EP0364370B1 - Textile composite anti-feu imperméable et vêtement et siège comportant un tel textile - Google Patents

Textile composite anti-feu imperméable et vêtement et siège comportant un tel textile Download PDF

Info

Publication number
EP0364370B1
EP0364370B1 EP89402853A EP89402853A EP0364370B1 EP 0364370 B1 EP0364370 B1 EP 0364370B1 EP 89402853 A EP89402853 A EP 89402853A EP 89402853 A EP89402853 A EP 89402853A EP 0364370 B1 EP0364370 B1 EP 0364370B1
Authority
EP
European Patent Office
Prior art keywords
layer
textile
composite
water
impermeable
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
EP89402853A
Other languages
German (de)
English (en)
French (fr)
Other versions
EP0364370A1 (fr
Inventor
Christian Paire
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
PROLINE TEXTILE
Original Assignee
Lainiere de Picardie SA
Lainiere de Picardie BC SAS
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Family has litigation
First worldwide family litigation filed litigation Critical https://patents.darts-ip.com/?family=9371045&utm_source=google_patent&utm_medium=platform_link&utm_campaign=public_patent_search&patent=EP0364370(B1) "Global patent litigation dataset” by Darts-ip is licensed under a Creative Commons Attribution 4.0 International License.
Application filed by Lainiere de Picardie SA, Lainiere de Picardie BC SAS filed Critical Lainiere de Picardie SA
Priority to AT89402853T priority Critical patent/ATE99008T1/de
Publication of EP0364370A1 publication Critical patent/EP0364370A1/fr
Application granted granted Critical
Publication of EP0364370B1 publication Critical patent/EP0364370B1/fr
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Images

Classifications

    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N3/00—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
    • D06N3/0002—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof characterised by the substrate
    • D06N3/0015—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof characterised by the substrate using fibres of specified chemical or physical nature, e.g. natural silk
    • A—HUMAN NECESSITIES
    • A41—WEARING APPAREL
    • A41D—OUTERWEAR; PROTECTIVE GARMENTS; ACCESSORIES
    • A41D31/00—Materials specially adapted for outerwear
    • A41D31/04—Materials specially adapted for outerwear characterised by special function or use
    • A41D31/08—Heat resistant; Fire retardant
    • A41D31/085—Heat resistant; Fire retardant using layered materials
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M17/00—Producing multi-layer textile fabrics
    • D06M17/04—Producing multi-layer textile fabrics by applying synthetic resins as adhesives
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N7/00—Flexible sheet materials not otherwise provided for, e.g. textile threads, filaments, yarns or tow, glued on macromolecular material
    • D06N7/0092—Non-continuous polymer coating on the fibrous substrate, e.g. plastic dots on fabrics
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N2201/00—Chemical constitution of the fibres, threads or yarns
    • D06N2201/02—Synthetic macromolecular fibres
    • D06N2201/0263—Polyamide fibres
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N2203/00—Macromolecular materials of the coating layers
    • D06N2203/06—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • D06N2203/068—Polyurethanes
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N2205/00—Condition, form or state of the materials
    • D06N2205/04—Foam
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N2209/00—Properties of the materials
    • D06N2209/06—Properties of the materials having thermal properties
    • D06N2209/067—Flame resistant, fire resistant
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N2209/00—Properties of the materials
    • D06N2209/12—Permeability or impermeability properties
    • D06N2209/121—Permeability to gases, adsorption
    • D06N2209/123—Breathable
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N2209/00—Properties of the materials
    • D06N2209/12—Permeability or impermeability properties
    • D06N2209/126—Permeability to liquids, absorption
    • D06N2209/128—Non-permeable
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N2211/00—Specially adapted uses
    • D06N2211/10—Clothing
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S297/00—Chairs and seats
    • Y10S297/05—Fireproof
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S428/00—Stock material or miscellaneous articles
    • Y10S428/92—Fire or heat protection feature
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/24—Structurally defined web or sheet [e.g., overall dimension, etc.]
    • Y10T428/24802—Discontinuous or differential coating, impregnation or bond [e.g., artwork, printing, retouched photograph, etc.]
    • Y10T428/24826—Spot bonds connect components
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T442/00—Fabric [woven, knitted, or nonwoven textile or cloth, etc.]
    • Y10T442/60—Nonwoven fabric [i.e., nonwoven strand or fiber material]
    • Y10T442/647—Including a foamed layer or component
    • Y10T442/651—Plural fabric layers
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T442/00—Fabric [woven, knitted, or nonwoven textile or cloth, etc.]
    • Y10T442/60—Nonwoven fabric [i.e., nonwoven strand or fiber material]
    • Y10T442/647—Including a foamed layer or component
    • Y10T442/652—Nonwoven fabric is coated, impregnated, or autogenously bonded

Definitions

  • This treatment has a certain number of drawbacks, it is likely to reduce the fire resistance capacity of the textile and moreover it generally withstands maintenance well.
  • the waterproofing of the fabric obtained is not stable and decreases during washing or dry cleaning. It is difficult to obtain a resistance to a water column greater than 300mm in this way.
  • Document FR-A 2 283 201 proposes for this purpose to cover the foam with a glass fiber fabric.
  • Document DE-A 3,519,963 proposes the use of an external polyacrylate envelope.
  • films which are impermeable and permeable to water vapor and carbon dioxide, often called breathable (cf. DE-U 8 703 947, GB-A 2 143 151, Chemical Abstracts, vol. 102, no. 6, February 1985, page 70, summary no.47208p).
  • Document EP 0 037 744 proposes the use of a particular continuous non-porous breathable film in the production of protective clothing. This film can enter into the composition of a composite structure comprising a textile layer.
  • the invention also relates to the production of a garment or seat incorporating the textile of the invention so as to make the best use of its properties.
  • the clothing and seat thus produced must be comfortable.
  • a protective garment comprising an external textile assembly constituting its external surface and a lining constituting its internal surface, characterized in that it comprises an insert mounted flywheel between the external textile and the lining, said insert being a composite textile waterproof fireproof, comprising a first non-woven, needle-punched textile layer based on thermostable fibers, a second layer constituted by a microporous film, waterproof, permeable to water vapor, non-flammable and a discontinuous adhesive layer, placed between the first textile layer and the second layer ensuring the fixing of the second layer on the first textile layer, the first layer of the composite textile being placed towards the lining.
  • a seat comprising a textile covering and foam elements, which comprises an insert mounted flywheel between the external textile and the foam elements, said insert being a waterproof fireproof composite textile, comprising a first nonwoven textile layer. , needled on the basis of thermostable fibers, a second layer consisting of a microporous film, impermeable, permeable to water vapor and carbon dioxide, and a discontinuous layer of adhesive, placed between the first textile layer and the second layer ensuring the fixing of the second layer on the first textile layer, the first layer of the composite textile being placed towards the textile coating.
  • the textile of the invention comprises a first needled nonwoven textile layer 1 based on thermostable fibers.
  • a needled nonwoven containing a large volume of air makes it possible to obtain excellent fire resistance for a relatively low weight.
  • a weight of 100 to 150g per m2 makes it possible to obtain a textile having very good properties.
  • the use of a needle punch also makes it possible to avoid a chemical bond of the fibers which can reduce the qualities of fire resistance.
  • the fibers used can be either thermostable by nature or flame retarded after their manufacture.
  • the fibers are for example in meta or para aramid, polyamideimide, polyacrylate, polybenzimidazole, aromatic copolyimide, polyacrylonitryl oxide, polyacrylate, phenylene polysulfide, polyester ether ketone, FR viscose, cotton, Zirpo or in a phenolic compound, or also fluorocarbons, or modacrylic.
  • a mixture of these thermostable fibers is also usable.
  • These fibers can also be chlorofibers, viscoses, polyesters or wool. They must then have been subjected to flame retardant treatment.
  • the first layer 1 can be a needled nonwoven layer based on thermostable polyamide imide fibers. These fibers with a cutting length of 40 to 60mm for a denier of 2.2 to 3 decitex.
  • this felt contains 40 to 50% of air volume trapped between the fibers, thus offering excellent thermal insulation in cold or fire.
  • the second layer 2 consists of a film connected to the first by a discontinuous adhesive layer 3.
  • This layer is impermeable and permeable to water vapor.
  • This type of layer is often called “breathable”. It is a layer impermeable to liquid but allowing free circulation of water vapor and carbon dioxide.
  • this layer while playing a role of barrier to the liquid makes it possible to avoid the condensation of perspiration and ensures a great comfort for the user.
  • It consists of an impermeable waterproof film, for example of polyurethane or polyamino acid, having micro-perforations or pores with a diameter of 0.2 microns which allow the circulation of the water and gas molecule carbon dioxide but not liquid water.
  • this breathable film is based on flame-retardant polyurethane, for example by adding a nitrogen and phosphorus additive.
  • This film produced by a coagulation method has a microporous structure with pores of about 0.2 microns and has a thickness of 25 to 50 microns depending on the final requirements of the composite textile.
  • the first textile layer 1 and the second layer 2 of the composite textile of the invention constituted by a film are bonded together using a layer of adhesive 3.
  • the adhesive layer can be discontinuous, for example consisting of adhesion points so as to ensure the circulation of water vapor through the bonding means and therefore through the whole of the textile. composite.
  • Bonding may be carried out by points comprising thermoplastic polymers, of the polyamide, polyester, polyurethane type, polymers which can be crosslinked by themselves such as two-component polyurethanes, ethylene-acrylic acid copolymers, terpolymers ethylene-acrylic ester-maleic anhydride ..., or by the action of crosslinking agents incorporated into the adhesive such as a melamine formaldehyde resin, a urea formaldehyde resin, a phenol formaldehyde resin, an alkali metal hydroxide, a zinc or zirconium complex, polyamines, epoxies, polyfunctional aziridines ....
  • thermoadhesive polymer used will itself be non-flammable.
  • chlorinated antimony trioxide gives it this quality. This arrangement which improves the quality of the composite textile is not always necessary.
  • the points are deposited in the form of a paste or powder or else sprinkled on one of the two layers 1, 2 and the association of the two layers 1, 2 is carried out in a conventional manner on a press.
  • a formulation based on crosslinkable polymer is deposited on one of the substrates, and preferably on the needled nonwoven.
  • the composite textile exhibits, after 24 hours of rest, the qualities required to ensure perfect protection in fire-fighting clothing.
  • Bonding can also be obtained by using "foaming", that is to say by inserting an adhesive foam between the two layers 1, 2 by flaming on the two faces to be bonded.
  • the adhesive layer 3 can also be produced by spraying a liquid adhesive such as polyurethane, possibly capable of crosslinking. The spraying is then advantageously carried out on one of the supports, the second being applied to the first by calendering.
  • a liquid adhesive such as polyurethane
  • Adhesive layer 3 can also be produced by spraying with "Moisture Crosslinkable" with moisture having an application temperature of 80 to 110 ° C., it is sprayed onto the nonwoven needled or film using a battery of traditional pistols. Then, the second substrate is applied by cold calendering. The operation can be repeated a second time if one wishes to apply a jersey of thermostable fibers with a grammage of between 50 and 130 g / m2 on the face of the film and / or on the face of the needled nonwoven which is still free.
  • the adhesive thus partially applied according to a grammage of 6 to 10 g / m2 cross-links in 24 hours with humidity and makes it possible to obtain an adhesion resistant to the various cleaning interviews, an important flexibility of the complex by the punctual bonding, and thus allows by the assembly of the film and a light woven or knitted fabric made of heat-resistant or flame-retardant fibers improves the tear resistance of the needle-punched nonwoven and the abrasion resistance of the film during maintenance and wearing.
  • a composite textile according to the invention is a good hrydrofuge, a suitable choice of the second layer allows it to withstand without difficulty a column of water of about 7000mm.
  • the main tests are there to verify the good breathability of the complex and its impermeability vis-à-vis water and hrydrocarbons.
  • the water inlet pressure (hrydrostatic resistance) is measured according to Federal Standard 191, method 5 512 (MULLEN test) without external fabric or lining, and we obtain a value of 500kPa, when we consider the value of 310 kPa as sufficient to ensure complete waterproofing under all weather conditions.
  • the breathability of an impermeable and breathable complex is determined by measuring the resistance to wet vapor transmission according to DIN 54 101 part 1 and which gives a resistance to the passage of water vapor (HET) of 0.155m2. mbar / w. According to the same standard, a value less than 0.200 is necessary to ensure good breathability of the complex.
  • the convective protection index at a flame of 1050 ° C according to ISO DP 9 151 gives a protection index of 25 seconds while a leather jacket traditionally used by firefighters offers an index of 12 seconds, and that 'It is 2 to 4 times heavier than a jacket made with the composite textile of the invention.
  • the waterproof fireproof composite textile comprises a third textile layer 7, placed on the side opposite to the first textile layer relative to the second, a second discontinuous layer of adhesive 8, placed between the third textile layer and the second layer ensuring the fixing of the third textile layer on the second layer.
  • the adhesive layer 8 ensuring the fixing of the third textile layer on the breathable film 2 is of the same nature as the adhesive layer 3 described above. It can have any of the compositions described above with regard to the adhesive layer 3. The application of the adhesive layer 8 can also be carried out in a similar manner to that of the layer 3.
  • a particularly effective and light safety and / or fire-fighting garment can be produced with the composite textile of the invention.
  • Such protective clothing shown in Figures 2 to 4 comprises an outer textile assembly 4 constituting its outer surface and a lining 5 constituting its inner surface. It comprises an insert 6 mounted flywheel between the external textile 4 and the lining 5, said insert being a waterproof fireproof composite textile, comprising a first non-woven textile layer 1, needled based on thermostable fibers, a second layer consisting of a microporous film 2, impermeable, permeable to water vapor, non-flammable and a discontinuous layer of adhesive 3, placed between the first textile layer 1 and the second layer 2 ensuring the fixing of the second layer 2 on the first textile layer 1, the first composite textile layer 1 being placed towards the lining.
  • a waterproof fireproof composite textile comprising a first non-woven textile layer 1, needled based on thermostable fibers, a second layer consisting of a microporous film 2, impermeable, permeable to water vapor, non-flammable and a discontinuous layer of adhesive 3, placed between the first textile layer 1 and the second layer 2 ensuring the fixing of
  • the second waterproof layer 2 is placed towards the outside of the garment. This arrangement allows the protection of layer 1 of thermostable fibers from water or any other liquid (hydrocarbon, etc.) when the garment is sprayed.
  • the garment since the garment is subjected to significant watering due to atmospheric conditions or to the technique of protecting firefighters during their fight against fire, the garment remains relatively light and does not hinder the movements of the wearer.
  • the insert 6 is mounted flywheel between the external textile 4 and the lining 5 which means that it is fixed simultaneously to the external textile 4 and to the lining by its periphery 9 during manufacture, for example by sewing along the lines of usual stitching of the lining 5 to the external textile 4. Outside these lines the insert 6 is free, between the external textile 4 and the lining 5 and without any other attachment to these elements.
  • the insert 6 and the lining 5 constitute an assembly 11 that can be separated from the exterior assembly 4. It can for example be connected to the exterior assembly by a zipper 12.
  • the insert 6 and the lining 5 can be separated from the external textile 4. It is thus possible to subject these two elements to different cleaning modes.
  • the external textile which is, by its position, more exposed to dirt is more energetically and more often cleaned than the insert and the lining which are fragile.
  • the tightness of the garment is improved by the addition of waterproof strips on all its seams.
  • the garment When the garment is subjected to excessive conditions causing deterioration of the impermeable layer 2, the user remains protected by the layer 1 based on thermostable fibers.
  • the invention also relates to a seat comprising a textile covering and foam elements. It comprises an insert mounted flywheel between the external textile and the foam elements, said insert being a waterproof fireproof composite textile, comprising a first non-woven textile layer, needled based on thermostable fibers, a second layer consisting of a film microporous, waterproof, permeable to water vapor and carbon dioxide, and a discontinuous layer of adhesive, placed between the first textile layer 1 and the second layer 2 ensuring the fixing of the second layer 2 on the first textile layer 1, the first layer 1 of the composite textile being placed towards the textile covering.
  • a waterproof fireproof composite textile comprising a first non-woven textile layer, needled based on thermostable fibers, a second layer consisting of a film microporous, waterproof, permeable to water vapor and carbon dioxide, and a discontinuous layer of adhesive, placed between the first textile layer 1 and the second layer 2 ensuring the fixing of the second layer 2 on the first textile layer 1, the first layer 1 of the composite textile being placed towards the
  • this seat comprises elements consisting of foam injected in situ covered at least partially by the composite textile.
  • the production of elements composed of foam injected in situ results in the emission of gas and in particular carbon dioxide.
  • the composite textile of the invention constitutes a barrier confining the foam in the space reserved for it and allows the carbon dioxide to be evacuated without difficulty. Indeed, the dimension of the carbon dioxide molecule is of the same order of magnitude as that of the water molecule and therefore the composite textiles permeable to water vapor are generally so with carbon dioxide.
  • the tightness of the seat will be improved by sticking waterproof strips on all its seams.

Landscapes

  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Laminated Bodies (AREA)
  • Professional, Industrial, Or Sporting Protective Garments (AREA)
  • Nonwoven Fabrics (AREA)
  • Chemical Or Physical Treatment Of Fibers (AREA)
  • Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
  • Gloves (AREA)
EP89402853A 1988-10-14 1989-10-16 Textile composite anti-feu imperméable et vêtement et siège comportant un tel textile Expired - Lifetime EP0364370B1 (fr)

Priority Applications (1)

Application Number Priority Date Filing Date Title
AT89402853T ATE99008T1 (de) 1988-10-14 1989-10-16 Feuerfestes, undurchlaessiges verbundtextil und bekleidung und sessel mit einem solchen textil.

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
FR8813563A FR2637919B1 (fr) 1988-10-14 1988-10-14 Textile composite anti-feu impermeable vetement et siege comportant un tel textile
FR8813563 1988-10-14

Publications (2)

Publication Number Publication Date
EP0364370A1 EP0364370A1 (fr) 1990-04-18
EP0364370B1 true EP0364370B1 (fr) 1993-12-22

Family

ID=9371045

Family Applications (1)

Application Number Title Priority Date Filing Date
EP89402853A Expired - Lifetime EP0364370B1 (fr) 1988-10-14 1989-10-16 Textile composite anti-feu imperméable et vêtement et siège comportant un tel textile

Country Status (8)

Country Link
US (1) US5098770A (es)
EP (1) EP0364370B1 (es)
JP (1) JPH0661889B2 (es)
AT (1) ATE99008T1 (es)
CA (1) CA2000662C (es)
DE (2) DE68911643T2 (es)
ES (1) ES2047141T3 (es)
FR (1) FR2637919B1 (es)

Families Citing this family (72)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2673207B1 (fr) * 1991-02-25 1994-07-22 Picardie Lainiere Doublure composite anti-feu de vetement.
FR2673204B1 (fr) * 1991-02-25 1995-03-24 Picardie Lainiere Textile d'entoilage composite et son procede de fabrication.
FR2685170B1 (fr) * 1991-12-20 1995-02-03 Nicolas Tronc Piece de vetement moulant perfectionnee, notamment pour des vetements sportifs, tels que les combinaisons de plongee.
US5342673A (en) * 1993-02-23 1994-08-30 W. L. Gore & Associates, Inc. Sterilizable packaging material
US5520980A (en) * 1994-01-31 1996-05-28 Kimberly-Clark Corporation Protective barrier apparel fabric
ES2084562B1 (es) * 1994-03-22 1996-12-16 Nuretex S L Complejo textil destinado al revestimiento antifuego de mobiliario.
ES2088741B1 (es) * 1994-05-12 1997-03-16 Figueras Ind Sa Procedimiento para la fabricacion de un complejo textil para asientos y similares, y complejo textil obtenido.
ES2114387B1 (es) * 1994-06-22 1999-06-01 Fainsa Sa Procedimiento de fabricacion de cuerpos laminares constitutivos de partes de asientos para vehiculos y similares.
US5742936A (en) * 1994-08-18 1998-04-28 Tronc; Nicolas Tight-fitting garment, notably for sportswear such as diving suits
US5691040A (en) * 1995-12-18 1997-11-25 Marcanada Inc. Liner for firefighter garment made of a laminate of a woven fabric and a non-woven material
FI101590B1 (fi) * 1995-12-19 1998-07-31 Kosmala Ky Käsisuojus kuumatyötä varten
US5860163A (en) * 1996-05-21 1999-01-19 Lion Apparel, Inc. Garment thermal liner having insulating beads
NL1003545C2 (nl) * 1996-07-09 1998-01-12 B V Prof Doekstructuur.
EP0818304B1 (en) * 1996-07-11 2002-10-30 Asahi Fiber Glass Company, Limited Composite substrate for waterproofing structure, and waterproofing method and waterproofing structure using such composite substrate
FR2752367B1 (fr) * 1996-08-13 1999-10-15 Martinas Doublure, en particulier pour vetement de protection contre le feu et la chaleur
WO1999035926A1 (en) * 1998-01-14 1999-07-22 Gore Enterprise Holdings, Inc. Waterproof and thermal barrier material
US6713411B2 (en) * 1998-04-20 2004-03-30 Precision Fabric Group Chemical resistant, water and dry particle impervious, flame resistant laminate
FR2781341B1 (fr) * 1998-07-23 2000-10-20 Dollfus Mieg Et Compagnie Dmc Complexe textile pour la realisation de vetements de protection thermique
DE19839758C1 (de) * 1998-09-01 2000-02-17 Freudenberg Carl Fa Halbzeugmaterial zur Herstellung von Schutzbekleidung sowie Verfahren zu seiner Herstellung
US6531419B1 (en) * 1999-07-01 2003-03-11 R. H. Wyner Associates, Inc. Multi-layer protective fabrics
IT1306681B1 (it) * 1999-07-06 2001-10-02 Nottington Holding Bv Struttura di capo traspirante da indossare per migliorare il comfortdel corpo umano.
US6430754B1 (en) 2000-03-03 2002-08-13 Lion Apparel, Inc. Firefighting garment
DE10106341B4 (de) * 2000-12-08 2016-03-03 Jackon Insulation Gmbh Kunststoffschaumplatten großer Dicke
ATE264422T1 (de) * 2002-01-30 2004-04-15 Sympatex Technologies Gmbh Wasserdampfdurchlässiges, wasserresistentes verbundmaterial
US20030203114A1 (en) * 2002-04-26 2003-10-30 Nash John L. Back-coated upholstery fabrics and methods of making same
US20040040222A1 (en) * 2002-06-06 2004-03-04 Foss Stephen W. Protective roof walkway for synthetic membrane roofs
FR2842398B1 (fr) * 2002-07-17 2005-04-22 Abeil Gant composite a protection multifactorielle: chaleur seche, chaleur humide, flamme, liquides, coupures, electrique
FR2846201A1 (fr) * 2002-10-23 2004-04-30 Proline Textile Textile composite anti-feu impermeable comprenant au moins deux nappes non tissees
FR2846202A1 (fr) * 2002-10-23 2004-04-30 Proline Textile Textile composite anti-feu impermeable comprenant un reseau de fibres floquees
FR2846200B1 (fr) * 2002-10-23 2005-01-14 Proline Textile Textile composite anti-feu impermeable comprenant un reseau de fils en relief
CN100457448C (zh) * 2003-05-12 2009-02-04 上海服装集团进出口有限公司 可阻燃、隔热、防水、透气并穿着舒适的消防服用面料
CA2525257C (en) * 2003-05-12 2010-08-03 Sundridge Tackle Limited Foam material and garments made therefrom
US7013496B2 (en) * 2003-09-05 2006-03-21 Southern Mills, Inc. Patterned thermal liner for protective garments
US20050130521A1 (en) * 2003-12-10 2005-06-16 Wyner Daniel M. Protective laminates
US20060040575A1 (en) * 2004-08-18 2006-02-23 Kelleher Karen A Reflective printing on flame resistant fabrics
CA2633173C (en) * 2005-12-16 2014-08-05 Southern Mills, Inc. Protective garments that provide thermal protection and are relatively lightweight and flexible
US20090089911A1 (en) * 2007-10-05 2009-04-09 Smith Timothy J Comfortable Protective Garments
BRPI0906415A2 (pt) 2008-01-04 2015-07-14 Southern Miils Inc Tecido de proteção resistente a chamas com resistência melhorada à abrasão ou formação de borboto superficial e vestimenta de proteção compreendendo o dito tecido.
ES2427643T5 (es) 2008-11-13 2018-03-14 Otmar Schneider Estructura de tejidos para una ropa de protección
CN104068954B (zh) 2009-02-26 2017-09-19 欧苏尔公司 用于治疗背部的矫形装置
US20110041246A1 (en) * 2009-08-20 2011-02-24 Hong Kong Applied Science And Technology Research Institute Co., Ltd. Systems and methods providing temperature regulated cushion structure
US20110041230A1 (en) * 2009-08-21 2011-02-24 Tex-Ray Industrial Co., Ltd. Clothing and cloth structure thereof
US8657769B2 (en) 2009-11-04 2014-02-25 Ossur Hf Thoracic lumbar sacral orthosis
US7937772B1 (en) * 2010-01-28 2011-05-10 Lakeland Industries, Inc. Chemical/biological protective garments and laminates
EP2540909B1 (en) * 2010-02-26 2016-09-07 Kolon Industries, Inc Artificial leather
DE102010011966A1 (de) 2010-03-18 2011-09-22 Jacken Insulation Gmbh Kunststoffschaumplatten aus Polystyrol
JP6037837B2 (ja) * 2010-10-20 2016-12-07 帝人株式会社 積層耐熱防護衣
WO2012177700A2 (en) 2011-06-20 2012-12-27 Ossur Hf Orthopedic device, use of orthopedic device and method for producing the same
US9797073B1 (en) 2011-07-18 2017-10-24 Lakeland Industries, Inc. Process for producing polyvinyl alcohol articles
US9523172B2 (en) 2011-07-18 2016-12-20 Lakeland Industries, Inc. Process for producing polyvinyl alcohol articles
EP2755509B1 (en) 2011-09-12 2016-10-26 NIKE Innovate C.V. Multilayered waterproof moisture management athletic garments
EP2802299B1 (en) 2012-01-13 2016-03-16 Össur HF Spinal orthosis
US9572705B2 (en) 2012-01-13 2017-02-21 Ossur Hf Spinal orthosis
CN104853699B (zh) 2012-09-19 2017-08-15 欧苏尔公司 用于矫形装置的嵌板附着件与周长调整系统
DE102012020839A1 (de) 2012-10-24 2014-04-24 Jackon Insulation Gmbh Herstellung von XPS-Schaumplatten großer Dicke durch Schweißen
US9314363B2 (en) 2013-01-24 2016-04-19 Ossur Hf Orthopedic device for treating complications of the hip
US9554935B2 (en) 2013-01-24 2017-01-31 Ossur Hf Orthopedic device for treating complications of the hip
US9795500B2 (en) 2013-01-24 2017-10-24 Ossur Hf Orthopedic device for treating complications of the hip
US10357391B2 (en) 2013-01-24 2019-07-23 Ossur Hf Orthopedic device for treating complications of the hip
US10085518B2 (en) * 2014-12-12 2018-10-02 Joseph Flaherty Boot top opening covers
CN104490151A (zh) * 2014-12-23 2015-04-08 常熟市梅李镇赵市永宏红木家具厂 防水的红木家具
US10561520B2 (en) 2015-02-27 2020-02-18 Ossur Iceland Ehf Spinal orthosis, kit and method for using the same
EP3261590B1 (en) 2015-02-27 2020-08-19 Ossur Iceland EHF Spinal orthosis and kit comprising a spinal orthosis
CN109068776A (zh) * 2016-01-14 2018-12-21 南磨房公司 改进的阻燃热衬里和由其制成的服装
EP3330060A1 (de) 2016-11-30 2018-06-06 Jackon Insulation GmbH Herstellung von xps-schaumplatten grosser breite und/oder länge durch schweissen
JP6945328B2 (ja) * 2017-03-09 2021-10-06 山田　菊夫 複合繊維シート、複合繊維シートを用いた使い捨て繊維製品、マスク及び手術着
EP3678613B1 (en) 2017-09-07 2023-08-09 Össur Iceland EHF Thoracic lumbar sacral orthosis attachment
EP3687743B1 (en) 2017-09-28 2023-10-25 Ossur Iceland EHF Body interface
CN109750501A (zh) * 2017-11-02 2019-05-14 丹阳八紫光能有限公司 一种防火防水沙发布料
US11821220B2 (en) * 2019-09-18 2023-11-21 Dupont Safety & Construction, Inc. Composite structural board and wall systems containing same
CN110733213A (zh) * 2019-09-25 2020-01-31 安徽天恩旅行用品科技有限公司 一种复合型箱包防水面料及其制备方法
US11849791B1 (en) * 2022-06-30 2023-12-26 Createme Technologies Inc. Methods of assembling apparel products having imine adhesives

Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0238014A2 (de) * 1986-03-15 1987-09-23 Hänsel Textil GmbH & Co. Thermoplastische Folie, insbesondere thermoplastische Membranfolie, Verfahren zu ihrer Herstellung und Vorrichtung zur Durchführung des Verfahrens

Family Cites Families (20)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3532588A (en) * 1967-04-12 1970-10-06 Kendall & Co Needled nonwoven textile laminate
US3922418A (en) * 1970-10-19 1975-11-25 Raduner & Co Ag Heat-sealable interlining for textile fabrics
FR2283201A1 (fr) * 1974-09-02 1976-03-26 Compin Ets Procede permettant d'empecher la combustion des mousses de polyurethane
US4143424A (en) * 1975-11-08 1979-03-13 Firma Carl Freudenberg Combined interlining and chest piece for garments
FR2439593A1 (fr) * 1978-10-27 1980-05-23 Vetement Temps Nouveaux Veste de protection
CA1172920A (en) * 1980-04-09 1984-08-21 Walther G. Grot Protective clothing of fabric containing a layer of highly fluorinated ion exchange polymer
DE3021039A1 (de) * 1980-06-03 1981-12-10 Kufner Textilwerke KG, 8000 München Einlagen fuer kleidungsstuecke und verfahren zu deren herstellung
DE3032349A1 (de) * 1980-08-28 1982-03-04 Fa. Carl Freudenberg, 6940 Weinheim Einlagevliesstoff
DE3038664C2 (de) * 1980-10-13 1984-04-05 Fa. Carl Freudenberg, 6940 Weinheim Aufbügelbarer Einlagevliesstoff
US4302496A (en) * 1980-10-21 1981-11-24 Albany International Corp. Composite waterproof and flame resistant fabrics
JPS58136803A (ja) * 1982-02-03 1983-08-15 日本バイリーン株式会社 テ−プ状融着芯地
JPS58160134U (ja) * 1982-04-21 1983-10-25 大日本インキ化学工業株式会社 積層体
JPS5915574A (ja) * 1982-07-15 1984-01-26 ソニー株式会社 衣服素材
US4504528A (en) * 1983-07-11 1985-03-12 Rm Industrial Products Company, Inc. Process for coating aqueous fluoropolymer coating on porous substrate
DE3519963A1 (de) * 1985-06-04 1986-12-04 AVS Stich GmbH & Co KG, 3533 Willebadessen Polsterkoerper
FR2586717B1 (fr) * 1985-09-04 1988-03-18 Picardie Lainiere Produit thermocollant ameliore et son procede de fabrication
DE8703947U1 (es) * 1986-03-15 1987-09-24 Haensel Textil Gmbh & Co, 5860 Iserlohn, De
US4781962A (en) * 1986-09-09 1988-11-01 Kimberly-Clark Corporation Composite cover material for absorbent articles and the like
GB8630881D0 (en) * 1986-12-24 1987-02-04 Markwell E R Protective garment
JPS6434226U (es) * 1987-08-24 1989-03-02

Patent Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0238014A2 (de) * 1986-03-15 1987-09-23 Hänsel Textil GmbH & Co. Thermoplastische Folie, insbesondere thermoplastische Membranfolie, Verfahren zu ihrer Herstellung und Vorrichtung zur Durchführung des Verfahrens

Also Published As

Publication number Publication date
DE364370T1 (de) 1992-05-21
FR2637919A1 (fr) 1990-04-20
CA2000662A1 (en) 1990-04-14
JPH0661889B2 (ja) 1994-08-17
ATE99008T1 (de) 1994-01-15
FR2637919B1 (fr) 1991-06-28
US5098770A (en) 1992-03-24
JPH02217238A (ja) 1990-08-30
ES2047141T3 (es) 1994-02-16
DE68911643D1 (de) 1994-02-03
EP0364370A1 (fr) 1990-04-18
DE68911643T2 (de) 1994-05-26
CA2000662C (en) 1994-04-26

Similar Documents

Publication Publication Date Title
EP0364370B1 (fr) Textile composite anti-feu imperméable et vêtement et siège comportant un tel textile
EP0501080B1 (fr) Doublure composite anti-feu de vêtement
EP1129633B1 (fr) Barrière isolante thermique antifeu, procédé de fabrication d'une telle barrière, vêtement comprenant au moins une telle barrière en tant qu'isolant interne.
JP5443339B2 (ja) 耐火性ラミネート及びこれから製造された物品
US20140259328A1 (en) Moisture-insensitive thermally protective materials and garments made therefrom
EP1441613B1 (fr) Complexe textile pour isolation thermique
FR2846201A1 (fr) Textile composite anti-feu impermeable comprenant au moins deux nappes non tissees
EP1147719B1 (en) Heat resistant fireproof material and variants
EP1413213B1 (fr) Textile composite anti-feu impermeable comprenant un reseau de fils en relief
EP0272952B1 (fr) Matériau composite pour vêtement de protection contre les projections de matières et métaux en fusion
WO2006024786A1 (fr) Vetement de securite comprenant une barriere d'isolation thermique antifeu perforee
JP7379691B2 (ja) テキスタイル複合材料及び履物
RU2233603C2 (ru) Боевая одежда пожарного из термостойких материалов
FR2876253A1 (fr) Complexe textile

Legal Events

Date Code Title Description
PUAI Public reference made under article 153(3) epc to a published international application that has entered the european phase

Free format text: ORIGINAL CODE: 0009012

AK Designated contracting states

Kind code of ref document: A1

Designated state(s): AT BE CH DE ES FR GB GR IT LI LU NL SE

17P Request for examination filed

Effective date: 19900403

17Q First examination report despatched

Effective date: 19920227

GBC Gb: translation of claims filed (gb section 78(7)/1977)
DET De: translation of patent claims
GRAA (expected) grant

Free format text: ORIGINAL CODE: 0009210

AK Designated contracting states

Kind code of ref document: B1

Designated state(s): AT BE CH DE ES FR GB GR IT LI LU NL SE

REF Corresponds to:

Ref document number: 99008

Country of ref document: AT

Date of ref document: 19940115

Kind code of ref document: T

GBT Gb: translation of ep patent filed (gb section 77(6)(a)/1977)

Effective date: 19931221

ITF It: translation for a ep patent filed

Owner name: BUGNION S.P.A.

REF Corresponds to:

Ref document number: 68911643

Country of ref document: DE

Date of ref document: 19940203

REG Reference to a national code

Ref country code: ES

Ref legal event code: FG2A

Ref document number: 2047141

Country of ref document: ES

Kind code of ref document: T3

REG Reference to a national code

Ref country code: GR

Ref legal event code: FG4A

Free format text: 3010218

PLBI Opposition filed

Free format text: ORIGINAL CODE: 0009260

26 Opposition filed

Opponent name: W. L. GORE & ASSOCIATES GMBH

Effective date: 19940922

NLR1 Nl: opposition has been filed with the epo

Opponent name: W. L. GORE & ASSOCIATES GMBH

EAL Se: european patent in force in sweden

Ref document number: 89402853.9

PLBO Opposition rejected

Free format text: ORIGINAL CODE: EPIDOS REJO

APAC Appeal dossier modified

Free format text: ORIGINAL CODE: EPIDOS NOAPO

APAE Appeal reference modified

Free format text: ORIGINAL CODE: EPIDOS REFNO

APAC Appeal dossier modified

Free format text: ORIGINAL CODE: EPIDOS NOAPO

APAE Appeal reference modified

Free format text: ORIGINAL CODE: EPIDOS REFNO

APAE Appeal reference modified

Free format text: ORIGINAL CODE: EPIDOS REFNO

APAE Appeal reference modified

Free format text: ORIGINAL CODE: EPIDOS REFNO

APAE Appeal reference modified

Free format text: ORIGINAL CODE: EPIDOS REFNO

APAC Appeal dossier modified

Free format text: ORIGINAL CODE: EPIDOS NOAPO

REG Reference to a national code

Ref country code: GB

Ref legal event code: IF02

REG Reference to a national code

Ref country code: GB

Ref legal event code: 732E

PLBO Opposition rejected

Free format text: ORIGINAL CODE: EPIDOS REJO

NLS Nl: assignments of ep-patents

Owner name: CHARGETEX 14

NLT1 Nl: modifications of names registered in virtue of documents presented to the patent office pursuant to art. 16 a, paragraph 1

Owner name: PROLINE TEXTILE

APAC Appeal dossier modified

Free format text: ORIGINAL CODE: EPIDOS NOAPO

APAC Appeal dossier modified

Free format text: ORIGINAL CODE: EPIDOS NOAPO

APAC Appeal dossier modified

Free format text: ORIGINAL CODE: EPIDOS NOAPO

APAC Appeal dossier modified

Free format text: ORIGINAL CODE: EPIDOS NOAPO

REG Reference to a national code

Ref country code: CH

Ref legal event code: PUE

Owner name: LAINIERE DE PICARDIE SOCIETE ANONYME TRANSFER- CHA

Ref country code: CH

Ref legal event code: PFA

Free format text: CHARGETEX 14 TRANSFER- PROLINE TEXTILE

REG Reference to a national code

Ref country code: CH

Ref legal event code: NV

Representative=s name: RIEDERER HASLER & PARTNER PATENTANWAELTE AG

RAP2 Party data changed (patent owner data changed or rights of a patent transferred)

Owner name: PROLINE TEXTILE

NLT2 Nl: modifications (of names), taken from the european patent patent bulletin

Owner name: PROLINE TEXTILE

BECA Be: change of holder's address

Free format text: 20020325 *PROLINE TEXTILE:BUIRE COURCELLES, F-80202 PERONNE

BECN Be: change of holder's name

Effective date: 20020325

PGFP Annual fee paid to national office [announced via postgrant information from national office to epo]

Ref country code: GR

Payment date: 20040924

Year of fee payment: 16

PGFP Annual fee paid to national office [announced via postgrant information from national office to epo]

Ref country code: NL

Payment date: 20041003

Year of fee payment: 16

PGFP Annual fee paid to national office [announced via postgrant information from national office to epo]

Ref country code: SE

Payment date: 20041006

Year of fee payment: 16

PGFP Annual fee paid to national office [announced via postgrant information from national office to epo]

Ref country code: FR

Payment date: 20041008

Year of fee payment: 16

PGFP Annual fee paid to national office [announced via postgrant information from national office to epo]

Ref country code: AT

Payment date: 20041013

Year of fee payment: 16

Ref country code: GB

Payment date: 20041013

Year of fee payment: 16

Ref country code: LU

Payment date: 20041013

Year of fee payment: 16

PGFP Annual fee paid to national office [announced via postgrant information from national office to epo]

Ref country code: DE

Payment date: 20041014

Year of fee payment: 16

PGFP Annual fee paid to national office [announced via postgrant information from national office to epo]

Ref country code: CH

Payment date: 20041015

Year of fee payment: 16

PGFP Annual fee paid to national office [announced via postgrant information from national office to epo]

Ref country code: ES

Payment date: 20041116

Year of fee payment: 16

PGFP Annual fee paid to national office [announced via postgrant information from national office to epo]

Ref country code: BE

Payment date: 20041215

Year of fee payment: 16

APBU Appeal procedure closed

Free format text: ORIGINAL CODE: EPIDOSNNOA9O

PLBN Opposition rejected

Free format text: ORIGINAL CODE: 0009273

STAA Information on the status of an ep patent application or granted ep patent

Free format text: STATUS: OPPOSITION REJECTED

27O Opposition rejected

Effective date: 20050426

NLR2 Nl: decision of opposition

Effective date: 20050426

APAH Appeal reference modified

Free format text: ORIGINAL CODE: EPIDOSCREFNO

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: IT

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES;WARNING: LAPSES OF ITALIAN PATENTS WITH EFFECTIVE DATE BEFORE 2007 MAY HAVE OCCURRED AT ANY TIME BEFORE 2007. THE CORRECT EFFECTIVE DATE MAY BE DIFFERENT FROM THE ONE RECORDED.

Effective date: 20051016

Ref country code: GB

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20051016

Ref country code: AT

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20051016

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: SE

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20051017

Ref country code: ES

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20051017

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: CH

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20051031

Ref country code: LU

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20051031

Ref country code: LI

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20051031

Ref country code: BE

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20051031

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: NL

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20060501

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: DE

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20060503

REG Reference to a national code

Ref country code: CH

Ref legal event code: PL

EUG Se: european patent has lapsed
GBPC Gb: european patent ceased through non-payment of renewal fee

Effective date: 20051016

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: FR

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20060630

NLV4 Nl: lapsed or anulled due to non-payment of the annual fee

Effective date: 20060501

REG Reference to a national code

Ref country code: FR

Ref legal event code: ST

Effective date: 20060630

REG Reference to a national code

Ref country code: ES

Ref legal event code: FD2A

Effective date: 20051017

BERE Be: lapsed

Owner name: *PROLINE TEXTILE

Effective date: 20051031

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: GR

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 19931222