EP0216301A2 - Agent de nettoyage liquide - Google Patents

Agent de nettoyage liquide Download PDF

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Publication number
EP0216301A2
EP0216301A2 EP86112821A EP86112821A EP0216301A2 EP 0216301 A2 EP0216301 A2 EP 0216301A2 EP 86112821 A EP86112821 A EP 86112821A EP 86112821 A EP86112821 A EP 86112821A EP 0216301 A2 EP0216301 A2 EP 0216301A2
Authority
EP
European Patent Office
Prior art keywords
alkyl
fatty
sulfate
fatty acid
anionic surfactants
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
EP86112821A
Other languages
German (de)
English (en)
Other versions
EP0216301B1 (fr
EP0216301A3 (en
Inventor
Manfred Biermann
Martin Bischoff
Ortburg Guirr
Peter Sandkuehler
Harald Schnegelberger
Karl-Heinz Schmid
Klaus Schumann
Eric Sung
Klaus-Dieter Wisotzki
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Henkel AG and Co KGaA
Original Assignee
Henkel AG and Co KGaA
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Family has litigation
First worldwide family litigation filed litigation Critical https://patents.darts-ip.com/?family=6281832&utm_source=google_patent&utm_medium=platform_link&utm_campaign=public_patent_search&patent=EP0216301(A2) "Global patent litigation dataset” by Darts-ip is licensed under a Creative Commons Attribution 4.0 International License.
Application filed by Henkel AG and Co KGaA filed Critical Henkel AG and Co KGaA
Priority to AT86112821T priority Critical patent/ATE66687T1/de
Publication of EP0216301A2 publication Critical patent/EP0216301A2/fr
Publication of EP0216301A3 publication Critical patent/EP0216301A3/de
Application granted granted Critical
Publication of EP0216301B1 publication Critical patent/EP0216301B1/fr
Anticipated expiration legal-status Critical
Revoked legal-status Critical Current

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/0005—Other compounding ingredients characterised by their effect
    • C11D3/0094—High foaming compositions
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66—Non-ionic compounds
    • C11D1/662—Carbohydrates or derivatives
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/86—Mixtures of anionic, cationic, and non-ionic compounds
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/02—Anionic compounds
    • C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
    • C11D1/14—Sulfonic acids or sulfuric acid esters; Salts thereof derived from aliphatic hydrocarbons or mono-alcohols
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/02—Anionic compounds
    • C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
    • C11D1/29—Sulfates of polyoxyalkylene ethers
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/38—Cationic compounds
    • C11D1/52—Carboxylic amides, alkylolamides or imides or their condensation products with alkylene oxides
    • C11D1/523—Carboxylic alkylolamides, or dialkylolamides, or hydroxycarboxylic amides (R1-CO-NR2R3), where R1, R2 or R3 contain one hydroxy group per alkyl group

Definitions

  • Liquid cleaning agents usually consist of aqueous solutions of synthetic anionic and / or nonionic surfactants and conventional additives. They are particularly used for cleaning hard surfaces, for example glass, ceramic materials, plastics, painted and polished surfaces.
  • An important area of application for liquid cleaning agents is the manual washing of eating and cooking utensils.
  • the dishes are usually cleaned at slightly elevated temperatures of around 35 to 45 ° C in very dilute liquors.
  • the cleaning power of an agent is rated by the consumer the better and the longer the cleaning liquor foams. Due to the contact of the hands with the cleaning solution over a longer period of time, the skin-friendliness of the agent is of particular importance when washing dishes. For these reasons, the expert makes different considerations when selecting the components and the composition of an agent for the manual cleaning of dishes than with liquid detergents for other hard surfaces.
  • the present invention relates to liquid, manually applicable, skin-friendly dishwashing detergents with strong foaming and good cleaning power.
  • alkyl ether sulfates that is to say salts of sulfated adducts of about 2 to 5 moles of ethylene oxide with fatty alcohols of about 10 to 18, are preferred wise 12 to 16 carbon atoms in the aliphatic rest have good foaming and cleaning power as well as skin-friendly properties.
  • the commercially available, manual dishwashing detergents also known as dishwashing detergents
  • dishwashing detergents therefore generally represent aqueous solutions of such alkyl ether sulfates in conjunction with other surfactants, in particular alkylbenzenesulfonates and solubilizers, colors and fragrances.
  • Swiss patent 354 195 discloses liquid detergents for manual dishwashing, which are a combination of an alkyl ether sulfate and a nonionic surfactant of the fatty acid alkanolamide type from mono- or dialkanolamides with no more than 3 carbon atoms in each alkanol residue of saturated fatty acids with 10 to 14 Contain carbon atoms, together with water, solubilizers, colors and fragrances.
  • alkyl monoglucosides not only develop stable foam themselves, but also act as foam stabilizers for other anionic and nonionic surfactants. They are said to be comparable to fatty acid alkanolamides and in some cases to be somewhat better than these. Combinations with such alkanolamides are not described.
  • European patent application 70 076 discloses foaming liquid detergents containing anionic surfactants, alkyl glucosides and amine oxides or fatty acid alkanolamides, the alkyl glucosides being alkyl oligoglucosides which contain the glucose unit about 1.5 to 10 times. This value is an average value and also takes into account the presence of alkyl monoglucosides in a corresponding proportion. Alkyl glucosides with a degree of oligomerization of higher than 2 are found to be particularly suitable.
  • fatty alkyl glucosides can be increased, that one chooses fatty alkyl glucosides of the fatty alkyl monoglucoside type.
  • Fatty alkyl monoglucosides are understood here to mean compounds with an average of less than two glucose units per fatty alkyl radical, in particular those with 1 to 1.4 glucose units.
  • the fatty alkyl radical has 10 to 18, in particular essentially 12 to 14, carbon atoms.
  • “Fatty alkyl” is understood to mean the residues of the fatty alcohols produced by hydrogenation of natural fatty acids which are wholly or predominantly saturated or which also comprise unsaturated portions.
  • an alkyl sulfate or an alkyl ether sulfate is used as the synthetic anionic surfactant.
  • the invention creates a cleaning agent made from three different types of surfactants, the hydrophobic part of which is produced entirely from renewable raw materials (fats).
  • the hydrophilic part of the molecule also consists of a renewable one Raw material (sugar).
  • the anionic surfactants which have a petrochemical base, in particular alkylbenzenesulfonate, are therefore not used.
  • alkyl sulfates or alkyl ether sulfates are commercially available, they have a straight-chain aliphatic C 12- C18, preferably C12-C14 radical.
  • the associated cation is preferably an alkali metal or ammonium ion.
  • the degree of ethoxylation of alkyl ether sulfates is 1 to 5; it is preferred to use an alkyl ether sulfate mixture consisting of 50 percent by weight of a C12 alkyl ether sulfate and 50 percent by weight of a C14 alkyl ether sulfate with 1 to 5, preferably 2 to 4, ethylene oxide groups instead of the alkyl ether sulfate mixture usually used, which contains the same components in a weight ratio of 70:30 , because it leads to a reduction in skin irritation without reducing the known good washing power of such agents. Small additional amounts of alkyl ether sulfates with less than 12 or more than 14 carbon atoms in the alkyl radical change these good results only insignificantly, but should be avoided if necessary.
  • the amount of alkyl and alkyl ether sulfates used is 2 to 25, preferably 3 to 20 percent by weight, based on the total agent.
  • the fatty acid alkanolamides used have an alkyl group with 8 to 18, preferably 10 to 14 carbon atoms in the fatty acid residue, while the amide group either with two hydroxyalkyl groups with 1 to 3 carbon atoms (dialkanolamide) or with such a hydroxyalkyl group and with hydrogen or a C1-C3 -Alkyl distr is substituted.
  • This verb disme are used in an amount of 1 to 15, preferably from 1 to 5 percent by weight, based on the total agent.
  • Mixtures of fatty acid mono- and dialkanolamides are preferably used.
  • the amount of the alkyl monoglucosides added according to the invention is 2 to 25, preferably 3 to 20 percent by weight, based on the total agent, this amount preferably being equal to or less than the combined amount of sulfate surfactant and fatty acid alkanolamide.
  • solubilizers for example for dyes and perfume oils, for example alkanolamines, polyols, such as ethylene glycol, propylene glycol-1,2 or glycerol, and as hydrotropes, alkali alkylbenzenesulfonates having 1 to 3 carbon atoms in the alkyl radical, preferably sodium cumene sulfonate, can be used.
  • the amounts used are between 3 and 15 percent by weight, based on the total agent.
  • solvents such as low molecular weight alkanols with 1 to 4 carbon atoms in the molecule, preferably ethanol and isopropyl alcohol, are usually used.
  • the amounts used are also 3 to 15 percent by weight, based on the total agent.
  • Thickeners such as urea, sodium chloride, ammonium chloride and magnesium chloride can also be used individually or in combination.
  • Other common optional additives are corrosion inhibitors, preservatives, dyes and perfume oils.
  • the remainder to be calculated for a total of 100 percent by weight for the total composition consists of water.
  • liquid cleaning agents according to the invention according to the following examples were prepared by stirring the individual
  • the liquid cleaning agents according to the invention according to the following examples were obtained by stirring the individual constituents together and allowing the mixture to stand until there were no bubbles.
  • the sodium salts were used as anionic surfactants.
  • the plate test is described in this example.
  • the amount of 9 g of sodium C 12-14 alkyl (EO) 2 sulfate was stirred at room temperature with 7.5 g of sodium cumene sulfonate in 68.5 g of water and 12 g of C 12 in succession in any order with further stirring -14 -Alkyl monoglucoside with 1.3 glucose units (GE) in the molecule and 2 g of C 12-14 fatty acid monoethanolamide and 1 g of C12-C14 fatty acid diethanolamide were added.
  • the product was clear and had a Höppler viscosity of 15 mPas at 20 ° C.
  • saucers were coated with 2 g of melted beef tallow (test soil A) and accordingly with 2 g of a mixed soil of protein, fat and carbohydrates (MiNO-1 from Henkel) (test soil B) mixed with water. Then 8 liters of tap water (16 ° d) at 45 ° C were placed in a bowl. To clean the plates soiled with (A), 4 g, ie 0.5 g / l, of the cleaning agent prepared were added and the plates were washed. Until the foam of the initially foaming solution disappeared, 18 plates could be washed clean.
  • Example 1 According to the information in Example 1, 6 different compositions were produced with respect to the alkyl ether sulfate and the alkyl glucoside content with a constant content of C 12-14 fatty acid diethanolamide, and products with 1.1 GE and 2.2 GE were compared as alkyl glucosides.
  • the agents were each subjected to the plate test. The results are shown in the table below. They show the advantage of the product with 1.1 GE.
  • Example 2 According to the information in Example 1, this time the C 12-14 alkyl (EO) 2 sulfate was replaced by C 12-14 alkyl sulfate and the procedure was as in Example 2. One with 1.4 GE and one with 2.2 GE were used as glucosides. The results are shown in the table below. They show that the advantages of using alkyl monoglucosides with GE less than 1.5 also occur in conjunction with alkyl sulfates.

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Molecular Biology (AREA)
  • Detergent Compositions (AREA)
EP86112821A 1985-09-25 1986-09-17 Agent de nettoyage liquide Revoked EP0216301B1 (fr)

Priority Applications (1)

Application Number Priority Date Filing Date Title
AT86112821T ATE66687T1 (de) 1985-09-25 1986-09-17 Fluessiges reinigungsmittel.

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DE3534082 1985-09-25
DE19853534082 DE3534082A1 (de) 1985-09-25 1985-09-25 Fluessiges reinigungsmittel

Publications (3)

Publication Number Publication Date
EP0216301A2 true EP0216301A2 (fr) 1987-04-01
EP0216301A3 EP0216301A3 (en) 1988-08-31
EP0216301B1 EP0216301B1 (fr) 1991-08-28

Family

ID=6281832

Family Applications (1)

Application Number Title Priority Date Filing Date
EP86112821A Revoked EP0216301B1 (fr) 1985-09-25 1986-09-17 Agent de nettoyage liquide

Country Status (6)

Country Link
US (1) US4732704A (fr)
EP (1) EP0216301B1 (fr)
JP (1) JPS6274999A (fr)
AT (1) ATE66687T1 (fr)
DE (2) DE3534082A1 (fr)
ES (1) ES2001985A6 (fr)

Cited By (17)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0341071A2 (fr) * 1988-05-06 1989-11-08 Unilever Plc Compositions détergentes
EP0353735A2 (fr) * 1988-08-04 1990-02-07 Kao Corporation Composition détergente
WO1990002164A1 (fr) * 1988-08-19 1990-03-08 Colgate Palmolive Company Compositions de detergents liquides pour lavages delicats
EP0370312A2 (fr) * 1988-11-17 1990-05-30 Henkel Kommanditgesellschaft auf Aktien Agent de lavage et de nettoyage contenant un mélange d'agents tensio-actifs composé d'alkylglycosides et de tensio-actifs anioniques
EP0403948A1 (fr) * 1989-06-22 1990-12-27 Henkel Kommanditgesellschaft auf Aktien Composition détergente
GB2234983A (en) * 1989-07-25 1991-02-20 Kao Corp Liquid detergent composition
EP0418479A1 (fr) * 1989-08-04 1991-03-27 Hüls Aktiengesellschaft Agents émulsifiants pour la préparation d'émulsions aqueuses d'huiles de polysiloxane et/ou de paraffine stables au stockage
WO1991018963A1 (fr) * 1990-06-05 1991-12-12 Henkel Kommanditgesellschaft Auf Aktien Concentre liquide, fluide et pompable d'agents tensio-actifs
WO1992001772A1 (fr) * 1990-07-23 1992-02-06 Henkel Kommanditgesellschaft Auf Aktien Concentre tensio-actif liquide ayant une bonne fluidite et pompabilite
EP0486786A1 (fr) * 1990-11-17 1992-05-27 Hüls Aktiengesellschaft Détergent liquide moussant
US5268126A (en) * 1989-08-04 1993-12-07 Huels Aktiengesellschaft Emulsifiers for the preparation of aqueous polysiloxane emulsions and aqueous polysiloxane-paraffin oil emulsions with long shelf lives
WO1994012601A1 (fr) * 1992-11-26 1994-06-09 Henkel Kommanditgesellschaft Auf Aktien Preparations tensioactives visqueuses aqueuses
DE4409189A1 (de) * 1994-03-17 1995-09-21 Chem Y Tensid-Zusammensetzung, insbesondere zur Verwendung in Körperreinigungsmitteln
WO1996013567A1 (fr) * 1994-10-28 1996-05-09 Henkel Kommanditgesellschaft Auf Aktien Detergent aqueux pour lavage manuel de la vaisselle
US5575864A (en) * 1994-03-23 1996-11-19 Haley; Kalliopi S. Method for cleaning a hard surface with an all-purpose liquid cleaning composition
US6555515B1 (en) 1995-12-06 2003-04-29 Henkel Kommanitgesellschaft Auf Aktien Formulations for cleaning hard surfaces based on at least partly branched-chain alkyl oligoglucosides
US8093200B2 (en) 2007-02-15 2012-01-10 Ecolab Usa Inc. Fast dissolving solid detergent

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US4834903A (en) * 1986-09-29 1989-05-30 Henkel Corporation Alkylene oxide adducts of glycoside surfactants and detergent compositions containing same
DE3706015A1 (de) * 1987-02-25 1988-11-17 Henkel Kgaa Fluessiges reinigungsmittel
JPH01168613A (ja) * 1987-12-24 1989-07-04 Shiseido Co Ltd 洗浄剤組成物
US5230835A (en) * 1988-08-04 1993-07-27 Kao Corporation Mild non-irritating alkyl glycoside based detergent compositions
JP2566816B2 (ja) * 1988-08-29 1996-12-25 花王株式会社 洗浄剤組成物
CA2002095C (fr) * 1988-11-03 1998-06-02 Ralph S. Itoku Gel nettoyant a haut degre de viscosite et methode de fabrication connexe
JPH0699710B2 (ja) * 1989-01-09 1994-12-07 花王株式会社 洗浄剤組成物
JPH0699708B2 (ja) * 1989-03-20 1994-12-07 花王株式会社 中性液体洗浄剤組成物
DE4003098A1 (de) * 1990-02-02 1991-08-08 Henkel Kgaa Waessriges fluessiges reinigungsmittel
US5118440A (en) * 1990-03-05 1992-06-02 The Procter & Gamble Company Light-duty liquid dishwashing detergent composition containing alkyl polysaccharide and alpha-sulfonated fatty acid alkyl ester surfactants
JPH04126799A (ja) * 1990-09-17 1992-04-27 Kanebo Ltd 洗浄剤組成物
DE4102744A1 (de) * 1991-01-30 1992-08-06 Henkel Kgaa Schwachschaeumendes scheuerpulver
US5480586A (en) * 1991-04-15 1996-01-02 Colgate-Palmolive Co. Light duty liquid detergent compostion comprising a sulfosuccinamate-containing surfactant blend
US5565146A (en) * 1991-04-15 1996-10-15 Cologate-Palmolive Co. Light duty liquid detergent compositions
GB9207637D0 (en) * 1991-04-24 1992-05-27 Kao Corp Milky detergent composition for hard surfaces
DE4117689A1 (de) * 1991-05-29 1992-12-03 Henkel Kgaa Fluessige, giess- und pumpfaehige tensidzubereitung
US5266690A (en) * 1991-12-19 1993-11-30 Henkel Corporation Preparation of alkylpolyglycosides
US5449763A (en) * 1991-10-10 1995-09-12 Henkel Corporation Preparation of alkylpolyglycosides
ES2154639T3 (es) * 1991-10-10 2001-04-16 Cognis Corp Preparacion de mezclas mejoradas de agentes tensioactivos alquilpoliglicosidicos.
US5298195A (en) * 1992-03-09 1994-03-29 Amway Corporation Liquid dishwashing detergent
US6071429A (en) * 1992-09-21 2000-06-06 Henkel Corporation Viscosity-stabilized amide composition, methods of preparing and using same
DE4234487A1 (de) * 1992-10-14 1994-04-21 Henkel Kgaa Wäßrige Detergensgemische
US5759979A (en) * 1993-04-05 1998-06-02 Henkel Kommanditgesellschaft Auf Aktien Detergent mixtures comprising APG and fatty alcohol polyglycol ether
US5474713A (en) * 1994-03-23 1995-12-12 Amway Corporation High actives cleaning compositions and methods of use
US5837668A (en) * 1996-04-30 1998-11-17 Rhodia Inc. Acyloxyalkane sulfonate and amphoteric surfactant blend compositions and methods for preparing same
EP0981594A4 (fr) * 1997-02-18 2001-03-21 Henkel Corp Amelioration de l'activite de sulfate d'ether utilise dans des liquides de lavage delicat, au moyen d'alkylpolyglycoside
US6767881B1 (en) 2003-03-19 2004-07-27 Ecolab, Inc. Cleaning concentrate

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US2970962A (en) * 1958-02-11 1961-02-07 Sugar Res Foundation Inc Novel detergent compositions
EP0070076A2 (fr) * 1981-07-13 1983-01-19 THE PROCTER & GAMBLE COMPANY Compositions liquides moussantes de rinçage pour la vaisselle
EP0075994A2 (fr) * 1981-09-28 1983-04-06 THE PROCTER & GAMBLE COMPANY Compositions détergentes contenant un mélange d'alkylpolysaccharide, d'agents tensio-actifs d'oxydes d'amine et de savon d'acides gras
EP0105556A1 (fr) * 1982-09-30 1984-04-18 THE PROCTER & GAMBLE COMPANY Composition détergente liquide contenant des tensides nonioniques et ioniques

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US4536318A (en) * 1982-04-26 1985-08-20 The Procter & Gamble Company Foaming surfactant compositions
US4599188A (en) * 1982-04-26 1986-07-08 The Procter & Gamble Company Foaming surfactant compositions
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US2970962A (en) * 1958-02-11 1961-02-07 Sugar Res Foundation Inc Novel detergent compositions
EP0070076A2 (fr) * 1981-07-13 1983-01-19 THE PROCTER & GAMBLE COMPANY Compositions liquides moussantes de rinçage pour la vaisselle
EP0075994A2 (fr) * 1981-09-28 1983-04-06 THE PROCTER & GAMBLE COMPANY Compositions détergentes contenant un mélange d'alkylpolysaccharide, d'agents tensio-actifs d'oxydes d'amine et de savon d'acides gras
EP0105556A1 (fr) * 1982-09-30 1984-04-18 THE PROCTER & GAMBLE COMPANY Composition détergente liquide contenant des tensides nonioniques et ioniques

Cited By (33)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0341071A2 (fr) * 1988-05-06 1989-11-08 Unilever Plc Compositions détergentes
EP0341071A3 (en) * 1988-05-06 1990-07-11 Unilever Plc Detergent compositions
EP0353735A2 (fr) * 1988-08-04 1990-02-07 Kao Corporation Composition détergente
EP0353735A3 (fr) * 1988-08-04 1992-03-18 Kao Corporation Composition détergente
GR890100505A (en) * 1988-08-19 1990-08-22 Colgate Palmolive Co Liqht duty liquid detergent compositions
WO1990002164A1 (fr) * 1988-08-19 1990-03-08 Colgate Palmolive Company Compositions de detergents liquides pour lavages delicats
WO1990005772A3 (fr) * 1988-11-17 1990-11-29 Henkel Kgaa Produit de lavage et de nettoyage comprenant un melange tensio-actif a base d'alkylglycosides et d'agents de surface anioniques
EP0370312A3 (fr) * 1988-11-17 1990-11-14 Henkel Kommanditgesellschaft auf Aktien Agent de lavage et de nettoyage contenant un mélange d'agents tensio-actifs composé d'alkylglycosides et de tensio-actifs anioniques
WO1990005772A2 (fr) * 1988-11-17 1990-05-31 Henkel Kommanditgesellschaft Auf Aktien Produit de lavage et de nettoyage comprenant un melange tensio-actif a base d'alkylglycosides et d'agents de surface anioniques
EP0370312A2 (fr) * 1988-11-17 1990-05-30 Henkel Kommanditgesellschaft auf Aktien Agent de lavage et de nettoyage contenant un mélange d'agents tensio-actifs composé d'alkylglycosides et de tensio-actifs anioniques
EP0403948A1 (fr) * 1989-06-22 1990-12-27 Henkel Kommanditgesellschaft auf Aktien Composition détergente
WO1990015855A1 (fr) * 1989-06-22 1990-12-27 Henkel Kommanditgesellschaft Auf Aktien Produits liquides de lavage
GB2234983A (en) * 1989-07-25 1991-02-20 Kao Corp Liquid detergent composition
GB2234983B (en) * 1989-07-25 1993-01-06 Kao Corp Liquid detergent composition
US5268126A (en) * 1989-08-04 1993-12-07 Huels Aktiengesellschaft Emulsifiers for the preparation of aqueous polysiloxane emulsions and aqueous polysiloxane-paraffin oil emulsions with long shelf lives
EP0418479A1 (fr) * 1989-08-04 1991-03-27 Hüls Aktiengesellschaft Agents émulsifiants pour la préparation d'émulsions aqueuses d'huiles de polysiloxane et/ou de paraffine stables au stockage
WO1991018963A1 (fr) * 1990-06-05 1991-12-12 Henkel Kommanditgesellschaft Auf Aktien Concentre liquide, fluide et pompable d'agents tensio-actifs
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WO1992001772A1 (fr) * 1990-07-23 1992-02-06 Henkel Kommanditgesellschaft Auf Aktien Concentre tensio-actif liquide ayant une bonne fluidite et pompabilite
EP0486786A1 (fr) * 1990-11-17 1992-05-27 Hüls Aktiengesellschaft Détergent liquide moussant
WO1994012601A1 (fr) * 1992-11-26 1994-06-09 Henkel Kommanditgesellschaft Auf Aktien Preparations tensioactives visqueuses aqueuses
DE4409189A1 (de) * 1994-03-17 1995-09-21 Chem Y Tensid-Zusammensetzung, insbesondere zur Verwendung in Körperreinigungsmitteln
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WO1996013567A1 (fr) * 1994-10-28 1996-05-09 Henkel Kommanditgesellschaft Auf Aktien Detergent aqueux pour lavage manuel de la vaisselle
US6090764A (en) * 1994-10-28 2000-07-18 Henkel Kommanditgesellschaft Auf Aktien Water-based manual dishwashing detergents comprising glycerol sulfates
US6555515B1 (en) 1995-12-06 2003-04-29 Henkel Kommanitgesellschaft Auf Aktien Formulations for cleaning hard surfaces based on at least partly branched-chain alkyl oligoglucosides
US8093200B2 (en) 2007-02-15 2012-01-10 Ecolab Usa Inc. Fast dissolving solid detergent
US8309509B2 (en) 2007-02-15 2012-11-13 Ecolab Usa Inc. Fast dissolving solid detergent
US8697625B2 (en) 2007-02-15 2014-04-15 Ecolab Usa Inc. Fast dissolving solid detergent
US10005986B2 (en) 2007-02-15 2018-06-26 Ecolab Usa Inc. Fast dissolving solid detergent
US10577565B2 (en) 2007-02-15 2020-03-03 Ecolab Usa Inc. Fast dissolving solid detergent
US11261406B2 (en) 2007-02-15 2022-03-01 Ecolab Usa Inc. Fast dissolving solid detergent

Also Published As

Publication number Publication date
EP0216301B1 (fr) 1991-08-28
JPS6274999A (ja) 1987-04-06
EP0216301A3 (en) 1988-08-31
US4732704A (en) 1988-03-22
DE3534082C2 (fr) 1988-07-28
ATE66687T1 (de) 1991-09-15
DE3681103D1 (de) 1991-10-02
ES2001985A6 (es) 1988-07-01
DE3534082A1 (de) 1987-04-02

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