EP0390338B1 - Méthode pour fabriquer un substrat pour une tête d'enregistrement à jet liquide - Google Patents
Méthode pour fabriquer un substrat pour une tête d'enregistrement à jet liquide Download PDFInfo
- Publication number
- EP0390338B1 EP0390338B1 EP90302165A EP90302165A EP0390338B1 EP 0390338 B1 EP0390338 B1 EP 0390338B1 EP 90302165 A EP90302165 A EP 90302165A EP 90302165 A EP90302165 A EP 90302165A EP 0390338 B1 EP0390338 B1 EP 0390338B1
- Authority
- EP
- European Patent Office
- Prior art keywords
- recording head
- ink
- jet recording
- protective layer
- substrate
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 239000000758 substrate Substances 0.000 title claims abstract description 23
- 238000004519 manufacturing process Methods 0.000 title claims abstract description 14
- 239000007788 liquid Substances 0.000 title description 41
- 239000011241 protective layer Substances 0.000 claims abstract description 38
- 238000000034 method Methods 0.000 claims abstract description 30
- 239000011148 porous material Substances 0.000 claims description 19
- 239000000463 material Substances 0.000 claims description 10
- 230000001681 protective effect Effects 0.000 claims description 8
- 238000005530 etching Methods 0.000 claims description 7
- 239000000126 substance Substances 0.000 claims description 4
- 239000000945 filler Substances 0.000 abstract description 12
- 238000004544 sputter deposition Methods 0.000 abstract description 6
- 239000000976 ink Substances 0.000 description 55
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 34
- 239000010410 layer Substances 0.000 description 26
- 238000007599 discharging Methods 0.000 description 19
- 239000010408 film Substances 0.000 description 19
- 229910052681 coesite Inorganic materials 0.000 description 17
- 229910052906 cristobalite Inorganic materials 0.000 description 17
- 239000000377 silicon dioxide Substances 0.000 description 17
- 235000012239 silicon dioxide Nutrition 0.000 description 17
- 229910052682 stishovite Inorganic materials 0.000 description 17
- 229910052905 tridymite Inorganic materials 0.000 description 17
- 239000000428 dust Substances 0.000 description 14
- 239000011810 insulating material Substances 0.000 description 9
- BLRPTPMANUNPDV-UHFFFAOYSA-N Silane Chemical compound [SiH4] BLRPTPMANUNPDV-UHFFFAOYSA-N 0.000 description 8
- 230000007547 defect Effects 0.000 description 7
- 230000000694 effects Effects 0.000 description 6
- MGWGWNFMUOTEHG-UHFFFAOYSA-N 4-(3,5-dimethylphenyl)-1,3-thiazol-2-amine Chemical compound CC1=CC(C)=CC(C=2N=C(N)SC=2)=C1 MGWGWNFMUOTEHG-UHFFFAOYSA-N 0.000 description 5
- 230000008859 change Effects 0.000 description 5
- JCXJVPUVTGWSNB-UHFFFAOYSA-N nitrogen dioxide Inorganic materials O=[N]=O JCXJVPUVTGWSNB-UHFFFAOYSA-N 0.000 description 5
- 229910052782 aluminium Inorganic materials 0.000 description 4
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 4
- 230000008569 process Effects 0.000 description 4
- 229910000077 silane Inorganic materials 0.000 description 4
- 230000009471 action Effects 0.000 description 3
- 238000009835 boiling Methods 0.000 description 3
- 238000005520 cutting process Methods 0.000 description 3
- 239000007787 solid Substances 0.000 description 3
- LTPBRCUWZOMYOC-UHFFFAOYSA-N Beryllium oxide Chemical compound O=[Be] LTPBRCUWZOMYOC-UHFFFAOYSA-N 0.000 description 2
- 229910003862 HfB2 Inorganic materials 0.000 description 2
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 2
- 238000009825 accumulation Methods 0.000 description 2
- 238000004140 cleaning Methods 0.000 description 2
- 230000000052 comparative effect Effects 0.000 description 2
- 239000004020 conductor Substances 0.000 description 2
- 230000007797 corrosion Effects 0.000 description 2
- 238000005260 corrosion Methods 0.000 description 2
- 238000001704 evaporation Methods 0.000 description 2
- 230000008020 evaporation Effects 0.000 description 2
- 238000010438 heat treatment Methods 0.000 description 2
- 238000009413 insulation Methods 0.000 description 2
- 238000000206 photolithography Methods 0.000 description 2
- 238000011084 recovery Methods 0.000 description 2
- 229910052710 silicon Inorganic materials 0.000 description 2
- 229910017083 AlN Inorganic materials 0.000 description 1
- 229910011255 B2O3 Inorganic materials 0.000 description 1
- 239000004642 Polyimide Substances 0.000 description 1
- 229910052581 Si3N4 Inorganic materials 0.000 description 1
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 description 1
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 1
- 230000008901 benefit Effects 0.000 description 1
- 230000008033 biological extinction Effects 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 239000003086 colorant Substances 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- 229910052593 corundum Inorganic materials 0.000 description 1
- JKWMSGQKBLHBQQ-UHFFFAOYSA-N diboron trioxide Chemical compound O=BOB=O JKWMSGQKBLHBQQ-UHFFFAOYSA-N 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- 238000001182 laser chemical vapour deposition Methods 0.000 description 1
- 230000007774 longterm Effects 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 229910003465 moissanite Inorganic materials 0.000 description 1
- 230000003287 optical effect Effects 0.000 description 1
- 238000000059 patterning Methods 0.000 description 1
- 239000012466 permeate Substances 0.000 description 1
- 239000012071 phase Substances 0.000 description 1
- 238000001020 plasma etching Methods 0.000 description 1
- 229920001721 polyimide Polymers 0.000 description 1
- 230000009467 reduction Effects 0.000 description 1
- 230000004044 response Effects 0.000 description 1
- 239000010703 silicon Substances 0.000 description 1
- 229910010271 silicon carbide Inorganic materials 0.000 description 1
- PBCFLUZVCVVTBY-UHFFFAOYSA-N tantalum pentoxide Inorganic materials O=[Ta](=O)O[Ta](=O)=O PBCFLUZVCVVTBY-UHFFFAOYSA-N 0.000 description 1
- 239000010409 thin film Substances 0.000 description 1
- 229910052718 tin Inorganic materials 0.000 description 1
- ZNOKGRXACCSDPY-UHFFFAOYSA-N tungsten(VI) oxide Inorganic materials O=[W](=O)=O ZNOKGRXACCSDPY-UHFFFAOYSA-N 0.000 description 1
- 239000012808 vapor phase Substances 0.000 description 1
- 229910001845 yogo sapphire Inorganic materials 0.000 description 1
Images
Classifications
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
- B41J—TYPEWRITERS; SELECTIVE PRINTING MECHANISMS, i.e. MECHANISMS PRINTING OTHERWISE THAN FROM A FORME; CORRECTION OF TYPOGRAPHICAL ERRORS
- B41J2/00—Typewriters or selective printing mechanisms characterised by the printing or marking process for which they are designed
- B41J2/005—Typewriters or selective printing mechanisms characterised by the printing or marking process for which they are designed characterised by bringing liquid or particles selectively into contact with a printing material
- B41J2/01—Ink jet
- B41J2/135—Nozzles
- B41J2/14—Structure thereof only for on-demand ink jet heads
- B41J2/14016—Structure of bubble jet print heads
- B41J2/14088—Structure of heating means
- B41J2/14112—Resistive element
- B41J2/14129—Layer structure
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
- B41J—TYPEWRITERS; SELECTIVE PRINTING MECHANISMS, i.e. MECHANISMS PRINTING OTHERWISE THAN FROM A FORME; CORRECTION OF TYPOGRAPHICAL ERRORS
- B41J2/00—Typewriters or selective printing mechanisms characterised by the printing or marking process for which they are designed
- B41J2/005—Typewriters or selective printing mechanisms characterised by the printing or marking process for which they are designed characterised by bringing liquid or particles selectively into contact with a printing material
- B41J2/01—Ink jet
- B41J2/135—Nozzles
- B41J2/16—Production of nozzles
- B41J2/1601—Production of bubble jet print heads
- B41J2/1603—Production of bubble jet print heads of the front shooter type
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
- B41J—TYPEWRITERS; SELECTIVE PRINTING MECHANISMS, i.e. MECHANISMS PRINTING OTHERWISE THAN FROM A FORME; CORRECTION OF TYPOGRAPHICAL ERRORS
- B41J2/00—Typewriters or selective printing mechanisms characterised by the printing or marking process for which they are designed
- B41J2/005—Typewriters or selective printing mechanisms characterised by the printing or marking process for which they are designed characterised by bringing liquid or particles selectively into contact with a printing material
- B41J2/01—Ink jet
- B41J2/135—Nozzles
- B41J2/16—Production of nozzles
- B41J2/1601—Production of bubble jet print heads
- B41J2/1604—Production of bubble jet print heads of the edge shooter type
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
- B41J—TYPEWRITERS; SELECTIVE PRINTING MECHANISMS, i.e. MECHANISMS PRINTING OTHERWISE THAN FROM A FORME; CORRECTION OF TYPOGRAPHICAL ERRORS
- B41J2/00—Typewriters or selective printing mechanisms characterised by the printing or marking process for which they are designed
- B41J2/005—Typewriters or selective printing mechanisms characterised by the printing or marking process for which they are designed characterised by bringing liquid or particles selectively into contact with a printing material
- B41J2/01—Ink jet
- B41J2/135—Nozzles
- B41J2/16—Production of nozzles
- B41J2/1621—Manufacturing processes
- B41J2/1626—Manufacturing processes etching
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
- B41J—TYPEWRITERS; SELECTIVE PRINTING MECHANISMS, i.e. MECHANISMS PRINTING OTHERWISE THAN FROM A FORME; CORRECTION OF TYPOGRAPHICAL ERRORS
- B41J2/00—Typewriters or selective printing mechanisms characterised by the printing or marking process for which they are designed
- B41J2/005—Typewriters or selective printing mechanisms characterised by the printing or marking process for which they are designed characterised by bringing liquid or particles selectively into contact with a printing material
- B41J2/01—Ink jet
- B41J2/135—Nozzles
- B41J2/16—Production of nozzles
- B41J2/1621—Manufacturing processes
- B41J2/1626—Manufacturing processes etching
- B41J2/1628—Manufacturing processes etching dry etching
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
- B41J—TYPEWRITERS; SELECTIVE PRINTING MECHANISMS, i.e. MECHANISMS PRINTING OTHERWISE THAN FROM A FORME; CORRECTION OF TYPOGRAPHICAL ERRORS
- B41J2/00—Typewriters or selective printing mechanisms characterised by the printing or marking process for which they are designed
- B41J2/005—Typewriters or selective printing mechanisms characterised by the printing or marking process for which they are designed characterised by bringing liquid or particles selectively into contact with a printing material
- B41J2/01—Ink jet
- B41J2/135—Nozzles
- B41J2/16—Production of nozzles
- B41J2/1621—Manufacturing processes
- B41J2/1632—Manufacturing processes machining
- B41J2/1634—Manufacturing processes machining laser machining
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
- B41J—TYPEWRITERS; SELECTIVE PRINTING MECHANISMS, i.e. MECHANISMS PRINTING OTHERWISE THAN FROM A FORME; CORRECTION OF TYPOGRAPHICAL ERRORS
- B41J2/00—Typewriters or selective printing mechanisms characterised by the printing or marking process for which they are designed
- B41J2/005—Typewriters or selective printing mechanisms characterised by the printing or marking process for which they are designed characterised by bringing liquid or particles selectively into contact with a printing material
- B41J2/01—Ink jet
- B41J2/135—Nozzles
- B41J2/16—Production of nozzles
- B41J2/1621—Manufacturing processes
- B41J2/164—Manufacturing processes thin film formation
- B41J2/1642—Manufacturing processes thin film formation thin film formation by CVD [chemical vapor deposition]
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
- B41J—TYPEWRITERS; SELECTIVE PRINTING MECHANISMS, i.e. MECHANISMS PRINTING OTHERWISE THAN FROM A FORME; CORRECTION OF TYPOGRAPHICAL ERRORS
- B41J2/00—Typewriters or selective printing mechanisms characterised by the printing or marking process for which they are designed
- B41J2/005—Typewriters or selective printing mechanisms characterised by the printing or marking process for which they are designed characterised by bringing liquid or particles selectively into contact with a printing material
- B41J2/01—Ink jet
- B41J2/135—Nozzles
- B41J2/16—Production of nozzles
- B41J2/1621—Manufacturing processes
- B41J2/164—Manufacturing processes thin film formation
- B41J2/1643—Manufacturing processes thin film formation thin film formation by plating
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
- B41J—TYPEWRITERS; SELECTIVE PRINTING MECHANISMS, i.e. MECHANISMS PRINTING OTHERWISE THAN FROM A FORME; CORRECTION OF TYPOGRAPHICAL ERRORS
- B41J2/00—Typewriters or selective printing mechanisms characterised by the printing or marking process for which they are designed
- B41J2/005—Typewriters or selective printing mechanisms characterised by the printing or marking process for which they are designed characterised by bringing liquid or particles selectively into contact with a printing material
- B41J2/01—Ink jet
- B41J2/135—Nozzles
- B41J2/16—Production of nozzles
- B41J2/1621—Manufacturing processes
- B41J2/164—Manufacturing processes thin film formation
- B41J2/1645—Manufacturing processes thin film formation thin film formation by spincoating
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
- B41J—TYPEWRITERS; SELECTIVE PRINTING MECHANISMS, i.e. MECHANISMS PRINTING OTHERWISE THAN FROM A FORME; CORRECTION OF TYPOGRAPHICAL ERRORS
- B41J2/00—Typewriters or selective printing mechanisms characterised by the printing or marking process for which they are designed
- B41J2/005—Typewriters or selective printing mechanisms characterised by the printing or marking process for which they are designed characterised by bringing liquid or particles selectively into contact with a printing material
- B41J2/01—Ink jet
- B41J2/135—Nozzles
- B41J2/16—Production of nozzles
- B41J2/1621—Manufacturing processes
- B41J2/164—Manufacturing processes thin film formation
- B41J2/1646—Manufacturing processes thin film formation thin film formation by sputtering
Definitions
- This invention as a typical manner of recording, relates to a method of manufacturing a substrate used as constitutional member for a liquid jet recording head which causes a condition change including the production of bubbles in liquid by heat energy, discharges the liquid from a discharge opening by the condition change to thereby form flying droplets, and causes the flying droplets to adhere to a recording surface to thereby accomplish recording of information such as characters and images, a substrate manufactured by the method, a liquid jet recording head formed by use of the substrate, and liquid jet recording apparatus having the haed.
- the non-impact recording methods have recently drawn more attention in that the production of noise during recording is negligibly small.
- the so-called ink jet recording method (the liquid jet recording method) which is capable of high-speed recording and moreover can effect recording on plain paper without requiring the special process of fixation is a very promising recording method, and various systems using it have heretofore been proposed and apparatuses which embody them have been desired, and some of them have been improved and commercialized and some are still now under the effort to put them into practical use.
- the liquid jet recording methods described, for example, in Japanese Laid-Open Patent Application No. 54-59936 (corresponding USP 4723129, 4740796) and German Laid-Open Patent Application (DOLS) No. 2843064 have a feature differing from that of the other liquid jet recording methods in that heat energy which is energy to be used for discharging liquid is caused to act on liquid to thereby obtain a motive force for liquid droplet discharge.
- liquid subjected to the action of the heat energy causes a condition change involving a steep increase in volume, and by an action force based on the condition change, a liquid is discharged as droplet from a discharge opening (hereinafter referred to as the orifice), for example, provided at the fore end of a recording head unit and flies and adheres to a recording medium, whereby recording of information is accomplished.
- a discharge opening hereinafter referred to as the orifice
- the liquid jet recording method disclosed in the above Gazzette can not only be very effectively applied to the so-called drop-on demand recording method, but also can be easily realized by providing the recording head unit with highly dense multiple orifices over the full line width thereof corresponding to the recording region of the recorded member and therefore, has an advantage that images of high resolution and high quality can be obtained at a high speed.
- An embodiment of the recording head of an apparatus applied to the above-described recording system is provided with a liquid discharge portion having an orifice provided to discharge ink as droplet therethrough and an ink liquid path provided with a heat-acting portion as a portion communicating with the orifice and causing heat energy to be used for discharging ink to act on the ink, and an electro-thermal transducer provided corresponding to the heat-acting portion as means for generating the heat energy.
- a typical example of this electro-thermal transducer comprises a pair of electrodes, and a heat generating resistance layer connected to these electrodes and a heat generating region (a heat generating portion) being constituted at a position corresponding to the portion between the electrodes.
- the heat generating resistance layer and electrodes are generally formed in the surface portion of the base plate of the ink jet recording head as a layer.
- An example of the prior-art construction of the base plate in which such an electro-thermal transducer is formed is shown in Figures 1A and 1B of the accompanying drawings. The example of the prior art will hereinafter be described with reference to these figures.
- Figure 1A is a fragmentary plan view showing the vicinity of an electro-thermal transducer in a substrate (hereinafter also referred to as the base plate) constituting an ink jet recording head
- Figure 1B is a fragmentary cross-sectional view of a portion indicated by dot-and-dash line XY in Figure 1A.
- the base plate 101 is formed by a lower layer 106, a heat generating resistance layer 107, electrodes 103, 104, a first upper protective layer 108, a second upper protective layer 109 and a third upper protective layer 110 successively laminated on a supporting member 105.
- the heat generating resistance layer 107 and electrodes 103 and 104 are patterned into a predetermined shape by etching. That is, in the other portions than the portion being constituted the heat generating region 102, they are patterned almost into one and the same shape, and in the portion, being constituted the heat generating region 102, the electrodes are not laminated on the heat generating resistance layer 107, but the heat generating resistance layer 107 constitutes a heat generating portion 111.
- the first upper protective layer 108 and the third upper protective layer 110 are laminated over the whole surface of the base plate 101, while the second upper protective layer 109 is patterned so as not to be laminated on the heat generating region 102.
- each layer provided in the surface portion of the base plate formed as described above is suitably chosen based on characteristics such as heat-resisting property, liquid-resisting property, heat conductivity and insulativeness required corresponding to respective portion of layers.
- the main function of the first upper protective layer 108 in the above-described example of the prior art is to keep the insulativeness between the common electrode 103 and the selected electrode 104
- the main function of the second upper protective layer 109 is to prevent the permeation of liquid and resist the liquid
- the main function of the third upper protective layer 110 is to reinforce the liquid-resisting property and mechanical strength.
- the third protective layer 110 is in contact with ink, and with regard to the defects of the film forming these layers, care must be particularly taken of insulativeness or the like.
- Pin-holes and dust in the film may be mentioned as the defects of the film, and with regard to pin-holes, for example, as shown in JP Laid-Open Patent Application No. 60-157872 (corresponding USP 4777494), could be dissolved by anode-oxidizing the ground of the film portion, but the entry of dust into the film could not be sufficiently dissolved.
- the first and third protective layers 108 and 110 need to be formed thin (for example, 3 ⁇ m at greatest) in view of efficiency of heat conductivity and accordingly, as the forming method therefor the vacuum accumulation method has been preferred.
- the vacuum accumulation method because of its system, cannot avoid the entry of dust into the film with a certain probability. And this is because, for example, when a vacuum container is made vacuum or again made vacuum after film formation, part of the film which has peeled from the wall of the vacuum container adheres to the base plate and becomes dust in the film.
- the presence of defects in the protective layers of the heat generating portion due to the entry of dust into the film reduces the durability of the head remarkably.
- the base plate is one on which for example, about twenty-four heater portions for discharging are formed, the probability with which the base plate becomes unsatisfactory is low and therefore, it will pose no problem in terms of yield to regard base plate entered dust as being unsatisfactory, but in the case of, for example, a base plate on which one thousand or more heater portions for discharging are formed, the probability of heater portions for discharging which suffer from the entry of dust into a base plate will become great and if all these are regarded as being unsatisfactory, it will cause a reduction in yield.
- an upper protective layer 204 is formed near the wirings 203 by a film making method such as the sputtering method, but in the location of this large hole 206, the wiring 203 could not be sufficiently covered with the upper protective layer 204.
- the ink has sometimes permeated into the portion in which the hole 206 has been formed to thereby corrode the electrodes 203, and finally this has sometimes led to the disconnection of the wirings.
- the reference numeral 205 designates that portion of the electrode which has been corroded by the ink.
- An object of the present invention is to provide a method of manufacturing a substrate for an ink jet recording head in which the problems due to pores created in the protective layer of an electro-thermal transducer generating heat energy to be used for discharging ink are overcome, whereby the durability of the recording head can be increased and the yield of manufacture thereof can be improved, a substrate manufactured by the method, a liquid jet recording head formed using the substrate, and a liquid jet recording apparatus having the head.
- a method of manufacturing a substrate for an ink jet recording head having an electro-thermal transducer disposed on a substrate supporting member and generating heat energy available to discharge ink, and a protective layer laminated so as to cover said electro-thermal transducer in order to protect said electro-thermal transducer from the ink, characterised by the step of filling any pore created in said protective layer with a protective material.
- Figures 3A and 3B are a top plan view and a side cross-sectional view, respectively, of a base plate (also called a substrate) for a recording head according to an embodiment of the present invention.
- a base plate also called a substrate
- FIGS 3A and 3B on a lower layer comprising SiO2 on which a supporting member 105 comprising Si is formed, a heat generating resistance member, a layer comprising HfB2 and Al conductive layer to form electrode are formed by the use of the vacuum thin film making technique.
- the patterns of a heat generating resistance member 102 and electrodes 103 and 104 are formed by the photolithography technique.
- a first protective layer 108 formed of SiO2 is formed with a thickness of 0.5 ⁇ m by sputtering.
- the base plate is inspected by means of an optical microscope, and the base plate having a defect 112 in the protective layer 108 for the heat generating resistance member 102 is extracted.
- This extracted base plate is then placed into a powerful ultrasonic wave tank, and dust (foreign substance) in the defect 112 is removed.
- the reference character 112A designates the pore from which the foreign substance has been removed.
- the base plate is placed into a vacuum chamber and silane (SiH4) and NO2 are poured thereinto to provide an atmosphere of 1 Torr.
- a laser beam is applied to the pore 112A, and in this portion, silane (SiH4) and NO2 are caused to react to each other.
- a filler 113 comprising SiO2 is accumulated in the pore 112A.
- the amount of SiO2 accumulated in the pore is adjusted by adjusting the application time of the laser beam.
- upper protective layers 109 and 110 are formed as shown in Figure 6, whereupon the manufacturing process for the base plate is completed.
- SiO2 layer 116 is formed into film having a thickness of 0.5 ⁇ m on the base plate as shown in Figure 4 by sputtering.
- Resist 114 (OFPR 800; trade name, manufactured by TOK Co., Ltd.) is then applied with a thickness of 4 ⁇ m by spin coat. A pattern having a window 114A formed corresponding to the pore is formed by the photolithography technique.
- resist 115 (OFPR 800; trade name, manufactured by TOK Co., Ltd.) is applied with a thickness of 1 ⁇ m by spin coat. The thickness of the resist 115 applied later is smaller than the thickness of the resist 114 applied earlier and therefore is not flattened, but assumes a shape as shown in Figure 8.
- CF4 and H2 are poured at a ratio of 1 : 1 by the use of a reactive ion etching apparatus, and etching is effected at a power of 400 W.
- the etching speed of the resist is 500 ⁇ /min. and that of SiO2 is 500 ⁇ /min. and therefore, the resist and SiO2 are etched at an equal speed.
- that portion of the heat generating resistance member to which the resist has been applied is such that the thickness of SiO2 116 is 0.5 ⁇ m, whereas the thickness of the resist 115 is 1 ⁇ m and therefore, the surface formed by etching becomes flat and accordingly, the resist is etched while keeping its original shape.
- etching is terminated.
- the shape of the base plate becomes such as shown in Figure 9.
- the resists 114 and 115 are peeled off, and a second protective layer 109 formed of organic polyimide is formed as a protective layer for electrodes 103 and 104.
- Ta is formed into film as a third protective layer 110 by sputtering, to thereby provide such a shape as shown in Figure 10.
- a recording head constructed of a base plate having a defect of about 3 ⁇ m diameter.
- the applied pulse use was made of a rectangular pulse having a frequency of 2 kHz and a pulse width of 10 ⁇ s, and the applied voltage was 1.2 times as great as the voltage value for ordinary discharge.
- the life of the recording head filled pore was more than 5 times that of the comparative example.
- the insulation between the ink and the electro-thermal transducer is reliably ensured.
- the defects of the base plate can be reduced and the yield is improved with a result that the manufacturing cost of the recording head can be reduced.
- Figures 11A-1 to 11A-4 and 11B-1 to 11B-4 show the steps of an embodiment of the present invention disclosed in EPC patent application EP-A-0 559 295 published on 08/03/93 being a divisional application of the present application.
- Figures 11A-1 to 11A-4 are plan views showing the course of the steps
- Figures 11B-1 to 11B-4 are corresponding cross-sectional views along line X-Y in Figures 11A-1 to 11A-4 which show the course of the steps.
- the reference numeral 201 designates a support member for a substrate (also called a base plate) 201A for a recording head
- the reference numeral 201B denotes a lower layer formed on the support member
- the reference numeral 202 denotes a heat generating resistance layer provided on the lower layer 201B
- the reference numeral 203 designates lead-out electrodes of aluminum connected to the heat generating resistance layer 202
- the reference numeral 204 denotes an upper protective layer formed of SiO2 and provided on the heat generating resistance layer 202 and the electrodes 203
- the reference numeral 206 designates a hole (a recess) created in the support member 201 by the cutting by a laser beam
- the reference numeral 207 denotes a short-circuited wiring portion
- the reference numeral 208 designates a filler formed of an insulating material such as SiO2 embedded in the hole 206.
- the electro-thermal transducer has at least the heat generating resistance layer 202 and the electrode
- the heat generating resistance layer 202 formed of HfB2 is laminated on the lower layer 201B formed of heat-oxidized SiO2 on the Si (silicon) support member 201, and the electrodes 203 of aluminum are deposited thereon by evaporation with a thickness of 5000 ⁇ and are subjected to patterning and wiring.
- the portion 207 is short-circuited.
- this short-circuited wiring portion 207 is cut by a laser beam.
- the short-circuited wiring portion 207 was actually short three times by a laser beam having a wavelength of 1.06 ⁇ m, a beam intensity of 20 mJ/puls and a pulse width of 20 nS, the short-circuited wiring portion 207 could be cut.
- Figure 11A-2 shows the state of that portion after cut, and it is seen that as shown in Figure 11B-2, a hole 206 is formed on the support member 201 at the cut portion thereof.
- the insulating material 208 as a filler is embedded into this hole 206.
- the depth of the hole 206 is 2 ⁇ m. Therefore, the substrate 201 - 204 is placed into a vacuum chamber, not shown, and a mixture gas of silane (SiH4) and nitrogen dioxide (NO2) is caused to flow into the chamber to thereby provide an atmosphere of 1 Torr.
- SiH4 silane
- NO2 nitrogen dioxide
- FIG. 11A-3 The state in which the hole 206 has been filled with the insulating material 208 which is SiO2 by such laser CVD (vapor phase growing method) is shown in Figure 11A-3.
- the filler 208 which is the insulating material is formed with said application time adjusted so that there may hardly be provided a level difference with respect to the height of the electrodes 203 of the wiring.
- the layer 204 of SiO2 as an upper protective layer is formed with a thickness of 1 ⁇ m on the filler 208 and the electrodes 203 by the sputtering method.
- the protective layer 204 of SiO2 sufficiently covers the hole 206 formed by cutting the short-circuited wiring portion of the electrodes 203 by the laser beam and the lead-out electrodes 203.
- Figure 12 shows an example of a recording head made by forming discharge openings of recording liquid in the recording head substrate made in this manner, and actually mounting an integrated circuit thereon.
- the reference numeral 211 designates heat generating portions (heater portions)
- the reference numeral 402 denotes discharge opening
- the reference numeral 403 designates an ink path wall forming liquid paths
- the reference numeral 404 denotes a common liquid chamber
- the reference numeral 405 designates a top plate
- the reference numeral 406 denotes ink supply ports.
- the liquid jet recording head shown in Figure 12 was subjected to an ink permeation test for a long period of time, but there occurred no corrosion of the electrodes 203 by the permeation of ink from the portion in which the hole 206 was created, i.e., the portion filled with the filler 208. Accordingly, it could be confirmed that the reliability of the recording head can be enhanced by filling the recess created in that portion of the support member in which the short-circuited wiring portion was cut by the laser beam as in the present embodiment with a filler such as an insulating material.
- the filler embedded into the hole may preferably be an insulating material, because there is the possibility of short-circuiting being caused between the wirings if the filler is not an insulating material.
- the insulating material embedded into the recess is SiO2, but of course, another insulating material may be used. That is, at least one kind selected from SiO2, Si3N4, SiC, Ta2O5, Al2O3, AlN, BN, B2O3, BeO, TiN, TiO2 and WO3 can be used as a preferred material.
- the direction of ink discharge is the surface direction of the heater portion 211, but the present invention is also applicable to a liquid jet recording head as shown in Figure 13 wherein ink is discharged in a direction almost perpendicular to the heater portion 211.
- the recess formed in the support member of the substrate by cutting the short-circuited wiring portion by a laser beam or the like is filled with a filler and the great level difference of the recess is eliminated so that the covering property of the upper protective layer for protecting the wiring may be improved and therefore, the permeation of the recording liquid into the electrode wiring portion can be prevented and the wiring is not corroded with a result that disconnection does not occur and the long-term reliability of the recording head can be improved.
- FIG 14 is a schematic perspective view showing an example of the ink jet recording apparatus IJRA to which the present invention is applied.
- a carriage HC which engages with a spiral groove 5004 of a lead screw 5005 being rotatable through driving force transmitting gears 5011, 5009 in conjunction with the reciprocal rotation of a drive motor 5013 has a pin (not shown) and is reciprocated in the directions of arrows a, b.
- 5002 is a paper holding plate and presses paper against a platen 5000 throughout the range of the movement of the carriage.
- 5007, 5008 are photocouplers, which are used as home position detecting means for detecting the presence of the lever 5006 of the carriage in the predetermined area to switch the direction of rotation of the motor 5013.
- 5016 is a member which holds a capping member 5022 for capping the front surface of a cartridge recording head IJC integrally provided with an ink tank.
- 5015 is a suction means for suction of the inside of the cap and effects suction recovery of the head through a opening 5023 in the cap.
- 5017 is a cleaning blade and 5019 is a member for moving the blade forward and afterward, the both being supported on a mainbody supporting member 5018.
- the shape of the blade is not limited to that shown in the figure, and any one of well known blades may be employed for this example.
- a lever for starting suction for suction recovery which moves in conjunction with the movement of a cam 5020 engaged with the carriage, whereby the driving force of the drive motor is transmitted by a conventional transmitting means such as clutch transfer and the like to be utilized for control.
- the present invention brings about excellent effects particularly in a recording head, recording device of the bubble jet system among the ink jet recording system.
- the on-demand type is effective because, by applying at least one driving signal which gives rapid temperature elevation exceeding nucleus boiling corresponding to the recording information on an electricity-heat convertors arranged corresponding to the sheets or liquid channels holding liquid (ink), heat energy is generated at the electricity-heat converters to effect film boiling at the heat acting surface of the recording head, and consequently the bubbles within the liquid (ink) can be formed corresponding one by one to the driving signals.
- the constitution of the recording head in addition to the combination constitutions of discharging orifice, liquid channel, electricity-heat converter (linear liquid channel or right angle liquid channel) as disclosed in the above-mentioned respective specifications, the constitution by use of U.S. Patent 4,558,333, 4,459,600 disclosing the constitution having the heat acting portion arranged in the flexed region is also included in the present invention.
- the present invention can be also effectively made the constitution as disclosed in Japanese Patent Laid-Open Application No. 59-123670 which discloses the constitution using a slit common to a plurality of electricity-heat converters as the discharging portion of the electricity-heat converter or Japanese Patent laid-Open Application No. 59-138461 which discloses the constitution having the opening for absorbing pressure wave of heat energy correspondent to the discharging portion.
- the recording head of the full line type having a length corresponding to the maximum width of recording medium which can be recorded by the recording device
- either the constitution which satisfies its length by combination of a plurality of recording heads as disclosed in the above-mentioned specifications or the constitution as one recording head integrally formed may be used, and the present invention can exhibit the effects as described above further effectively.
- the present invention is effective for a recording head of the freely exchangeable chip type which enables electrical connection to the main device or supply of ink from the main device by being mounted on the main device, or for the case by use of a recording head of the cartridge type provided integrally on the recording head itself.
- a restoration means for the recording head, a preliminary auxiliary means, etc. provided as the constitution of the recording device of the present invention is preferable, because the effect of the present invention can be further stabilized.
- Specific examples of these may include, for the recording head, capping means, cleaning means, pressurization or aspiration means, electricity-heat converters or another heating element or preliminary heating means according to a combination of these, and it is also effective for performing stable recording to perform preliminary mode which performs discharging separate from recording.
- the present invention is extremely effective for not only the recording mode only of a primary stream color such as black etc., but also a device equipped with at least one of plural different colors or full color by color mixing, whether the recording head may be either integrally constituted or combined in plural number.
- any ink which is solid or softened at room temperature may also be used in the present invention.
- the ink jet recording apparatus it is a common practice to control the temperature of ink itself within a range of 30 to 70 °C, thus adjusting the viscosity of the ink to be within the stable ejection range. Accordingly any ink which is liquid upon applying a recording signal may be used. Furthermore, any ink which is liquefied upon application of thermal energy may also be used in the present invention.
- Such a type of inks include, for example, one which upon application of thermal energy depending on recording signal, is liquefied to be ejected in the form of ink droplet and one which is being solidified at the time of arriving at a recording medium.
- Such a type of inks are used for the purpose of, for example, positively utilizing thermal energy as the energy for phase change of ink from solid to liquid to prevent temperature elevation due to thermal energy or using an ink which is solidified when left to stand to prevent evaporation of ink.
- the ink When such an ink is to be used, the ink may be held in the form of liquid or solid in recessed portions or through holes of a porous sheet while facing the electro-thermal transducer as shown in, for example, Japanese Laid-Open Patent Application Nos. 54-56847 and 60-71260.
- the most useful system for use of the inks as described above is the system effecting film boiling as described above.
Landscapes
- Engineering & Computer Science (AREA)
- Manufacturing & Machinery (AREA)
- Physics & Mathematics (AREA)
- Optics & Photonics (AREA)
- Particle Formation And Scattering Control In Inkjet Printers (AREA)
Claims (5)
- Procédé de fabrication d'un substrat pour une tête d'enregistrement à jet d'encre ayant un transducteur électrothermique disposé sur un élément de support de substrat et générant de l'énergie thermique utilisable pour décharger de l'encre, et une couche protectrice appliquée par stratification de façon à recouvrir ledit transducteur électrothermique pour protéger ledit transducteur électrothermique de l'encre, caractérisé par l'étape qui consiste à remplir d'une matière protectrice tout pore formé dans ladite couche protectrice.
- Procédé selon la revendication 1, dans lequel on réalise ledit remplissage en amenant plusieurs substances destinées à composer ladite matière protectrice à réagir entre elles dans ledit pore.
- Procédé selon la revendication 1, dans lequel on réalise ledit remplissage en formant en film ladite matière protectrice sur ledit pore dans ladite couche protectrice.
- Procédé selon la revendication 1, dans lequel on réalise ledit remplissage en formant en film ladite matière protectrice sur ledit pore dans ladite couche protectrice, et, après ladite formation en film, on élimine par attaque chimique, conformément à la configuration dudit pore, la partie de ladite matière protectrice autre que celle qui est concernée dans ledit remplissage.
- Procédé selon l'une quelconque des revendications 1-4, caractérisé par l'étape qui consiste à éliminer toute substance étrangère ayant pénétré dans ladite couche protectrice avant de remplir de matière protectrice un pore formé par ladite élimination.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
EP93201057A EP0559295B1 (fr) | 1989-03-01 | 1990-02-28 | Méthode pour fabriquer un substrat pour une tête d'enregistrement à jet liquide |
Applications Claiming Priority (4)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP4883989A JPH02227255A (ja) | 1989-03-01 | 1989-03-01 | 液体噴射記録ヘッド用基体の製造方法およびその方法により製造された基体、並びにその基体を用いた液体噴射記録ヘッド |
JP48838/89 | 1989-03-01 | ||
JP48839/89 | 1989-03-01 | ||
JP4883889A JP2659238B2 (ja) | 1989-03-01 | 1989-03-01 | インクジェット記録ヘッド、該ヘッド用基体および該基体の製造方法 |
Related Child Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP93201057.2 Division-Into | 1990-02-28 |
Publications (2)
Publication Number | Publication Date |
---|---|
EP0390338A1 EP0390338A1 (fr) | 1990-10-03 |
EP0390338B1 true EP0390338B1 (fr) | 1994-12-07 |
Family
ID=26389165
Family Applications (2)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP93201057A Expired - Lifetime EP0559295B1 (fr) | 1989-03-01 | 1990-02-28 | Méthode pour fabriquer un substrat pour une tête d'enregistrement à jet liquide |
EP90302165A Expired - Lifetime EP0390338B1 (fr) | 1989-03-01 | 1990-02-28 | Méthode pour fabriquer un substrat pour une tête d'enregistrement à jet liquide |
Family Applications Before (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP93201057A Expired - Lifetime EP0559295B1 (fr) | 1989-03-01 | 1990-02-28 | Méthode pour fabriquer un substrat pour une tête d'enregistrement à jet liquide |
Country Status (3)
Country | Link |
---|---|
EP (2) | EP0559295B1 (fr) |
AT (2) | ATE115051T1 (fr) |
DE (2) | DE69027685T2 (fr) |
Families Citing this family (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US5660739A (en) * | 1994-08-26 | 1997-08-26 | Canon Kabushiki Kaisha | Method of producing substrate for ink jet recording head, ink jet recording head and ink jet recording apparatus |
JPH09109392A (ja) | 1995-10-13 | 1997-04-28 | Canon Inc | インクジェット記録ヘッドの製造方法および同方法により製造されたインクジェット記録ヘッド、並びにインクジェット記録装置 |
RU2151066C1 (ru) * | 1998-11-03 | 2000-06-20 | Самсунг Электроникс Ко., Лтд. | Узел пластины сопла микроинжектора и способ его изготовления |
Citations (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP0217306A2 (fr) * | 1985-09-27 | 1987-04-08 | Hitachi, Ltd. | Imprimante à transmission de chaleur |
Family Cites Families (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
FR2473214A1 (fr) * | 1980-01-04 | 1981-07-10 | Thomson Csf | Plaquette de resistances en ligne a tres faible pas et barrette d'impression thermique utilisant cette plaquette de resistances en ligne |
JPS59194867A (ja) * | 1983-04-20 | 1984-11-05 | Canon Inc | ヘッドの製造方法 |
-
1990
- 1990-02-28 EP EP93201057A patent/EP0559295B1/fr not_active Expired - Lifetime
- 1990-02-28 DE DE69027685T patent/DE69027685T2/de not_active Expired - Fee Related
- 1990-02-28 EP EP90302165A patent/EP0390338B1/fr not_active Expired - Lifetime
- 1990-02-28 AT AT90302165T patent/ATE115051T1/de not_active IP Right Cessation
- 1990-02-28 DE DE69014690T patent/DE69014690T2/de not_active Expired - Fee Related
- 1990-02-28 AT AT93201057T patent/ATE139940T1/de not_active IP Right Cessation
Patent Citations (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP0217306A2 (fr) * | 1985-09-27 | 1987-04-08 | Hitachi, Ltd. | Imprimante à transmission de chaleur |
Non-Patent Citations (2)
Title |
---|
IEEE CIRCUITS AND DEVICES MAGAZINE, vol.2, no.1, January 1986, pages 18-24, New York, US; J.G. Eden: "Photochemical Processing of Semiconductors: New Applications for Visible and Ultraviolet Lasers" * |
PATENT ABSTRACTS OF JAPAN, vol.12, no.57 (M-670)(2904), 20 February 1988; & JP-A-62 204952 * |
Also Published As
Publication number | Publication date |
---|---|
ATE115051T1 (de) | 1994-12-15 |
EP0390338A1 (fr) | 1990-10-03 |
EP0559295B1 (fr) | 1996-07-03 |
DE69014690D1 (de) | 1995-01-19 |
EP0559295A1 (fr) | 1993-09-08 |
DE69027685T2 (de) | 1996-11-28 |
DE69014690T2 (de) | 1995-05-04 |
ATE139940T1 (de) | 1996-07-15 |
DE69027685D1 (de) | 1996-08-08 |
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