EP0416278B2 - Gekrepptes Zellstoff-Tissuepapier - Google Patents
Gekrepptes Zellstoff-Tissuepapier Download PDFInfo
- Publication number
- EP0416278B2 EP0416278B2 EP90114566A EP90114566A EP0416278B2 EP 0416278 B2 EP0416278 B2 EP 0416278B2 EP 90114566 A EP90114566 A EP 90114566A EP 90114566 A EP90114566 A EP 90114566A EP 0416278 B2 EP0416278 B2 EP 0416278B2
- Authority
- EP
- European Patent Office
- Prior art keywords
- paper
- tissue paper
- unbleached
- tissue
- ply
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 229920002678 cellulose Polymers 0.000 title claims abstract description 13
- 239000001913 cellulose Substances 0.000 title claims abstract description 13
- 229920005610 lignin Polymers 0.000 claims abstract description 8
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 claims abstract description 6
- 229910021653 sulphate ion Inorganic materials 0.000 claims abstract 3
- LSNNMFCWUKXFEE-UHFFFAOYSA-L sulfite Chemical compound [O-]S([O-])=O LSNNMFCWUKXFEE-UHFFFAOYSA-L 0.000 claims abstract 2
- 239000000835 fiber Substances 0.000 claims description 7
- 241000294754 Macroptilium atropurpureum Species 0.000 claims description 5
- 239000000126 substance Substances 0.000 claims description 3
- 230000007935 neutral effect Effects 0.000 abstract 1
- 238000004519 manufacturing process Methods 0.000 description 13
- 239000002023 wood Substances 0.000 description 5
- 239000000853 adhesive Substances 0.000 description 4
- 230000001070 adhesive effect Effects 0.000 description 4
- 238000001035 drying Methods 0.000 description 4
- 229910052801 chlorine Inorganic materials 0.000 description 3
- 239000000460 chlorine Substances 0.000 description 3
- 238000000034 method Methods 0.000 description 3
- 238000012360 testing method Methods 0.000 description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 3
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 2
- 241000218657 Picea Species 0.000 description 2
- LSNNMFCWUKXFEE-UHFFFAOYSA-N Sulfurous acid Chemical compound OS(O)=O LSNNMFCWUKXFEE-UHFFFAOYSA-N 0.000 description 2
- 238000004061 bleaching Methods 0.000 description 2
- 238000002474 experimental method Methods 0.000 description 2
- 230000009965 odorless effect Effects 0.000 description 2
- 238000012545 processing Methods 0.000 description 2
- 239000000243 solution Substances 0.000 description 2
- 239000002351 wastewater Substances 0.000 description 2
- 244000166124 Eucalyptus globulus Species 0.000 description 1
- 240000000731 Fagus sylvatica Species 0.000 description 1
- 235000010099 Fagus sylvatica Nutrition 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- -1 chlorine dioxins Chemical class 0.000 description 1
- 239000002274 desiccant Substances 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 238000011156 evaluation Methods 0.000 description 1
- 230000001815 facial effect Effects 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 238000001228 spectrum Methods 0.000 description 1
- 238000005507 spraying Methods 0.000 description 1
- 239000000725 suspension Substances 0.000 description 1
- 230000003655 tactile properties Effects 0.000 description 1
- 231100000331 toxic Toxicity 0.000 description 1
- 230000002588 toxic effect Effects 0.000 description 1
- 239000003053 toxin Substances 0.000 description 1
- 231100000765 toxin Toxicity 0.000 description 1
- 108700012359 toxins Proteins 0.000 description 1
- 238000000209 wet digestion Methods 0.000 description 1
Classifications
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H11/00—Pulp or paper, comprising cellulose or lignocellulose fibres of natural origin only
- D21H11/02—Chemical or chemomechanical or chemothermomechanical pulp
- D21H11/04—Kraft or sulfate pulp
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H11/00—Pulp or paper, comprising cellulose or lignocellulose fibres of natural origin only
- D21H11/02—Chemical or chemomechanical or chemothermomechanical pulp
- D21H11/06—Sulfite or bisulfite pulp
Definitions
- the invention relates to a creped tissue paper, the basis weight of which is 14-16 g / m 2 atro.
- tissue paper are used in particular for the production of hygiene paper, for example toilet paper, handkerchiefs, facial tissues or kitchen towels.
- hygiene paper for example toilet paper, handkerchiefs, facial tissues or kitchen towels.
- they are put together on laying machines to form 2-layer, 3-layer or 4-layer sheets and, if necessary, stamped together.
- Their special properties are that they are remarkably tear-resistant with great softness and are also suitable for absorbing practically sufficient amounts of liquid.
- bleached raw cellulose is produced from various types of wood, for example spruce wood, beech wood, eucalyptus wood, by chemical wet digestion using the sulfite or sulfate process.
- the bleached raw pulp fibers are suspended in water for the production of tissue paper and then formed into a web on the paper machine, usually on the twin-wire paper machine.
- the web is finally dried on a heated drying cylinder, with sufficient adhesion of the web to the cylinder surface being ensured by spraying an adhesive onto the surface of the drying cylinder or by adding adhesive chemicals to the stock suspension.
- the web dries with a single revolution of the cylinder; the web is then scraped off the cylinder surface using a scraper with creping.
- the dry tensile strengths achieved in the longitudinal direction vary depending on the basis weight. For a 1-ply web with a basis weight of 15 g / m 2 lutro, dry tensile strengths in the machine direction of 6-7 N / 50 mm are generally achieved.
- the prerequisite for the production of creped tissue paper qualities of this type is the use of bleached raw pulp grades, the lignin content of which is practically reduced to zero%.
- the use of unbleached cellulose grades has not been considered for high-quality hygienic paper, since the residual lignin content in the unbleached cellulose leads to rough tissue qualities.
- it would be desirable to be able to use unbleached raw pulp for the production of tissue paper since it is known that the chlorine bleaching process that was previously necessary and also carried out leads to wastewater heavily contaminated with dirt and toxins. In particular, it interferes with the inevitable formation of toxic chlorine dioxins, which pollute the wastewater. This is basically not a problem of the actual tissue paper production, but concerns the pulp manufacturing; nevertheless, the entire chain from the initial wood to the finished tissue product must be taken into account from an environmental point of view.
- the invention is therefore based on the object of proposing a creped cellulose tissue paper with improved dry tear strength in the machine direction and improved tactile softness.
- tissue webs with a basis weight of 15.2 ⁇ 0.5 g / m 2 lutro (1-ply) were produced.
- the weight per unit area is reduced by approx. 0.2 g / m 2 by stretching the web, by processing by a further 0.5 to 0.7 g / m 2 .
- tissue webs of the same basis weight were then produced on the same paper machine using unbleached sulfate raw pulp.
- 2-ply and 3-ply toilet paper sheets and 4-ply handkerchief sheets were produced from both webs on fabrication laying machines and various paper-technical measured values were determined on them. The following compilation shows the result.
- the products produced had a tactile softness that was superior to that of bleached pulp webs.
- the products produced therefore have good properties in terms of dry tensile strength in the machine direction and also good tactile softness.
- they sometimes have the disadvantage that a slight smell is noticeable when the wipes are moistened, similar to the case with moist wrapping paper. It was determined by further experiments that this odor can be completely eliminated if the paper contains 5-30% by weight, preferably 25% by weight, of unbleached sulfite pulp fibers. This admixture has no influence on the strength or the tactile properties; however, it causes the paper produced to be odorless in both dry and wet conditions.
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Paper (AREA)
- Sanitary Thin Papers (AREA)
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE3928129 | 1989-08-25 | ||
DE3928129A DE3928129C1 (enrdf_load_stackoverflow) | 1989-08-25 | 1989-08-25 |
Publications (4)
Publication Number | Publication Date |
---|---|
EP0416278A2 EP0416278A2 (de) | 1991-03-13 |
EP0416278A3 EP0416278A3 (en) | 1991-12-04 |
EP0416278B1 EP0416278B1 (de) | 1994-09-21 |
EP0416278B2 true EP0416278B2 (de) | 1997-12-03 |
Family
ID=6387872
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP90114566A Expired - Lifetime EP0416278B2 (de) | 1989-08-25 | 1990-07-30 | Gekrepptes Zellstoff-Tissuepapier |
Country Status (4)
Country | Link |
---|---|
EP (1) | EP0416278B2 (enrdf_load_stackoverflow) |
AT (1) | ATE111991T1 (enrdf_load_stackoverflow) |
DE (2) | DE3928129C1 (enrdf_load_stackoverflow) |
ES (1) | ES2059926T5 (enrdf_load_stackoverflow) |
Families Citing this family (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE3928129C1 (enrdf_load_stackoverflow) * | 1989-08-25 | 1991-03-07 | Vp-Schickedanz Ag, 8500 Nuernberg, De | |
DE4409372A1 (de) * | 1994-03-18 | 1995-09-21 | Schickedanz Ver Papierwerk | Verfahren zur Herstellung von gekrepptem Hygiene-Zellstoffpapier |
DE4414238A1 (de) * | 1994-04-23 | 1995-10-26 | Schickedanz Ver Papierwerk | Haushalts- oder Hygienepapier sowie Verfahren zur Steigerung dessen Weichheit und Verringerung dessen Packvolumens |
DE19909835A1 (de) * | 1999-03-05 | 2000-09-07 | Sca Hygiene Prod Gmbh | Mehrschichtige Tissuebahn, Tissueprodukt sowie deren Herstellung |
PT115563B (pt) | 2019-06-03 | 2022-02-01 | Raiz Instituto De Investig Da Floresta E Papel | Pasta celulósica de eucalyptus globulus crua para produtos de papel tissue |
Family Cites Families (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
NO124193B (enrdf_load_stackoverflow) * | 1970-09-17 | 1972-03-20 | Star Paper Mill As | |
US3812000A (en) * | 1971-06-24 | 1974-05-21 | Scott Paper Co | Soft,absorbent,fibrous,sheet material formed by avoiding mechanical compression of the elastomer containing fiber furnished until the sheet is at least 80%dry |
DE3928129C1 (enrdf_load_stackoverflow) * | 1989-08-25 | 1991-03-07 | Vp-Schickedanz Ag, 8500 Nuernberg, De | |
DE3943404C1 (enrdf_load_stackoverflow) * | 1989-12-30 | 1990-11-29 | Vp-Schickedanz Ag, 8500 Nuernberg, De |
-
1989
- 1989-08-25 DE DE3928129A patent/DE3928129C1/de not_active Revoked
-
1990
- 1990-07-30 ES ES90114566T patent/ES2059926T5/es not_active Expired - Lifetime
- 1990-07-30 EP EP90114566A patent/EP0416278B2/de not_active Expired - Lifetime
- 1990-07-30 AT AT90114566T patent/ATE111991T1/de not_active IP Right Cessation
- 1990-07-30 DE DE59007226T patent/DE59007226D1/de not_active Expired - Fee Related
Also Published As
Publication number | Publication date |
---|---|
DE3928129C1 (enrdf_load_stackoverflow) | 1991-03-07 |
ES2059926T3 (es) | 1994-11-16 |
ATE111991T1 (de) | 1994-10-15 |
DE59007226D1 (de) | 1994-10-27 |
EP0416278B1 (de) | 1994-09-21 |
EP0416278A3 (en) | 1991-12-04 |
EP0416278A2 (de) | 1991-03-13 |
ES2059926T5 (es) | 1998-04-01 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
DE69528835T2 (de) | Verfahren zur herstellung von sanftem tissuepapier mit kationischen silikonen | |
DE1461271C3 (de) | Verfahren zur Herstellung von weichem, voluminösem und saugfähigem Papier | |
DE2231645A1 (de) | Weiches absorbierendes, faseriges Blattmaterial und Verfahren sowie Vorrichtung zur Herstellung desselben | |
DE68926800T2 (de) | Hand- oder Wischtuch | |
DE2608269A1 (de) | Weiches voluminoeses papiervlies und verfahren zur herstellung desselben | |
DE2725243A1 (de) | Verfahren zur herstellung geleimter papiere | |
DD222367A5 (de) | Herstellung von packpapier | |
DE2443099B2 (de) | Beschichtetes Papier für druckempfindliche Durchschreibsätze und Verfahren zu dessen Herstellung | |
DE69014433T2 (de) | Verfahren zur Herstellung eines Doppelgewebes und eines Produktes aus einem Doppelgewebe. | |
DE102014210879A1 (de) | Verfahren zur Herstellung von mehrlagigem Verpackungspapier, Papiermaschine zur Herstellung von mehrlagigem Verpackungspapier und mehrlagiges Verpackungspapier hergestellt nach diesem Verfahren | |
EP0416278B2 (de) | Gekrepptes Zellstoff-Tissuepapier | |
EP0851950B1 (de) | Mehrlagiges tissueprodukt mit ctmp-innenlage sowie dessen herstellung | |
DE60121010T2 (de) | Dünnes, weiches tissuepapier für badezimmer | |
DE19858616B4 (de) | Tissuepapierprodukt und dessen Verwendung sowie Lotion zur Behandlung des Tissueprodukts | |
AT524998B1 (de) | Bedruckbares, mehrlagiges Papier für Verpackungen und Verfahren zu dessen Herstellung | |
DE1097802B (de) | Verfahren zum Aufloesen von Altfaserstoffen, insbesondere Altpapier | |
DE1918415B2 (de) | Verfahren zum Oberflachenleimen einer Cellulosebahn | |
EP0856607A2 (de) | Mehrschichtiges Papier | |
EP1039027A1 (de) | Mehrschichtige Tissue-Papierbahn, Tissue-Papierprodukt sowie deren Herstellung | |
DE2542511C2 (de) | Verfahren zum Herstellen einer mehrschichtigen Bahn aus Zellulosematerial | |
DE102011005540A1 (de) | Herstellverfahren für eine Faserstoffbahn | |
DE2838799C3 (de) | Vulkanfiber und Verfahren zu ihrer Herstellung | |
DE3044781A1 (de) | Verfahren zur herstellung von photographischen papieren | |
DE4334367A1 (de) | Verfahren zur Herstellung von Gebrauchspapieren mit verbessertem Weichgriff | |
DE10141513A1 (de) | Verfahren und Vorrichtung zur Herstellung einer Faserstoffbahn aus mindestens einer Faserstoffsuspension |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
PUAI | Public reference made under article 153(3) epc to a published international application that has entered the european phase |
Free format text: ORIGINAL CODE: 0009012 |
|
AK | Designated contracting states |
Kind code of ref document: A2 Designated state(s): AT BE CH DE ES FR GB GR IT LI LU NL |
|
PUAL | Search report despatched |
Free format text: ORIGINAL CODE: 0009013 |
|
AK | Designated contracting states |
Kind code of ref document: A3 Designated state(s): AT BE CH DE ES FR GB GR IT LI LU NL |
|
17P | Request for examination filed |
Effective date: 19920415 |
|
17Q | First examination report despatched |
Effective date: 19930202 |
|
GRAA | (expected) grant |
Free format text: ORIGINAL CODE: 0009210 |
|
AK | Designated contracting states |
Kind code of ref document: B1 Designated state(s): AT BE CH DE ES FR GB GR IT LI LU NL |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: NL Effective date: 19940921 Ref country code: GR Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 19940921 Ref country code: BE Effective date: 19940921 |
|
REF | Corresponds to: |
Ref document number: 111991 Country of ref document: AT Date of ref document: 19941015 Kind code of ref document: T |
|
GBT | Gb: translation of ep patent filed (gb section 77(6)(a)/1977) |
Effective date: 19940928 |
|
REF | Corresponds to: |
Ref document number: 59007226 Country of ref document: DE Date of ref document: 19941027 |
|
ITF | It: translation for a ep patent filed | ||
REG | Reference to a national code |
Ref country code: ES Ref legal event code: FG2A Ref document number: 2059926 Country of ref document: ES Kind code of ref document: T3 |
|
ET | Fr: translation filed | ||
NLV1 | Nl: lapsed or annulled due to failure to fulfill the requirements of art. 29p and 29m of the patents act | ||
PLBI | Opposition filed |
Free format text: ORIGINAL CODE: 0009260 |
|
PLBI | Opposition filed |
Free format text: ORIGINAL CODE: 0009260 |
|
26 | Opposition filed |
Opponent name: PWA HYGIENEPAPIERE GMBH Effective date: 19950616 |
|
26 | Opposition filed |
Opponent name: MOELNLYCKE AB Effective date: 19950621 Opponent name: PWA HYGIENEPAPIERE GMBH Effective date: 19950616 |
|
PLBF | Reply of patent proprietor to notice(s) of opposition |
Free format text: ORIGINAL CODE: EPIDOS OBSO |
|
PLAW | Interlocutory decision in opposition |
Free format text: ORIGINAL CODE: EPIDOS IDOP |
|
PLAW | Interlocutory decision in opposition |
Free format text: ORIGINAL CODE: EPIDOS IDOP |
|
RAP2 | Party data changed (patent owner data changed or rights of a patent transferred) |
Owner name: THE PROCTER & GAMBLE COMPANY |
|
PUAH | Patent maintained in amended form |
Free format text: ORIGINAL CODE: 0009272 |
|
STAA | Information on the status of an ep patent application or granted ep patent |
Free format text: STATUS: PATENT MAINTAINED AS AMENDED |
|
REG | Reference to a national code |
Ref country code: CH Ref legal event code: PUE Owner name: VP - SCHICKEDANZ AG TRANSFER- THE PROCTER & GAMBLE |
|
27A | Patent maintained in amended form |
Effective date: 19971203 |
|
AK | Designated contracting states |
Kind code of ref document: B2 Designated state(s): AT BE CH DE ES FR GB GR IT LI LU NL |
|
REG | Reference to a national code |
Ref country code: CH Ref legal event code: AEN Free format text: AUFRECHTERHALTUNG DES PATENTES IN GEAENDERTER FORM |
|
ITF | It: translation for a ep patent filed | ||
ET3 | Fr: translation filed ** decision concerning opposition | ||
GBTA | Gb: translation of amended ep patent filed (gb section 77(6)(b)/1977) | ||
REG | Reference to a national code |
Ref country code: ES Ref legal event code: DC2A Kind code of ref document: T5 Effective date: 19980227 |
|
REG | Reference to a national code |
Ref country code: GB Ref legal event code: 732E |
|
REG | Reference to a national code |
Ref country code: GB Ref legal event code: IF02 |
|
PGFP | Annual fee paid to national office [announced via postgrant information from national office to epo] |
Ref country code: LU Payment date: 20030626 Year of fee payment: 14 |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: LU Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES Effective date: 20040730 |
|
PGFP | Annual fee paid to national office [announced via postgrant information from national office to epo] |
Ref country code: GB Payment date: 20060614 Year of fee payment: 17 Ref country code: AT Payment date: 20060614 Year of fee payment: 17 |
|
PGFP | Annual fee paid to national office [announced via postgrant information from national office to epo] |
Ref country code: FR Payment date: 20060705 Year of fee payment: 17 |
|
PGFP | Annual fee paid to national office [announced via postgrant information from national office to epo] |
Ref country code: CH Payment date: 20060707 Year of fee payment: 17 |
|
PGFP | Annual fee paid to national office [announced via postgrant information from national office to epo] |
Ref country code: ES Payment date: 20060710 Year of fee payment: 17 |
|
PGFP | Annual fee paid to national office [announced via postgrant information from national office to epo] |
Ref country code: IT Payment date: 20060731 Year of fee payment: 17 Ref country code: DE Payment date: 20060731 Year of fee payment: 17 |
|
REG | Reference to a national code |
Ref country code: CH Ref legal event code: PL |
|
GBPC | Gb: european patent ceased through non-payment of renewal fee |
Effective date: 20070730 |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: LI Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES Effective date: 20070731 Ref country code: DE Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES Effective date: 20080201 Ref country code: CH Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES Effective date: 20070731 |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: GB Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES Effective date: 20070730 |
|
REG | Reference to a national code |
Ref country code: FR Ref legal event code: ST Effective date: 20080331 |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: AT Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES Effective date: 20070730 |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: FR Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES Effective date: 20070731 |
|
REG | Reference to a national code |
Ref country code: ES Ref legal event code: FD2A Effective date: 20070731 |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: ES Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES Effective date: 20070731 |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: IT Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES Effective date: 20070730 |