EP0094118B1 - Phosphatarme Wäschewaschmittelzusammensetzungen - Google Patents

Phosphatarme Wäschewaschmittelzusammensetzungen Download PDF

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Publication number
EP0094118B1
EP0094118B1 EP83200604A EP83200604A EP0094118B1 EP 0094118 B1 EP0094118 B1 EP 0094118B1 EP 83200604 A EP83200604 A EP 83200604A EP 83200604 A EP83200604 A EP 83200604A EP 0094118 B1 EP0094118 B1 EP 0094118B1
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EP
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Prior art keywords
surfactant
nonionic
surfactants
compositions
ethylene oxide
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French (fr)
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EP0094118A1 (de
EP0094118B2 (de
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Thomas Edward Cook
Ernest Wilson Dolle
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Procter and Gamble Co
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Procter and Gamble Co
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Classifications

    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66—Non-ionic compounds
    • C11D1/835—Mixtures of non-ionic with cationic compounds
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66—Non-ionic compounds
    • C11D1/662—Carbohydrates or derivatives
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/38—Cationic compounds
    • C11D1/62—Quaternary ammonium compounds
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66—Non-ionic compounds
    • C11D1/72—Ethers of polyoxyalkylene glycols

Definitions

  • This invention relates to laundry detergent compositions which exhibit surprisingly effective detergency as well as fabric softening and static control, even in the total absence of detergency builder materials. Specifically, completely unbuilt compositions of the present invention have demonstrated the ability to provide good detergency, fabric softening and static control.
  • Other detergent compositions which utilize mixtures of selected nonionic surfactants and cationic surfactants are defined in U.S. Patents 4,259,217 and 4,222,905, as well as in European Patent Application 12 483 and in German Patent Application 2 948 921. European Patent Applications No. 75 995 and 75 996, both published 06.04.83, disclose built detergent compositions containing alkylpolysaccharides and nonionic surfactants.
  • compositions of the present invention have excellent cleaning capabilities and are relatively insensitive to water hardness conditions, performing well in both hard and soft water conditions. Finally, in addition to this cleaning performance, the present invention provides, in a single detergent product, fabric softening and static control to the laundered fabrics.
  • the present invention relates to low- or no- phosphate laundry detergent compositions, especially beneficial for good cleaning and the effective provision of softening and antistatic benefits, having a pH in the laundry solution of greater than about 7, and, preferably, containing no more than 15% phosphate, and no more than 10% silicate materials, which comprise from 5% to 100%, by weight, of a surfactant mixture containing:
  • the weight ratio of nonionic surfactant to alkylpolysaccharide surfactant is not greater than 7:1 preferably from 3:1 to 1:3, and the weight ratio of nonionic surfactant plus alkylpolysaccharide surfactant to quaternary ammonium cationic surfactant is in the range of from 2:1 to 12:1.
  • compositions of the present invention comprise, by weight, from 5 to 100%, preferably from 15 to 90%, and most preferably from 20 to 80%, of a mixture of particularly defined nonionic, alkylpolysaccharide and cationic surfactants in the ratios stated herein.
  • Preferred compositions contain at least 15% of the nonionic/alkylpoly- saccharide/cationic surfactant mixture and at least 1 1/2 of the cationic component, itself, in order to assure the presence of a sufficient amount of both the cationic surfactant and the mixture to provide the desired cleaning and fabric conditioning benefits.
  • compositions of the present invention contain the nonionic, alkylpolysaccharide and cationic surfactants, defined hereinafter, within ratios of nonionic and alkylpolysaccharide to cationic surfactant of from 2:1 to 12:1, preferably from 3:1 to 9:1 for cleaning; and most preferably from 4:1 to 9:1, in order to achieve the best soil removal performance.
  • compositions of the present invention are formulated so as to have a pH of greater than 7 in the laundry solution, at conventional usage concentrations, in order to optimize their overall cleaning performance, to aid in their manufacturing and processing, and to minimize the possibility of washing machine corrosion.
  • Alkalinity sources such as potassium hydroxide, potassium carbonate, potassium bicarbonate, sodium hydroxide, sodium carbonate and sodium bicarbonate, may be included in the compositions for this purpose.
  • Some of the cationic/nonionic systems of the present invention may attain optimum removal of greasy/oily soils at higher pH's, while attaining optimum particulate soil removal at relatively lower pH's. In these systems, overall performance may be enhanced by varying the pH of the wash solution during the laundering process.
  • compositions have a pH of at least about 8 in the laundry solution, in order to optimize the removal of greasy/oily and body soils.
  • these preferred compositions should also have the ability to maintain a pH in the laundry solution of from about 8 to 11 throughout the washing operation (reserve alkalinity).
  • a reserve alkalinity may be obtained by incorporating compounds which buffer at pH's of from about 8 to 11, such as monoethanolamine, diethanolamine or triethanolamine.
  • compositions of the present invention are also essentially free of oily hydrocarbon materials and solvents, such as mineral oil, paraffin oil and kerosene, since these materials, which are themselves oily by nature, load the washing liquor with excessive oily material, thereby diminishing the cleaning effectiveness of the compositions.
  • oily hydrocarbon materials and solvents such as mineral oil, paraffin oil and kerosene
  • the alkylpolysaccharides are those having a hydrophobic group containing preferably from 10 to 16 carbon atoms and a polysaccharide, e.g., a polyglycoside, hydrophilic group containing from 1,to 10, preferably from Is to 3, most preferably from 1.6 to 2.7 saccharide units.
  • Any reducing saccharide containing 5 or 6 carbon atoms can be used, e.g. glucose, galactose and galactosyl moieties can substitute for the glucosyl moieties.
  • hydrophobic group is attached at the 2, 3, 4 etc. positions thus giving a glucose or galactose as opposed to a glucoside or galactoside).
  • the intersaccharide bonds can be between the one position of the additional saccharide units and the 2-, 3-, 4-, and/or 6 positions on the preceding saccharide units.
  • polyalkoxide chain joining the hydrophobic moiety and the polysaccharide moiety.
  • the preferred alkoxide is ethylene oxide.
  • Typical hydrophobic groups include alkyl groups, either saturated or unsaturated, branched or unbranched containing from 8 to 18, preferably from 10 to 16 carbon atoms.
  • the alkyl group is a straight chain saturated alkyl group.
  • the alkyl group can contain up to 3 hydroxy groups and/or the polyalkoxide chain can contain up to 10, preferably less than 5, most preferably 0, alkoxide moieties.
  • Suitable alkyl polysaccharides are octyl, nonyl, decyl, undecyl, dodecyl, tridecyl, tetradecyl, pentadecyl, hexadecyl, heptadecyl, and octadecyl, di-, tri-, tetra-, penta-, and hexaglucosides, galactosides, lactosides, glucoses, fructosides, fructoses, and/or galactoses.
  • Suitable mixtures include coconut alkyl, di-, tri-, tetra-, and pentaglucosides and tallow alkyl tetra-, penta-, and hexaglucosides.
  • the preferred alkylpolyglycosides have the formula wherein R 2 is selected from the group consisting of alkyl, alkylphenyl, hydroxyalkyl, hydroxyalkylphenyl, and mixtures thereof in which said alkyl groups contain from 10 to 18, preferably from 12 to 14 carbon atoms; n is 2 or 3, preferably 2; t is from 0 to 10, preferably 0; and x is from 1a to 10, preferably from 12 to 3, most preferably from 1.6 to 2.7.
  • the glycosyl is preferably derived from glucose. To prepare compounds the alcohol or alkylpolyethoxy alcohol is formed first and then reacted with glucose, or a source of glucose, to form the glucoside (attachment at the 1-position). The additional glycosyl units are attached between their 1-position and the preceding glycosyl units 2-, 3-, 4- and/or 6- position, preferably predominately the 2-position.
  • the content of alkylmonoglycoside is low, preferably less than 60%, more preferably less than 50%.
  • Nonionic surfactants are well known in the detergency art. They are included in the compositions of the present invention together with the, e.g. alkylpolyglycoside surfactants defined hereinbefore. They may be used singly or in combination with one or more of the preferred alcohol ethoxylate nonionic surfactants, described below, to form nonionic surfactant mixtures useful in combination with the alkylpolyglycosides. Examples of such surfactants are listed in U.S. Pat. No. 3,717,630, Booth, issued Feb 20,1973, and U.S. Pat. No. 3,332,880, Kessler et al, issued July 25, 1967.
  • suitable nonionic surfactants which may be used in the present invention are as follows:
  • the conventional nonionic detergent surfactants which are preferred for use in the compositions of the present invention are biodegradable and have the formula R(OC2H4)nOH, wherein R is a primary alkyl chain containing an average of from 10 to 18, preferably from 10 to 16, carbon atoms, and n is an average of from 2 to 9, preferably from 2 to 7.
  • These nonionic surfactants have an HLB (hydrophilic-lipophilic balance) of from 5 to 14, preferably from 6 to 13.
  • HLB hydrophilic-lipophilic balance
  • HLB an indicator of a surfactants' hydrophilic or lipophilic nature, is defined in detail in Nonionic Surfactants, by M. J. Schick, Marcel Dekker, Inc., 1966, pages 607-613.
  • Preferred nonionic surfactants for use in the present invention include the condensation product of coconut alcohol with 5 moles of ethylene oxide; the condensation product of coconut alcohol with 6 moles of ethylene oxide; the condensation product of C 12-15 alcohol with 7 moles of ethylene oxide; the condensation product of C 12 - 15 alcohol with 9 moles of ethylene oxide; the condensation product of C 14-15 alcohol with 2.25 moles of ethylene oxide; the condensation product of C 14 - 15 alcohol with 7 moles of ethylene oxide; the condensation product of C 9-11 alcohol with 8 moles of ethylene oxide, which is stripped so as to remove unethoxylated and lower ethoxylate fractions; the condensation product of C 12 - 13 alcohol with 6.5 moles of ethylene oxide, and this same alcohol ethoxylate which is stripped so as to remove unethoxylated and lower ethoxylate fractions.
  • a preferred class of such surfactants utilize alcohols which contain 20% 2-methyl branched isomers, and are commercially available, under the tradename Neodol@, from Shell Chemical Company.
  • the condensation product of tallow alcohol with 9 moles of ethylene oxide is also a preferred nonionic surfactant for use herein.
  • Particularly preferred nonionic surfactants for use in the compositions of the present invention include the condensation product of coconut alcohol with 5 moles of ethylene oxide, the condensation product of C 12 - 13 alcohol with 6.5 moles of ethylene oxide, the condensation product of C 12 - 15 alcohol with 7 moles of ethylene oxide, the condensation product of C 14 - 15 alcohol with 7 moles of ethylene oxide, and mixtures of those surfactants.
  • nonionic surfactants well known in the detergency art may be used, in combination with one or more of the required nonionic surfactants, to form useful nonionic surfactant mixtures. Examples of such surfactants are listed in U.S. Pat. No. 3,717,630, Booth, issued Feb. 20, 1973, and U.S. Pat. No. 3,332,880, Kessler et al, issued July 25, 1967.
  • Nonlimiting examples of suitable nonionic surfactants which may be used in conjunction with the required nonionic surfactants, defined above, are: polyethylene oxide condensates of alkyl phenols, such as the Igepal@ surfactants, marketed by the GAF Corporation, and the Triton@ surfactants, marketed by the Rohm & Haas Company; condensation products of aliphatic alcohols with from 10 to 25 moles of ethylene oxide, where those alcohols are of a primary, branched or secondary alkyl chain structure; condensation products of ethylene oxide with a hydrophobic base formed by the condensation of propylene oxide with propylene glycol, such as Pluronic@ surfactants, marketed by Wyandotte Chemical Corporation; and condensation products of ethylene oxide with the product resulting from the reaction of propylene oxide and ethylene diamine, such as the Tetronic@ surfactants, marketed by Wyandotte Chemical Corporation.
  • polyethylene oxide condensates of alkyl phenols such as the Igepal@ surfactants, marketed
  • compositions of the present invention are substantially free of fatty acid polyglycol ether di-ester compounds, such as polyethylene glycol-600-dioleate or polyethylene glycol-800- distearate.
  • fatty acid polyglycol ether di-ester compounds such as polyethylene glycol-600-dioleate or polyethylene glycol-800- distearate.
  • the cationic surfactants used in the compositions of the present invention are of the di-long chain quaternary ammonium type, having two chains which contain an average of from 16 to 22, preferably from 16 to 18, carbon atoms.
  • the remaining groups, if any, attached to the quaternary nitrogen atom are preferably C 1 to C 4 alkyl or hydroxyalkyl groups.
  • the long chains be alkyl groups, these chains can contain hydroxy groups or can contain heteroatoms or other linkages, such as double or triple carbon-carbon bonds, and ester, amide, or ether linkages as long as each chain falls within the carbon atoms ranges required given above.
  • Preferred cationic surfactants are those having the formulae or wherein the R' and R groups contain an average of from 16 to 22 carbon atoms, preferably as alkyl groups, and most preferably contain an average of from 16 to 18 carbon atoms, R 3 and R 4 are C, to C 4 alkyl or hydroxyalkyl groups, and X is any compatible anion, particularly one selected from the group consisting of a halide (e.g., chloride), hydroxide, methylsulfate, or acetate anions.
  • a halide e.g., chloride
  • cationic surfactants can also be mixed with other types of cationic surfactants, such as sulfonium, phosphonium, and mono- or tri-long chain quaternary ammonium materials, as long as the amount of required cationic surfactant contained in the composition, falls with the nonionic:cationic ratio requirements specified herein.
  • cationic surfactants which can be used together with those required herein, include those described in U.S. Pat. 4,259,217, Murphy, U.S. Pat. 4,222,905, Cockrell, U.S. Pat. 4,260,529, Letton, and U.S. Pat. 4,228,042, Letton.
  • Preferred cationic surfactants include ditallow- alkyldimethyl (or diethyl or dihydroxyethyl) ammonium chloride, ditallowalkyldimethylammonium methyl sulfate, dihexadecylalkyl (C 16 ) dimethyl (or diethyl or dihydroxyethyl) ammonium chloride, dioctodecylalkyl (C, s )-dimethylammonium chloride, dieicosylalkyl-(C 20 ) dimethylammonium chloride, methyl (1) tallowalkyl amido ethyl (2) tallowalkyl imidazolinium methyl sulfate (commercially available as Varisoft@ 475 from Ashland Chemical Company), or mixtures of those surfactants.
  • Particularly preferred cationic surfactants are ditallowalkyldimethylammonium methyl sulfate, methyl (1) tallowalkyl amido ethyl (2) tallowalkyl imidazolinium methyl sulfate, and mixtures of those surfactants, with ditallowalkyldimethylammonium chloride being especially preferred.
  • compositions of the present invention can be formulated so as to be substantially free of ethoxylated cationic surfactants which contain more than an average of 10, and preferably free of those which contain more than an average of 7, moles of ethylene oxide per mole of surfactant. It is to be noted that polyethoxylated cationic surfactants having relatively low levels of ethoxylation, i.e., those with less than 10, and particularly less than 7, ethylene oxide groups exhibit better biodegradability characteristics.
  • the detergent compositions additionally contain from 2 to 25%, preferably from 2 to 16%, and most preferably from 2 to 10% of a fatty amide surfactant, such as ammonia amides (e.g., coconut ammonia amides), diethanol amides, and ethoxylated amides.
  • a fatty amide surfactant such as ammonia amides (e.g., coconut ammonia amides), diethanol amides, and ethoxylated amides.
  • ammonia amides e.g., coconut ammonia amides
  • diethanol amides e.g., diethanol amides
  • ethoxylated amides e.g., ethoxylated amides.
  • the ratio of the cationic/nonionic mixture to the amide component in the composition is in the range of from 5:1 to 50:1, preferably from 8:1 to 25:1.
  • These amide components may also be added in small amounts, i.e., from 2% to 5%, to act as suds modifiers. Specifically, it is believed that they tend to boost the sudsing in an active system which exhibits relatively low sudsing, and depress the sudsing in an active system which exhibits relatively high sudsing.
  • compositions of the present invention may also contain additional ingredients generally found in laundry detergent compositions, at their conventional art-established levels, as long as these ingredients are compatible with the nonionic and cationic components required herein.
  • the compositions can contain up to 15%, preferably up to 5%, and most preferably from 0.001 to 2%, of a suds suppressor component.
  • Typical suds suppressors useful in the compositions of the present invention include, but are not limited to, silicone-type suds suppressing additives which are described in U.S. Pat. 3,933,672, issued Jan. 20, 1976, Bartolotta et al, and the self-emulsifying silicone suds suppressors, described in U.S. Pat. 4,075,118, Gault et al.
  • An example of such a compound is DB-544@, commercially available from Dow Corning, which contains a siloxane/glycol copolymer together with solid silica and a siloxane resin.
  • Microcrystalline waxes having a melting point in the range from 35°C-115°C and a saponification value of less than 100 represent additional examples of a preferred suds regulating component for use in the subject compositions, and are described in detail in U.S. Pat. 4,056,481, Tate, issued Nov. 1, 1977.
  • Alkyl phosphate esters represent an additional preferred suds suppressant for use herein. These preferred phosphate esters are predominantly monostearyl phosphate which, in addition thereto, can contain di- and tristearyl phosphates and monooleyl phosphates, which can contain di-and trioleyl phosphates.
  • adjunct components which can be included in the compositions of the present invention, in their conventional art-established levels for use (i.e., from 0 to 40%), include semi-polar nonionic (such as trialkyl amine oxides), zwitterionic and ampholytic detergency cosurfactants; detergency builders; bleaching agents; bleach activators; soil release agents; soil suspending agents; corrosion inhibitors; dyes, fillers; optical brighteners; germicides; pH adjusting agents; alkalinity sources; hydrotropes; enzymes; enzyme-stabilizing agents; perfumes; solvents; carriers; suds modifiers; opacifiers; and the like.
  • compositions of the present invention can contain less than 15% phosphate materials.
  • Preferred compositions contain less than 7% phosphate, and can even be substantially, or totally free of such phosphate materials, without excessively decreasing the performance of the compositions.
  • the compositions of the present invention preferably contain less than 10%, and are preferably substantially free of, silicate, materials.
  • Preferred compositions of the present invention are also substantially free of carboxymethylcellulose.
  • compositions of the present invention can contain very small amounts of anionic materials, such as hydrotropes (e.g., alkali metal toluene sulfonates), it is preferred that particular anionic materials be contained in amounts sufficiently small such that not more than 10%, preferably not more than 1%, of the cationic surfactant, contained in the laundry solution, is complexed by the anionic material. Such a complexing of the anionic material with the cationic surfactant, decreases the overall cleaning and fabric conditioning performance of the composition. Suitable anionic materials can be selected based on their strength of complexation with the cationic material included in the composition (as indicated by their dissociation constant).
  • an anionic material when it has a dissociation constant of at least about 1x10- 3 (such as sodium toluene sulfonate), it can be contained in an amount up to 40%, by weight, of the cationic surfactant; and where the anionic material has a dissociation constant of at least 1 ⁇ 10 ⁇ °, but less than about 1x10- 3 , it can be contained in an amount up to 15%, by weight, of the cationic surfactant.
  • Preferred compositions are substantially or completely free of such anionic materials.
  • cosurfactants and detergency builders which can be used in the compositions of the present invention are found in U.S. Pat. 3,717,630, Booth, issued Feb. 20, 1973, and U.S. Pat. 4,259,217, Murphy.
  • these components, particularly the anionic surfactants should be checked with the particular nonionic/ cationic surfactant system chosen, and used in an amount, so as to be certain that they will be compatible with the nonionic/cationic surfactant system.
  • compositions of the present invention can be produced in a variety of forms, including liquid, solid, granular, paste, powder or substrate compositions.
  • the compositions of the present invention are formulated as liquids and contain up to 20% of a lower alkyl (C 1 to C 4 ) alcohol, particularly ethanol. Liquid compositions containing lower levels of such alcohols (i.e., 7 to 12%) tend to exhibit less phase separation than compositions containing higher alcohol levels.
  • compositions of the present invention are used in the laundering process by forming an aqueous solution containing from 0.01 (100 parts per million) to 0.3% (3,000 parts per million), preferably from 0.02 to 0.2%, and most preferably from 0.03 to 0.15%, of the nonionic/cationic detergent mixture, and agitating the soiled fabrics in that solution. The fabrics are then rinsed and dried.
  • the compositions of the present invention yield exceptionally good particulate soil removal, and also provide fabric softening, static control, color fidelity, and dye transfer inhibition to the laundered fabrics, without requiring the use of any of the other conventionally-used fabric softening and/or static control laundry additives.
  • compositions illustrate the advantage in softening and antistatic performance for the invention as compared to conventional compositions containing only conventional nonionic detergent surfactants.
  • Softening is determined by grading with expert graders who used a grading scale of 0 to 4 in which 0 is equal; 1 is “I think this one is better.”; 2 is “I know this one is a little better.”; 3 is “This one is a lot better.”; and 4 is “This one is a whole lot better.” A difference of about 3/4 is significant.
  • the softening grades for A and B as compared to the base were 1.6 to 1.9 which are significant.
  • C was compared to the base and was essentially equal in cleaning and static control, but was superior in softening.
  • the invention provides equal or better cleaning. With respect to static only, H is equivalent to the base with only one half of the static agent.
  • nonionic surfactant in Composition A is replaced, in whole or in part, by the condensation product of C 14 - 15 alcohol with 2.25 moles of ethylene oxide; the condensation product of C 14 - 15 alcohol with 7 moles of ethylene oxide; the condensation product of C 12-5 alcohol with 9 moles of ethylene oxide; the condensation product of C 12-13 alcohol with 6.5 moles of ethylene oxide, which is stripped so as to remove lower ethoxylate and nonethoxylated fractions; the condensation product of coconut alcohol with 5 moles of ethylene oxide; the condensation product of coconut alcohol with 6 moles of ethylene oxide; the condensation product of C 12 - 15 alcohol with 7 moles of ethylene oxide; the condensation product of tallow alcohol with 9 moles of ethylene oxide; a 1:1 by weight mixture of the condensation product of C 12 - 15 alcohol with 7 moles of ethylene oxide and the condensation product of C 14-15 alcohol with 7 moles of ethylene oxide; and other mixtures of those surfactants.
  • the above composition additionally contains monoethanolamine, diethanolamine or triethanolamine, as an alkalinity source.
  • compositions contain a silicone suds suppressor selected from the group consisting of trimethyl-, diethyl-, dipropyl-, dibutyl-, methylethyl-, phenylmethyl polysiloxane, and mixtures thereof; a petrolatum or oxidized petrolatum wax; a Fischer-Tropsch or oxidized Fischer-Tropsch wax; ozokerite; ceresin; montan wax; beeswax; candelilla; or carnauba wax.
  • silicone suds suppressor selected from the group consisting of trimethyl-, diethyl-, dipropyl-, dibutyl-, methylethyl-, phenylmethyl polysiloxane, and mixtures thereof; a petrolatum or oxidized petrolatum wax; a Fischer-Tropsch or oxidized Fischer-Tropsch wax; ozokerite; ceresin; montan wax; beeswax; candelilla; or carnauba wax.

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Claims (4)

1. Eine phosphatarme Wäschewschmittelzusammensetzung, die in der Wäschewaschlösung einen pH von mehr als 7 aufweist, umfassend 5 Gew.-% bis 100 Gew.-% eines Gemisches oberflächenaktiver Mittel mit einem Gehalt an
- einem nichtionischen Detergens-oberflächenaktiven Mittel mit einem HLB von 5 bis 14, oder einem Gemisch solcher oberflächenaktiver Mittel;
- einem kationischen, quaternären Ammonium-oberflächenaktiven Mittel, das 2 Ketten aufweist, welche im Durchschnitt 16 bis 22 Kohlenstoffatome enthalten, oder einem Gemisch solcher oberflächenaktiver Mittel,

dadurch gekennzeichnet, daß das Gemisch oberflächenaktiver Mittel zusätzlich ein Alkylpolysaccharid - Detergens - oberflächenaktives Mittel der Formel RO (R'O)y(Z)x, worin R ein Alkyl, Hydroxyalkyl, Alkylphenyl, Hydroxyalkylphenyl, Alkylbenzyl, oder Mischungen davon, ist, enthält, wobei die genannten Alkylgruppen 8 bis 18 Kohlenstoffatome enthalten; jeder Rest R' 2 bis 4 Kohlenstoffatome enthält, und y für 0 bis 12 steht; und wobei jeder Rest Z ein solcher ist, der aus einem reduzierenden, 5 oder 6 Kohlenstoffatome enthaltenden Saccharid stammt, und x eine Zahl von 1 1/2 bis 10 darstellt; und wobei
das Gewichtsverhältnis von nichtionischem oberflächenaktivem Mittel zu Alkylpolyaccharid - oberflächenaktivem Mittel nicht größer als 7:1 ist; und das Gewichtsverhältnis von nichtionischem oberflächenaktivem Mittel+Alkylpolysaccharid- oberflächenaktivem Mittel zu kationischen, quaternärem Ammonium - oberflächenaktivem Mittel im Bereich von 2:1 bis 12:1 liegt.
2. Eine Zusammensetzung nach Anspruch 1, wobei das Gewichtsverhältnis von nichtionischem oberflächenaktivem Mittel+Alkylpolysaccharid - oberflächenaktivem Mittel zu kationischem, quaternärem Ammonium - oberflächenaktivem Mittel im Bereich von 3:1 bis 9:1 liegt.
3. Eine Zusammensetzung nach Anspruch 1 oder 2, wobei das Alkylpolysaccharid-oberflächenaktive Mittet die Formel R2O(C2H4O)t (Glycosyl)x hat, worin R aus der Gruppe aus- . gewählt ist, die aus Alkyl, Alkylphenyl, Hydroxyalkyl, Hydroxyalkylphenyl, und Mischungen davon, besteht, t 0 bis 10 ist, der Glycosylrest von Glucose abgeleitet ist, und x 1/2 bis 3 beträgt.
4. Eine Zusammensetzung nach Anspruch 3, wobei das Gewichtsverhältnis von nichtionischem oberflächenaktivem Mittel zu Alkylpolysaccharid-oberflächenaktivem Mittel 3:1 bis 1:3 beträgt.
EP83200604A 1982-05-10 1983-04-28 Phosphatarme Wäschewaschmittelzusammensetzungen Expired - Lifetime EP0094118B2 (de)

Priority Applications (1)

Application Number Priority Date Filing Date Title
AT83200604T ATE21926T1 (de) 1982-05-10 1983-04-28 Phosphatarme waeschewaschmittelzusammensetzungen.

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US37687782A 1982-05-10 1982-05-10
US376877 1982-05-10

Publications (3)

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EP0094118A1 EP0094118A1 (de) 1983-11-16
EP0094118B1 true EP0094118B1 (de) 1986-09-03
EP0094118B2 EP0094118B2 (de) 1993-04-21

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EP83200604A Expired - Lifetime EP0094118B2 (de) 1982-05-10 1983-04-28 Phosphatarme Wäschewaschmittelzusammensetzungen

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EP (1) EP0094118B2 (de)
JP (1) JPS5925896A (de)
AT (1) ATE21926T1 (de)
CA (1) CA1209005A (de)
DE (1) DE3365810D1 (de)
GR (1) GR78555B (de)
IE (1) IE55426B1 (de)

Cited By (20)

* Cited by examiner, † Cited by third party
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US4622154A (en) * 1984-04-19 1986-11-11 Lever Brothers Company Aqueous fabric softening composition
US4627925A (en) * 1984-04-19 1986-12-09 Lever Brothers Company Aqueous concentrated fabric softening composition
FR2593516A1 (fr) * 1986-01-30 1987-07-31 Colgate Palmolive Co Composition detergente et assouplissante liquide pour tissus contenant un alkyl-glycoside et procede pour nettoyer et assouplir simultanement des tissus
EP0246246A1 (de) * 1985-09-26 1987-11-25 Henkel Kommanditgesellschaft auf Aktien Waschmittelzubereitung für feine gewebe
US4780234A (en) * 1986-05-06 1988-10-25 Staley Continental, Inc. Built liquid laundry detergent containing alkyl glycoside surfactant
EP0377500A2 (de) * 1989-01-05 1990-07-11 Unilever Plc Wäschebehandlungsmittel
EP0418479A1 (de) * 1989-08-04 1991-03-27 Hüls Aktiengesellschaft Emulgatoren zur Herstellung von lagerstabilen, wässrigen Polysiloxan-bzw. Polysiloxan-Paraffinöl-Emulsionen
EP0439019A1 (de) * 1990-01-10 1991-07-31 Kao Corporation Flüssiges Reinigungsmittel für Kleider
WO1993003130A1 (de) * 1991-07-29 1993-02-18 Henkel Kommanditgesellschaft Auf Aktien Flüssiges waschmittel
US5268126A (en) * 1989-08-04 1993-12-07 Huels Aktiengesellschaft Emulsifiers for the preparation of aqueous polysiloxane emulsions and aqueous polysiloxane-paraffin oil emulsions with long shelf lives
US5330674A (en) * 1992-09-09 1994-07-19 Henkel Corporation Method for increasing the efficiency of a disinfectant cleaning composition using alkyl polyglycosides
US5576284A (en) * 1994-09-26 1996-11-19 Henkel Kommanditgesellschaft Auf Aktien Disinfecting cleanser for hard surfaces
EP0753567A1 (de) 1995-07-14 1997-01-15 The Procter & Gamble Company Beim Waschen weichmachende Zusammensetzungen
EP0753569A1 (de) 1995-07-14 1997-01-15 The Procter & Gamble Company Stabile flüssige, beim Waschen weichmachende Zusammensetzungen
US5627144A (en) * 1992-09-11 1997-05-06 Henkel Kommanditgesellschaft Auf Aktien Composition for enhanced crude oil recovery operations containing hydrochloric acid or hydrofluoric acid, or mixtures thereof with ester quaternary ammonium compounds or/and alkyl quaternary ammonium compounds
EP0773284A1 (de) 1995-11-10 1997-05-14 The Procter & Gamble Company Mikroemulsion mit hohem Gehalt an anionischen Tensiden unter Verwendung verzweigter Fettsäuren
GB2323377A (en) * 1997-03-20 1998-09-23 Procter & Gamble Detergent compositions
GB2323382A (en) * 1997-03-20 1998-09-23 Procter & Gamble Detergent compositions
GB2323391A (en) * 1997-03-20 1998-09-23 Akzo Nobel Nv Dryer-activated fabric conditioning and antistatic compositions
GB2323375A (en) * 1997-03-20 1998-09-23 Procter & Gamble Detergent compositions

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EP0680314B1 (de) * 1993-01-23 1997-05-07 Henkel Kommanditgesellschaft auf Aktien Detergensgemische mit verbesserten avivageeigenschaften
EP0752466A1 (de) 1995-07-05 1997-01-08 The Procter & Gamble Company Brausesysteme enthaltende nichtwässrige Waschmittelzusammensetzungen
JP3264837B2 (ja) * 1996-08-23 2002-03-11 花王株式会社 濃厚系液体洗浄剤組成物
JP3398286B2 (ja) * 1996-08-23 2003-04-21 花王株式会社 液体洗浄剤組成物
DE10005855A1 (de) * 2000-02-10 2001-08-23 Wacker Chemie Gmbh Flächengebilde aus Polyester
US7998920B2 (en) 2008-01-22 2011-08-16 Stepan Company Sulfonated estolide compositions containing magnesium sulfate and processes employing them
US7879790B2 (en) 2008-01-22 2011-02-01 Stepan Company Mixed salts of sulfonated estolides and other derivatives of fatty acids, and methods of making them
US7666828B2 (en) 2008-01-22 2010-02-23 Stepan Company Sulfonated estolides and other derivatives of fatty acids, methods of making them, and compositions and processes employing them
BRPI0915728A2 (pt) 2008-07-07 2015-10-27 Basf Se composição enzimática, processo para preparar a composição, uso da composição enzimática, e, composição detergente.
US8119588B2 (en) 2009-01-21 2012-02-21 Stepan Company Hard surface cleaner compositions of sulfonated estolides and other derivatives of fatty acids and uses thereof
US8058223B2 (en) 2009-01-21 2011-11-15 Stepan Company Automatic or machine dishwashing compositions of sulfonated estolides and other derivatives of fatty acids and uses thereof
US7884064B2 (en) 2009-01-21 2011-02-08 Stepan Company Light duty liquid detergent compositions of sulfonated estolides and other derivatives of fatty acids
US8124577B2 (en) 2009-01-21 2012-02-28 Stepan Company Personal care compositions of sulfonated estolides and other derivatives of fatty acids and uses thereof
EP2277860B1 (de) 2009-07-22 2015-08-19 Stepan Company Zusammensetzungen, die sulfonierte Estolide und Alkylestersulfonate umfassen, Verfahren zu deren Herstellung und Zusammensetzungen und Verfahren, die diese Zusammensetzungen einsetzen
BR112016028904A8 (pt) 2014-06-09 2021-05-04 Stepan Co detergente de vestuário, líquido, pó, pasta, grânulo, tablete, sólido moldado, folha solúvel em água, sachê solúvel em água, cápsula, ou casulo solúvel em água e método
WO2016111884A2 (en) 2015-01-08 2016-07-14 Stepan Company Cold-water laundry detergents
WO2016160407A1 (en) 2015-03-31 2016-10-06 Stepan Company Detergents based on alpha-sulfonated fatty ester surfactants
WO2016196555A1 (en) 2015-06-02 2016-12-08 Stepan Company Cold-water cleaning method
WO2017100051A2 (en) 2015-12-07 2017-06-15 Stepan Comapny Cold-water cleaning compositions and methods
CN109642188A (zh) 2016-05-20 2019-04-16 斯特潘公司 用于衣物洗涤剂的聚醚胺组合物

Family Cites Families (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3707535A (en) * 1969-07-24 1972-12-26 Atlas Chem Ind Process for preparing mono- and polyglycosides
JPS4945772A (de) * 1972-09-04 1974-05-01 Seiko Instr & Electronics
US4228042A (en) * 1978-06-26 1980-10-14 The Procter & Gamble Company Biodegradable cationic surface-active agents containing ester or amide and polyalkoxy group
JPS54163907A (en) * 1978-03-13 1979-12-27 Procter & Gamble Low phosphate detergent composition for washing
CH644891A5 (de) * 1978-03-13 1984-08-31 Procter & Gamble Waeschewaschmittel.
US4239659A (en) * 1978-12-15 1980-12-16 The Procter & Gamble Company Detergent compositions containing nonionic and cationic surfactants, the cationic surfactant having a long alkyl chain of from about 20 to about 30 carbon atoms
GR76287B (de) * 1981-09-28 1984-08-04 Procter & Gamble
GR76286B (de) * 1981-09-28 1984-08-04 Procter & Gamble

Cited By (24)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4627925A (en) * 1984-04-19 1986-12-09 Lever Brothers Company Aqueous concentrated fabric softening composition
US4622154A (en) * 1984-04-19 1986-11-11 Lever Brothers Company Aqueous fabric softening composition
EP0246246A1 (de) * 1985-09-26 1987-11-25 Henkel Kommanditgesellschaft auf Aktien Waschmittelzubereitung für feine gewebe
EP0246246A4 (de) * 1985-09-26 1988-01-07 Staley Mfg Co A E Waschmittelzubereitung für feine gewebe.
BE1002958A4 (fr) * 1986-01-30 1991-10-08 Colgate Palmolive Co Composition detergente et assouplissante liquide pour tissus contenant un alkyl-glycoside et procede pour nettoyer et assouplir simultanement des tissus.
FR2593516A1 (fr) * 1986-01-30 1987-07-31 Colgate Palmolive Co Composition detergente et assouplissante liquide pour tissus contenant un alkyl-glycoside et procede pour nettoyer et assouplir simultanement des tissus
US4780234A (en) * 1986-05-06 1988-10-25 Staley Continental, Inc. Built liquid laundry detergent containing alkyl glycoside surfactant
EP0377500A2 (de) * 1989-01-05 1990-07-11 Unilever Plc Wäschebehandlungsmittel
EP0377500A3 (de) * 1989-01-05 1991-11-21 Unilever Plc Wäschebehandlungsmittel
US5268126A (en) * 1989-08-04 1993-12-07 Huels Aktiengesellschaft Emulsifiers for the preparation of aqueous polysiloxane emulsions and aqueous polysiloxane-paraffin oil emulsions with long shelf lives
EP0418479A1 (de) * 1989-08-04 1991-03-27 Hüls Aktiengesellschaft Emulgatoren zur Herstellung von lagerstabilen, wässrigen Polysiloxan-bzw. Polysiloxan-Paraffinöl-Emulsionen
EP0439019A1 (de) * 1990-01-10 1991-07-31 Kao Corporation Flüssiges Reinigungsmittel für Kleider
WO1993003130A1 (de) * 1991-07-29 1993-02-18 Henkel Kommanditgesellschaft Auf Aktien Flüssiges waschmittel
US5330674A (en) * 1992-09-09 1994-07-19 Henkel Corporation Method for increasing the efficiency of a disinfectant cleaning composition using alkyl polyglycosides
US5627144A (en) * 1992-09-11 1997-05-06 Henkel Kommanditgesellschaft Auf Aktien Composition for enhanced crude oil recovery operations containing hydrochloric acid or hydrofluoric acid, or mixtures thereof with ester quaternary ammonium compounds or/and alkyl quaternary ammonium compounds
US5576284A (en) * 1994-09-26 1996-11-19 Henkel Kommanditgesellschaft Auf Aktien Disinfecting cleanser for hard surfaces
US5856290A (en) * 1994-09-26 1999-01-05 Henkel Kommanditgesellschaft Auf Aktien Disinfecting cleanser for hard surfaces based on mixtures of APG and C8 -C18 alkyl ether
EP0753569A1 (de) 1995-07-14 1997-01-15 The Procter & Gamble Company Stabile flüssige, beim Waschen weichmachende Zusammensetzungen
EP0753567A1 (de) 1995-07-14 1997-01-15 The Procter & Gamble Company Beim Waschen weichmachende Zusammensetzungen
EP0773284A1 (de) 1995-11-10 1997-05-14 The Procter & Gamble Company Mikroemulsion mit hohem Gehalt an anionischen Tensiden unter Verwendung verzweigter Fettsäuren
GB2323377A (en) * 1997-03-20 1998-09-23 Procter & Gamble Detergent compositions
GB2323382A (en) * 1997-03-20 1998-09-23 Procter & Gamble Detergent compositions
GB2323391A (en) * 1997-03-20 1998-09-23 Akzo Nobel Nv Dryer-activated fabric conditioning and antistatic compositions
GB2323375A (en) * 1997-03-20 1998-09-23 Procter & Gamble Detergent compositions

Also Published As

Publication number Publication date
DE3365810D1 (en) 1986-10-09
EP0094118A1 (de) 1983-11-16
JPH05438B2 (de) 1993-01-05
EP0094118B2 (de) 1993-04-21
CA1209005A (en) 1986-08-05
JPS5925896A (ja) 1984-02-09
ATE21926T1 (de) 1986-09-15
IE831062L (en) 1983-11-10
IE55426B1 (en) 1990-09-12
GR78555B (de) 1984-09-27

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