EP0286139A1 - Lubrifiant ou concentré de lubrifiant - Google Patents
Lubrifiant ou concentré de lubrifiant Download PDFInfo
- Publication number
- EP0286139A1 EP0286139A1 EP88105725A EP88105725A EP0286139A1 EP 0286139 A1 EP0286139 A1 EP 0286139A1 EP 88105725 A EP88105725 A EP 88105725A EP 88105725 A EP88105725 A EP 88105725A EP 0286139 A1 EP0286139 A1 EP 0286139A1
- Authority
- EP
- European Patent Office
- Prior art keywords
- lubricant
- concentrate according
- mpa
- component
- weight
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000000314 lubricant Substances 0.000 title claims abstract description 114
- 239000012141 concentrate Substances 0.000 title claims abstract description 52
- 239000003921 oil Substances 0.000 claims abstract description 32
- 125000004432 carbon atom Chemical group C* 0.000 claims abstract description 18
- 229910052500 inorganic mineral Inorganic materials 0.000 claims abstract description 13
- 239000011707 mineral Substances 0.000 claims abstract description 13
- 239000000654 additive Substances 0.000 claims abstract description 10
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 claims abstract description 9
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 claims abstract description 9
- 229910052698 phosphorus Inorganic materials 0.000 claims abstract description 9
- 239000011574 phosphorus Substances 0.000 claims abstract description 9
- 229910052799 carbon Inorganic materials 0.000 claims abstract description 8
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims abstract description 6
- 150000002902 organometallic compounds Chemical class 0.000 claims abstract description 6
- 229910052751 metal Inorganic materials 0.000 claims description 40
- 239000002184 metal Substances 0.000 claims description 40
- -1 aliphatic dicarboxylic acid ester Chemical class 0.000 claims description 24
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 claims description 22
- WXZMFSXDPGVJKK-UHFFFAOYSA-N pentaerythritol Chemical compound OCC(CO)(CO)CO WXZMFSXDPGVJKK-UHFFFAOYSA-N 0.000 claims description 22
- 150000002148 esters Chemical class 0.000 claims description 20
- ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 claims description 17
- 229910052750 molybdenum Inorganic materials 0.000 claims description 17
- 239000011733 molybdenum Substances 0.000 claims description 17
- 239000002253 acid Substances 0.000 claims description 13
- 229910052725 zinc Inorganic materials 0.000 claims description 13
- 239000011701 zinc Substances 0.000 claims description 13
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 claims description 11
- 229910052759 nickel Inorganic materials 0.000 claims description 11
- WFKWXMTUELFFGS-UHFFFAOYSA-N tungsten Chemical compound [W] WFKWXMTUELFFGS-UHFFFAOYSA-N 0.000 claims description 11
- 229910052721 tungsten Inorganic materials 0.000 claims description 11
- 239000010937 tungsten Substances 0.000 claims description 11
- 125000000217 alkyl group Chemical group 0.000 claims description 10
- 229920002367 Polyisobutene Polymers 0.000 claims description 9
- NFHFRUOZVGFOOS-UHFFFAOYSA-N palladium;triphenylphosphane Chemical compound [Pd].C1=CC=CC=C1P(C=1C=CC=CC=1)C1=CC=CC=C1.C1=CC=CC=C1P(C=1C=CC=CC=1)C1=CC=CC=C1.C1=CC=CC=C1P(C=1C=CC=CC=1)C1=CC=CC=C1.C1=CC=CC=C1P(C=1C=CC=CC=1)C1=CC=CC=C1 NFHFRUOZVGFOOS-UHFFFAOYSA-N 0.000 claims description 9
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 claims description 8
- 125000003118 aryl group Chemical group 0.000 claims description 8
- 239000002480 mineral oil Substances 0.000 claims description 8
- 229910052717 sulfur Inorganic materials 0.000 claims description 8
- 239000011593 sulfur Substances 0.000 claims description 8
- 229910052719 titanium Inorganic materials 0.000 claims description 8
- 239000010936 titanium Substances 0.000 claims description 8
- ZOXJGFHDIHLPTG-UHFFFAOYSA-N Boron Chemical compound [B] ZOXJGFHDIHLPTG-UHFFFAOYSA-N 0.000 claims description 7
- 229910052796 boron Inorganic materials 0.000 claims description 7
- 229910052720 vanadium Inorganic materials 0.000 claims description 7
- LEONUFNNVUYDNQ-UHFFFAOYSA-N vanadium atom Chemical compound [V] LEONUFNNVUYDNQ-UHFFFAOYSA-N 0.000 claims description 7
- 235000010446 mineral oil Nutrition 0.000 claims description 6
- 229910017052 cobalt Inorganic materials 0.000 claims description 5
- 239000010941 cobalt Substances 0.000 claims description 5
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 claims description 5
- 125000002887 hydroxy group Chemical group [H]O* 0.000 claims description 5
- PTJWCLYPVFJWMP-UHFFFAOYSA-N 2-[[3-hydroxy-2-[[3-hydroxy-2,2-bis(hydroxymethyl)propoxy]methyl]-2-(hydroxymethyl)propoxy]methyl]-2-(hydroxymethyl)propane-1,3-diol Chemical compound OCC(CO)(CO)COCC(CO)(CO)COCC(CO)(CO)CO PTJWCLYPVFJWMP-UHFFFAOYSA-N 0.000 claims description 4
- 125000003710 aryl alkyl group Chemical group 0.000 claims description 4
- 150000002739 metals Chemical class 0.000 claims description 4
- OJMIONKXNSYLSR-UHFFFAOYSA-N phosphorous acid Chemical compound OP(O)O OJMIONKXNSYLSR-UHFFFAOYSA-N 0.000 claims description 4
- PWHULOQIROXLJO-UHFFFAOYSA-N Manganese Chemical compound [Mn] PWHULOQIROXLJO-UHFFFAOYSA-N 0.000 claims description 3
- 239000003963 antioxidant agent Substances 0.000 claims description 3
- 239000002199 base oil Substances 0.000 claims description 3
- 239000003599 detergent Substances 0.000 claims description 3
- 229910052748 manganese Inorganic materials 0.000 claims description 3
- 239000011572 manganese Substances 0.000 claims description 3
- 150000002903 organophosphorus compounds Chemical class 0.000 claims description 3
- 229920000151 polyglycol Polymers 0.000 claims description 3
- 239000010695 polyglycol Substances 0.000 claims description 3
- 229920000193 polymethacrylate Polymers 0.000 claims description 3
- FZWLAAWBMGSTSO-UHFFFAOYSA-N Thiazole Chemical compound C1=CSC=N1 FZWLAAWBMGSTSO-UHFFFAOYSA-N 0.000 claims description 2
- WNLRTRBMVRJNCN-UHFFFAOYSA-L adipate(2-) Chemical compound [O-]C(=O)CCCCC([O-])=O WNLRTRBMVRJNCN-UHFFFAOYSA-L 0.000 claims description 2
- 230000001476 alcoholic effect Effects 0.000 claims description 2
- 150000004996 alkyl benzenes Chemical class 0.000 claims description 2
- NMAKPIATXQEXBT-UHFFFAOYSA-N didecyl phenyl phosphite Chemical compound CCCCCCCCCCOP(OCCCCCCCCCC)OC1=CC=CC=C1 NMAKPIATXQEXBT-UHFFFAOYSA-N 0.000 claims description 2
- 239000002270 dispersing agent Substances 0.000 claims description 2
- 239000006078 metal deactivator Substances 0.000 claims description 2
- SLCVBVWXLSEKPL-UHFFFAOYSA-N neopentyl glycol Chemical compound OCC(C)(C)CO SLCVBVWXLSEKPL-UHFFFAOYSA-N 0.000 claims description 2
- DCKVNWZUADLDEH-UHFFFAOYSA-N sec-butyl acetate Chemical compound CCC(C)OC(C)=O DCKVNWZUADLDEH-UHFFFAOYSA-N 0.000 claims description 2
- 235000019198 oils Nutrition 0.000 claims 7
- FCGAIWGWXFLBOH-UHFFFAOYSA-K N,N-bis(2-methylpropyl)carbamodithioate nickel(3+) Chemical compound [Ni+3].CC(C)CN(CC(C)C)C([S-])=S.CC(C)CN(CC(C)C)C([S-])=S.CC(C)CN(CC(C)C)C([S-])=S FCGAIWGWXFLBOH-UHFFFAOYSA-K 0.000 claims 1
- 235000019484 Rapeseed oil Nutrition 0.000 claims 1
- GPEHVEMECCJPPP-UHFFFAOYSA-K [B+3].CC(C)CN(CC(C)C)C([S-])=S.CC(C)CN(CC(C)C)C([S-])=S.CC(C)CN(CC(C)C)C([S-])=S Chemical compound [B+3].CC(C)CN(CC(C)C)C([S-])=S.CC(C)CN(CC(C)C)C([S-])=S.CC(C)CN(CC(C)C)C([S-])=S GPEHVEMECCJPPP-UHFFFAOYSA-K 0.000 claims 1
- 239000002518 antifoaming agent Substances 0.000 claims 1
- 125000004122 cyclic group Chemical group 0.000 claims 1
- UHKDZFIPIJSOTR-UHFFFAOYSA-N didodecyl phenyl phosphite Chemical compound CCCCCCCCCCCCOP(OCCCCCCCCCCCC)OC1=CC=CC=C1 UHKDZFIPIJSOTR-UHFFFAOYSA-N 0.000 claims 1
- 125000005442 diisocyanate group Chemical group 0.000 claims 1
- 229940117969 neopentyl glycol Drugs 0.000 claims 1
- XNGIFLGASWRNHJ-UHFFFAOYSA-L phthalate(2-) Chemical compound [O-]C(=O)C1=CC=CC=C1C([O-])=O XNGIFLGASWRNHJ-UHFFFAOYSA-L 0.000 claims 1
- 229940116351 sebacate Drugs 0.000 claims 1
- CXMXRPHRNRROMY-UHFFFAOYSA-L sebacate(2-) Chemical compound [O-]C(=O)CCCCCCCCC([O-])=O CXMXRPHRNRROMY-UHFFFAOYSA-L 0.000 claims 1
- 230000001050 lubricating effect Effects 0.000 abstract description 7
- 238000005260 corrosion Methods 0.000 abstract description 4
- 239000005864 Sulphur Substances 0.000 abstract 1
- 229940059574 pentaerithrityl Drugs 0.000 description 23
- 239000010687 lubricating oil Substances 0.000 description 22
- 239000000047 product Substances 0.000 description 19
- 238000005461 lubrication Methods 0.000 description 15
- 150000001875 compounds Chemical class 0.000 description 13
- 238000010586 diagram Methods 0.000 description 12
- 238000005259 measurement Methods 0.000 description 9
- 235000010755 mineral Nutrition 0.000 description 9
- 239000000203 mixture Substances 0.000 description 8
- 150000003839 salts Chemical class 0.000 description 7
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 description 6
- 150000001721 carbon Chemical group 0.000 description 6
- 229910052804 chromium Inorganic materials 0.000 description 6
- 239000011651 chromium Substances 0.000 description 6
- 239000000126 substance Substances 0.000 description 6
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 description 5
- 238000005299 abrasion Methods 0.000 description 5
- 239000004519 grease Substances 0.000 description 5
- 230000003647 oxidation Effects 0.000 description 5
- 238000007254 oxidation reaction Methods 0.000 description 5
- 229910052718 tin Inorganic materials 0.000 description 5
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 4
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical group [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 description 4
- 239000007983 Tris buffer Substances 0.000 description 4
- 230000000052 comparative effect Effects 0.000 description 4
- 229910052802 copper Inorganic materials 0.000 description 4
- 239000010949 copper Substances 0.000 description 4
- RGMHCYNAXLBTPP-UHFFFAOYSA-N didecyl 2,2,3-trimethylhexanedioate Chemical compound CCCCCCCCCCOC(=O)CCC(C)C(C)(C)C(=O)OCCCCCCCCCC RGMHCYNAXLBTPP-UHFFFAOYSA-N 0.000 description 4
- 230000007774 longterm Effects 0.000 description 4
- 239000000463 material Substances 0.000 description 4
- 229910052709 silver Inorganic materials 0.000 description 4
- 239000004332 silver Substances 0.000 description 4
- 239000004711 α-olefin Substances 0.000 description 4
- QCWXUUIWCKQGHC-UHFFFAOYSA-N Zirconium Chemical compound [Zr] QCWXUUIWCKQGHC-UHFFFAOYSA-N 0.000 description 3
- 230000000996 additive effect Effects 0.000 description 3
- 239000000853 adhesive Substances 0.000 description 3
- 230000001070 adhesive effect Effects 0.000 description 3
- 229910052787 antimony Inorganic materials 0.000 description 3
- WATWJIUSRGPENY-UHFFFAOYSA-N antimony atom Chemical compound [Sb] WATWJIUSRGPENY-UHFFFAOYSA-N 0.000 description 3
- 229910052793 cadmium Inorganic materials 0.000 description 3
- BDOSMKKIYDKNTQ-UHFFFAOYSA-N cadmium atom Chemical compound [Cd] BDOSMKKIYDKNTQ-UHFFFAOYSA-N 0.000 description 3
- 238000006243 chemical reaction Methods 0.000 description 3
- 239000007795 chemical reaction product Substances 0.000 description 3
- 230000007797 corrosion Effects 0.000 description 3
- 238000000034 method Methods 0.000 description 3
- 239000007787 solid Substances 0.000 description 3
- 229910052715 tantalum Inorganic materials 0.000 description 3
- GUVRBAGPIYLISA-UHFFFAOYSA-N tantalum atom Chemical compound [Ta] GUVRBAGPIYLISA-UHFFFAOYSA-N 0.000 description 3
- 229910052726 zirconium Inorganic materials 0.000 description 3
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 2
- SNRUBQQJIBEYMU-UHFFFAOYSA-N Dodecane Natural products CCCCCCCCCCCC SNRUBQQJIBEYMU-UHFFFAOYSA-N 0.000 description 2
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 description 2
- VKCLPVFDVVKEKU-UHFFFAOYSA-N S=[P] Chemical class S=[P] VKCLPVFDVVKEKU-UHFFFAOYSA-N 0.000 description 2
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 2
- IBKKMFMBXQARGV-UHFFFAOYSA-N [3-nonanoyloxy-2,2-bis(nonanoyloxymethyl)propyl] nonanoate Chemical compound CCCCCCCCC(=O)OCC(COC(=O)CCCCCCCC)(COC(=O)CCCCCCCC)COC(=O)CCCCCCCC IBKKMFMBXQARGV-UHFFFAOYSA-N 0.000 description 2
- 229910052784 alkaline earth metal Inorganic materials 0.000 description 2
- 229920001577 copolymer Polymers 0.000 description 2
- 235000014113 dietary fatty acids Nutrition 0.000 description 2
- 230000005496 eutectics Effects 0.000 description 2
- 239000000194 fatty acid Substances 0.000 description 2
- 229930195729 fatty acid Natural products 0.000 description 2
- 239000010439 graphite Substances 0.000 description 2
- 229910002804 graphite Inorganic materials 0.000 description 2
- 125000000959 isobutyl group Chemical group [H]C([H])([H])C([H])(C([H])([H])[H])C([H])([H])* 0.000 description 2
- 239000011133 lead Substances 0.000 description 2
- 239000003879 lubricant additive Substances 0.000 description 2
- WPBNNNQJVZRUHP-UHFFFAOYSA-L manganese(2+);methyl n-[[2-(methoxycarbonylcarbamothioylamino)phenyl]carbamothioyl]carbamate;n-[2-(sulfidocarbothioylamino)ethyl]carbamodithioate Chemical compound [Mn+2].[S-]C(=S)NCCNC([S-])=S.COC(=O)NC(=S)NC1=CC=CC=C1NC(=S)NC(=O)OC WPBNNNQJVZRUHP-UHFFFAOYSA-L 0.000 description 2
- CWQXQMHSOZUFJS-UHFFFAOYSA-N molybdenum disulfide Chemical compound S=[Mo]=S CWQXQMHSOZUFJS-UHFFFAOYSA-N 0.000 description 2
- 229910052982 molybdenum disulfide Inorganic materials 0.000 description 2
- CBFCDTFDPHXCNY-UHFFFAOYSA-N octyldodecane Natural products CCCCCCCCCCCCCCCCCCCC CBFCDTFDPHXCNY-UHFFFAOYSA-N 0.000 description 2
- CYQAYERJWZKYML-UHFFFAOYSA-N phosphorus pentasulfide Chemical compound S1P(S2)(=S)SP3(=S)SP1(=S)SP2(=S)S3 CYQAYERJWZKYML-UHFFFAOYSA-N 0.000 description 2
- 229920005862 polyol Polymers 0.000 description 2
- 229910001220 stainless steel Inorganic materials 0.000 description 2
- 239000010935 stainless steel Substances 0.000 description 2
- HVLLSGMXQDNUAL-UHFFFAOYSA-N triphenyl phosphite Chemical compound C=1C=CC=CC=1OP(OC=1C=CC=CC=1)OC1=CC=CC=C1 HVLLSGMXQDNUAL-UHFFFAOYSA-N 0.000 description 2
- JIAARYAFYJHUJI-UHFFFAOYSA-L zinc dichloride Chemical compound [Cl-].[Cl-].[Zn+2] JIAARYAFYJHUJI-UHFFFAOYSA-L 0.000 description 2
- FFMKLGYETFERPE-UHFFFAOYSA-N (3,4-didecyl-2-methylphenyl) dihydrogen phosphite Chemical compound CCCCCCCCCCC1=C(C(=C(C=C1)OP(O)O)C)CCCCCCCCCC FFMKLGYETFERPE-UHFFFAOYSA-N 0.000 description 1
- GBURUDXSBYGPBL-UHFFFAOYSA-N 2,2,3-trimethylhexanedioic acid Chemical compound OC(=O)C(C)(C)C(C)CCC(O)=O GBURUDXSBYGPBL-UHFFFAOYSA-N 0.000 description 1
- TXBCBTDQIULDIA-UHFFFAOYSA-N 2-[[3-hydroxy-2,2-bis(hydroxymethyl)propoxy]methyl]-2-(hydroxymethyl)propane-1,3-diol Chemical compound OCC(CO)(CO)COCC(CO)(CO)CO TXBCBTDQIULDIA-UHFFFAOYSA-N 0.000 description 1
- GBRSPKXOFRTAHS-UHFFFAOYSA-N 5-(4-nitrophenyl)-1,2-oxazole-3-carboxylic acid Chemical compound O1N=C(C(=O)O)C=C1C1=CC=C([N+]([O-])=O)C=C1 GBRSPKXOFRTAHS-UHFFFAOYSA-N 0.000 description 1
- 241000251468 Actinopterygii Species 0.000 description 1
- 241000894006 Bacteria Species 0.000 description 1
- 235000016068 Berberis vulgaris Nutrition 0.000 description 1
- 241000335053 Beta vulgaris Species 0.000 description 1
- OWIKALOENCRAKO-UHFFFAOYSA-N CCCCCCCCCCCCC1=CC=CC(P(O)(O)O)=C1CCCCCCCCCCCC Chemical compound CCCCCCCCCCCCC1=CC=CC(P(O)(O)O)=C1CCCCCCCCCCCC OWIKALOENCRAKO-UHFFFAOYSA-N 0.000 description 1
- 241000283153 Cetacea Species 0.000 description 1
- ZVFDTKUVRCTHQE-UHFFFAOYSA-N Diisodecyl phthalate Chemical compound CC(C)CCCCCCCOC(=O)C1=CC=CC=C1C(=O)OCCCCCCCC(C)C ZVFDTKUVRCTHQE-UHFFFAOYSA-N 0.000 description 1
- 102220470005 Parvalbumin-like EF-hand-containing protein_N36A_mutation Human genes 0.000 description 1
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 description 1
- KDYFGRWQOYBRFD-UHFFFAOYSA-N Succinic acid Natural products OC(=O)CCC(O)=O KDYFGRWQOYBRFD-UHFFFAOYSA-N 0.000 description 1
- 239000004809 Teflon Substances 0.000 description 1
- 229920006362 Teflon® Polymers 0.000 description 1
- XCYKXNWUFTZFJC-UHFFFAOYSA-A [V+5].[V+5].[V+5].[O-]P([O-])([S-])=S.[O-]P([O-])([S-])=S.[O-]P([O-])([S-])=S.[O-]P([O-])([S-])=S.[O-]P([O-])([S-])=S Chemical compound [V+5].[V+5].[V+5].[O-]P([O-])([S-])=S.[O-]P([O-])([S-])=S.[O-]P([O-])([S-])=S.[O-]P([O-])([S-])=S.[O-]P([O-])([S-])=S XCYKXNWUFTZFJC-UHFFFAOYSA-A 0.000 description 1
- 150000007513 acids Chemical class 0.000 description 1
- 150000001298 alcohols Chemical class 0.000 description 1
- 150000001338 aliphatic hydrocarbons Chemical class 0.000 description 1
- 150000001336 alkenes Chemical class 0.000 description 1
- 229910000147 aluminium phosphate Inorganic materials 0.000 description 1
- 125000000129 anionic group Chemical group 0.000 description 1
- 230000003078 antioxidant effect Effects 0.000 description 1
- 229910052788 barium Inorganic materials 0.000 description 1
- DSAJWYNOEDNPEQ-UHFFFAOYSA-N barium atom Chemical compound [Ba] DSAJWYNOEDNPEQ-UHFFFAOYSA-N 0.000 description 1
- RQPZNWPYLFFXCP-UHFFFAOYSA-L barium dihydroxide Chemical compound [OH-].[OH-].[Ba+2] RQPZNWPYLFFXCP-UHFFFAOYSA-L 0.000 description 1
- 229910001863 barium hydroxide Inorganic materials 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- SXXILWLQSQDLDL-UHFFFAOYSA-N bis(8-methylnonyl) phenyl phosphite Chemical compound CC(C)CCCCCCCOP(OCCCCCCCC(C)C)OC1=CC=CC=C1 SXXILWLQSQDLDL-UHFFFAOYSA-N 0.000 description 1
- KDYFGRWQOYBRFD-NUQCWPJISA-N butanedioic acid Chemical class O[14C](=O)CC[14C](O)=O KDYFGRWQOYBRFD-NUQCWPJISA-N 0.000 description 1
- 150000004657 carbamic acid derivatives Chemical class 0.000 description 1
- 239000000969 carrier Substances 0.000 description 1
- 150000001768 cations Chemical class 0.000 description 1
- 150000008280 chlorinated hydrocarbons Chemical class 0.000 description 1
- 239000013065 commercial product Substances 0.000 description 1
- 239000013078 crystal Substances 0.000 description 1
- 239000010730 cutting oil Substances 0.000 description 1
- 125000006165 cyclic alkyl group Chemical group 0.000 description 1
- 239000010727 cylinder oil Substances 0.000 description 1
- GLOQRSIADGSLRX-UHFFFAOYSA-N decyl diphenyl phosphite Chemical compound C=1C=CC=CC=1OP(OCCCCCCCCCC)OC1=CC=CC=C1 GLOQRSIADGSLRX-UHFFFAOYSA-N 0.000 description 1
- 230000001236 detergent effect Effects 0.000 description 1
- UCTMWXXYJNOJIU-UHFFFAOYSA-N didecyl (4-methylphenyl) phosphite Chemical compound CCCCCCCCCCOP(OCCCCCCCCCC)OC1=CC=C(C)C=C1 UCTMWXXYJNOJIU-UHFFFAOYSA-N 0.000 description 1
- HAHARTSOYLFEBH-UHFFFAOYSA-N dihexyl phenyl phosphite Chemical compound CCCCCCOP(OCCCCCC)OC1=CC=CC=C1 HAHARTSOYLFEBH-UHFFFAOYSA-N 0.000 description 1
- MKZVQIIAAIPNGH-UHFFFAOYSA-N dioctyl phenyl phosphite Chemical compound CCCCCCCCOP(OCCCCCCCC)OC1=CC=CC=C1 MKZVQIIAAIPNGH-UHFFFAOYSA-N 0.000 description 1
- 238000009826 distribution Methods 0.000 description 1
- 239000012990 dithiocarbamate Substances 0.000 description 1
- 150000004659 dithiocarbamates Chemical class 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 125000004185 ester group Chemical group 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 150000004665 fatty acids Chemical class 0.000 description 1
- HOXINJBQVZWYGZ-UHFFFAOYSA-N fenbutatin oxide Chemical compound C=1C=CC=CC=1C(C)(C)C[Sn](O[Sn](CC(C)(C)C=1C=CC=CC=1)(CC(C)(C)C=1C=CC=CC=1)CC(C)(C)C=1C=CC=CC=1)(CC(C)(C)C=1C=CC=CC=1)CC(C)(C)C1=CC=CC=C1 HOXINJBQVZWYGZ-UHFFFAOYSA-N 0.000 description 1
- 239000012208 gear oil Substances 0.000 description 1
- 229930195733 hydrocarbon Natural products 0.000 description 1
- 238000011065 in-situ storage Methods 0.000 description 1
- 239000003112 inhibitor Substances 0.000 description 1
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 description 1
- 229910052746 lanthanum Inorganic materials 0.000 description 1
- FZLIPJUXYLNCLC-UHFFFAOYSA-N lanthanum atom Chemical compound [La] FZLIPJUXYLNCLC-UHFFFAOYSA-N 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- HGPXWXLYXNVULB-UHFFFAOYSA-M lithium stearate Chemical compound [Li+].CCCCCCCCCCCCCCCCCC([O-])=O HGPXWXLYXNVULB-UHFFFAOYSA-M 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 239000000155 melt Substances 0.000 description 1
- 239000005300 metallic glass Substances 0.000 description 1
- 229910052961 molybdenite Inorganic materials 0.000 description 1
- CXMXRPHRNRROMY-UHFFFAOYSA-N n-Decanedioic acid Natural products OC(=O)CCCCCCCCC(O)=O CXMXRPHRNRROMY-UHFFFAOYSA-N 0.000 description 1
- 125000004108 n-butyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
- 229910052758 niobium Inorganic materials 0.000 description 1
- 239000010955 niobium Substances 0.000 description 1
- GUCVJGMIXFAOAE-UHFFFAOYSA-N niobium atom Chemical compound [Nb] GUCVJGMIXFAOAE-UHFFFAOYSA-N 0.000 description 1
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 description 1
- 230000010355 oscillation Effects 0.000 description 1
- 230000002093 peripheral effect Effects 0.000 description 1
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 1
- 150000008301 phosphite esters Chemical class 0.000 description 1
- 229920013639 polyalphaolefin Polymers 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 238000003825 pressing Methods 0.000 description 1
- 238000005096 rolling process Methods 0.000 description 1
- 238000010008 shearing Methods 0.000 description 1
- APSBXTVYXVQYAB-UHFFFAOYSA-M sodium docusate Chemical group [Na+].CCCCC(CC)COC(=O)CC(S([O-])(=O)=O)C(=O)OCC(CC)CCCC APSBXTVYXVQYAB-UHFFFAOYSA-M 0.000 description 1
- 239000002689 soil Substances 0.000 description 1
- 150000005846 sugar alcohols Polymers 0.000 description 1
- 150000004763 sulfides Chemical class 0.000 description 1
- 239000000725 suspension Substances 0.000 description 1
- 239000003784 tall oil Substances 0.000 description 1
- 235000007586 terpenes Nutrition 0.000 description 1
- 125000000999 tert-butyl group Chemical group [H]C([H])([H])C(*)(C([H])([H])[H])C([H])([H])[H] 0.000 description 1
- WYURNTSHIVDZCO-UHFFFAOYSA-N tetrahydrofuran Substances C1CCOC1 WYURNTSHIVDZCO-UHFFFAOYSA-N 0.000 description 1
- 150000007979 thiazole derivatives Chemical class 0.000 description 1
- 150000003558 thiocarbamic acid derivatives Chemical class 0.000 description 1
- 239000011135 tin Substances 0.000 description 1
- 125000002889 tridecyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- WMYJOZQKDZZHAC-UHFFFAOYSA-H trizinc;dioxido-sulfanylidene-sulfido-$l^{5}-phosphane Chemical compound [Zn+2].[Zn+2].[Zn+2].[O-]P([O-])([S-])=S.[O-]P([O-])([S-])=S WMYJOZQKDZZHAC-UHFFFAOYSA-H 0.000 description 1
- 239000003981 vehicle Substances 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
- 210000002268 wool Anatomy 0.000 description 1
- 239000011592 zinc chloride Substances 0.000 description 1
- 235000005074 zinc chloride Nutrition 0.000 description 1
- UXDZLUCNRYCZCG-UHFFFAOYSA-L zinc;phthalate Chemical compound [Zn+2].[O-]C(=O)C1=CC=CC=C1C([O-])=O UXDZLUCNRYCZCG-UHFFFAOYSA-L 0.000 description 1
Classifications
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- C10M101/00—Lubricating compositions characterised by the base-material being a mineral or fatty oil
- C10M101/02—Petroleum fractions
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- C10M101/00—Lubricating compositions characterised by the base-material being a mineral or fatty oil
- C10M101/04—Fatty oil fractions
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- C10M105/02—Well-defined hydrocarbons
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- C10M135/18—Thio-acids; Thiocyanates; Derivatives thereof having a carbon-to-sulfur double bond thiocarbamic type, e.g. containing the groups
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Definitions
- the invention relates to a new lubricant or lubricant concentrate based on mineral oil and / or synthetic oil with improved lubricating properties, in particular improved load-bearing, sliding and corrosion protection properties.
- solid lubricants were developed which were introduced between the moving metal parts, such as graphite, MoS2, TiO2, Ca3 (PO4) 2, Teflon and the like, which were introduced as lubricious outer layers, suspensions, pastes or greases. Thereby the friction partners were better separated and their resilience increased. With centripetal movements of higher peripheral speeds and at higher temperatures, however, the solid lubricants and carrier media separate sooner or later due to their different specific densities. This limited the long-term lubrication. In a further step, it was possible to apply suitable metal cations to rubbing surfaces during operation from chemical complexes dissolved in a lubricant.
- lubricating oils containing soluble reaction products of phosphorus pentasulfide with liquid or solid aliphatic hydrocarbons or terpene hydrocarbons are known.
- DE-PS 923 984 a lubricating oil is known which contains metal-containing alkylphenol sulfide esters in combination with zinc sulfonates.
- DE-AS 1 444 892 a lubricating oil is known which contains a salt of an aromatic zinc dithiophosphate and a zinc carboxylic acid salt in the presence of water. While the first two products are lubricating oil detergents, the latter product is intended to prevent corrosion of silver bearing surfaces.
- a lubricating oil which contains a salt of a substituted succinic acid, optionally together with a salt of an alkylated or esterified phosphoric acid. It is an antioxidant with a detergent effect.
- a combination of dithiophosphate and dithiophosphinate salts is known from DE-AS 1 271 878.
- From DE-OS 15 94 555 cutting oils containing free sulfur, a dialkyl dithiophosphate and a chlorinated hydrocarbon are known.
- Lubricating oils containing zinc or antimondithiocarbamate are known from US Pat. No. 3,462,367. Lubricating oils are known from US Pat. No.
- Lubricating oil additives are also known from US Pat. No. 2,734,864, which are formed from a dithiophosphate of the alkaline earth metal salts in combination with a complex reaction product of phosphorus sulfides, wool fat and alcohol esters.
- the undefined product contains considerable amounts of barium and zinc.
- Such a lubricating oil additive cannot be used in practice because of its unbearable smell, which also endangers the people who come into contact with it.
- lubricants based on mineral oil or synthetic oil which, in addition to the mineral or synthetic oil, contain an ester of an epoxidized fatty acid having 10 to 18 carbon atoms with mono- or polyhydric alcohols, an alkyl -, Aralkyl- or aryldithiophosphate of zinc, lead, tin, tungsten, molybdenum, niobium or lanthanum and optionally contain a sulfur phosphorus compound.
- lubricants based on mineral or synthetic oil or lubricant concentrates which in addition to a lead, tungsten, molybdenum and / or vanadium dithiophosphate esterified with alkyl, aryl or aralkyl groups, also contain at least one zinc dialkyldithiophosphate and a metal-free sulfur-phosphorus compound.
- These last-mentioned lubricants which have found widespread use, no longer meet all the requirements of modern long-term and high-performance lubricants. Their coefficient of friction and abrasion are too high, their shelf life is inadequate in long-term use, and the complaint rate in the lubrication technology area is too high.
- the object of the invention was therefore to create a new lubricant or lubricant concentrate based on mineral or synthetic oil, which is further improved with regard to its lubricating properties, in particular its friction and wear properties, thus noticeably reducing the need for energy and spare parts and thus also meets the highest requirements.
- a mineral and / or synthetic oil contains at least one 4- to 8-valent alcohol with at least one quaternary carbon atom and at least one ester bond in the molecule with a density d20 of at least 0.900 and an enthalpy H of at least 350 kcal / kg, at least one asymmetric organometallic compound, at least one phosphorus carrier and at least one sulfur carrier are added.
- the lubricants or lubricant concentrates according to the invention have significantly improved properties compared to the known lubricants or lubricant concentrates, in particular with regard to friction and wear, and thus have a reduced need for energy and spare parts. It is believed that this is due to the fact that when they are used in the rubbing and sliding area, metallic glass surfaces are formed from amorphously solidified metal melts, which no longer have metal crystal lattice structures.
- the glass-like smooth friction and sliding surfaces which are presumably produced with the lubricant or lubricant concentrate according to the invention, significantly improve the entire lubrication process, since the coefficient of friction and with it the abrasion, oxidation and corrosion are significantly reduced.
- the so-called fretting rust is also prevented by the lubricant or lubricant concentrate according to the invention.
- the lubricants or lubricant concentrates according to the invention are extremely environmentally friendly since they contain no lead, no sulfurized whale sperm oil and hardly any phosphorus. This has been shown by fish tests and bacteria washing tests, which were carried out with the lubricants or lubricant concentrates according to the invention. It was also found that they are 60% biodegradable in normal soil within 3 to 4 months, so that they can also be described as extremely environmentally friendly.
- the quaternary carbon atom-containing polyol ester compounds used according to the invention are thermally very stable and therefore allow high operating temperatures of up to 300 ° C. They therefore open up the possibility of lifetime lubrication of highly loaded motors, turbines, rolling bearings, constant velocity joints and other high-performance machine elements.
- lubricant or lubricant concentrate based on mineral and / or synthetic oil used here means both lubricating oils and lubricating greases based on mineral and / or synthetic oil.
- Compounds containing quaternary carbon atoms are to be understood here as those compounds in which the four main valences of at least one carbon atom per molecule are occupied by four carbon atoms.
- Examples of such compounds are mono-, di- and trimeric pentaerythritol esters, other polyol esters, pentaerythritol ethoxy esters and telomeric acid pentaerythritol esters and the corresponding ethoxylated esters.
- the lubricants or lubricant concentrates according to the invention have significantly improved properties compared to the known lubricants or lubricant concentrates, as the examples below show.
- the glass-like smooth friction and sliding surfaces produced by the lubricant according to the invention save drive energy and lower the coefficient of friction per se and by building up a very adhesive boundary lubrication film which enables elastohydrodynamic lubrication even under point loads.
- the friction temperature of the lubricant and lubrication point is reduced, the oxidation resistance of both is extended and the metallic friction partners are subjected to less specific alternating loads and temperatures. Overall, these effects greatly reduce wear and significantly increase the service life of the friction partners and the lubricant.
- the lubricant or lubricant concentrate contains, as component (b), mono-, di- or tripentaerythritol, the alcoholic hydroxyl group (s) of which is preferably an unbranched or branched alkyl, aralkyl or aryl group having 6 to 18 carbon atoms 6 to 12 carbon atoms, in particular 8 to 12 carbon atoms, is (are) esterified or ethoxy-esterified.
- component (b) mono-, di- or tripentaerythritol
- component (b) contains as component (b) a mono-, di-, tri- or tetraester of pentaerythritol.
- the lubricant or lubricant concentrate additionally contains a component with at least one free hydroxyl group.
- the lubricant or lubricant concentrate according to the invention contains component (b) in an amount of 0.1 to 40% by weight, preferably 0.1 to 20% by weight, in particular 1 to 12 % By weight, especially from 2 to 6% by weight, based on the weight of the mineral and / or synthetic oil.
- the lubricant or lubricant concentrate according to the invention contains as component (b) an ester and / or ethoxylated ester derivative of mono-, di- or tripentaerythritol and / or a telomeric acid pentaerythritol ester or an ethoxylated derivative thereof.
- the lubricant or lubricant concentrate according to the invention preferably contains beet oil, natural oil and / or a synthetic oil with a viscosity in the range from 1.0 mPa.s at 20 ° C to 2.106 mPa.s at 20 ° C.
- a mineral oil with a visco is particularly preferred Sity of 1.0 mPa.s at 20 ° C to 540 mPa.s at 50 ° C as a natural oil and the use of an aromatic or aliphatic dicarboxylic acid ester, especially poly- ⁇ -olefin dicarboxylic acid ester, especially butyl ester, with a molecular weight in the range from 1000 to 3000, preferably from phthalic acid diisodecyl ester, trimethyladipic acid diidyl ester and sebacic acid diocyl ester, a polyisobutylene with a molecular weight of 1000 to 100,000 and a viscosity of 200 to 43,000 mPa.s at 100 ° C, a polymethacrylate with a viscosity of 1000 mPa.s 100 ° C, a non-water-soluble polyglycol with a viscosity of 5 to 60 mPa.s at 100
- lubricant according to the invention and lubricant concentrate preferably contains a sulfur carrier, particularly a thiazole, at least one metal dialkyldithiocarbamate and / or a metal dialkyldithiophosphate and / or a phosphorus carrier, in particular an organo phosphite, preferably a Dialkylarylphosphit, particularly didecyl or Didodecylphenylphosphit, and / or a metal dialkyldithiophosphate .
- a sulfur carrier particularly a thiazole
- at least one metal dialkyldithiocarbamate and / or a metal dialkyldithiophosphate and / or a phosphorus carrier in particular an organo phosphite, preferably a Dialkylarylphosphit, particularly didecyl or Didodecylphenylphosphit, and / or a metal dialkyldithiophosphate
- the sulfur carrier is preferably contained in the lubricant or lubricant concentrate in an amount of 0.5 to 10% by weight, in particular 1 to 3% by weight, while it is preferably in an amount of 0.1 to 10% in the phosphorus carrier % By weight, in particular from 0.1 to 5% by weight, especially from 0.5 to 2% by weight.
- the lubricant or lubricant concentrate according to the invention can contain conventional antioxidants, metal deactivators, detergents, dispersants, antifoams and / or viscosity index improvers as further conventional additives.
- polyolester compounds with at least one quaternary carbon atom in the molecule which are preferably used according to the invention include the following compounds:
- the underlying mono- and dipentaerythritol has the structure: in which the hydroxyl groups are partially or fully esterified, the ester groups of which are preferably straight or branched alkyl, aralkyl or aryl groups having 6 to 18, preferably 8 to 12, carbon atoms.
- pentaerythritol ester examples include pentaerythritol monohexyl, pentaerythritol monooctyl, pentaerythritol monononylester, pentaerythritol monodecylester, pentaerythritol monododecylester, pentaerythritol monomyristylester, pentaerythritol monohexadecylester, Pentaerythritmonostearylester, pentaerythritol monooleylester, pentaerythritol monoisostearyl- and -isopalmitinklarester; the corresponding dihexyl, dioctyl, dinonyl, didecyl, didodecyl, dimyristyl, dihexadecyl, distearyl, dioleyl, diisostearyl
- T telomer
- R T or alkyl
- telomeric acids are compounds with relatively high molecular weights and long-chain star-like structures which can be esterified in the usual way and whose esters are valuable lubricants (commercial product Kortacid T from Akzo Chemie).
- Mineral oils which can be used according to the invention are all the usual mineral oils, from isoparaffin oil with a viscosity of 1.0 mPa.s at 20 ° C to thin spindle oil with a viscosity of 12 mPa.s at 20 ° C to highly viscous bright stock and cylinder oil with a viscosity of 540 mPa .s at 50 ° C.
- Ucolub N9 with a viscosity of 5.7 mPa.s at 100 ° C.
- Ucolub N36A with a viscosity of 18 mPa.s at 100 ° C
- Ucolub N 120A with a viscosity of 55 MPa.s at 100 ° C (all non-water-soluble polyglycols) from Union Carbide
- Isopar J from Esso (an isoparaffin oil) with a viscosity at 20 ° C of 1.0 mPa.s.
- organophosphorus compounds which can be used as phosphorus supports according to the invention are compounds of the formula R - - R in which R in each case denotes a straight-chain, branched or cyclic alkyl group having 6 to 12 carbon atoms or phenyl group substituted in the o- or p-position by a lower alkyl radical having 1 to 6 carbon atoms.
- organophosphorus compounds of the above formula are monodecyl diphenyl phosphite, dide cylphenyl phosphite, triphenyl phosphite, dioctyl phenyl phosphite, dihexyl phenyl phosphite, diisodecyl phenyl phosphite, diisooctyl phenyl phosphite, didecyl-o-methylphenyl phosphite and didecyl p-methylphenyl phosphite.
- the metal dialkyldithiocarbamates which can be used according to the invention as sulfur carriers are compounds of the formula wherein Me is a metal from the group copper, silver, zinc, cadmium, boron, titanium, zirconium, tin, lead, vanadium, tantalum, antimony, chromium, molybdenum, tungsten, manganese, cobalt and nickel, preferably boron, nickel, cobalt or molybdenum , means.
- the metal dialkyldithiophosphates which can be used according to the invention both as a sulfur carrier and as a phosphorus carrier are compounds of the formula wherein Me for a metal from the group copper, silver, zinc, cadmium, boron, titanium, zirconium, tin, lead, vanadium, tantalum, antimony, chromium, molybdenum, tungsten, manganese, cobalt and nickel, preferably for zinc, nickel, Titanium, vanadium, molybdenum, tungsten and manganese.
- the alkyl group in the above metal dialkyldithio Carbamates and metal dialkyldithiophosphates each preferably contain 4 to 8 carbon atoms, so that the metal salts mentioned are still soluble in the commercially available base oils.
- particularly advantageous alkyl groups include the n-, i- and tert-butyl group, the n- and i-amyl group, the n- and i-hexyl group, the n- and i-heptyl group and the 2-ethylhexyl group.
- the i-butyl group, the n- and i-amyl group and the 2-ethylhexyl group are very particularly preferred.
- metal dialkyldithiocarbamates which can be used according to the invention with particular advantage are the following: copper dialkyldithiocarbamates and copper bisdialkyldithiocarbamates; Silver dialkyldithiocarbamates; Zinc and cadmium bisdialkyldithiocarbamates; Boron trisdialkyldithiocarbamate; Titanium, zirconium, tin and lead tetrakisdialkyldithiocarbamates and tin and lead bisdialkyldithiocarbamates; Antimony, vanadium and tantalum dialkyldithiocarbamates, tetrakis and pentakis dialkyldithiocarbamates and the dialkyldithiocarbamates in which these metals are present in mixed oxidation states; Chromium, chromium tris, chromium tetrakis and chromium hexakisdialkyldithiocarbamates
- Particularly preferred among these compounds are the boron trisdialkyldithiocarbamates, the nickeltrisdialkyldithiocarbamates and the molybdenum tetrakis and molybdenum oxytetrakisdialkyldithiocarbamates.
- Metal dialkyldithiophosphates which can be used with particular advantage according to the invention are the dialkyldithiophosphates of the same metals in the same oxidation states as those above for the metal dialkyldi thiocarbamates have been listed.
- Zinc bisdialkyldithiophosphates, nickel bis and tris dialkyl dithiophosphates, titanium and vanadium tetrakis dialkyl dithiophosphates, molybdenum and tungsten tetrakis dialkyl dithiophosphates and molybdenum and tungsten oxytetrakis dialkyl dithiophosphates are very particularly advantageous.
- Particularly preferred representatives of the metal dialkyldithiocarbamates used according to the invention are: Bortrisdiisobutyldithiocarbamat, Bortrisdiamyldithiocarbamat, Bortrisdi-2-ethylhexyldithiocarbamat, Nickeltrisdiisobutyldithiocarbamat, Nickeltrisdiamyldithiocarbamat, Nickeltrisdi-2-ethylhexyldithiocarbamat, Molybdäntetrakisdi-2-ethylhexyldithiocarbamat, Molybdänoxytetrakisdi-2-ethylhexyldithiocarbamat and Kobaltbisdiisobutyldithiocarbamat.
- metal dialkyldithiophosphates used according to the invention are zinc bisdi-2-ethylhexyldithiophosphate, nickel bis- and trisdi-2-ethylhexyldithiophosphate, titanium and vanadium tetrakisdi-2-ethylhexyldithiophosphate as well as molybdenum and tungsten tetrakis and molybdenum oxythi-tetrahydrofuran.
- a circular disk made of stainless steel with a diameter of 23 mm and a thickness of 10 mm was used, on the surface of which a drop of the lubricating oil or grease to be examined was applied.
- a ball made of the same stainless steel with a diameter of 10 mm was applied, which exerted pressure on the surface of the metal disc due to its load.
- the wear profile transverse to the direction of oscillation of the ball, which was generated due to the friction between the loaded ball and the surface of the metal disk within the test period, was recorded by means of a suitable recording device, whereby the diagrams given below were obtained, in which the wear height as the difference between the highest was obtained on the ordinate and the lowest point of the surface profile of the metal disk as a function of the scanning distance of the surface of the metal disk is shown on the abscissa.
- a profile depth on the ordinate of 1 cm corresponds to a real profile depth in the surface of the metal disc of 1 ⁇ m, with the exception of diagram B ⁇ of Example 2.
- a profile depth of 1 cm corresponds to a real profile depth of 2.5 ⁇ m.
- a product was used as the lubricant concentrate according to the invention with the following composition: 50% C10-C18 pentaerythritol ester with quaternary carbon atom 20% copolymer of ⁇ -olefin esters 9.5% trimethyl adipate 2.5% dialkylaryl phosphite 9% metal dialkyldithiophosphate / metal dialkyldithiocarbamate 7% thiazole derivative 2% sterically hindered phenol as an oxidation inhibitor
- a highly viscous lubricating oil with a viscosity of 2200 mPa.s at 50 ° C of the following composition was produced and tested: Trimethyladipic acid didecyl ester 34% Polyisobutylene 43000mPa.s / 100 ° C 32% Lubricant drag substance 6% Lubricant concentrate according to the invention 28%
- the lubricant concentrate according to the invention was omitted in the comparison product.
- a medium-viscosity lubricating oil with a viscosity of 190 to 200 mPa.s at 50 ° C with the following composition was produced: polymeric ⁇ -olefin ester 12% Trimethyladipic acid didecyl ester 36% Polyisobutylene 4300 mPa.s / 100 ° C 18% Lubricant drag substance 6% Lubricant concentrate according to the invention 28%
- the lubricant concentrate according to the invention was omitted from the comparison product.
- the profile depth was 0.875 ⁇ m (average of two measurements) when using the lubricant according to the invention, the profile depth was 13.98 ⁇ m when using the comparative product.
- a lubricating oil with an average viscosity of 120 to 150 mPa.s at 50 ° C was prepared with the following composition: highly viscous ⁇ -olefin ester copolymer 4% medium viscosity ⁇ -olefin ester polymer 12% Trimethyladipic acid didecyl ester 34% Polyisobutylene 200 mPa.s / 100 ° C 12% Lubricant drag substance 6% concentrate according to the invention 32%
- the lubricant concentrate according to the invention was omitted in the comparison product.
- the profile rigidity when using the lubricating oil according to the invention was 1.12 ⁇ m (average of three measurements).
- the profile stiffness when using the comparison product was 3.48 microns.
- a highly viscous adhesive and high-temperature lubricating oil with a viscosity of 15,000 mPa.s at 50 ° C with the following composition was produced: Trimethyladipic acid didecyl ester 29% Polyisobutylene 43000 mPa.s / 100 ° C 52% Lubricant concentrate according to the invention 19%
- the tests were carried out for 1 hour at a temperature of 150 ° C. and a load of 200 N under identical conditions.
- the profile depth was 0.80 ⁇ m (average value from three measurements), while the profile depth when using the comparison product was 1.57 ⁇ m, as the following diagrams D (according to the invention) and D ⁇ (comparison product) show.
- a high-performance gear oil SAE 85/90 was tested with the addition of 10% by weight of monopentaerythritol tetraester according to the invention or without this addition.
- the comparative experiments were carried out for 1 hour at a temperature of 90 ° C. and under a load of 200 N under identical conditions.
- a lubricating grease for the multi-purpose lubrication of highly loaded gears and constant velocity joints with the following composition was produced: Mineral oil 70% Consistency generator based on lithium stearate 9% Lubricant concentrate according to the invention 21%
- the profile depth was 0.95 ⁇ m (average value from three measurements), while the profile depth when using the comparison product was 1.63 ⁇ m (average from three measurements), as the following diagrams F (according to the invention) and F ⁇ (comparison product) ) demonstrate.
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- Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Emergency Medicine (AREA)
- Engineering & Computer Science (AREA)
- Lubricants (AREA)
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE19873712133 DE3712133A1 (de) | 1987-04-10 | 1987-04-10 | Schmiermittel bzw. schmiermittelkonzentrat |
DE3712133 | 1987-04-10 |
Publications (2)
Publication Number | Publication Date |
---|---|
EP0286139A1 true EP0286139A1 (fr) | 1988-10-12 |
EP0286139B1 EP0286139B1 (fr) | 1994-09-07 |
Family
ID=6325305
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP88105725A Expired - Lifetime EP0286139B1 (fr) | 1987-04-10 | 1988-04-11 | Lubrifiant ou concentré de lubrifiant |
Country Status (8)
Country | Link |
---|---|
EP (1) | EP0286139B1 (fr) |
JP (1) | JP2843584B2 (fr) |
KR (1) | KR960014936B1 (fr) |
AT (1) | ATE111149T1 (fr) |
CA (1) | CA1340272C (fr) |
DE (2) | DE3712133A1 (fr) |
ES (1) | ES2064326T3 (fr) |
WO (1) | WO1988008021A1 (fr) |
Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO1991013955A1 (fr) * | 1990-03-07 | 1991-09-19 | Exxon Research And Engineering Company | Composition de graisse lubrifiante |
EP0316610B1 (fr) * | 1987-10-22 | 1992-07-08 | Idemitsu Kosan Company Limited | Composition d'huile lubrifiante |
WO1993005130A1 (fr) * | 1991-08-29 | 1993-03-18 | Henkel Kommanditgesellschaft Auf Aktien | Utilisation d'esters de l'acide isopalmitique comme lubrifiant pour moteurs a deux temps |
FR2684108A1 (fr) * | 1991-11-27 | 1993-05-28 | Mobil Oil France | Nouvelle graisse destinee notamment a etre utilisee dans des joints homocinetiques. |
Families Citing this family (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE3714260A1 (de) * | 1987-04-29 | 1988-11-10 | Spiess C F & Sohn | Bor-tris-(dialkyl-dithiocarbamate) und verfahren zu ihrer herstellung |
DE4128646A1 (de) * | 1991-08-29 | 1993-03-04 | Henkel Kgaa | Estermischungen von stark verzweigten carbonsaeuren |
JP4098513B2 (ja) * | 2001-02-02 | 2008-06-11 | 新日本石油株式会社 | 潤滑油組成物 |
JP4801574B2 (ja) * | 2006-12-11 | 2011-10-26 | 株式会社リコー | 像担持体用保護剤、及び保護層形成装置、並びに画像形成方法、画像形成装置、及びプロセスカートリッジ |
JP2008297501A (ja) * | 2007-06-01 | 2008-12-11 | New Japan Chem Co Ltd | 軸受用潤滑油 |
Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
FR1543830A (fr) * | 1966-11-10 | 1968-10-25 | Mobil Oil Corp | Compositions lubrifiantes contenant des additifs anti-corrosion perfectionnés |
FR2194770A1 (fr) * | 1972-07-31 | 1974-03-01 | Chevron Res | |
GB2134538A (en) * | 1983-01-20 | 1984-08-15 | Idemitsu Kosan Co | Lubricating oils |
WO1986001529A1 (fr) * | 1984-09-06 | 1986-03-13 | Exxon Research And Engineering Company | Compositions lubrifiantes pour formage a chaud |
EP0208541A2 (fr) * | 1985-07-08 | 1987-01-14 | Nippon Oil Co. Ltd. | Compositions lubrifiantes |
Family Cites Families (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
GB1301003A (en) * | 1969-07-10 | 1972-12-29 | Ethyl Corp | Lubricant materials |
JPS5328862B2 (fr) * | 1972-04-18 | 1978-08-17 | ||
IT1010487B (it) * | 1974-05-08 | 1977-01-10 | Snam Progetti | Esteri come componenti di lubrifi canti |
US3896050A (en) * | 1974-07-05 | 1975-07-22 | Texaco Inc | Lubricating oil additives |
US4097388A (en) * | 1976-10-12 | 1978-06-27 | The United States Of America As Represented By The Secretary Of The Air Force | Linear fluorinated polyether lubricant compositions containing perfluoroalkylether substituted phosphines |
IT1188166B (it) * | 1985-04-24 | 1988-01-07 | Montefluos Spa | Stabilizzanti a struttura arilfosfinica per olii e grassi perfluoropolieterei |
JPS6210193A (ja) * | 1985-07-08 | 1987-01-19 | Nippon Oil Co Ltd | トラクシヨンドライブ用流体組成物 |
-
1987
- 1987-04-10 DE DE19873712133 patent/DE3712133A1/de active Granted
-
1988
- 1988-04-08 CA CA000563732A patent/CA1340272C/fr not_active Expired - Fee Related
- 1988-04-11 DE DE3851355T patent/DE3851355D1/de not_active Expired - Lifetime
- 1988-04-11 EP EP88105725A patent/EP0286139B1/fr not_active Expired - Lifetime
- 1988-04-11 JP JP63503324A patent/JP2843584B2/ja not_active Expired - Fee Related
- 1988-04-11 WO PCT/EP1988/000300 patent/WO1988008021A1/fr unknown
- 1988-04-11 AT AT88105725T patent/ATE111149T1/de not_active IP Right Cessation
- 1988-04-11 KR KR1019880701563A patent/KR960014936B1/ko not_active IP Right Cessation
- 1988-04-11 ES ES88105725T patent/ES2064326T3/es not_active Expired - Lifetime
Patent Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
FR1543830A (fr) * | 1966-11-10 | 1968-10-25 | Mobil Oil Corp | Compositions lubrifiantes contenant des additifs anti-corrosion perfectionnés |
FR2194770A1 (fr) * | 1972-07-31 | 1974-03-01 | Chevron Res | |
GB2134538A (en) * | 1983-01-20 | 1984-08-15 | Idemitsu Kosan Co | Lubricating oils |
WO1986001529A1 (fr) * | 1984-09-06 | 1986-03-13 | Exxon Research And Engineering Company | Compositions lubrifiantes pour formage a chaud |
EP0208541A2 (fr) * | 1985-07-08 | 1987-01-14 | Nippon Oil Co. Ltd. | Compositions lubrifiantes |
Cited By (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP0316610B1 (fr) * | 1987-10-22 | 1992-07-08 | Idemitsu Kosan Company Limited | Composition d'huile lubrifiante |
WO1991013955A1 (fr) * | 1990-03-07 | 1991-09-19 | Exxon Research And Engineering Company | Composition de graisse lubrifiante |
WO1993005130A1 (fr) * | 1991-08-29 | 1993-03-18 | Henkel Kommanditgesellschaft Auf Aktien | Utilisation d'esters de l'acide isopalmitique comme lubrifiant pour moteurs a deux temps |
US5507964A (en) * | 1991-08-29 | 1996-04-16 | Henkel Kommanditgesellschaft Auf Aktien | Use of isopalmitic acid esters as lubricants for two-stroke engines |
FR2684108A1 (fr) * | 1991-11-27 | 1993-05-28 | Mobil Oil France | Nouvelle graisse destinee notamment a etre utilisee dans des joints homocinetiques. |
WO1993011208A1 (fr) * | 1991-11-27 | 1993-06-10 | Mobil Oil Française | Nouvelle graisse destinee notamment a etre utilisee dans des joints homocinetiques |
Also Published As
Publication number | Publication date |
---|---|
WO1988008021A1 (fr) | 1988-10-20 |
ES2064326T3 (es) | 1995-02-01 |
JP2843584B2 (ja) | 1999-01-06 |
DE3851355D1 (de) | 1994-10-13 |
EP0286139B1 (fr) | 1994-09-07 |
CA1340272C (fr) | 1998-12-15 |
DE3712133C2 (fr) | 1993-07-15 |
ATE111149T1 (de) | 1994-09-15 |
KR960014936B1 (ko) | 1996-10-21 |
DE3712133A1 (de) | 1988-10-20 |
JPH01503543A (ja) | 1989-11-30 |
KR890701717A (ko) | 1989-12-21 |
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