EP0311689A4 - Procede de mono-hydroformylation selective de diolefine. - Google Patents

Procede de mono-hydroformylation selective de diolefine.

Info

Publication number
EP0311689A4
EP0311689A4 EP19880902548 EP88902548A EP0311689A4 EP 0311689 A4 EP0311689 A4 EP 0311689A4 EP 19880902548 EP19880902548 EP 19880902548 EP 88902548 A EP88902548 A EP 88902548A EP 0311689 A4 EP0311689 A4 EP 0311689A4
Authority
EP
European Patent Office
Prior art keywords
selectively
diolefin
monohydroformylating
arylethenyl
vinylbenzene
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
EP19880902548
Other languages
German (de)
English (en)
Other versions
EP0311689B1 (fr
EP0311689A1 (fr
Inventor
Isoo Shimizu
Yasuo Matsumura
Yutaka Arai
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Eneos Corp
Original Assignee
Nippon Petrochemicals Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Nippon Petrochemicals Co Ltd filed Critical Nippon Petrochemicals Co Ltd
Publication of EP0311689A1 publication Critical patent/EP0311689A1/fr
Publication of EP0311689A4 publication Critical patent/EP0311689A4/fr
Application granted granted Critical
Publication of EP0311689B1 publication Critical patent/EP0311689B1/fr
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
    • C07C51/16—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation
    • C07C51/21—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen
    • C07C51/255—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen of compounds containing six-membered aromatic rings without ring-splitting
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C15/00—Cyclic hydrocarbons containing only six-membered aromatic rings as cyclic parts
    • C07C15/40—Cyclic hydrocarbons containing only six-membered aromatic rings as cyclic parts substituted by unsaturated carbon radicals
    • C07C15/50—Cyclic hydrocarbons containing only six-membered aromatic rings as cyclic parts substituted by unsaturated carbon radicals polycyclic non-condensed
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/49—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reaction with carbon monoxide
    • C07C45/50—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reaction with carbon monoxide by oxo-reactions
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/78—Separation; Purification; Stabilisation; Use of additives
    • C07C45/81—Separation; Purification; Stabilisation; Use of additives by change in the physical state, e.g. crystallisation
    • C07C45/82—Separation; Purification; Stabilisation; Use of additives by change in the physical state, e.g. crystallisation by distillation
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C47/00—Compounds having —CHO groups
    • C07C47/20—Unsaturated compounds having —CHO groups bound to acyclic carbon atoms
    • C07C47/228—Unsaturated compounds having —CHO groups bound to acyclic carbon atoms containing six-membered aromatic rings, e.g. phenylacetaldehyde
    • C07C47/232—Unsaturated compounds having —CHO groups bound to acyclic carbon atoms containing six-membered aromatic rings, e.g. phenylacetaldehyde having unsaturation outside the aromatic rings
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C47/00—Compounds having —CHO groups
    • C07C47/28—Saturated compounds having —CHO groups bound to carbon atoms of rings other than six—membered aromatic rings
    • C07C47/32—Saturated compounds having —CHO groups bound to carbon atoms of rings other than six—membered aromatic rings with a six-membered ring
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C5/00—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms
    • C07C5/32—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by dehydrogenation with formation of free hydrogen
    • C07C5/327—Formation of non-aromatic carbon-to-carbon double bonds only
    • C07C5/333—Catalytic processes
    • C07C5/3332—Catalytic processes with metal oxides or metal sulfides
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
    • C07C51/16—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation
    • C07C51/21—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen
    • C07C51/23—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen of oxygen-containing groups to carboxyl groups
    • C07C51/245—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen of oxygen-containing groups to carboxyl groups of keto groups or secondary alcohol groups
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
    • C07C51/347—Preparation of carboxylic acids or their salts, halides or anhydrides by reactions not involving formation of carboxyl groups
    • C07C51/373—Preparation of carboxylic acids or their salts, halides or anhydrides by reactions not involving formation of carboxyl groups by introduction of functional groups containing oxygen only in doubly bound form
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C59/00—Compounds having carboxyl groups bound to acyclic carbon atoms and containing any of the groups OH, O—metal, —CHO, keto, ether, groups, groups, or groups
    • C07C59/40—Unsaturated compounds
    • C07C59/76—Unsaturated compounds containing keto groups
    • C07C59/84—Unsaturated compounds containing keto groups containing six membered aromatic rings

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Materials Engineering (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Catalysts (AREA)

Abstract

Procédé d'hydroformylation sélective de dioléfine, consistant à faire réagir un (1-aryléthényl)-vinylbenzène avec de l'oxyde de carbone et de l'hydrogène à une température de réaction comprise entre 40 et 200°C et à une pression égale ou supérieure à 5 kg/cm2 en présence d'un catalyseur de carbonylation à base d'un métal de transition, afin de n'effectuer que l'hydroformylation sélective du groupe vinyle, pour produire le alpha-((1-aryléthényl)phényl)-propionaldéhyde. La substance de départ pour l'hydroformylation peut être un mélange de vinylbenzène avec un 1,1-di(aryle substitué)éthylène non substitué par un groupe vinyle.
EP88902548A 1987-03-12 1988-03-12 Procede de mono-hydroformylation selective de diolefine Expired - Lifetime EP0311689B1 (fr)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
JP62057098A JPH07100678B2 (ja) 1987-03-12 1987-03-12 α−（３−ベンゾイルフエニル）プロピオン酸の製造方法
JP57098/87 1987-03-12

Publications (3)

Publication Number Publication Date
EP0311689A1 EP0311689A1 (fr) 1989-04-19
EP0311689A4 true EP0311689A4 (fr) 1989-07-24
EP0311689B1 EP0311689B1 (fr) 1992-06-10

Family

ID=13046031

Family Applications (2)

Application Number Title Priority Date Filing Date
EP88103828A Expired - Lifetime EP0282066B1 (fr) 1987-03-12 1988-03-10 Aldéhyde (phényléthényl)phénylpropionique et procédé de préparation de l'acide (benzoylphényl)propionique à l'aide de ce composé
EP88902548A Expired - Lifetime EP0311689B1 (fr) 1987-03-12 1988-03-12 Procede de mono-hydroformylation selective de diolefine

Family Applications Before (1)

Application Number Title Priority Date Filing Date
EP88103828A Expired - Lifetime EP0282066B1 (fr) 1987-03-12 1988-03-10 Aldéhyde (phényléthényl)phénylpropionique et procédé de préparation de l'acide (benzoylphényl)propionique à l'aide de ce composé

Country Status (7)

Country Link
US (2) US4889952A (fr)
EP (2) EP0282066B1 (fr)
JP (1) JPH07100678B2 (fr)
KR (2) KR930010405B1 (fr)
CA (1) CA1304401C (fr)
DE (2) DE3871410D1 (fr)
WO (1) WO1988007033A1 (fr)

Families Citing this family (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH07100678B2 (ja) * 1987-03-12 1995-11-01 日本石油化学株式会社 α−（３−ベンゾイルフエニル）プロピオン酸の製造方法
JPS63233945A (ja) * 1987-03-23 1988-09-29 Nippon Petrochem Co Ltd ジオレフインの選択的ヒドロフオルミル化方法
CA2005845C (fr) * 1988-12-21 2001-01-09 Isoo Shimizu Methode de preparation de l'acide -(4-isobutylphenyl)propionique ou de son precurseur
JP2782080B2 (ja) * 1989-03-06 1998-07-30 日本石油化学株式会社 α―（３―ベンゾイルフェニル）プロピオン酸誘導体の製造方法
US5175266A (en) * 1991-04-19 1992-12-29 Triplex Pharmaceutical Corporation Nucleosides and oligonucleosides with a phosphate-free internucleoside backbone and process for preparing the same
US5318246A (en) * 1991-05-29 1994-06-07 Shimano Inc. Drag apparatus for a fishing reel
JP2000016952A (ja) * 1998-07-01 2000-01-18 Nippon Petrochem Co Ltd 炭化水素の製造方法
WO2004113265A1 (fr) * 2003-06-20 2004-12-29 William Marsh Rice University Nouveaux polymeres ignifuges
FR2869901B1 (fr) * 2004-05-07 2006-07-07 Arkema Sa Procede de fabrication de diphenyl ethylene
EP2076482B1 (fr) * 2006-10-17 2010-08-11 Ge Healthcare As Procede de fabrication d'acides alpha-ceto et de leurs esters
DE102014201122A1 (de) * 2014-01-22 2015-07-23 Leibniz-Institut Für Katalyse E.V. An Der Universität Rostock (Likat) Verfahren zur katalytischen Herstellung von ungesättigten Aldehyden

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0282066A2 (fr) * 1987-03-12 1988-09-14 Nippon Petrochemicals Company, Limited Aldéhyde (phényléthényl)phénylpropionique et procédé de préparation de l'acide (benzoylphényl)propionique à l'aide de ce composé
EP0304495A1 (fr) * 1987-03-12 1989-03-01 Nippon Petrochemicals Company, Limited Procede de monohydroesterification selective de diolefine

Family Cites Families (16)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4028404A (en) * 1967-07-31 1977-06-07 Allen & Hanburys Limited Acetic acid derivatives
DE2235466C3 (de) * 1972-07-20 1975-03-13 Basf Ag, 6700 Ludwigshafen 3-Phenylpropanale und 4-Phenylbutanale sowie ein Verfahren zu deren Herstellung
US4035376A (en) * 1972-10-24 1977-07-12 Janssen Pharmaceutica N.V. Aroyl-substituted phenylacetic acid derivatives
US4268688A (en) * 1973-02-16 1981-05-19 Monsanto Company Asymmetric hydroformylation process
DE2340812C2 (de) * 1973-08-11 1982-05-27 Basf Ag, 6700 Ludwigshafen Phenylpropanale sowie ein Verfahren zu deren Herstellung
IT1035947B (it) * 1975-06-05 1979-10-20 Acraf Sintesi dell acido m. benzoil idratropico
YU39566B (en) * 1978-04-07 1984-12-31 Lek Tovarna Farmacevtskih Process of preparing 2-(3-benzoyl-phenyl)-propionic acid
YU39415B (en) * 1978-04-10 1984-12-31 Lek Tovarna Farmacevtskih Process for preparing 2-(3-benzoyl-phenyl)-propionic acid
DE3170330D1 (en) * 1980-11-21 1985-06-05 Givaudan & Cie Sa Process for the production of aldehydes and intermediate products
JPS59110643A (ja) * 1982-12-16 1984-06-26 Kao Corp ２−エチリデン−５（又は６）−ホルミルビシクロ〔２．２．１〕ヘプタンの製造法
JPS58210033A (ja) * 1982-06-02 1983-12-07 Kao Corp ビシクロ〔２，２，１〕ヘブタン誘導体およびその製造法ならびにこれを含有する香料組成物
US4694100A (en) * 1984-07-14 1987-09-15 Nippon Petrochemicals Company, Ltd. Method for producing α-(p-isobutylphenyl)propionic acid or its alkyl esters
JPS63233945A (ja) * 1987-03-23 1988-09-29 Nippon Petrochem Co Ltd ジオレフインの選択的ヒドロフオルミル化方法
JPH02238234A (ja) * 1989-03-10 1990-09-20 Matsushita Seiko Co Ltd 換気空調ユニット
JPH052614A (ja) * 1991-06-26 1993-01-08 Omron Corp レイアウト設計支援システム
JPH0697249A (ja) * 1992-09-11 1994-04-08 Ikutoku Gakuen シリコンウェーハの評価方法及びその装置

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0282066A2 (fr) * 1987-03-12 1988-09-14 Nippon Petrochemicals Company, Limited Aldéhyde (phényléthényl)phénylpropionique et procédé de préparation de l'acide (benzoylphényl)propionique à l'aide de ce composé
EP0304495A1 (fr) * 1987-03-12 1989-03-01 Nippon Petrochemicals Company, Limited Procede de monohydroesterification selective de diolefine

Non-Patent Citations (2)

* Cited by examiner, † Cited by third party
Title
PATENT ABSTRACTS OF JAPAN, vol. 13, no. 29 (C-562)[3377], 23rd January 1989; & JP-A-63 233 945 (NIPPON PETROCHEM. CO. LTD) 29-09-1988 *
See also references of WO8807033A1 *

Also Published As

Publication number Publication date
KR960002599B1 (ko) 1996-02-23
CA1304401C (fr) 1992-06-30
JPS63225334A (ja) 1988-09-20
WO1988007033A1 (fr) 1988-09-22
US4982007A (en) 1991-01-01
US4889952A (en) 1989-12-26
KR880011061A (ko) 1988-10-26
KR890700564A (ko) 1989-04-25
EP0282066B1 (fr) 1992-05-27
EP0282066A2 (fr) 1988-09-14
EP0311689B1 (fr) 1992-06-10
JPH07100678B2 (ja) 1995-11-01
DE3871410D1 (de) 1992-07-02
EP0282066A3 (en) 1989-09-27
EP0311689A1 (fr) 1989-04-19
DE3871898D1 (de) 1992-07-16
KR930010405B1 (ko) 1993-10-23
DE3871898T2 (de) 1993-02-04

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