EP0260419B1 - Verbrennbarer Treibladungsbehälter mit verbesserter Temperaturbeständigkeit - Google Patents
Verbrennbarer Treibladungsbehälter mit verbesserter Temperaturbeständigkeit Download PDFInfo
- Publication number
- EP0260419B1 EP0260419B1 EP87111101A EP87111101A EP0260419B1 EP 0260419 B1 EP0260419 B1 EP 0260419B1 EP 87111101 A EP87111101 A EP 87111101A EP 87111101 A EP87111101 A EP 87111101A EP 0260419 B1 EP0260419 B1 EP 0260419B1
- Authority
- EP
- European Patent Office
- Prior art keywords
- propellant container
- temperature resistance
- container according
- cartridge case
- improved temperature
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 239000003380 propellant Substances 0.000 title claims description 9
- 238000000576 coating method Methods 0.000 claims description 11
- 239000011248 coating agent Substances 0.000 claims description 7
- 239000011230 binding agent Substances 0.000 claims description 6
- POCJOGNVFHPZNS-ZJUUUORDSA-N (6S,7R)-2-azaspiro[5.5]undecan-7-ol Chemical compound O[C@@H]1CCCC[C@]11CNCCC1 POCJOGNVFHPZNS-ZJUUUORDSA-N 0.000 claims description 4
- XTFIVUDBNACUBN-UHFFFAOYSA-N 1,3,5-trinitro-1,3,5-triazinane Chemical group [O-][N+](=O)N1CN([N+]([O-])=O)CN([N+]([O-])=O)C1 XTFIVUDBNACUBN-UHFFFAOYSA-N 0.000 claims description 4
- BSPUVYFGURDFHE-UHFFFAOYSA-N Nitramine Natural products CC1C(O)CCC2CCCNC12 BSPUVYFGURDFHE-UHFFFAOYSA-N 0.000 claims description 4
- 239000002360 explosive Substances 0.000 claims description 4
- POCJOGNVFHPZNS-UHFFFAOYSA-N isonitramine Natural products OC1CCCCC11CNCCC1 POCJOGNVFHPZNS-UHFFFAOYSA-N 0.000 claims description 4
- DHKHKXVYLBGOIT-UHFFFAOYSA-N acetaldehyde Diethyl Acetal Natural products CCOC(C)OCC DHKHKXVYLBGOIT-UHFFFAOYSA-N 0.000 claims description 3
- 239000004014 plasticizer Substances 0.000 claims description 3
- 229920002554 vinyl polymer Polymers 0.000 claims description 3
- MQIUGAXCHLFZKX-UHFFFAOYSA-N Di-n-octyl phthalate Natural products CCCCCCCCOC(=O)C1=CC=CC=C1C(=O)OCCCCCCCC MQIUGAXCHLFZKX-UHFFFAOYSA-N 0.000 claims description 2
- 239000005062 Polybutadiene Substances 0.000 claims description 2
- 239000004372 Polyvinyl alcohol Substances 0.000 claims description 2
- BJQHLKABXJIVAM-UHFFFAOYSA-N bis(2-ethylhexyl) phthalate Chemical compound CCCCC(CC)COC(=O)C1=CC=CC=C1C(=O)OCC(CC)CCCC BJQHLKABXJIVAM-UHFFFAOYSA-N 0.000 claims description 2
- 238000005474 detonation Methods 0.000 claims description 2
- 229920000058 polyacrylate Polymers 0.000 claims description 2
- 229920002857 polybutadiene Polymers 0.000 claims description 2
- 229920002451 polyvinyl alcohol Polymers 0.000 claims description 2
- 239000000126 substance Substances 0.000 claims 2
- 125000002777 acetyl group Chemical class [H]C([H])([H])C(*)=O 0.000 claims 1
- 239000011347 resin Substances 0.000 description 5
- 229920005989 resin Polymers 0.000 description 5
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 3
- 238000002485 combustion reaction Methods 0.000 description 2
- 239000010410 layer Substances 0.000 description 2
- 239000007788 liquid Substances 0.000 description 2
- 239000004925 Acrylic resin Substances 0.000 description 1
- 239000011354 acetal resin Substances 0.000 description 1
- 150000001241 acetals Chemical class 0.000 description 1
- 230000001680 brushing effect Effects 0.000 description 1
- 239000011247 coating layer Substances 0.000 description 1
- -1 cyclotetramethylene tetramine Chemical compound 0.000 description 1
- 238000004200 deflagration Methods 0.000 description 1
- 238000007598 dipping method Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 239000004922 lacquer Substances 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 239000003973 paint Substances 0.000 description 1
- 229920006324 polyoxymethylene Polymers 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 238000005096 rolling process Methods 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 238000005507 spraying Methods 0.000 description 1
Classifications
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F42—AMMUNITION; BLASTING
- F42B—EXPLOSIVE CHARGES, e.g. FOR BLASTING, FIREWORKS, AMMUNITION
- F42B5/00—Cartridge ammunition, e.g. separately-loaded propellant charges
- F42B5/02—Cartridges, i.e. cases with charge and missile
- F42B5/18—Caseless ammunition; Cartridges having combustible cases
- F42B5/192—Cartridge cases characterised by the material of the casing wall
- F42B5/196—Coatings
-
- C—CHEMISTRY; METALLURGY
- C06—EXPLOSIVES; MATCHES
- C06B—EXPLOSIVES OR THERMIC COMPOSITIONS; MANUFACTURE THEREOF; USE OF SINGLE SUBSTANCES AS EXPLOSIVES
- C06B45/00—Compositions or products which are defined by structure or arrangement of component of product
- C06B45/12—Compositions or products which are defined by structure or arrangement of component of product having contiguous layers or zones
Definitions
- the present invention is concerned with combustible propellant containers, such as sleeves or cartridges, whose temperature resistance is improved. At the same time, mechanical properties of these containers are also improved.
- the object was therefore to develop combustible containers for propellant charge powders which are as temperature-resistant as possible and at the same time have mechanical property values which are at least equivalent to those of known containers. Furthermore, the container should burn off without residues and not negatively affect the energy balance of the entire combustion system.
- combustible propellant charge containers which are provided with a surface coating and are characterized by a coating with a nitramine known as an explosive and which is embedded in a binder.
- nitramines to be used are those which are known per se as explosives, have a detonation speed of more than 7,400 m / s and, when burned, deliver a high normal gas volume, preferably more than 650 l / kg (measured by the CIT method). Furthermore, they should have deflagration points above 200 ° C, preferably above 230 ° C.
- Nitramines that meet these conditions are e.g. Cyclotrimethylene trinitramine (hexogen) or the cyclotetramethylene tetramine (octogenes).
- Suitable liquid binders are those liquid resins which have a desensitizing effect on the nitramines, so that they do not detonate, but rather uniformly burn down. The resins are also said to cure when standing in the air. Resins with such properties are known per se to the person skilled in the art. Resins based on polyvinyl alcohol, polyvinyl acetal, polybutadiene or polyacrylates may be mentioned as examples.
- the proportion of binders in the coating can vary between 5 and 20% by weight, depending on the type of resin used. It is preferably between 10 and 15% by weight, especially if a polyvinyl acetal resin is used as the binder.
- the thickness of the coatings depends on the respective application and the components used; it can vary between 0.1 and 1.0 mm, preferably it is between 0.2 and 0.5 mm.
- the application is carried out in a manner known per se, optionally dissolved in a suitable solvent; e.g. by spraying, dipping, rolling or brushing.
- the application can be carried out both on the sleeve which has not yet been processed as well as on a sleeve which has already been provided with a load and projectile.
- the paint to be applied also contains a plasticizer known per se.
- the coating according to the invention is always on the outer surfaces of the containers. It can also be attached to the inner wall. In any case, it burns together with the container.
- the containers which are coated according to the invention are known per se to the person skilled in the art. These are both flammable sleeves or cartridges as well as containers that can be used instead of bag loads.
- the containers preferably have a central tube for receiving an ignition boost and are cylindrical or slightly conical.
- the coating according to the invention improves the cook-off behavior of the sleeves; it also protects the sleeves from moisture and also improves the mechanical properties of the sleeves, e.g. the tensile strength, impact and impact resistance.
- a cartridge made with this sleeve moves without residue when fired in the weapon.
Landscapes
- Chemical & Material Sciences (AREA)
- Crystallography & Structural Chemistry (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- General Engineering & Computer Science (AREA)
- Paints Or Removers (AREA)
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE3630019 | 1986-09-03 | ||
DE19863630019 DE3630019A1 (de) | 1986-09-03 | 1986-09-03 | Verbrennbarer treibladungsbehaelter mit verbesserter temperaturbestaendigkeit |
Publications (3)
Publication Number | Publication Date |
---|---|
EP0260419A2 EP0260419A2 (de) | 1988-03-23 |
EP0260419A3 EP0260419A3 (en) | 1989-10-04 |
EP0260419B1 true EP0260419B1 (de) | 1993-01-27 |
Family
ID=6308844
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP87111101A Expired - Lifetime EP0260419B1 (de) | 1986-09-03 | 1987-07-31 | Verbrennbarer Treibladungsbehälter mit verbesserter Temperaturbeständigkeit |
Country Status (2)
Country | Link |
---|---|
EP (1) | EP0260419B1 (enrdf_load_stackoverflow) |
DE (2) | DE3630019A1 (enrdf_load_stackoverflow) |
Families Citing this family (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE3825581C1 (en) * | 1988-07-28 | 1993-05-13 | Dynamit Nobel Ag, 5210 Troisdorf, De | Combustible or consumable cartridge cases for ammunition - made of wrapping(s) of fibres of polyester, polyamide, polyolefin. polyacrylate, polyurethane, metal glass, coal etc. |
DE3830902C1 (enrdf_load_stackoverflow) * | 1988-09-10 | 1992-04-09 | Diehl Gmbh & Co, 8500 Nuernberg, De | |
US5069133A (en) * | 1990-08-31 | 1991-12-03 | Olin Corporation | Elastomer-containing casings for propellants |
DE4223143A1 (de) * | 1991-08-16 | 1993-02-18 | Eidgenoess Munitionsfab Thun | Verfahen zur verbesserung der mechanischen beanspruchbarkeit von hochbeschleunigten und/oder schockwellen unterworfenen munitionskoerpern, insbesondere solche mit hohlladungen sowie dessen anwendung |
FR2928917B1 (fr) * | 2008-03-21 | 2010-09-24 | Eurenco France | Revetement de finition inflammable pour chargement pyrotechnique; composition liquide precurseur dudit revetement |
US12337511B2 (en) | 2021-09-27 | 2025-06-24 | General Dynamics Ordnance And Tactical Systems—Canada Inc | Combustible containers manufactured using reactive injection molding of azido polymers |
Family Cites Families (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3927616A (en) * | 1974-04-23 | 1975-12-23 | Us Army | Combustible cartridge case |
DE2458877C2 (de) * | 1974-12-12 | 1983-02-10 | Deutsch-Französisches Forschungsinstitut Saint-Louis, Saint-Louis | Verbrennbare Schutzhülle gegen thermische Einflüsse für Geschoßtreibladungen für automatische Waffen |
DE2710451C2 (de) * | 1977-03-10 | 1990-11-15 | Rheinmetall GmbH, 4000 Düsseldorf | Oberflächenschutzbeschichtung für Munition mit verbrennbarer Hülse bzw. hülsenlose Munition |
DE2843477C2 (de) * | 1978-10-05 | 1987-04-09 | Dynamit Nobel Ag, 5210 Troisdorf | Hülsenlose Treibmittelkörper |
FR2444251A1 (fr) * | 1978-12-15 | 1980-07-11 | Poudres & Explosifs Ste Nale | Objets combustibles, et notamment douilles combustibles, resistant a la chaleur |
FR2590013B1 (fr) * | 1985-11-12 | 1989-07-13 | France Etat Armement | Vernis protecteur contre la thermo-initiation d'une munition sans douille ou a douille combustible |
-
1986
- 1986-09-03 DE DE19863630019 patent/DE3630019A1/de active Granted
-
1987
- 1987-07-31 EP EP87111101A patent/EP0260419B1/de not_active Expired - Lifetime
- 1987-07-31 DE DE8787111101T patent/DE3783839D1/de not_active Expired - Fee Related
Also Published As
Publication number | Publication date |
---|---|
DE3630019C2 (enrdf_load_stackoverflow) | 1989-10-12 |
DE3630019A1 (de) | 1988-03-17 |
EP0260419A3 (en) | 1989-10-04 |
DE3783839D1 (de) | 1993-03-11 |
EP0260419A2 (de) | 1988-03-23 |
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