EP0172244A1 - Installation de nettoyage des surfaces d'echange thermique des masses d'accumulation d'echangeurs thermiques a regeneration circulante. - Google Patents

Installation de nettoyage des surfaces d'echange thermique des masses d'accumulation d'echangeurs thermiques a regeneration circulante.

Info

Publication number
EP0172244A1
EP0172244A1 EP85901403A EP85901403A EP0172244A1 EP 0172244 A1 EP0172244 A1 EP 0172244A1 EP 85901403 A EP85901403 A EP 85901403A EP 85901403 A EP85901403 A EP 85901403A EP 0172244 A1 EP0172244 A1 EP 0172244A1
Authority
EP
European Patent Office
Prior art keywords
tube
nozzles
heat exchanger
nozzle
cleaning
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
EP85901403A
Other languages
German (de)
English (en)
Other versions
EP0172244B1 (fr
Inventor
Martin Frauenfeld
Georg Goldschmidt
Horst Huber
Karlheinz Mock
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Svenska Rotor Maskiner AB
Original Assignee
Svenska Rotor Maskiner AB
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Svenska Rotor Maskiner AB filed Critical Svenska Rotor Maskiner AB
Publication of EP0172244A1 publication Critical patent/EP0172244A1/fr
Application granted granted Critical
Publication of EP0172244B1 publication Critical patent/EP0172244B1/fr
Expired legal-status Critical Current

Links

Classifications

    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F28HEAT EXCHANGE IN GENERAL
    • F28GCLEANING OF INTERNAL OR EXTERNAL SURFACES OF HEAT-EXCHANGE OR HEAT-TRANSFER CONDUITS, e.g. WATER TUBES OR BOILERS
    • F28G9/00Cleaning by flushing or washing, e.g. with chemical solvents
    • F28G9/005Cleaning by flushing or washing, e.g. with chemical solvents of regenerative heat exchanger
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F28HEAT EXCHANGE IN GENERAL
    • F28GCLEANING OF INTERNAL OR EXTERNAL SURFACES OF HEAT-EXCHANGE OR HEAT-TRANSFER CONDUITS, e.g. WATER TUBES OR BOILERS
    • F28G1/00Non-rotary, e.g. reciprocated, appliances
    • F28G1/16Non-rotary, e.g. reciprocated, appliances using jets of fluid for removing debris
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10STECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S165/00Heat exchange
    • Y10S165/009Heat exchange having a solid heat storage mass for absorbing heat from one fluid and releasing it to another, i.e. regenerator
    • Y10S165/01Cleaning storage mass
    • Y10S165/011Reciprocating cleaner device, e.g. scraper, sprayer

Definitions

  • the invention relates to a device for cleaning the heat-exchanging surfaces of the food masses
  • Regenerative heat exchangers with at least one row next to one another, essentially tangentially aligned and radially displaceable in front of the end face of the storage mass in the interior of the heat exchanger, which guide the cleaning agent supplied to them by a detergent source directed to the storage mass.
  • the high-pressure cleaning nozzles emit sharp, punctiform impinging cleaning jets which, in their entirety, cause the heating surfaces to be impacted and flexing, which means that firmly adhering, poorly water-soluble incrustations and deposits are blasted off and crushed.
  • the high-pressure nozzles designed for higher liquid throughput were connected downstream and preferably likewise arranged in a plane parallel to the high-pressure nozzles.
  • the nozzles are arranged on a carriage which is moved radially above the storage mass face in the cleaning process.
  • the intensive cleaning process requires cleaning to be carried out with the heat exchanger out of operation.
  • injector nozzles for a gas under low to medium pressure or gaseous or vaporous cleaning agent in the direction of the emerging jet of nozzles have also been proposed in such a way that they suck the surrounding heat-looking gaseous medium into the pipe and feed aligned blends mixed with the cleaning agent with a speed profile balanced over the injector cross section to the through-channels between the heat-exchanging surfaces (DE-PS 26 15 433).
  • Superheated steam with a pressure of at least 4 atm and one is preferably used as the blowing medium Temperature of approximately 300 ° C is provided.
  • a series of high-pressure nozzles have already been connected downstream of the injector nozzles or these have been arranged within the injector tubes in the region of their outlet mouth.
  • such a device can be used at different times to use the solution and blowing process on the one hand as regular daily cleaning to remove light soiling, and on the other hand the high-pressure cleaning process alone or combined with the injector nozzles as cleaning at longer intervals to remove heavy soiling .
  • the water jets emitted by the high-pressure nozzles blow off the deposits from the heating surfaces and shred them, while the gaseous or vaporous detergent mixture supplied by the injector nozzles rinses or blows out the blasted, shredded deposits.
  • the device offers the advantage of both operational cleaning and flushing of the heating surfaces, including the air flowing through the heat exchanger or the flue gas as flushing agent, due to the injector effect of the flushing medium supplied to the injector nozzles in the form of superheated steam or compressed air.
  • so-called soot blowers are known for cleaning boiler heating surfaces, in which a pair of nozzles is arranged on a blowing lance, with which a cooling water stream is first applied to the incrustations through the one nozzle and cracks are formed in these incrustations through embrittlement and contraction, whereupon a pulsed high-speed current is sprayed through the other nozzle, which drives water into the cracks formed in the incrustation and, due to the explosive force of the water evaporating in the cracks, causes these incrustations to flake off (DE-OS 32 40 721; DE-OS 32 40 737 ).
  • One nozzle of the pair of nozzles is connected to a coaxial outer tube and the other to an inner tube and the blowing lance is supported on a mechanically moved slide.
  • the nozzles are directed backwards in the direction of the boiler wall, and hose lines are interposed between the room-side fixed connections at the ends of the media lines supplying the water as cleaning medium and the connections provided at the outer end of the moving blowing lance.
  • the connection ends of the hose lines are moved towards and away from one another during the movement of the sootblower, so that the size of their sag changes during their advance inside the boiler from a maximum to a minimum. Up to the permissible minimum radius of the hose line used, a free choice of the starting position for the movement sequence is thus possible, while the end position of the connections moved with the slide only depends on the length of the hose line used.
  • the invention is based on the object of providing a device for reliably cleaning the storage masses of a circulating and regenerative heat exchanger, with which, using small amounts of high-pressure cleaning or washing-up liquid, during of the boiler operation, soiling can be removed, the basic possibility of designing the device being such that it can be used either for flushing in the medium or low pressure range during operation of the heat exchanger and for flushing in the high and low pressure range when the heat exchanger is not in operation can be.
  • this task is solved according to the invention in that the nozzles are provided on at least two nozzle heads arranged at a distance from one another and essentially radially extending over one half of the end face of the storage mass, such that they are sealed in the interior of the heat exchanger guided pipe is radially displaceable back and forth and can be moved back and forth by a drive above the storage mass, the pipe being connected via movable connecting means to at least one fixed media line supplying the cleaning agent, and that the radially inner nozzle head has a smaller number of nozzles, as the next radially outward following nozzle head.
  • the tube carrying the nozzle heads is designed as a double tube which, at least in the region of the sealed introduction into the interior of the heat exchanger, has an inner tube and an outer tube and tube essentially coaxially surrounding the inner tube, the outer tube / the inner tube connecting to separate outer media lines are connected, in which cleaning agents of different or the same type are supplied under different or the same pressure, and the outer and inner tubes are connected on the nozzle head side to separately adapted nozzles.
  • the device thus opens up the possibility of acting separately or together with smaller amounts of liquid cleaning agent under high pressure on the soiled coverings and / or of flushing constantly during operation with a gaseous or vaporous cleaning agent.
  • the nozzle heads each have a distributor connected to the outer tube, essentially at right angles to the tube axis of the storage mass front side, for the cleaning agent supplied in the outer tube of lower pressure and / or greater amount, which on the storage mass side carries one of the assigned nozzles Nozzle plate is complete.
  • the nozzles of the nozzle heads assigned to the cleaning medium supplied via the inner tube are expediently connected to the inner tube via a branch line which is routed outside the wall of the outer tube and the distributor box, it being possible for the nozzle plate of the distributor box to be supplemented by a further nozzle plate, in which one with the Branch pipe-connected cavity for distributing the cleaning agent of higher pressure and / or less amount is formed on the nozzle (s) arranged on the storage mass side on the further nozzle plate.
  • the movable connecting means are expediently formed by flexible connecting lines, that is to say pressure-resistant hoses, connected to the double tube carrying the nozzle heads on the one hand and to the room-side fixed connections of the media lines, which are guided and / or held by supporting means in such a way that their outer end sections run essentially parallel and straight , during which the outer End sections connecting inner middle section is guided on an approximately semicircular arc.
  • the support means can underlie or overlap one of the two outer end sections of the flexible connecting lines, which are approximately parallel and parallel, e.g. in the form of a profiled support rail, which guide the sewing lines of the connecting lines, for example in a vertical plane.
  • the connecting webs connecting the tab elements are expediently designed in such a way that they secure the flexible connecting lines against lateral displacements, which is possible, for example, by arching out or bulging the connecting webs to match the line cross sections.
  • a simplification of the connection of the flexible connecting lines to the double pipe and at the same time a reliable support and guidance of the end of the double pipe located outside the heat exchanger can be achieved in that a box-like collector for the cleaning agent or detergents is switched on between the connecting lines and the outer end of the double pipe is, for example, sliding on runners or on rollers in the longitudinal direction of the double tube back and forth on one
  • Rail is guided and connected to a drive motor via force transmission means, for example a chain, spindle or rack.
  • force transmission means for example a chain, spindle or rack.
  • the motor is permanently attached, while in the case of a rack and pinion drive, the motor is moved with the collector and, for this purpose, its electrical supply lines are expediently included in the routing and support of the flexible connecting lines. Switching the direction of movement in the end positions of the double tube feed can be done using conventional limit switches or the like. respectively.
  • a cantilevered outwardly projecting carrier supported on the jacket of the heat exchanger housing for holding the outer end of the tube, its drive and the movable connecting means, ie the flexible connecting lines.
  • a radially extending support is expediently also arranged inside the regenerative heat exchanger at a distance from the front side of the storage mass, on which the inner portion of the tube carrying the nozzle heads is guided and held in a rolling or sliding manner is.
  • at least one end of the carrier is expediently held in the housing of the regenerative heat exchanger so as to be longitudinally displaceable.
  • Figure 1 is a vertical section through a portion of a regenerative heat exchanger with a fixed housing and circumferential storage mass on the housing, the cleaning device according to the invention is attached.
  • Figure 2 is a partially broken side view of the part of the cleaning device located outside the heat exchanger housing on an enlarged scale.
  • FIG 3 shows a view of a nozzle head of the cleaning device, seen in the direction of the longitudinal central axis of the double pipe;
  • Fig. 4 is a vertical section similar to Fig. 1 through a portion of a regenerative heat exchanger equipped with a cleaning device according to the invention with a fixed storage mass and rotating hoods.
  • the rotating storage mass 1 of the revolving regenerative heat exchanger is enclosed by a housing 3, a part of which is shown with an inlet or outlet nozzle 5 for one of the heat-exchanging gaseous media.
  • a housing socket 5 protrudes - starting from the housing jacket a carrier 7 radially in the direction of the axis of rotation of the revolving regenerative heat exchanger.
  • the carrier 7 is slidably supported on a central guide of the housing 9.
  • the double pipe serves to hold and guide a double tube, sealed from the outside, through the housing jacket of the preheater, with an outer tube 11 and an inner tube 13, which is guided in a sliding or rolling manner on support arms 15 on the support arm 7.
  • the double pipe has two nozzle heads 17, 19.
  • the jacket-side nozzle head 17 is shown as a distributor box for several rinsing nozzles and the nozzle head 19 provided near the axis of rotation of the storage mass as a distributor for a pair of nozzles, ie the 17 nozzle head / is provided with a larger number of nozzles than the nozzle head 19.
  • a further outwardly projecting carrier 31 is attached, which in turn carries the drive of the cleaning device, the outer guides of the double tube 11, 13 and flexible connecting lines of the cleaning device with the cleaning agent supplying media lines 49, 51 including a housing enclosing these flexible connecting lines.
  • the connecting lines each have rectilinear end sections 20, 24 and one the end sections arcuate connecting middle section 22.
  • FIG. 2 shows the part of the cleaning device arranged outside the heat exchanger housing on an enlarged scale compared to the illustration according to FIG. 1.
  • a drive motor 33 is screwed to the carrier 31 and drives a chain 35 which is deflected via a chain wheel held in the bearing 37.
  • a box-shaped collector 39 for the lines supplying the cleaning agent as a carrier of the double pipe is moved back and forth on a rail 41 between two end positions, the contact 43a arranged near the deflecting chain wheel 37 and the one at the other end of the Stroke provided contact 43b can be determined.
  • the collector 39 is provided with rollers 45 which run on the rail 41.
  • the associated flexible connecting line section 24 is connected directly to the inner tube 13, which is passed through the collector 39 for this purpose.
  • the other flexible line section 24 connected via the collector to the annular space between the outer and the inner tube lies therein
  • the above-mentioned housing enclosing the flexible connecting lines has supports 50, 52 formed on the upper and lower sides of profile rails, which overlap or overlap the end sections 20, 24 of the connecting lines.
  • the connecting lines within the housing are guided on both sides by tab elements 100 which are pivotally connected at their ends to one another in a chain-like manner and are each connected in pairs by connecting webs (not shown).
  • FIG. 3 shows the nozzle head 17 seen in the axial direction of the double pipe 11, 13 on an enlarged scale compared to FIG. 1.
  • the outer tube 11 of the double tube opens into a distributor box 60 on the front side of the nozzle head in the illustration, while a section of the outer tube that supplies the detergent to further nozzles is connected to the rear side of the distributor box in the illustration.
  • the outer tube 11 has a removable cover 62 which allows access to its interior.
  • the distribution box 60 is divided into an upper and a lower part via the flanges 64, 66.
  • the lower part 61 widens conically in the direction of a lower nozzle plate 68. In the case shown, this lower nozzle plate 68 carries four nozzles 70, 72, 74, 76. From the jacket of the outer tube 11 leads in the area of the removable cover 62 in front of the
  • Branch line 80 leads out, which leads the cleaning agent supplied via the inner tube to a further nozzle plate 82 which complements the nozzle plate 68 and carries three nozzles 84, 86 and 88.
  • the interior of the nozzle plate 82 is provided with a cavity, via which the branch line 80 is connected to the nozzles.
  • the nozzle heads are arranged with nozzles pointing downward in association with one below the cleaning device
  • an inverted arrangement can also be realized, in which the part of the double pipe, including the nozzle heads, provided inside the housing of the circulating regenerative heat exchanger, instead of hanging on a carrier, is also slidably guided thereon with upwardly directed nozzle heads and nozzles provided thereon perform the cleaning of the storage mass from the lower front.
  • Fig. 4 the cleaning device according to the invention for heat-exchanging surfaces is shown in connection with a type of revolving regenerative heat exchanger, in which the kinematic reversal of the relationships to the heat exchanger shown in Fig. 1
  • Storage mass 201 rests, while in front of its opposite end faces air duct connection 202 circulates one of the heat-exchanging media within the other, resting duct connection 205 connected to the housing.
  • the outside of the storage mass 201 in this 1 is not located on a jacket 3 enclosing the storage mass, but rather on a hub tube running around the hub tube 204 of the storage mass carrier supporting the storage mass 201 and connecting the rotating hoods 202 in front of the opposite end faces of the storage mass 206 supported.
  • the device according to the invention can be used to clean the storage mass both during operation and during downtimes, with the choice of different cleaning methods or flushing media with different pressure levels can be adapted to the special soiling.
  • the device according to the invention is of particular importance for the operational cleaning of circulating regenerative heat exchangers which are used for reheating the clean gases after the raw gas scrubbing. In this case, the system is blown with low pressure and also flushed with high pressure water during operation.

Landscapes

  • Engineering & Computer Science (AREA)
  • Chemical & Material Sciences (AREA)
  • Combustion & Propulsion (AREA)
  • Mechanical Engineering (AREA)
  • General Engineering & Computer Science (AREA)
  • Heat-Exchange Devices With Radiators And Conduit Assemblies (AREA)
  • Cleaning In General (AREA)
  • Pressure Welding/Diffusion-Bonding (AREA)
  • Ultra Sonic Daignosis Equipment (AREA)
  • Soil Working Implements (AREA)
  • Orthopedics, Nursing, And Contraception (AREA)
  • Treatment Of Fiber Materials (AREA)

Abstract

L'installation comporte une série de buses dirigées essentiellement tangentiellement et disposées de manière déplaçable radialement devant le côté frontal de la masse d'accumulation (1) à l'intérieur de l'échangeur thermique, buses qui laissent sortir l'agent de nettoyage amené d'une source d'agent de nettoyage en le dirigeant sur la masse d'accumulation (1). Les buses sont prévues sur au moins deux têtes de buses (19, 17) disposées à un certain écart d'un tuyau (11, 13) s'étendant essentiellement radialement sur une moitié du côté frontal de la masse d'accumulation (1), le tuyau étant amené de manière étanche dans l'espace intérieur de l'échangeur thermique et pouvant effectuer un mouvement de va-et-vient grâce à un entraînement radialement sur la masse d'accumulation (1). Grâce à des liaisons mobiles, le tuyau (11, 13) est raccordé à au moins une conduite extérieure fixe amenant l'agent de nettoyage. La tête de buses radialement intérieure (19) comporte - en raison de la vitesse périphérique de l'échangeur thermique réduite dans cette zone - un nombre de buses inférieur à celui de la tête de buses suivante (17) située radialement vers l'extérieur.
EP85901403A 1984-02-23 1985-02-21 Installation de nettoyage des surfaces d'echange thermique des masses d'accumulation d'echangeurs thermiques a regeneration circulante Expired EP0172244B1 (fr)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DE3406516 1984-02-23
DE3406516A DE3406516A1 (de) 1984-02-23 1984-02-23 Vorrichtung zur reinigung der waermetauschenden flaechen der speichermassen von umlaufenden regenerativ-waermetauschern

Publications (2)

Publication Number Publication Date
EP0172244A1 true EP0172244A1 (fr) 1986-02-26
EP0172244B1 EP0172244B1 (fr) 1987-12-23

Family

ID=6228581

Family Applications (2)

Application Number Title Priority Date Filing Date
EP85101754A Expired EP0153685B1 (fr) 1984-02-23 1985-02-16 Dispositif de nettoyage des surfaces d'échange de chaleur de la masse intermédiaire d'un échangeur de chaleur de régénération
EP85901403A Expired EP0172244B1 (fr) 1984-02-23 1985-02-21 Installation de nettoyage des surfaces d'echange thermique des masses d'accumulation d'echangeurs thermiques a regeneration circulante

Family Applications Before (1)

Application Number Title Priority Date Filing Date
EP85101754A Expired EP0153685B1 (fr) 1984-02-23 1985-02-16 Dispositif de nettoyage des surfaces d'échange de chaleur de la masse intermédiaire d'un échangeur de chaleur de régénération

Country Status (10)

Country Link
US (1) US4649987A (fr)
EP (2) EP0153685B1 (fr)
JP (1) JPH0731033B2 (fr)
AT (1) ATE30771T1 (fr)
DE (1) DE3406516A1 (fr)
DK (1) DK162411C (fr)
ES (1) ES8606630A1 (fr)
FI (1) FI78349C (fr)
PT (1) PT80000B (fr)
WO (1) WO1985003768A1 (fr)

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US4700662A (en) * 1986-06-13 1987-10-20 The Babcock & Wilcox Company Sludge lance wand
US4869738A (en) * 1987-08-26 1989-09-26 W. R. Grace & Co.-Conn. Particulate trap
GB9223679D0 (en) * 1992-11-12 1992-12-23 Clyde Blowers Plc Cleaning apparatus for heat exchange surfaces and an improved nozzle device therefor
GB9224823D0 (en) * 1992-11-26 1993-01-13 Howden Group Plc Ljungstrom heat exchanger
US5261600A (en) * 1992-11-30 1993-11-16 Serv-Tech, Inc. Vertical tube bundle cleaner
DE19510558A1 (de) * 1995-03-23 1996-09-26 Inro Maschinentechnik Gmbh Reinigungsvorrichtung für Wärmetauscherelemente
US6065528A (en) * 1999-08-09 2000-05-23 Abb Air Preheater, Inc. Air preheater cleaner
US7132017B2 (en) * 2002-08-21 2006-11-07 Laurence George M Low-pressure cleaning system using high velocity high volume air
US7017592B2 (en) * 2002-12-10 2006-03-28 Pro-Environmental Inc. Regenerative fume-incinerator with on-line burn-out and wash-down system
DE102004017684B3 (de) * 2004-04-10 2005-06-16 BRÜNDERMANN, Georg Reinigungseinrichtung
US7418997B2 (en) * 2005-12-19 2008-09-02 Caterpillar Inc. Radiator debris removing apparatus and work machine using same
DE102010047589A1 (de) * 2010-10-07 2012-04-12 Techno-Coat Sa Vorrichtung zur Innenbehandlung von Rohren
US9587894B2 (en) * 2014-01-13 2017-03-07 General Electric Technology Gmbh Heat exchanger effluent collector
KR101748802B1 (ko) * 2016-10-18 2017-06-19 주식회사 지스코 수트 블로워 및 이를 이용한 튜브형 열 교환기의 세정 방법
USD930924S1 (en) * 2017-12-13 2021-09-14 Peinemann Equipment B.V. High pressure bundle cleaner
WO2022141015A1 (fr) * 2020-12-29 2022-07-07 苏州西热节能环保技术有限公司 Appareil de soufflage de suie à la vapeur, préchauffeur d'air rotatif et procédé de conception de paramètres de jet de vapeur

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US2766969A (en) * 1952-04-05 1956-10-16 Air Preheater Inter-deck soot blower
US3144900A (en) * 1961-05-29 1964-08-18 Combustion Eng Retractable cleaner for rotary regenerative heat exchanger
DE2514173C3 (de) * 1975-04-01 1980-03-20 Kraftanlagen Ag, 6900 Heidelberg Vorrichtung zur Reinigung der wärmetauschenden Flächen der Speichermassen von umlaufenden Regenerativ-Wärmetauschern
DE2615433C2 (de) * 1976-04-09 1982-08-12 Kraftanlagen Ag, 6900 Heidelberg Vorrichtung zur Reinigung der wärmetauschenden Flächen der Speichermassen von umlaufenden Regenerativ-Wärmetauschern
IT1069399B (it) * 1976-12-23 1985-03-25 Autelli Giulio Lancia multipla pluriugelli per il lavaggio di scambiatori di calore rotanti e distributore per dette lance
JPS607200B2 (ja) * 1977-05-06 1985-02-22 スベンスカ・ロ−トル・マスキナ−・アクチ−ボラグ 回転蓄熱式熱交換器の熱伝達板の熱交換面を清掃する方法及び装置
US4141754A (en) * 1977-05-10 1979-02-27 Svenska Rotor Maskiner Aktiebolag Apparatus and method for cleaning the heat exchanging surfaces of the heat transfer plates of a rotary regenerative heat exchanger
JPS5782698A (en) * 1980-11-10 1982-05-24 Gadelius Kk Soot sweeping device for rotary recovery type heat exchanger
US4422882A (en) * 1981-12-29 1983-12-27 The Babcock & Wilcox Company Pulsed liquid jet-type cleaning of highly heated surfaces
CA1172244A (fr) * 1981-12-29 1984-08-07 Charles W. Hammond Methode et dispositif de decrassage de surfaces soumises a des temperatures tres elevees

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Also Published As

Publication number Publication date
FI850551A0 (fi) 1985-02-11
EP0172244B1 (fr) 1987-12-23
WO1985003768A1 (fr) 1985-08-29
FI78349C (fi) 1989-07-10
ES8606630A1 (es) 1986-04-16
DK162411C (da) 1992-03-16
DK82085D0 (da) 1985-02-22
DE3406516C2 (fr) 1992-03-19
EP0153685A1 (fr) 1985-09-04
DK162411B (da) 1991-10-21
DK82085A (da) 1985-08-24
JPS61501280A (ja) 1986-06-26
JPH0731033B2 (ja) 1995-04-10
ES540656A0 (es) 1986-04-16
FI78349B (fi) 1989-03-31
FI850551L (fi) 1985-08-24
EP0153685B1 (fr) 1987-11-11
DE3406516A1 (de) 1985-08-29
ATE30771T1 (de) 1987-11-15
US4649987A (en) 1987-03-17
PT80000B (pt) 1987-05-29
PT80000A (de) 1985-03-01

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