EP0076986A1 - Verfahren zum Färben oder/und Bedrucken von nativer oder regenerierter merzerisierter oder laugierter Zellulose - Google Patents
Verfahren zum Färben oder/und Bedrucken von nativer oder regenerierter merzerisierter oder laugierter Zellulose Download PDFInfo
- Publication number
- EP0076986A1 EP0076986A1 EP82109096A EP82109096A EP0076986A1 EP 0076986 A1 EP0076986 A1 EP 0076986A1 EP 82109096 A EP82109096 A EP 82109096A EP 82109096 A EP82109096 A EP 82109096A EP 0076986 A1 EP0076986 A1 EP 0076986A1
- Authority
- EP
- European Patent Office
- Prior art keywords
- parts
- reactive
- dye
- dyeing
- mercerized
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Withdrawn
Links
- 238000004043 dyeing Methods 0.000 title claims abstract description 19
- 238000000034 method Methods 0.000 title claims abstract description 16
- 239000004627 regenerated cellulose Substances 0.000 title claims 2
- 239000000203 mixture Substances 0.000 claims abstract description 19
- 239000012209 synthetic fiber Substances 0.000 claims abstract description 3
- 229920002994 synthetic fiber Polymers 0.000 claims abstract description 3
- 239000000975 dye Substances 0.000 claims description 46
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 claims description 24
- 229920000742 Cotton Polymers 0.000 claims description 15
- 229910052717 sulfur Inorganic materials 0.000 claims description 12
- 239000011593 sulfur Substances 0.000 claims description 12
- 239000000835 fiber Substances 0.000 claims description 10
- 239000003599 detergent Substances 0.000 claims description 4
- GIKMWFAAEIACRF-UHFFFAOYSA-N 2,4,5-trichloropyrimidine Chemical compound ClC1=NC=C(Cl)C(Cl)=N1 GIKMWFAAEIACRF-UHFFFAOYSA-N 0.000 claims description 3
- 239000000463 material Substances 0.000 claims description 3
- 239000000985 reactive dye Substances 0.000 claims description 3
- SPSSDDOTEZKOOV-UHFFFAOYSA-N 2,3-dichloroquinoxaline Chemical compound C1=CC=C2N=C(Cl)C(Cl)=NC2=C1 SPSSDDOTEZKOOV-UHFFFAOYSA-N 0.000 claims description 2
- HXBAGLRPNSWXRY-UHFFFAOYSA-N 2-chloro-4-fluoropyrimidine Chemical compound FC1=CC=NC(Cl)=N1 HXBAGLRPNSWXRY-UHFFFAOYSA-N 0.000 claims description 2
- XPVPPZLJRZSNTD-UHFFFAOYSA-N 5-fluorotriazine Chemical compound FC1=CN=NN=C1 XPVPPZLJRZSNTD-UHFFFAOYSA-N 0.000 claims description 2
- 238000009993 causticizing Methods 0.000 claims description 2
- 238000007730 finishing process Methods 0.000 claims description 2
- 229920000728 polyester Polymers 0.000 claims description 2
- 239000004094 surface-active agent Substances 0.000 claims description 2
- JUJWROOIHBZHMG-UHFFFAOYSA-N Pyridine Chemical compound C1=CC=NC=C1 JUJWROOIHBZHMG-UHFFFAOYSA-N 0.000 claims 1
- CZPWVGJYEJSRLH-UHFFFAOYSA-N Pyrimidine Chemical compound C1=CN=CN=C1 CZPWVGJYEJSRLH-UHFFFAOYSA-N 0.000 claims 1
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 claims 1
- 239000004744 fabric Substances 0.000 abstract description 25
- 229920003043 Cellulose fiber Polymers 0.000 abstract 2
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 22
- 239000003086 colorant Substances 0.000 description 19
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 description 13
- 239000005864 Sulphur Substances 0.000 description 12
- 235000002639 sodium chloride Nutrition 0.000 description 12
- 239000007787 solid Substances 0.000 description 12
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 11
- INOIOAWTVPHTCJ-UHFFFAOYSA-N 6-acetamido-4-hydroxy-3-[[4-(2-sulfooxyethylsulfonyl)phenyl]diazenyl]naphthalene-2-sulfonic acid Chemical compound CC(=O)NC1=CC=C2C=C(C(N=NC3=CC=C(C=C3)S(=O)(=O)CCOS(O)(=O)=O)=C(O)C2=C1)S(O)(=O)=O INOIOAWTVPHTCJ-UHFFFAOYSA-N 0.000 description 8
- 239000011780 sodium chloride Substances 0.000 description 8
- 235000011121 sodium hydroxide Nutrition 0.000 description 8
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 7
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 description 7
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 description 6
- 238000005517 mercerization Methods 0.000 description 6
- WVDDGKGOMKODPV-UHFFFAOYSA-N Benzyl alcohol Chemical compound OCC1=CC=CC=C1 WVDDGKGOMKODPV-UHFFFAOYSA-N 0.000 description 4
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 4
- 239000004202 carbamide Substances 0.000 description 4
- 150000003839 salts Chemical class 0.000 description 4
- 239000011734 sodium Substances 0.000 description 4
- 229910052708 sodium Inorganic materials 0.000 description 4
- BRLQWZUYTZBJKN-UHFFFAOYSA-N Epichlorohydrin Chemical compound ClCC1CO1 BRLQWZUYTZBJKN-UHFFFAOYSA-N 0.000 description 3
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 description 3
- 229920002678 cellulose Polymers 0.000 description 3
- 239000001913 cellulose Substances 0.000 description 3
- LQZZUXJYWNFBMV-UHFFFAOYSA-N dodecan-1-ol Chemical compound CCCCCCCCCCCCO LQZZUXJYWNFBMV-UHFFFAOYSA-N 0.000 description 3
- 238000006386 neutralization reaction Methods 0.000 description 3
- 229910000029 sodium carbonate Inorganic materials 0.000 description 3
- 238000011282 treatment Methods 0.000 description 3
- HZAXFHJVJLSVMW-UHFFFAOYSA-N 2-Aminoethan-1-ol Chemical compound NCCO HZAXFHJVJLSVMW-UHFFFAOYSA-N 0.000 description 2
- SVTBMSDMJJWYQN-UHFFFAOYSA-N 2-methylpentane-2,4-diol Chemical compound CC(O)CC(C)(C)O SVTBMSDMJJWYQN-UHFFFAOYSA-N 0.000 description 2
- STOOUUMSJPLRNI-UHFFFAOYSA-N 5-amino-4-hydroxy-3-[[4-[4-[(4-hydroxyphenyl)diazenyl]phenyl]phenyl]diazenyl]-6-[(4-nitrophenyl)diazenyl]naphthalene-2,7-disulfonic acid Chemical compound OS(=O)(=O)C1=CC2=CC(S(O)(=O)=O)=C(N=NC=3C=CC(=CC=3)C=3C=CC(=CC=3)N=NC=3C=CC(O)=CC=3)C(O)=C2C(N)=C1N=NC1=CC=C([N+]([O-])=O)C=C1 STOOUUMSJPLRNI-UHFFFAOYSA-N 0.000 description 2
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 2
- PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 description 2
- UIIMBOGNXHQVGW-UHFFFAOYSA-M Sodium bicarbonate Chemical compound [Na+].OC([O-])=O UIIMBOGNXHQVGW-UHFFFAOYSA-M 0.000 description 2
- 239000001045 blue dye Substances 0.000 description 2
- 239000001049 brown dye Substances 0.000 description 2
- 239000003518 caustics Substances 0.000 description 2
- 239000000982 direct dye Substances 0.000 description 2
- UCYWDWSKWUEDSC-UHFFFAOYSA-M disodium;sulfanide;nonahydrate Chemical compound O.O.O.O.O.O.O.O.O.[Na+].[Na+].[SH-] UCYWDWSKWUEDSC-UHFFFAOYSA-M 0.000 description 2
- 239000002270 dispersing agent Substances 0.000 description 2
- 238000001035 drying Methods 0.000 description 2
- KYIDJMYDIPHNJS-UHFFFAOYSA-N ethanol;octadecanoic acid Chemical compound CCO.CCCCCCCCCCCCCCCCCC(O)=O KYIDJMYDIPHNJS-UHFFFAOYSA-N 0.000 description 2
- 238000005187 foaming Methods 0.000 description 2
- 239000001046 green dye Substances 0.000 description 2
- 238000009434 installation Methods 0.000 description 2
- 229910052979 sodium sulfide Inorganic materials 0.000 description 2
- GRVFOGOEDUUMBP-UHFFFAOYSA-N sodium sulfide (anhydrous) Chemical compound [Na+].[Na+].[S-2] GRVFOGOEDUUMBP-UHFFFAOYSA-N 0.000 description 2
- UGCDBQWJXSAYIL-UHFFFAOYSA-N vat blue 6 Chemical compound O=C1C2=CC=CC=C2C(=O)C(C=C2Cl)=C1C1=C2NC2=C(C(=O)C=3C(=CC=CC=3)C3=O)C3=CC(Cl)=C2N1 UGCDBQWJXSAYIL-UHFFFAOYSA-N 0.000 description 2
- JXUKQCUPTNLTCS-UHFFFAOYSA-N vat green 1 Chemical compound C1=CC=C[C]2C(=O)C(C3=C45)=CC=C4C(C4=C67)=CC=C7C(=O)[C]7C=CC=CC7=C6C=C(OC)C4=C5C(OC)=CC3=C21 JXUKQCUPTNLTCS-UHFFFAOYSA-N 0.000 description 2
- KJPJZBYFYBYKPK-UHFFFAOYSA-N vat yellow 1 Chemical compound C12=CC=CC=C2C(=O)C2=CC=C3N=C4C5=CC=CC=C5C(=O)C5=C4C4=C3C2=C1N=C4C=C5 KJPJZBYFYBYKPK-UHFFFAOYSA-N 0.000 description 2
- UOCLXMDMGBRAIB-UHFFFAOYSA-N 1,1,1-trichloroethane Chemical compound CC(Cl)(Cl)Cl UOCLXMDMGBRAIB-UHFFFAOYSA-N 0.000 description 1
- IXPNQXFRVYWDDI-UHFFFAOYSA-N 1-methyl-2,4-dioxo-1,3-diazinane-5-carboximidamide Chemical compound CN1CC(C(N)=N)C(=O)NC1=O IXPNQXFRVYWDDI-UHFFFAOYSA-N 0.000 description 1
- ORLGPUVJERIKLW-UHFFFAOYSA-N 5-chlorotriazine Chemical compound ClC1=CN=NN=C1 ORLGPUVJERIKLW-UHFFFAOYSA-N 0.000 description 1
- ONMOULMPIIOVTQ-UHFFFAOYSA-N 98-47-5 Chemical compound OS(=O)(=O)C1=CC=CC([N+]([O-])=O)=C1 ONMOULMPIIOVTQ-UHFFFAOYSA-N 0.000 description 1
- BVKZGUZCCUSVTD-UHFFFAOYSA-M Bicarbonate Chemical compound OC([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-M 0.000 description 1
- 102100022404 E3 ubiquitin-protein ligase Midline-1 Human genes 0.000 description 1
- 101710102210 E3 ubiquitin-protein ligase Midline-1 Proteins 0.000 description 1
- 239000002202 Polyethylene glycol Substances 0.000 description 1
- 235000021355 Stearic acid Nutrition 0.000 description 1
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 239000002671 adjuvant Substances 0.000 description 1
- 230000006399 behavior Effects 0.000 description 1
- 235000019445 benzyl alcohol Nutrition 0.000 description 1
- ZBNARPCCDMHDDV-UHFFFAOYSA-N chembl1206040 Chemical compound C1=C(S(O)(=O)=O)C=C2C=C(S(O)(=O)=O)C(N=NC3=CC=C(C=C3C)C=3C=C(C(=CC=3)N=NC=3C(=CC4=CC(=CC(N)=C4C=3O)S(O)(=O)=O)S(O)(=O)=O)C)=C(O)C2=C1N ZBNARPCCDMHDDV-UHFFFAOYSA-N 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 235000021189 garnishes Nutrition 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 229940051250 hexylene glycol Drugs 0.000 description 1
- 239000010446 mirabilite Substances 0.000 description 1
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 description 1
- OQCDKBAXFALNLD-UHFFFAOYSA-N octadecanoic acid Natural products CCCCCCCC(C)CCCCCCCCC(O)=O OQCDKBAXFALNLD-UHFFFAOYSA-N 0.000 description 1
- 229920001223 polyethylene glycol Polymers 0.000 description 1
- 238000004904 shortening Methods 0.000 description 1
- 239000000344 soap Substances 0.000 description 1
- 239000000661 sodium alginate Substances 0.000 description 1
- 235000010413 sodium alginate Nutrition 0.000 description 1
- 229940005550 sodium alginate Drugs 0.000 description 1
- 235000017557 sodium bicarbonate Nutrition 0.000 description 1
- 229910000030 sodium bicarbonate Inorganic materials 0.000 description 1
- JVBXVOWTABLYPX-UHFFFAOYSA-L sodium dithionite Chemical compound [Na+].[Na+].[O-]S(=O)S([O-])=O JVBXVOWTABLYPX-UHFFFAOYSA-L 0.000 description 1
- HYHCSLBZRBJJCH-UHFFFAOYSA-N sodium polysulfide Chemical compound [Na+].S HYHCSLBZRBJJCH-UHFFFAOYSA-N 0.000 description 1
- 229910052938 sodium sulfate Inorganic materials 0.000 description 1
- 235000011152 sodium sulphate Nutrition 0.000 description 1
- LJRGBERXYNQPJI-UHFFFAOYSA-M sodium;3-nitrobenzenesulfonate Chemical compound [Na+].[O-][N+](=O)C1=CC=CC(S([O-])(=O)=O)=C1 LJRGBERXYNQPJI-UHFFFAOYSA-M 0.000 description 1
- 239000007921 spray Substances 0.000 description 1
- 239000008117 stearic acid Substances 0.000 description 1
- 239000000988 sulfur dye Substances 0.000 description 1
- 239000004753 textile Substances 0.000 description 1
- 210000001519 tissue Anatomy 0.000 description 1
- 230000001052 transient effect Effects 0.000 description 1
- 239000000984 vat dye Substances 0.000 description 1
Classifications
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
- D06M11/32—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond
- D06M11/36—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond with oxides, hydroxides or mixed oxides; with salts derived from anions with an amphoteric element-oxygen bond
- D06M11/38—Oxides or hydroxides of elements of Groups 1 or 11 of the Periodic Table
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
- D06P1/22—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using vat dyestuffs including indigo
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
- D06P1/30—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using sulfur dyes
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P3/00—Special processes of dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form, classified according to the material treated
- D06P3/58—Material containing hydroxyl groups
- D06P3/60—Natural or regenerated cellulose
- D06P3/62—Natural or regenerated cellulose using direct dyes
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P3/00—Special processes of dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form, classified according to the material treated
- D06P3/58—Material containing hydroxyl groups
- D06P3/60—Natural or regenerated cellulose
- D06P3/66—Natural or regenerated cellulose using reactive dyes
Definitions
- cellulosic fibers can be mercerized with mercerizing liquors and then dyed.
- Mercerization that is to say treatment with, for example, sodium hydroxide, is a known finishing process for cotton. Mercerization processes are carried out in a variety of ways. But the thread or fabric is always rinsed or neutralized after mercerization and before dyeing to get rid of the free mercerizing lye adhering to it.
- the present invention relates to a process for dyeing natural or regenerated cellulosic fibers and their mixtures, mercerized with an alkaline or caustic solution, characterized in that the mercerization solution has inherent in mercerized cellulose is left completely or in part, pending dyeing or printing of threads or fabrics.
- the subject of the invention also relates to natural or regenerated cellulosic fibers and their mixtures dyed according to this method and preferably in the form of knitted textiles.
- mercerized cellulose Under mercerized cellulose is meant the mercerized cotton and its blends with synthetic fibers, and primarily the polyester or regenerated cellulosic fibers, said fibers having p û be treated or not before mercerizing or causticizing, in order to impart their transient changes or definitive of their characteristics, their behaviors concerning hydrophility, affinity, resistance or others.
- the usual processes with reactive, tank or direct dyes are taken into account. It should preferably be dyed immediately after mercerization itself, either on the mercerization installation, or on a neighboring or next installation.
- the suitable reactive dyes are those usually used for dyeing cellulose, knowing that the dyeing is carried out according to conditions known per se, but characterized by short bath ratios, in particular for the threads.
- the suitable reactive dyes are preferably fluorochloropyr midin, monofluorotriazine, dichlorotryazine, trichloropyrimidine, dichlorochinoxaline, and methyl-sulfonated -chloro-methyl-pyrimidine, knowing that the dyes may contain more than one reactive group.
- Dyeing begins as usual at 10 to 25 ° C, the bath containing in addition to the dye, from 10 to 80 g / 1 of non-foaming reference p salt, with or without a surfactant of non-foaming preference; then it is heated to 30 - 40 ° C. If the bath additionally contains 5 to 40 g / l of sodium carbonate, we start at 30 or 40 ° and heat to 50 or 60 ° C.
- the dye bath usually contains 20 to 80 g / l of salt as well as the appropriate additives. We start dyeing at 40 or 50 ° C and heat to 70 - 80 ° C. If the bath additionally contains 5 to 40 g / l of sodium carbonate, it is started at 60 - 70 ° C and heated to 90 - 98 ° C.
- the dye bath contains 5 to 20 g / l of salt and the vat dye as well as the appropriate adjuvants. Then, the mixture is heated to 40-70 ° and 1 to 2 g / 1 of caustic soda and 1 to 10 g / 1 of sodium hydrosulfite are added.
- the bath contains 1 to 10 g / l of salt and the dye. We start to dye at 40 - 50 ° C, heat to 80 - 90 ° C and rinse after 30 minutes.
- a dye bath 1000 parts of water at 40 ° C. is filled with 30 parts of sodium carbonate 1 part of an adduct of epichlorohydrin with stearic acid monoethanol and 100 parts of mercerized wire or fabric.
- the mixture is heated to 60 ° C. and treated for 15 minutes.
- a dye bath (1000 parts of water) is filled at 20 ° with 1 part of an epichlorohydrin adduct with stearic acid monoethanol and 300 parts of mercerized cotton thread or fabric.
- a cotton cloth On a rower, a cotton cloth is mercerized at 120 ° with caustic soda. The fabric is dried on the rower and it is fouled with a bath containing, for 100 parts of water.
- CI Reactive Brown 24 dye 100 parts of urea and 5 parts of sodium alginate.
- the fabric is then dried continuously and the dye is fixed continuously for 60 seconds at 150 °. After rinsing and soaping the fabric, a solid, intense brown color is obtained.
- the product is then sprayed for three minutes at 102 ° and the dye is fixed. After rinsing and soaping the fabric, a solid, shiny green color is obtained.
Landscapes
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Coloring (AREA)
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE3138892 | 1981-09-30 | ||
DE3138892 | 1981-09-30 |
Publications (1)
Publication Number | Publication Date |
---|---|
EP0076986A1 true EP0076986A1 (de) | 1983-04-20 |
Family
ID=6143040
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP82109096A Withdrawn EP0076986A1 (de) | 1981-09-30 | 1982-09-30 | Verfahren zum Färben oder/und Bedrucken von nativer oder regenerierter merzerisierter oder laugierter Zellulose |
Country Status (5)
Country | Link |
---|---|
EP (1) | EP0076986A1 (de) |
GR (1) | GR77669B (de) |
PT (1) | PT75628B (de) |
WO (1) | WO1983001261A1 (de) |
ZA (1) | ZA827102B (de) |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP0137989A2 (de) * | 1983-09-16 | 1985-04-24 | Brückner Apparatebau GmbH | Verfahren zur Nassbehandlung von Textilware |
FR2661927A1 (fr) * | 1990-05-11 | 1991-11-15 | Sandoz Sa | Procede pour le mercerisage et la teinture au mouille de materiau cellulosique humide. |
Citations (9)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2892668A (en) * | 1956-02-14 | 1959-06-30 | Celanese Corp | Coloring of cellulose-cellulose triacetate textiles |
DE1948995A1 (de) * | 1969-09-27 | 1971-04-15 | Basf Ag | Verfahren zum gleichzeitigen Laugieren oder Mercerisieren und Faerben von Textilgut |
US3824076A (en) * | 1972-09-25 | 1974-07-16 | Kane And Co | Liquid ammonia-caustic dye solution and dyeing therewith |
US3892521A (en) * | 1972-05-18 | 1975-07-01 | Omnium De Prospective Ind Sa | Process for dyeing cellulosic materials |
EP0013220A1 (de) * | 1978-12-19 | 1980-07-09 | Société Linvosges Société anonyme dite: | Verfahren zum Behandeln von mit Küpenfarbstoff stückweise gefärbtem Gewebe |
GB2073269A (en) * | 1980-02-22 | 1981-10-14 | Pamutnyomoipari Vallalat | Process for the production of crepe fabrics |
DE3121043A1 (de) * | 1980-06-04 | 1982-03-11 | Sandoz-Patent-GmbH, 7850 Lörrach | Verfahren zum bedrucken von cellulosefasern mit reaktivfarbstoffen |
DE3129990A1 (de) * | 1980-07-31 | 1982-03-11 | Výzkumný ústav zušlecht'ovací, Dvur Králové nad Labem | Verfahren zur vorbehandlung von cellulose enthaltenden textilmaterialien |
WO1982002566A1 (en) * | 1981-01-19 | 1982-08-05 | Balland Jean | Method for dyeing with reactive dyestuffs applied by leaching on cellulose fibers,alone or mixed with synthetic fibers |
Family Cites Families (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CH371087A (de) * | 1961-03-14 | 1963-04-30 | Sandoz Ag | Verfahren zum Färben von Textilfasern aus Cellulose mit Reaktivfarbstoffen |
-
1982
- 1982-09-28 ZA ZA827102A patent/ZA827102B/xx unknown
- 1982-09-29 GR GR69401A patent/GR77669B/el unknown
- 1982-09-29 PT PT75628A patent/PT75628B/pt unknown
- 1982-09-30 EP EP82109096A patent/EP0076986A1/de not_active Withdrawn
- 1982-09-30 WO PCT/EP1982/000219 patent/WO1983001261A1/en unknown
Patent Citations (9)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2892668A (en) * | 1956-02-14 | 1959-06-30 | Celanese Corp | Coloring of cellulose-cellulose triacetate textiles |
DE1948995A1 (de) * | 1969-09-27 | 1971-04-15 | Basf Ag | Verfahren zum gleichzeitigen Laugieren oder Mercerisieren und Faerben von Textilgut |
US3892521A (en) * | 1972-05-18 | 1975-07-01 | Omnium De Prospective Ind Sa | Process for dyeing cellulosic materials |
US3824076A (en) * | 1972-09-25 | 1974-07-16 | Kane And Co | Liquid ammonia-caustic dye solution and dyeing therewith |
EP0013220A1 (de) * | 1978-12-19 | 1980-07-09 | Société Linvosges Société anonyme dite: | Verfahren zum Behandeln von mit Küpenfarbstoff stückweise gefärbtem Gewebe |
GB2073269A (en) * | 1980-02-22 | 1981-10-14 | Pamutnyomoipari Vallalat | Process for the production of crepe fabrics |
DE3121043A1 (de) * | 1980-06-04 | 1982-03-11 | Sandoz-Patent-GmbH, 7850 Lörrach | Verfahren zum bedrucken von cellulosefasern mit reaktivfarbstoffen |
DE3129990A1 (de) * | 1980-07-31 | 1982-03-11 | Výzkumný ústav zušlecht'ovací, Dvur Králové nad Labem | Verfahren zur vorbehandlung von cellulose enthaltenden textilmaterialien |
WO1982002566A1 (en) * | 1981-01-19 | 1982-08-05 | Balland Jean | Method for dyeing with reactive dyestuffs applied by leaching on cellulose fibers,alone or mixed with synthetic fibers |
Non-Patent Citations (4)
Title |
---|
CHEMICAL ABSTRACTS, vol. 93, no. 20, 27 novembre 1980, page 62, no. 187644y, Columbus Ohio (USA); * |
CHEMICAL ABSTRACTS, vol. 95, no. 10, 7 septembre 1981, page 58, no. 82297a, Columbus Ohio (USA); * |
TEXTILE CHEMIST AND COLORIST, vol. 13, no. 4, avril 1981, pages 85-91, Research Triangle Park, North Carolina (USA); * |
TEXTILVEREDLUNG, vol. 13, no. 12, 1978, pages 486-489, Basel (CH); * |
Cited By (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP0137989A2 (de) * | 1983-09-16 | 1985-04-24 | Brückner Apparatebau GmbH | Verfahren zur Nassbehandlung von Textilware |
EP0137989A3 (de) * | 1983-09-16 | 1985-06-05 | Brückner Apparatebau GmbH | Verfahren zur Nassbehandlung von Textilware |
FR2661927A1 (fr) * | 1990-05-11 | 1991-11-15 | Sandoz Sa | Procede pour le mercerisage et la teinture au mouille de materiau cellulosique humide. |
GB2244723A (en) * | 1990-05-11 | 1991-12-11 | Sandoz Ltd | A process for wet-on-wet mercerization and dyeing of cellulose material |
GB2244723B (en) * | 1990-05-11 | 1994-05-04 | Sandoz Ltd | A process for wet-on-wet mercerization and dyeing of cellulose material |
Also Published As
Publication number | Publication date |
---|---|
PT75628B (fr) | 1985-01-08 |
WO1983001261A1 (en) | 1983-04-14 |
PT75628A (fr) | 1982-10-01 |
GR77669B (de) | 1984-09-25 |
ZA827102B (en) | 1983-07-27 |
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