EP0150872B2 - Flüssige, organo-funktionelle Polysiloxane enthaltende Detergenszusammensetzungen - Google Patents

Flüssige, organo-funktionelle Polysiloxane enthaltende Detergenszusammensetzungen Download PDF

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Publication number
EP0150872B2
EP0150872B2 EP85200027A EP85200027A EP0150872B2 EP 0150872 B2 EP0150872 B2 EP 0150872B2 EP 85200027 A EP85200027 A EP 85200027A EP 85200027 A EP85200027 A EP 85200027A EP 0150872 B2 EP0150872 B2 EP 0150872B2
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Prior art keywords
alkyl
siloxane
polydimethylsiloxane
composition
anionic
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French (fr)
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EP0150872A1 (de
EP0150872B1 (de
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Christian Roland Barrat
Alfred Busch
Kosmas Sardelis
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Procter and Gamble European Technical Center
Procter and Gamble Co
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Procter and Gamble European Technical Center
Procter and Gamble Co
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    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16Organic compounds
    • C11D3/37Polymers
    • C11D3/3703Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • C11D3/373Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds containing silicones
    • C11D3/3742Nitrogen containing silicones
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16Organic compounds
    • C11D3/37Polymers
    • C11D3/3703Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • C11D3/373Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds containing silicones

Definitions

  • compositions herein comprise conventional ingredients inclusive of surface-active agents, liquid carrier and optional ingredients such as detergent builders, enzymes and side regulants and low levels of organo-functional polydi-short alkylsiloxanes.
  • the latter ingredient unexpectedly provides desirable through-the-wash textile benefits inclusive of softness.
  • the preferred siloxanes embrace amino derivatives.
  • the essential siloxanes are further characterized by a degree of substitution in the range from 0.01-0.7.
  • liquid compositions herein can be divided arbitrarily in (mostly P-)-built compositions and in substantially unbuilt compositions. Both kinds of compositions will procure textile handling benefits. Selective preference can originate from the combined use of anionic surface-active agents in combination with the subject siloxanes.
  • silicones/polydialkylsiloxanes are crowded and diverse.
  • the like siloxanes have, for example, found widespread commercial application in a detergent suds regulant functionality.
  • Silicone polymers have also found widespread application in the textile industry to provide fiber properties inclusive of softness, water proofing and easy ironing. To that effect the silicone polymers are applied (in the textile industry) to the fabrics during manufacture or during make-up of clothing, in the form of relatively concentrated dispersions or solutions either by padding or spray-on. Often, especially for long lasting softness, water proofing treatment or other benefits, mixtures or organofunctional polydialkylsiloxanes are used. The fabrics are subsequently treated with catalysts or heated to cause crosslinking of setting of the silicone polymers.
  • German Patent 27 54 704 discloses a treating agent consisting of a polydimethylsiloxane containing dia- minoalkyl groups for providing softness to natural and synthetic fabrics.
  • Japanese Patent 79,131,096 pertains to a treating agent consisting of a mixture of polydimethylsiloxane with NHR-groups and a polydimethylsiloxane with hydroxy groups, for providing softness to acrylics.
  • the fabrics are spray coated and then heated for curing.
  • German Patent 20 16 095 uses polydimethylsiloxane containing pendant epoxy groups for providing softness and smoothness to synthetic organic fabrics.
  • US Patent 4,247,592 discloses a treating agent consisting of a polydimethylsiloxane containing diami- noalkyl groups in providing softness to fire retardant synthetic textile.
  • the treating agent is applied by brushing, rinsing, padding, dipping and spraying, and is then durably affixed to the textile by heating.
  • European Patent 058 493 relates to a treating agent mixture of an organo polysiloxane containing diami- noalkyl and polyoxyalkylene groups, with an organopolysiloxane containing carboxylic acid ester groups orwith an organopolysiloxane containing epoxy and polyalkylene groups.
  • the mixture is added by spray-on and treated for curing. It is said to provide softness, anti-wrinklig and long lasting electrostatic prevention benefits.
  • German Patent application DOS. 26.31.419 relates to fabric rinse softening compositions containing a fabric-substantive cationic component and a polydimethylsiloxane possibly amino substituted. The mixture is applied as an aqueous dispersion.
  • This invention is based on the discovery that liquid detergent compositions capable of simultaneously providing fibre-cleaning and textile handling benefits, inclusive of softness, can now be formulated containing a binary component systems and an organo-functional siloxane.
  • compositions herein comprise:
  • substituted siloxanes are incorporated in liquid detergent compositions containing inorganic builder salts such as (poly)-phosphates.
  • the siloxanes are incorporated in concentrated liquid compositions which are substantially free of builders.
  • the invention herein broadly relates to liquid detergent compositions comprising a surface-active agent, a liquid carrier, an organo-functional polydi-alkylsiloxane textile treatment agent, and, if desirable, conventional detergent additives.
  • a first essential component for use in the compositions of this invention is represented by a surface-active agent selected from the group of anionic, nonionic, amphoteric (ampholytic) and zwitterionic surface-active agents and mixtures thereof, said surface-active agent comprising an anionic surface-active agent
  • nonionic surface-active agent is meant to include semi-polar nonionic surfactants.
  • non-ionic surfactants examples include E.P.A. 0.028.865 page 4, line 23 to page 5, line 10 and page 8 line 14 to page 9, line 4.
  • Adisclosure of zwitterionic and ampholytic surfactants for use herein can also be found in E.P.A. 0.028.865 page 7, line 21 to page 8, line 13.
  • anionic surfactants for use herein can be represented by known synthetic and natural anionic surface-active agent which are known to be suitable for use in detergents and frequently have found commercial application. Suitable synthetic anionic surfactants are described in E.P.A. 0.028.865 page 5, line 12 to line 31.
  • natural anionic surface-active agents for use in this invention can be represented by saturated and unsaturated fatty acids having from 10 to 20 carbon atoms in the alkyl chain or the alkalimetal, earth-alkali- metal and amine or alkanolamine soaps thereof. Preferred fatty acids/soaps have from 12 to 18 carbon atoms in the alkyl chain.
  • fatty acids/soaps suitable for use herein are natural coconut fatty acid containing a majority of C 12 and C 14 acids and tallow fatty acids containing a mixture of saturated and unsaturated C 16 and C 18 -fatty acids/soaps.
  • the surface-active agent is used generally at levels from 5% to 70%. While th surface-active agent may be varied over the broad range depending upon the intended utility of the composition and the quantitative and qualitative definition of the additional ingredients and possibly optional components, two preferred executions can be formulated depending upon the presence of (poly)-phosphate builders.
  • liquid compositions are envisaged which are substantially unbuilt.
  • the surface active agents are frequently used in an amount from 25% to 55% and are represented by a mixture of anionic and nonionic surface-active agents, more preferably in a weight ratio of anionic to nonionic in the range from 4:1 to 1:4.
  • liquid built detergent compositions are contemplated containing from 5% to 25%, preferably from 5% to 15% surface-active agent.
  • the latter ingredient can preferably be represented by a mixture of anionic and nonionic surface-active agents whereby the anionic species represents at least 20% of the sum of anionic and nonionic surface-active agents, an at least 3%, calculated on the detergent composition.
  • the like detergent compositions frequently comprise from 5% to 30%, preferably from 12% to 25% of a detergent builder which can be represented by conventional detergent builders many of which have already found commercial application.
  • a detergent builder which can be represented by conventional detergent builders many of which have already found commercial application.
  • suitable builders include the alkali, often sodium, metal salts of (poly)phosphates, e.g. tripolyphosphoric acid, nitrilotriacetic acid (NTA), citric acid and crystalline, completely hydrated, synthetically prepared zeolite builders having a particle diameter in the range from 0.1 to 10, preferably from 0.1 to 4 micrometers.
  • Suitable zeolite builders are ZEOLITE A, X and P (registered trade marks). Mixtures of detergent builders can also be used.
  • compositions herein can additionally contain, as an optional ingredient, a cationic surfactant.
  • a cationic surfactant Suitable cationic surfactant species for use herein are described in European Patent application 0.028.865, page 5, line 32 to page 7 line 21, this passage being incorporated herein by referene.
  • the cationic surfactants can provide and/or enhance a broad range of textile treatment benefits inclusive of cleaning, feel, and bactericidal advantages.
  • These optional cationic surface-active agents are used in additive levels, such as in levels not exceeding 10% of the cumulative amount of anionic and nonionic surfactants defined hereinbefore, and more preferred in a range from 1% to 5% of the detergent composition.
  • compositions herein contain as a further essential component a liquid carrier, possibly a mixture of liquid carriers.
  • the liquid carrier component can be represented by water and conventional liquid organic carriers.
  • Non-limiting examples of the like organic carriers include lower aliphatic alcohol having from 2 to about 6 carbon atoms and 1 to 3 hydroxyl groups; ethers of diethylene glycol and lower aliphatic mono-alcohols having from 1 to 4 carbon atoms and mixtures thereof.
  • liquid carriers are: ethanol; n-propanol; isopropanol; butanol; 1,2-propanediol; 1,3-propanediol; n-hexanol; monomethyl-, -ethyl-, -propyl, and mono-butyl ethers and di-ethylene glycol.
  • Other organic solvents having a relatively high boiling point and low vapor pressure can also be used, provided they do not react with any of the other ingredients present.
  • the relative quantities of liquid carriers needed to insure the liquid state of the composition can vary depending upon the qualitative and quantitative ingredient parameters in a given composition. However, the adequate choice of the carrier is based on routine determinations well-known in the art.
  • the essential organo-functional siloxane for use herein can be present in levels from 0.05% to 5%, preferably from 0.1%-3%, and most preferably from 0.15%-1%. Using levels below 0.05% will not anymore produce, to any noticeable extent, the claimed benefits whereas the incorporation of levels exceeding 5% will not produce additional benefits commensurate with (proportional to) the level increase.
  • the siloxane component is preferably represented by amino-functional polydialkylsiloxanes which are frequently used in levels from 01 % to 3%, more preferably from 0.15-1.0%.
  • the degree of substitution of preferred siloxanes can be expressed as the molar (moiety) proportion of non-terminal silicones carrying a substituent other than a C 1-4 alkyl group to total non-terminal silicones.
  • the numerical value or the degree of substitution of preferred siloxanes lies in the range from 0.01 to 0.7; preferably from 0.02 to 0.3. While non-terminal substitution is preferred for enhanced through-the-wash fiber substantivity, it is understood that siloxanes with substituted terminal silicone atoms can also be used.
  • n 3 or 4
  • X and Y are, selected independently, hydrogen, - C1-4-alkyl; -C 5-6 -cycloalkyl and -C 2-4 -NH 2 -
  • Preferred organofunctional polydimethyl siloxanes include aminofunctional siloxanes such as:
  • the organofunctional siloxanes have a viscosity in the range from 250 mm 2 /s to 100.000 mm 2 /s, preferably from 250 mm 2 /s to 2000 mm 2 /s.
  • the viscosity of the siloxane is measured on the pure raw material at 25°C with the aid of a BROOKFIELD@ viscometer (LV Digital).
  • the organofunctional polydimethyl siloxanes in addition to the essential substituents defined hereinbefore, can contain polyalkylene oxide chains attached to unsubstituted silicone atoms (in the meaning of this invention).
  • the polyalkylene, such as propylene or ethylene, oxide chains are attached to the silicone atoms instead of a C 1-4 alkyl group.
  • the alkoxylation enhances the hydrophilic and antistatic (charge-reducing) properties of the component in relation to the textiles.
  • compositions herein can contain a series of optional detergent ingredients with a view to improve the composition taking into consideration the specific utilization.
  • optional components can be presented by virtually all substances, which are known to suitable for use in the like composition, for their known functionality in the art established levels.
  • the non-built or built compositions of the invention can contain, in addition to the detergent builder, other types of sequestrants, having precipitation inhibitor or anti-incrustation properties, in varying levels e.g. in an amount from 0.2% to 5%.
  • Such further sequestrants can be water-soluble copolymeric ingredients e.g.: polyacrylates, polymaleates and copolymeric carboxylates including those obtained from the copolymerization of unsaturated polyacids such a maleic or citraconic acid with suitable polymerizable reaction partners such as methacrylic acid, acrylic acid, mesaconic acid and methyl-vinyl-ether. Mixture of the like watersoluble detergent sequestrant can also be used.
  • detergent enzymes such as proteases, amylases, lipases and mixtures thereof, and stablizing agents for the like enzymes, soil suspending agents such as sodium carboxymethylcellulose and polyvinylpyrrolidone, suds regulants, such as C 16-22 fatty acids and methylated polysiloxanes, especially dimethylpolysiloxane, said silicone being used preferably at levels from 0.01 % to 0.4%.
  • Hydrotropes can also be used and are frequently desirable in built compositions.
  • hydrotropes examples include the water-soluble alkylaryl sulfonates having up to 3 carbon atoms in an alkyl group such as sodium, potassium, ammonium, and ethanol amine salts of xylene-, toluene-, ethylbenzene- and isopropyl benzene sulfonic acids.
  • the subject compositions further can comprise brighteners, perfumes, dyes, bactericidal agents, antioxidants, opacifiers, photoactivators, fillers and the like.
  • liquid detergent compositions were prepared by mixing, in a conventional manner, the following ingredients in the stated proportions; the aminofunctional polysiloxane was admixed directly in liquid composition under agitation.
  • compositions of examples I and B were compared for through-the-wash softness versus identical compositions A and B which did not contain the aminofunctional polydimethylsiloxane.
  • the testing conditions were as follows:
  • compositions in accordance with the invention are as follows:

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Claims (15)

1. Flüssige Detergenszusammensetzung, fähig zum Schaffen wünschenswerter Gewebevorteile einschließlich der Weichheit, enthaltend:
(a) von 5 Gew.-% bis 70 Gew.-% eines grenzflächenaktiven Mittels, ausgewählt aus der Gruppe von anionischen, nichtionischen, amphoteren und zwitterionischen grenzflächenaktiven Mitteln und Gemischen hievon, welches grenzflächenaktive Mittel ein anionisches grenzflächenaktives Mittel umfaßt;
(b) einen flüssigen Träger; und
(c) gewünschtenfalls herkömmliche Detergenszusätze einschließlich Detergensgerüststoffen, Enzymen und Schaumregulatoren,

dadurch gekennzeichnet, daß sie:
(d) von 0,05 Gew.-% bis 5 Gew.-% eines organo-funktionellen Poly-di-C1-4-alkylsiloxan-Gewebebehandlungsmittels der allgemeinen Formel:
Figure imgb0028
enthält, worin R für C1-4-Alkyl steht; n eine ganze Zahl von 1 bis 6 ist; Z für
Figure imgb0029
steht, worin X und Y voneinander unabhängig unter -H; -C1-30-Alkyl; -C6-Aryl; -C5-6-Cycloalkyl; -C1-6-Alkylen-NH2; -CO-R ausgewählt sind, oder Z so ist, daß das Siloxangewebebehandlungsmittel ein (4-Carboxy-5-(N-talgamid)pentyl-1)-polydimethylsiloxan ist; mit der Maßgabe, daß der Stickstoff quaternisiert sein kann, um
Figure imgb0030
zu entsprechen, worin W unter X oder Y ausgewählt sein kann; oder Z für
Figure imgb0031
steht, worin P und M -COOH; -CO-NR'2; oder-CO-OR' sind, worin R' für Wasserstoff oder C1-2-Alkyl steht; mit der weiteren Maßgabe, daß der Substitutionsgrad, d.h. das molare Verhältnis der Siliciumatome, welche einen anderen Substituenten als eine C1-4-Alkylgruppe tragen, zur Gesamtzahl an Siliciumatomen im Bereich von 0,01 bis 0,7 liegt, welche Siloxane eine Viskosität (25° C) von 250 - 100.000 mm2/s besitzen.
2. Zusammensetzung nach Anspruch 1, worin das Siloxan Amino-substituiert ist.
3. Zusammensetzung nach Anspruch 1, worin das Siloxan einen Substitutionsgrad im Bereich von 0,02 bis 0,3 besitzt.
4. Gerüststofffreie, flüssige Detergenszusammensetzung, fähig zum Schaffen wünschenswerter Gewebevorteile einschließlich der Weichheit, enthaltend:
(a) von 25 Gew.-% bis 55 Gew.-% eines grenzflächenaktiven Mittels, ausgewählt aus der Gruppe von anionischen, nichtionischen, amphoteren und zwitterionischen grenzflächenaktiven Mitteln und Gemischen hievon, welches grenzflächenaktive Mittel ein anionisches grenzflächenaktives Mittel umfaßt;
(b) einen flüssigen Träger;
(c) gewünschtenfalls herkömmliche Detergenszusätze einschließlich Enzymen und Schaumregulatoren,

dadurch gekennzeichnet, daß sie:
(d) von 0,05 Gew.-% bis 5 Gew.-% eines organo-funktionellen Polydi-C1-4-alkylsiloxan-Gewebebehandlungsmittels der allgemeinen Formel:
Figure imgb0032
enthält, worin R für C1-4-Alkyl steht; n eine ganze Zahl von 1 bis 6 ist; Z für
Figure imgb0033
steht, worin X und Y voneinander unabhängig unter -H; -C1-30-Alkyl; -C6-Aryl; -C5-6-Cycloalkyl; -C1-6-Alkylen-NH2; -CO-R ausgewählt sind, oder Z so ist, daß das Siloxangewebebehandlungsmittel ein (4-Carboxy-5-(N-talgamid)pentyl-1)-polydimethylsiloxan ist; mit der Maßgabe, daß der Stickstoff quaternisiert sein kann, um
Figure imgb0034
zu entsprechen, worin W unter X oder Y ausgewählt sein kann; oder Z für
Figure imgb0035
steht, worin P und M -COOH; -CO-NR'2; oder-CO-OR' sind, worin R' für Wasserstoff oder C1-2-Alkyl steht; mit der weiteren Maßgabe, daß der Substitutionsgrad, d.h. das molare Verhältnis der Siliciumatome, welche einen anderen Substituenten als eine C1-4-Alkylgruppe tragen, zur Gesamtzahl an Siliciumatomen im Bereich von 0,01 bis 0,7 liegt, welche Siloxane eine Viskosität (25° C) von 250 - 100.000 mm2/s besitzen.
5. Zusammensetzung nach Anspruch 4, worin das grenzflächenaktive Mittel durch ein Gemisch aus anionischen und nichtionischen grenzflächenaktiven Mitteln in einem Gewichtsverhältnis von anionischem zu nichtionischem grenzflächenaktivem Mittel im Bereich von 4:1 bis 1:4 gebildet wird.
6. Zusammensetzung nach Anspruch 4, worin das Siloxan Amino-substituiert ist.
7. Zusammensetzung nach Anspruch 4, worin das Siloxan einen Substitutionsgrad im Bereich von 0,02 bis 0,3 besitzt.
8. Zusammensetzung nach Anspruch 4, worin das Siloxan wie folgt gekennzeichnet ist: n ist 3 oder 4 und X und Y sind unabhängig voneinander unter: Wasserstoff; -C1-4-Alkyl; -C5-6-Cycloalkyl; und -C2H4-NH2 ausgewählt.
9. Zusammensetzung nach Anspruch 4 und 5, worin die Siloxankomponente unter:
- (N-Cyclohexylamino-4-amino-butyl-1)-polydimethylsiloxan;
- [N-(2-Amino-ethylen)-4-amino-butyl-1]-polydimethylsiloxan;
- (N-Dodecyl-4-amino-butyl-1)-polydimethylsiloxan;
- (4-(N,N-Dimethylammonium)-butyl-1)-polydimethylsiloxan;
- (5-(Talgamid)-4-carboxy-pentyl-1)-polydimethylsiloxan

ausgewählt ist.
10. Gerüststoff enthaltende, flüssige Detergenszusammensetzung, fähig zum Schaffen wünschenswerter Gewebevorteile einschließlich der Weichheit, enthaltend:
(a) von 5 Gew.-% bis 25 Gew.-% eines grenzflächenaktiven Mittels, ausgewählt aus der Gruppe von anionischen, nichtionischen, amphoteren und zwitterionischen grenzflächenaktiven Mitteln und Gemischen hievon, welches grenzflächenaktive Mittel ein anionisches grenzflächenaktives Mittel umfaßt;
(b) einen flüssigen Träger;
(c) von 5 Gew.-% bis 30 Gew. -% eines Detergensgerüststoffes;
(d) gewünschtenfalls herkömmliche Detergenszusätze einschlließlich Enzymen und Schaumregulatoren,

dadurch gekennzeichnet, daß sie:
(e) von 0,05 Gew.-% bis 5 Gew.-% eines organo-funktionellen Polydi-C1-4-alkylsiloxan-Gewebebehandlungsmittels der allgemeinen Formel:
Figure imgb0036
enthält, worin R für C1-4-Alkyl steht; n eine ganze Zahl von 1 bis 6 ist; Z für
Figure imgb0037
steht, worin X und Y voneinander unabhängig unter -H; -C1-30-Alkyl; -C6-Aryl; -C5-6-Cycloalkyl; -C1-6-Alkylen-NH2; -CO-R ausgewählt sind, oder Z so ist, daß das Siloxangewebebehandlungsmittel ein (4-Carboxy-5-(N-talgamid)pentyl-1)-polydimethylsiloxan ist; mit der Maßgabe, daß der Stickstoff quaternisiert sein kann, um
Figure imgb0038
zu entsprechen, worin W unter X oder Y ausgewählt sein kann; oder Z für
Figure imgb0039
steht, worin P und M -COOH; -CO-NR'2; oder-CO-OR' sind, worin R' für Wasserstoff oder C1-2-Alkyl steht; mit der weiteren Maßgabe, daß der Substitutionsgrad, d.h. das molare Verhältnis der Siliciumatome, welche einen anderen Substituenten als eine C1-4-Alkylgruppe tragen, zur Gesamtzahl an Siliciumatomen im Bereich von 0,01 bis 0,7 liegt, welche Siloxane eine Viskosität (25° C) von 250 - 100.000 mm2/s besitzen.
11. Zusammensetzung nach Anspruch 10, worin das grenzflächenaktive Mittel, welches 5 Gew.-% bis 15 Gew.-% darstellt, durch ein Gemisch aus anionischen und nichtionischen grenzflächenaktiven Mitteln gebildet wird, wodurch die anionische Spezies mindestens 20 % (Gewichtsprozent) der Summe aus anionischen und nichtionischen grenzflächenaktiven Mitteln bildet.
12. Zusammensetzung nach Anspruch 10, worin das Siloxan Amino-substituiert ist.
13. Zusammensetzung nach Anspruch 10, worin der Detergensgerüststoffvon 12 Gew.-% bis 25 Gew.-% darstellt und unter den Alkalimetallsalzen von Polyphosphorsäure, Citronensäure und Nitrilotriessigsäure und ZEOLITH A, X und P mit einem Teilchendurchmesser im Bereich von 0,1 bis 4 µm ausgewählt ist.
14. Zusammensetzung nach Anspruch 10, worin das Siloxan wie folgt gekennzeichnet ist: n ist 3 oder 4 und X und Y sind unabhängig voneinander unter: Wasserstoff; -C1-4-Alkyl; -C5-6-Cycloalkyl; und -C2H4-NH2 ausgewählt.
15. Zusammensetzung nach Anspruch 13, worin das Siloxan unter:
- (N-Cyclohexylamino-4-amino-butyl-1)-polydimethylsiloxan;
- [N-(2-Amino-ethylen)-4-amino-butyl-1]-polydimethylsiloxan;
- (N-Dodecyl-4-amino-butyl-1)-polydimethylsiloxan;
- (4-(N,N-Dimethylammonium)-butyl-1)-polydimethylsiloxan;
- (5-(Talgamid)-4-carboxy-pentyl-1)-polydimethylsiloxan

ausgewählt ist.
EP85200027A 1984-01-25 1985-01-15 Flüssige, organo-funktionelle Polysiloxane enthaltende Detergenszusammensetzungen Expired - Lifetime EP0150872B2 (de)

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GB848401875A GB8401875D0 (en) 1984-01-25 1984-01-25 Liquid detergent compositions
GB8401875 1984-01-25

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EP0150872B1 EP0150872B1 (de) 1990-04-11
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JP (1) JPH0657839B2 (de)
AT (1) ATE51892T1 (de)
CA (1) CA1232412A (de)
DE (1) DE3577107D1 (de)
GB (1) GB8401875D0 (de)
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US11624156B2 (en) 2013-12-09 2023-04-11 The Procter & Gamble Company Fibrous structures including an active agent and having a graphic printed thereon

Families Citing this family (136)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0189225A2 (de) * 1985-01-22 1986-07-30 The Procter & Gamble Company Verstärktes flüssiges Reinigungsmittel, das anionische, ethoxilierte nichtionische und amidhaltige oberflächenaktive Verbindungen enthält
US4810253A (en) * 1985-04-01 1989-03-07 Dow Corning Corporation Method of improving the draining of water from textiles during a laundering operation
US4848981A (en) * 1985-11-25 1989-07-18 Dow Corning Corp. Method of improving the draining of water from textiles during a laundering operation
US4853319A (en) * 1986-12-22 1989-08-01 Eastman Kodak Company Photographic silver halide element and process
GB2200365A (en) * 1987-01-26 1988-08-03 Goodjet Ltd Detergent composition
GB8710889D0 (en) * 1987-05-08 1987-06-10 Dow Corning Ltd Removal of water haze from distillate fuel
JP2649061B2 (ja) * 1988-05-26 1997-09-03 東レ・ダウコーニング・シリコーン株式会社 繊維用処理剤
DE4026029A1 (de) * 1989-09-07 1992-02-20 Sandoz Ag Waessrige aminopolysiloxanmikroemulsionen, deren herstellung und verwendung
DE3929757A1 (de) * 1989-09-07 1991-03-14 Sandoz Ag Waessrige aminopolysiloxanmikroemulsionen, deren herstellung und verwendung
JPH03115498A (ja) * 1989-09-29 1991-05-16 Kao Corp 洗浄剤組成物
GB8922595D0 (en) * 1989-10-06 1989-11-22 Unilever Plc Fabric treatment composition with softening properties
FR2652818B1 (fr) * 1989-10-09 1994-04-01 Rhone Poulenc Chimie Suspension de zeolite comprenant une resine silicone.
JPH06102797B2 (ja) * 1990-01-10 1994-12-14 花王株式会社 洗浄剤組成物
JPH06102796B2 (ja) * 1990-01-10 1994-12-14 花王株式会社 衣料用液体洗浄剤組成物
US5026489A (en) * 1990-04-04 1991-06-25 Dow Corning Corporation Softening compositions including alkanolamino functional siloxanes
JPH05508889A (ja) * 1990-07-23 1993-12-09 ザ、プロクター、エンド、ギャンブル、カンパニー ミクロ乳化アミノシランを含有する液体布帛柔軟剤
EP0693549A1 (de) 1994-07-19 1996-01-24 The Procter & Gamble Company Feste Bleichaktivatorzusammensetzungen
EP0778342A1 (de) 1995-12-06 1997-06-11 The Procter & Gamble Company Waschmittelzusammensetzungen
AU5725996A (en) 1996-05-03 1997-11-26 Procter & Gamble Company, The Detergent compositions comprising polyamine polymers with improved soil dispersancy
US6040288A (en) * 1997-02-21 2000-03-21 Rhodia Inc. Fabric color protection compositions and methods
MXPA02003223A (es) 1999-09-27 2002-09-30 Procter & Gamble Composiciones limpiadoras de superficies duras, panos prehumedecidos, metodos de uso y articulos que comprenden tales composiciones o panos e instrucciones de uso que resultan en un limpiado y mantenimiento mas faciles, una apariencia de superficie y
BR0014502A (pt) 1999-10-05 2002-06-11 Ciba Sc Holding Ag Composições amaciantes de tecidos
ATE307186T1 (de) * 1999-10-05 2005-11-15 Ciba Sc Holding Ag Verwendung von wäscheeichmacherzusammensetzungen
WO2001025382A1 (en) * 1999-10-05 2001-04-12 Ciba Speciality Chemicals Holding Inc. Fabric softener compositions
US6949503B2 (en) 1999-10-05 2005-09-27 Ciba Specialty Chemicals Corporation Fabric softener compositions
DE60022528T2 (de) 1999-10-05 2006-06-29 Ciba Speciality Chemicals Holding Inc. Verwendung von wäscheweichmacherzusammensetzungen
MXPA02003466A (es) * 1999-10-05 2002-08-20 Ciba Sc Holding Ag Composiciones suavizantes de telas.
AU7421900A (en) * 1999-10-05 2001-05-10 Ciba Specialty Chemicals Holding Inc. Fabric softener compositions
US6566320B1 (en) 1999-10-19 2003-05-20 The Procter & Gamble Company Bleaching composition containing chromotropic compound
ATE284942T1 (de) * 2002-09-05 2005-01-15 Procter & Gamble Strukturierte flüssige weichmacherzusammensetzungen
DE602004009406T2 (de) 2003-01-29 2008-02-07 Unilever N.V. Waschmittel
US7326677B2 (en) 2003-07-11 2008-02-05 The Procter & Gamble Company Liquid laundry detergent compositions comprising a silicone blend of non-functionalized and amino-functionalized silicone polymers
US7326676B2 (en) 2003-07-11 2008-02-05 The Procter & Gamble Company Liquid laundry detergent compositions with silicone fabric care agents
MXPA06011879A (es) * 2004-04-16 2006-12-14 Procter & Gamble Composiciones detergentes liquidas para lavanderia con mezclas de siliconas como agentes para el cuidado de las telas.
EP1749879A1 (de) 2005-08-05 2007-02-07 The Procter & Gamble Company Zusammensetzung zum Waschen oder Behandeln von Wäsche und Herstellungsverfahren
ATE395401T1 (de) 2005-08-05 2008-05-15 Procter & Gamble Teilchenförmige textilbehandlungsmittelzusammensetzung enthaltend silikone, schichtsilikate und anionische tenside
CA2629687A1 (en) 2005-11-17 2007-05-24 The Procter & Gamble Company Use and application of defined zwitterionic copolymer
EP2083065A1 (de) 2008-01-22 2009-07-29 The Procter and Gamble Company Farbpflegezusammensetzung
WO2011017406A1 (en) 2009-08-06 2011-02-10 Arkema Inc. Liquid cleaning compositions
US8933131B2 (en) 2010-01-12 2015-01-13 The Procter & Gamble Company Intermediates and surfactants useful in household cleaning and personal care compositions, and methods of making the same
EP2569406A4 (de) 2010-05-14 2013-11-13 Sun Products Corp Polymerhaltige reinigungszusammensetzungen und verfahren zu ihrer herstellung und verwendung
JP5770280B2 (ja) 2010-07-02 2015-08-26 ザ プロクター アンド ギャンブルカンパニー 非香料系活性剤を含むフィラメントの不織布ウェブ及びその作製方法
RU2555042C2 (ru) 2010-07-02 2015-07-10 Дзе Проктер Энд Гэмбл Компани Способ доставки активнодействующего вещества
MX345026B (es) 2010-07-02 2017-01-12 Procter & Gamble Material de trama y método para su elaboración.
HUE030120T2 (en) 2010-07-02 2017-04-28 Procter & Gamble Procedure for forming a film from a non-woven web
WO2012003319A2 (en) 2010-07-02 2012-01-05 The Procter & Gamble Company Filaments comprising an active agent nonwoven webs and methods for making same
US8628760B2 (en) 2010-07-15 2014-01-14 The Procter & Gamble Company Personal care composition comprising a near-terminal branched compound
US20120172281A1 (en) 2010-07-15 2012-07-05 Jeffrey John Scheibel Detergent compositions comprising microbially produced fatty alcohols and derivatives thereof
WO2012052349A1 (en) 2010-10-22 2012-04-26 Unilever Plc Improvements relating to fabric conditioners
EP2705145B1 (de) 2011-05-05 2020-06-17 The Procter and Gamble Company Zusammensetzungen und verfahren mit serinproteasevarianten
EP2705146B1 (de) 2011-05-05 2018-11-07 Danisco US Inc. Zusammensetzungen und verfahren mit serinproteasevarianten
US20140371435A9 (en) 2011-06-03 2014-12-18 Eduardo Torres Laundry Care Compositions Containing Thiophene Azo Dyes
US20140141126A1 (en) 2011-06-29 2014-05-22 Solae Llc Baked food compositions comprising soy whey proteins that have been isolated from processing streams
WO2013029904A1 (en) 2011-09-01 2013-03-07 Unilever Plc Improvements relating to fabric conditioners
JP5830779B2 (ja) * 2011-09-08 2015-12-09 ライオン株式会社 衣料用液体洗剤組成物
WO2013043852A2 (en) 2011-09-20 2013-03-28 The Procter & Gamble Company Easy-rinse detergent compositions comprising isoprenoid-based surfactants
CA2849149A1 (en) 2011-09-20 2013-03-28 The Procter & Gamble Company Detergent compositions comprising sustainable surfactant systems comprising isoprenoid-derived surfactants
EP2758504A1 (de) 2011-09-20 2014-07-30 The Procter and Gamble Company Waschmittelzusammensetzungen mit primärtensidsystemen mit hochverzweigten tensiden, insbesondere tensiden auf isoprenoidbasis
US20130072415A1 (en) 2011-09-20 2013-03-21 The Procter & Gamble Company DETERGENT COMPOSITIONS COMPRISING SPECIFIC BLEND RATIOS of ISOPRENOID-BASED SURFACTANTS
BR112014011245A2 (pt) 2011-11-11 2017-05-09 Procter & Gamble composições para tratamento de superfícies que incluem sais protetores
CN106968050B (zh) 2012-01-04 2019-08-27 宝洁公司 具有多个区域的含活性物质纤维结构
FR2985272B1 (fr) 2012-01-04 2021-10-22 Procter & Gamble Structures fibreuses contenant des actifs et ayant des regions multiples aux caracteristiques distinctes
BR122021018583B1 (pt) 2012-02-03 2022-09-06 The Procter & Gamble Company Método para limpar um material têxtil ou uma superfície dura ou outra superfície em cuidados com tecidos e com a casa
CA2867714A1 (en) 2012-03-19 2013-09-26 The Procter & Gamble Company Laundry care compositions containing dyes
US9909109B2 (en) 2012-04-02 2018-03-06 Novozymes A/S Lipase variants and polynucleotides encoding same
JP2015525248A (ja) 2012-05-16 2015-09-03 ノボザイムス アクティーゼルスカブ リパーゼを含む組成物およびその使用方法
EP2855648B1 (de) 2012-05-24 2015-12-02 Unilever Plc. Verbesserungen im zusammenhang mit wäscheweichmachern
WO2013189661A1 (en) 2012-06-21 2013-12-27 Unilever Plc Improvements relating to fabric conditioners
US10246692B2 (en) 2012-07-12 2019-04-02 Novozymes A/S Polypeptides having lipase activity and polynucleotides encoding same
EP2877562B1 (de) 2012-07-26 2018-04-25 The Procter and Gamble Company Enzymhaltige flüssige reinigungszusammensetzungen mit niedrigem ph-wert
CN105051174B (zh) 2013-03-21 2018-04-03 诺维信公司 具有脂肪酶活性的多肽和编码它们的多核苷酸
CN105102600A (zh) 2013-03-28 2015-11-25 宝洁公司 包含聚醚胺、去垢性聚合物和羧甲基纤维素的清洁组合物
MY192746A (en) 2013-05-14 2022-09-06 Novozymes As Detergent compositions
MX2015016438A (es) 2013-05-28 2016-03-01 Procter & Gamble Composiciones que comprenden tintes fotocromicos para el tratamiento de superficies.
US20160160196A1 (en) 2013-07-09 2016-06-09 Novozymes A/S Polypeptides with Lipase Activity And Polynucleotides Encoding Same
MX2016003538A (es) 2013-09-18 2016-06-28 Procter & Gamble Composiciones para el cuidado de la ropa que contienen colorantes azoicos de tiofeno y carboxilato.
US9834682B2 (en) 2013-09-18 2017-12-05 Milliken & Company Laundry care composition comprising carboxylate dye
WO2015042086A1 (en) 2013-09-18 2015-03-26 The Procter & Gamble Company Laundry care composition comprising carboxylate dye
CN105555935A (zh) 2013-09-18 2016-05-04 宝洁公司 包含羧化物染料的衣物洗涤护理组合物
EP3097173B1 (de) 2014-01-22 2020-12-23 The Procter and Gamble Company Gewebebehandlungszusammensetzung
WO2015112341A1 (en) 2014-01-22 2015-07-30 The Procter & Gamble Company Fabric treatment composition
WO2015112338A1 (en) 2014-01-22 2015-07-30 The Procter & Gamble Company Method of treating textile fabrics
WO2015109972A1 (en) 2014-01-22 2015-07-30 Novozymes A/S Polypeptides with lipase activity and polynucleotides encoding same
WO2015112340A1 (en) 2014-01-22 2015-07-30 The Procter & Gamble Company Method of treating textile fabrics
US20150210964A1 (en) 2014-01-24 2015-07-30 The Procter & Gamble Company Consumer Product Compositions
CN111500552A (zh) 2014-03-12 2020-08-07 诺维信公司 具有脂肪酶活性的多肽和编码它们的多核苷酸
US20150275143A1 (en) 2014-03-27 2015-10-01 The Procter & Gamble Company Cleaning compositions containing a polyetheramine
CA2941253A1 (en) 2014-03-27 2015-10-01 Frank Hulskotter Cleaning compositions containing a polyetheramine
EP3131921B1 (de) 2014-04-15 2020-06-10 Novozymes A/S Polypeptide mit lipaseaktivität und polynukleotide zur codierung davon
US11530374B2 (en) 2014-05-06 2022-12-20 Milliken & Company Laundry care compositions
CN106459937A (zh) 2014-05-27 2017-02-22 诺维信公司 用于产生脂肪酶的方法
WO2015181119A2 (en) 2014-05-27 2015-12-03 Novozymes A/S Lipase variants and polynucleotides encoding same
EP3152288A1 (de) 2014-06-06 2017-04-12 The Procter & Gamble Company Waschmittelzusammensetzung mit polyalkyleniminpolymeren
KR102254335B1 (ko) 2014-06-18 2021-05-24 로디아 오퍼레이션스 사차 암모늄 화합물, 양이온성 다당류 및 비이온성 다당류를 포함하는 조성물의 이용 방법
WO2016081437A1 (en) 2014-11-17 2016-05-26 The Procter & Gamble Company Benefit agent delivery compositions
CN107002054A (zh) 2014-12-05 2017-08-01 诺维信公司 脂肪酶变体以及编码它们的多核苷酸
WO2016113376A1 (en) 2015-01-16 2016-07-21 Rhodia Operations Method for reducing greying of a fabric
WO2016120291A1 (en) 2015-01-28 2016-08-04 Rhodia Operations Composition containing ester quat, cationic polysaccharide and nonionic polysaccharide
US20180079993A1 (en) 2015-02-27 2018-03-22 Rhodia Operations Composition comprising a quaternary ammonium compound, a cationic polysaccharide and a nonionic polymer
EP3088502B1 (de) 2015-04-29 2018-05-23 The Procter and Gamble Company Verfahren zur behandlung eines stoffes
HUE039245T2 (hu) 2015-04-29 2018-12-28 Procter & Gamble Mosószerkészítmény
EP3088504B1 (de) 2015-04-29 2021-07-21 The Procter & Gamble Company Verfahren zur behandlung eines stoffes
ES2683568T3 (es) 2015-04-29 2018-09-26 The Procter & Gamble Company Método para tratar un tejido
EP3088505B1 (de) 2015-04-29 2020-06-03 The Procter and Gamble Company Verfahren zur behandlung eines stoffes
CN107532007B (zh) 2015-05-04 2020-06-30 美利肯公司 在洗衣护理组合物中作为上蓝剂的隐色三苯甲烷着色剂
EP3298121B1 (de) 2015-05-19 2019-03-20 Novozymes A/S Geruchsreduzierung
WO2016202739A1 (en) 2015-06-16 2016-12-22 Novozymes A/S Polypeptides with lipase activity and polynucleotides encoding same
CN107922930A (zh) 2015-07-01 2018-04-17 诺维信公司 减少气味的方法
WO2017005816A1 (en) 2015-07-06 2017-01-12 Novozymes A/S Lipase variants and polynucleotides encoding same
JP2019502779A (ja) 2015-11-26 2019-01-31 ザ プロクター アンド ギャンブル カンパニー プロテアーゼを含む液体洗剤組成物及び封入リパーゼ
US10870838B2 (en) 2015-12-01 2020-12-22 Novozymes A/S Methods for producing lipases
WO2017100992A1 (en) 2015-12-15 2017-06-22 Rhodia Operations Compositions comprising quat and polysaccharides
US10351805B2 (en) 2015-12-22 2019-07-16 Rhodia Operations Compositions comprising a quat and a mixture of a nonionic and two cationic polysaccharides
EP4357453A2 (de) 2016-07-18 2024-04-24 Novozymes A/S Lipasevarianten, polynukleotide zur codierung davon und verwendung davon
EP3272850A1 (de) 2016-07-19 2018-01-24 Henkel AG & Co. KGaA Vorteil von leichtem bügeln/weniger falten/weniger knittern von stoffbehandlungszusammensetzungen mithilfe von schmutzlösenden polymeren
US20180119056A1 (en) 2016-11-03 2018-05-03 Milliken & Company Leuco Triphenylmethane Colorants As Bluing Agents in Laundry Care Compositions
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US11078445B2 (en) 2017-05-05 2021-08-03 Novozymes A/S Compositions comprising lipase and sulfite
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WO2019154951A1 (en) 2018-02-08 2019-08-15 Novozymes A/S Lipases, lipase variants and compositions thereof
CN111757930A (zh) 2018-02-08 2020-10-09 诺维信公司 脂肪酶变体及其组合物
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CN114555769A (zh) 2019-08-27 2022-05-27 诺维信公司 包含脂肪酶的组合物
CN114787329A (zh) 2019-08-27 2022-07-22 诺维信公司 洗涤剂组合物
EP4038169A1 (de) 2019-10-03 2022-08-10 Rhodia Operations Polymerdispersion und dieselbe umfassende stoffkonditionierungszusammensetzung
WO2021063779A1 (en) 2019-10-03 2021-04-08 Rhodia Operations Fabric conditioning composition comprising polymer dispersion
JP2023547450A (ja) 2020-10-29 2023-11-10 ノボザイムス アクティーゼルスカブ リパーゼ変異体及びそのようなリパーゼ変異体を含む組成物
WO2022103725A1 (en) 2020-11-13 2022-05-19 Novozymes A/S Detergent composition comprising a lipase
EP4112707A1 (de) 2021-06-30 2023-01-04 The Procter & Gamble Company Textilbehandlung
CA3228918A1 (en) 2021-08-10 2023-02-16 Nippon Shokubai Co., Ltd. Polyalkylene-oxide-containing compound
WO2023118015A1 (en) 2021-12-21 2023-06-29 Basf Se Environmental attributes for care composition ingredients
WO2023116569A1 (en) 2021-12-21 2023-06-29 Novozymes A/S Composition comprising a lipase and a booster
WO2023247664A2 (en) 2022-06-24 2023-12-28 Novozymes A/S Lipase variants and compositions comprising such lipase variants
WO2024121058A1 (en) 2022-12-05 2024-06-13 Novozymes A/S A composition comprising a lipase and a peptide

Family Cites Families (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB1407997A (en) * 1972-08-01 1975-10-01 Procter & Gamble Controlled sudsing detergent compositions
DE2631419A1 (de) * 1975-07-16 1977-02-03 Procter & Gamble Europ Zusammensetzungen fuer die textilbehandlung
US4075118A (en) * 1975-10-14 1978-02-21 The Procter & Gamble Company Liquid detergent compositions containing a self-emulsified silicone suds controlling agent
CA1118163A (en) * 1977-02-02 1982-02-16 Robert E. Kalinowski Method for treating synthetic fibers with aminoalkyl-containing polydiorganosiloxanes
NZ187298A (en) * 1977-08-22 1980-09-12 Gen Electric Silicone composition comprising colloidal silica paper or textiles coating
US4279765A (en) * 1979-09-15 1981-07-21 Dow Corning Limited Soap composition containing an amino-substituted polysiloxane
US4287082A (en) * 1980-02-22 1981-09-01 The Procter & Gamble Company Homogeneous enzyme-containing liquid detergent compositions containing saturated acids
US4247592A (en) * 1980-03-12 1981-01-27 Dow Corning Corporation Method for treating synthetic textiles with aminoalkyl-containing polydiorganosiloxanes
GR75649B (de) * 1980-07-28 1984-08-02 Procter & Gamble

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6991747B2 (en) 1999-10-19 2006-01-31 Procter & Gamble Company Radical scavenger
US11624156B2 (en) 2013-12-09 2023-04-11 The Procter & Gamble Company Fibrous structures including an active agent and having a graphic printed thereon
US11795622B2 (en) 2013-12-09 2023-10-24 The Procter & Gamble Company Fibrous structures including an active agent and having a graphic printed thereon
US11970821B2 (en) 2013-12-09 2024-04-30 The Procter & Gamble Company Fibrous structures including an active agent and having a graphic printed thereon

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DE3577107D1 (de) 1990-05-17
GB8401875D0 (en) 1984-02-29
GR850050B (de) 1985-04-18
EP0150872A1 (de) 1985-08-07
JPS60215099A (ja) 1985-10-28
ATE51892T1 (de) 1990-04-15
EP0150872B1 (de) 1990-04-11
MX163030B (es) 1991-08-05
JPH0657839B2 (ja) 1994-08-03

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