EP0100845B1 - Reinforcing or supporting element for building material, in particular an electrode - Google Patents

Reinforcing or supporting element for building material, in particular an electrode Download PDF

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Publication number
EP0100845B1
EP0100845B1 EP83106099A EP83106099A EP0100845B1 EP 0100845 B1 EP0100845 B1 EP 0100845B1 EP 83106099 A EP83106099 A EP 83106099A EP 83106099 A EP83106099 A EP 83106099A EP 0100845 B1 EP0100845 B1 EP 0100845B1
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EP
European Patent Office
Prior art keywords
net
voltage
carrier
reinforcing
synthetic resin
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Expired
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EP83106099A
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German (de)
French (fr)
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EP0100845A3 (en
EP0100845A2 (en
Inventor
Hans Oppitz
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Eltac Nogler und Daum KG
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Eltac Nogler und Daum KG
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Classifications

    • EFIXED CONSTRUCTIONS
    • E04BUILDING
    • E04BGENERAL BUILDING CONSTRUCTIONS; WALLS, e.g. PARTITIONS; ROOFS; FLOORS; CEILINGS; INSULATION OR OTHER PROTECTION OF BUILDINGS
    • E04B1/00Constructions in general; Structures which are not restricted either to walls, e.g. partitions, or floors or ceilings or roofs
    • E04B1/62Insulation or other protection; Elements or use of specified material therefor
    • E04B1/70Drying or keeping dry, e.g. by air vents
    • E04B1/7007Drying or keeping dry, e.g. by air vents by using electricity, e.g. electro-osmosis
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00Stock material or miscellaneous articles
    • Y10T428/29Coated or structually defined flake, particle, cell, strand, strand portion, rod, filament, macroscopic fiber or mass thereof
    • Y10T428/2913Rod, strand, filament or fiber
    • Y10T428/2918Rod, strand, filament or fiber including free carbon or carbide or therewith [not as steel]
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00Stock material or miscellaneous articles
    • Y10T428/29Coated or structually defined flake, particle, cell, strand, strand portion, rod, filament, macroscopic fiber or mass thereof
    • Y10T428/2913Rod, strand, filament or fiber
    • Y10T428/2927Rod, strand, filament or fiber including structurally defined particulate matter
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00Stock material or miscellaneous articles
    • Y10T428/29Coated or structually defined flake, particle, cell, strand, strand portion, rod, filament, macroscopic fiber or mass thereof
    • Y10T428/2913Rod, strand, filament or fiber
    • Y10T428/2933Coated or with bond, impregnation or core
    • Y10T428/294Coated or with bond, impregnation or core including metal or compound thereof [excluding glass, ceramic and asbestos]
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T442/00Fabric [woven, knitted, or nonwoven textile or cloth, etc.]
    • Y10T442/10Scrim [e.g., open net or mesh, gauze, loose or open weave or knit, etc.]
    • Y10T442/102Woven scrim
    • Y10T442/109Metal or metal-coated fiber-containing scrim
    • Y10T442/131Including a coating or impregnation of synthetic polymeric material
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T442/00Fabric [woven, knitted, or nonwoven textile or cloth, etc.]
    • Y10T442/10Scrim [e.g., open net or mesh, gauze, loose or open weave or knit, etc.]
    • Y10T442/102Woven scrim
    • Y10T442/133Inorganic fiber-containing scrim
    • Y10T442/134Including a carbon or carbonized fiber

Definitions

  • the invention relates to a reinforcing or supporting element for building materials, as described in the preamble of claim 1.
  • Reinforcing or supporting elements for building materials consist of rod-shaped or net-shaped or lattice-shaped materials.
  • mesh or mesh made of structural steel or as a plaster base mainly fine metal meshes are used. If the metal grids are used as a plaster base, they are often coated with fired ceramic materials to ensure better adhesion of the plaster mortar.
  • the disadvantage of these metallic plaster bases is that, due to different pH values, they are exposed to corrosion in the building structure and the different moisture conditions. In many cases, the arrangement of the grids in zones with different pH values leads to the formation of a galvanic element and thus to a field structure which causes the structures to be destroyed or the moisture to be drawn up from the ground into the structures.
  • the electroosmotic processes use the phenomenon of electroosmosis to slow down the moisture rising in the capillaries of the masonry and to push it down.
  • Polarization occurs at the interface between water and a solid, with a negative charge on the surface of the solid and a positive charge on the liquid particles. This charge (polarization) does not normally appear, only in an electric field does a migration occur, whereby the solids (as far as they are mobile) migrate to the positive anode (also known as electrophoresis), the liquid particles, especially if the solid particles on the Mobility are prevented, strive to migrate to the negative cathode.
  • DE-A 2 706 172 proposes electrodes with additional foils in order to prevent corrosion.
  • the voltage that can be used in the active process is limited by the decomposition voltage, depending on the composition of the masonry and the salinity of the water, since electrolysis by decomposition of the Water would produce gases that the components in which the electrodes are installed, for. B. plaster, must destroy.
  • DE-A 2 705 814 the formation of detonating gas could even lead to an explosion, so that a limit of 2.8 V is required.
  • the invention is based on a device for the electroosmotic drying of moist structures made of mineral raw materials - according to DD-A 47 791 - which works without the use of an external voltage. It comprises two barrier levels in the form of two electrodes, spaced apart from each other in a damp building.
  • the two barrier levels are electrically conductively connected to one another, the electrode forming the barrier level consisting of a metal and the electrode forming the other barrier level consisting of an electrically conductive non-metal.
  • the metallic electrode can consist of iron or galvanized iron, the electrode of non-metal of graphite or of graphite dispersed in plastic or applied in a film.
  • the electrode formed from non-metal can also be designed in the form of wire, tape, foil or mesh.
  • the electric field to transport liquids in kapilla according to the electroosmotic principles Ren cavities is caused by the combination of the electrically conductive non-metal with a metal, which are built into a working galvanic element.
  • the electrode which is made of non-metal, will set itself up as a cathode with respect to the metal due to its distance in the electrochemical voltage series of the metals from hydrogen. Accordingly, the anode - which is then formed by the metal, that is, the iron - continues to degrade and passivate, as a result of which the operating time of the known device is also very short.
  • the invention is based on the object of creating a reinforcement or support element for building materials of the type mentioned at the beginning, which can be used in areas with different or changing pH values and an intimate connection with the surrounding building materials enables, and moreover it should be possible to use this for a dehumidification system working on an electro-osmotic basis with external current.
  • the chemical-neutral electrode acts as an anode regardless of its distance in the electrochemical voltage series of the metals to hydrogen, since it is connected to an energy supply system at the positive pole. This not only prevents degradation of the anode, but also enables the electrode to be installed in building structures regardless of different pH values. At the same time, however, this also prevents electrochemical degradation in the area of the electrical field at the anode, so that the use of such an electrode is also possible in the renovation of old historical structures with moistened structures.
  • this design makes it possible that when using the reinforcement or support elements as electrodes, even in large-scale systems and at higher operating voltages, no disturbances due to electrolytic decomposition or hydrogen deposits on an anode can occur.
  • the decisive factor here is the continuous coating of the mesh with conductive plastic. Thanks to the flexibility of the network, it can be easily adapted to different environmental conditions, such as different floor levels or building levels. This advantage comes to the fore especially when used for the renovation of dampened building structures. Since the coating of the mesh with the conductive plastic causes the voltage to be evenly distributed over the entire surface of the electrode, a large-area electrokinetic effect, for example a large-area electroosmosis, is achieved.
  • the power supply lines improve the strength of the networks against mechanical stress and at the same time the conductivity.
  • the use of titanium is characterized by the small electrochemical potential difference compared to hydrogen, so that the risk that a galvanic element can build up is further reduced.
  • the high surface roughness has the advantage that there is an intimate connection of the surrounding building materials, in particular of the plastering mortar, with the network. In conjunction with the low proportion of plasticizer, this intimate connection is also maintained and there is no shrinkage on the circumference of the network, so that even over a long period of time, perfect contacting of the surrounding construction materials, especially when using the reinforcing elements as electrodes for dehumidification systems, is guaranteed is.
  • the permanent contacting is additionally increased by the use of plastics doped with oxygen-reducing metals, since the passivation of the anode network is switched off.
  • a design according to claim 6 is also advantageous.
  • the use of a plastic having semiconductor properties is distinguished by the fact that the charge transport by electrons and holes, in contrast to the so-called ion semiconductors, in which a mass transfer occurs with the charge transport port is connected.
  • the conductivity in the temperature conditions occurring in building bodies is advantageous for the use of such reinforcing or supporting elements for building materials. Since the carbon components in these semiconductors do not have to form a skeleton in order to increase the conductivity, it is possible to find sufficiency with a low carbon component, as a result of which the fragility of such plastic coatings is reduced.
  • An embodiment according to claim 8 is also advantageous, since this makes it easier to plaster in or incorporate the reinforcing elements into the building materials and allows them to be well adapted to the surfaces of the building bodies.
  • Such a circuit can be produced very easily in the different technologies, such as, for example, relay control, transistor control or with integrated switching modules, so that simple adaptation to the different applications and ambient conditions is possible.
  • the invention also includes an independent method according to the preamble of claim 11.
  • This method is defined by the characterizing features of claim 11.
  • the feature of the larger positive time integral enables the desired electroosmotic effect, while the negative voltage eliminates any substances formed by electrolytic decomposition, in particular the unfavorable gases, in a reverse reaction.
  • the high concentration of the substances produced on the electrodes results in a rapid and preferred reversal of the chemical processes, while the build-up of the reversed electric field and thus the reversal of the electroosmotic effect is reduced or completely prevented.
  • a procedure according to claim 14 is also advantageous.
  • the voltage peak of the negative period can be cut off or only the part of the sine voltage exceeding a certain voltage can be used.
  • the advantage of the process lies not only in the increased desired effect, which leads to the desired success in a fraction of the time, even with very high water pressure with old and thick masonry, but also in the reliable avoidance of chemical decomposition of the water while preventing gas formation or separation of heavy metals, which in turn can lead to the destruction of building materials.
  • the measured effective voltages of the positive portion of the AC voltage can be greater than 16 V. Electrodes made of conductive or semiconducting plastics are not attacked.
  • a support body 1 is shown as a reinforcement or support element for the building serves fabrics. This support body 1 is designed as a network 2.
  • a power supply line 3 is integrated, which is formed by a conveyor belt 4.
  • the power supply line 3 is arranged in the longitudinal direction - arrow 5 - of the band-shaped network 2 approximately centrally between the two longitudinal edges 6.
  • the Lahnband 4 consists, as indicated over part of its length, from a plurality of individual strands 7, which are formed by metal threads 8.
  • the surface of the metal threads 8 can be silver-coated, or e.g. Titanium wire is used to obtain a good conductivity and a small potential difference between the surface of these metal threads 8 and the plastic 9 surrounding them. If the potential difference is small, then an electromotive force can hardly develop between the different materials, such as silver or titanium, and the plastic 9 according to the invention, and therefore no current flows. However, this does not lead to metal degradation, especially of those metals that have a more negative intrinsic potential, so that no ions go into solution.
  • a support body 10 is shown, which is formed by a network 11.
  • the individual threads 12 to 14 of the network 11 consist of a plastic 15.
  • This plastic 15 is essentially ion-free and is designed in the manner of a thermoset with a macromolecular structure.
  • This plastic 15 is preferably e.g. an acrylate with at least partially crosslinked polymers, which has a high surface roughness and a low proportion of plasticizer.
  • the plastic 15 can preferably be designed according to the Austrian patent specification 313 588 by the same inventor. It is advantageous if the plastic is doped with oxygen-reducing metals. When using a network 11 with a plastic 15 doped in this way as the anode, the oxidation of the anode and its passivation is switched off.
  • FIG. 2 is further recommended if a power supply line 18 is formed by a thread 14 of the network.
  • metal threads 16 or carbon threads 17, which can optionally be provided with a silver coating 19, are arranged in these mesh threads 14 to increase the conductivity, but also in addition to increase the mechanical strength.
  • This silver coating achieves the advantages already described in connection with FIG. 1.
  • any plastic 15 which is highly elastic, flexible or limp and conductive, in the manufacture of the network 11.
  • the entire network is covered with the plastic 15 to produce the desired surface quality of the network 11, as is indicated in the region of the crossing threads 12 and 14 of the network 11.
  • the carbon or metal threads 17 or 16 regardless of their function with regard to improved electrical properties, such as higher conductivity and the like, form a strength-enhancing, thread-like carrier material 20.
  • the carrier material 20 can of course be formed by threads made of any materials that However, metal threads are preferably used because they have a good combination of high strength and good conductivity within the scope of the desired properties according to the invention.
  • FIG. 3 shows a section through a thread 13 of the net 11 on an enlarged scale.
  • 13 metal threads 16 or carbon threads 17 are embedded in the plastic 15 of the thread, some of which are provided with a silver coating 19.
  • carbon components 21 are freely suspended in the plastic 15. This free-floating arrangement of carbon components 21 is possible because the plastic 15 has semiconductor properties and the carbon is therefore not required to build up a line system, but only to increase the conductivity.
  • FIGS. 4 and 5 show two different design variants of how the support body 1 or nets 2 or 11 according to the invention can be arranged on structures 22 and 23, respectively.
  • the building structure 22 or 23 consists, for example, of brick masonry or reinforced concrete in the exemplary embodiments shown.
  • two nets 24 and 25 are fastened to the building structure 22 by means of fastening means 27 consisting of resistant materials 26, for example plastic clamping plugs.
  • fastening means 27 consisting of resistant materials 26, for example plastic clamping plugs.
  • the networks 24 and 25 are embedded in a building material 32, in the present case a plastering mortar 33.
  • the plastering mortar 33 is applied in such a thickness that the nets 24 and 25 come to lie below its outside 34.
  • the nets 24 and 25 thus form an anode 35 and a cathode 36 of an electro-kinetic system 37.
  • the network 25 is again arranged in the region of the bottom 39 and when the two networks 24, 25 are applied to the DC voltage source 30, an intense electrical field 41 is created, which is indicated schematically by field lines 42.
  • the DC voltage source 30 is assigned a counter-pole switching element 44.
  • This opposite pole switching element 44 has the effect that the polarity in the electro-kinetic system 37 is periodically and briefly reversed. As a result, the ions in the electric field cannot be deposited and depolarization is avoided.
  • the high conductivity achieved in this way in the building structure 22 or 23 prevents the salt ions migrating between the networks 24 and 25 from depositing and blooming. Due to the high conductivity, a high current passage in the structure 22 or 23 is also achieved, so that a very intensive field is built up, which causes an intensive water transport in the direction of the cathode.
  • the networks 2, 11, 24, 25 according to the invention in two different high positions relative to the floor 39 and to short-circuit them, i.e. i.e. to connect, which balances out the natural potential difference and creates a so-called horizontal barrier, which prevents the water from migrating up through the built-in networks.
  • the advantage of using the networks according to the invention as a reinforcing or supporting element for building materials is, above all, that the special plastic used, due to the high surface roughness and the low shrinkage, ensures an intimate connection between the building material and the reinforcing element over a long period of time , whereby moisture accumulations in the area of the reinforcing elements and thus subsequent corrosion are switched off and a high electrical conductivity of the system is achieved when using the network as electrodes.
  • FIG. 6 shows a voltage supply device 45 for the networks 48, 49 designed according to the invention, which form an anode 46 or a cathode 47.
  • the voltage supply device comprises a transformer 50, smoothing diodes 51, an opposing pole switching element 52 and a timing element 53.
  • the opposing pole switching element 52 has a pulse switch 55 which is arranged in parallel with the smoothing diodes 51 of a rectifier circuit 54 and is formed by a transistor 56.
  • the signal passage through the transistor 56 is made possible for a certain period of time via the timing element 53.
  • the diode 57 assigned to the opposite pole switching element 52 ensures that a voltage passage is only possible if a negative potential is present at an output 58 of the transformer 50.
  • An input 59 of the pulse switch 55 is present at the output 58 of a DC voltage source 60 formed by the transformer 50.
  • An output 61 is connected to a lead 62 to the anode 46.
  • the transistor 56 serving as a make contact is driven by the timing element 53.
  • a changeover switch 65 is also provided, with which the voltage supply of the two networks 48 and 49 can be reversed, if necessary, so that the anode acts as a cathode or vice versa.
  • a current display device 66 is assigned to the voltage supply device 45.
  • the design of this voltage supply device can be modified as desired within the scope of the invention without deviating from it, and it is also possible to use corresponding relay controls or integrated circuits or microprocessors or the like instead of the transistor circuit shown.
  • the method according to the invention is not restricted to sinusoidal voltages of 50 or 60 S - 1 .
  • This preferred form of the voltage-time curve can, for example, with the voltage supply device described in Figure 6 45 can be achieved.
  • the passage through the transistor 56 is only opened after the positive potential has been present for a certain period of time, so that the anode 46 is subjected to a negative voltage.
  • the supply of the negative voltage via the lead 62 through the transistor 56 is then blocked again when the preselected voltage level is undershot. This creates the special voltage curve shown in FIG. 7.
  • the present invention when using the reinforcement or support elements according to the invention as electrodes if their minimum distance in the vertical direction of the structure is at least 10 cm.
  • the network forming the cathode is preferably to be arranged approximately 30 to 50 cm below the surface of the ground.

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  • Engineering & Computer Science (AREA)
  • Architecture (AREA)
  • Electrochemistry (AREA)
  • Chemical & Material Sciences (AREA)
  • Water Supply & Treatment (AREA)
  • Physics & Mathematics (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Electromagnetism (AREA)
  • Civil Engineering (AREA)
  • Structural Engineering (AREA)
  • Prevention Of Electric Corrosion (AREA)
  • Building Environments (AREA)
  • Separation Using Semi-Permeable Membranes (AREA)
  • Laminated Bodies (AREA)

Abstract

Reinforcing or carrier elements for plaster are used as electrodes in electro-osmotic dehumidification installations. The elements comprise a carrier body constituted by a flexible net having a surface of synthetic resin in contact with the plaster and the net has filamentary carrier materials incorporated therein. The synthetic resin is a conductive, essentially ion-free thermosetting resin of macromolecular structure, preferably an at least partially cross-linked acrylate polymer having a high surface roughness and containing a small amount of a plasticizer, and forms either the matrix or a coating of the flexible net. The filamentary carrier materials may be carbon or metal filaments. In the use of the dehumidification installation, a voltage alternating between a positive and a negative potential is conducted between the cathode and the anode, the time interval of the positive potential exceeding that of the negative potential.

Description

Die Erfindung betrifft ein Verstärkungs- bzw. Tragelement für Bauwerkstoffe, wie es im Oberbegriff des Patentanspruches 1 beschrieben ist.The invention relates to a reinforcing or supporting element for building materials, as described in the preamble of claim 1.

Bekannt sind Verstärkungs- bzw. Tragelemente für Baustoffe, die aus stabförmigen bzw. netz-oder gitterförmigen Materialien bestehen. So kommen bei der Bewehrung von Betonbaukörpern vorwiegend Matten bzw. Gitter aus Baustahl bzw. als Putzträger vornehmlich feine Metallgitter zum Einsatz. Werden die Metallgitter als Putzträger verwendet, sind sie vielfach mit gebrannten keramischen Massen beschichtet, um ein besseres Haften des Putzmörtels sicherzustellen. Nachteilig ist bei diesen metallischen Putzträgern, dass sie, bedingt durch verschiedene pH-Werte, im Baukörper und den unterschiedlichen Feuchtigkeitsverhältnissen der Korrosion ausgesetzt sind. Vielfach kommt es dabei durch die Anordnung der Gitter in Zonen mit verschiedenen pH-Werten zur Ausbildung eines galvanischen Elementes und somit zu einem Feldaufbau, der eine Zerstörung der Baukörper bzw. ein Hochziehen der Feuchtigkeit aus dem Untergrund in die Baukörper bewirkt. Diese nachteiligen Effekte kommen vor allem dann zum Tragen, wenn die Putzträger zur Sanierung alter historischer Gebäude, die trocken zu legen sind, verwendet werden. Es ist daher vielfach erforderlich, zusätzlich zu den Putzträgern Elektroden von auf elektroosmotischer Basis arbeitenden Entfeuchtungsanlagen einzubauen, um eine Entfeuchtung der Bauwerkskörper zu erzielen.Reinforcing or supporting elements for building materials are known which consist of rod-shaped or net-shaped or lattice-shaped materials. For reinforcement of concrete structures, mainly mesh or mesh made of structural steel or as a plaster base, primarily fine metal meshes are used. If the metal grids are used as a plaster base, they are often coated with fired ceramic materials to ensure better adhesion of the plaster mortar. The disadvantage of these metallic plaster bases is that, due to different pH values, they are exposed to corrosion in the building structure and the different moisture conditions. In many cases, the arrangement of the grids in zones with different pH values leads to the formation of a galvanic element and thus to a field structure which causes the structures to be destroyed or the moisture to be drawn up from the ground into the structures. These adverse effects are particularly noticeable when the plaster base is used to renovate old historic buildings that have to be drained. It is therefore often necessary to install electrodes of dehumidification systems working on an electro-osmotic basis in addition to the plaster base in order to dehumidify the structure.

Zahlreiche unterschiedliche Verfahren zur Trockenlegung von Mauern sind heute in Gebrauch. Wie aus einer unter dem Titel «Mauerfeuchtigkeit» erschienenen Forschungsarbeit des Österr. Institutes für Bauforschung (Verlag Strassenbau, Chemie und Technik Verlagsgesellschaft mbH, Heidelberg 1967) hervorgeht, werden hiebei nachstehende Möglichkeiten unterschieden: Massnahmen am Verputz, Belüftungsverfahren, Entfeuchtungskörper, Einbau von Dichtungsschichten, Porenfüllung, elektroosmotische und sonstige Verfahren. Die vorliegende Erfindung gehört zu den elektroosmotischen Verfahren, weshalb kurz auf die theoretischen Grundlagen gemäss der o.a. Veröffentlichung eingegangen wird.Numerous different methods of draining walls are in use today. As from a research work by the Austrian Institute for Building Research (Verlag Strassenbau, Chemie und Technik Verlagsgesellschaft mbH, Heidelberg 1967), the following options are differentiated: Plastering measures, ventilation processes, dehumidifiers, installation of sealing layers, pore filling, electroosmotic and other processes. The present invention belongs to the electroosmotic method, which is why briefly on the theoretical basis according to the above. Publication is received.

Die elektroosmotischen Verfahren bedienen sich der Erscheinung der Elektroosmose, um die in den Kapillaren des Mauerwerks aufsteigende Feuchtigkeit zu bremsen und abwärts zu drücken. An der Grenzfläche zwischen Wasser und einem Feststoff tritt eine Polarisierung auf, wobei sich auf der Oberfläche des Feststoffes eine negative, bei den Flüssigkeitsteilchen eine positive Aufladung ergibt. Diese Ladung (Polarisierung) tritt normalerweise nicht in Erscheinung, erst in einem elektrischen Feld kommt es zur Wanderung, wobei die Feststoffe (soweit sie beweglich sind) zur positiven Anode wandern (auch als Elektrophorese bezeichnet), die Flüssigkeitsteilchen, insbesondere wenn die Feststoffteilchen an der Beweglichkeit gehindert sind, das Bestreben haben, zur negativen Kathode zu wandern.The electroosmotic processes use the phenomenon of electroosmosis to slow down the moisture rising in the capillaries of the masonry and to push it down. Polarization occurs at the interface between water and a solid, with a negative charge on the surface of the solid and a positive charge on the liquid particles. This charge (polarization) does not normally appear, only in an electric field does a migration occur, whereby the solids (as far as they are mobile) migrate to the positive anode (also known as electrophoresis), the liquid particles, especially if the solid particles on the Mobility are prevented, strive to migrate to the negative cathode.

Da das Wasser z. B. im Mauerwerk auch immer Salze enthält, ergibt sich eine Leitfähigkeit, sodass man durch entsprechende Wahl der Elektrodenmaterialien galvanische Elemente hervorrufen kann, die die elektroosmotischen Erscheinungen bewirken. Nachteile sind dabei Korrosionserscheinungen und die begrenzte Lebensdauer der Elektroden, Vorteil die Wartungsfreiheit der Einrichtung.Since the water z. B. always contains salts in the masonry, there is a conductivity, so that by appropriate choice of the electrode materials, galvanic elements can be produced, which cause the electroosmotic phenomena. Disadvantages are signs of corrosion and the limited life of the electrodes, and the fact that the device is maintenance-free is an advantage.

Bei den aktiven Methoden wird das elektrische Feld zwischen eingebauten oder angebrachten Elektroden durch Fremdstrom erzeugt. Auch hier können Korrosionserscheinungen auftreten, welches Problem aber heute durch Anwendung von Graphit oder elektrisch leitfähige Kunststoffe gelöst ist.With the active methods, the electric field between the installed or attached electrodes is generated by external current. Corrosion can also occur here, but the problem that is solved today by using graphite or electrically conductive plastics.

Die umfangreiche Patentliteratur befasst sich mit der Anordnung und der Zusammensetzung der Elektroden (DE-C 2 722 985, DE-C 2 603 135, DE-A 2703813, DE-A 2706193). Die DE-A 2 706 172 schlägt Elektroden mit zusätzlichen Folien vor, um die Korrosion zu verhindern.The extensive patent literature deals with the arrangement and composition of the electrodes (DE-C 2 722 985, DE-C 2 603 135, DE-A 2703813, DE-A 2706193). DE-A 2 706 172 proposes electrodes with additional foils in order to prevent corrosion.

Wie der DE-A 2 705 814 und DE-C 2 503 670 zu entnehmen ist, ist die beim aktiven Verfahren anwendbare Spannung in Abhängigkeit von der Zusammensetzung von Mauerwerk und Salzgehalt des Wassers nach oben durch die Zersetzungsspannung begrenzt, da eine Elektrolyse durch Zersetzung des Wassers Gase erzeugen würde, die die Bauteile, in die die Elektroden eingebaut sind, z. B. Putz, zerstören müssen. Gemäss DE-A 2 705 814 könnte sich durch Knallgasbildung sogar eine Explosionsgefahr ergeben, sodass eine Grenze von 2,8 V gefordert wird. Andererseits wäre es wünschenswert, das elektrische Feld durch Spannungserhöhung zu vergrössern, um die gewünschte Wirkung zu verbessern. Dies ist insbesondere bei altem oder sehr dickem Mauerwerk oder bei sehr starkem Feuchtigkeitsdruck notwendig. Auch kann bei Erhöhen der Spannung der Trocknungseffekt wesentlich rascher erzielt werden.As can be seen from DE-A 2 705 814 and DE-C 2 503 670, the voltage that can be used in the active process is limited by the decomposition voltage, depending on the composition of the masonry and the salinity of the water, since electrolysis by decomposition of the Water would produce gases that the components in which the electrodes are installed, for. B. plaster, must destroy. According to DE-A 2 705 814, the formation of detonating gas could even lead to an explosion, so that a limit of 2.8 V is required. On the other hand, it would be desirable to increase the electric field by increasing the voltage in order to improve the desired effect. This is particularly necessary with old or very thick masonry or with very strong moisture pressure. The drying effect can also be achieved much more quickly by increasing the voltage.

Die Erfindung geht von einer Vorrichtung zur elektroosmotischen Trocknung von feuchten Bauwerken aus mineralischen Grundstoffen - gemäss DD-A 47 791 - die ohne Verwendung einer äusseren Spannung arbeitet, aus. Sie umfasst zwei in feuchtem Bauwerk voneinander distanziert angeordnete Sperrebenen in Form zweier Elektroden.The invention is based on a device for the electroosmotic drying of moist structures made of mineral raw materials - according to DD-A 47 791 - which works without the use of an external voltage. It comprises two barrier levels in the form of two electrodes, spaced apart from each other in a damp building.

Die beiden Sperrebenen sind elektrisch leitend miteinander verbunden, wobei die die eine Sperrebene bildende Elektrode aus einem Metall und die die andere Sperrebene bildende Elektrode aus einem elektrisch leitenden Nichtmetall besteht. Die metallische Elektrode kann dabei aus Eisen oder verzinktem Eisen, die Elektrode aus Nichtmetall aus Graphit oder aus in Kunststoff dispergiertem oder filmartig aufgetragenem Graphit bestehen. Die aus Nichtmetall gebildete Elektrode kann weiters in Form von Draht, Band, Folie oder Netz ausgebildet sein. Das elektrische Feld, um entsprechend den elektroosmotischen Prinzipien einen Transport von Flüssigkeiten in kapillaren Hohlräumen zu bewirken, wird durch die Kombination des elektrisch leitenden Nichtmetalls mit einem Metall, die zu einem arbeitenden galvanischen Element aufgebaut werden, bewirkt. Nachteilig ist hiebei, dass die aus Nichtmetall bestehende Elektrode aufgrund ihres Abstandes in der elektrochemischen Spannungsreihe der Metalle zu Wasserstoff sich als Kathode gegenüber dem Metall einstellen wird. Demgemäss kommt es an der Anode - die dann durch das Metall, also das Eisen gebildet wird - nach wie vor zu einem Abbau sowie einer Passivierung, wodurch die Funktionsdauer der bekannten Vorrichtung ebenfalls sehr gering ist.The two barrier levels are electrically conductively connected to one another, the electrode forming the barrier level consisting of a metal and the electrode forming the other barrier level consisting of an electrically conductive non-metal. The metallic electrode can consist of iron or galvanized iron, the electrode of non-metal of graphite or of graphite dispersed in plastic or applied in a film. The electrode formed from non-metal can also be designed in the form of wire, tape, foil or mesh. The electric field to transport liquids in kapilla according to the electroosmotic principles Ren cavities is caused by the combination of the electrically conductive non-metal with a metal, which are built into a working galvanic element. The disadvantage here is that the electrode, which is made of non-metal, will set itself up as a cathode with respect to the metal due to its distance in the electrochemical voltage series of the metals from hydrogen. Accordingly, the anode - which is then formed by the metal, that is, the iron - continues to degrade and passivate, as a result of which the operating time of the known device is also very short.

Die Erfindung liegt nunmehr die Aufgabe zugrunde, ein als Elektrode ausgebildetes Verstärkungs- bzw. Tragelement für Bauwerkstoffe der eingangs genannten Art zu schaffen, das auch in Bereichen mit unterschiedlichen bzw. wechselnden pH-Werten eingesetzt werden kann und eine innige Verbindung mit den sie umgebenden Bauwerkstoffen ermöglicht, und darüberhinaus soll es möglich sein, diese für eine auf elektroosmotischer Basis mit Fremdstrom arbeitende Entfeuchtungsanlage zu verwenden.The invention is based on the object of creating a reinforcement or support element for building materials of the type mentioned at the beginning, which can be used in areas with different or changing pH values and an intimate connection with the surrounding building materials enables, and moreover it should be possible to use this for a dehumidification system working on an electro-osmotic basis with external current.

Diese Aufgabe der Erfindung wird durch die im Patentanspruch 1 genannten Merkmale gelöst. Die überraschenden Vorteile dieser Lösung liegen darin, dass die chemisch-neutrale Elektrode unabhängig von ihrem Abstand in der elektrochemischen Spannungsreihe der Metalle zu Wasserstoff als Anode wirkt, da sie am Pluspol an eine Energieversorgungsanlage angeschlossen wird. Damit kann nicht nur ein Abbau der Anode verhindert werden, sondern es ist ein Einbau der Elektrode unabhängig von verschiedenen pH-Werten in Bauwerkskörpern möglich. Damit wird gleichzeitig aber auch ein elektrochemischer Abbau im Bereich des elektrischen Feldes an der Anode verhindert, sodass der Einsatz einer derartigen Elektrode auch bei der Sanierung von alten historischen Baukörpern mit durchfeuchteten Bauwerkskörpern möglich ist. Vor allem dadurch, dass je nach Ausbildung des Netzes und der Maschenweite, sowie der Fadendicke bzw. den Abständen zwischen den Öffnungen der Elektrode diese gleichzeitig als Verstärkungs- bzw. Tragelement für Bauwerkstoffe dient. Dadurch können auch nachfolgende Setzungen zwischen den einzelnen Bauwerkstoffen bzw. des gesamten Baukörpers den intensiven Feldaufbau durch die erfindungsgemässe Elektrode nicht behindern. Werden einzelne Fäden des Netzes unterbrochen, so ist durch die Verbindung über die parallel-laufenden Fäden, sowie die sich in Längsrichtung des Tragkörpers bzw. des bandförmigen Netzes erstreckende Stromversorgungsleitung die Zufuhr von Fremdstrom und damit der Feldaufbau sichergestellt. Darüberhinaus ist es in manchen Fällen unter Umständen möglich, die Verwendung zusätzlicher Verstärkungs- bzw. Tragelemente beim Aufbringen des Putzes einzusparen, da diese Funktion bei entsprechender Ausbildung direkt übernommen werden kann. Weiters ist es durch diese Ausbildung möglich, dass bei Einsatz der Verstärkungs- bzw. Tragelemente als Elektroden auch bei grossflächigen Anlagen und bei höheren Betriebsspannungen keine Störungen durch elektrolytische Zersetzungen bzw. durch Wasserstoff-Ablagerungen an einer Anode entstehen können. Ausschlaggebend dafür ist die durchgehende Beschichtung des Netzes mit leitendem Kunststoff. Durch die Flexibilität des Netzes ist eine gute Anpassung desselben an verschiedene Umgebungszustände, wie unterschiedliches Bodenniveau oder Baukörperniveau, möglich. Dieser Vorteil tritt vor allem beim Einsatz für die Sanierung von durchfeuchteten Bauwerkskörpern stark in den Vordergrund. Da durch die Beschichtung des Netzes mit dem leitenden Kunststoff die Spannungsabgabe über die gesamte Fläche der Elektrode gleichmässig erfolgt, wird ein grossflächiger elektrokinetischer Effekt, beispielsweise eine grossflächige Elektroosmose, erreicht.This object of the invention is achieved by the features mentioned in claim 1. The surprising advantages of this solution are that the chemical-neutral electrode acts as an anode regardless of its distance in the electrochemical voltage series of the metals to hydrogen, since it is connected to an energy supply system at the positive pole. This not only prevents degradation of the anode, but also enables the electrode to be installed in building structures regardless of different pH values. At the same time, however, this also prevents electrochemical degradation in the area of the electrical field at the anode, so that the use of such an electrode is also possible in the renovation of old historical structures with moistened structures. Above all in that, depending on the design of the network and the mesh size, as well as the thread thickness or the distances between the openings of the electrode, this serves simultaneously as a reinforcing or supporting element for building materials. As a result, subsequent settlements between the individual building materials or the entire building body cannot hinder the intensive field build-up by the electrode according to the invention. If individual threads of the network are interrupted, the connection via the parallel threads and the power supply line extending in the longitudinal direction of the support body or the band-shaped network ensures the supply of external current and thus the field structure. In addition, in some cases it may be possible to save on the use of additional reinforcement or support elements when applying the plaster, since this function can be performed directly with the appropriate training. Furthermore, this design makes it possible that when using the reinforcement or support elements as electrodes, even in large-scale systems and at higher operating voltages, no disturbances due to electrolytic decomposition or hydrogen deposits on an anode can occur. The decisive factor here is the continuous coating of the mesh with conductive plastic. Thanks to the flexibility of the network, it can be easily adapted to different environmental conditions, such as different floor levels or building levels. This advantage comes to the fore especially when used for the renovation of dampened building structures. Since the coating of the mesh with the conductive plastic causes the voltage to be evenly distributed over the entire surface of the electrode, a large-area electrokinetic effect, for example a large-area electroosmosis, is achieved.

Eine weitere Ausführungsform ist im Kennzeichenteil des Patentanspruches 2 beschrieben. Dies ermöglicht eine gleichmässig durchgehende Kontaktierung des Netzes, wobei die Stromversorgungsleitung eine gute Leitfähigkeit und Festigkeit aufweist.Another embodiment is described in the characterizing part of claim 2. This enables uniform, continuous contacting of the network, the power supply line having good conductivity and strength.

Weiters ist aber auch eine Ausbildung nach Patentanspruch 3 möglich. Dadurch verbessern die Stromversorgungsleitungen die Festigkeit der Netze gegen mechanische Beanspruchungen und gleichzeitig die Leitfähigkeit. Darüberhinaus zeichnet sich die Verwendung von Titan durch die geringe elektrochemische Potentialdifferenz gegenüber Wasserstoff aus, sodass die Gefahr, dass sich ein galvanisches Element aufbauen kann, zusätzlich verringert ist.Furthermore, training according to claim 3 is also possible. As a result, the power supply lines improve the strength of the networks against mechanical stress and at the same time the conductivity. In addition, the use of titanium is characterized by the small electrochemical potential difference compared to hydrogen, so that the risk that a galvanic element can build up is further reduced.

Es ist aber auch eine Weiterbildung nach Patentanspruch 4 möglich. Dadurch wird eine gleichmässige Spannungsversorgung der verschiedenen Netzteile sichergestellt und vor allem werden beschädigte Netzteile dadurch leicht überbrückt.However, further development according to claim 4 is also possible. This ensures an even power supply for the various power supplies and, above all, easily damages bridged power supplies.

Weiters ist auch eine Ausführung nach Patentanspruch 5 vorgesehen. Die hohe Oberflächenrauhigkeit hat den Vorteil, dass eine innige Verbindung der umgebenden Bauwerkstoffe, insbesondere des Putzmörtels mit dem Netz, gegeben ist. In Verbindung mit dem geringen Weichmacheranteil wird erreicht, dass diese innige Verbindung auch aufrecht erhalten wird und keine Schrumpfung am Umfang des Netzes einsetzt, sodass auch über längere Zeit eine einwandfreie Kontaktierung der umgebenden Bauwerkstoffe, vor allem beim Einsatz der Verstärkungselemente als Elektroden für Entfeuchtungsanlagen, gewährleistet ist. Die dauerhafte Kontaktierung wird noch zusätzlich durch den Einsatz von mit Sauerstoff reduzierenden Metallen dotierten Kunststoffen erhöht, da die Passivierung des Anodennetzes ausgeschaltet wird.Furthermore, an embodiment according to claim 5 is also provided. The high surface roughness has the advantage that there is an intimate connection of the surrounding building materials, in particular of the plastering mortar, with the network. In conjunction with the low proportion of plasticizer, this intimate connection is also maintained and there is no shrinkage on the circumference of the network, so that even over a long period of time, perfect contacting of the surrounding construction materials, especially when using the reinforcing elements as electrodes for dehumidification systems, is guaranteed is. The permanent contacting is additionally increased by the use of plastics doped with oxygen-reducing metals, since the passivation of the anode network is switched off.

Von Vorteil ist weiters eine Ausbildung nach Patentanspruch 6. Die Verwendung eines Halbleitereigenschaften aufweisenden Kunststoffes zeichnet sich dadurch aus, dass der Ladungstransport durch Elektronen und Löcher im Gegensatz zu den sogenannten lonenhalbleitern, bei denen mit dem Ladungstransport ein Stofftransport verbunden ist, erfolgt. Vor allem die Leitfähigkeit in den in Bauwerkskörpern vorkommenden Temperaturverhältnissen ist für die Verwendung derartiger Verstärkungs- bzw. Tragelemente für Bauwerkstoffe vorteilhaft. Da in diesen Halbleitern die Kohlenstoffanteile zur Erhöhung der Leitfähigkeit kein Skelett bilden müssen, kann mit einem geringen Kohlenstoffanteil das Auslangen gefunden werden, wodurch die Brüchigkeit derartiger Kunststoffbeschichtungen herabgesetzt wird.A design according to claim 6 is also advantageous. The use of a plastic having semiconductor properties is distinguished by the fact that the charge transport by electrons and holes, in contrast to the so-called ion semiconductors, in which a mass transfer occurs with the charge transport port is connected. Above all, the conductivity in the temperature conditions occurring in building bodies is advantageous for the use of such reinforcing or supporting elements for building materials. Since the carbon components in these semiconductors do not have to form a skeleton in order to increase the conductivity, it is possible to find sufficiency with a low carbon component, as a result of which the fragility of such plastic coatings is reduced.

Eine weitere vorteilhafte Ausführungsform ist im Patentanspruch 7 beschrieben. Dadurch ist es möglich, die Verstärkungs- bzw. Tragelemente an ihren Einsatzbereich anzupassen, sodass beim Einbringen der Bauwerkstoffe das Netz nicht beschädigt werden kann.Another advantageous embodiment is described in claim 7. This makes it possible to adapt the reinforcement or support elements to their area of application, so that the mesh cannot be damaged when the construction materials are introduced.

Vorteilhaft ist weiters eine Ausführung nach Patentanspruch 8, da dadurch das Einputzen bzw. Einarbeiten der Verstärkungselemente in die Bauwerkstoffe erleichtert und eine gute Anpassung derselben an die Oberflächen der Bauwerkskörper erzielt werden kann.An embodiment according to claim 8 is also advantageous, since this makes it easier to plaster in or incorporate the reinforcing elements into the building materials and allows them to be well adapted to the surfaces of the building bodies.

Es ist aber auch eine weitere selbständige im Oberbegriff des Patentanspruches 9 beschriebene Ausführungsform möglich. Diese ist durch die im Kennzeichenteil des Patentanspruches 9 enthaltenen Merkmale definiert. Durch die Verwendung gleichartiger Elektroden können die Nachteile durch einen elektrolytischen Abbau aufgrund von in Bauwerkskörpern bestehenden Potentialdifferenzen vermieden werden. Darüberhinaus kann mit relativ geringen Spannungen bei der Verwendung der Verstärkungselemente als Elektroden bei sogenannten aktiven Elektrokineseanlagen gearbeitet werden, da durch die Verwendung eines Gegenpolschaltgliedes elektrolytische Ablagerungen an der Anode vermieden werden und somit keine Passivierung bzw. Isolierung des am Pluspol anliegenden Netzes gegeben ist.However, a further independent embodiment described in the preamble of claim 9 is also possible. This is defined by the features contained in the characterizing part of claim 9. By using electrodes of the same type, the disadvantages of electrolytic degradation due to potential differences existing in building structures can be avoided. In addition, it is possible to work with relatively low voltages when using the reinforcing elements as electrodes in so-called active electro-kinetic systems, since by using a counter-pole switching element, electrolytic deposits on the anode are avoided and therefore there is no passivation or insulation of the network connected to the positive pole.

Es ist aber auch eine Ausbildung nach Patentanspruch 10 möglich. Eine derartige Schaltung lässt sich sehr einfach in den unterschiedlichen Technologien, wie beispielsweise Relaissteuerung, Transistorsteuerung oder mit integrierten Schaltbausteinen herstellen, sodass eine einfache Anpassung an die unterschiedlichen Einsatzfälle und Umgebungsbedingungen einfach möglich ist.However, training according to claim 10 is also possible. Such a circuit can be produced very easily in the different technologies, such as, for example, relay control, transistor control or with integrated switching modules, so that simple adaptation to the different applications and ambient conditions is possible.

Schliesslich umfasst die Erfindung auch ein eigenständiges Verfahren gemäss dem Oberbegriff des Patentanspruches 11.Finally, the invention also includes an independent method according to the preamble of claim 11.

Dieses Verfahren ist durch die kennzeichnenden Merkmale des Patentanspruches 11 definiert. Das Merkmal des grösseren positiven Zeitintegrals ermöglicht erst den gewünschten elektroosmotischen Effekt, während die negative Spannung allfällige, durch elektrolytische Zersetzung gebildete Stoffe, insbesondere die ungünstigen Gase, in umgekehrter Reaktion beseitigt. Dabei bewirkt die hohe Konzentration der an den Elektroden entstandenen Stoffe eine rasche und bevorzugte Umkehr der chemischen Vorgänge, während der Aufbau des umgekehrten elektrischen Feldes und damit die Umkehrung des elektroosmotischen Effektes vermindert bzw. völlig verhindert wird.This method is defined by the characterizing features of claim 11. The feature of the larger positive time integral enables the desired electroosmotic effect, while the negative voltage eliminates any substances formed by electrolytic decomposition, in particular the unfavorable gases, in a reverse reaction. The high concentration of the substances produced on the electrodes results in a rapid and preferred reversal of the chemical processes, while the build-up of the reversed electric field and thus the reversal of the electroosmotic effect is reduced or completely prevented.

Weitere vorteilhafte Verfahrensweisen sind in den Patentansprüchen 12 und 13 beschrieben.Further advantageous procedures are described in claims 12 and 13.

Vorteilhaft ist auch ein Vorgehen gemäss Patentanspruch 14. Hiebei kann die Spannungsspitze der negativen Periode abgeschnitten werden oder nur der eine bestimmte Spannung überschreitende Teil der Sinusspannung verwendet werden.A procedure according to claim 14 is also advantageous. The voltage peak of the negative period can be cut off or only the part of the sine voltage exceeding a certain voltage can be used.

Der Vorteil des Verfahrens liegt nicht nur in dem verstärkten gewünschten Effekt, der in einem Bruchteil der Zeit, auch bei sehr hohem Wasserdruck bei altem und dickem Mauerwerk zum gewünschten Erfolg führt, sondern auch in der verlässlichen Vermeidung chemischer Zersetzungen des Wassers unter Verhinderung von Gasbildungen oder einer Abscheidung von Schwermetallen, was wiederum zur Zerstörung von Baustoffen führen kann. Es können dabei die gemessenen Effektivspannungen des positiven Anteiles der Wechselspannung grösser als 16 V sein. Dabei werden auch Elektroden aus leitenden oder halbleitenden Kunststoffen nicht angegriffen.The advantage of the process lies not only in the increased desired effect, which leads to the desired success in a fraction of the time, even with very high water pressure with old and thick masonry, but also in the reliable avoidance of chemical decomposition of the water while preventing gas formation or separation of heavy metals, which in turn can lead to the destruction of building materials. The measured effective voltages of the positive portion of the AC voltage can be greater than 16 V. Electrodes made of conductive or semiconducting plastics are not attacked.

Schliesslich sind auch Massnahmen nach Patentanspruch 15 möglich. Dies ermöglicht mit Vorteil die Kombination eines Verstärkungs- bzw. Tragelementes mit der Verwendung als Elektrode für ein auf elektroosmotischem Prinzip arbeitendes Entfeuchtungssystem. Durch die sinnvolle Aufeinanderfolge der einzelnen Verfahrensschritte wird ein optimales Ergebnis beim Einsatz des Verstärkungs- bzw. Tragelementes erreicht.Finally, measures according to claim 15 are also possible. This advantageously enables the combination of a reinforcement or support element with the use as an electrode for a dehumidification system operating on the electroosmotic principle. Due to the sensible sequence of the individual process steps, an optimal result is achieved when using the reinforcement or support element.

Zum besseren Verständnis der Erfindung wird diese im folgenden anhand der in den Zeichnungen dargestellten Ausführungsbeispiele näher erläutert.For a better understanding of the invention, it is explained in more detail below with reference to the exemplary embodiments shown in the drawings.

Es zeigen

  • Fig. 1 eine Draufsicht auf einen netzförmigen Tragkörper, gemäss der Erfindung;
  • Fig. 2 einen netzförmigen Tragkörper nach Figur 1 in schaubildlicher Darstellung, teilweise geschnitten;
  • Fig. 3 einen Faden des Tragkörpers im Schnitt, gemäss den Linien 111-111 in Figur 2;
  • Fig. 4 die Anordnung der erfindungsgemässen, netzförmigen Tragkörper bei gleichzeitiger Verwendung als Elektroden für ein Entfeuchtungssystem;
  • Fig. 5 eine Ausführungsvariante einer auf elektroosmotischem Prinzip arbeitenden Elektro- Kinetik-Anlage, bei der der erfindungsgemässe netzförmige Tragkörper als Verstärkungs- bzw. Tragelement und gleichzeitig als Elektrode eingesetzt wird;
  • Fig. 6 eine Spannungsversorgungsvorrichtung für die erfindungsgemässen Verstärkungs- bzw. Tragelemente, wenn diese als Elektroden für eine Elektro-Kinetik-Anlage verwendet werden.
  • Fig. 7 eine Spannungszeitkurve für die zwischen positivem und negativem Potential wechselnde Spannung, wie sie an die Verstärkungs- bzw. Tragelemente angelegt werden kann, wenn diese als Elektroden einer Entfeuchtungsanlage verwendet werden.
Show it
  • Figure 1 is a plan view of a net-shaped support body, according to the invention.
  • 2 shows a reticulated support body according to FIG. 1 in a diagrammatic representation, partly in section;
  • 3 shows a thread of the support body in section, according to lines 111-111 in FIG. 2;
  • 4 shows the arrangement of the net-shaped support body according to the invention while simultaneously being used as electrodes for a dehumidification system;
  • 5 shows an embodiment variant of an electro-kinetic system operating on the electroosmotic principle, in which the net-shaped support body according to the invention is used as a reinforcement or support element and at the same time as an electrode;
  • Fig. 6 shows a voltage supply device for the reinforcement or support elements according to the invention when these are used as electrodes for an electro-kinetic system.
  • 7 shows a voltage-time curve for the voltage alternating between positive and negative potential, as can be applied to the reinforcement or support elements when these are used as electrodes of a dehumidification system.

In Figur 1 ist ein Tragkörper 1 dargestellt, der als Verstärkungs- bzw. Tragelement für Bauwerkstoffe dient. Dieser Tragkörper 1 ist als Netz 2 ausgebildet.In Figure 1, a support body 1 is shown as a reinforcement or support element for the building serves fabrics. This support body 1 is designed as a network 2.

In das Netz 2 ist eine Stromversorgungsleitung 3 integriert, die durch ein Lahnband 4 gebildet ist. Die Stromversorgungsleitung 3 ist in Längsrichtung - Pfeil 5 - des bandförmigen Netzes 2 etwa mittig zwischen den beiden Längsrändern 6 angeordnet. Das Lahnband 4 besteht, wie über einen Teil seiner Länge angedeutet, aus einer Mehrzahl von Einzellitzen 7, die durch Metallfäden 8 gebildet sind. Die Oberfläche der Metallfäden 8 kann silberbeschichtet sein, oder es wird z.B. Titandraht verwendet, um eine gute Leitfähigkeit und einen geringen Potentialunterschied zwischen der Oberfläche dieser Metallfäden 8 und dem diese umgebenden Kunststoff 9 zu erhalten. Ist der Potentialunterschied gering, so kann sich zwischen den unterschiedlichen Werkstoffen, wie Silber bzw. Titan und dem erfindungsgemässen Kunststoff 9 kaum eine elektromotorische Kraft ausbilden und es fliesst somit kein Strom. Dadurch kommt es aber auch zu keinem Metallabbau, vor allem von jenen Metallen, die ein negativeres Eigenpotential haben, sodass keine Ionen in Lösung gehen.In the network 2, a power supply line 3 is integrated, which is formed by a conveyor belt 4. The power supply line 3 is arranged in the longitudinal direction - arrow 5 - of the band-shaped network 2 approximately centrally between the two longitudinal edges 6. The Lahnband 4 consists, as indicated over part of its length, from a plurality of individual strands 7, which are formed by metal threads 8. The surface of the metal threads 8 can be silver-coated, or e.g. Titanium wire is used to obtain a good conductivity and a small potential difference between the surface of these metal threads 8 and the plastic 9 surrounding them. If the potential difference is small, then an electromotive force can hardly develop between the different materials, such as silver or titanium, and the plastic 9 according to the invention, and therefore no current flows. However, this does not lead to metal degradation, especially of those metals that have a more negative intrinsic potential, so that no ions go into solution.

In Figur 2 ist ein Tragkörper 10 dargestellt, der durch ein Netz 11 gebildet ist. Die einzelnen Fäden 12 bis 14 des Netzes 11 bestehen aus einem Kunststoff 15. Dieser Kunststoff 15 ist im wesentlichen ionenfrei und in Art eines Duroplastes mit makromolekularem Aufbau ausgebildet. Bevorzugt ist dieser Kunststoff 15 z.B. ein Acrylat mit mindestens zum Teil vernetzten Polymeren, welches eine hohe Oberflächenrauhigkeit sowie einen geringen Weichmacheranteil aufweist. Der Kunststoff 15 kann bevorzugt, gemäss der österreichischen Patentschrift 313 588 des gleichen Erfinders ausgebildet sein. Vorteilhaft ist es, wenn der Kunststoff mit Sauerstoff reduzierenden Metallen dotiert ist. Beim Einsatz von einem Netz 11 mit einem derart dotierten Kunststoff 15 als Anode wird die Oxidation der Anode und deren Passivierung ausgeschaltet. Um das Netz auch gegen mechanische Beanspruchungen entsprechend widerstandsfähig zu machen, bzw. die Leitfähigkeit der Netzfäden zu erhöhen, können in diesen Netzfäden Metallfäden 16 bzw. Karbonfäden 17 eingearbeitet sein. Die Metall- bzw. Karbonfäden 16 bzw. 17 sind dabei im Kunststoff 15 der Fäden 13 des Netzes eingearbeitet.In Figure 2, a support body 10 is shown, which is formed by a network 11. The individual threads 12 to 14 of the network 11 consist of a plastic 15. This plastic 15 is essentially ion-free and is designed in the manner of a thermoset with a macromolecular structure. This plastic 15 is preferably e.g. an acrylate with at least partially crosslinked polymers, which has a high surface roughness and a low proportion of plasticizer. The plastic 15 can preferably be designed according to the Austrian patent specification 313 588 by the same inventor. It is advantageous if the plastic is doped with oxygen-reducing metals. When using a network 11 with a plastic 15 doped in this way as the anode, the oxidation of the anode and its passivation is switched off. In order to make the network correspondingly resistant to mechanical stresses or to increase the conductivity of the network threads, metal threads 16 or carbon threads 17 can be incorporated into these network threads. The metal or carbon threads 16 and 17 are incorporated in the plastic 15 of the threads 13 of the network.

Die Ausführungsform in Figur 2 empfiehlt sich weiter, wenn eine Stromversorgungsleitung 18 durch einen Faden 14 des Netzes gebildet ist. In diesem Fall sind in diesen Netzfäden 14 zur Erhöhung der Leitfähigkeit, aber auch zusätzlich zur Erhöhung der mechanischen Festigkeit Metallfäden 16 bzw. Karbonfäden 17 angeordnet, die gegebenenfalls mit einer Silberbeschichtung 19 versehen sein können. Durch diese Silberbeschichtung werden die bereits in Verbindung mit Figur 1 geschilderten Vorteile erreicht. Selbstverständlich ist es auch möglich, um die Leitfähigkeit des gesamten Netzes, und somit einen verstärkten Feldaufbau über die gesamte Netzfläche zu erreichen, die Metall- bzw. Karbonfäden 16, 17 in den Fäden 13 mit einer Silberbeschichtung zu versehen.The embodiment in FIG. 2 is further recommended if a power supply line 18 is formed by a thread 14 of the network. In this case, metal threads 16 or carbon threads 17, which can optionally be provided with a silver coating 19, are arranged in these mesh threads 14 to increase the conductivity, but also in addition to increase the mechanical strength. This silver coating achieves the advantages already described in connection with FIG. 1. Of course, it is also possible to provide the metal or carbon threads 16, 17 in the threads 13 with a silver coating in order to achieve the conductivity of the entire network, and thus an increased field structure over the entire network surface.

Im Rahmen der Erfindung ist es weiters auch möglich, bei der Herstellung des Netzes 11 jeden beliebigen Kunststoff 15, der hochelastisch, biegeweich bzw. biegeschlaff sowie leitfähig ist, zu verwenden. In diesem Fall wird zur Herstellung der gewünschten Oberflächenbeschaffenheit des Netzes 11 das gesamte Netz mit dem Kunststoff 15 überzogen, wie dies im Bereich der einander kreuzenden Fäden 12 und 14 des Netzes 11 angedeutet ist.In the context of the invention, it is also possible to use any plastic 15 which is highly elastic, flexible or limp and conductive, in the manufacture of the network 11. In this case, the entire network is covered with the plastic 15 to produce the desired surface quality of the network 11, as is indicated in the region of the crossing threads 12 and 14 of the network 11.

Die Karbon- bzw. Metallfäden 17 bzw. 16 bilden unabhängig von ihrer Funktion hinsichtlich verbesserter elektrischer Eigenschaften, wie höhere Leitfähigkeit und dgl., ein festigkeitsverstärkendes, fadenförmiges Trägermaterial 20. Das Trägermaterial 20 kann selbstverständlich durch Fäden aus beliebigen Werkstoffen gebildet sein, die Karbon- und Metallfäden werden jedoch deshalb bevorzugt verwendet, da sie im Rahmen der gewünschten erfindungsgemässen Eigenschaften eine gute Kombination zwischen hoher Festigkeit und guter Leitfähigkeit aufweisen.The carbon or metal threads 17 or 16, regardless of their function with regard to improved electrical properties, such as higher conductivity and the like, form a strength-enhancing, thread-like carrier material 20. The carrier material 20 can of course be formed by threads made of any materials that However, metal threads are preferably used because they have a good combination of high strength and good conductivity within the scope of the desired properties according to the invention.

In Figur 3 ist ein Schnitt durch einen Faden 13 des Netzes 11 in vergrössertem Massstab dargestellt. Wie ersichtlich, sind in dem Kunststoff 15 des Fadens 13 Metallfäden 16 bzw. Karbonfäden 17 eingelagert, die zum Teil mit einer Silberbeschichtung 19 versehen sind. Weiters ist aus diesem Schnitt ersichtlich, dass in dem Kunststoff 15 Kohlenstoffbestandteile 21 freischwebend eingelagert sind. Diese freischwebende Anordnung von Kohlenstoffbestandteilen 21 ist deshalb möglich, da der Kunststoff 15 Halbleitereigenschaften besitzt und der Kohlenstoff daher nicht zum Aufbau eines Leitungssystems, sondern nur zur Erhöhung der Leitfähigkeit benötigt wird.FIG. 3 shows a section through a thread 13 of the net 11 on an enlarged scale. As can be seen, 13 metal threads 16 or carbon threads 17 are embedded in the plastic 15 of the thread, some of which are provided with a silver coating 19. Furthermore, it can be seen from this section that carbon components 21 are freely suspended in the plastic 15. This free-floating arrangement of carbon components 21 is possible because the plastic 15 has semiconductor properties and the carbon is therefore not required to build up a line system, but only to increase the conductivity.

In Figur 4 und 5 sind zwei verschiedene Ausführungsvarianten gezeigt, wie der erfindungsgemässen Tragkörper 1 bzw. Netze 2 oder 11 an Baukörpern 22 bzw. 23 angeordnet werden können. Der Baukörper 22 bzw. 23 besteht bei den dargestellten Ausführungsbeispielen beispielsweise aus Ziegelmauerwerk oder Stahlbeton.FIGS. 4 and 5 show two different design variants of how the support body 1 or nets 2 or 11 according to the invention can be arranged on structures 22 and 23, respectively. The building structure 22 or 23 consists, for example, of brick masonry or reinforced concrete in the exemplary embodiments shown.

Bei der Ausführungsform nach Figur 4 sind zwei Netze 24 bzw. 25 über aus resistenten Materialien 26 bestehende Befestigungsmittel 27, z.B. Kunststoffklemmdübel, auf dem Baukörper 22 befestigt. Nachdem das Netz 24 an den Pluspol 28 und das Netz 25 an den Minuspol 29 einer Gleichspannungsquelle 30 einer Spannungsversorgungsvorrichtung 31 angeschlossen ist, werden die Netze 24 und 25 in einen Bauwerkstoff 32, im vorliegenden Fall einen Putzmörtel 33, eingebettet. Der Putzmörtel 33 wird in einer derartigen Dicke aufgetragen, dass die Netze 24 bzw. 25 unterhalb seiner Aussenseite 34 zu liegen kommen. Die Netze 24 bzw. 25 bilden somit eine Anode 35 bzw. eine Kathode 36 einer Elektro-Kinetik-Anlage 37. Um eine wirksame Horizontalsperre gegen das Hochsteigen von Feuchtigkeit 38, die im Fundamentbereich des Baukörpers 22 enthalten ist, zu unterbinden, sind die beiden Netze 24 und 25 in Vertikalrichtung übereinander an der Aussenseite des Bauwerkskörpers angeordnet. Das die Kathode 36 bildende Netz 25 ist im Boden 39 angeordnet, wobei im Bereich des Netzes 25 vorteilhafterweise eine Bodenauswechselung stattfindet, sodass im Bereich des Netzes poröse, gut wasserableitende Schichten angeordnet sind. Bei der in Figur 5 gezeigten Anwendungsform der erfindungsgemässen Tragkörper-bei deren Beschreibung für die gleichen Teile die gleichen Bezugsziffern wie in Figur 4 verwendet werden - ist bedingt durch eine Dicke 40 des Baukörpers 23 das die Anode 35 bildende Netz 24 auf der der Innenseite des Gebäudes zugewandten Seite des Baukörpers 23 und das die Kathode 36 bildende Netz 25 auf dessen Aussenseite befestigt.In the embodiment according to FIG. 4, two nets 24 and 25 are fastened to the building structure 22 by means of fastening means 27 consisting of resistant materials 26, for example plastic clamping plugs. After the network 24 is connected to the positive pole 28 and the network 25 to the negative pole 29 of a DC voltage source 30 of a voltage supply device 31, the networks 24 and 25 are embedded in a building material 32, in the present case a plastering mortar 33. The plastering mortar 33 is applied in such a thickness that the nets 24 and 25 come to lie below its outside 34. The nets 24 and 25 thus form an anode 35 and a cathode 36 of an electro-kinetic system 37. In order to prevent an effective horizontal barrier against the rising of moisture 38, which is contained in the foundation area of the structure 22, the two are Nets 24 and 25 in the vertical direction one above the other on the outside of the structure arranged. The grid 25 forming the cathode 36 is arranged in the bottom 39, with a change of the floor advantageously taking place in the area of the net 25, so that porous, highly water-draining layers are arranged in the area of the net. In the application form of the support body according to the invention shown in FIG. 5 - in the description of which the same reference numbers are used as in FIG. 4 for the same parts - the net 24 forming the anode 35 on the inside of the building is due to a thickness 40 of the structure 23 facing side of the structure 23 and the grid 25 forming the cathode 36 attached to the outside thereof.

Wie beim Ausführungsbeispiel gemäss Figur 4 ist das Netz 25 wieder im Bereich des Bodens 39 angeordnet und es entsteht beim Anlegen der beiden Netze 24, 25 an die Gleichspannungsquelle 30 ein intensives elektrisches Feld 41, welches durch Feldlinien 42 schematisch angedeutet ist.As in the exemplary embodiment according to FIG. 4, the network 25 is again arranged in the region of the bottom 39 and when the two networks 24, 25 are applied to the DC voltage source 30, an intense electrical field 41 is created, which is indicated schematically by field lines 42.

Aufgrund der Anordnung der Anode oberhalb der Kathode wandert die Feuchtigkeit innerhalb des Baukörpers 23 in Richtung der Kathode bzw. wird die im Fundament hochsteigende Feuchtigkeit38 an einem Hochsteigen in dem Baukörper 23 gehindert. Dieser Entfeuchtungs- bzw. Trocknungseffekt ist bei beiden Ausführungsbeispielen in Figur 4 und 5 durch Pfeile 43 symbolisch angedeutet. Der Feldaufbau zwischen den Netzen 24 und 25 in Figur 4 ist ebenfalls durch Feldlinien 42 symbolisch angedeutet.Due to the arrangement of the anode above the cathode, the moisture migrates within the structure 23 in the direction of the cathode or the moisture 38 rising in the foundation is prevented from rising in the structure 23. This dehumidification or drying effect is symbolically indicated by arrows 43 in FIGS. 4 and 5 in both exemplary embodiments. The field structure between the networks 24 and 25 in FIG. 4 is also symbolically indicated by field lines 42.

Um unabhängig von der oder zusätzlich zur Dotierung des Kunststoffes eine Depolarisation der Anode und somit eine Schwächung der Leitfähigkeit sowie eine Verringerung der Feldstärke zu vermeiden, ist der Gleichspannungsquelle 30 ein Gegenpol-Schaltglied 44 zugeordnet. Dieses Gegenpol-Schaltglied 44 bewirkt, dass die Polung in der Elektro-Kinetik-Anlage 37 periodisch und kurzzeitig umgekehrt wird. Die Ionen im elektrischen Feld können sich dadurch nicht ablagern, die Depolarisation wird vermieden. Die derart erzielte hohe Leitfähigkeit im Baukörper 22 bzw. 23 verhindert, dass sich die zwischen den Netzen 24 bzw. 25 wandernden Salzionen ablagern und ausblühen. Durch die hohe Leitfähigkeit wird weiters ein hoher Stromdurchgang im Baukörper 22 bzw. 23 erzielt, sodass ein sehr intensives Feld aufgebaut wird, welches einen intensiven Wassertransport in Richtung der Kathode bewirkt.In order to avoid depolarization of the anode and thus a weakening of the conductivity and a reduction in the field strength regardless of or in addition to the doping of the plastic, the DC voltage source 30 is assigned a counter-pole switching element 44. This opposite pole switching element 44 has the effect that the polarity in the electro-kinetic system 37 is periodically and briefly reversed. As a result, the ions in the electric field cannot be deposited and depolarization is avoided. The high conductivity achieved in this way in the building structure 22 or 23 prevents the salt ions migrating between the networks 24 and 25 from depositing and blooming. Due to the high conductivity, a high current passage in the structure 22 or 23 is also achieved, so that a very intensive field is built up, which causes an intensive water transport in the direction of the cathode.

Selbstverständlich ist es auch möglich, die erfindungsgemässen Netze 2, 11, 24, 25 in zwei verschiedenen Hohenlagen relativ zum Boden 39 anzuordnen und miteinander kurzzuschliessen, d. h., zu verbinden, wodurch sich die natürliche Potentialdifferenz ausgleicht und eine sogenannte Horizontalsperre entsteht, die ein Hochwandern des Wassers über die eingebauten Netze verhindert.Of course, it is also possible to arrange the networks 2, 11, 24, 25 according to the invention in two different high positions relative to the floor 39 and to short-circuit them, i.e. i.e. to connect, which balances out the natural potential difference and creates a so-called horizontal barrier, which prevents the water from migrating up through the built-in networks.

Der Vorteil beim Einsatz der erfindungsgemässen Netze als Verstärkungs- bzw. Tragelement für Bauwerkstoffe liegt vor allem darin, dass durch den speziellen verwendeten Kunststoff, bedingt durch die hohe Oberflächenrauhigkeit und die geringe Schrumpfung, über lange Zeit eine innige Verbindung zwischen dem Bauwerkstoff und dem Verstärkungselement besteht, wodurch Feuchtigkeitsansammlungen im Bereich der Verstärkungselemente und somit nachfolgende Korrosionen ausgeschaltet und eine hohe elektrische Leitfähigkeit des Systems bei Verwendung des Netzes als Elektroden erreicht wird.The advantage of using the networks according to the invention as a reinforcing or supporting element for building materials is, above all, that the special plastic used, due to the high surface roughness and the low shrinkage, ensures an intimate connection between the building material and the reinforcing element over a long period of time , whereby moisture accumulations in the area of the reinforcing elements and thus subsequent corrosion are switched off and a high electrical conductivity of the system is achieved when using the network as electrodes.

In Figur 6 ist eine Spannungsversorgungsvorrichtung 45 für die eine Anode 46 bzw. eine Kathode 47 bildenden erfindungsgemäss ausgeführten Netze 48, 49 gezeigt. Die Spannungsversorgungsvorrichtung umfasst einen Transformator 50, Glättungsdioden 51, ein Gegenpol-Schaltglied 52 sowie ein Zeitglied 53. Das Gegenpol-Schaltglied 52 weist einen parallel zu den Glättungsdioden 51 einer Gleichrichterschaltung 54 angeordneten Impulsschalter 55 auf, der durch einen Transistor 56 gebildet ist. Über das Zeitglied 53 wird für eine bestimmte Zeitdauer der Signaldurchgang durch den Transistor 56 ermöglicht. Durch die dem Gegenpol-Schaltglied 52 zugeordnete Diode 57 wird sichergestellt, dass ein Spannungsdurchgang nur dann möglich ist, wenn an einem Ausgang 58 des Transformators 50 negatives Potential anliegt. Ein Eingang 59 des Impulsschalters 55 liegt am Ausgang 58 einer durch den Transformator 50 gebildeten Gleichspannungsquelle 60 an. Ein Ausgang 61 ist mit einer Zuleitung 62 zur Anode 46 verbunden. Der als Schliesskontakt dienende Transistor 56 wird vom Zeitglied 53 angesteuert. Zwischen der Zuleitung 62 und einer Zuleitung 64 und der Anode 46 bzw. der Kathode 47 ist weiters ein Umschalter 65 vorgesehen, mit dem bedarfsweise die Spannungsversorgung der beiden Netze 48 bzw. 49 umgekehrt werden kann, sodass die Anode als Kathode wirkt bzw. umgekehrt. Desweiteren ist der Spannungsversorgungsvorrichtung 45 ein Stromanzeigegerät 66 zugeordnet. Selbstverständlich ist die Ausbildung dieser Spannungsversorgungsvorrichtung im Rahmen der Erfindung, ohne von dieser abzuweichen, beliebig abwandelbar und es ist anstelle der gezeigten TransistorSchaltung auch möglich, entsprechende Relaissteuerungen oder integrierte Schaltkreise bzw. Mikroprozessoren oder dgl. einzusetzen.FIG. 6 shows a voltage supply device 45 for the networks 48, 49 designed according to the invention, which form an anode 46 or a cathode 47. The voltage supply device comprises a transformer 50, smoothing diodes 51, an opposing pole switching element 52 and a timing element 53. The opposing pole switching element 52 has a pulse switch 55 which is arranged in parallel with the smoothing diodes 51 of a rectifier circuit 54 and is formed by a transistor 56. The signal passage through the transistor 56 is made possible for a certain period of time via the timing element 53. The diode 57 assigned to the opposite pole switching element 52 ensures that a voltage passage is only possible if a negative potential is present at an output 58 of the transformer 50. An input 59 of the pulse switch 55 is present at the output 58 of a DC voltage source 60 formed by the transformer 50. An output 61 is connected to a lead 62 to the anode 46. The transistor 56 serving as a make contact is driven by the timing element 53. Between the supply line 62 and a supply line 64 and the anode 46 or the cathode 47, a changeover switch 65 is also provided, with which the voltage supply of the two networks 48 and 49 can be reversed, if necessary, so that the anode acts as a cathode or vice versa. Furthermore, a current display device 66 is assigned to the voltage supply device 45. Of course, the design of this voltage supply device can be modified as desired within the scope of the invention without deviating from it, and it is also possible to use corresponding relay controls or integrated circuits or microprocessors or the like instead of the transistor circuit shown.

In Figur 7 wird eine bevorzugte Form der Spannungszeitkurve dargestellt. Die positive Sinuskurve 67 einer entsprechend herabtransformierten Netzspannung ist erhalten, während der negative Anteil 68 der Sinuskurve im unteren Spannungsbereich abgeschnitten ist, sodass, solange der negative Anteil der ursprünglichen Sinuskurve eine bestimmte Spannung nicht überschreitet, keine Spannung anliegt und erst, wenn die Sinusspannung die vorgegebene Spannungsgrenze überschreitet, die diese Spannungsgrenze überschreitende Spannung an die Elektroden angelegt wird.A preferred form of the voltage-time curve is shown in FIG. The positive sine curve 67 of a correspondingly stepped down mains voltage is preserved, while the negative part 68 of the sine curve is cut off in the lower voltage range, so that as long as the negative part of the original sine curve does not exceed a certain voltage, no voltage is present and only when the sine voltage reaches the predetermined one Voltage limit is exceeded, the voltage exceeding this voltage limit is applied to the electrodes.

Wenn auch die Verwendung der Netzfrequenz besondere Vorteile bietet, ist das erfindungsgemässe Verfahren nicht auf Sinusspannungen von 50 oder 60 S-1 beschränkt.Although the use of the mains frequency offers particular advantages, the method according to the invention is not restricted to sinusoidal voltages of 50 or 60 S - 1 .

Diese bevorzugte Form der Spannungszeitkurve kann beispielsweise mit der in Figur 6 beschriebenen Spannungsversorgungsvorrichtung 45 erreicht werden. Durch den im Zeitglied 53 angeordneten Kondensator wird der Durchgang durch den Transistor 56 erst nach dem eine gewisse Zeitdauer positives Potential anliegt geöffnet, sodass die Anode 46 mit negativer Spannung beaufschlagt wird. Bei entsprechender Auslegung des Zeitgliedes 53 wird dann bei Unterschreiten dieses vorgewählten Spannungsniveaus die Zufuhr der negativen Spannung über die Zuleitung 62 durch den Transistor 56 wieder gesperrt. Damit entsteht der in Figur 7 gezeigte spezielle Spannungsverlauf.This preferred form of the voltage-time curve can, for example, with the voltage supply device described in Figure 6 45 can be achieved. Through the capacitor arranged in the timing element 53, the passage through the transistor 56 is only opened after the positive potential has been present for a certain period of time, so that the anode 46 is subjected to a negative voltage. With a corresponding design of the timing element 53, the supply of the negative voltage via the lead 62 through the transistor 56 is then blocked again when the preselected voltage level is undershot. This creates the special voltage curve shown in FIG. 7.

Für die vorliegende Erfindung ist bei Verwendung der erfindungsgemässen Verstärkungs- bzw. Tragelemente als Elektroden vorteilhaft, wenn deren Minimalabstand in Vertikalrichtung des Baukörpers zumindest 10 cm beträgt. Bevorzugt ist das die Kathode bildende Netz ca. 30 bis 50 cm unterhalb der Erdbodenoberfläche anzuordnen. Für das erfindungsgemässe Verfahren in Verbindung mit der Spannungsversorgungsvorrichtung 45 ist von ausschlaggebender Bedeutung, dass das Belastungsintegral an einer beliebigen Stelle der Elektroden hinsichtlich der Spannung bzw. der Stromstärke so angesetzt wird, dass die Produktion von agressivem Sauerstoff vernachlässigbar klein ist bzw. sich nur in einer Grössenordnung bewegt, durch die die Verstärkungs- bzw. Tragelemente nicht zerstört werden können.It is advantageous for the present invention when using the reinforcement or support elements according to the invention as electrodes if their minimum distance in the vertical direction of the structure is at least 10 cm. The network forming the cathode is preferably to be arranged approximately 30 to 50 cm below the surface of the ground. For the method according to the invention in connection with the voltage supply device 45, it is of crucial importance that the load integral is set at any point on the electrodes with regard to the voltage or the current intensity in such a way that the production of aggressive oxygen is negligibly small or only in one Order of magnitude moved by which the reinforcement or support elements can not be destroyed.

Claims (15)

1. Reinforcing or carrier element for structural materials, constructed as an electrode for electro- osmotic dehumidification installations, with a net-like carrier body, comprising a conductive synthetic resin at least on its surface, characterised in that the net-like carrier body (1, 10) is an essentially band-shaped net (2, 11, 24, 25, 48, 49) constituted by flexible net strands which is made of synthetic resin and/or coated therewith, and a current supply conductor (3) is connected to the net and extends in the longitudinal direction of the carrier body or band-shaped net (2, 11, 24, 25, 48, 49) and is in contact therewith, which conductor comprises filamentary carrier materials (20) and is also connected to a positive pole (28) of a voltage supply circuit (31, 45) for an electrokinetic installation (37), and in that the net forms an anode.
2. Reinforcing or carrier element according to claim 1, characterised in that the current supply conductor (3) is formed by flattened bands (4) constituted by a plurality of flexible individual strands (7).
3. Reinforcing or carrier element according to one of claims 1 or 2 characterised in that the current supply conductor (3) is formed by carbon filaments (17) or metal filaments (8, 16) for example of titanium or the like, incorporated in the net strands and advantageously silver-coated.
4. Reinforcing or carrier element according to one of claims 1 to 3, characterised in that the electric power supply conductor (3) is disposed approximately centrally between the longitudinal edges (6) of the net.
5. Reinforcing or carrier element according to one of claims 1 to 4, characterised in that the conductive synthetic resin of the electric power supply conductor (3) and/or the net (2, 11, 24, 25, 48, 49) is a substantially ion-free synthetic resin of the thermosetting type with a macromolecular structure, for example an acrylate, with polymers at least partially crosslinked, and has a high surface roughness and a small proportion of plasticiser, and is advantageously doped with an oxygen-reducing metal, for example titanium or boron.
6. Reinforcing or carrier element according to one of claims 1 to 5, characterised in that the synthetic resin (9, 15) surrounding the current supply conductor and the filamentary carrier material (20) has semiconductor properties and a relatively small proportion of carbon, the carbon components (21) being disposed so as to be freely floating in the synthetic resin (9, 15).
7. Reinforcing or carrier element according to one of claims 1 to 6, characterised in that the mesh size is adapted to the structural material (32) surrounding the net (2, 11, 24, 25, 48, 49) and advantageously comprises a mesh size of 5 mm when used as a plaster carrier.
8. Reinforcing or carrier element according to one of claims 1 to 7, characterised in that the net (2, 11, 24, 25, 48, 49) is constructed to be elastic and shape-retaining, and more particularly is of a flexible synthetic resin (9, 15).
9. Reinforcing or carrier element for structural materials, constructed as an electrode for electro- osmotic dehumidification installations, with a net-like carrier body, comprising a conductive synthetic resin at least on its surface, in particular according to one of claims 1 to 8, characterised in that the carrier body (1, 10) is realised as a flexible net (2, 11, 24, 25, 48, 49) which is made of a conductive synthetic resin and/or coated therewith and with which filamentary carrier materials (20) are associated, and in that the net (2, 11, 24, 25, 48, 49) forms a cathode (36, 47) and/or an anode (35, 46) of a voltage supply circuit (31, 45) for an electrokinetic installation (37) and in that the two nets (2, 11, 24, 25, 48, 49) are disposed one above the other in a vertical direction, such that the net (2,11, 25, 49) nearer the ground (39) is connected to the negative pole (29) of a direct current voltage source (30, 60) and the other net (2, 11, 24, 48) is connected to a positive pole (28), and in that a polarity reversal switching member (44, 52) is disposed between the net (2, 11, 24, 48) in contact with the positive pole (28) and the direct current voltage source (30, 60).
10. Reinforcing or carrier element according to claim 9, characterised in that the polarity reversal switching member (44, 52) comprises a pulse switch (55) disposed parallel to stabilizing diodes (51) of a rectifier circuit (54), one input of the switch being connected to the negative pole (29) of a direct current source (30, 60) and its output (61) to a connecting lead (62) to the anode (35, 46), such that a closing contact (63) of the pulse switch (55) is actuated using a timing member (53).
11. A method for the electro-osomotic movement of polar liquids in porous materials (masonry or the like) by supplying an electrical voltage between electrodes, using net-like carrier bodies of a reinforcing or carrier element for structural materials, in particular according to one of claims 1 to 10, characterised in that the carrier body formed as a flexible net is made of a conductive synthetic resin and/or coated therewith and filamentary carrier materials are associated with the latter, and in that two carrier bodies are disposed one above the other in the vertical direction of the structural material, and in that the voltage supplied to them is a voltage alternating between a positive and a negative potential, where the time integral of the voltage with a positive potential exceeds that of the voltage with a negative potential, whereby the voltage with a positive potential advantageously exceeds that with a negative potential.
12. A method according to claim 11, characterised in that the time interval of the voltage supplied with a positive potential exceeds that with a negative potential.
13. A method according to either one of claims 11 or 12, characterised in that the alternating voltage is a sine voltage of mains frequency, such that the voltage of the negative cycle is reduced, and more particularly the voltage peak of the negative cycle is chopped.
14. A method according to claim 13, characterised in that in the negative cycle only the portion (68) of the sine voltage exceeding a predetermined voltage is supplied, and advantageously the sine voltage (67) of the positive half-wave exceeds 6 volts.
15. A method according to one of claims 11 to 14, characterised in that the net (2, 11, 24, 25, 48, 49) is connected to a structural body (22) by chemically or electrochemically resistant materials (26) and subsequently a structural material (32), in particular plaster (33) is applied to the net (2, 11, 24, 25, 48, 49) and is embedded between the external surface (34) of the structural material (32) and the structural body (22), after which the net (2, 11, 24, 25, 48, 49) is connected to the direct current source (30, 60) via the polarity reversal switching member (44, 52) and is actuated by the voltage alternating between a positive and a negative potential.
EP83106099A 1982-08-16 1983-06-22 Reinforcing or supporting element for building material, in particular an electrode Expired EP0100845B1 (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
AT3101/82 1982-08-16
AT0310182A AT375709B (en) 1982-08-16 1982-08-16 METHOD FOR THE ELECTROOSMOTIC DRYING OF MASONRY OD. DGL.

Publications (3)

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EP0100845A2 EP0100845A2 (en) 1984-02-22
EP0100845A3 EP0100845A3 (en) 1984-12-19
EP0100845B1 true EP0100845B1 (en) 1988-12-07

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EP83106099A Expired EP0100845B1 (en) 1982-08-16 1983-06-22 Reinforcing or supporting element for building material, in particular an electrode

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US (2) US4500410A (en)
EP (1) EP0100845B1 (en)
AT (2) AT375709B (en)
DE (1) DE3378644D1 (en)
HU (1) HU189319B (en)

Families Citing this family (22)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2568485B1 (en) * 1984-08-06 1990-03-23 Rhone Poulenc Rech PROTEIN-CONTAINING ELECTROPHORESIS APPARATUS FOR USE, IN PARTICULAR FOR FRACTIONATION OF HUMAN PLASMA
AT387990B (en) * 1985-01-14 1989-04-10 Nogler & Daum Eltac CORROSION PROTECTION METHOD FOR METAL PARTS EMBEDDED IN A PROTECTIVE SHEATH AND APPARATUS FOR CARRYING OUT THE METHOD
US4678554A (en) * 1985-02-21 1987-07-07 Eltac Nogler & Daum Kg Method and installation for generating an electrical field in the soil
DE3610388A1 (en) * 1986-03-27 1987-10-01 Bernhard Dr Wessling STABLE ELECTRODES BASED ON MACROMOLECULAR MATERIALS AND METHOD FOR THEIR USE
AT396700B (en) * 1986-05-07 1993-11-25 Nogler & Daum Eltac SYSTEM FOR DEHUMIDIFYING (DRYING OUT) CONSTRUCTIONS USING ELECTRODES
AT392108B (en) * 1986-07-18 1991-01-25 Fuerhacker Erich Apparatus for drying masonrywork, and keeping it dry, by means of electroosmosis
US5015351A (en) * 1989-04-04 1991-05-14 Miller John B Method for electrochemical treatment of porous building materials, particularly for drying and re-alkalization
DE3736576A1 (en) * 1987-10-28 1989-05-11 Manfred Hilleberg PLASTIC ELECTRODE
NO891034L (en) * 1989-03-10 1990-09-11 Elcraft As PROCEDURE AND APPARATUS FOR MANAGING RELATIVE MOISTURE IN CONCRETE AND WALL CONSTRUCTIONS.
US5092974A (en) * 1990-01-25 1992-03-03 Shinko Pantec Co., Ltd. Electrode and method for compressive and electro-osmotic dehydration
AT404270B (en) * 1992-09-01 1998-10-27 Nogler & Daum Eltac DEVICE AND METHOD FOR DEHUMIDIFYING CONSTRUCTIONS
US5396744A (en) * 1993-10-25 1995-03-14 The United States Of America As Represented By The Administrator Of The U.S. Environmental Protection Agency Electrically induced radon barriers
NO303820B1 (en) * 1995-07-19 1998-09-07 Elektro Puls Teknologier As Method and apparatus for regulating and optimizing the transport of liquid
US5755945A (en) * 1996-10-11 1998-05-26 Electro Pulse Technologies Of America, Inc. Method for dehydrating capillary materials
KR19980080170A (en) * 1997-04-10 1998-11-25 리챠드 더글라스 산다나사미 Vertical drain
US6117295A (en) * 1998-04-15 2000-09-12 Drytronic, Inc. Method for dehydrating a porous material
FR2809426A1 (en) * 2000-05-25 2001-11-30 Thierry Patrice Allain Electrical domestic appliance for removing dampness includes circuit generating pulsed low voltage supply to move water by electro-capillary action
DE10058507A1 (en) * 2000-11-24 2002-06-06 Dutkewitz Wolfgang Wall moisture electro-osmotic removal assembly has electrically-conducting plastic electrodes
US6916411B2 (en) * 2002-02-22 2005-07-12 Lynntech, Inc. Method for electrically controlled demolition of concrete
DE102005019220A1 (en) * 2005-04-22 2006-10-26 Egbert Nensel Electrical osmosis method for carrying out electrical osmosis in draining masonry/buildings applies a pulsed electrical voltage to electrodes in masonry/buildings and their surroundings
EP1813735A1 (en) * 2006-01-27 2007-08-01 Harald Schürer Method for dehumidification of masonry
FR2933721B1 (en) * 2008-07-09 2012-09-28 Freyssinet PROCESS FOR SALT TREATMENT IN POROUS STRUCTURE AND CORRESPONDING DEVICE

Family Cites Families (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3523884A (en) * 1968-05-10 1970-08-11 Systron Donner Corp Method and apparatus for making wall structure impervious to moisture
US4145270A (en) * 1977-05-23 1979-03-20 Institutul De Cercetari In Constructii Si Economia Constructiilor Method of, and apparatus for drying damp basements
US4154430A (en) * 1977-07-15 1979-05-15 Anchor Post Products, Inc. Conductive insulation electrical grounding or charging system for insulation coated chain link fabric
US4208696A (en) * 1977-09-06 1980-06-17 Minnesota Mining And Manufacturing Company Electrically conductive web
DE2927049A1 (en) * 1979-07-04 1981-01-08 Meisel Jun Curt SYSTEM AND SYSTEM FOR DRYING CONSTRUCTIONS

Also Published As

Publication number Publication date
US4500410A (en) 1985-02-19
DE3378644D1 (en) 1989-01-12
EP0100845A3 (en) 1984-12-19
US4600486A (en) 1986-07-15
EP0100845A2 (en) 1984-02-22
AT375709B (en) 1984-09-10
HU189319B (en) 1986-06-30
ATE39149T1 (en) 1988-12-15
ATA310182A (en) 1984-01-15

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