EP0439019A1 - Flüssiges Reinigungsmittel für Kleider - Google Patents
Flüssiges Reinigungsmittel für Kleider Download PDFInfo
- Publication number
- EP0439019A1 EP0439019A1 EP91100209A EP91100209A EP0439019A1 EP 0439019 A1 EP0439019 A1 EP 0439019A1 EP 91100209 A EP91100209 A EP 91100209A EP 91100209 A EP91100209 A EP 91100209A EP 0439019 A1 EP0439019 A1 EP 0439019A1
- Authority
- EP
- European Patent Office
- Prior art keywords
- carbon atoms
- detergent composition
- weight
- alkyl
- clothes
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Withdrawn
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- 239000003599 detergent Substances 0.000 title claims abstract description 29
- 239000000203 mixture Substances 0.000 title claims abstract description 25
- 239000007788 liquid Substances 0.000 title claims abstract description 8
- -1 alkyl glycoside Chemical class 0.000 claims abstract description 31
- 229930182470 glycoside Natural products 0.000 claims abstract description 18
- 229920001296 polysiloxane Polymers 0.000 claims abstract description 16
- 125000004432 carbon atom Chemical group C* 0.000 claims description 20
- 125000000217 alkyl group Chemical group 0.000 claims description 14
- 229920003171 Poly (ethylene oxide) Polymers 0.000 claims description 5
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 claims description 4
- 125000003342 alkenyl group Chemical group 0.000 claims description 2
- 125000005037 alkyl phenyl group Chemical group 0.000 claims description 2
- 125000002947 alkylene group Chemical group 0.000 claims description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 17
- 238000005406 washing Methods 0.000 description 11
- 239000004744 fabric Substances 0.000 description 10
- 238000009950 felting Methods 0.000 description 8
- 230000000694 effects Effects 0.000 description 7
- 150000001412 amines Chemical class 0.000 description 6
- 150000001875 compounds Chemical class 0.000 description 5
- 210000002268 wool Anatomy 0.000 description 5
- CYTYCFOTNPOANT-UHFFFAOYSA-N Perchloroethylene Chemical compound ClC(Cl)=C(Cl)Cl CYTYCFOTNPOANT-UHFFFAOYSA-N 0.000 description 4
- 239000004094 surface-active agent Substances 0.000 description 4
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 3
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 3
- 238000011156 evaluation Methods 0.000 description 3
- 150000004676 glycans Chemical class 0.000 description 3
- 125000001165 hydrophobic group Chemical group 0.000 description 3
- 238000000034 method Methods 0.000 description 3
- 150000002772 monosaccharides Chemical class 0.000 description 3
- 229920001282 polysaccharide Polymers 0.000 description 3
- 239000005017 polysaccharide Substances 0.000 description 3
- OWEGMIWEEQEYGQ-UHFFFAOYSA-N 100676-05-9 Natural products OC1C(O)C(O)C(CO)OC1OCC1C(O)C(O)C(O)C(OC2C(OC(O)C(O)C2O)CO)O1 OWEGMIWEEQEYGQ-UHFFFAOYSA-N 0.000 description 2
- SRBFZHDQGSBBOR-IOVATXLUSA-N D-xylopyranose Chemical compound O[C@@H]1COC(O)[C@H](O)[C@H]1O SRBFZHDQGSBBOR-IOVATXLUSA-N 0.000 description 2
- 102000004190 Enzymes Human genes 0.000 description 2
- 108090000790 Enzymes Proteins 0.000 description 2
- 229930091371 Fructose Natural products 0.000 description 2
- 239000005715 Fructose Substances 0.000 description 2
- RFSUNEUAIZKAJO-ARQDHWQXSA-N Fructose Chemical compound OC[C@H]1O[C@](O)(CO)[C@@H](O)[C@@H]1O RFSUNEUAIZKAJO-ARQDHWQXSA-N 0.000 description 2
- WQZGKKKJIJFFOK-GASJEMHNSA-N Glucose Natural products OC[C@H]1OC(O)[C@H](O)[C@@H](O)[C@@H]1O WQZGKKKJIJFFOK-GASJEMHNSA-N 0.000 description 2
- GUBGYTABKSRVRQ-PICCSMPSSA-N Maltose Natural products O[C@@H]1[C@@H](O)[C@H](O)[C@@H](CO)O[C@@H]1O[C@@H]1[C@@H](CO)OC(O)[C@H](O)[C@H]1O GUBGYTABKSRVRQ-PICCSMPSSA-N 0.000 description 2
- CZMRCDWAGMRECN-UGDNZRGBSA-N Sucrose Chemical compound O[C@H]1[C@H](O)[C@@H](CO)O[C@@]1(CO)O[C@@H]1[C@H](O)[C@@H](O)[C@H](O)[C@@H](CO)O1 CZMRCDWAGMRECN-UGDNZRGBSA-N 0.000 description 2
- 229930006000 Sucrose Natural products 0.000 description 2
- MUPFEKGTMRGPLJ-UHFFFAOYSA-N UNPD196149 Natural products OC1C(O)C(CO)OC1(CO)OC1C(O)C(O)C(O)C(COC2C(C(O)C(O)C(CO)O2)O)O1 MUPFEKGTMRGPLJ-UHFFFAOYSA-N 0.000 description 2
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 description 2
- 150000005215 alkyl ethers Chemical class 0.000 description 2
- 239000002280 amphoteric surfactant Substances 0.000 description 2
- PYMYPHUHKUWMLA-UHFFFAOYSA-N arabinose Natural products OCC(O)C(O)C(O)C=O PYMYPHUHKUWMLA-UHFFFAOYSA-N 0.000 description 2
- SRBFZHDQGSBBOR-UHFFFAOYSA-N beta-D-Pyranose-Lyxose Natural products OC1COC(O)C(O)C1O SRBFZHDQGSBBOR-UHFFFAOYSA-N 0.000 description 2
- WQZGKKKJIJFFOK-VFUOTHLCSA-N beta-D-glucose Chemical compound OC[C@H]1O[C@@H](O)[C@H](O)[C@@H](O)[C@@H]1O WQZGKKKJIJFFOK-VFUOTHLCSA-N 0.000 description 2
- GUBGYTABKSRVRQ-QUYVBRFLSA-N beta-maltose Chemical compound OC[C@H]1O[C@H](O[C@H]2[C@H](O)[C@@H](O)[C@H](O)O[C@@H]2CO)[C@H](O)[C@@H](O)[C@@H]1O GUBGYTABKSRVRQ-QUYVBRFLSA-N 0.000 description 2
- 239000003795 chemical substances by application Substances 0.000 description 2
- 239000004205 dimethyl polysiloxane Substances 0.000 description 2
- 235000013870 dimethyl polysiloxane Nutrition 0.000 description 2
- 229940088598 enzyme Drugs 0.000 description 2
- 239000008103 glucose Substances 0.000 description 2
- 125000002791 glucosyl group Chemical group C1([C@H](O)[C@@H](O)[C@H](O)[C@H](O1)CO)* 0.000 description 2
- 125000004435 hydrogen atom Chemical group [H]* 0.000 description 2
- 230000002401 inhibitory effect Effects 0.000 description 2
- 239000004816 latex Substances 0.000 description 2
- 229920000126 latex Polymers 0.000 description 2
- 239000002736 nonionic surfactant Substances 0.000 description 2
- 229920000435 poly(dimethylsiloxane) Polymers 0.000 description 2
- 229920000642 polymer Polymers 0.000 description 2
- 239000002904 solvent Substances 0.000 description 2
- 239000005720 sucrose Substances 0.000 description 2
- LGQKSQQRKHFMLI-SJYYZXOBSA-N (2s,3r,4s,5r)-2-[(3r,4r,5r,6r)-4,5,6-trihydroxyoxan-3-yl]oxyoxane-3,4,5-triol Chemical compound O[C@@H]1[C@@H](O)[C@H](O)CO[C@H]1O[C@H]1[C@H](O)[C@@H](O)[C@H](O)OC1 LGQKSQQRKHFMLI-SJYYZXOBSA-N 0.000 description 1
- BKZXZGWHTRCFPX-UHFFFAOYSA-N 2-tert-butyl-6-methylphenol Chemical compound CC1=CC=CC(C(C)(C)C)=C1O BKZXZGWHTRCFPX-UHFFFAOYSA-N 0.000 description 1
- QIGJYVCQYDKYDW-UHFFFAOYSA-N 3-O-alpha-D-mannopyranosyl-D-mannopyranose Natural products OC1C(O)C(O)C(CO)OC1OC1C(O)C(CO)OC(O)C1O QIGJYVCQYDKYDW-UHFFFAOYSA-N 0.000 description 1
- LGQKSQQRKHFMLI-UHFFFAOYSA-N 4-O-beta-D-xylopyranosyl-beta-D-xylopyranose Natural products OC1C(O)C(O)COC1OC1C(O)C(O)C(O)OC1 LGQKSQQRKHFMLI-UHFFFAOYSA-N 0.000 description 1
- GUBGYTABKSRVRQ-XLOQQCSPSA-N Alpha-Lactose Chemical compound O[C@@H]1[C@@H](O)[C@@H](O)[C@@H](CO)O[C@H]1O[C@@H]1[C@@H](CO)O[C@H](O)[C@H](O)[C@H]1O GUBGYTABKSRVRQ-XLOQQCSPSA-N 0.000 description 1
- 239000004382 Amylase Substances 0.000 description 1
- 102000013142 Amylases Human genes 0.000 description 1
- 108010065511 Amylases Proteins 0.000 description 1
- UXVMQQNJUSDDNG-UHFFFAOYSA-L Calcium chloride Chemical compound [Cl-].[Cl-].[Ca+2] UXVMQQNJUSDDNG-UHFFFAOYSA-L 0.000 description 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- 229920002134 Carboxymethyl cellulose Polymers 0.000 description 1
- 108010059892 Cellulase Proteins 0.000 description 1
- 229920000742 Cotton Polymers 0.000 description 1
- GUBGYTABKSRVRQ-CUHNMECISA-N D-Cellobiose Chemical compound O[C@@H]1[C@@H](O)[C@H](O)[C@@H](CO)O[C@H]1O[C@@H]1[C@@H](CO)OC(O)[C@H](O)[C@H]1O GUBGYTABKSRVRQ-CUHNMECISA-N 0.000 description 1
- WQZGKKKJIJFFOK-QTVWNMPRSA-N D-mannopyranose Chemical compound OC[C@H]1OC(O)[C@@H](O)[C@@H](O)[C@@H]1O WQZGKKKJIJFFOK-QTVWNMPRSA-N 0.000 description 1
- QWIZNVHXZXRPDR-UHFFFAOYSA-N D-melezitose Natural products O1C(CO)C(O)C(O)C(O)C1OC1C(O)C(CO)OC1(CO)OC1OC(CO)C(O)C(O)C1O QWIZNVHXZXRPDR-UHFFFAOYSA-N 0.000 description 1
- SQNRKWHRVIAKLP-UHFFFAOYSA-N D-xylobiose Natural products O=CC(O)C(O)C(CO)OC1OCC(O)C(O)C1O SQNRKWHRVIAKLP-UHFFFAOYSA-N 0.000 description 1
- QEVGZEDELICMKH-UHFFFAOYSA-N Diglycolic acid Chemical class OC(=O)COCC(O)=O QEVGZEDELICMKH-UHFFFAOYSA-N 0.000 description 1
- MUPFEKGTMRGPLJ-OBAJZVCXSA-N Gentianose Natural products O(C[C@@H]1[C@@H](O)[C@H](O)[C@H](O)[C@@H](O[C@@]2(CO)[C@H](O)[C@H](O)[C@@H](CO)O2)O1)[C@H]1[C@@H](O)[C@@H](O)[C@H](O)[C@@H](CO)O1 MUPFEKGTMRGPLJ-OBAJZVCXSA-N 0.000 description 1
- AYRXSINWFIIFAE-SCLMCMATSA-N Isomaltose Natural products OC[C@H]1O[C@H](OC[C@@H](O)[C@@H](O)[C@H](O)[C@@H](O)C=O)[C@@H](O)[C@@H](O)[C@@H]1O AYRXSINWFIIFAE-SCLMCMATSA-N 0.000 description 1
- GUBGYTABKSRVRQ-QKKXKWKRSA-N Lactose Natural products OC[C@H]1O[C@@H](O[C@H]2[C@H](O)[C@@H](O)C(O)O[C@@H]2CO)[C@H](O)[C@@H](O)[C@H]1O GUBGYTABKSRVRQ-QKKXKWKRSA-N 0.000 description 1
- 102000004882 Lipase Human genes 0.000 description 1
- 239000004367 Lipase Substances 0.000 description 1
- 108090001060 Lipase Proteins 0.000 description 1
- AYRXSINWFIIFAE-UHFFFAOYSA-N O6-alpha-D-Galactopyranosyl-D-galactose Natural products OCC1OC(OCC(O)C(O)C(O)C(O)C=O)C(O)C(O)C1O AYRXSINWFIIFAE-UHFFFAOYSA-N 0.000 description 1
- 108091005804 Peptidases Proteins 0.000 description 1
- 239000002202 Polyethylene glycol Substances 0.000 description 1
- 239000004365 Protease Substances 0.000 description 1
- MUPFEKGTMRGPLJ-RMMQSMQOSA-N Raffinose Natural products O(C[C@H]1[C@@H](O)[C@H](O)[C@@H](O)[C@@H](O[C@@]2(CO)[C@H](O)[C@@H](O)[C@@H](CO)O2)O1)[C@@H]1[C@H](O)[C@@H](O)[C@@H](O)[C@@H](CO)O1 MUPFEKGTMRGPLJ-RMMQSMQOSA-N 0.000 description 1
- 102100037486 Reverse transcriptase/ribonuclease H Human genes 0.000 description 1
- 229920002125 Sokalan® Polymers 0.000 description 1
- DRQXUCVJDCRJDB-UHFFFAOYSA-N Turanose Natural products OC1C(CO)OC(O)(CO)C1OC1C(O)C(O)C(O)C(CO)O1 DRQXUCVJDCRJDB-UHFFFAOYSA-N 0.000 description 1
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 1
- 150000001298 alcohols Chemical class 0.000 description 1
- 125000003545 alkoxy group Chemical group 0.000 description 1
- WQZGKKKJIJFFOK-PHYPRBDBSA-N alpha-D-galactose Chemical compound OC[C@H]1O[C@H](O)[C@H](O)[C@@H](O)[C@H]1O WQZGKKKJIJFFOK-PHYPRBDBSA-N 0.000 description 1
- SRBFZHDQGSBBOR-STGXQOJASA-N alpha-D-lyxopyranose Chemical compound O[C@@H]1CO[C@H](O)[C@@H](O)[C@H]1O SRBFZHDQGSBBOR-STGXQOJASA-N 0.000 description 1
- 235000019418 amylase Nutrition 0.000 description 1
- 125000000129 anionic group Chemical group 0.000 description 1
- 239000003945 anionic surfactant Substances 0.000 description 1
- 239000003242 anti bacterial agent Substances 0.000 description 1
- 239000003963 antioxidant agent Substances 0.000 description 1
- PYMYPHUHKUWMLA-WDCZJNDASA-N arabinose Chemical compound OC[C@@H](O)[C@@H](O)[C@H](O)C=O PYMYPHUHKUWMLA-WDCZJNDASA-N 0.000 description 1
- SRSXLGNVWSONIS-UHFFFAOYSA-N benzenesulfonic acid Chemical class OS(=O)(=O)C1=CC=CC=C1 SRSXLGNVWSONIS-UHFFFAOYSA-N 0.000 description 1
- 150000001558 benzoic acid derivatives Chemical class 0.000 description 1
- 239000001110 calcium chloride Substances 0.000 description 1
- 229910001628 calcium chloride Inorganic materials 0.000 description 1
- 239000004202 carbamide Substances 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 125000005588 carbonic acid salt group Chemical group 0.000 description 1
- 239000001768 carboxy methyl cellulose Substances 0.000 description 1
- 235000010948 carboxy methyl cellulose Nutrition 0.000 description 1
- 239000008112 carboxymethyl-cellulose Substances 0.000 description 1
- 125000002091 cationic group Chemical group 0.000 description 1
- 239000003093 cationic surfactant Substances 0.000 description 1
- 229940106157 cellulase Drugs 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- 150000001896 cresols Chemical class 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- 239000010419 fine particle Substances 0.000 description 1
- 239000007850 fluorescent dye Substances 0.000 description 1
- 239000006260 foam Substances 0.000 description 1
- 229930182830 galactose Natural products 0.000 description 1
- MUPFEKGTMRGPLJ-WSCXOGSTSA-N gentianose Chemical compound O[C@H]1[C@H](O)[C@@H](CO)O[C@@]1(CO)O[C@@H]1[C@H](O)[C@@H](O)[C@H](O)[C@@H](CO[C@H]2[C@@H]([C@@H](O)[C@H](O)[C@@H](CO)O2)O)O1 MUPFEKGTMRGPLJ-WSCXOGSTSA-N 0.000 description 1
- DLRVVLDZNNYCBX-CQUJWQHSSA-N gentiobiose Chemical compound O[C@@H]1[C@@H](O)[C@H](O)[C@@H](CO)O[C@H]1OC[C@@H]1[C@@H](O)[C@H](O)[C@@H](O)C(O)O1 DLRVVLDZNNYCBX-CQUJWQHSSA-N 0.000 description 1
- 150000002334 glycols Chemical class 0.000 description 1
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 1
- 238000010348 incorporation Methods 0.000 description 1
- 238000011835 investigation Methods 0.000 description 1
- DLRVVLDZNNYCBX-RTPHMHGBSA-N isomaltose Chemical compound O[C@@H]1[C@@H](O)[C@H](O)[C@@H](CO)O[C@@H]1OC[C@@H]1[C@@H](O)[C@H](O)[C@@H](O)C(O)O1 DLRVVLDZNNYCBX-RTPHMHGBSA-N 0.000 description 1
- 239000008101 lactose Substances 0.000 description 1
- 235000019421 lipase Nutrition 0.000 description 1
- QWIZNVHXZXRPDR-WSCXOGSTSA-N melezitose Chemical compound O([C@@]1(O[C@@H]([C@H]([C@@H]1O[C@@H]1[C@@H]([C@@H](O)[C@H](O)[C@@H](CO)O1)O)O)CO)CO)[C@H]1O[C@H](CO)[C@@H](O)[C@H](O)[C@H]1O QWIZNVHXZXRPDR-WSCXOGSTSA-N 0.000 description 1
- QIGJYVCQYDKYDW-NSYYTRPSSA-N nigerose Chemical compound O[C@@H]1[C@@H](O)[C@H](O)[C@@H](CO)O[C@@H]1O[C@H]1[C@H](O)[C@@H](CO)OC(O)[C@@H]1O QIGJYVCQYDKYDW-NSYYTRPSSA-N 0.000 description 1
- 125000004433 nitrogen atom Chemical group N* 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 239000002304 perfume Substances 0.000 description 1
- 238000005191 phase separation Methods 0.000 description 1
- 150000003016 phosphoric acids Chemical class 0.000 description 1
- 239000004584 polyacrylic acid Substances 0.000 description 1
- 229920001223 polyethylene glycol Polymers 0.000 description 1
- 238000006116 polymerization reaction Methods 0.000 description 1
- 239000001267 polyvinylpyrrolidone Substances 0.000 description 1
- 229920000036 polyvinylpyrrolidone Polymers 0.000 description 1
- 235000013855 polyvinylpyrrolidone Nutrition 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 230000002265 prevention Effects 0.000 description 1
- 235000019419 proteases Nutrition 0.000 description 1
- 238000000425 proton nuclear magnetic resonance spectrum Methods 0.000 description 1
- 125000001453 quaternary ammonium group Chemical group 0.000 description 1
- 150000003242 quaternary ammonium salts Chemical class 0.000 description 1
- MUPFEKGTMRGPLJ-ZQSKZDJDSA-N raffinose Chemical compound O[C@H]1[C@H](O)[C@@H](CO)O[C@@]1(CO)O[C@@H]1[C@H](O)[C@@H](O)[C@H](O)[C@@H](CO[C@@H]2[C@@H]([C@@H](O)[C@@H](O)[C@@H](CO)O2)O)O1 MUPFEKGTMRGPLJ-ZQSKZDJDSA-N 0.000 description 1
- 238000002310 reflectometry Methods 0.000 description 1
- 210000002374 sebum Anatomy 0.000 description 1
- 238000001179 sorption measurement Methods 0.000 description 1
- 239000003381 stabilizer Substances 0.000 description 1
- 238000010186 staining Methods 0.000 description 1
- 125000001302 tertiary amino group Chemical group 0.000 description 1
- JOXIMZWYDAKGHI-UHFFFAOYSA-N toluene-4-sulfonic acid Chemical class CC1=CC=C(S(O)(=O)=O)C=C1 JOXIMZWYDAKGHI-UHFFFAOYSA-N 0.000 description 1
- RULSWEULPANCDV-PIXUTMIVSA-N turanose Chemical compound OC[C@@H](O)[C@@H](O)[C@@H](C(=O)CO)O[C@H]1O[C@H](CO)[C@@H](O)[C@H](O)[C@H]1O RULSWEULPANCDV-PIXUTMIVSA-N 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/37—Polymers
- C11D3/3703—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- C11D3/373—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds containing silicones
- C11D3/3742—Nitrogen containing silicones
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/662—Carbohydrates or derivatives
Definitions
- the present invention relates to a liquid detergent composition.
- the present invention relates to a light-duty liquid detergent composition having an excellent effect of preventing the shrinkage of clothes (effect of preventing felting shrinkage) and also a good rinsability.
- Delicate clothes made of wool or silk are usually washed by hands or a weak mechanical power with a light-duty detergent so as to prevent the damage to them.
- Conventional light-duty detergents of this type contain a polyoxyethylene alkyl ether, polyoxyethylene alkyl ether sulfate, alkylbenzenesulfonate, etc., as the main detergent base.
- alkyl saccharide surfactants attract attention, since they little irritate the skin and have lathering properties and, therefore, are usable as the light-duty detergent base.
- Japanese Patent Laid-Open No. 501641/1988 discloses a detergent composition for delicate cloths which contains an alkyl glycoside and an antistatic quaternary ammonium surfactant
- Japanese Patent Laid-Open No. 501642/1988 describes that a detergent composition for delicate cloths which contains an alkyl glycoside and an antistatic amine oxide is capable of imparting antistatic properties superior to those imparted when an ordinary polyoxyethylene alkyl ether is used.
- Japanese Patent Laid-Open No. 69695/1989 discloses a detergent composition containing both of an alkyl glycoside and an amphoteric surfactant and Japanese Patent Publication No.
- JP-A No. 25896/1984 describes that a detergent composition containing a nonionic surfactant having an HLB of 5 to 14, an alkyl glycoside and a di-(long-chain alkyl) quaternary ammonium salt is quite effective in removing stains in granular form and is capable of imparting softness and antistatic properties to the clothes.
- liquid detergent composition for clothes comprising:
- R1 in the general formula (I) preferably has 9 to 14 carbon atoms.
- R2 has preferably 2 or 3 carbon atoms.
- the water solubility and crystallizability vary depending on the value of x . The higher the value of x, the higher the water solubility and the lower the crystallizability.
- x is preferably in the range of 0 to 2, particularly 0.
- y is preferably in the range of 1 to 4. y is desirably selected in consideration of the properties ascribable to the hydrophobic group R1.
- R1 is a hydrophobic group having 9 to 11 carbon atoms on the average
- y is preferably 1 to 1.4
- y is preferably 1.5 to 4.0.
- the average degree of polymerization, y , of the reducing sugar can be determined by proton NMR.
- the bonds in the sugar chain may be 1-2, 1-3, 1-4 or 1-6 bond, ⁇ - or ⁇ -pyranoside bond or furanoside bond, or a combination of them.
- the structure of G varies depending on the starting monosaccharide or polysaccharide.
- the monosaccharides include glucose, fructose, galactose, xylose, mannose, lyxose and arabinose.
- the polysaccharides include maltose, xylobiose, isomaltose, cellobiose, gentiobiose, lactose, sucrose, nigerose, turanose, raffinose, gentianose and melezitose. They can be used either alone or in combination of two or more of them. Glucose and fructose are preferred among the monosaccharides and maltose and sucrose are preferred among the polysaccharides, because they are easily available and inexpensive.
- the amount of the component (a) is 5 to 70% by weight, preferably 10 to 40% by weight, based on the composition.
- Examples of the preferred amino-modified silicone or derivative thereof used as the component (b) in the present invention are compounds of the following general formula (II): wherein: R represents an alkyl group having 1 to 4 carbon atoms, a hydroxyl group or an alkoxy group, R1 groups may be the same or different from one another and each represent an alkyl group having 1 to 4 carbon atoms, A represents R1 or -(CH2) a -(OC2H4) b -(OC3H6) c -OR2 in which: a represents 2 or 3, b and c each represent 0 or 1 to 30 with the proviso that both of them do not represent 0 at the same time, and R2 represents an alkyl group having 1 to 24 carbon atoms; B represents in which: d and e each represent 2 to 6, R3 and R4 each represent a hydrogen atom or an alkyl group having 1 to 4 carbon atoms, X represents a hydrogen atom, an alkyl group having 1 to 24 carbon atoms or
- silicone compounds represented by the above general formula (II) those wherein B represents and X represents an alkyl group having 1 to 24 carbon atoms or are preferred.
- silicone compounds of the above general formula (II) those having a molecular weight of 2,000 to 150,000 and amine equivalent in the range of 1,000 to 20,000 are preferred and m and n are numbers variable depending on the molecular weight.
- the amount of the component (b) is 0.05 to 5% by weight, preferably 0.1 to 3% by weight, based on the composition.
- silicone compounds such as dimethylpolysiloxane can be incorporated into detergents in a very small amount as a lathering regulator.
- Japanese Patent Laid-Open No. 215099/1985 describes that when a small amount of an amino-modified silicone or its derivative is incorporated into a detergent in a small amount, the clothes washed therewith can be softened.
- these techniques neither teach nor suggest the construction or effect of the present invention wherein an alkyl glycoside is used.
- the balance of the composition of the present invention comprises water.
- another nonionic surfactant particularly, a polyoxyethylene (having an average molar number of addition of 5 to 20) alkyl (C9 to C14) ether
- the deterging effect thereof is further improved without impairing the effect of the present invention.
- Incorporation of a cationic surfactant is undesirable, since its adsorbability on the clothes is higher than that of the modified silicone and, therefore, the adsorption of the amino-modified silicone would be inhibited.
- An anionic or amphoteric surfactant can be incorporated thereinto in only a small amount (not more than 5% by weight, preferably not more than 1% by weight, based on the composition).
- composition of the present invention may contain other components ordinarily incorporated into such a light-duty detergent.
- antiredeposition agents such as polyacrylic acid, polyvinylpyrrolidone, polyethylene glycol and carboxymethylcellulose; enzymes such as protease, amylase, lipase and cellulase; enzyme stabilizers such as calcium chloride; a solubilizing agent such as lower alcohols such as ethanol, benzenesulfonates and lower alkylbenzenesulfonates such as p-toluenesulfonates, glycols such as propylene glycol, benzoic acid salts and urea; antioxidants such as t-butylhydroxytoluene and distyrenated cresol; as well as fluorescent dyes, bluing agents, perfumes and antibacterial agents.
- solubilizer Up to 15 wt.%, preferably up to 10 wt.%, of the solubilizer may be used here to prevent the phase separation. It is not needed when a small amount of a surfactant is only used.
- composition of the present invention is desirably substantially free from ordinary builders for detergents, not more than 2 or 3% by weight of a builder component such as a diglycolic acid salt, phosphoric acid salt or carbonic acid salt can be incorporated thereinto.
- a builder component such as a diglycolic acid salt, phosphoric acid salt or carbonic acid salt can be incorporated thereinto.
- a wool cloth, not yet treated for prevention of shrinking, having a size of 10 x 10 cm, three sides of which had been hemstitched with a lockstitch machine was immersed in city water at ambient temperature for 30 min, then dewatered in a dewatering tank of a washing machine for 30 sec, dried on a net and kept at 20°C and 65% RH for at least 4 h.
- the cloth was marked at four points with an oil-base felt pen and numbers were given to the marks. The distances between the marks (a 0 1 and a 0 2 in the direction of the length and b 0 1 and b 0 2 in the direction of the width) were measured. The distances will be called the "original length".
- R.M. represents the distances measured before washing (original length) and W.M. represents the distance measured after washing.
- W.S. represents the felting shrinkage in the direction of the width and L.S. represents the felt shrinkage in the direction of the length.
- rinse index The height (cm) of the lather 5 min after the washing and that 1 min after the press rinsing were macroscopically observed and evaluated according to the following criteria: rinse index:
- Perclene is the tradename of perchloroethylene.
- the detergency was determined by measuring the reflectivity of the original cloth before staining and those of the stained cloth before and after washing with an autographic colorimeter (mfd. by Shimadzu Corp. to calculate the deterging rate (%) according to the following equation (the average of the five samples is given in the Table):
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- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Molecular Biology (AREA)
- Detergent Compositions (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP4224/90 | 1990-01-10 | ||
| JP2004224A JPH06102796B2 (ja) | 1990-01-10 | 1990-01-10 | 衣料用液体洗浄剤組成物 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| EP0439019A1 true EP0439019A1 (de) | 1991-07-31 |
Family
ID=11578619
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| EP91100209A Withdrawn EP0439019A1 (de) | 1990-01-10 | 1991-01-08 | Flüssiges Reinigungsmittel für Kleider |
Country Status (3)
| Country | Link |
|---|---|
| EP (1) | EP0439019A1 (de) |
| JP (1) | JPH06102796B2 (de) |
| MY (1) | MY107192A (de) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US6043328A (en) * | 1995-05-19 | 2000-03-28 | Novartis Ag | Polysiloxane-polyol macromers, their preparation and their use |
| WO2025036643A1 (en) | 2023-08-15 | 2025-02-20 | Evonik Operations Gmbh | Biosurfactant for washing wool |
Families Citing this family (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE4225224A1 (de) * | 1992-07-30 | 1994-02-03 | Henkel Kgaa | Verfahren zur Herstellung von lagerstabilen nichtionischen Tensiden |
| JP3299865B2 (ja) * | 1995-09-01 | 2002-07-08 | 花王株式会社 | 洗浄剤組成物 |
| GB9604623D0 (en) * | 1996-03-04 | 1996-05-01 | Johnson & Son Inc S C | Stable aqueous silane solutions |
| JP3909143B2 (ja) * | 1997-04-21 | 2007-04-25 | 東レ・ダウコーニング株式会社 | 化粧品用基剤 |
| JP3909131B2 (ja) * | 1997-04-21 | 2007-04-25 | 東レ・ダウコーニング株式会社 | 化粧品用添加剤 |
| JP5184734B2 (ja) * | 2004-01-23 | 2013-04-17 | 日華化学株式会社 | ドライクリーニング用洗浄剤組成物 |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0094118B1 (de) * | 1982-05-10 | 1986-09-03 | THE PROCTER & GAMBLE COMPANY | Phosphatarme Wäschewaschmittelzusammensetzungen |
| EP0230565A1 (de) * | 1985-12-03 | 1987-08-05 | Hoffmann's Stärkefabriken AG | Wäschenachbehandlungsmittel |
| EP0363346A2 (de) * | 1988-10-07 | 1990-04-11 | The Procter & Gamble Company | Flüssiges Waschmittel mit härtbarer Siliciumverbindung mit Amin als funktioneller Gruppe zur Verminderung des Knitterns |
Family Cites Families (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB8401875D0 (en) * | 1984-01-25 | 1984-02-29 | Procter & Gamble | Liquid detergent compositions |
| US4848981A (en) * | 1985-11-25 | 1989-07-18 | Dow Corning Corp. | Method of improving the draining of water from textiles during a laundering operation |
| JP2657495B2 (ja) * | 1987-09-09 | 1997-09-24 | 株式会社資生堂 | 洗浄剤組成物 |
| JPH01168613A (ja) * | 1987-12-24 | 1989-07-04 | Shiseido Co Ltd | 洗浄剤組成物 |
-
1990
- 1990-01-10 JP JP2004224A patent/JPH06102796B2/ja not_active Expired - Lifetime
-
1991
- 1991-01-08 MY MYPI91000023A patent/MY107192A/en unknown
- 1991-01-08 EP EP91100209A patent/EP0439019A1/de not_active Withdrawn
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0094118B1 (de) * | 1982-05-10 | 1986-09-03 | THE PROCTER & GAMBLE COMPANY | Phosphatarme Wäschewaschmittelzusammensetzungen |
| EP0230565A1 (de) * | 1985-12-03 | 1987-08-05 | Hoffmann's Stärkefabriken AG | Wäschenachbehandlungsmittel |
| EP0363346A2 (de) * | 1988-10-07 | 1990-04-11 | The Procter & Gamble Company | Flüssiges Waschmittel mit härtbarer Siliciumverbindung mit Amin als funktioneller Gruppe zur Verminderung des Knitterns |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US6043328A (en) * | 1995-05-19 | 2000-03-28 | Novartis Ag | Polysiloxane-polyol macromers, their preparation and their use |
| WO2025036643A1 (en) | 2023-08-15 | 2025-02-20 | Evonik Operations Gmbh | Biosurfactant for washing wool |
Also Published As
| Publication number | Publication date |
|---|---|
| JPH06102796B2 (ja) | 1994-12-14 |
| JPH03207796A (ja) | 1991-09-11 |
| MY107192A (en) | 1995-09-30 |
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