EP1129633A1 - Isolierende feuerfeste Thermobarriere, Verfahren zu deren Herstellung und Bekleidung mit mindestens so einer Barriere als Innenisolierschicht - Google Patents

Isolierende feuerfeste Thermobarriere, Verfahren zu deren Herstellung und Bekleidung mit mindestens so einer Barriere als Innenisolierschicht Download PDF

Info

Publication number
EP1129633A1
EP1129633A1 EP20010490008 EP01490008A EP1129633A1 EP 1129633 A1 EP1129633 A1 EP 1129633A1 EP 20010490008 EP20010490008 EP 20010490008 EP 01490008 A EP01490008 A EP 01490008A EP 1129633 A1 EP1129633 A1 EP 1129633A1
Authority
EP
European Patent Office
Prior art keywords
fibers
insulation barrier
barrier according
holes
insulation
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
EP20010490008
Other languages
English (en)
French (fr)
Other versions
EP1129633B1 (de
Inventor
Jacques Fourmeux
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Duflot Industrie SA
Original Assignee
Duflot Industrie SA
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Duflot Industrie SA filed Critical Duflot Industrie SA
Publication of EP1129633A1 publication Critical patent/EP1129633A1/de
Application granted granted Critical
Publication of EP1129633B1 publication Critical patent/EP1129633B1/de
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Images

Classifications

    • A—HUMAN NECESSITIES
    • A41—WEARING APPAREL
    • A41D—OUTERWEAR; PROTECTIVE GARMENTS; ACCESSORIES
    • A41D31/00—Materials specially adapted for outerwear
    • A41D31/04—Materials specially adapted for outerwear characterised by special function or use
    • A41D31/08—Heat resistant; Fire retardant
    • D—TEXTILES; PAPER
    • D10—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B2331/00—Fibres made from polymers obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. polycondensation products
    • D10B2331/02—Fibres made from polymers obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. polycondensation products polyamides
    • D10B2331/021—Fibres made from polymers obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. polycondensation products polyamides aromatic polyamides, e.g. aramides
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S428/00—Stock material or miscellaneous articles
    • Y10S428/92—Fire or heat protection feature
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S428/00—Stock material or miscellaneous articles
    • Y10S428/92—Fire or heat protection feature
    • Y10S428/921—Fire or flameproofing
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/24—Structurally defined web or sheet [e.g., overall dimension, etc.]
    • Y10T428/24273—Structurally defined web or sheet [e.g., overall dimension, etc.] including aperture
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/24—Structurally defined web or sheet [e.g., overall dimension, etc.]
    • Y10T428/24273—Structurally defined web or sheet [e.g., overall dimension, etc.] including aperture
    • Y10T428/24322—Composite web or sheet
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/24—Structurally defined web or sheet [e.g., overall dimension, etc.]
    • Y10T428/24273—Structurally defined web or sheet [e.g., overall dimension, etc.] including aperture
    • Y10T428/24322—Composite web or sheet
    • Y10T428/24331—Composite web or sheet including nonapertured component
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/24—Structurally defined web or sheet [e.g., overall dimension, etc.]
    • Y10T428/24273—Structurally defined web or sheet [e.g., overall dimension, etc.] including aperture
    • Y10T428/24322—Composite web or sheet
    • Y10T428/24331—Composite web or sheet including nonapertured component
    • Y10T428/24339—Keyed
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T442/00—Fabric [woven, knitted, or nonwoven textile or cloth, etc.]
    • Y10T442/20—Coated or impregnated woven, knit, or nonwoven fabric which is not [a] associated with another preformed layer or fiber layer or, [b] with respect to woven and knit, characterized, respectively, by a particular or differential weave or knit, wherein the coating or impregnation is neither a foamed material nor a free metal or alloy layer
    • Y10T442/2631—Coating or impregnation provides heat or fire protection

Definitions

  • the invention relates to the technical field of textile materials thermally insulating and fireproof.
  • thermal insulating is meant here textile materials with through which the heat flux densities are low, when they are subjected to a thermal gradient.
  • fire-resistant is meant here thermostable textile materials, retaining good mechanical strength up to temperatures such as those from exposure to 400 ° C.
  • the invention relates in particular, but not exclusively, to linings thermally insulating fire safety clothing.
  • the clothing liners used in these different contexts activity must have, in addition to good barrier properties thermal and temperature resistance, as limited an impact as possible on the comfort of use of the garment.
  • an uncomfortable safety garment may not be constantly worn, and the feeling of discomfort may cause a drop in vigilance.
  • the presence of the liner should not ideally result in a excessive weight or volume of the garment.
  • the thermal barrier properties of the lining should not, in at the same time, suppressing the essential physical sensation of heat.
  • the presence of the fire-resistant insulating lining must guarantee that the interval between the pain threshold and the irreversible damage threshold is always greater than the reaction time of the person wearing the fire-resistant clothing.
  • fire-resistant thermal insulation liners are made of fibrous and porous material.
  • This transfer takes place by radiation, conduction, and convection natural.
  • Radiation is the most often dominant mode of transfer in fibrous materials, especially as the thermal gradient in which they are exposed is great.
  • the density of conduction flux depends on the porosity overall of the fibrous material, of the volume surface of fibers illustrating its state of division, anisotropy of fiber distribution.
  • the natural convection flux density is generally limited in thermally insulating fibrous materials.
  • the insulation obtained by a sheet of fibrous material is generally inversely proportional to the density of this material, to the density of the fibers the constituent and the thermal conductivity of these constituents.
  • This insulation is proportional to the thickness of the sheet.
  • a first example is linked to the choice of a porosity value for the lining material.
  • a second example is related to the choice of a material thickness of lining.
  • a significant thickness of lining certainly leads to a power high insulation, all the more since the volume of fiber used per unit is reduced lining volume. But a significant thickness of lining can hinder the movements of the wearer of the garment. In addition, an insulating power high thermal for the lining should not be obtained at the expense of the physical sensation of pain, this pain threshold varying from one person to another.
  • a third example is more fundamentally linked to the choice of a high thermal insulation lining.
  • thermal barriers use non-woven, thermally stable fabrics and knitwear that are non-flammable by nature of the fibers used.
  • thermal barriers known in the prior art do not respond that imperfectly at the request of their users, in particular with regard to is their heat exchange capacity from their internal face to their face external.
  • the object of the invention is to propose a thermally insulating barrier thermostable, fire-resistant allowing increased evacuation of heat and body sweating, so as to maintain an impression of second skin for the person using a garment provided with such a barrier thermal, however retaining good protective properties fire and thermal flashes.
  • thermostable and fire-resistant thermal barrier especially for protective clothing security, comprising a front face intended to come opposite a source of heat or external radiation, and a rear face opposite the face before, this sheet comprising a plurality of holes each opening onto the front face and the rear face of said sheet.
  • this sheet is made from a material polymer chosen from the group comprising: imide polyamides, polyimides such as P.84 (P.I.), aramids, para aramids, polyacrylates, aromatic copolyimides, polyacrylonitriles, polyester-ether-ketone, polybenzimidazol, polytetrafluoroethylene (P.T.F.E.), polysulfones (P.S.O), polyethersulfones (P.E.S.), ployphenylsulfones and polysulfides of phenylenes (P.P.S.), mixtures of aramid and polybenzimidazole, mixtures of thermally stabilized polyacrylonitrile and polyamide, the polytrifluorochlorethylenes (P.T.F.C.E.), tetrafluore
  • P.T.F.C.E. polytrifluorochlorethylenes
  • the thermal barrier is developed from fibers of the above-mentioned polymeric materials, or mixtures of fibers at least two of these polymeric materials.
  • this thermal barrier is made of composite material provided with a matrix made from a material polymer chosen from those mentioned above and a fiber reinforcement short or long, woven or non-woven.
  • these reinforcing fibers are chosen among the group comprising metallic fibers, glass fibers, fibers of "flame retardant” viscose, carbon fibers, peroxidized carbon fibers, modacrylic fibers.
  • this thermal barrier is developed composite with reinforcement of recycled aramid fibers.
  • the invention relates, according to a second aspect, to a method of manufacture of a sheet as presented above, this process comprising a needling step.
  • the invention relates, according to a third aspect, to a garment of fire protection, comprising at least one thermal barrier thermostable fireproof as presented above.
  • this garment also presents, from its face external towards its internal face: an aramid-based fabric, a micro membrane porous waterproof-breathable, said thermostable and fire-resistant thermal barrier, a lining.
  • the semi-permeable membrane is for example made from a phosphor polyurethane sheet or PTFE, assembled on a substrate aramid fibers.
  • a needled nonwoven 1 insulating thermal and fireproof insulation for safety clothing is provided with perforations 2, 3.
  • This needle punched nonwoven is made from blends of fibers aramids such as Nomex ®, Isomex ® or Kevlar ® fibers from Dupont from Nemours, or Kermel ® fibers from Rhône Poulenc, Teijin fibers Conex ® or Technora ® from Teijin Ltd, Twaron ® from Akzo, Apyeil ® from the company Unitika, HMA ® from the company Hoechst.
  • fibers aramids such as Nomex ®, Isomex ® or Kevlar ® fibers from Dupont from Nemours, or Kermel ® fibers from Rhône Poulenc, Teijin fibers Conex ® or Technora ® from Teijin Ltd, Twaron ® from Akzo, Apyeil ® from the company Unitika, HMA ® from the company Hoechst.
  • the table below presents some properties of the non-woven non-perforated fabric made from an Isomex® 5119WSM913 felt, this felt comprising a mixture of meta-aramid and para-aramid fibers, of denier 1.4 / 1, 7 / 2.2 / 6.1 dtex and between 38 and 140mm in length.
  • Characteristics Test standards Values Tolerance s Surface mass ISO-9073-1 155 g / m2 + -8% Thickness under load of 0.5kPa ISO 9073-2 2.5 mm + -0.50
  • a surface mass of the nonwoven felt of between 100 and 200 g / m 2 is suitable.
  • the aramid fibers used can come from recycling, by example of falls.
  • the perforations made in the needled nonwoven sheet are, in the illustrated embodiment, circular holes 2, 3, of two diameters different.
  • the directions D1 and D2 are defined, to facilitate the understanding of the description, such as longitudinal directions and transverse.
  • the longitudinal and transverse terms are used in order to convenience and do not predict the direction of use of the sheet.
  • a first type of hole 2 is diameter on the order of three millimeters and a second type of hole 3 is diameter of the order of 2 millimeters.
  • the holes 2, of larger diameter, are arranged in a pattern with rectangular mesh.
  • the holes 3, of smaller diameter, are arranged in the same pattern with rectangular mesh, the two patterns being offset by half a side of mesh.
  • large diameter holes are arranged in lines equidistant transverse, of identical spacing to those on which are arranged the holes of small diameters.
  • the four closest holes next to each small diameter hole 3 are large diameter holes 3, arranged along the mesh of their network.
  • the nearest four holes next to each large diameter 2 are holes of small diameter 3, arranged along the mesh of their network.
  • the density of holes is of the order of two to three holes per centimeter square.
  • the perforation allows a reduction in sheet weight of the order of 20 to 30%.
  • the thermal barrier can also include more than two types of holes.
  • the perforation density is not homogeneous.
  • thermal barrier 1 when the thermal barrier 1 is put in place as an insulator fire-resistant clothing, a higher density of holes may be provided for areas of the body that are a priori little exposed to the risk of direct burns or indirect.
  • the perforations may be more numerous to the right of the hood wearer's ears.
  • the perforations are arranged in a simple and regular pattern.
  • this type of implementation has the advantage of facilitating the mechanical and thermal modeling of the barrier behavior thermostable thermal insulating fire-resistant.
  • the heat-insulating non-woven fire-resistant thermal barrier needled is flexible, with a thickness for example of the order of one to five millimeters.
  • Figure 2 is shown schematically in cross section a protective clothing structure, comprising at least one barrier thermal 1 as internal insulation.
  • the value of the evaporative resistance of garments of the above type, provided with a conventional lining generally varies between 22 and 30 bar.m 2 / W.
  • Such values are obtained for example when a needled nonwoven of Isomex® fibers of 100 g / m 2 is used.
  • Nomex ® fibers allows this value of evaporative resistance to be lowered to less than 22 bar.m 2 / W.
  • Perforation on a needled nonwoven fabric in Isomex ® improves the evaporative resistance value by 10 to 30%.
  • the external fabric 4 is substantially raincoat.
  • This property is particularly important for certain interventions firefighters, or when the intervention atmosphere is potentially harmful or toxic.
  • this outer fabric is provided with bands phosphorescent and / or fluorescent.
  • the microporous membrane 5 is, for example, of Gore-tex®, or of phosphorus polyurethane type, assembled on an aramid fiber substrate.
  • nonwoven thermal barrier 1 Depending on the expected exposure temperatures, various types of fibers can be used for the realization of a nonwoven thermal barrier 1.
  • the fibers mentioned above in particular polyaramides, can be mixed with fiberglass, carbon or silica.
  • the perforated needled nonwoven felt When mechanical resistance and resistance to washing are more particularly desired for the perforated needled nonwoven felt, it can be sewn, using non-rectilinear stitching lines but by sinuous example, on a fire-resistant membrane.

Landscapes

  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Nonwoven Fabrics (AREA)
  • Professional, Industrial, Or Sporting Protective Garments (AREA)
  • Laminated Bodies (AREA)
  • Thermal Insulation (AREA)
  • Building Environments (AREA)
EP20010490008 2000-03-03 2001-03-02 Isolierende feuerfeste Thermobarriere, Verfahren zu deren Herstellung und Bekleidung mit mindestens so einer Barriere als Innenisolierschicht Expired - Lifetime EP1129633B1 (de)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
FR0002788A FR2805718A1 (fr) 2000-03-03 2000-03-03 Barriere isolante thermique antifeu, procede de fabrication d'une telle barriere, vetement comprenant au moins une telle barriere en tant qu'isolant interne
FR0002788 2000-03-03

Publications (2)

Publication Number Publication Date
EP1129633A1 true EP1129633A1 (de) 2001-09-05
EP1129633B1 EP1129633B1 (de) 2004-08-11

Family

ID=8847714

Family Applications (1)

Application Number Title Priority Date Filing Date
EP20010490008 Expired - Lifetime EP1129633B1 (de) 2000-03-03 2001-03-02 Isolierende feuerfeste Thermobarriere, Verfahren zu deren Herstellung und Bekleidung mit mindestens so einer Barriere als Innenisolierschicht

Country Status (11)

Country Link
US (1) US6743498B2 (de)
EP (1) EP1129633B1 (de)
AT (1) ATE272952T1 (de)
AU (1) AU4076101A (de)
CA (1) CA2372970A1 (de)
DE (1) DE60104741T2 (de)
DK (1) DK1129633T3 (de)
ES (1) ES2225452T3 (de)
FR (1) FR2805718A1 (de)
PT (1) PT1129633E (de)
WO (1) WO2001064064A1 (de)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2873901A1 (fr) * 2004-08-04 2006-02-10 Duflot Ind Sa Barriere d'isolation thermique antifeu
WO2018078396A1 (en) * 2016-10-31 2018-05-03 RLEPL Limited An insulating material

Families Citing this family (31)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
NO312205B1 (no) * 1999-12-23 2002-04-08 Fridtjov Johansen Miljövennlig isolasjonsmateriale og fremgangsmåte for fremstilling av dette
ITVI20030037A1 (it) * 2003-02-25 2004-08-26 Q2 Roma Srl Tessuto ad elevate proprieta' ignifughe.
DE102004011296B4 (de) * 2004-03-09 2006-05-11 Sächsisches Textilforschungsinstitut e.V. Schutzkleidung, insbesondere Feuerwehrkleidung
US7348059B2 (en) * 2004-03-18 2008-03-25 E. I. Du Pont De Nemours And Company Modacrylic/aramid fiber blends for arc and flame protection and reduced shrinkage
US20050251900A1 (en) * 2004-05-17 2005-11-17 Harlacker John A Hazardous duty garments
US7913322B2 (en) * 2005-12-20 2011-03-29 Lion Apparel, Inc. Garment with padding
US9170071B2 (en) * 2006-05-01 2015-10-27 Warwick Mills Inc. Mosaic extremity protection system with transportable solid elements
US10364527B2 (en) * 2007-10-24 2019-07-30 W. L. Gore & Associates, Inc. Burn protective materials
US20090111345A1 (en) * 2007-10-24 2009-04-30 Dattatreya Panse Thermally protective materials
US20090110919A1 (en) * 2007-10-24 2009-04-30 Dattatreya Panse Burn protective materials
WO2009091432A1 (en) 2007-10-30 2009-07-23 Warwick Mills, Inc. Soft plate soft panel bonded multi layer armor materials
US7744999B2 (en) * 2008-07-11 2010-06-29 E. I. Du Pont De Nemours And Company Crystallized meta-aramid blends for improved flash fire and arc protection
IT1390963B1 (it) * 2008-07-24 2011-10-27 Roberto Fantino Prodotto stratificato ad elevata capacita' di isolamento termico ed autoestinguenza.
DE102008035351B4 (de) * 2008-07-29 2018-10-11 Dräger Safety AG & Co. KGaA Mehrschichtige Materialbahn insbesondere für Schutzanzüge
US8904915B2 (en) 2009-03-20 2014-12-09 Warwick Mills, Inc. Thermally vented body armor
USD670435S1 (en) * 2009-05-07 2012-11-06 Columbia Sportswear North America, Inc. Heat reflective material with pattern
USD670917S1 (en) 2011-02-18 2012-11-20 Columbia Sportswear North America, Inc. Heat reflective lining material
US20110041230A1 (en) * 2009-08-21 2011-02-24 Tex-Ray Industrial Co., Ltd. Clothing and cloth structure thereof
EP2556324A4 (de) 2010-04-08 2015-09-30 Warwick Mills Inc Panzerungsanordnung aus einem titanmosaikkörper
US9392825B2 (en) 2012-04-18 2016-07-19 Nike, Inc. Cold weather vented garment
US11606992B2 (en) 2012-04-18 2023-03-21 Nike, Inc. Vented garment
USD707974S1 (en) 2012-05-11 2014-07-01 Columbia Sportswear North America, Inc. Patterned prismatic bodywear lining material
US9409378B2 (en) 2012-09-25 2016-08-09 Pbi Performance Products, Inc. Thermal liner for protective garments
US10160184B2 (en) * 2013-06-03 2018-12-25 Xefco Pty Ltd Insulated radiant barriers in apparel
US11406148B2 (en) 2015-10-07 2022-08-09 Nike, Inc. Vented garment
EP3402355A4 (de) * 2016-01-14 2019-11-13 Southern Mills, Inc. Verbesserte flammhemmende thermische auskleidungen und kleidungsstücke damit
CA2964708A1 (en) * 2016-04-22 2017-10-22 General Recycled Protective fabric and process of manufacturing same
US11019865B2 (en) * 2016-10-06 2021-06-01 Nike, Inc. Insulated garment
US10743596B2 (en) * 2016-10-06 2020-08-18 Nike, Inc. Insulated vented garment formed using non-woven polymer sheets
CN107415385B (zh) * 2017-07-31 2018-06-12 圣华盾防护科技股份有限公司 防电弧服
CA3078246A1 (en) 2017-10-16 2019-04-25 Columbia Sportswear North America, Inc. Limited conduction heat reflecting materials

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0108865A1 (de) * 1982-10-14 1984-05-23 Sigri Elektrographit Gmbh Schutzkleidung
US4540617A (en) * 1984-08-22 1985-09-10 Teikoku Sen-I Co., Ltd. Fabric articles having a flame-resistant coating on at least one surface thereof
EP0501080A1 (de) * 1991-02-25 1992-09-02 LAINIERE DE PICARDIE: Société anonyme Feuerresistenter Verbundfutterstoff für Kleidung
US5697101A (en) * 1993-09-10 1997-12-16 Lion Apparel, Inc. Protective garment with apertured closed-cell foam liner
DE19827567A1 (de) * 1998-06-20 1999-12-23 Corovin Gmbh Verfahren zur Herstellung eines Vlieses aus Fasern

Family Cites Families (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5136723A (en) * 1991-02-15 1992-08-11 Lion Apparel, Inc. Firefighter garment with mesh liner
US5924134A (en) * 1993-09-10 1999-07-20 Lion Apparel, Inc. Protective garment with apertured closed-cell foam liner
DE60044465D1 (de) * 1999-07-27 2010-07-08 Claude Q C Hayes Wärmeschutzschicht

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0108865A1 (de) * 1982-10-14 1984-05-23 Sigri Elektrographit Gmbh Schutzkleidung
US4540617A (en) * 1984-08-22 1985-09-10 Teikoku Sen-I Co., Ltd. Fabric articles having a flame-resistant coating on at least one surface thereof
EP0501080A1 (de) * 1991-02-25 1992-09-02 LAINIERE DE PICARDIE: Société anonyme Feuerresistenter Verbundfutterstoff für Kleidung
US5697101A (en) * 1993-09-10 1997-12-16 Lion Apparel, Inc. Protective garment with apertured closed-cell foam liner
DE19827567A1 (de) * 1998-06-20 1999-12-23 Corovin Gmbh Verfahren zur Herstellung eines Vlieses aus Fasern

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2873901A1 (fr) * 2004-08-04 2006-02-10 Duflot Ind Sa Barriere d'isolation thermique antifeu
WO2006024786A1 (fr) * 2004-08-04 2006-03-09 Duflot Industrie, (S.A) Vetement de securite comprenant une barriere d'isolation thermique antifeu perforee
WO2018078396A1 (en) * 2016-10-31 2018-05-03 RLEPL Limited An insulating material

Also Published As

Publication number Publication date
DK1129633T3 (da) 2004-12-06
DE60104741T2 (de) 2005-09-01
US6743498B2 (en) 2004-06-01
ATE272952T1 (de) 2004-08-15
ES2225452T3 (es) 2005-03-16
CA2372970A1 (fr) 2001-09-07
FR2805718A1 (fr) 2001-09-07
WO2001064064A1 (fr) 2001-09-07
DE60104741D1 (de) 2004-09-16
US20020142132A1 (en) 2002-10-03
PT1129633E (pt) 2004-12-31
EP1129633B1 (de) 2004-08-11
AU4076101A (en) 2001-09-12

Similar Documents

Publication Publication Date Title
EP1129633B1 (de) Isolierende feuerfeste Thermobarriere, Verfahren zu deren Herstellung und Bekleidung mit mindestens so einer Barriere als Innenisolierschicht
EP1827151B1 (de) Mehrlagiges material für hitzeschutzbekleidung
EP1441612B1 (de) Komplexes schichtmaterial für schutzbekleidung, insbesondere für feuerwehrbekleidung
EP1098575B2 (de) Textilverbundmaterial zur herstellung von wärmeschutzkleidungstücken
EP0364370B1 (de) Feuerfestes, undurchlässiges Verbundtextil und Bekleidung und Sessel mit einem solchen Textil
FR2673207A1 (fr) Doublure composite anti-feu de vetement.
FR2846202A1 (fr) Textile composite anti-feu impermeable comprenant un reseau de fibres floquees
EP1441613B1 (de) Komplexes textilmaterial zur anwendung als wärmedämmung
EP1299013A1 (de) Wärmeschutzgewebe
EP1624767B1 (de) Textile fläche für schutzbekleidung, insbesondere für feuerwehrmänner, und mehrlagige systeme mit dieser fläche
FR2822855A1 (fr) Tissu renforce
WO2006024786A1 (fr) Vetement de securite comprenant une barriere d'isolation thermique antifeu perforee
FR2846201A1 (fr) Textile composite anti-feu impermeable comprenant au moins deux nappes non tissees
EP1413213B1 (de) Wasserundurchlässiges feuerfestes Verbundtextil mit Relief Fadennetwerk
EP1974623B1 (de) Textilkomplex bestehend aus einer Schicht, in die eine Reliefstruktur durch Verknüpfung eingefügt ist
FR2831773A1 (fr) Materiau complexe multicouches en feuille utilisable pour la realisation de vetements de protection, notamment pour sapeurs-pompiers
FR2830790A1 (fr) Nouveau produit composite pour la constitution de pieces ou structures allegees et resistantes

Legal Events

Date Code Title Description
PUAI Public reference made under article 153(3) epc to a published international application that has entered the european phase

Free format text: ORIGINAL CODE: 0009012

AK Designated contracting states

Kind code of ref document: A1

Designated state(s): AT BE CH CY DE DK ES FI FR GB GR IE IT LI LU MC NL PT SE TR

AX Request for extension of the european patent

Free format text: AL;LT;LV;MK;RO;SI

17P Request for examination filed

Effective date: 20020212

AKX Designation fees paid

Free format text: AT BE CH CY DE DK ES FI FR GB GR IE IT LI LU MC NL PT SE TR

17Q First examination report despatched

Effective date: 20030828

GRAP Despatch of communication of intention to grant a patent

Free format text: ORIGINAL CODE: EPIDOSNIGR1

GRAS Grant fee paid

Free format text: ORIGINAL CODE: EPIDOSNIGR3

GRAA (expected) grant

Free format text: ORIGINAL CODE: 0009210

AK Designated contracting states

Kind code of ref document: B1

Designated state(s): AT BE CH CY DE DK ES FI FR GB GR IE IT LI LU MC NL PT SE TR

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: AT

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20040811

Ref country code: FI

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20040811

Ref country code: NL

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20040811

Ref country code: IE

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20040811

REG Reference to a national code

Ref country code: GB

Ref legal event code: FG4D

Free format text: NOT ENGLISH

REG Reference to a national code

Ref country code: CH

Ref legal event code: EP

REG Reference to a national code

Ref country code: IE

Ref legal event code: FG4D

Free format text: FRENCH

REF Corresponds to:

Ref document number: 60104741

Country of ref document: DE

Date of ref document: 20040916

Kind code of ref document: P

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: GR

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20041111

Ref country code: SE

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20041111

REG Reference to a national code

Ref country code: DK

Ref legal event code: T3

REG Reference to a national code

Ref country code: PT

Ref legal event code: TE4A

Free format text: DUFLOT INDUSTRIE, S. A. FR

Effective date: 20041028

Ref country code: PT

Ref legal event code: SC4A

Free format text: AVAILABILITY OF NATIONAL TRANSLATION

Effective date: 20041028

GBT Gb: translation of ep patent filed (gb section 77(6)(a)/1977)

Effective date: 20041213

NLV1 Nl: lapsed or annulled due to failure to fulfill the requirements of art. 29p and 29m of the patents act
PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: CY

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20050302

Ref country code: LU

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20050302

REG Reference to a national code

Ref country code: ES

Ref legal event code: FG2A

Ref document number: 2225452

Country of ref document: ES

Kind code of ref document: T3

REG Reference to a national code

Ref country code: IE

Ref legal event code: FD4D

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: CH

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20050331

Ref country code: MC

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20050331

Ref country code: LI

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20050331

PLBE No opposition filed within time limit

Free format text: ORIGINAL CODE: 0009261

STAA Information on the status of an ep patent application or granted ep patent

Free format text: STATUS: NO OPPOSITION FILED WITHIN TIME LIMIT

26N No opposition filed

Effective date: 20050512

REG Reference to a national code

Ref country code: CH

Ref legal event code: PL

REG Reference to a national code

Ref country code: CH

Ref legal event code: PFA

Owner name: DUFLOT INDUSTRIE

Free format text: DUFLOT INDUSTRIE, S.A.#14, RUE DE L'INDUSTRIE#59157 BEAUVOIS-EN-CAMBRESIS (FR) -TRANSFER TO- DUFLOT INDUSTRIE#ZONE INDUSTRIELLE CHEMIN DEPARTEMENTAL 115 A#F-59542 CAUDRY CEDEX (FR)

PGFP Annual fee paid to national office [announced via postgrant information from national office to epo]

Ref country code: TR

Payment date: 20060213

Year of fee payment: 6

PGFP Annual fee paid to national office [announced via postgrant information from national office to epo]

Ref country code: DK

Payment date: 20060221

Year of fee payment: 6

PGFP Annual fee paid to national office [announced via postgrant information from national office to epo]

Ref country code: PT

Payment date: 20060302

Year of fee payment: 6

PGFP Annual fee paid to national office [announced via postgrant information from national office to epo]

Ref country code: DE

Payment date: 20060307

Year of fee payment: 6

PGFP Annual fee paid to national office [announced via postgrant information from national office to epo]

Ref country code: ES

Payment date: 20060317

Year of fee payment: 6

PGFP Annual fee paid to national office [announced via postgrant information from national office to epo]

Ref country code: BE

Payment date: 20060403

Year of fee payment: 6

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: PT

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20070903

REG Reference to a national code

Ref country code: PT

Ref legal event code: MM4A

Free format text: LAPSE DUE TO NON-PAYMENT OF FEES

Effective date: 20070903

REG Reference to a national code

Ref country code: DK

Ref legal event code: EBP

GBPC Gb: european patent ceased through non-payment of renewal fee

Effective date: 20070302

BERE Be: lapsed

Owner name: S.A. *DUFLOT INDUSTRIE

Effective date: 20070331

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: BE

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20070331

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: DE

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20071002

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: GB

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20070302

Ref country code: DK

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20070402

REG Reference to a national code

Ref country code: ES

Ref legal event code: FD2A

Effective date: 20070303

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: ES

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20070303

PGFP Annual fee paid to national office [announced via postgrant information from national office to epo]

Ref country code: GB

Payment date: 20060217

Year of fee payment: 6

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: TR

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20040811

PGFP Annual fee paid to national office [announced via postgrant information from national office to epo]

Ref country code: IT

Payment date: 20091228

Year of fee payment: 9

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: IT

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20100302

REG Reference to a national code

Ref country code: FR

Ref legal event code: PLFP

Year of fee payment: 16

REG Reference to a national code

Ref country code: FR

Ref legal event code: PLFP

Year of fee payment: 17

REG Reference to a national code

Ref country code: FR

Ref legal event code: PLFP

Year of fee payment: 18

PGFP Annual fee paid to national office [announced via postgrant information from national office to epo]

Ref country code: FR

Payment date: 20191218

Year of fee payment: 20