EP0286845B1 - Verfahren zum Verfeuern von insb. salzhaltiger Braunkohle - Google Patents
Verfahren zum Verfeuern von insb. salzhaltiger Braunkohle Download PDFInfo
- Publication number
- EP0286845B1 EP0286845B1 EP88103982A EP88103982A EP0286845B1 EP 0286845 B1 EP0286845 B1 EP 0286845B1 EP 88103982 A EP88103982 A EP 88103982A EP 88103982 A EP88103982 A EP 88103982A EP 0286845 B1 EP0286845 B1 EP 0286845B1
- Authority
- EP
- European Patent Office
- Prior art keywords
- free space
- fluidised bed
- ash
- temperature
- flue gas
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 239000003077 lignite Substances 0.000 title claims abstract description 17
- 238000000034 method Methods 0.000 title claims description 10
- 238000002485 combustion reaction Methods 0.000 title abstract description 16
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 title abstract description 7
- 239000011780 sodium chloride Substances 0.000 title abstract description 7
- 239000003546 flue gas Substances 0.000 claims abstract description 25
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 claims abstract description 24
- 239000000567 combustion gas Substances 0.000 claims abstract 3
- 238000001816 cooling Methods 0.000 claims abstract 2
- 238000010438 heat treatment Methods 0.000 claims description 8
- 239000003245 coal Substances 0.000 claims description 7
- 238000010304 firing Methods 0.000 claims description 5
- 239000007789 gas Substances 0.000 claims description 4
- 150000003839 salts Chemical class 0.000 claims description 4
- 206010022000 influenza Diseases 0.000 claims description 3
- 206010016256 fatigue Diseases 0.000 claims 1
- 239000003513 alkali Substances 0.000 abstract description 5
- 238000004064 recycling Methods 0.000 abstract 1
- 239000002956 ash Substances 0.000 description 14
- 239000000446 fuel Substances 0.000 description 4
- 239000000463 material Substances 0.000 description 4
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 3
- 239000000470 constituent Substances 0.000 description 3
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
- 150000003841 chloride salts Chemical class 0.000 description 2
- 238000004140 cleaning Methods 0.000 description 2
- 238000010276 construction Methods 0.000 description 2
- 239000000428 dust Substances 0.000 description 2
- 239000002245 particle Substances 0.000 description 2
- 150000003467 sulfuric acid derivatives Chemical class 0.000 description 2
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- 235000008733 Citrus aurantifolia Nutrition 0.000 description 1
- 235000002918 Fraxinus excelsior Nutrition 0.000 description 1
- 235000011941 Tilia x europaea Nutrition 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 230000002378 acidificating effect Effects 0.000 description 1
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 1
- 239000002585 base Substances 0.000 description 1
- 238000005452 bending Methods 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 239000010883 coal ash Substances 0.000 description 1
- 229910052681 coesite Inorganic materials 0.000 description 1
- 229910052593 corundum Inorganic materials 0.000 description 1
- 229910052906 cristobalite Inorganic materials 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
- 230000002349 favourable effect Effects 0.000 description 1
- 239000012530 fluid Substances 0.000 description 1
- 238000005243 fluidization Methods 0.000 description 1
- 239000010881 fly ash Substances 0.000 description 1
- 239000004571 lime Substances 0.000 description 1
- 238000002844 melting Methods 0.000 description 1
- 230000008018 melting Effects 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- 230000002035 prolonged effect Effects 0.000 description 1
- 230000003134 recirculating effect Effects 0.000 description 1
- 238000009938 salting Methods 0.000 description 1
- 239000004576 sand Substances 0.000 description 1
- 239000000377 silicon dioxide Substances 0.000 description 1
- 235000012239 silicon dioxide Nutrition 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 229910052682 stishovite Inorganic materials 0.000 description 1
- 229910052905 tridymite Inorganic materials 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
- 229910001845 yogo sapphire Inorganic materials 0.000 description 1
Images
Classifications
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F23—COMBUSTION APPARATUS; COMBUSTION PROCESSES
- F23C—METHODS OR APPARATUS FOR COMBUSTION USING FLUID FUEL OR SOLID FUEL SUSPENDED IN A CARRIER GAS OR AIR
- F23C10/00—Fluidised bed combustion apparatus
- F23C10/002—Fluidised bed combustion apparatus for pulverulent solid fuel
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F22—STEAM GENERATION
- F22B—METHODS OF STEAM GENERATION; STEAM BOILERS
- F22B31/00—Modifications of boiler construction, or of tube systems, dependent on installation of combustion apparatus; Arrangements of dispositions of combustion apparatus
- F22B31/0007—Modifications of boiler construction, or of tube systems, dependent on installation of combustion apparatus; Arrangements of dispositions of combustion apparatus with combustion in a fluidized bed
- F22B31/0015—Modifications of boiler construction, or of tube systems, dependent on installation of combustion apparatus; Arrangements of dispositions of combustion apparatus with combustion in a fluidized bed for boilers of the water tube type
- F22B31/003—Modifications of boiler construction, or of tube systems, dependent on installation of combustion apparatus; Arrangements of dispositions of combustion apparatus with combustion in a fluidized bed for boilers of the water tube type with tubes surrounding the bed or with water tube wall partitions
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F23—COMBUSTION APPARATUS; COMBUSTION PROCESSES
- F23C—METHODS OR APPARATUS FOR COMBUSTION USING FLUID FUEL OR SOLID FUEL SUSPENDED IN A CARRIER GAS OR AIR
- F23C9/00—Combustion apparatus characterised by arrangements for returning combustion products or flue gases to the combustion chamber
- F23C9/003—Combustion apparatus characterised by arrangements for returning combustion products or flue gases to the combustion chamber for pulverulent fuel
Definitions
- the invention relates to a method for firing lignite, in particular salt-containing lignite with an excessive amount of alkalis according to the preamble of claim 1, as is known from DE-A-3 503 603.
- Lignites of normal composition can be burned in dust and fluidized bed furnaces from steam generators.
- the ash of the lignite has an unfavorable ratio of so-called basic constituents such as CaO and MgO to so-called acidic constituents such as SiO2 and Al2O3 in the presence of alkalis, the lignite becomes more difficult to burn, the higher the base / acid ratio and become alkaline (BRAUNKOHLE 1976, No. 6, pp. 206 - 217).
- These lignites can then only be fired using special constructions or are not considered suitable for firing.
- As a special construction on dust-fired boilers a low flame temperature by recirculating cold flue gas in question.
- EP-A-0 003 792 discloses a process for the combustion of salt-laden residues in a fluidized bed furnace. With this method, a temperature of 720 ° C. should not be exceeded in the fluidized bed, which is achieved via the fuel supply. In order to maintain a flue gas temperature of 850 ° C, additional fuel is fed into the free space above the fluidized bed. Fluidized bed material is withdrawn discontinuously from the fluidized bed and replaced by fresh sand.
- DE-A-3 503 603 describes a firing system which is also suitable for the combustion of more volatile fuels such as lignite.
- the combustion system comprises a combustion chamber which consists at least partially of cooled walls and which contains a smoldering chamber in the lower part and an afterburning chamber in the upper part, the smoldering chamber being able to have a fluidized bed.
- the melting chamber is operated under substoichiometric conditions at a temperature of 500 to 1200 ° C and the afterburning chamber is operated under superstoichiometric conditions at a temperature of 800 to 1400 ° C.
- Cold flue gas can be added to the combustion air in order to achieve low combustion chamber temperatures.
- the invention has for its object to provide a method for burning lignite, in which the most favorable combustion temperature in the fluidized bed and the free space can be set when using normal lignite and which is also suitable for those saline lignites that are not used in conventional steam generators or could only be used to a limited extent.
- the fluidized bed allows a lower combustion temperature compared to dust firing.
- the cold flue gas serves in the absence of bundle heating surfaces in the fluidized bed and / or the free space as a heat carrier for receiving the Combustion heat from the fluidized bed and the free space.
- saline lignite with an increased alkali content it is possible to maintain such a low temperature that the alkalis are only partially evaporated. Maintaining low wall temperatures in the free space prevents deposits that are difficult to remove from sticking to the pipe wall.
- a selectively adjustable, higher temperature ensures that the gaseous constituents of the coal and the entrained coal particles escaping from the fluidized bed are burned out. It is achieved by the features of claim 2 that the heating surfaces with a high wall temperature, on which fuel-related saline deposits adhere, are laid in a second flue gas duct. The salt-containing products resulting from the cleaning of the heating surfaces therefore do not get back into the fluidized bed, so that salting is avoided.
- the features of claim 3 serve to maintain a sufficient amount of bed material for the operation of the fluidized bed without the alkali content accumulating in the fluidized bed.
- a steam generator used to fire lignite is designed as a multi-pass boiler and has a first flue gas duct 1, a second flue gas duct 2 and a third flue gas duct 3, which are delimited by gas-tight pipe walls through which water and steam flow.
- the first flue gas duct 1 serves as a combustion chamber and takes up a fluidized bed 4 in the lower part.
- the fluidized bed 4 is with an outside Ash processing device 5 connected.
- a constriction 6 can be formed above the fluidized bed 4 by bending, which causes an additional mixing of the flue gases.
- the interior of the first flue gas flue 1 is kept free of bundle heating surfaces and represents a free space 7.
- the second and third flue gas flues 2, 3 are connected by a boiler funnel 8, at the lower end of which a discharge device 9 is arranged.
- a discharge device 9 is arranged in the second and third flue gas flues 2, 3, heating surfaces 10, 11 are arranged, which are connected as superheaters or economizers. Sootblowers are provided for cleaning the heating surfaces 10, 11.
- saline lignite is preferably fired, the ash of which contains an alkali fraction of more than 2%.
- This coal is fed via a coal entry 12 into the fluidized bed 4, in which it is burned with the aid of air.
- the air is fed into the fluidized bed via a fan 13 through an air line 14. All of the air required for the combustion is preferably introduced into the fluidized bed 4. Alternatively, it can also be provided that part of the air is introduced as secondary and tertiary air into the free space 7 above the fluidized bed 4. Such an air division is particularly to be provided when normal brown coal with an increased nitrogen content is used.
- Cold flue gas with exhaust gas temperature is drawn off from the cold end of the steam generator and fed into the fluidized bed 4 and the free space 7 above the fluidized bed 4 via a recirculation blower 15 and flue gas lines 16.
- a pressure-increasing fan 17 is used to compensate for the pressure difference within the fluidized bed 4.
- the cold flue gas partly absorbs the combustion heat generated in the fluidized bed 4 and in the post-combustion zone within the free space 7.
- the amount and the distribution of the cold flue gas is carried out in such a way that a temperature of at most 780 degrees C. is set in the fluidized bed 4 and in front of the first heating surface 10 in the second flue gas duct 2.
- the gas temperature is about 850 degrees C.
- a wall temperature is set which is about 400 degrees C below the softening temperature of the fly ash.
- the low bed temperature ensures that a large part of the alkalis in the fluidized bed 4 do not evaporate and that the alkali chlorides and sulfates of the coal ash are bound, for example, to lime which is fed to the fluidized bed 4 together with the coal or separately therefrom.
- Prolonged continuous operation with saline lignite leads to a concentration of the salt content and to a uniform grain formation in the fluidized bed, which limits uniform fluidization. For this reason, it is necessary to continuously remove bed ash. For this reason, part of the bed ash is removed from the fluidized bed 4 via an ash line 18, cooled and fed to the ash processing device 5.
- the ash processing device is provided with an inlet 19 and a mixing device 20.
- By treating the ash with a solvent in the ash treatment device 5 a large part of the ash or the alkalis is dissolved and removed via a drain line 21.
- the bed material is reactivated to bind the sulfates and chlorides.
- the reactivated ash is returned to the fluidized bed 4 to maintain the salt-free bed material.
- the ashes can be returned directly or via the coal entry 12. Part of the processed ash can be removed from the system via a drain line 22.
Landscapes
- Engineering & Computer Science (AREA)
- Chemical & Material Sciences (AREA)
- Combustion & Propulsion (AREA)
- Mechanical Engineering (AREA)
- General Engineering & Computer Science (AREA)
- Physics & Mathematics (AREA)
- Thermal Sciences (AREA)
- Fluidized-Bed Combustion And Resonant Combustion (AREA)
- Solid Fuels And Fuel-Associated Substances (AREA)
- Solid-Fuel Combustion (AREA)
- Control Of Steam Boilers And Waste-Gas Boilers (AREA)
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
AT88103982T ATE64190T1 (de) | 1987-04-15 | 1988-03-14 | Verfahren zum verfeuern von insb. salzhaltiger braunkohle. |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE19873712801 DE3712801A1 (de) | 1987-04-15 | 1987-04-15 | Verfahren zum verfeuern von insb. salzhaltiger braunkohle |
DE3712801 | 1987-04-15 |
Publications (2)
Publication Number | Publication Date |
---|---|
EP0286845A1 EP0286845A1 (de) | 1988-10-19 |
EP0286845B1 true EP0286845B1 (de) | 1991-06-05 |
Family
ID=6325688
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP88103982A Expired - Lifetime EP0286845B1 (de) | 1987-04-15 | 1988-03-14 | Verfahren zum Verfeuern von insb. salzhaltiger Braunkohle |
Country Status (5)
Country | Link |
---|---|
EP (1) | EP0286845B1 (hu) |
AT (1) | ATE64190T1 (hu) |
AU (1) | AU594867B2 (hu) |
DD (1) | DD268758A5 (hu) |
DE (2) | DE3712801A1 (hu) |
Families Citing this family (9)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE3814314C1 (hu) * | 1988-04-28 | 1989-06-22 | Deutsche Babcock Werke Ag, 4200 Oberhausen, De | |
FI91800C (sv) * | 1991-09-12 | 1994-08-10 | Imatran Voima Oy | Förfarande och anordning vid avkylning av cirkulationsmassan i en svävväddspanna |
DE19855670A1 (de) | 1998-12-02 | 1999-12-09 | Siemens Ag | Verfahren zum Betreiben eines Dampferzeugers und Dampferzeuger zur Durchführung des Verfahrens |
DE19903510C2 (de) * | 1999-01-29 | 2002-03-07 | Mg Technologies Ag | Verfahren zum Verbrennen oder Vergasen in der zirkulierenden Wirbelschicht |
DE102005035659A1 (de) * | 2005-07-29 | 2007-02-01 | Siemens Ag | Verfahren zum Betreiben eines Kessels eines Kohlekraftwerkes sowie nach diesem Verfahren betreibbarer Kessel |
DE102011117325A1 (de) * | 2011-03-24 | 2012-09-27 | h s beratung GmbH & Co. KG | Erhöhung des Heizwertbereichs von Brennstoffen sowie des Bereichs zwischen Minimal- und Maximallast in Wirbelschichtfeuerungen |
CN104330437B (zh) * | 2014-10-15 | 2017-02-15 | 上海发电设备成套设计研究院 | 一种用于防止高碱煤结焦沾污研究的实验装置 |
US10415825B2 (en) * | 2016-06-07 | 2019-09-17 | The Babcock & Wilcox Company | Methods of generating energy from cellulosic biofuel waste |
CN113266844B (zh) * | 2021-06-08 | 2022-05-27 | 南方电网电力科技股份有限公司 | 一种基于对冲锅炉的壁温偏差控制方法及装置 |
Family Cites Families (13)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE2808029A1 (de) | 1978-02-24 | 1979-08-30 | Bayer Ag | Verbrennung von salzbeladenen rueckstaenden in einem wirbelbettofen |
DE2857527C2 (de) * | 1978-04-14 | 1982-11-18 | Babcock-Hitachi K.K., Tokyo | Verfahren zum Verbrennen von Abfällen |
DK310979A (da) * | 1978-08-04 | 1980-02-05 | Energy Equip | Fremgangsmaade til styring af driften af fyringsanlaeg med fluidiseret bund samt midler til brug ved fremgangsmaadens gennemfoerelse |
DE2935687A1 (de) * | 1978-09-08 | 1980-04-03 | Babcock Hitachi Kk | Verfahren und vorrichtung zur regenerierung eines fluidisiermediums |
CH651644A5 (de) * | 1980-11-13 | 1985-09-30 | Sulzer Ag | Gekuehlter verbrennungsraum mit einer wirbelschichtfeuerung und verfahren zum betrieb desselben. |
DE3107355C2 (de) * | 1981-02-27 | 1990-11-15 | L. & C. Steinmüller GmbH, 5270 Gummersbach | Verfahren zur Erzeugung einer Wirbelschicht mit Wirbelschichtmassenregulierung |
US4433631A (en) * | 1981-05-18 | 1984-02-28 | Fluidyne Engineering Corporation | Method and apparatus for producing a useful stream of hot gas from a fluidized bed combustor while controlling the bed's temperature |
DE3224909A1 (de) * | 1982-07-03 | 1984-01-05 | Ferdinand Lentjes, Dampfkessel- und Maschinenbau, 4000 Düsseldorf | Wirbelschichtfeuerung |
DD215144A1 (de) * | 1983-05-19 | 1984-10-31 | Wolfgang Kluge | Verfahren zur verbrennung fester, salzhaltiger brennstoffe in wirbelschichtfeuerungen |
DE3503603A1 (de) | 1985-02-02 | 1986-08-07 | Cornel. Schmidt GmbH & Co KG, 5090 Leverkusen | Feuerungsanlage |
CN1010425B (zh) * | 1985-05-23 | 1990-11-14 | 西门子股份有限公司 | 沸腾炉 |
JPS62182516A (ja) * | 1986-02-05 | 1987-08-10 | Ishikawajima Harima Heavy Ind Co Ltd | 流動床式焼却炉の燃焼方法 |
DE3604318C2 (de) * | 1986-02-12 | 1994-01-13 | Metallgesellschaft Ag | Verfahren zur Verbrennung von Kuhmist |
-
1987
- 1987-04-15 DE DE19873712801 patent/DE3712801A1/de active Granted
-
1988
- 1988-03-14 AT AT88103982T patent/ATE64190T1/de not_active IP Right Cessation
- 1988-03-14 DE DE8888103982T patent/DE3863115D1/de not_active Expired - Lifetime
- 1988-03-14 EP EP88103982A patent/EP0286845B1/de not_active Expired - Lifetime
- 1988-03-23 AU AU13506/88A patent/AU594867B2/en not_active Expired
- 1988-04-13 DD DD88314700A patent/DD268758A5/de not_active IP Right Cessation
Also Published As
Publication number | Publication date |
---|---|
DE3712801C2 (hu) | 1990-04-12 |
ATE64190T1 (de) | 1991-06-15 |
DE3712801A1 (de) | 1988-11-03 |
AU594867B2 (en) | 1990-03-15 |
DD268758A5 (de) | 1989-06-07 |
EP0286845A1 (de) | 1988-10-19 |
DE3863115D1 (de) | 1991-07-11 |
AU1350688A (en) | 1988-10-20 |
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