S and F150E available from 3M Industrial Chemical Products Division.
  • the ratio of FA100S to FA150E used may range from about 0.2 - 2, preferably from about 0.7 - 1.5.
  • the weight of the total halogenated polyolefin to the weight of the olefin used will be between about 5 and 25, preferably between about 10 - 20.
  • stabilizers are generally applied at levels sufficient to provide processing stability and improve long-term high heat exposure of the socket molding composition under anticipated molding conditions. Generally, amounts between about 0.1 - 10 parts by weight are sufficient.
  • the total amount of filler used may vary from 0 up to about 50 parts by weight.
  • the filler comprises a total of between about 20 - 45 parts by weight.
  • between about 20 - 35 parts by weight is a fumed silica filler.
  • Colorants if employed, are generally in amounts sufficient to give connectors the desired color which in many cases is brown.
  • cross-linking or vulcanization agent is generally applied at levels sufficient to cross-link or vulcanize the socket molding composition under anticipated molding conditions, usually an amount between about 1 - 10 parts by weight.
  • the cross-linking or vulcanization agent is applied at about 2 - 5 parts by weight.
  • the processing aid used is generally in an amount sufficient to give the desired flow rates for extrusion and performance under anticipated molding conditions. Usually amounts between about 0.1 - 5 parts by weight are sufficient.
  • the mold release agent will be used in amounts sufficient to give good release from the mold.
  • Lubricant proportions between about 0.1 - 10 parts by weight, preferably between about 0.5 - 2.5 parts by weight, are employed.
  • the present invention is not restricted to the above ingredients but may include other ingredients which do not detract from solvent resistant properties of the compositions of the grommets and sockets of the plug and receptacle inserts of the connector. Accordingly, other halogenated polyolefins, olefins, organic or inorganic materials or the like may be added under the above conditions.
  • the "solvent resistant test” referred to in the following examples of method 2013 of MIL-STD-1344 wherein the connectors the mating numbers are mounted to appropriate fixtures that hold the connector members in their normal manner, the fixtures being movable such that the members may be mated and unmated at a specific rate of movement.
  • the mating members are then brought to a position where mechanical mating begins.
  • the force or torque gage is set at 0, the mating connector members are fully mated at the rate specified and the force recorded.
  • the force is again measured as the connector members are unmated at the specified rate. Samples of the unmated connectors are then immersed fully in the respective fluids specified below for 20 hours as required by the specification.
  • the immersion is followed by a one hour drain (air dry at room temperature) and the mating and unmating forces of the plug and receptacle of the connector that had been immersed simultaneously in the fluids tested are then measured again. If the connector's mating and unmating forces fall within the forces as specified, the connector is considered solvent resistant within the meaning of the term as used herein.
  • Grommets compositions for both the plug and the receptacle inserts were prepared from the formulations indicated in Table 1.
  • Formulation 1 is a starting formulation and has molding difficulties due to the absence of a plasticizer, TYRINETM 566 available from Dow Chemical Company.
  • a different type of chlorinated-polyolefin other than TYRINETM 136 is used in Formulation 2.
  • Ethylene-propylene copolymer is added in formulation 3 to improve its chemical resistance.
  • an internal lubricant is added to improve its flow characteristics during molding.
  • Pigment is added to formulation 5 to give the desired color.
  • internal lubricant concentration is increased, but ethylene-propylene copolymer concentration decreased.
  • Formulation 6 gives a good compression molding composition.
  • formulations 7 and 8 the filler MV TALC was replaced by HISIL-233 available from PPG Industries, Chemical Division, Pittsburgh, Pennsylvania, and the amounts of plasticizer increased to 50 and 63 parts, respectively.
  • Formulation 9 gives the best grommet injection molding composition.
  • Formulation 9 is selected as molding material for fabricating the grommets for both the plug and the receptacle inserts.
  • the formulation is compression or injection molded at a temperature of 350° ⁇ 5° and a total cycle time of 2 - 15 minutes depending upon the size of the connector to be molded.
  • the molded grommets have a Shore A hardness of 55.
  • Preferred socket compositions for the insert of the plug with a Shore A hardness of 70 were prepared from the formulations indicated in Table 2.
  • Formulation 10 is a starting socket formulation for the plug insert and has molding difficulties.
  • formulation 11 more plasticizer was added and a finer type of filler is used to improve the flow of the formulation.
  • a different type of chlorinated polyethylene is used in formulation 12 to improve the physical properties of the compositions during the molding process.
  • formulation 13 ethylene-propylene copolymer is added to the composition in order to obtain better chemical resistance.
  • formulations 14 and 15 pigments were added to give formulation a dark brown color, internal lubricant and plasticizer were added for better release and flow properties of the composition during molding.
  • Formulation 15 is selected as molding material for fabricating the socket of the insert of the plug assembly.
  • the formulation is compression molded at a temperature of 350° ⁇ 5° F and for a total cycle time of 2-15 minutes depending upon the size of the connector to be molded.
  • the molded socket of the insert of the plug assembly has a Shore A hardness from about 65 to about 75.
  • Socket compositions for the insert of the receptacle shell having a Shore A hardness of 70 were prepared from formulation indicated in Table 3.
  • Formulations 16-21 contain a fluoroelastomer instead of the chlorinated elastomers as in formulations 10-15.
  • Formulation 16 is a basic formulation and has a low Shore A hardness.
  • Formulation 17 gives a Shore A hardness of 70 but the composition stick to the mold during processing.
  • 2 parts by weight of an internal release agent is added to improve its mold release and flow properties.
  • Dark brown pigment was added to formulation 19 to give its desirable color, but the composition has flow problem during processing.
  • Formulation 20 uses a high strength, medium viscosity fluoroelastomer, but its hot tear properties are inferior.
  • Formulation 21 uses a combination of the fluoroelastomer FA-100S and FA-100E give the best hot tear and molding properties, particularly for compression molding.
  • Formulation 21 is selected as molding material for fabricating the socket of the insert of the receptacle shell.
  • the formulation is compression molded at a temperature of 350° ⁇ 5° F for a total cycle time of 2-15 minutes depending upon the size of the connector to be molded.
  • the molded socket of the insert of the receptacle shell has a Shore A hardness of about 70.

Landscapes

  • Physics & Mathematics (AREA)
  • Spectroscopy & Molecular Physics (AREA)
  • Connector Housings Or Holding Contact Members (AREA)
  • Manufacturing Of Electrical Connectors (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
EP91109659A 1990-06-13 1991-06-12 Zusammensetzungen und Verfahren zur Herstellung von lösungsmittelbeständigen Verbindern Withdrawn EP0461641A2 (de)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US53834690A 1990-06-13 1990-06-13
US538346 1990-06-13

Publications (2)

Publication Number Publication Date
EP0461641A2 true EP0461641A2 (de) 1991-12-18
EP0461641A3 EP0461641A3 (de) 1994-02-09

Family

ID=24146541

Family Applications (1)

Application Number Title Priority Date Filing Date
EP91109659A Withdrawn EP0461641A2 (de) 1990-06-13 1991-06-12 Zusammensetzungen und Verfahren zur Herstellung von lösungsmittelbeständigen Verbindern

Country Status (2)

Country Link
EP (1) EP0461641A2 (de)
JP (1) JPH0722143A (de)

Families Citing this family (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2001339827A (ja) 2000-05-25 2001-12-07 Yazaki Corp グロメットの製造方法及びグロメット
US9860513B2 (en) 2010-02-19 2018-01-02 Thomson Licensing Stereo logo insertion

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3808580A (en) * 1972-12-18 1974-04-30 Matrix Science Corp Self-locking coupling nut for electrical connectors
JPS6060144A (ja) * 1983-09-12 1985-04-06 Nippon Synthetic Chem Ind Co Ltd:The ゴム用加硫剤
EP0170936A2 (de) * 1984-08-08 1986-02-12 Feldmühle Aktiengesellschaft Steuerelement für den Ventiltrieb eines Verbrennungsmotors
EP0342809A2 (de) * 1988-05-20 1989-11-23 Minnesota Mining And Manufacturing Company Bei Zimmertemperatur härtbare Zusammensetzungen zur Bildung von Organofluorosiloxanelastomeren
JPH1014808A (ja) * 1996-07-02 1998-01-20 Kiyo Okudera ポケット付き浴用タオル

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3808580A (en) * 1972-12-18 1974-04-30 Matrix Science Corp Self-locking coupling nut for electrical connectors
JPS6060144A (ja) * 1983-09-12 1985-04-06 Nippon Synthetic Chem Ind Co Ltd:The ゴム用加硫剤
EP0170936A2 (de) * 1984-08-08 1986-02-12 Feldmühle Aktiengesellschaft Steuerelement für den Ventiltrieb eines Verbrennungsmotors
EP0342809A2 (de) * 1988-05-20 1989-11-23 Minnesota Mining And Manufacturing Company Bei Zimmertemperatur härtbare Zusammensetzungen zur Bildung von Organofluorosiloxanelastomeren
JPH1014808A (ja) * 1996-07-02 1998-01-20 Kiyo Okudera ポケット付き浴用タオル

Non-Patent Citations (2)

* Cited by examiner, † Cited by third party
Title
DATABASE WPI Week 8520, Derwent Publications Ltd., London, GB; AN 85-119691 & JP-A-60 060 144 (NIPPON SYNTH CHEM) *
PATENT ABSTRACTS OF JAPAN vol. 13, no. 192 (E-753)1989 & JP-A-10 14 808 ( HITACHI ) *

Also Published As

Publication number Publication date
EP0461641A3 (de) 1994-02-09
JPH0722143A (ja) 1995-01-24

Similar Documents

Publication Publication Date Title
US5080942A (en) High stretch elastomeric pre-stretched tubes
US4197381A (en) Preparation of vulcanizable compositions by extruder mixing
TWI576382B (zh) 熱塑性半導電組成物
US3538028A (en) Vulcanizater of compositions comprising a fluorine-containing copolymer and silicone gum
US11774011B2 (en) Non conductive rubber hose
EP0216866B1 (de) Antistatische zusammensetzung und daraus hergestellte gegenstände
EP0132834A2 (de) Thermoplastische Fluorelastomere enthaltende Zusammensetzung
KR19990071566A (ko) 중합체 조성물
WO1998009808A1 (en) Polymeric compositions for power cables
US4153589A (en) Thermoplastic elastomeric molding composition and articles molded therefrom
EP0461641A2 (de) Zusammensetzungen und Verfahren zur Herstellung von lösungsmittelbeständigen Verbindern
EP1629042A1 (de) Fluorelastomerer kaltschrumpfgegenstand
US4681691A (en) Moldable composition
CA2114552C (en) Moisture resistant thermoset cable jacket
EP0802224A1 (de) Lufvernetzende extrudierbare Zusammensetzung
JP4610856B2 (ja) フッ素ゴム系シール材用組成物及びフッ素ゴム系シール材
CA1147088A (en) Flame retardant polymeric materials
KR930009297B1 (ko) 적층 제품
US4948830A (en) Broad temperature capability elastomer
EP0272071A1 (de) Elastomere Zusammensetzungen
US3244663A (en) High temperature resistant rubber-like composition
Maclachlan Fluorocarbon elastomers: A technical review
EP0638108B1 (de) Felixibles pvc material enthaltend glycidylacrylat mit hoher beständigkeit gegen hitzealterung, sowie verfahren zur herstellung und dessen verwendung
KR20200036673A (ko) 연료전지 냉각호스용 고무 조성물 및 이를 이용한 냉각호스
CN108864518B (zh) 抗静电溴化丁基橡胶/聚丙烯热塑性弹性体及其组合物和制备方法与应用

Legal Events

Date Code Title Description
PUAI Public reference made under article 153(3) epc to a published international application that has entered the european phase

Free format text: ORIGINAL CODE: 0009012

AK Designated contracting states

Kind code of ref document: A2

Designated state(s): DE FR GB IT SE

PUAL Search report despatched

Free format text: ORIGINAL CODE: 0009013

AK Designated contracting states

Kind code of ref document: A3

Designated state(s): DE FR GB IT SE

STAA Information on the status of an ep patent application or granted ep patent

Free format text: STATUS: THE APPLICATION IS DEEMED TO BE WITHDRAWN

18D Application deemed to be withdrawn

Effective date: 19940810