EP0461558B1 - Tintenstrahldruckmittel und dessen Verwendungsverfahren - Google Patents

Tintenstrahldruckmittel und dessen Verwendungsverfahren Download PDF

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Publication number
EP0461558B1
EP0461558B1 EP91109366A EP91109366A EP0461558B1 EP 0461558 B1 EP0461558 B1 EP 0461558B1 EP 91109366 A EP91109366 A EP 91109366A EP 91109366 A EP91109366 A EP 91109366A EP 0461558 B1 EP0461558 B1 EP 0461558B1
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EP
European Patent Office
Prior art keywords
ink
jet recording
recording medium
magnesium carbonate
basic magnesium
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
EP91109366A
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English (en)
French (fr)
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EP0461558A1 (de
Inventor
Tomomi C/O Canon Kabushiki Kaisha Nakatsugawa
Mamoru C/O Canon Kabushiki Kaisha Sakaki
Yutaka C/O Canon Kabushiki Kaisha Kurabayashi
Hiroshi C/O Canon Kabushiki Kaisha Sato
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Canon Inc
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Canon Inc
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Publication date
Priority claimed from JP2150571A external-priority patent/JPH0443068A/ja
Priority claimed from JP2150572A external-priority patent/JP2621098B2/ja
Application filed by Canon Inc filed Critical Canon Inc
Publication of EP0461558A1 publication Critical patent/EP0461558A1/de
Application granted granted Critical
Publication of EP0461558B1 publication Critical patent/EP0461558B1/de
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Expired - Lifetime legal-status Critical Current

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Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
    • B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
    • B41M5/00—Duplicating or marking methods; Sheet materials for use therein
    • B41M5/50—Recording sheets characterised by the coating used to improve ink, dye or pigment receptivity, e.g. for ink-jet or thermal dye transfer recording
    • B41M5/52—Macromolecular coatings
    • B41M5/5218—Macromolecular coatings characterised by inorganic additives, e.g. pigments, clays
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/25—Web or sheet containing structurally defined element or component and including a second component containing structurally defined particles
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/25—Web or sheet containing structurally defined element or component and including a second component containing structurally defined particles
    • Y10T428/258—Alkali metal or alkaline earth metal or compound thereof
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/27—Web or sheet containing structurally defined element or component, the element or component having a specified weight per unit area [e.g., gms/sq cm, lbs/sq ft, etc.]
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/27—Web or sheet containing structurally defined element or component, the element or component having a specified weight per unit area [e.g., gms/sq cm, lbs/sq ft, etc.]
    • Y10T428/273—Web or sheet containing structurally defined element or component, the element or component having a specified weight per unit area [e.g., gms/sq cm, lbs/sq ft, etc.] of coating

Definitions

  • the present invention relates to a recording medium suitable for ink-jet recording, and a method of ink-jet recording employing the recording medium.
  • Non-treated ordinary paper and coated paper having an ink-receiving layer have been conventionally used as recording mediums for ink-jet recording.
  • the non-treated ordinary paper when used for recording with aqueous ink, involves disadvantage that formed images undergo running or feathering, giving neither high density of images nor high resolution of the images.
  • Japanese Patent Application Laid-Open No. 56-148585 describes coated paper comprising ink-absorbing base paper and an ink-receiving layer formed thereon with inorganic porous pigment:
  • Japanese Patent Application Laid-Open No. 61-135785 describes an ink-jet recording medium containing a hydrotalcite compound;
  • Japanese Patent Application Laid-Open No. 61-57380 describes an ink-jet recording medium comprising an ink-receiving layer containing porous inorganic pigment and a slightly soluble magnesium compound.
  • the recording mediums of the prior art as described above have advantages that neither feathering of ink nor fattening of printed letters occurs and high resolution of images can be achieved. These recording mediums, however, do not readily give high image density.
  • silica or alumina having a large specific surface area is employed as described, for example, in Japanese Patent Application Laid-Open No. 59-185690 for the purpose of achieving higher image density, another disadvantage is involved that the recording dye discolors with lapse of time and the recorded image deteriorates under normal environmental conditions, for example, only by posting on an indoor wall.
  • the above described indoor discoloration can be retarded by forming the ink-receiving layer by use of calcium carbonate or kaolin having a small specific surface area, or a hydrotalcite compound as disclosed in Japanese Patent Application Laid-Open No. 61-135785, and the like.
  • the density of the resulting image is low, and feathering or fattening of letters occurs, thus no clear image being given.
  • the fattening of the printed letters can be avoided by adding a cationic polymer having high dye-absorbing power into the ink-receiving layer, but preservability of the recorded images is deteriorated thereby.
  • the conventional coated paper having a thin ink-receiving layer cannot achieve high density of images without feathering of images nor fattening of letters, and cannot avoid white haze and indoor discoloration, not easily satisfying the general requirements for ink jet-recording mediums at the same time.
  • An object of the present invention is to provide an ink-jet recording medium which is free from the disadvantages of prior art discussed above, namely feathering, fattening of letters, white haze, indoor discoloration, and which enables formation of images of high density.
  • Another object of the present invention is to provide a ink-jet recording method employing the above recording medium.
  • an ink-jet recording medium comprising basic magnesium carbonate and a magnesium salt of silicic acid.
  • an ink-jet recording medium comprising a layer containing basic magnesium carbonate and a magnesium salt of silicic acid formed on a support.
  • an ink-jet recording medium comprising basic magnesium carbonate and a magnesium salt of phosphorus oxy-acid.
  • an ink-jet recording medium comprising a layer containing basic magnesium carbonate and a magnesium salt of phosphorus oxy-acid formed on a support.
  • an ink-jet recording method conducted by applying droplets of aqueous ink onto a recording medium, the recording medium comprising basic magnesium carbonate and a magnesium salt of silicic acid.
  • an ink-jet recording method conducted by applying droplets of aqueous ink onto a recording medium, the recording medium comprising a layer containing basic magnesium carbonate and a magnesium salt of silicic acid formed on a support.
  • an ink-jet recording method conducted by applying droplets of aqueous ink onto a recording medium, the ink-jet recording medium comprising basic magnesium carbonate and a magnesium salt of phosphorus oxy-acid.
  • an ink-jet recording method conducted by applying droplets of aqueous ink onto a recording medium, the recording medium comprising a layer containing basic magnesium carbonate and a magnesium salt of phosphorus oxy-acid formed on a support.
  • the magnesium salts of silicic acids employed in the present invention are known substances per se.
  • any substance is useful which has a composition of combination of magnesium oxide with silicon dioxide and water in an arbitrary ratio, including, for example, magnesium orthosilicate (Mg2SiO4), magnesium metasilicate (Mg2SiO3), and further talc, magnesium tetrasilicate (Mg3Si4O11 ⁇ H2O), magnesium trisilicate (2MgO ⁇ 3SiO2 ⁇ nH2O) and the like.
  • the particle diameter of the silicic acid salt is preferably not larger than 7 »m in average diameter, more preferably not large than 12 »m in 90%-diameter, but is not limited thereto. A particle size larger than that specified above is not preferable in view of prevention of white haze of image and prevention of fattening of letters because of presence of non-covered fiber due to insufficiency of coverage of supporting paper.
  • the magnesium salts of phosphorus oxy-acid per se employed in the present invention are known compounds.
  • a particularly preferable one is magnesium phosphate, including an anhydrous salt, tetrahydrate, octahydrate, docosa(22)hydrate, which are all useful in the present invention.
  • the particle diameter of the salt is preferably not larger than 7 »m in average diameter, more preferably not large than 12 »m in 90%-diameter, but is not limited thereto.
  • a particle size larger than that specified above is not preferable in view of prevention of white haze of image and prevention of fattening of letters because of presence of non-covered fiber due to insufficiency of coverage of supporting paper.
  • the basic magnesium carbonate which is combinedly used with the magnesium salt of silicic acid or the magnesium salt of phosphorus oxy-acid is not specially limited. Among them, spherical basic magnesium carbonate having shapes disclosed in Japanese Patent Application Laid-Open Nos. 60-54915, 61-63526, and 63-89418 is desirable, but the preparative method is not limited to those described therein.
  • spherical in the present invention is referred to about the shape of agglomeration of primary particles, and the particles are not necessarily in a precisely sphere form.
  • the preferable spherical shape herein has the major axis "a” and the minor axis "b” in the ratio within the range of 0.7 ⁇ b/a ⁇ 1.0 .
  • spherical basic magnesium carbonate precisely spherical shape is not always achievable depending on the reaction conditions varied to adjust the particle diameter, the specific surface area, the oil absorption ability, and other pigment properties.
  • agglomeration is in a partially defective spherical shape or a petal-shape agglomeration.
  • those in a defective spherical shape having the lacking portion of not more than 1/4 of the total imaginary sphere is included in the spherical shape.
  • the average particle diameter of the basic magnesium carbonate is preferably in the range of from 0.5 to 20 »m, more preferably from 1 to 12 »m.
  • the above range is preferable in the aspects of improvement in ink absorbing ability and prevention of powder-falling off and additionally, in the aspects of slurry application property and printing property.
  • An excessively large number of larger particles causes decrease of dispersibility to cause formation of big coagulum, giving adverse effect in coating suitability or printing suitability, and is undesirable.
  • a preferable support employed in the present invention is a base paper sheet having ink-absorbing property, but is not limited thereto.
  • the support may be a polymer film such as a polyester film.
  • base paper having ink absorption ability is used as the support.
  • the ink-receiving layer of the ink-jet recording medium of the present invention is constituted of the aforementioned magnesium salt of silicic acid or of phosphorus oxy-acid, basic magnesium carbonate, a binder, and other additives.
  • the ratio of the basic magnesium carbonate to the magnesium salt of silicic acid or of phosphorus oxy-acid is preferably in the range of from 1/5 to 9/1 by weight.
  • the above range is preferable in all the aspects including indoor discoloration of formed image, higher image density and prevention of feathering, running and white haze.
  • a conventionally used inorganic or organic pigment may be used in addition to the above-specified pigments within the range that does not prevent the object of the present invention.
  • the binders useful in the present invention include known water-soluble polymers such as polyvinyl alcohol, starch, oxidized starch, cationic starch, casein, carboxymethylcellulose, gelatin, hydroxyethylcellulose, acrylic resins and the like; water-dispersion type polymers such as SBR latex, polyvinyl acetate emulsion, and the like; and mixtures of two or more thereof.
  • the preferable ratio of the use of the pigment to the binder is in the range of from 10/1 to 1/4, more preferably from 6/1 to 1/1.
  • the above range is preferable in the aspects of improvement in ink absorbing ability and prevention of powder falling-off.
  • the ink-receiving layer may contain an additive such as a dye-fixing agent (a water-proofing agent), a fluorescent whitener, a surface active agent, an anti-foaming agent, a pH adjusting agent, a mildew-proofing agent, a UV absorbing agent, a dispersing agent, a viscosity-reducing agent, and the like, if necessary.
  • an additive such as a dye-fixing agent (a water-proofing agent), a fluorescent whitener, a surface active agent, an anti-foaming agent, a pH adjusting agent, a mildew-proofing agent, a UV absorbing agent, a dispersing agent, a viscosity-reducing agent, and the like, if necessary.
  • an aqueous coating liquid which contains pigments, a binder, and other additives as mentioned above is applied on a base material according to a known coating method such as a roll coater method, a blade coater method, an air-knife coater method, a gate-roll coater method, a size press method and the like, and thereafter the coating is dried with a drier such as a hot-air drier, a hot drum, and the like, thus giving a recording medium of the present invention
  • the recording medium thus produced may further be treated with a supercalender for smoothening or strengthening the ink-receiving layer surface.
  • the coating amount of the ink-receiving layer is preferably in the range of from 0.2 to 50 g/m2, more preferably from 0.2 to 20 g/m2. With a smaller amount of coating, a portion of the base material may be exposed at the surface.
  • the above range is preferable in the aspects of improvement in color development of dyes and prevention of powder falling-off from the coat layer.
  • the preferable coating amount is shown by coating thickness to be in the range of from 0.5 to 100 »m.
  • the recording medium of the present invention includes those having the above-mentioned pigments incorporated in the interior of the supporting paper in addition to those having the ink-receiving layer formed on the surface of the support.
  • Any usual recording agent may be used without special limitation, including water-soluble dyes such as direct dyes, acidic dyes, basic dyes, reactive dyes, and food dyes.
  • the water soluble dye is contained in conventional inks generally at a concentration of from about 0.1 to about 20 % by weight.
  • the concentration may be the same in the present invention.
  • the solvent for the aqueous ink of the present invention is water or a mixed solvent of water with a water-soluble organic solvent.
  • Particularly preferable are mixed solvents of water with an organic solvent, containing a polyhydric alcohol giving ink-drying prevention effect as the water-soluble organic solvent.
  • the recording on the aforementioned recording medium is conducted by applying the above ink thereon, preferably by ink-jet recording method.
  • the recording method may be any method in which ink is ejected effectively from a nozzle onto a shooting object of the recording medium.
  • an ink-jet recording method is effectively employed in which an ink, on receiving thermal energy, abruptly changes its volume by phase transition to be ejected from a nozzle by the action of the volume change as described in Japanese Patent Application Laid-Open No. 54-59936.
  • the average particle diameters of the magnesium salts of silicic acid used in producing the recording mediums of the present invention are shown in Table 1 below.
  • As the basic magnesium carbonate spherical basic magnesium carbonate A and spherical basic magnesium carbonate B having the average particle diameters and the BET specific surface areas shown in Table 1 were prepared and used (prepared according to the method disclosed in Japanese Patent Application Laid-Open No. 60-54915 with modification of reaction conditions).
  • Table 1 Sample Maker Average particle diameter (»m) BET specific surface area (m2/g) Tomix AD600 (I) *1 Tomita Seiyaku K.K. 1.22 - Pulverized one (II) *2 5.6 - KYOWAAD 600 (III) *1 Kyowa Kagaku K.K.
  • the recording mediums were prepared by the method below.
  • aqueous binder solution aqueous 10% polyvinyl alcohol solution
  • desired pigment/binder ratio based on solid contents
  • the coating liquid prepared as above was applied onto a base paper having a reduced sizing degree of 3 second as a basis weight of 65 g/m2 in a coating solid amount of 5 g/m2,
  • the coated matter was dried at 110°C for 5 minutes, and was subjected to a supercalender treatment to give a recording medium of the present invention.
  • PAS-A-120S made by Nitto Boseki Co., Ltd. (a polyamine sulfonate salt, molecular weight: 105) was added in an amount of 10% by weight based on the pigments.
  • the ratio of the pigments to the binder was 2/1.
  • ink-jet recording was practiced by use of the ink having the composition below in an amount of ink of 8 nl/mm2 for each single color.
  • Ink composition Dye 5 parts Diethylene glycol 20 parts Water 80 parts Dye Y: C.I. Direct Yellow 86 M: C.I. Acid Red 35 C: C.I. Direct Blue 199 Bk: C.I. Food Black 2
  • the image density was evaluated by measuring the optical density, OD (Bk), of reflection at a solid black print portion by means of a McBeth reflectodensitometer RD-918.
  • the indoor preservability was evaluated by leaving the printed matters standing in an office environment where outdoor air circulates and direct sunshine is intercepted, and measuring the color difference ( ⁇ E*) after one month and after three months by means of a color-difference meter CA-35 made by Murakami Shikisai Kenkyusho K.K.
  • the white haze and the fattening of letters were evaluated organoleptically in three grades of good ( ⁇ ), medium ( ⁇ ), and poor (X).
  • a recording medium was prepared in the same manner as in Examples 1 - 5 except that the only one pigment, P-Type (basic magnesium carbonate 4MgCO3 ⁇ Mg(OH)2 ⁇ 4H2O, average particle diameter: 12.8 »m, BET specific surface area: 35 m2/g) made by Ube Chemical Industries Co. Ltd., was used, and was evaluated in the same manner as in Example 6. Consequently, the recording medium was satisfactory in prevention of indoor discoloration but was unsatisfactory in white haze and letter-fattening with low image density as shown in Table 4.
  • P-Type basic magnesium carbonate 4MgCO3 ⁇ Mg(OH)2 ⁇ 4H2O, average particle diameter: 12.8 »m, BET specific surface area: 35 m2/g
  • a recording medium was prepared in the same manner as in Examples 1 - 5 except that the only one pigment, Tomix AD600, was used, and was evaluated in the same manner as in Example 6. Consequently, the recording medium was satisfactory in indoor discoloration, white haze and letter-fattening, but was unsatisfactory in image density as shown in Table 4.
  • a recording medium was prepared in the same manner as in Examples 3 - 5 except that a synthesized hydrotalcite (basic magnesium aluminum hydroxy carbonate hydrate, Mg 4.5 Al2(OH)13CO3 ⁇ 3.5H2O, average particle diameter: 2.98 »m) made by Tomita Seiyaku K.K. was used in place of magnesium silicate, and was evaluated in the same manner as in Example 6. Consequently, the recording medium was less satisfactory in indoor discoloration, white haze and letter-fattening, and was unsatisfactory in image density as shown in Table 4.
  • a synthesized hydrotalcite basic magnesium aluminum hydroxy carbonate hydrate, Mg 4.5 Al2(OH)13CO3 ⁇ 3.5H2O, average particle diameter: 2.98 »m
  • the average particle diameters of the magnesium salt of phosphorus oxy-acid used in producing the recording mediums of the present invention are shown in Table 5 below.
  • As the basic magnesium carbonate spherical basic magnesium carbonate A and spherical basic magnesium carbonate B having the average particle diameters and the BET specific surface areas shown in Table 5 were prepared and used (prepared according to the method disclosed in Japanese Patent Application Laid-Open No. 60-54915 with modification of reaction conditions).
  • the recording mediums were prepared by the method below.
  • aqueous binder solution aqueous 10% polyvinyl alcohol solution
  • desired pigment/binder ratio based on solid contents
  • the coating liquid prepared as above was applied onto a base paper having a reduced sizing degree of 3 second as a basis weight of 65 g/m2 in a coating solid amount of 5 g/m2,
  • the coated matter was dried at 110°C for 5 minutes, and was subjected to a supercalender treatment to give a recording medium of the present invention.
  • PAS-A-120S made by Nitto Boseki Co., Ltd. (a polyamine sulfonate salt, molecular weight: 105) was added in an amount of 10% by weight based on the pigments.
  • the ratio of the pigments to the binder was 2/1.
  • ink-jet recording was practiced by use of the ink having the composition below in an amount of ink of 8 nl/mm2 for each single color.
  • Ink composition Dye 5 parts Diethylene glycol 20 parts Water 80 parts Dye Y: C.I. Direct Yellow 86 M: C.I. Acid Red 35 C: C.I. Direct Blue 199 Bk: C.I. Food Black 2
  • the image density was evaluated by measuring the optical density, OD (Bk), of reflection at a solid black print portion by means of a McBeth reflectodensitometer RD-918.
  • the indoor preservability was evaluated by leaving the printed matters standing in an office environment where outdoor air circulates and direct sunshine is intercepted, and measuring the color difference ( ⁇ E*) after one month and after three months by means of a color-difference meter CA-35 made by Murakami Shikisai Kenkyusho K.K.
  • the white haze and the fattening of letters were evaluated organoleptically in three grades of good ( ⁇ ), medium ( ⁇ ), and poor (X).
  • the present invention provides an ink-jet recording medium which is capable of giving a recorded image of high density and is free from the problems of indoor discoloration, white haze, fattening of letters, and so on, as well as an ink-jet recording method using the same.
  • a recording medium comprises basic magnesium carbonate and a magnesium salt of silicic acid or of phosphorus oxy-acid. Ink-jet recording is conducted using the recording medium to obtain high image density without any problem such as indoor discoloration, white haze, fattening of letters, etc.

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  • Chemical & Material Sciences (AREA)
  • Inorganic Chemistry (AREA)
  • Ink Jet Recording Methods And Recording Media Thereof (AREA)
  • Ink Jet (AREA)
  • Materials For Medical Uses (AREA)
  • Inks, Pencil-Leads, Or Crayons (AREA)

Claims (29)

  1. Tintenstrahl-Aufzeichnungsträger, umfassend basisches Magnesiumcarbonat und ein Magnesiumsalz einer Kieselsäure.
  2. Tintenstrahl-Aufzeichnungsträger, umfassend eine auf einem Träger gebildete Schicht, die basisches Magnesiumcarbonat und ein Magnesiumsalz einer Kieselsäure enthält.
  3. Tintenstrahl-Aufzeichnungsträger nach Anspruch 1 oder Anspruch 2, wobei das basische Magnesiumcarbonat kugelförmiges basisches Magnesiumcarbonat ist.
  4. Tintenstrahl-Aufzeichnungsträger nach Anspruch 1 oder Anspruch 2, wobei das Magnesiumsalz einer Kieselsäure einen mittleren Teilchendurchmesser von nicht mehr als 7 »m aufweist.
  5. Tintenstrahl-Aufzeichnungsträger nach Anspruch 1 oder Anspruch 2, wobei das Magnesiumsalz einer Kieselsäure Magnesiumsilicat ist.
  6. Tintenstrahl-Aufzeichnungsträger nach Anspruch 1 oder Anspruch 2, wobei das Gewichtsverhältnis von dem basischem Magnesiumcarbonat zu dem Magnesiumsalz einer Kieselsäure in einem Bereich von 1/5 bis 9/1 liegt.
  7. Tintenstrahl-Aufzeichnungsträger nach Anspruch 2, wobei das basische Magnesiumcarbonat und das Magnesiumsalz einer Kieselsäure auf den Träger in einer Menge von 0,2 bis 50 g/m², bezogen auf den Feststoff, aufgebracht sind.
  8. Tintenstrahl-Aufzeichnungsträger, umfassend basisches Magnesiumcarbonat und ein Magnesiumsalz einer Phophorsauerstoffsäure.
  9. Tintenstrahl-Aufzeichnungsträger, umfassend eine auf einem Träger gebildete Schicht, die basisches Magnesiumcarbonat und ein Magnesiumsalz einer Phosphorsauerstoffsäure enthält.
  10. Tintenstrahl-Aufzeichnungsträger nach Anspruch 8 oder Anspruch 9, wobei das basische Magnesiumcarbonat kugelförmiges basisches Magnesiumcarbonat ist.
  11. Tintenstrahl-Aufzeichnungsträger nach Anspruch 8 oder Anspruch 9, wobei das Magnesiumsalz einer Phosphorsauerstoffsäure einen mittleren Teilchendurchmesser von nicht mehr als 7 »m aufweist.
  12. Tintenstrahl-Aufzeichnungsträger nach Anspruch 8 oder Anspruch 9, wobei das Magnesiumsalz einer Phosphorsauerstoffsäure Magnesiumphosphat ist.
  13. Tintenstrahl-Aufzeichnungsträger nach Anspruch 8 oder Anspruch 9, wobei das Gewichtsverhältnis von dem basischem Magnesiumcarbonat zu dem Magnesiumsalz einer Phosphorsauerstoffsäure in einem Bereich von 1/5 bis 9/1 liegt.
  14. Tintenstrahl-Aufzeichnungsträger nach Anspruch 9, wobei das basische Magnesiumcarbonat und das Magnesiumsalz einer Phosphorsauerstoffsäure auf den Träger in einer Menge von 0,2 bis 50 g/m², bezogen auf den Feststoff, aufgebracht sind.
  15. Tintenstrahl-Aufzeichnungsverfahren, das mittels Aufbringens von Tröpfchen wäßriger Tinte auf einen Aufzeichnungsträger durchgeführt wird, wobei der Aufzeichnungsträger basisches Magnesiumcarbonat und ein Magnesiumsalz einer Kieselsäure enthält.
  16. Tintenstrahl-Aufzeichnungsverfahren, das mittels Aufbringens von Tröpfchen wäßriger Tinte auf einen Aufzeichnungsträger durchgeführt wird, wobei der Aufzeichnungsträger eine auf einem Träger gebildete Schicht umfaßt, die basisches Magnesiumcarbonat und ein Magnesiumsalz einer Kieselsäure enthält.
  17. Tintenstrahl-Aufzeichnungsverfahren nach Anspruch 15 oder Anspruch 16, wobei das basische Magnesiumcarbonat kugelförmiges basisches Magnesiumcarbonat ist.
  18. Tintenstrahl-Aufzeichnungsverfahren nach Anspruch 15 oder Anspruch 16, wobei das Magnesiumsalz einer Kieselsäure einen mittleren Teilchendurchmesser von nicht mehr als 7 »m aufweist.
  19. Tintenstrahl-Aufzeichnungsverfahren nach Anspruch 15 oder Anspruch 16, wobei das Magnesiumsalz einer Kieselsäure Magnesiumsilicat ist.
  20. Tintenstrahl-Aufzeichnungsverfahren nach Anspruch 15 oder Anspruch 16, wobei das Gewichtsverhältnis von dem basischem Magnesiumcarbonat zu dem Magnesiumsalz einer Kieselsäure in einem Bereich von 1/5 bis 9/1 liegt.
  21. Tintenstrahl-Aufzeichnungsverfahren nach Anspruch 16, wobei das basische Magnesiumcarbonat und das Magnesiumsalz einer Kieselsäure auf den Träger in einer Menge von 0,2 bis 50 g/m², bezogen auf den Feststoff, aufgebracht sind.
  22. Tintenstrahl-Aufzeichnungsverfahren, das mittels Aufbringens von Tröpfchen wäßriger Tinte auf einen Aufzeichnungsträger durchgeführt wird, wobei der Aufzeichnungsträger basisches Magnesiumcarbonat und ein Magnesiumsalz einer Phosphorsauerstoffsäure umfaßt.
  23. Tintenstrahl-Aufzeichnungsverfahren, das mittels Aufbringens von Tröpfchen wäßriger Tinte auf einen Aufzeichnungsträger durchgeführt wird, wobei der Aufzeichnungsträger eine auf einem Träger gebildete Schicht umfaßt, die basisches Magnesiumcarbonat und ein Magnesiumsalz einer Phosphorsauerstoffsäure enthält.
  24. Tintenstrahl-Aufzeichnungsverfahren nach Anspruch 22 oder Anspruch 23, wobei das basische Magnesiumcarbonat kugelförmiges basisches Magnesiumcarbonat ist.
  25. Tintenstrahl-Aufzeichnungsverfahren nach Anspruch 22 oder Anspruch 23, wobei das Magnesiumsalz einer Phosphorsauerstoffsäure einen mittleren Teilchendurchmesser von nicht mehr als 7 »m aufweist.
  26. Tintenstrahl-Aufzeichnungsverfahren nach Anspruch 22 oder Anspruch 23, wobei das Magnesiumsalz einer Phosphorsauerstoffsäure Magnesiumphosphat ist.
  27. Tintenstrahl-Aufzeichnungsverfahren nach Anspruch 22 oder Anspruch 23, wobei das Gewichtsverhältnis von dem basischem Magnesiumcarbonat zu dem Magnesiumsalz einer Phosphorsauerstoffsäure in einem Bereich von 1/5 bis 9/1 liegt.
  28. Tintenstrahl-Aufzeichnungsverfahren nach Anspruch 23, wobei das basische Magnesiumcarbonat und das Magnesiumsalz einer Phosphorsauerstoffsäure auf den Träger in einer Menge von 0,2 bis 50 g/m², bezogen auf den Feststoff, aufgebracht sind.
  29. Tintenstrahl-Aufzeichnungsverfahren nach einem der Ansprüche 15, 16, 22 und 23, wobei eine Vielzahl unterschiedlicher Tintenfarben verwendet wird.
EP91109366A 1990-06-09 1991-06-07 Tintenstrahldruckmittel und dessen Verwendungsverfahren Expired - Lifetime EP0461558B1 (de)

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JP2150571A JPH0443068A (ja) 1990-06-09 1990-06-09 インクジェット記録媒体及びインクジェット記録方法
JP150572/90 1990-06-09
JP150571/90 1990-06-09
JP2150572A JP2621098B2 (ja) 1990-06-09 1990-06-09 インクジェット記録媒体及びインクジェット記録方法

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EP0461558B1 true EP0461558B1 (de) 1995-03-29

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Families Citing this family (28)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE69110307T2 (de) * 1990-01-24 1996-02-22 Canon Kk Mehrfarbiges Tintenstrahlaufzeichnungsverfahren.
US5137778A (en) * 1990-06-09 1992-08-11 Canon Kabushiki Kaisha Ink-jet recording medium, and ink-jet recording method employing the same
JPH06239014A (ja) * 1993-02-16 1994-08-30 Canon Inc 記録媒体
CN1069370C (zh) * 1993-06-15 2001-08-08 佳能株式会社 墨水喷射记录用高光泽印刷纸、其制造方法及使用这种纸的墨水喷射记录方法
US5620793A (en) * 1993-11-05 1997-04-15 Canon Kabushiki Kaisha Printing paper and method of image formation employing the same
ATE183143T1 (de) * 1994-03-08 1999-08-15 Canon Kk Aufzeichnungspapier, tintenstrahlaufzeichnungsverfahren und aufzeichnungssystem unter verwendung des aufzeichnungspapiers
JPH0999628A (ja) 1994-10-07 1997-04-15 Canon Inc 画像形成方法
DE69510748T2 (de) * 1994-10-20 2000-04-06 Canon K.K. Giessbeschichtetes Papier für Tintenstrahlaufzeichnung, dessen Verfahren zur Herstellung und Tintenstrahldruckverfahren damit
JP3591938B2 (ja) 1994-10-27 2004-11-24 キヤノン株式会社 インクジェット用記録媒体及びこれを用いた画像形成方法
JP3486492B2 (ja) * 1994-10-27 2004-01-13 キヤノン株式会社 記録紙及びこれを用いた画像形成方法
US6051306A (en) * 1996-11-15 2000-04-18 Fargo Electronics, Inc. Ink jet printable surface
US6270858B1 (en) 1996-11-15 2001-08-07 Fargo Electronics, Inc. Method of coating using an ink jet printable mixture
US6153288A (en) * 1997-07-24 2000-11-28 Avery Dennison Corporation Ink-receptive compositions and coated products
KR20010111567A (ko) * 1999-02-12 2001-12-19 캐롤린 에이. 베이츠 이미지 수용 매체 및 이의 제조방법 및 용도
EP1088930B1 (de) 1999-10-01 2007-07-18 Canon Kabushiki Kaisha Druckverfahren und damit hergestellte Drucke sowie mit diesem Verfahren hergestellter Artikel
US7037013B2 (en) 2001-03-05 2006-05-02 Fargo Electronics, Inc. Ink-receptive card substrate
US6979141B2 (en) * 2001-03-05 2005-12-27 Fargo Electronics, Inc. Identification cards, protective coatings, films, and methods for forming the same
US7399131B2 (en) 2001-03-05 2008-07-15 Fargo Electronics, Inc. Method and Device for forming an ink-receptive card substrate
JP4856885B2 (ja) * 2004-03-16 2012-01-18 キヤノン株式会社 液体組成物、液体組成物とインクのセット及び画像記録方法
KR100864548B1 (ko) * 2004-03-16 2008-10-20 캐논 가부시끼가이샤 잉크젯용 잉크 및 잉크젯 기록 방법
WO2005092993A1 (ja) * 2004-03-26 2005-10-06 Canon Kabushiki Kaisha 活性エネルギー線硬化型水性インク、それを用いたインクジェット記録方法、インクカートリッジ、記録ユニット及びインクジェット記録装置
CN100564461C (zh) 2004-03-26 2009-12-02 佳能株式会社 活性能量射线固化型水性油墨组合物、使用该组合物的喷墨记录方法、墨盒、记录单元和喷墨记录装置
US8956490B1 (en) 2007-06-25 2015-02-17 Assa Abloy Ab Identification card substrate surface protection using a laminated coating
WO2009145790A1 (en) 2008-05-30 2009-12-03 Hewlett-Packard Development Company, L.P. Media for inkjet printing
US8282725B2 (en) * 2009-04-22 2012-10-09 Canon Kabushiki Kaisha Self-dispersion pigment, production process of self-dispersion pigment, ink set and ink jet recording method
JP2011241384A (ja) 2010-04-22 2011-12-01 Canon Inc 活性エネルギー線硬化型のインクジェット記録用液体組成物、及びそれを用いたインクジェット記録方法
US8939570B2 (en) 2011-12-02 2015-01-27 Canon Kabushiki Kaisha Ink jet ink, ink cartridge, ink jet recording method and polymer particle
US8845085B2 (en) 2011-12-02 2014-09-30 Canon Kabushiki Kaisha Image recording method, and set of ink jet ink and liquid composition

Family Cites Families (19)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS5459936A (en) * 1977-10-03 1979-05-15 Canon Inc Recording method and device therefor
US4446174A (en) * 1979-04-27 1984-05-01 Fuiji Photo Film Company, Ltd. Method of ink-jet recording
JPS56148585A (en) * 1980-04-21 1981-11-18 Canon Inc Recording material
JPS5738185A (en) * 1980-08-20 1982-03-02 Matsushita Electric Ind Co Ltd Ink jet recording paper
JPS58110287A (ja) * 1981-12-24 1983-06-30 Mitsubishi Paper Mills Ltd 記録用シ−ト
JPS59185690A (ja) * 1983-04-07 1984-10-22 Jujo Paper Co Ltd インクジエツト記録用紙
JPS6054915A (ja) * 1983-09-01 1985-03-29 Tokuyama Soda Co Ltd 球状塩基性炭酸マグネシウム及びその製造方法
JPS6157380A (ja) * 1984-08-28 1986-03-24 Mitsubishi Paper Mills Ltd インクジエツト記録媒体
JPS6163526A (ja) * 1984-09-04 1986-04-01 Tokuyama Soda Co Ltd 球状塩基性炭酸マグネシウムの製造方法
JPS61135785A (ja) * 1984-12-07 1986-06-23 Mitsubishi Paper Mills Ltd インクジエツト記録媒体
EP0199874A1 (de) * 1985-02-25 1986-11-05 The Mead Corporation Aufzeichnungsblatt für Tintenstrahlaufzeichnung mit einer tintenempfänglichen Polyäthylen enthaltenden Schicht
DE3780181T2 (de) * 1986-02-07 1993-02-25 Canon Kk Bildaufzeichnungsverfahren.
JPS6389418A (ja) * 1986-10-02 1988-04-20 Kounoshima Kagaku Kogyo Kk 多孔質球状塩基性炭酸マグネシウムの製造方法
US4758461A (en) * 1986-12-05 1988-07-19 Canon Kabushiki Kaisha Recording paper and ink jet recording method by use thereof
US5041328A (en) * 1986-12-29 1991-08-20 Canon Kabushiki Kaisha Recording medium and ink jet recording method by use thereof
JPH0813895B2 (ja) * 1987-09-24 1996-02-14 王子油化合成紙株式会社 印刷性の優れた合成樹脂フイルム
JP2622173B2 (ja) * 1989-06-26 1997-06-18 キヤノン株式会社 被記録材及びこれを用いた記録方法
JP2668442B2 (ja) * 1989-08-04 1997-10-27 キヤノン株式会社 記録媒体及びインクジェット記録方法
US5137778A (en) * 1990-06-09 1992-08-11 Canon Kabushiki Kaisha Ink-jet recording medium, and ink-jet recording method employing the same

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DE69108455T2 (de) 1995-08-31
US5137778A (en) 1992-08-11
US5277962A (en) 1994-01-11
DE69108455D1 (de) 1995-05-04
CA2044129C (en) 1996-08-20
ATE120408T1 (de) 1995-04-15
CA2044129A1 (en) 1991-12-10
EP0461558A1 (de) 1991-12-18

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