EP1129633B1 - Isolierende feuerfeste Thermobarriere, Verfahren zu deren Herstellung und Bekleidung mit mindestens so einer Barriere als Innenisolierschicht - Google Patents
Isolierende feuerfeste Thermobarriere, Verfahren zu deren Herstellung und Bekleidung mit mindestens so einer Barriere als Innenisolierschicht Download PDFInfo
- Publication number
- EP1129633B1 EP1129633B1 EP20010490008 EP01490008A EP1129633B1 EP 1129633 B1 EP1129633 B1 EP 1129633B1 EP 20010490008 EP20010490008 EP 20010490008 EP 01490008 A EP01490008 A EP 01490008A EP 1129633 B1 EP1129633 B1 EP 1129633B1
- Authority
- EP
- European Patent Office
- Prior art keywords
- barrier
- fibres
- insulation
- thermal
- insulation barrier
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
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Classifications
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- A—HUMAN NECESSITIES
- A41—WEARING APPAREL
- A41D—OUTERWEAR; PROTECTIVE GARMENTS; ACCESSORIES
- A41D31/00—Materials specially adapted for outerwear
- A41D31/04—Materials specially adapted for outerwear characterised by special function or use
- A41D31/08—Heat resistant; Fire retardant
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- D—TEXTILES; PAPER
- D10—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B2331/00—Fibres made from polymers obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. polycondensation products
- D10B2331/02—Fibres made from polymers obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. polycondensation products polyamides
- D10B2331/021—Fibres made from polymers obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. polycondensation products polyamides aromatic polyamides, e.g. aramides
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S428/00—Stock material or miscellaneous articles
- Y10S428/92—Fire or heat protection feature
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S428/00—Stock material or miscellaneous articles
- Y10S428/92—Fire or heat protection feature
- Y10S428/921—Fire or flameproofing
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/24—Structurally defined web or sheet [e.g., overall dimension, etc.]
- Y10T428/24273—Structurally defined web or sheet [e.g., overall dimension, etc.] including aperture
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/24—Structurally defined web or sheet [e.g., overall dimension, etc.]
- Y10T428/24273—Structurally defined web or sheet [e.g., overall dimension, etc.] including aperture
- Y10T428/24322—Composite web or sheet
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/24—Structurally defined web or sheet [e.g., overall dimension, etc.]
- Y10T428/24273—Structurally defined web or sheet [e.g., overall dimension, etc.] including aperture
- Y10T428/24322—Composite web or sheet
- Y10T428/24331—Composite web or sheet including nonapertured component
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/24—Structurally defined web or sheet [e.g., overall dimension, etc.]
- Y10T428/24273—Structurally defined web or sheet [e.g., overall dimension, etc.] including aperture
- Y10T428/24322—Composite web or sheet
- Y10T428/24331—Composite web or sheet including nonapertured component
- Y10T428/24339—Keyed
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T442/00—Fabric [woven, knitted, or nonwoven textile or cloth, etc.]
- Y10T442/20—Coated or impregnated woven, knit, or nonwoven fabric which is not [a] associated with another preformed layer or fiber layer or, [b] with respect to woven and knit, characterized, respectively, by a particular or differential weave or knit, wherein the coating or impregnation is neither a foamed material nor a free metal or alloy layer
- Y10T442/2631—Coating or impregnation provides heat or fire protection
Definitions
- the invention relates to the technical field of textile materials thermally insulating and fireproof.
- thermal insulating is meant here textile materials with through which the heat flux densities are low, when they are subjected to a thermal gradient.
- fire-resistant is meant here heat-stable textile materials, retaining good mechanical strength up to temperatures such as those from exposure to 400 ° C.
- the invention relates in particular, but not exclusively, to linings thermally insulating fire safety clothing.
- the clothing liners used in these different contexts activity must have, in addition to good barrier properties thermal and temperature resistance, as limited an impact as possible on the comfort of use of the garment.
- an uncomfortable safety garment may not be constantly worn, and the feeling of discomfort may cause a drop in vigilance.
- the presence of the liner should not ideally result in a excessive weight or volume of the garment.
- the thermal barrier properties of the lining should not, in at the same time, suppressing the essential physical sensation of heat.
- the presence of the fire-resistant insulating lining must guarantee that the interval between the pain threshold and the irreversible damage threshold is always greater than the reaction time of the person wearing the fire-resistant clothing.
- fire-resistant thermal insulation liners are made of fibrous and porous material.
- This transfer takes place by radiation, conduction, and convection natural.
- Radiation is the most often dominant mode of transfer in fibrous materials, especially as the thermal gradient in which they are exposed is great.
- the density of conduction flux depends on the porosity overall of the fibrous material, of the volume surface of fibers illustrating its state of division, anisotropy of fiber distribution.
- the natural convection flux density is generally limited in thermally insulating fibrous materials.
- the insulation obtained by a sheet of fibrous material is generally inversely proportional to the density of this material, to the density of the fibers the constituent and the thermal conductivity of these constituents.
- This insulation is proportional to the thickness of the sheet.
- a first example is linked to the choice of a porosity value for the lining material.
- the air separating the fibers is a medium perfectly transparent to radiation, so that only fibers are involved in the diffusion, absorption and re-emission of radiation infrared. But maximum porosity can cause mechanical strength reduced, especially when washing and wearing, or too much lining important, hindering the movements of the wearer of the garment.
- a second example is related to the choice of a material thickness of lining.
- a significant thickness of lining certainly leads to a power high insulation, all the more so as the volume of fiber used per unit is reduced lining volume. But a significant thickness of lining can hinder the movements of the wearer of the garment. In addition, an insulating power high thermal for the lining should not be obtained at the expense of the physical sensation of pain, this pain threshold varying from one person to another.
- a third example is more fundamentally linked to the choice of a high thermal insulation lining.
- thermal barriers use non-woven, thermally stable fabrics and knitwear that are non-flammable by nature of the fibers used.
- thermal barriers known in the prior art do not respond that imperfectly at the request of their users, in particular with regard to is their heat exchange capacity from their internal face to their face external.
- the object of the invention is to propose a thermally insulating barrier thermostable, fire-resistant allowing increased evacuation of heat and body sweating, so as to maintain an impression of second skin for the person using a garment provided with such a barrier thermal, however retaining good protective properties fire and thermal flashes.
- the invention relates, according to a first aspect, to a thermostable and fire-resistant thermal barrier, especially for protective clothing security as defined in claim 1.
- this sheet is produced from a polymer material chosen from the group comprising: imide polyamides, polyimides such as P.84 (PI), aramides, para aramides, polyacrylates, aromatic copolyimides, polyacrylonitriles, polyester-ether-ketone, polybenzimidazol, polytetrafluoroethylene (PTFE), polysulfones (PSO), polyethersulfones (PES), ployphenylsulfones and phenylene polysulfides (PPS), mixtures of aramid and polybenzimidazole, mixtures of thermally stabilized polyacrylonitrile and polyamide, polytrifluorochlorethylenes (PTFCE), tetrafluorethene-perfluoroprene (FEP) copolymers, melamines (for example Basofil PI), aramides, para aramides, polyacrylates, aromatic copolyimides, polyacrylonitriles, polyester-ether-ketone, polybenzimida
- the thermal barrier is developed from fibers of the above-mentioned polymeric materials, or mixtures of fibers at least two of these polymeric materials.
- this thermal barrier is made of composite material provided with a matrix made from a material polymer chosen from those mentioned above and a fiber reinforcement short or long, woven or non-woven.
- these reinforcing fibers are chosen among the group comprising metallic fibers, glass fibers, fibers of "flame retardant” viscose, carbon fibers, peroxidized carbon fibers, modacrylic fibers.
- this thermal barrier is developed composite with reinforcement of recycled aramid fibers.
- the invention relates, according to a second aspect, to a method of manufacturing a sheet as presented above, this process comprising a needling step.
- the invention relates, according to a third aspect, to a garment of fire protection, comprising at least one thermal barrier thermostable fire resistant as presented above.
- this garment also presents, from its face external towards its internal face: an aramid-based fabric, a micro membrane porous waterproof-breathable, said thermostable and fire-resistant thermal barrier, a lining.
- the semi-permeable membrane is for example made from a phosphor polyurethane sheet or PTFE, assembled on a substrate aramid fibers.
- a needled nonwoven 1 insulating thermal and fireproof for insulation of safety clothing is provided with perforations 2, 3.
- This needled nonwoven is made from blends of fibers aramids such as Nomex ®, Isomex ® or Kevlar ® fibers from Dupont from Nemours, or Kermel ® fibers from Rhône Poulenc, Teijin fibers Conex ® or Technora ® from Teijin Ltd, Twaron ® from Akzo, Apyeil ® from the company Unitika, HMA ® from the company Hoechst.
- fibers aramids such as Nomex ®, Isomex ® or Kevlar ® fibers from Dupont from Nemours, or Kermel ® fibers from Rhône Poulenc, Teijin fibers Conex ® or Technora ® from Teijin Ltd, Twaron ® from Akzo, Apyeil ® from the company Unitika, HMA ® from the company Hoechst.
- the table below presents some properties of the non-woven non-perforated fabric made from an Isomex® 5119WSM913 felt, this felt comprising a mixture of meta-aramid and para-aramid fibers, of denier 1.4 / 1, 7 / 2.2 / 6.1 dtex and between 38 and 140mm in length.
- Characteristics Test standards Values tolerances Surface mass ISO-9073-1 155 g / m2 + -8% Thickness under load of 0.5kPa ISO 9073-2 2.5 mm + -0.50
- a surface mass of the nonwoven felt of between 100 and 200 g / m 2 is suitable.
- the aramid fibers used can come from recycling, by example of falls.
- the perforations made in the needled nonwoven sheet are, in the illustrated embodiment, circular holes 2, 3, of two diameters different.
- the directions D1 and D2 are defined, to facilitate the understanding of the description, such as the longitudinal directions and cross.
- the longitudinal and transverse terms are used in order to convenience and do not predict the direction of use of the sheet.
- a first type of hole 2 is diameter on the order of three millimeters and a second type of hole 3 is diameter of the order of 2 millimeters.
- the holes 2, of larger diameter, are arranged in a pattern with rectangular mesh.
- the holes 3, of smaller diameter, are arranged in the same pattern with rectangular mesh, the two patterns being offset by half a side of mesh.
- the large diameter holes are arranged in lines equidistant transverse, of identical spacing to those on which are arranged the holes of small diameters.
- the four closest holes next to each small diameter hole 3 are large diameter holes 3, arranged along the mesh of their network.
- the nearest four holes next to each large diameter 2 are holes of small diameter 3, arranged along the mesh of their network.
- the density of holes is of the order of two to three holes per centimeter square.
- the perforation allows a reduction in sheet weight of the order of 20 to 30%.
- the thermal barrier can also include more than two types of holes.
- the perforation density is not homogeneous.
- thermal barrier 1 when the thermal barrier 1 is put in place as an insulator fire-resistant clothing, a higher density of holes may be provided for areas of the body which are little exposed a priori to the risks of direct burns or indirect.
- the perforations may be more numerous to the right of the hood wearer's ears.
- the perforations are arranged in a simple and regular pattern.
- This type of implementation has, among other advantages, to facilitate the mechanical and thermal modeling of the barrier behavior thermostable thermal insulation fire.
- thermostable insulating non-woven fire thermal barrier needled is flexible, with a thickness for example of the order of one to five millimeters.
- Figure 2 is shown schematically in cross section a protective clothing structure, comprising at least one barrier thermal 1 as internal insulation.
- the value of the evaporative resistance of garments of the above type, provided with a conventional lining generally varies between 22 and 30 bar.m 2 / W.
- Such values are obtained for example when a needled nonwoven of Isomex® fibers of 100 g / m 2 is used.
- Nomex ® fibers allows this value of evaporative resistance to be lowered to less than 22 bar.m 2 / W.
- Perforation on a needled nonwoven fabric in Isomex ® improves the evaporative resistance value by 10 to 30%.
- the external fabric 4 is substantially raincoat.
- This property is particularly important for certain interventions firefighters, or when the intervention atmosphere is potentially harmful or toxic.
- this outer fabric is provided with bands phosphorescent and / or fluorescent.
- the microporous membrane 5 is, for example, of Gore-tex®, or of phosphorus polyurethane type, assembled on an aramid fiber substrate.
- nonwoven thermal barrier 1 Depending on the expected exposure temperatures, various types of fibers can be used for the realization of a nonwoven thermal barrier 1.
- the fibers mentioned above in particular polyaramides, can be mixed with glass fibers, carbon or silica.
- the perforated needled nonwoven felt When mechanical resistance and resistance to washing are more particularly desired for the perforated needled nonwoven felt, it can be sewn, using non-rectilinear stitching lines but by sinuous example, on a fire-resistant membrane.
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- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Nonwoven Fabrics (AREA)
- Professional, Industrial, Or Sporting Protective Garments (AREA)
- Laminated Bodies (AREA)
- Thermal Insulation (AREA)
- Building Environments (AREA)
Claims (12)
- Wärmebeständige, nicht entflammbare Wärmeisolierschicht, insbesondere für Sicherheitskleidung, die umfasst eine Vorderseite, die einer äußeren Wärmequelle oder Strahlungsquelle zugewandt ist, und eine der Vorderseite gegenüberliegende Rückseite, wobei diese Wärmeisolierschicht eine Mehrzahl von Löchern (2, 3) aufweist, die jeweils in die Vorderseite und in die Rückseite dieser Wärmeisolierschicht münden, wobei die Wärmeisolierschicht in Form eines Vliesstoffes vorliegt, der mit kreisförmigen Löchern versehen ist, dadurch gekennzeichnet, dass die Dichte der Löcher in der Größenordnung von 2 pro cm2 liegt, wobei ein erster Loch-Typ einen Durchmesser in der Größenordnung von 3 mm hat und ein zweiter Loch-Typ einen Durchmesser in der Größenordnung von 2 mm hat.
- Wärmeisolierschicht nach Anspruch 1, dadurch gekennzeichnet, dass sie hergestellt ist aus einem Material, ausgewählt aus der Gruppe, die besteht aus Polyamidimiden, Polyimiden, Aramiden, p-Aramiden, m-Aramiden, Polyacrylaten, aromatischen Copolyimiden, Polyacrylnitrilen, Polyester-etherketonen, Polybenzimidazolen, Polytetraflurethylenen, Polysulfonen, Polyethersulfonen, Polyphenylsulfonen und Polysulfiden von Phenylenen, Mischungen von Aramid und Polybenzimidazol, thermisch stabilisierten Mischungen von Polyacrylnitril und Polyamid, Polytrifluorchlorethylenen und Tetrafluorethenperfluoropren-Copolymeren.
- Wärmeisolierschicht nach Anspruch 2, dadurch gekennzeichnet, dass sie hergestellt ist aus einem Material, das außerdem Fasern umfasst, die ausgewählt sind aus der Gruppe, die umfasst Metallfasern, Glasfasern, feuerfeste Viscosefasern, Kohlefasern, peroxidierte Kohlefasern, Siliciumdioxidfasern und Modacrylfasern.
- Wärmeisolierschicht nach einem der Ansprüche 1 bis 3, dadurch gekennzeichnet, dass die beiden Typen von Löchern (2, 3) jeweils in aufeinanderfolgenden rechteckigen Gitter- bzw. Mascheneinheiten angeordnet sind.
- Wärmeisolierschicht nach Anspruch 4, dadurch gekennzeichnet, dass die beiden rechteckigen Gitter- bzw. Mascheneinheiten identisch und gegeneinander versetzt sind.
- Wärmeisolierschicht nach Anspruch 5, dadurch gekennzeichnet, dass die beiden Einheiten um eine halbe Gitter- bzw. Maschen-Seitenlänge gegeneinander versetzt sind.
- Wärmeisolierschicht nach einem der Ansprüche 1 bis 6, dadurch gekennzeichnet, dass ihre Dicke in der Größenordnung von 1 bis 5 mm liegt.
- Wärmeisolierschicht nach einem der Ansprüche 2 bis 7, dadurch gekennzeichnet, dass sie aus recyclisierten Aramidfasern hergestellt ist.
- Verfahren zur Herstellung einer Wärmeisolierschicht, wie sie in einem der Ansprüche 1 bis 8 beschrieben ist, dadurch gekennzeichnet, dass es eine Nadelungsstufe umfasst, wobei die Wärmeisolierschicht ein durch Nadeln perforierter Vliesstoff ist.
- Feuerfeste Schutzkleidung, dadurch gekennzeichnet, dass sie mindestens eine Wärmeisolierschicht (1), wie sie in mindestens einem der Ansprüche 1 bis 8 beschrieben ist, als innere Isolierschicht umfasst.
- Feuerfeste Schutzkleidung nach Anspruch 10, dadurch gekennzeichnet, dass sie umfasst:ein äußeres Gewebe (4) auf Aramid-Basis;eine mikroporöse atmungsinaktive Membran (5);die wärmeisolierende Schicht (1); undein Sauberkeits-Innenfutter (6).
- Schutzkleidung nach Anspruch 10 oder 11, dadurch gekennzeichnet, dass die mikroporöse Membran (4) hergestellt ist aus einer phosphorhaltigen Polyurethanfolie, die auf ein Substrat aus Aramidfasern aufgebracht ist.
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
FR0002788 | 2000-03-03 | ||
FR0002788A FR2805718A1 (fr) | 2000-03-03 | 2000-03-03 | Barriere isolante thermique antifeu, procede de fabrication d'une telle barriere, vetement comprenant au moins une telle barriere en tant qu'isolant interne |
Publications (2)
Publication Number | Publication Date |
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EP1129633A1 EP1129633A1 (de) | 2001-09-05 |
EP1129633B1 true EP1129633B1 (de) | 2004-08-11 |
Family
ID=8847714
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP20010490008 Expired - Lifetime EP1129633B1 (de) | 2000-03-03 | 2001-03-02 | Isolierende feuerfeste Thermobarriere, Verfahren zu deren Herstellung und Bekleidung mit mindestens so einer Barriere als Innenisolierschicht |
Country Status (11)
Country | Link |
---|---|
US (1) | US6743498B2 (de) |
EP (1) | EP1129633B1 (de) |
AT (1) | ATE272952T1 (de) |
AU (1) | AU4076101A (de) |
CA (1) | CA2372970A1 (de) |
DE (1) | DE60104741T2 (de) |
DK (1) | DK1129633T3 (de) |
ES (1) | ES2225452T3 (de) |
FR (1) | FR2805718A1 (de) |
PT (1) | PT1129633E (de) |
WO (1) | WO2001064064A1 (de) |
Families Citing this family (34)
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NO312205B1 (no) * | 1999-12-23 | 2002-04-08 | Fridtjov Johansen | Miljövennlig isolasjonsmateriale og fremgangsmåte for fremstilling av dette |
ITVI20030037A1 (it) * | 2003-02-25 | 2004-08-26 | Q2 Roma Srl | Tessuto ad elevate proprieta' ignifughe. |
DE102004011296B4 (de) * | 2004-03-09 | 2006-05-11 | Sächsisches Textilforschungsinstitut e.V. | Schutzkleidung, insbesondere Feuerwehrkleidung |
US7348059B2 (en) * | 2004-03-18 | 2008-03-25 | E. I. Du Pont De Nemours And Company | Modacrylic/aramid fiber blends for arc and flame protection and reduced shrinkage |
US20050251900A1 (en) * | 2004-05-17 | 2005-11-17 | Harlacker John A | Hazardous duty garments |
FR2873901B1 (fr) * | 2004-08-04 | 2006-12-29 | Duflot Ind Sa | Barriere d'isolation thermique antifeu |
US7913322B2 (en) * | 2005-12-20 | 2011-03-29 | Lion Apparel, Inc. | Garment with padding |
US9170071B2 (en) * | 2006-05-01 | 2015-10-27 | Warwick Mills Inc. | Mosaic extremity protection system with transportable solid elements |
US20090110919A1 (en) * | 2007-10-24 | 2009-04-30 | Dattatreya Panse | Burn protective materials |
US10364527B2 (en) * | 2007-10-24 | 2019-07-30 | W. L. Gore & Associates, Inc. | Burn protective materials |
US20090111345A1 (en) * | 2007-10-24 | 2009-04-30 | Dattatreya Panse | Thermally protective materials |
WO2009091432A1 (en) | 2007-10-30 | 2009-07-23 | Warwick Mills, Inc. | Soft plate soft panel bonded multi layer armor materials |
US7744999B2 (en) * | 2008-07-11 | 2010-06-29 | E. I. Du Pont De Nemours And Company | Crystallized meta-aramid blends for improved flash fire and arc protection |
IT1390963B1 (it) * | 2008-07-24 | 2011-10-27 | Roberto Fantino | Prodotto stratificato ad elevata capacita' di isolamento termico ed autoestinguenza. |
DE102008035351B4 (de) * | 2008-07-29 | 2018-10-11 | Dräger Safety AG & Co. KGaA | Mehrschichtige Materialbahn insbesondere für Schutzanzüge |
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USD670917S1 (en) | 2011-02-18 | 2012-11-20 | Columbia Sportswear North America, Inc. | Heat reflective lining material |
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US20110041230A1 (en) * | 2009-08-21 | 2011-02-24 | Tex-Ray Industrial Co., Ltd. | Clothing and cloth structure thereof |
EP2556324A4 (de) | 2010-04-08 | 2015-09-30 | Warwick Mills Inc | Panzerungsanordnung aus einem titanmosaikkörper |
US9392825B2 (en) | 2012-04-18 | 2016-07-19 | Nike, Inc. | Cold weather vented garment |
US11606992B2 (en) * | 2012-04-18 | 2023-03-21 | Nike, Inc. | Vented garment |
US12035770B2 (en) | 2012-04-18 | 2024-07-16 | Nike, Inc. | Vented garment |
USD707974S1 (en) | 2012-05-11 | 2014-07-01 | Columbia Sportswear North America, Inc. | Patterned prismatic bodywear lining material |
US9409378B2 (en) | 2012-09-25 | 2016-08-09 | Pbi Performance Products, Inc. | Thermal liner for protective garments |
US10160184B2 (en) * | 2013-06-03 | 2018-12-25 | Xefco Pty Ltd | Insulated radiant barriers in apparel |
US11406148B2 (en) | 2015-10-07 | 2022-08-09 | Nike, Inc. | Vented garment |
BR112018014393A2 (pt) * | 2016-01-14 | 2018-12-11 | Southern Mills Inc | ?compósito de vestimenta? |
US10760189B2 (en) * | 2016-04-22 | 2020-09-01 | General Recycled | Protective fabric and process of manufacturing same |
US10743596B2 (en) * | 2016-10-06 | 2020-08-18 | Nike, Inc. | Insulated vented garment formed using non-woven polymer sheets |
US11019865B2 (en) * | 2016-10-06 | 2021-06-01 | Nike, Inc. | Insulated garment |
WO2018078396A1 (en) * | 2016-10-31 | 2018-05-03 | RLEPL Limited | An insulating material |
CN107415385B (zh) * | 2017-07-31 | 2018-06-12 | 圣华盾防护科技股份有限公司 | 防电弧服 |
JP7294751B2 (ja) | 2017-10-16 | 2023-06-20 | コロンビア・スポーツウェア・ノース・アメリカ・インコーポレーテッド | 制限された伝導の熱反射材料 |
Citations (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US5136723A (en) * | 1991-02-15 | 1992-08-11 | Lion Apparel, Inc. | Firefighter garment with mesh liner |
Family Cites Families (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE8228859U1 (de) * | 1982-10-14 | 1983-01-20 | Sigri Elektrographit Gmbh, 8901 Meitingen | Schutzkleidung |
JPS6155268A (ja) * | 1984-08-22 | 1986-03-19 | 帝国繊維株式会社 | 耐炎加工布 |
FR2673207B1 (fr) * | 1991-02-25 | 1994-07-22 | Picardie Lainiere | Doublure composite anti-feu de vetement. |
US5720045A (en) * | 1993-09-10 | 1998-02-24 | Lion Apparel, Inc. | Protective garment with apertured closed-cell foam liner |
US5924134A (en) * | 1993-09-10 | 1999-07-20 | Lion Apparel, Inc. | Protective garment with apertured closed-cell foam liner |
DE19827567A1 (de) * | 1998-06-20 | 1999-12-23 | Corovin Gmbh | Verfahren zur Herstellung eines Vlieses aus Fasern |
EP1259131B1 (de) * | 1999-07-27 | 2010-05-26 | Claude Q.C. Hayes | Wärmeschutzschicht |
-
2000
- 2000-03-03 FR FR0002788A patent/FR2805718A1/fr not_active Withdrawn
-
2001
- 2001-03-02 EP EP20010490008 patent/EP1129633B1/de not_active Expired - Lifetime
- 2001-03-02 US US09/980,695 patent/US6743498B2/en not_active Expired - Fee Related
- 2001-03-02 AT AT01490008T patent/ATE272952T1/de not_active IP Right Cessation
- 2001-03-02 DE DE2001604741 patent/DE60104741T2/de not_active Expired - Fee Related
- 2001-03-02 DK DK01490008T patent/DK1129633T3/da active
- 2001-03-02 WO PCT/FR2001/000633 patent/WO2001064064A1/fr active Application Filing
- 2001-03-02 PT PT01490008T patent/PT1129633E/pt unknown
- 2001-03-02 AU AU40761/01A patent/AU4076101A/en not_active Abandoned
- 2001-03-02 CA CA 2372970 patent/CA2372970A1/fr not_active Abandoned
- 2001-03-02 ES ES01490008T patent/ES2225452T3/es not_active Expired - Lifetime
Patent Citations (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US5136723A (en) * | 1991-02-15 | 1992-08-11 | Lion Apparel, Inc. | Firefighter garment with mesh liner |
Also Published As
Publication number | Publication date |
---|---|
US6743498B2 (en) | 2004-06-01 |
EP1129633A1 (de) | 2001-09-05 |
US20020142132A1 (en) | 2002-10-03 |
DE60104741T2 (de) | 2005-09-01 |
FR2805718A1 (fr) | 2001-09-07 |
PT1129633E (pt) | 2004-12-31 |
ES2225452T3 (es) | 2005-03-16 |
AU4076101A (en) | 2001-09-12 |
ATE272952T1 (de) | 2004-08-15 |
DK1129633T3 (da) | 2004-12-06 |
WO2001064064A1 (fr) | 2001-09-07 |
CA2372970A1 (fr) | 2001-09-07 |
DE60104741D1 (de) | 2004-09-16 |
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