EP0364370B1 - Feuerfestes, undurchlässiges Verbundtextil und Bekleidung und Sessel mit einem solchen Textil - Google Patents

Feuerfestes, undurchlässiges Verbundtextil und Bekleidung und Sessel mit einem solchen Textil Download PDF

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Publication number
EP0364370B1
EP0364370B1 EP89402853A EP89402853A EP0364370B1 EP 0364370 B1 EP0364370 B1 EP 0364370B1 EP 89402853 A EP89402853 A EP 89402853A EP 89402853 A EP89402853 A EP 89402853A EP 0364370 B1 EP0364370 B1 EP 0364370B1
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EP
European Patent Office
Prior art keywords
layer
textile
composite
water
impermeable
Prior art date
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Expired - Lifetime
Application number
EP89402853A
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English (en)
French (fr)
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EP0364370A1 (de
Inventor
Christian Paire
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PROLINE TEXTILE
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Lainiere de Picardie SA
Lainiere de Picardie BC SAS
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Application filed by Lainiere de Picardie SA, Lainiere de Picardie BC SAS filed Critical Lainiere de Picardie SA
Priority to AT89402853T priority Critical patent/ATE99008T1/de
Publication of EP0364370A1 publication Critical patent/EP0364370A1/de
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    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N3/00—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
    • D06N3/0002—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof characterised by the substrate
    • D06N3/0015—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof characterised by the substrate using fibres of specified chemical or physical nature, e.g. natural silk
    • A—HUMAN NECESSITIES
    • A41—WEARING APPAREL
    • A41D—OUTERWEAR; PROTECTIVE GARMENTS; ACCESSORIES
    • A41D31/00—Materials specially adapted for outerwear
    • A41D31/04—Materials specially adapted for outerwear characterised by special function or use
    • A41D31/08—Heat resistant; Fire retardant
    • A41D31/085—Heat resistant; Fire retardant using layered materials
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M17/00—Producing multi-layer textile fabrics
    • D06M17/04—Producing multi-layer textile fabrics by applying synthetic resins as adhesives
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N7/00—Flexible sheet materials not otherwise provided for, e.g. textile threads, filaments, yarns or tow, glued on macromolecular material
    • D06N7/0092—Non-continuous polymer coating on the fibrous substrate, e.g. plastic dots on fabrics
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N2201/00—Chemical constitution of the fibres, threads or yarns
    • D06N2201/02—Synthetic macromolecular fibres
    • D06N2201/0263—Polyamide fibres
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N2203/00—Macromolecular materials of the coating layers
    • D06N2203/06—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • D06N2203/068—Polyurethanes
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N2205/00—Condition, form or state of the materials
    • D06N2205/04—Foam
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N2209/00—Properties of the materials
    • D06N2209/06—Properties of the materials having thermal properties
    • D06N2209/067—Flame resistant, fire resistant
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N2209/00—Properties of the materials
    • D06N2209/12—Permeability or impermeability properties
    • D06N2209/121—Permeability to gases, adsorption
    • D06N2209/123—Breathable
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N2209/00—Properties of the materials
    • D06N2209/12—Permeability or impermeability properties
    • D06N2209/126—Permeability to liquids, absorption
    • D06N2209/128—Non-permeable
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N2211/00—Specially adapted uses
    • D06N2211/10—Clothing
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S297/00—Chairs and seats
    • Y10S297/05—Fireproof
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S428/00—Stock material or miscellaneous articles
    • Y10S428/92—Fire or heat protection feature
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/24—Structurally defined web or sheet [e.g., overall dimension, etc.]
    • Y10T428/24802—Discontinuous or differential coating, impregnation or bond [e.g., artwork, printing, retouched photograph, etc.]
    • Y10T428/24826—Spot bonds connect components
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T442/00—Fabric [woven, knitted, or nonwoven textile or cloth, etc.]
    • Y10T442/60—Nonwoven fabric [i.e., nonwoven strand or fiber material]
    • Y10T442/647—Including a foamed layer or component
    • Y10T442/651—Plural fabric layers
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T442/00—Fabric [woven, knitted, or nonwoven textile or cloth, etc.]
    • Y10T442/60—Nonwoven fabric [i.e., nonwoven strand or fiber material]
    • Y10T442/647—Including a foamed layer or component
    • Y10T442/652—Nonwoven fabric is coated, impregnated, or autogenously bonded

Definitions

  • This treatment has a certain number of drawbacks, it is likely to reduce the fire resistance capacity of the textile and moreover it generally withstands maintenance well.
  • the waterproofing of the fabric obtained is not stable and decreases during washing or dry cleaning. It is difficult to obtain a resistance to a water column greater than 300mm in this way.
  • Document FR-A 2 283 201 proposes for this purpose to cover the foam with a glass fiber fabric.
  • Document DE-A 3,519,963 proposes the use of an external polyacrylate envelope.
  • films which are impermeable and permeable to water vapor and carbon dioxide, often called breathable (cf. DE-U 8 703 947, GB-A 2 143 151, Chemical Abstracts, vol. 102, no. 6, February 1985, page 70, summary no.47208p).
  • Document EP 0 037 744 proposes the use of a particular continuous non-porous breathable film in the production of protective clothing. This film can enter into the composition of a composite structure comprising a textile layer.
  • the invention also relates to the production of a garment or seat incorporating the textile of the invention so as to make the best use of its properties.
  • the clothing and seat thus produced must be comfortable.
  • a protective garment comprising an external textile assembly constituting its external surface and a lining constituting its internal surface, characterized in that it comprises an insert mounted flywheel between the external textile and the lining, said insert being a composite textile waterproof fireproof, comprising a first non-woven, needle-punched textile layer based on thermostable fibers, a second layer constituted by a microporous film, waterproof, permeable to water vapor, non-flammable and a discontinuous adhesive layer, placed between the first textile layer and the second layer ensuring the fixing of the second layer on the first textile layer, the first layer of the composite textile being placed towards the lining.
  • a seat comprising a textile covering and foam elements, which comprises an insert mounted flywheel between the external textile and the foam elements, said insert being a waterproof fireproof composite textile, comprising a first nonwoven textile layer. , needled on the basis of thermostable fibers, a second layer consisting of a microporous film, impermeable, permeable to water vapor and carbon dioxide, and a discontinuous layer of adhesive, placed between the first textile layer and the second layer ensuring the fixing of the second layer on the first textile layer, the first layer of the composite textile being placed towards the textile coating.
  • the textile of the invention comprises a first needled nonwoven textile layer 1 based on thermostable fibers.
  • a needled nonwoven containing a large volume of air makes it possible to obtain excellent fire resistance for a relatively low weight.
  • a weight of 100 to 150g per m2 makes it possible to obtain a textile having very good properties.
  • the use of a needle punch also makes it possible to avoid a chemical bond of the fibers which can reduce the qualities of fire resistance.
  • the fibers used can be either thermostable by nature or flame retarded after their manufacture.
  • the fibers are for example in meta or para aramid, polyamideimide, polyacrylate, polybenzimidazole, aromatic copolyimide, polyacrylonitryl oxide, polyacrylate, phenylene polysulfide, polyester ether ketone, FR viscose, cotton, Zirpo or in a phenolic compound, or also fluorocarbons, or modacrylic.
  • a mixture of these thermostable fibers is also usable.
  • These fibers can also be chlorofibers, viscoses, polyesters or wool. They must then have been subjected to flame retardant treatment.
  • the first layer 1 can be a needled nonwoven layer based on thermostable polyamide imide fibers. These fibers with a cutting length of 40 to 60mm for a denier of 2.2 to 3 decitex.
  • this felt contains 40 to 50% of air volume trapped between the fibers, thus offering excellent thermal insulation in cold or fire.
  • the second layer 2 consists of a film connected to the first by a discontinuous adhesive layer 3.
  • This layer is impermeable and permeable to water vapor.
  • This type of layer is often called “breathable”. It is a layer impermeable to liquid but allowing free circulation of water vapor and carbon dioxide.
  • this layer while playing a role of barrier to the liquid makes it possible to avoid the condensation of perspiration and ensures a great comfort for the user.
  • It consists of an impermeable waterproof film, for example of polyurethane or polyamino acid, having micro-perforations or pores with a diameter of 0.2 microns which allow the circulation of the water and gas molecule carbon dioxide but not liquid water.
  • this breathable film is based on flame-retardant polyurethane, for example by adding a nitrogen and phosphorus additive.
  • This film produced by a coagulation method has a microporous structure with pores of about 0.2 microns and has a thickness of 25 to 50 microns depending on the final requirements of the composite textile.
  • the first textile layer 1 and the second layer 2 of the composite textile of the invention constituted by a film are bonded together using a layer of adhesive 3.
  • the adhesive layer can be discontinuous, for example consisting of adhesion points so as to ensure the circulation of water vapor through the bonding means and therefore through the whole of the textile. composite.
  • Bonding may be carried out by points comprising thermoplastic polymers, of the polyamide, polyester, polyurethane type, polymers which can be crosslinked by themselves such as two-component polyurethanes, ethylene-acrylic acid copolymers, terpolymers ethylene-acrylic ester-maleic anhydride ..., or by the action of crosslinking agents incorporated into the adhesive such as a melamine formaldehyde resin, a urea formaldehyde resin, a phenol formaldehyde resin, an alkali metal hydroxide, a zinc or zirconium complex, polyamines, epoxies, polyfunctional aziridines ....
  • thermoadhesive polymer used will itself be non-flammable.
  • chlorinated antimony trioxide gives it this quality. This arrangement which improves the quality of the composite textile is not always necessary.
  • the points are deposited in the form of a paste or powder or else sprinkled on one of the two layers 1, 2 and the association of the two layers 1, 2 is carried out in a conventional manner on a press.
  • a formulation based on crosslinkable polymer is deposited on one of the substrates, and preferably on the needled nonwoven.
  • the composite textile exhibits, after 24 hours of rest, the qualities required to ensure perfect protection in fire-fighting clothing.
  • Bonding can also be obtained by using "foaming", that is to say by inserting an adhesive foam between the two layers 1, 2 by flaming on the two faces to be bonded.
  • the adhesive layer 3 can also be produced by spraying a liquid adhesive such as polyurethane, possibly capable of crosslinking. The spraying is then advantageously carried out on one of the supports, the second being applied to the first by calendering.
  • a liquid adhesive such as polyurethane
  • Adhesive layer 3 can also be produced by spraying with "Moisture Crosslinkable" with moisture having an application temperature of 80 to 110 ° C., it is sprayed onto the nonwoven needled or film using a battery of traditional pistols. Then, the second substrate is applied by cold calendering. The operation can be repeated a second time if one wishes to apply a jersey of thermostable fibers with a grammage of between 50 and 130 g / m2 on the face of the film and / or on the face of the needled nonwoven which is still free.
  • the adhesive thus partially applied according to a grammage of 6 to 10 g / m2 cross-links in 24 hours with humidity and makes it possible to obtain an adhesion resistant to the various cleaning interviews, an important flexibility of the complex by the punctual bonding, and thus allows by the assembly of the film and a light woven or knitted fabric made of heat-resistant or flame-retardant fibers improves the tear resistance of the needle-punched nonwoven and the abrasion resistance of the film during maintenance and wearing.
  • a composite textile according to the invention is a good hrydrofuge, a suitable choice of the second layer allows it to withstand without difficulty a column of water of about 7000mm.
  • the main tests are there to verify the good breathability of the complex and its impermeability vis-à-vis water and hrydrocarbons.
  • the water inlet pressure (hrydrostatic resistance) is measured according to Federal Standard 191, method 5 512 (MULLEN test) without external fabric or lining, and we obtain a value of 500kPa, when we consider the value of 310 kPa as sufficient to ensure complete waterproofing under all weather conditions.
  • the breathability of an impermeable and breathable complex is determined by measuring the resistance to wet vapor transmission according to DIN 54 101 part 1 and which gives a resistance to the passage of water vapor (HET) of 0.155m2. mbar / w. According to the same standard, a value less than 0.200 is necessary to ensure good breathability of the complex.
  • the convective protection index at a flame of 1050 ° C according to ISO DP 9 151 gives a protection index of 25 seconds while a leather jacket traditionally used by firefighters offers an index of 12 seconds, and that 'It is 2 to 4 times heavier than a jacket made with the composite textile of the invention.
  • the waterproof fireproof composite textile comprises a third textile layer 7, placed on the side opposite to the first textile layer relative to the second, a second discontinuous layer of adhesive 8, placed between the third textile layer and the second layer ensuring the fixing of the third textile layer on the second layer.
  • the adhesive layer 8 ensuring the fixing of the third textile layer on the breathable film 2 is of the same nature as the adhesive layer 3 described above. It can have any of the compositions described above with regard to the adhesive layer 3. The application of the adhesive layer 8 can also be carried out in a similar manner to that of the layer 3.
  • a particularly effective and light safety and / or fire-fighting garment can be produced with the composite textile of the invention.
  • Such protective clothing shown in Figures 2 to 4 comprises an outer textile assembly 4 constituting its outer surface and a lining 5 constituting its inner surface. It comprises an insert 6 mounted flywheel between the external textile 4 and the lining 5, said insert being a waterproof fireproof composite textile, comprising a first non-woven textile layer 1, needled based on thermostable fibers, a second layer consisting of a microporous film 2, impermeable, permeable to water vapor, non-flammable and a discontinuous layer of adhesive 3, placed between the first textile layer 1 and the second layer 2 ensuring the fixing of the second layer 2 on the first textile layer 1, the first composite textile layer 1 being placed towards the lining.
  • a waterproof fireproof composite textile comprising a first non-woven textile layer 1, needled based on thermostable fibers, a second layer consisting of a microporous film 2, impermeable, permeable to water vapor, non-flammable and a discontinuous layer of adhesive 3, placed between the first textile layer 1 and the second layer 2 ensuring the fixing of
  • the second waterproof layer 2 is placed towards the outside of the garment. This arrangement allows the protection of layer 1 of thermostable fibers from water or any other liquid (hydrocarbon, etc.) when the garment is sprayed.
  • the garment since the garment is subjected to significant watering due to atmospheric conditions or to the technique of protecting firefighters during their fight against fire, the garment remains relatively light and does not hinder the movements of the wearer.
  • the insert 6 is mounted flywheel between the external textile 4 and the lining 5 which means that it is fixed simultaneously to the external textile 4 and to the lining by its periphery 9 during manufacture, for example by sewing along the lines of usual stitching of the lining 5 to the external textile 4. Outside these lines the insert 6 is free, between the external textile 4 and the lining 5 and without any other attachment to these elements.
  • the insert 6 and the lining 5 constitute an assembly 11 that can be separated from the exterior assembly 4. It can for example be connected to the exterior assembly by a zipper 12.
  • the insert 6 and the lining 5 can be separated from the external textile 4. It is thus possible to subject these two elements to different cleaning modes.
  • the external textile which is, by its position, more exposed to dirt is more energetically and more often cleaned than the insert and the lining which are fragile.
  • the tightness of the garment is improved by the addition of waterproof strips on all its seams.
  • the garment When the garment is subjected to excessive conditions causing deterioration of the impermeable layer 2, the user remains protected by the layer 1 based on thermostable fibers.
  • the invention also relates to a seat comprising a textile covering and foam elements. It comprises an insert mounted flywheel between the external textile and the foam elements, said insert being a waterproof fireproof composite textile, comprising a first non-woven textile layer, needled based on thermostable fibers, a second layer consisting of a film microporous, waterproof, permeable to water vapor and carbon dioxide, and a discontinuous layer of adhesive, placed between the first textile layer 1 and the second layer 2 ensuring the fixing of the second layer 2 on the first textile layer 1, the first layer 1 of the composite textile being placed towards the textile covering.
  • a waterproof fireproof composite textile comprising a first non-woven textile layer, needled based on thermostable fibers, a second layer consisting of a film microporous, waterproof, permeable to water vapor and carbon dioxide, and a discontinuous layer of adhesive, placed between the first textile layer 1 and the second layer 2 ensuring the fixing of the second layer 2 on the first textile layer 1, the first layer 1 of the composite textile being placed towards the
  • this seat comprises elements consisting of foam injected in situ covered at least partially by the composite textile.
  • the production of elements composed of foam injected in situ results in the emission of gas and in particular carbon dioxide.
  • the composite textile of the invention constitutes a barrier confining the foam in the space reserved for it and allows the carbon dioxide to be evacuated without difficulty. Indeed, the dimension of the carbon dioxide molecule is of the same order of magnitude as that of the water molecule and therefore the composite textiles permeable to water vapor are generally so with carbon dioxide.
  • the tightness of the seat will be improved by sticking waterproof strips on all its seams.

Landscapes

  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Laminated Bodies (AREA)
  • Professional, Industrial, Or Sporting Protective Garments (AREA)
  • Nonwoven Fabrics (AREA)
  • Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
  • Gloves (AREA)
  • Chemical Or Physical Treatment Of Fibers (AREA)

Claims (19)

  1. Feuerfestes, undurchlässiges Verbundtextil, umfassend eine erste Textilschicht (1), bestehend aus einem nichtgewobenen Textil auf der Grundlage wärmebeständiger oder flammwidrig gemachter Fasern, ein eingeschlossenes Luftvolumen aufweisend, ausreichend für einen guten Widerstand gegen Feuer, und eine zweite Schicht (2) umfassend, gebildet aus einem mikroporösen, wasserundurchlässigen und wasserdampfdurchlässigen nichtentflammbaren Film, und eine unterbrochene Klebeschicht (3), angeordnet zwischen der ersten Textilschicht (1) und der zweiten Schicht (2), die Befestigung der zweiten Schicht (2) auf der ersten Schicht (1) gewährleistend.
  2. Verbundtextil nach Anspruch 1, dadurch gekennzeichnet, daß es eine dritte, auf der der ersten Textilschicht bezüglich der zweiten gegenüberliegenden Seite befindliche Textilschicht (7), und eine zweite, zwischen der dritten Textilschicht (7) und der zweiten Schicht (2) befindliche unterbrochene Klebeschicht (8) umfaßt, welche für den Halt der dritten Textilschicht (7) auf der zweiten Schicht (2) sorgt.
  3. Verbundtextil nach einem der Ansprüche 1 und 2, dadurch gekennzeichnet, daß eine Klebeschicht oder die Klebeschichten (3, 8) aus Punkten bestehen und durch Siebdruckbeschichtung erhalten worden sind.
  4. Verbundtextil nach einem der Ansprüche 1 bis 3, dadurch gekennzeichnet, daß eine Klebschicht oder die Klebschichten (3, 8) aus einem durch Feuchtigkeit vernetzbaren Polymer bestehen und daß sie durch Hitzezerstäubung hergestellt worden sind.
  5. Verbundtextil nach einem der Ansprüche 1 bis 4, dadurch gekennzeichnet, daß die erste nichtgewoben gefertigte Textilschicht (1) wärmebeständige Fasern aus Polyamid-Imid umfaßt.
  6. Verbundtextil nach einem der Ansprüche 1 bis 5, dadurch gekennzeichnet, daß die zweite, aus einem mikroporösen, wasserundurchlässigen und wasserdampfdurchlässigen Film bestehende Schicht (2) auf Polyurethan beruht.
  7. Schutzkleidung, umfassend einen äußeren Textilaufbau, welcher aus seiner Außenfläche und einer seine Innenfläche darstellenden Ausfütterung besteht, enthaltend eine Einlage (6), beweglich angebracht zwischen dem äußeren Textil (4) und der Ausfütterung (5), wobei die Einlage ein wasserundurchlässiges feuerfestes verbundtextil ist, umfassend eine erste nichtgewobene, auf der Grundlage wärmestabiler oder flammwidrig gemachter Fasern gefertigte Textilschicht (1) mit einem eingeschlossenen Luftvolumen, ausreichend für einen guten Widerstand gegen Feuer, eine zweite, aus einem mikroporösen, wasserundurchlässigen, wasserdampfdurchlässigen, nichtentflammbaren Film bestehende Schicht (2) und einer unterbrochenen Klebeschicht (3), angeordnet zwischen der ersten Textilschicht (1) und der zweiten Schicht (2), die Befestigung der zweiten Schicht (2) auf der ersten Textilschicht (1) gewährleistend, wobei die erste Verbundtextilschicht (1) in Richtung auf die Ausfütterung angebracht ist.
  8. Kleidung nach Anspruch 7, dadurch gekennzeichnet, daß die Einlage eine dritte Textilschicht (7) umfaßt, welche auf der ersten Textilschicht bezüglich der zweiten gegenüberliegenden Seite angebracht ist, und eine zweite, zwischen der dritten Textilschicht und der zweiten Schicht befindliche unterbrochen Klebeschicht (8) umfaßt, welche für den Halt der dritten Textilschicht auf der zweiten Schicht sorgt.
  9. Kleidung nach einem der Ansprüche 7 und 8, dadurch gekennzeichnet, daß die Klebeschicht oder die Klebeschichten (3, 8) aus Punkten bestehen und durch Siebdruckbeschichtung erhalten worden sind.
  10. Kleidung nach einem der Ansprüche 7 und 8, dadurch gekennzeichnet, daß die Klebschicht oder die Klebschichten (3, 8) aus einem durch Feuchtigkeit vernetzbaren Polymer bestehen und daß sie durch Hitzezerstäubung hergestellt worden sind.
  11. Kleidung nach einem der Ansprüche 7 bis 10, dadurch gekennzeichnet, daß die erste nichtgewoben gefertigte Textilschicht (1) wärmebeständige Fasern aus Polyamid-Imid umfaßt.
  12. Kleidung nach einem der Ansprüche 7 bis 11, dadurch gekennzeichnet, daß die zweite, aus einem mikroporösen, wasserundurchlässigen und wasserdampfdurchlässigen Film bestehende Schicht auf einem durch Zusatz eines Stickstoff- oder Phosphoradditivs flammwidrig gemachten Polyurethan begründet ist.
  13. Kleidung nach einem der Ansprüche 7 bis 12, dadurch gekennzeichnet, daß die Einlage und die Ausfütterung eine zum Beispiel bei der Pflege der Kleidung vom äußeren Textilaufbau abtrennbare Einheit bilden.
  14. Kleidung nach ein Anspruch 13, dadurch gekennzeichnet, daß die Einheit Einlage-Ausfütterung auf dem äußeren Textilaufbau durch einen Reißverschluß befestigt ist.
  15. Sessel, umfassend einen Textilbezug und Schaumstoffelemente, enthaltend eine Einlage, beweglich angebracht zwischen dem äußeren Textil und den Schaumstoffelementen, wobei diese Einlage ein feuerfestes, wasserundurchlässiges Verbundtextil ist, enthaltend eine erste nichtgewobene, auf der Grundlage wärmestabiler oder flammwidrig gemachten Fasern gefertigte Textilschicht mit einem eingeschlossenen Luftvolumen, ausreichend für eine guten Widerstand gegen Feuer, eine zweite, aus einem mikroporösen, wasserundurchlässigen, wasserdampfdurchlässigen und kohlensäuredurchlässigen Film bestehende Schicht und eine unterbrochene Klebeschicht, welche zwischen der ersten Textilschicht (1) und der zweiten Schicht (2) angebracht ist und dadurch für den Halt der zweiten Schicht (2) auf der ersten Textilschicht (1) sorgt, wobei die erste Verbundtextilschicht (1) in Richtung auf den Textilbezug angebracht ist.
  16. Sessel nach Anspruch 15, dadurch gekennzeichnet, daß die Schaumstoffelemente durch einen Spritzvorgang vor Ort hergestellt worden sind.
  17. Sessel nach einem der Ansprüche 15 und 16, dadurch gekennzeichnet, daß die Klebeschicht oder die Klebeschichten (3, 8) aus Punkten bestehen und durch Siebdruckbeschichtung erhalten worden sind.
  18. Sessel nach einem der Ansprüche 15 und 16, dadurch gekennzeichnet, daß die Klebeschicht oder die Klebeschichten (3, 8) aus einem durch Feuchtigkeit vernetzbaren Polymer bestehen und daß sie durch Hitzezerstäubung hergestellt worden sind.
  19. Sessel nach einem der Ansprüche 15 bis 18, dadurch gekennzeichnet, daß die zweite, aus einem mikroporösen, wasserundurchlässigen und wasserdampfdurchlässigen Film bestehende Schicht auf Polyurethan beruht.
EP89402853A 1988-10-14 1989-10-16 Feuerfestes, undurchlässiges Verbundtextil und Bekleidung und Sessel mit einem solchen Textil Expired - Lifetime EP0364370B1 (de)

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AT89402853T ATE99008T1 (de) 1988-10-14 1989-10-16 Feuerfestes, undurchlaessiges verbundtextil und bekleidung und sessel mit einem solchen textil.

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Application Number Priority Date Filing Date Title
FR8813563A FR2637919B1 (fr) 1988-10-14 1988-10-14 Textile composite anti-feu impermeable vetement et siege comportant un tel textile
FR8813563 1988-10-14

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EP0364370A1 EP0364370A1 (de) 1990-04-18
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US (1) US5098770A (de)
EP (1) EP0364370B1 (de)
JP (1) JPH0661889B2 (de)
AT (1) ATE99008T1 (de)
CA (1) CA2000662C (de)
DE (2) DE364370T1 (de)
ES (1) ES2047141T3 (de)
FR (1) FR2637919B1 (de)

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CA2000662A1 (en) 1990-04-14
FR2637919B1 (fr) 1991-06-28
JPH02217238A (ja) 1990-08-30
ATE99008T1 (de) 1994-01-15
CA2000662C (en) 1994-04-26
DE68911643D1 (de) 1994-02-03
JPH0661889B2 (ja) 1994-08-17
DE364370T1 (de) 1992-05-21
EP0364370A1 (de) 1990-04-18
FR2637919A1 (fr) 1990-04-20
US5098770A (en) 1992-03-24
DE68911643T2 (de) 1994-05-26
ES2047141T3 (es) 1994-02-16

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