EP0066915B1 - Reinigungsmittelzusammensetzung enthaltend einen wirkungsfördernden Zusatz und ein Kopolymer zum Gewährleisten der Verträglichkeit desselben - Google Patents

Reinigungsmittelzusammensetzung enthaltend einen wirkungsfördernden Zusatz und ein Kopolymer zum Gewährleisten der Verträglichkeit desselben Download PDF

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Publication number
EP0066915B1
EP0066915B1 EP82200602A EP82200602A EP0066915B1 EP 0066915 B1 EP0066915 B1 EP 0066915B1 EP 82200602 A EP82200602 A EP 82200602A EP 82200602 A EP82200602 A EP 82200602A EP 0066915 B1 EP0066915 B1 EP 0066915B1
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EP
European Patent Office
Prior art keywords
detergent composition
range
copolymeric
alkyl
detergent
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Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
EP82200602A
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English (en)
French (fr)
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EP0066915A3 (en
EP0066915A2 (de
Inventor
Robertus J.C. Koster
André Baeck
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Procter and Gamble European Technical Center
Procter and Gamble Co
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Procter and Gamble European Technical Center
Procter and Gamble Co
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Application filed by Procter and Gamble European Technical Center, Procter and Gamble Co filed Critical Procter and Gamble European Technical Center
Priority to AT82200602T priority Critical patent/ATE30738T1/de
Publication of EP0066915A2 publication Critical patent/EP0066915A2/de
Publication of EP0066915A3 publication Critical patent/EP0066915A3/en
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    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/37—Polymers
    • C11D3/3746—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • C11D3/3757—(Co)polymerised carboxylic acids, -anhydrides, -esters in solid and liquid compositions

Definitions

  • This invention relates to the detergent utilization of certain copolymeric ingredients in a compatibilizing functionality in conjunction with performance additives.
  • the copolymeric ingredient is prepared from an ethylenically unsaturated carboxylic acid and an ethylenically unsaturated dicarboxylic acid.
  • Preferred monomers are acrylic and methacrylic acids on one hand and maleic and citraconic acids on the other hand.
  • the copolymeric agent was found to be especially suitable for enhancing the compatibility of detergent additives which are known to be sensitive to various conditions inclusive of prolonged storage, temperature, alkalinity, and/or laundry conditions.
  • the copolymeric compatibilizing agent is capable of procuring, in contradistinction to their art-established functionality, unexpected transfer properties in relation to specific detergent additives. These transfer properties go against the prevailing opinion according to which comparable copolymeric adjuvants serve as deposition inhibitors, and consequently diminish the physical contact between detergent ingredients and e.g. the fiber.
  • the copolymer comprises a large majority of the (meth)acrylic acid monomer FR-A-2388045, The Procter & Gamble Company, published November 17, 1978, pertains to detergent compositions containing surface-active agents, builders and a binary system based on not more than 4% of a polyphosphonate and not more than 4% of a polymeric ingredient which can be represented by the copolymers obtained from the polymerization of (meth)-acrylic acid and maleic anhydride.
  • the copolymeric ingredient is claimed to provide effective active oxygen regulation.
  • copolymeric ingredient of the invention herein can be used beneficially with a view to secure very desirable performance benefits upon use in combination with particular detergent additives with the proviso that the copolymeric ingredient is preferably used in excess levels in relation to a given performance additive.
  • the performance additives are present in an amount from 0.002% to 5% by weight.
  • the copolymeric ingredient is prepared from an ethylenically unsaturated carboxylic acid monomer having not more than five carbon atoms and from an ethylenically unsaturated dicarboxylic acid monomer having not more than six carbon atoms, whereby these monomers are copolymerized in a molar proportion of 1:4 to 4:1.
  • the weight ratio of the copolymeric ingredient to the performance additives is from 500:1 to 1:5.
  • Performance additives for use in combination with the copolymeric ingredients are selected from water-soluble porphine photoactivators such as mixtures of sulfonated metal phthalocyanines; and renewable polyamine or amine oxide soil release agents.
  • the invention herein comprises at least three major parameters, namely: a conventional detergent matrix comprising surface-active agents and builders; a detergent performance additive; and a specific copolymeric ingredient.
  • major parameters of the invention are described in more detail hereinafter.
  • percent indications represent “percent by weight” indications.
  • the detergent matrix of the compositions of this invention can also contain other major components according to the particular needs and/or the physical state of the invention.
  • the compositions herein can be solid, pasty or liquid.
  • Major amounts of pH regulants, inert fillers like sodium sulfate, water and/or organic solvents like hydrocarbons and/or lower alcohols can be applied as is well-known in the art.
  • the detergent matrix can also contain major levels of bleaching agents, for example, oxygen bleach agents such as perborate, percarbonate, perpyrophosphate, persilicate or, more in general, all oxygen-bleach agents which are known to be suitable for use in detergent compositions in the established levels.
  • the copolymeric ingredient consists of an ethylenically unsaturated monocarboxylic acid monomer having not more than 5, preferably 3 or 4, carbon atoms, and an ethylenically unsaturated dicarboxylic acid monomer having not more than 6, preferably 4 carbon atoms, whereby the molar ratio of the monomers is in the range from 1:4 to 4:1 (i.e., monocarboxylic acid:dicarboxylic acid).
  • Suitable examples of the monocarboxylic acid monomer are: acrylic acid, methacrylic acid and vinyl acetic acid. Acrylic and methacrylic acids are preferred.
  • Suitable examples of the dicarboxylic acid monomers are: maleic acid; fumaric acid; citraconic acid; and mesaconic acid. Preferred dicarboxylic acids are maleic acid and citraconic acid.
  • the copolymeric ingredient can be further defined with the aid of the calcium sequestration value. These values can be measured by nephelometric titration methods (as described in literature
  • the sequestration value is expressed in mgCaC0 3 /gram of copolymeric ingredient.
  • the calcium sequestration value of the copolymeric ingredient is preferably in the range from 300-900 mgCaC0 3 /g.
  • the performance additives herein are present in an amount from 0.002% to 5%. Depending upon the particular functionality of the additive and the planned use of the final detergent composition, the preferred usage ranges for the individual additives vary from additive to additive.
  • performance additive as used herein is meant to express that the specific ingredient is added either to cure a deficiency of the general detergent matrix and/or to provide special laundry and cleaning benefits.
  • a class of performance additives that can be utilized beneficially in combination with the copolymeric agent is represented by a photoactivator, also frequently termed a photosensitizer.
  • the photoactivator is a porphine of a mono-, di-, tri-, or tetraaza porphine solubilized with anionic, nonionic, and/or cationic substituent groups and metal free or metallated with Zn(II), Ca(II), Cd(II), Mg(II), Sc(III), AI(III), or Sn(IV).
  • Preferred metal-ions forthe photoactivator are zinc and aluminum.
  • the photoactivator is frequently used in low levels, e.g., in the level from about 20 ppm to 2000 ppm.
  • the photoactivator is generally used in combination with a carrier material such as polyphosphates, sulfates, a.s.o.
  • a carrier material such as polyphosphates, sulfates, a.s.o.
  • the level of such photoactivator particles represents from 0.1 % to 1% of the detergent composition.
  • the photoactivator is believed to exhibit its activity in the direct environment of the fiber possibly in combination with perborate.
  • the copolymeric ingredient favors this transfer of photoactivator to the fiber in presence of the other components in the laundry liquor at the applicable temperatures, e.g., laundry temperatures in the range from up to about 60°C or up to the boil.
  • a water-soluble photoactivator used in the specified levels can be represented by the porphine activators of European Patent Application 0003149.
  • the weight ratio of copolymer to photoactivator performance additive is frequently in the range from 500:1 to 7:1.
  • the copolymeric ingredient was also found to be effective in combination with additive levels of renewable soil release agents as described in EP-A-0042187 and EP-A-0042188.
  • the copolymeric ingredient enhances and contributes to a more quantitative deposition of the renewable soil release agent, specifically the polyamines oxidized or not and/or the oxidized monoamines.
  • the renewable soil release agent which frequently is used in levels from 0.1% to 1.5% is represented by polyamines having the formula: wherein R is an alkyl or alkenyl group having 10 to 22 carbon atoms, the R i 's, which are identical or different, are ethylene oxide or propylene oxide, R 2 is hydrogen, C 1 - 4 alkyl or (R i )y, where x, y, and z are numbers such that the sum (x+y+z) is in the range from 2 to 25, n is a number from 1 to 6 and m is a number from 1 to 9; or amine oxides having the formula: wherein R is an alkyl or alkenyl group having 10 to 22 carbon atoms, the R 3 's which are identical or different are selected from C ' - 4 alkyl, ethylene oxide and propylene oxide, k is an integer from 1 to 6, is an integer from 0 to 6, p is 0 or 1, u, v, and w are each 1 for alkyl
  • a preferred polyamine for use herein is N-hydrogenated tallow C 16 ⁇ C 18 -N,N',N'-tri-(2-hydroxyethyl)-propylene-1,3-diamine.
  • Preferred amine oxide species are N-C 12 - 14 -coconutalkyl-N,N-dimethyl-N-amine oxide; N-tallow C 16-18 -alkyl-N,N',N-tri-(2-hydroxyethyl)-propylene-1,3-diamine-N,N'-dioxide; N-C 12-14- alkyl-N,N',N'-tri-(2-hydroxyethyl)-propylene-1,3-diamine-N,N'-dioxide; N-C 16-18 -tallow-alkyl-N, N-dimethyl-N-amine oxide; N-C 12-14 -coconutalkyl-N,N-di(2-hydroxyethyl)-N-amine
  • compositions of this invention can comprise a series of supplementary components to perfect and complement the performance advantages derived from the compositions.
  • additional components include brighteners, dyes, perfumes, bactericides, and antioxidants, processing aids, corrosion inhibitors, enzymes and so on.
  • processing aids i.e., frequently in the range from 0.1% to 5%.
  • the following granular detergent compositions are prepared by conventional spray-drying of a slurry of individual ingredients and subsequent dry-mixing of this base powder with spray-drying sensitive ingredients.
  • Solid detergent compositions are prepared having the following formulae.
  • a liquid detergent composition is made by mixing the following individual ingredients.

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Detergent Compositions (AREA)

Claims (4)

1. Eine Reinigungsmittelzusammensetzung mit einer üblichen Matrix auf Basis von grenzflächenaktiven Mitteln, Gerüststoffen, wirkungsfördernden Zusätzen und einem Copolymerbestandteil, dadurch gekennzeichnet, daß der wirkungsfördernde Zusatz in einer Menge von 0,002 Gew.-% bis 5 Gew.-% vorliegt und ausgewählt ist aus:
(a) einem wasserlöslichen Photoaktivator aus der Porphin-oder Mono-, Di-, Tri- oder Tetraazaporphingruppe, der mit anionischen, nichtionischen und/oder kationischen Substituentengruppen löslich gemacht und metallfrei oder mit Zn(11), Ca(ll), Cd(II), Mg(11), Sc(lll), Al(lll) oder Sn(IV) metallisiert ist; und
(b) einem Schmutzfreisetzungsmittel, das ein Polyamin der Formel
Figure imgb0008
worin R eine Alkyl- oder Alkenylgruppe mit 10 bis 22 Kohlenstoffatomen ist, die Reste Ri, welche gleich oder verschieden sind, Ethylenoxid oder Propylenoxid sind, R2 Wasserstoff, C1-4-Alkyl oder (R1)y ist, wobei x, y und z Zahlen derart sind, daß die Summe (x+y+z) im Bereich von 2 bis 25 liegt, n eine Zahl von 1 bis 6 ist, und m eine Zahl von 1 bis etwa 9 ist; oder eine Aminoxid der Formel:
Figure imgb0009
worin R eine Alkyl- oder Alkenylgruppe mit 10 bis 22 Kohlenstoffatomen ist, die Reste R3, die gleich oder verschieden sind, aus C1-4-Alkyl, Ethylenoxid und Propylenoxid ausgewählt sind, k eine ganze Zahl von 1 bis 6 ist, I eine ganze Zahl von 0 bis 6 ist, p 0 oder 1 ist, und u, v und w für Alkylsubstituenten jeweils 1 sind, und der artige ganze Zahlen im Bereich von 1 bis 10 für Ethylenoxid- oder Propylenoxidsubstituenten darstellen, daß die Summe von (u+v+w) nicht mehr als 25 beträgt, ist;

und daß der Copolymerbestandteil aus einem ethylenisch ungesättigten Monocarbonsäuremonomer mit nicht mehr als 5, vorzugsweise 3 oder 4, Kohlenstoffatomen, und einem ethylenisch ungesättigten Dicarbonsäuremonomer mit nicht mehr als 6, vorzugsweise 4, Kohlenstoffatomen besteht, wobei das Molverhältnis der Monomeren im Bereich von 1:4 bis 4:1 liegt; und wobei das Gewichtsverhältnis des Copolymers zum wirkungsfördernden Zusatz im Bereich von 500:1 bis 1:5 liegt.
2. Die Reinigungsmittelzusammensetzung nach Anspruch 1, wobei der Copolymerbestandteil aus (Meth)-acrylsäure- und Maleinsäuremonomeren besteht.
3. Die Reinigungsmittelzusammensetzung nach Anspruch 1, wobei der Photoaktivator in einer Menge von 20 TpM bis 2000 TpM vorliegt, und wobei das Gewichtsverhältnis von Copolymer zu Photoaktivator im Bereich von 500:1 bis 7:1 liegt.
4. Die Reinigungsmittelzusammensetzung nach Anspruch 1, wobei das Schmutzfreisetzungsmittel in einer Menge von 0,1 Gew.-% bis 1,5 Gew.-% bei einem Gewichtsverhältnis von Copolymer zu wirkungsförderndem Zusatz im Bereich von 10:1 bis 1:1 vorliegt, und wobei eine 1 %ige wässerige Lösung der Reinigungsmittelzusammensetzung einen alkalischen pH-Wert (20°C) aufweist.
EP82200602A 1981-05-30 1982-05-17 Reinigungsmittelzusammensetzung enthaltend einen wirkungsfördernden Zusatz und ein Kopolymer zum Gewährleisten der Verträglichkeit desselben Expired EP0066915B1 (de)

Priority Applications (1)

Application Number Priority Date Filing Date Title
AT82200602T ATE30738T1 (de) 1981-05-30 1982-05-17 Reinigungsmittelzusammensetzung enthaltend einen wirkungsfoerdernden zusatz und ein kopolymer zum gewaehrleisten der vertraeglichkeit desselben.

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GB8116607 1981-05-30
GB8116607 1981-05-30

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EP0066915A2 EP0066915A2 (de) 1982-12-15
EP0066915A3 EP0066915A3 (en) 1985-01-16
EP0066915B1 true EP0066915B1 (de) 1987-11-11

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AT (1) ATE30738T1 (de)
CA (1) CA1187373A (de)
DE (1) DE3277630D1 (de)

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US7867963B2 (en) 2007-06-12 2011-01-11 Rhodia Inc. Mono-, di- and polyol phosphate esters in personal care formulations
US7919073B2 (en) 2007-06-12 2011-04-05 Rhodia Operations Mono-, di- and polyol alkoxylate phosphate esters in oral care formulations and methods for using same
US7919449B2 (en) 2007-06-12 2011-04-05 Rhodia Operations Detergent composition with hydrophilizing soil-release agent and methods for using same
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* Cited by examiner, † Cited by third party
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DE3323621A1 (de) * 1982-07-08 1984-03-01 Yamasa Shoyu K.K., Choshi, Chiba Pharmazeutisches praeparat mit die antitumor-wirkung verstaerkender wirkung, ein solches praeparat enthaltende chemotherapeutische zusammensetzung und verwendung des praeparates zur unterstuetzung der antitumor-behandlung beim menschen und tier
DE3460228D1 (en) * 1983-04-08 1986-07-24 Procter & Gamble Granular detergent compositions containing mixed polymer additive system
DE3329400A1 (de) * 1983-08-13 1985-02-28 Henkel KGaA, 4000 Düsseldorf Vergrauungsverhuetender zusatz fuer phosphatfreie und phosphatarme waschmittel
GB2177717B (en) * 1983-09-09 1987-09-23 Godrej Soaps Ltd Laundry detergent composition containing alpha olefin sulphonate
DE3340164A1 (de) * 1983-11-07 1985-05-23 S.A. Camp, Fábrica de Jabones, Granollers, Barcelona Waschmittel
US4609473A (en) * 1984-11-26 1986-09-02 Colgate Palmolive Company Bentonite-sulfate fabric softening particulate agglomerate, processes for manufacture and use thereof, and detergent compositions containing it
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GB8730205D0 (en) * 1987-12-24 1988-02-03 Unilever Plc Detergent composition
DE4312972A1 (de) * 1993-04-21 1994-10-27 Basf Ag Verwendung von alkoxylierten Polyaminen und deren N--Oxiden als Hilfsmittel für die Lederfärbung
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Family Cites Families (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DK130544A (de) * 1968-11-27
DE2816770C2 (de) * 1977-04-22 1984-10-18 The Procter & Gamble Co., Cincinnati, Ohio Gerüststoffhaltiges Textilwaschmittel
DE2936984A1 (de) * 1979-09-13 1981-04-02 Basf Ag, 6700 Ludwigshafen Verwendung von (meth)acrylsaeure-maleinsaeure-copolymerisaten als inkrustierungsinhibitoren in waschmitteln
GR76045B (de) * 1981-04-08 1984-08-03 Procter & Gamble

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ATE30738T1 (de) 1987-11-15
EP0066915A3 (en) 1985-01-16
CA1187373A (en) 1985-05-21
EP0066915A2 (de) 1982-12-15

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